The aim of the present study was to evaluate the effects of baobab seed washing and origin on the chemical composition of the oil extracted by pressing. Six (6) oil samples were obtained from seeds of three (3) geogra...The aim of the present study was to evaluate the effects of baobab seed washing and origin on the chemical composition of the oil extracted by pressing. Six (6) oil samples were obtained from seeds of three (3) geographical origins. The identification and quantification of fatty acids and the polyphenolic profile were carried out by GC-MS and HPLC-UV, respectively. Analysis of fatty acid methyl esters allowed the identification and quantification of 18 fatty acids. Oils from unwashed seeds were richer in palmitic (C16:0), stearic (C18:0), oleic (C18:1) and arachidic (C20:0) acids. In addition, HPLC-UV analysis at 279 nm shows that oils from unwashed seeds are richer in tyrosol, hydroxytyrosol and caffeic acid. With regard to the polyphenolic profile, gallic acid and quercetin were not detected in these baobab oils. Principal component analysis of fatty acid and phenolic compound content showed that oils from unwashed seeds would best preserve their chemical and associated potential bioactive characteristics.展开更多
Due to their resource constraints,Internet of Things(IoT)devices require authentication mechanisms that are both secure and efficient.Elliptic curve cryptography(ECC)meets these needs by providing strong security with...Due to their resource constraints,Internet of Things(IoT)devices require authentication mechanisms that are both secure and efficient.Elliptic curve cryptography(ECC)meets these needs by providing strong security with shorter key lengths,which significantly reduces the computational overhead required for authentication algorithms.This paper introduces a novel ECC-based IoT authentication system utilizing our previously proposed efficient mapping and reverse mapping operations on elliptic curves over prime fields.By reducing reliance on costly point multiplication,the proposed algorithm significantly improves execution time,storage requirements,and communication cost across varying security levels.The proposed authentication protocol demonstrates superior performance when benchmarked against relevant ECC-based schemes,achieving reductions of up to 35.83%in communication overhead,62.51%in device-side storage consumption,and 71.96%in computational cost.The security robustness of the scheme is substantiated through formal analysis using the Automated Validation of Internet Security Protocols and Applications(AVISPA)tool and Burrows-Abadir-Needham(BAN)logic,complemented by a comprehensive informal analysis that confirms its resilience against various attack models,including impersonation,replay,and man-in-the-middle attacks.Empirical evaluation under simulated conditions demonstrates notable gains in efficiency and security.While these results indicate the protocol’s strong potential for scalable IoT deployments,further validation on real-world embedded platforms is required to confirm its applicability and robustness at scale.展开更多
The scalable integration of two-dimensional(2D)lamellar nanomaterials into flexible films opens up innovative possibilities for enhancing the performance and functionality of energy storage devices.However,a significa...The scalable integration of two-dimensional(2D)lamellar nanomaterials into flexible films opens up innovative possibilities for enhancing the performance and functionality of energy storage devices.However,a significant challenge lies in balancing mechanical strength with optimal energy storage properties.Achieving the necessary flexibility while maintaining high energy density and durability is complex due to the inherent trade-off between these properties.To address this issue and improve the overall performance of such nanomaterial films,researchers are exploring novel approaches such as hybridization with other materials,optimization of layer structures,and innovative fabrication techniques.In this vein,the emergence of hybrid nanomaterials composed of metal-organic frameworks(MOFs)and 2D MXene sheets offers exciting opportunities in the development of advanced materials for diverse applications.These MOF/MXene hybrid architectures exhibit a unique synergy that combines the exceptional surface area and tunable porosity of MOFs with the high electrical conductivity and mechanical strength of MXenes.This integration leads to the creation of versatile,multifunctional materials with promising capabilities in electrochemical energy storage and conversion,as well as environmental remediation.Hence,the present review delves into the various synthesis techniques employed to produce MOF/MXene hybrids,along with their diverse morphologies and properties,and examines the latest advancements in tailoring these nanoarchitectures for enhanced performance and efficiency.Additionally,the challenges and opportunities for future research are discussed in order to highlight the potential of these hybrid materials in pushing the boundaries of technological innovation across multiple scientific disciplines.展开更多
Reliable and efficient communication is essential for Unmanned Aerial Vehicle(UAV)networks,especially in dynamic and resource-constrained environments such as disaster management,surveillance,and environmental monitor...Reliable and efficient communication is essential for Unmanned Aerial Vehicle(UAV)networks,especially in dynamic and resource-constrained environments such as disaster management,surveillance,and environmental monitoring.Frequent topology changes,high mobility,and limited energy availability pose significant challenges to maintaining stable and high-performance routing.Traditional routing protocols,such as Ad hoc On-Demand Distance Vector(AODV),Load-Balanced Optimized Predictive Ad hoc Routing(LB-OPAR),and Destination-Sequenced Distance Vector(DSDV),often experience performance degradation under such conditions.To address these limitations,this study evaluates the effectiveness of Dynamic Adaptive Routing(DAR),a protocol designed to adapt routing decisions in real time based on network dynamics and resource constraints.The research utilizes the Network Simulator 3(NS-3)platform to conduct controlled simulations,measuring key performance indicators such as latency,Packet Delivery Ratio(PDR),energy consumption,and throughput.Comparative analysis reveals that DAR consistently outperforms conventional protocols,achieving a 20%-30% reduction in latency,a 25% decrease in energy consumption,and marked improvements in throughput and PDR.These results highlight DAR’s ability to maintain high communication reliability while optimizing resource usage in challenging operational scenarios.By providing empirical evidence of DAR’s advantages in highly dynamic UAV network environments,this study contributes to advancing adaptive routing strategies.The findings not only validate DAR’s robustness and scalability but also lay the groundwork for integrating artificial intelligence-driven decision-making and real-world UAV deployment.Future work will explore cross-layer optimization,multi-UAV coordination,and experimental validation in field trials,aiming to further enhance communication resilience and energy efficiency in next-generation aerial networks.展开更多
<span style="font-family:Verdana;">In this article, the effect of temperature on the photovoltaic parameters of mono-crystalline silicon Photovoltaic Panel is undertaken, using the Matlab environment w...<span style="font-family:Verdana;">In this article, the effect of temperature on the photovoltaic parameters of mono-crystalline silicon Photovoltaic Panel is undertaken, using the Matlab environment with varying module temperature in the range 25°C - 60°C at constant solar irradiations 200 - 500 W/m</span><sup><span style="font-family:Verdana;">2</span><span></span></sup><span style="font-family:Verdana;">.</span><span style="font-family:Verdana;"> The results show that the temperature has a significant impact on the various parameters of the photovoltaic panel and it controls the quality and performance of the solar panel</span><span style="font-family:Verdana;">.</span><span style="font-family:Verdana;"> The photovoltaic</span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span><span style="font-family:Verdana;">parameters are the current of short circuit </span><i></i></span><i><i><span><span style="font-family:Verdana;">I</span><sub><span style="font-family:Verdana;">sc</span></sub></span></i><span></span></i><span style="font-family:Verdana;">, the open circuit voltage </span><i></i></span><i><i><span><span style="font-family:Verdana;">V</span><sub><span style="font-family:Verdana;">co</span></sub></span></i><span></span></i><span style="font-family:Verdana;">, the form factor FF, the maximum power </span><i><i><span><span style="font-family:Verdana;">P</span><sub></sub></span></i><i><span style="font-family:Verdana;"><sub>max</sub></span></i><i><span></span></i><span></span></i><span style="font-family:Verdana;"> as well as efficiency. The relative change of these photovoltaic parameters with temperature is also evaluated in this article. A DS-100M solar panel has been used as reference model. The results show also that the open circuit voltage, maximum power, fill factor and efficiency decrease with temperature</span><span style="font-family:Verdana;">,</span><span style="font-family:Verdana;"> but the short circuit current increase</span><span style="font-family:Verdana;">s</span><span style="font-family:Verdana;"> with temperature</span><span style="font-family:Verdana;">.</span><span style="font-family:Verdana;"> Th</span><span style="font-family:Verdana;">e</span><span style="font-family:Verdana;"> results are in good agreement with the available literature.</span>展开更多
One of the most common types of soil degradation is water erosion.It reduces soil quality at the erosion site and may cause sedimentation issues at the deposition site.This phenomenon is estimated using a variety of m...One of the most common types of soil degradation is water erosion.It reduces soil quality at the erosion site and may cause sedimentation issues at the deposition site.This phenomenon is estimated using a variety of models.The Revised Universal Soil Loss Equation(RUSLE)model is the most often used,due to its consistence and low data requirement.It is useful for estimating annual soil loss at the watershed scale.To investigate the relationship between soil erosion and sediment deposition,the combined RUSLE and Sediment Delivery Ratio(SDR)models are used.The Wadi El Hachem watershed is a coastal and mountainous Mediterranean basin with rugged topography and high degree of climatic aggressiveness.Both of these characteristics can have an immediate effect on soil erosion and sediment yield.This research includes estimating the Average Annual Soil Loss(A)and Sediment Yield(SY)in the Wadi El Hachem watershed,mapping different RUSLE factors as well as A and SY,and studying the influence of rainfall erosivity(R)on A and SY in dry and rainy years.The A results vary from 0 to 410 t·ha^(-1)·yr^(-1)with an annual average of 52 t·ha^(-1)·yr^(-1).The Renfro's SDR model was selected as the best model for estimating SY,with standard error,standard deviation,coefficient of variation,and Nash–Sutcliffe efficiency(NSE)values of 0.38%,0.02,0.07%,and 1.00,respectively.The average SY throughout the whole watershed is around 27 t·ha^(-1)·yr^(-1).The SY map for the entire Wadi El Hachem watershed revealed that sediment production zones are mainly concentrated in the Northeast of the basin,at the basin’s outlet,and in the tributaries of the dam.The simulation results of soil loss and sediment yield in dry and rainy years revealed that R is one of the main factors affecting soil erosion and sediment deposition in the Wadi El Hachem watershed.The mean difference in R factor between dry year and rainy year is 671 MJ·mm·ha^(-1)·h^(-1)·yr^(-1).As a result of this fluctuation,the soil loss and sediment yield have increased by 15 and 8 t·ha^(-1)·yr^(-1),respectively.The results of this research can be used to provide scientific and technical support for conservation and management strategies of the Wadi El Hachem watershed.展开更多
Layered double hydroxides(LDH)frameworks have shown significant enhancement in stability and reusability,and their tailorable architecture brings new insight into the development of the next generation of hybrid mater...Layered double hydroxides(LDH)frameworks have shown significant enhancement in stability and reusability,and their tailorable architecture brings new insight into the development of the next generation of hybrid materials,which attracted considerable attention in many fields over the years.One of the factors contributing to the widespread applicability of layered double hydroxides is their adaptable composition,which can accommodate a wide spectrum of potential anionic vips.This exceptional property makes the LDH system simple to adjust for various applications.However,most LDH systems are synthesized in situ in an autoclave at high temperatures and pressures that severely restrict the industrial use of such coating systems.In this study,LDH was directly synthesized on a magnesium alloy that had undergone plasma electrolytic oxidation(PEO)treatment in the presence of ethylenediaminetetraacetic acid,thereby avoiding the use of hydrothermal autoclave conditions.This LDH system was compared with a hybrid architecture consisting of organic-inorganic self-assembly.An organic layer was fabricated on top of the LDH film using 4-Aminophenol(Aph)compound,resulting in a smart hierarchical structure that can provide a robust Aph@LDH film with excellent anti-corrosion performance.At the molecular level,the conjugation characteristics and adsorption mechanism of Aph molecule were studied using two levels of theory as follows.First,Localized orbit locator(LOL)-πisosurface,electrostatic potential(ESP)distribution,and average local ionization energy(ALIE)on the molecular surface were used to highlight localization region,reveal the favorable electrophilic and nucleophilic attacks,and clearly explore the type of interactions that occurred around interesting regions.Second,first-principles based on density functional theory(DFT)was applied to study the hybrid mechanism of Aph on LDH system and elucidate their mutual interactions.The experimental and computational analyses suggest that the highπ-electron density and delocalization characteristics of the functional groups and benzene ring in the Aph molecule played a leading role in the synergistic effects arising from the combination of organic and inorganic coatings.This work provides a promising approach to design advanced hybrid materials with exceptional electrochemical performance.展开更多
In this article, we give sufficient conditions for controllability of some partial neutral functional differential equations with infinite delay. We suppose that the linear part is not necessarily densely defined but ...In this article, we give sufficient conditions for controllability of some partial neutral functional differential equations with infinite delay. We suppose that the linear part is not necessarily densely defined but satisfies the resolvent estimates of the Hille-Yosida theorem. The results are obtained using the integrated semigroups theory. An application is given to illustrate our abstract result.展开更多
The effect of Argan plant extract (APE) on the corrosion of the steel in hydrochloric acid medium was studied using gravimetric, electrochemical polarization and impedance spectroscopy (EIS) measurements. Inhibiti...The effect of Argan plant extract (APE) on the corrosion of the steel in hydrochloric acid medium was studied using gravimetric, electrochemical polarization and impedance spectroscopy (EIS) measurements. Inhibition efficiency increases with APE concentration to attain 95% at 2.5 g/L. We note good agreement between gravimetric and electrochemical methods (potentiodynamic polarization and EIS). Effect of temperature is also made in the 298-328 K range. Polarization measurements show also that APE act as a mixed inhibitor. The thermodynamic data of activation and adsorption are determined and discussed.展开更多
In the Lower Cheliff Plain (northwestern of Algeria), the waters resources are limited; the adoption of a rational approach in the management of irrigation water in the irrigated perimeter poses an inequality in the...In the Lower Cheliff Plain (northwestern of Algeria), the waters resources are limited; the adoption of a rational approach in the management of irrigation water in the irrigated perimeter poses an inequality in the balance between supply and demand. The two surface water resources, Gargar and Merdjet Sidi Abed dams, do not satisfy the requirements of agriculture water. According to the National Office of the Irrigation and Drainage data, the quantity of allocated water is never distributed; the difference between allocated water and drop water can also exceed 20%, and then, another problem of management is that the water losses in the distribution can reach 20% again. The shortage irrigation water resource allocated has constrained the farmers to use groundwater. The chemical analysis of 56 simples to this water showed a significant chemical diversity in the compositions. There is a high salinity risk (C3 class) or very high risk (C4 class) of soil salinisation. A space chart distribution to the EC water probability to exceed 2.25 dS/m interpolated by the indicator kriging method showed that 78% of the groundwater surface presents a significant probability to exceed this limit. The average value of the SAR (sodium adsorption ratio) is lower than 10 that indicates a moderate risk of sodisation. This observation is in contradiction with the high values of the SAR measured in the soil solution. The approach of residual alkalinity (RSC) shows that a good number of drillings analyzed presents a positive sign RSC (RSC 〉 0). This water presents a real danger of sodisation. They have a low salinity, which, for a farmer, does not present any danger.展开更多
During the last decade, Jatropha curcas L. (J. curcas) has gained much attention worldwide as biofuel crop. Although its cultivation is promoted in the Sahel, there is a surprising lack of data on its water use regula...During the last decade, Jatropha curcas L. (J. curcas) has gained much attention worldwide as biofuel crop. Although its cultivation is promoted in the Sahel, there is a surprising lack of data on its water use regulation and growth in this region. Here, we investigated, in semi-controlled conditions, leaf transpiration and growth of six accessions of J. curcas at seedling stage under natural changing in vapour pressure deficit (VPD) and progressive soil drying in Senegal. The experimental layout was a randomized complete bloc design and after 3 months of growth arranged to a split-plot at the implementation of water stress to facilitate irrigation. Under well water condition, there was no significant difference between accessions for leave transpiration that was positively correlated to VPD with high values recorded between 13 h and 14 h pm. Accessions of J. curcas used in this study showed closed thresholds at which transpiration declined except accession from Ndawene that threshold was lower (0.30). There is no significant difference between accessions for growth during the experimentation period. In 3 months, we recorded 23.57 g for the aboveground dry biomass and seedlings had about 14 leaves and 24.3 cm height. Positive linear correlation was recorded between aboveground biomass and root dry weight (p J. curcas might need complement irrigation for a better growth of seedlings especially during the dry season.展开更多
Background: Investigating population ecology of urban bird species,particularly the invasive and expending spe?cies,is the key for the success of urban management and planning strategies.Methods: Populations of two Co...Background: Investigating population ecology of urban bird species,particularly the invasive and expending spe?cies,is the key for the success of urban management and planning strategies.Methods: Populations of two Columbidae species,the Woodpigeon(Columba palumbus) and the Eurasian Collared Dove(Streptopelia decaocto),were monitored from 1992 to 2010 in the Algiers Sahel,the Mitidja Plain and surround?ing areas(Northern Algeria).Monitoring of species densities was performed by the mapping?plot method.The foraging flight routes of Woodpigeon and the distribution of Eurasian Collared Dove were assessed by systematic observations.Results: The number of counted birds was statistically constant at first years of the survey,and then increased sig?nificantly,beginning from low numbers,their densities accelerated sharply between 2001 and 2006,then reached to an equilibrium state.The significant increase in Woodpigeon's population could be explained by the reduced hunt?ing pressure and by species adaptation to new food resources provided by nearby agriculture.Indeed,monitoring of flight directions of the species revealed the use of agricultural landscapes and habitats,which is a good indicator explaining adaptation and trophic niche of the species.The occurrence of the Eurasian Collared Dove in Algiers began in 2000.Its density experienced a rapid increase with similar trend pattern as that of Woodpigeon.Its distributional range is confined mainly in suburban environments of the Mitidja Plain.Conclusion: The modifications of habitats,urbanization increase and the lessening of hunting in the Mitidja Plain facilitated the rapid expansion of the Eurasian Collared Dove and Woodpigeon as well contributed to the increase in their numbers over time.展开更多
Casamance was perceived as an agricultural granary that had rice potential which could meet the high food demand of Senegal. Given that the rice-growing lands have been degraded due to pedoclimatic variabilities, impr...Casamance was perceived as an agricultural granary that had rice potential which could meet the high food demand of Senegal. Given that the rice-growing lands have been degraded due to pedoclimatic variabilities, improved modern varieties are not usually well adapted to the Casamance rice-growing ecosystems. This work aims to contribute to the increase of rice production through varietal diversification and enhancement of cultural heritage. A participatory evaluation of five local farmers’ traditional varieties along with one check was carried out in an experiment laid out in a one-factor complete randomized block design using the six accessions with five replications. ANOVA followed by a 5% mean comparison Tukey test and the Kendall Rate were performed with IBM SPSS Statistics software. The result showed very significant varietal differences for leaf blade of the penultimate leaves, 100-grains weight, panicle length, growth cycle, plant height, ramification of secondary branching of the spikelets, resistance to lodging and threshing facility (p ≤ 0.005). However, traits including flag leaf, tiller numbers, sterile tillers number, panicle numbers, panicle yield, and grain yield did not show a significant difference (p ≥ 0.06) among varieties. Thus, based on some of these characteristics, farmers selected their most preferred rice varieties or accessions. The most important characteristics were tillering ability, lodging resistance and fertility rate. Koussik Emandiouck selected by farmers as the best variety, had a high grain yield (4.9 t∙ha<sup>-1</sup>), higher lodging resistance (9), and higher fertility rate (80.53%). Koussik Emandiouck, Koufekeny and Awandiaho varieties were the most preferred by farmers.展开更多
In this paper, authors describe how to carry out a research assessing the impact of storage temperature on the stability and biocidal activity of formulated essential oils. Cereals, like other stored food, currently e...In this paper, authors describe how to carry out a research assessing the impact of storage temperature on the stability and biocidal activity of formulated essential oils. Cereals, like other stored food, currently experience serious health problems of storage. The offending agents are primary pests such as Sitophilusoryzae and secondary pests including Tribolium. This study focused on the evaluation of the biocidal effect on the essential oils of thyme and citrus, against red flour beetle adults (Triboliumcastaneum) under different temperature regimes. The results showed that different molecules produced a delayed effect (12 h-14 h-16 h-I 8 h) on the populations of Triboliumcastaneum at the storage temperature of 20 ~C. The same results showed an early striking effect of thymol and carvacrol on Triboliumcastaneum compared to limonene. The toxicity of thymol and carvacrol was much more active than limonene at 12 h, which was very remarkable as limonene expressed its toxicity from 14 h with a deadly effect. When temperatures are under 20 ℃ and 25℃, thymol showed a greater degree of efficiency followed by carvacrol and limonene which had lower efficiency. However, at 28℃, carvacrol expressed a very significant biocidal effect compared to the other two formulations, thymol and limonene.展开更多
Multi-layer membrane filtration is a widely used technology for separating and purifying different components ofa liquid mixture. This technique involves passing the liquid mixture through a series of membranes with d...Multi-layer membrane filtration is a widely used technology for separating and purifying different components ofa liquid mixture. This technique involves passing the liquid mixture through a series of membranes with decreasing pore sizes, which allows for the separation of different components according to their molecular size. Thisstudy investigates the filtration process of a fluid through a two-dimensional porous medium designed forseawater desalination. The focus is on understanding the impact of various parameters such as the coefficientof friction, velocity, and the number of layers on filtration efficiency. The results reveal that the number of layersplays a crucial role in desalination, with an increase in layers leading to enhanced filtration quality, following apower law relationship. The study explores the influence of the coefficient of friction on filtration performance,emphasizing its significant effect on the number of particles filtered over time. Additionally, the role of the initialvelocity in filtration efficiency is examined, showing distinct effects at both high and low velocities. Biofouling isidentified as a factor influencing filtration, with an initial increase in filtered particles followed by a decline due toparticle accumulation in pores.展开更多
We report on the structural,magnetic,and magnetocaloric properties of EuRhO_(3) powders.The oxidation states of Eu and Rh ions were studied using X-ray photoelectron spectroscopy(XPS).It is found that the Eu ions are ...We report on the structural,magnetic,and magnetocaloric properties of EuRhO_(3) powders.The oxidation states of Eu and Rh ions were studied using X-ray photoelectron spectroscopy(XPS).It is found that the Eu ions are mainly in the divalent oxidation state while the Rh ions have+4 state.EuRhO_(3) powders are found to be antiferromagnetic with a second order magnetic transition at Neel temperature(T_(N)=2.9 K).Analysis of the magnetic susceptibility versus temperature data in terms of the Curie=Weiss law:(χ=C/(T-θ_(W))) for T>T_(N),yields θ_(W)=-3.1 K and effective magne tic moment μ_(ff)^(exp),which is close to the theoretical value μ_(eff)^(theo).The magnetic entropy change(-Δ_(SM)),was determined by em ploying the thermodynam ic Maxwell's relation.At μ_0H=5 T and near T_(N),ΔS_(M)^(Max) and relative cooling power(RCP) exhibit large values of 33.7 J/(kg·K) and 238 J/kg,respectively.The large magnitude of-Δ_(SM) and RCP show that the EuRhO_(3) compound could be a potential candidate to be used in cryogenic magnetic refrigeration.展开更多
Today, various traditional country foods are increasingly being neglected as a result of modernisation. Consequently, the knowledge and know-how necessary to prepare those foods are strongly threatened. To safeguard a...Today, various traditional country foods are increasingly being neglected as a result of modernisation. Consequently, the knowledge and know-how necessary to prepare those foods are strongly threatened. To safeguard and foster appreciation of traditional knowledge, this study aims, on the one hand, to describe the manufacturing process of an alcoholic drink called “Mbite”. The latter is traditionally prepared with the fruits of Sclerocarya birrea (A. Rich) Hostcht in Senegal. On the other hand, various controlled fermentations have been tested for better control of their hygienic and sanitary qualities. The manufacturing of “Mbite” drink begins with a manual extraction of the juice using stems of Guiera senegalensis or Combretum glutinosum to facilitate the separation of the pericarp from the almond. Subsequently, the extracts are filtered and/or mixed according to the producers. Finally, a 2-day spontaneous fermentation by endogenous yeasts of the fruit makes it possible to obtain the alcoholic drink within 3 days. “Mbite” is a low acid drink with a pH ranging from 3.82 to 3.97 and its ethanol content varies from 2 to 4% (v/v). Polyphenols vary between 124.92 and 158.25 mg/100 mL. However, microbiological analyses have shown a high number of lactic acid bacteria involved in the formation of volatile acids. The controlled fermentation trials have resulted in a unique alcoholic fermentation of Sclerocarya birrea juices by selected strains of Saccharomyces cerevisae. This has the advantage of guaranteeing sanitary qualities and reducing the fermentation time from three days to one.展开更多
文摘The aim of the present study was to evaluate the effects of baobab seed washing and origin on the chemical composition of the oil extracted by pressing. Six (6) oil samples were obtained from seeds of three (3) geographical origins. The identification and quantification of fatty acids and the polyphenolic profile were carried out by GC-MS and HPLC-UV, respectively. Analysis of fatty acid methyl esters allowed the identification and quantification of 18 fatty acids. Oils from unwashed seeds were richer in palmitic (C16:0), stearic (C18:0), oleic (C18:1) and arachidic (C20:0) acids. In addition, HPLC-UV analysis at 279 nm shows that oils from unwashed seeds are richer in tyrosol, hydroxytyrosol and caffeic acid. With regard to the polyphenolic profile, gallic acid and quercetin were not detected in these baobab oils. Principal component analysis of fatty acid and phenolic compound content showed that oils from unwashed seeds would best preserve their chemical and associated potential bioactive characteristics.
文摘Due to their resource constraints,Internet of Things(IoT)devices require authentication mechanisms that are both secure and efficient.Elliptic curve cryptography(ECC)meets these needs by providing strong security with shorter key lengths,which significantly reduces the computational overhead required for authentication algorithms.This paper introduces a novel ECC-based IoT authentication system utilizing our previously proposed efficient mapping and reverse mapping operations on elliptic curves over prime fields.By reducing reliance on costly point multiplication,the proposed algorithm significantly improves execution time,storage requirements,and communication cost across varying security levels.The proposed authentication protocol demonstrates superior performance when benchmarked against relevant ECC-based schemes,achieving reductions of up to 35.83%in communication overhead,62.51%in device-side storage consumption,and 71.96%in computational cost.The security robustness of the scheme is substantiated through formal analysis using the Automated Validation of Internet Security Protocols and Applications(AVISPA)tool and Burrows-Abadir-Needham(BAN)logic,complemented by a comprehensive informal analysis that confirms its resilience against various attack models,including impersonation,replay,and man-in-the-middle attacks.Empirical evaluation under simulated conditions demonstrates notable gains in efficiency and security.While these results indicate the protocol’s strong potential for scalable IoT deployments,further validation on real-world embedded platforms is required to confirm its applicability and robustness at scale.
基金the Deanship of Scientific Research at King Khalid University for funding this work through the Large Group Research Project[grant number RGP2/300/46]。
文摘The scalable integration of two-dimensional(2D)lamellar nanomaterials into flexible films opens up innovative possibilities for enhancing the performance and functionality of energy storage devices.However,a significant challenge lies in balancing mechanical strength with optimal energy storage properties.Achieving the necessary flexibility while maintaining high energy density and durability is complex due to the inherent trade-off between these properties.To address this issue and improve the overall performance of such nanomaterial films,researchers are exploring novel approaches such as hybridization with other materials,optimization of layer structures,and innovative fabrication techniques.In this vein,the emergence of hybrid nanomaterials composed of metal-organic frameworks(MOFs)and 2D MXene sheets offers exciting opportunities in the development of advanced materials for diverse applications.These MOF/MXene hybrid architectures exhibit a unique synergy that combines the exceptional surface area and tunable porosity of MOFs with the high electrical conductivity and mechanical strength of MXenes.This integration leads to the creation of versatile,multifunctional materials with promising capabilities in electrochemical energy storage and conversion,as well as environmental remediation.Hence,the present review delves into the various synthesis techniques employed to produce MOF/MXene hybrids,along with their diverse morphologies and properties,and examines the latest advancements in tailoring these nanoarchitectures for enhanced performance and efficiency.Additionally,the challenges and opportunities for future research are discussed in order to highlight the potential of these hybrid materials in pushing the boundaries of technological innovation across multiple scientific disciplines.
文摘Reliable and efficient communication is essential for Unmanned Aerial Vehicle(UAV)networks,especially in dynamic and resource-constrained environments such as disaster management,surveillance,and environmental monitoring.Frequent topology changes,high mobility,and limited energy availability pose significant challenges to maintaining stable and high-performance routing.Traditional routing protocols,such as Ad hoc On-Demand Distance Vector(AODV),Load-Balanced Optimized Predictive Ad hoc Routing(LB-OPAR),and Destination-Sequenced Distance Vector(DSDV),often experience performance degradation under such conditions.To address these limitations,this study evaluates the effectiveness of Dynamic Adaptive Routing(DAR),a protocol designed to adapt routing decisions in real time based on network dynamics and resource constraints.The research utilizes the Network Simulator 3(NS-3)platform to conduct controlled simulations,measuring key performance indicators such as latency,Packet Delivery Ratio(PDR),energy consumption,and throughput.Comparative analysis reveals that DAR consistently outperforms conventional protocols,achieving a 20%-30% reduction in latency,a 25% decrease in energy consumption,and marked improvements in throughput and PDR.These results highlight DAR’s ability to maintain high communication reliability while optimizing resource usage in challenging operational scenarios.By providing empirical evidence of DAR’s advantages in highly dynamic UAV network environments,this study contributes to advancing adaptive routing strategies.The findings not only validate DAR’s robustness and scalability but also lay the groundwork for integrating artificial intelligence-driven decision-making and real-world UAV deployment.Future work will explore cross-layer optimization,multi-UAV coordination,and experimental validation in field trials,aiming to further enhance communication resilience and energy efficiency in next-generation aerial networks.
文摘<span style="font-family:Verdana;">In this article, the effect of temperature on the photovoltaic parameters of mono-crystalline silicon Photovoltaic Panel is undertaken, using the Matlab environment with varying module temperature in the range 25°C - 60°C at constant solar irradiations 200 - 500 W/m</span><sup><span style="font-family:Verdana;">2</span><span></span></sup><span style="font-family:Verdana;">.</span><span style="font-family:Verdana;"> The results show that the temperature has a significant impact on the various parameters of the photovoltaic panel and it controls the quality and performance of the solar panel</span><span style="font-family:Verdana;">.</span><span style="font-family:Verdana;"> The photovoltaic</span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span><span style="font-family:Verdana;">parameters are the current of short circuit </span><i></i></span><i><i><span><span style="font-family:Verdana;">I</span><sub><span style="font-family:Verdana;">sc</span></sub></span></i><span></span></i><span style="font-family:Verdana;">, the open circuit voltage </span><i></i></span><i><i><span><span style="font-family:Verdana;">V</span><sub><span style="font-family:Verdana;">co</span></sub></span></i><span></span></i><span style="font-family:Verdana;">, the form factor FF, the maximum power </span><i><i><span><span style="font-family:Verdana;">P</span><sub></sub></span></i><i><span style="font-family:Verdana;"><sub>max</sub></span></i><i><span></span></i><span></span></i><span style="font-family:Verdana;"> as well as efficiency. The relative change of these photovoltaic parameters with temperature is also evaluated in this article. A DS-100M solar panel has been used as reference model. The results show also that the open circuit voltage, maximum power, fill factor and efficiency decrease with temperature</span><span style="font-family:Verdana;">,</span><span style="font-family:Verdana;"> but the short circuit current increase</span><span style="font-family:Verdana;">s</span><span style="font-family:Verdana;"> with temperature</span><span style="font-family:Verdana;">.</span><span style="font-family:Verdana;"> Th</span><span style="font-family:Verdana;">e</span><span style="font-family:Verdana;"> results are in good agreement with the available literature.</span>
基金the framework of the SWATCH project (Prima project)funded by the DGRSDT,Algeria
文摘One of the most common types of soil degradation is water erosion.It reduces soil quality at the erosion site and may cause sedimentation issues at the deposition site.This phenomenon is estimated using a variety of models.The Revised Universal Soil Loss Equation(RUSLE)model is the most often used,due to its consistence and low data requirement.It is useful for estimating annual soil loss at the watershed scale.To investigate the relationship between soil erosion and sediment deposition,the combined RUSLE and Sediment Delivery Ratio(SDR)models are used.The Wadi El Hachem watershed is a coastal and mountainous Mediterranean basin with rugged topography and high degree of climatic aggressiveness.Both of these characteristics can have an immediate effect on soil erosion and sediment yield.This research includes estimating the Average Annual Soil Loss(A)and Sediment Yield(SY)in the Wadi El Hachem watershed,mapping different RUSLE factors as well as A and SY,and studying the influence of rainfall erosivity(R)on A and SY in dry and rainy years.The A results vary from 0 to 410 t·ha^(-1)·yr^(-1)with an annual average of 52 t·ha^(-1)·yr^(-1).The Renfro's SDR model was selected as the best model for estimating SY,with standard error,standard deviation,coefficient of variation,and Nash–Sutcliffe efficiency(NSE)values of 0.38%,0.02,0.07%,and 1.00,respectively.The average SY throughout the whole watershed is around 27 t·ha^(-1)·yr^(-1).The SY map for the entire Wadi El Hachem watershed revealed that sediment production zones are mainly concentrated in the Northeast of the basin,at the basin’s outlet,and in the tributaries of the dam.The simulation results of soil loss and sediment yield in dry and rainy years revealed that R is one of the main factors affecting soil erosion and sediment deposition in the Wadi El Hachem watershed.The mean difference in R factor between dry year and rainy year is 671 MJ·mm·ha^(-1)·h^(-1)·yr^(-1).As a result of this fluctuation,the soil loss and sediment yield have increased by 15 and 8 t·ha^(-1)·yr^(-1),respectively.The results of this research can be used to provide scientific and technical support for conservation and management strategies of the Wadi El Hachem watershed.
基金supported by the Fundamental-Core National Project of the National Research Foundation(NRF)funded by the Ministry of Science and ICT,Republic of Korea(2022R1F1A1072739).
文摘Layered double hydroxides(LDH)frameworks have shown significant enhancement in stability and reusability,and their tailorable architecture brings new insight into the development of the next generation of hybrid materials,which attracted considerable attention in many fields over the years.One of the factors contributing to the widespread applicability of layered double hydroxides is their adaptable composition,which can accommodate a wide spectrum of potential anionic vips.This exceptional property makes the LDH system simple to adjust for various applications.However,most LDH systems are synthesized in situ in an autoclave at high temperatures and pressures that severely restrict the industrial use of such coating systems.In this study,LDH was directly synthesized on a magnesium alloy that had undergone plasma electrolytic oxidation(PEO)treatment in the presence of ethylenediaminetetraacetic acid,thereby avoiding the use of hydrothermal autoclave conditions.This LDH system was compared with a hybrid architecture consisting of organic-inorganic self-assembly.An organic layer was fabricated on top of the LDH film using 4-Aminophenol(Aph)compound,resulting in a smart hierarchical structure that can provide a robust Aph@LDH film with excellent anti-corrosion performance.At the molecular level,the conjugation characteristics and adsorption mechanism of Aph molecule were studied using two levels of theory as follows.First,Localized orbit locator(LOL)-πisosurface,electrostatic potential(ESP)distribution,and average local ionization energy(ALIE)on the molecular surface were used to highlight localization region,reveal the favorable electrophilic and nucleophilic attacks,and clearly explore the type of interactions that occurred around interesting regions.Second,first-principles based on density functional theory(DFT)was applied to study the hybrid mechanism of Aph on LDH system and elucidate their mutual interactions.The experimental and computational analyses suggest that the highπ-electron density and delocalization characteristics of the functional groups and benzene ring in the Aph molecule played a leading role in the synergistic effects arising from the combination of organic and inorganic coatings.This work provides a promising approach to design advanced hybrid materials with exceptional electrochemical performance.
基金supported by TWAS (04-150RG/MATHS/AF/AC)the postdoctoral programme of the "Agence Universitaire de la Francophonie"+1 种基金The second author is supported by NSF of Shanghai (09ZR1408900)Shanghai Leading Academic Discipline Project (B407)
文摘In this article, we give sufficient conditions for controllability of some partial neutral functional differential equations with infinite delay. We suppose that the linear part is not necessarily densely defined but satisfies the resolvent estimates of the Hille-Yosida theorem. The results are obtained using the integrated semigroups theory. An application is given to illustrate our abstract result.
文摘The effect of Argan plant extract (APE) on the corrosion of the steel in hydrochloric acid medium was studied using gravimetric, electrochemical polarization and impedance spectroscopy (EIS) measurements. Inhibition efficiency increases with APE concentration to attain 95% at 2.5 g/L. We note good agreement between gravimetric and electrochemical methods (potentiodynamic polarization and EIS). Effect of temperature is also made in the 298-328 K range. Polarization measurements show also that APE act as a mixed inhibitor. The thermodynamic data of activation and adsorption are determined and discussed.
文摘In the Lower Cheliff Plain (northwestern of Algeria), the waters resources are limited; the adoption of a rational approach in the management of irrigation water in the irrigated perimeter poses an inequality in the balance between supply and demand. The two surface water resources, Gargar and Merdjet Sidi Abed dams, do not satisfy the requirements of agriculture water. According to the National Office of the Irrigation and Drainage data, the quantity of allocated water is never distributed; the difference between allocated water and drop water can also exceed 20%, and then, another problem of management is that the water losses in the distribution can reach 20% again. The shortage irrigation water resource allocated has constrained the farmers to use groundwater. The chemical analysis of 56 simples to this water showed a significant chemical diversity in the compositions. There is a high salinity risk (C3 class) or very high risk (C4 class) of soil salinisation. A space chart distribution to the EC water probability to exceed 2.25 dS/m interpolated by the indicator kriging method showed that 78% of the groundwater surface presents a significant probability to exceed this limit. The average value of the SAR (sodium adsorption ratio) is lower than 10 that indicates a moderate risk of sodisation. This observation is in contradiction with the high values of the SAR measured in the soil solution. The approach of residual alkalinity (RSC) shows that a good number of drillings analyzed presents a positive sign RSC (RSC 〉 0). This water presents a real danger of sodisation. They have a low salinity, which, for a farmer, does not present any danger.
文摘During the last decade, Jatropha curcas L. (J. curcas) has gained much attention worldwide as biofuel crop. Although its cultivation is promoted in the Sahel, there is a surprising lack of data on its water use regulation and growth in this region. Here, we investigated, in semi-controlled conditions, leaf transpiration and growth of six accessions of J. curcas at seedling stage under natural changing in vapour pressure deficit (VPD) and progressive soil drying in Senegal. The experimental layout was a randomized complete bloc design and after 3 months of growth arranged to a split-plot at the implementation of water stress to facilitate irrigation. Under well water condition, there was no significant difference between accessions for leave transpiration that was positively correlated to VPD with high values recorded between 13 h and 14 h pm. Accessions of J. curcas used in this study showed closed thresholds at which transpiration declined except accession from Ndawene that threshold was lower (0.30). There is no significant difference between accessions for growth during the experimentation period. In 3 months, we recorded 23.57 g for the aboveground dry biomass and seedlings had about 14 leaves and 24.3 cm height. Positive linear correlation was recorded between aboveground biomass and root dry weight (p J. curcas might need complement irrigation for a better growth of seedlings especially during the dry season.
基金the framework of Franco-Algerian cooperation program"Tassili"No.08MDU726
文摘Background: Investigating population ecology of urban bird species,particularly the invasive and expending spe?cies,is the key for the success of urban management and planning strategies.Methods: Populations of two Columbidae species,the Woodpigeon(Columba palumbus) and the Eurasian Collared Dove(Streptopelia decaocto),were monitored from 1992 to 2010 in the Algiers Sahel,the Mitidja Plain and surround?ing areas(Northern Algeria).Monitoring of species densities was performed by the mapping?plot method.The foraging flight routes of Woodpigeon and the distribution of Eurasian Collared Dove were assessed by systematic observations.Results: The number of counted birds was statistically constant at first years of the survey,and then increased sig?nificantly,beginning from low numbers,their densities accelerated sharply between 2001 and 2006,then reached to an equilibrium state.The significant increase in Woodpigeon's population could be explained by the reduced hunt?ing pressure and by species adaptation to new food resources provided by nearby agriculture.Indeed,monitoring of flight directions of the species revealed the use of agricultural landscapes and habitats,which is a good indicator explaining adaptation and trophic niche of the species.The occurrence of the Eurasian Collared Dove in Algiers began in 2000.Its density experienced a rapid increase with similar trend pattern as that of Woodpigeon.Its distributional range is confined mainly in suburban environments of the Mitidja Plain.Conclusion: The modifications of habitats,urbanization increase and the lessening of hunting in the Mitidja Plain facilitated the rapid expansion of the Eurasian Collared Dove and Woodpigeon as well contributed to the increase in their numbers over time.
文摘Casamance was perceived as an agricultural granary that had rice potential which could meet the high food demand of Senegal. Given that the rice-growing lands have been degraded due to pedoclimatic variabilities, improved modern varieties are not usually well adapted to the Casamance rice-growing ecosystems. This work aims to contribute to the increase of rice production through varietal diversification and enhancement of cultural heritage. A participatory evaluation of five local farmers’ traditional varieties along with one check was carried out in an experiment laid out in a one-factor complete randomized block design using the six accessions with five replications. ANOVA followed by a 5% mean comparison Tukey test and the Kendall Rate were performed with IBM SPSS Statistics software. The result showed very significant varietal differences for leaf blade of the penultimate leaves, 100-grains weight, panicle length, growth cycle, plant height, ramification of secondary branching of the spikelets, resistance to lodging and threshing facility (p ≤ 0.005). However, traits including flag leaf, tiller numbers, sterile tillers number, panicle numbers, panicle yield, and grain yield did not show a significant difference (p ≥ 0.06) among varieties. Thus, based on some of these characteristics, farmers selected their most preferred rice varieties or accessions. The most important characteristics were tillering ability, lodging resistance and fertility rate. Koussik Emandiouck selected by farmers as the best variety, had a high grain yield (4.9 t∙ha<sup>-1</sup>), higher lodging resistance (9), and higher fertility rate (80.53%). Koussik Emandiouck, Koufekeny and Awandiaho varieties were the most preferred by farmers.
文摘In this paper, authors describe how to carry out a research assessing the impact of storage temperature on the stability and biocidal activity of formulated essential oils. Cereals, like other stored food, currently experience serious health problems of storage. The offending agents are primary pests such as Sitophilusoryzae and secondary pests including Tribolium. This study focused on the evaluation of the biocidal effect on the essential oils of thyme and citrus, against red flour beetle adults (Triboliumcastaneum) under different temperature regimes. The results showed that different molecules produced a delayed effect (12 h-14 h-16 h-I 8 h) on the populations of Triboliumcastaneum at the storage temperature of 20 ~C. The same results showed an early striking effect of thymol and carvacrol on Triboliumcastaneum compared to limonene. The toxicity of thymol and carvacrol was much more active than limonene at 12 h, which was very remarkable as limonene expressed its toxicity from 14 h with a deadly effect. When temperatures are under 20 ℃ and 25℃, thymol showed a greater degree of efficiency followed by carvacrol and limonene which had lower efficiency. However, at 28℃, carvacrol expressed a very significant biocidal effect compared to the other two formulations, thymol and limonene.
文摘Multi-layer membrane filtration is a widely used technology for separating and purifying different components ofa liquid mixture. This technique involves passing the liquid mixture through a series of membranes with decreasing pore sizes, which allows for the separation of different components according to their molecular size. Thisstudy investigates the filtration process of a fluid through a two-dimensional porous medium designed forseawater desalination. The focus is on understanding the impact of various parameters such as the coefficientof friction, velocity, and the number of layers on filtration efficiency. The results reveal that the number of layersplays a crucial role in desalination, with an increase in layers leading to enhanced filtration quality, following apower law relationship. The study explores the influence of the coefficient of friction on filtration performance,emphasizing its significant effect on the number of particles filtered over time. Additionally, the role of the initialvelocity in filtration efficiency is examined, showing distinct effects at both high and low velocities. Biofouling isidentified as a factor influencing filtration, with an initial increase in filtered particles followed by a decline due toparticle accumulation in pores.
文摘We report on the structural,magnetic,and magnetocaloric properties of EuRhO_(3) powders.The oxidation states of Eu and Rh ions were studied using X-ray photoelectron spectroscopy(XPS).It is found that the Eu ions are mainly in the divalent oxidation state while the Rh ions have+4 state.EuRhO_(3) powders are found to be antiferromagnetic with a second order magnetic transition at Neel temperature(T_(N)=2.9 K).Analysis of the magnetic susceptibility versus temperature data in terms of the Curie=Weiss law:(χ=C/(T-θ_(W))) for T>T_(N),yields θ_(W)=-3.1 K and effective magne tic moment μ_(ff)^(exp),which is close to the theoretical value μ_(eff)^(theo).The magnetic entropy change(-Δ_(SM)),was determined by em ploying the thermodynam ic Maxwell's relation.At μ_0H=5 T and near T_(N),ΔS_(M)^(Max) and relative cooling power(RCP) exhibit large values of 33.7 J/(kg·K) and 238 J/kg,respectively.The large magnitude of-Δ_(SM) and RCP show that the EuRhO_(3) compound could be a potential candidate to be used in cryogenic magnetic refrigeration.
文摘Today, various traditional country foods are increasingly being neglected as a result of modernisation. Consequently, the knowledge and know-how necessary to prepare those foods are strongly threatened. To safeguard and foster appreciation of traditional knowledge, this study aims, on the one hand, to describe the manufacturing process of an alcoholic drink called “Mbite”. The latter is traditionally prepared with the fruits of Sclerocarya birrea (A. Rich) Hostcht in Senegal. On the other hand, various controlled fermentations have been tested for better control of their hygienic and sanitary qualities. The manufacturing of “Mbite” drink begins with a manual extraction of the juice using stems of Guiera senegalensis or Combretum glutinosum to facilitate the separation of the pericarp from the almond. Subsequently, the extracts are filtered and/or mixed according to the producers. Finally, a 2-day spontaneous fermentation by endogenous yeasts of the fruit makes it possible to obtain the alcoholic drink within 3 days. “Mbite” is a low acid drink with a pH ranging from 3.82 to 3.97 and its ethanol content varies from 2 to 4% (v/v). Polyphenols vary between 124.92 and 158.25 mg/100 mL. However, microbiological analyses have shown a high number of lactic acid bacteria involved in the formation of volatile acids. The controlled fermentation trials have resulted in a unique alcoholic fermentation of Sclerocarya birrea juices by selected strains of Saccharomyces cerevisae. This has the advantage of guaranteeing sanitary qualities and reducing the fermentation time from three days to one.