The paper is an introduction to the front-end pulse acquisition and the back-end pulse biomimetic reproduction system.This system is capable of faithfully replicating the complete pulse waveform collected at the front...The paper is an introduction to the front-end pulse acquisition and the back-end pulse biomimetic reproduction system.This system is capable of faithfully replicating the complete pulse waveform collected at the front end.Traditional Chinese Medicine(TCM)practitioners analyze and diagnose the pulse patterns at the replication end.Meanwhile,the obtained pulse waveforms are analyzed and learnt by a neural network based on key diagnostic points in TCM pulse taking,which enables the determination of the corresponding relationships between different pulse waveforms and various pulse patterns in TCM pulse taking.With the support of clinical samples,an auxiliary diagnostic system for TCM pulse patterns ensures the accuracy of pulse pattern replication.展开更多
Heterogeneity in carbonate formations due to discontinuities(e.g.,fractures and cavities)will bring about distinctive acid stimulation effects.However,the differences in fracturing behavior between homogeneous and het...Heterogeneity in carbonate formations due to discontinuities(e.g.,fractures and cavities)will bring about distinctive acid stimulation effects.However,the differences in fracturing behavior between homogeneous and heterogeneous carbonate formations remain unclear,complicating the optimization of acid fracturing strategies.In this paper,full-diameter carbonate rock samples with different degrees of discontinuity development are selected to investigate the fracturing behavior under different fluid types and injection schemes.Advanced techniques,including 3D CT scanning and 3D laser scanning,are employed to analyze fracture morphology and etching characteristics,respectively.Experimental results show that the coupled hydraulic-chemical effects play different roles in fracture induction between fracture-cavity developed and undeveloped carbonate rocks.Acid-fracturing stimulation consistently induces multiple types of complex fractures in fracture-cavity carbonate rocks,whereas it results in a single artificial fracture in less fracture-cavity carbonate rocks.Furthermore,localized etching patterns are prevalent in most fracture-cavity carbonate rocks,whereas homogeneous carbonate rocks exhibit regional or global etching characteristics.In both carbonate rocks,the stimulation effect of guar fluid is inferior to that of gelled acid but comparable to self-generating acid.Further findings are that alternating fracturing with guar and acid fluids in fracture-cavity carbonate rocks can sustain or even increase the injection pressure,facilitating the formation of new or depth-penetrating fractures.This phenomenon,however,is not observed in fracture-cavity undeveloped carbonate rocks.Potential interaction modes between induced fracture and natural fractures/cavities under different injection conditions are also identified.Finally,preferred fracturing schemes applicable to different carbonate formations are recommended based on the area,number and roughness of the induced fractures.展开更多
The increase in the population as a whole gradually requires solving the issues of continuous development of the agro-industrial complex in all directions and components.This development is accompanied by an increase ...The increase in the population as a whole gradually requires solving the issues of continuous development of the agro-industrial complex in all directions and components.This development is accompanied by an increase in energy consumption,in the total balance of which electricity occupies a significant share.The purpose of this study is to develop a mathematical model of the use of infrared means for heating agro-industrial premises,which affects the formation of energy-saving and energy-saving processes of enterprises.The agrarian potential of Ukraine was analyzed and compared with other countries of the world for awareness,analysis and relevant conclusions regarding energy consumption and frugality.This helped,based on calculations and foreign experience,to prove the effectiveness of the proposed mathematical model.And its empiric results of application in the form of the use of a copper plate allowed to prove efficiency due to the reduction of electricity consumption in the conditions of maintaining the temperature regime of industrial-type premises not higher than 22–26°C when the equipment is operating at an output power of 40 W.The results of the research are the development of the existing theoretical foundations of ensuring the effective use of energy resources in agricultural organizations and can be used by economic entities and regional authorities for the purpose of making informed decisions in the field of energy-saving policy development in the agricultural sector.展开更多
Challenges in the diagnosis and treatment of Parkinson’s disease:Parkinson’s disease(PD)is an increasingly prevalent neurodegenerative disease,at first sight primarily characterized by motor symptoms,although non-mo...Challenges in the diagnosis and treatment of Parkinson’s disease:Parkinson’s disease(PD)is an increasingly prevalent neurodegenerative disease,at first sight primarily characterized by motor symptoms,although non-motor symptoms also constitute a major part of the overall phenotype.Clinically,this disease cannot be diagnosed reliably until a large part of the vulnerable dopaminergic neurons has been irretrievably lost,and the disease progresses inexorably.New biological criteria for PD have been proposed recently and might eventually improve early diagnosis,but they require further validation,and their use will initially be restricted to a research environment(Darweesh et al.,2024).展开更多
To adapt to the uncertainty of new energy,increase new energy consumption,and reduce carbon emissions,a high-voltage distribution network energy storage planning model based on robustness-oriented planning and distrib...To adapt to the uncertainty of new energy,increase new energy consumption,and reduce carbon emissions,a high-voltage distribution network energy storage planning model based on robustness-oriented planning and distributed new energy consumption is proposed.Firstly,the spatio-temporal correlation of large-scale wind-photovoltaic energy is modeled based on the Vine Copula model,and the spatial correlation of the generated wind-photovoltaic power generation is corrected to get the spatio-temporal correlation of wind-photovoltaic power generation scenarios.Finally,considering the subsequent development of new energy on demand for high-voltage distribution network peaking margin and the economy of the system peaking,we propose the optimization model of high-voltage distribution network energy storage plant siting and capacity setting for source-storage cooperative peaking.The simulation results show that the proposed energy storage plant planning method can effectively alleviate the branch circuit blockage,promote new energy consumption,reduce the burden of the main grid peak shifting,and leave sufficient peak shifting margin for the subsequent development of a new energy distribution network while ensuring the economy.展开更多
Carbon risk has become the focal point of academic inquiry in the context of intensifying climate change and pursuing dual-carbon targets.This paper synthesizes domestic and international literature to clarify the con...Carbon risk has become the focal point of academic inquiry in the context of intensifying climate change and pursuing dual-carbon targets.This paper synthesizes domestic and international literature to clarify the concept of carbon risk,providing illustrative cases for various definitions.A key observation is the absence of a standardized approach within academia for measuring carbon risk.Notably,carbon emission data disclosed by Chinese enterprises are limited.In response,this study extends beyond traditional enterprise carbon emissions data and compiles current mainstream methodologies for assessing carbon risk.Using data from listed Chinese companies,this study examined the relevance and practicality of each metric.This study offers several recommendations for the future progress of carbon risk analyses in China and other emerging markets.展开更多
Lithium-ion batteries(LIBs)have been widely used in mobile energy storage systems because of their high energy density,long life,and strong environmental adaptability.Accurately estimating the state of health(SOH)for ...Lithium-ion batteries(LIBs)have been widely used in mobile energy storage systems because of their high energy density,long life,and strong environmental adaptability.Accurately estimating the state of health(SOH)for LIBs is promising and has been extensively studied for many years.However,the current prediction methods are susceptible to noise interference,and the estimation accuracy has room for improvement.Motivated by this,this paper proposes a novel battery SOH estimation method,the Beluga Whale Optimization(BWO)and Noise-Input Gaussian Process(NIGP)Stacked Model(BGNSM).This method integrates the BWO-optimized Gaussian Process Regression(GPR)with the NIGP.It combines their predictions using a stacked GPR model which reduces the problem of large input data noise and improves the prediction accuracy.The experimental results show that the BGNSM method has good accuracy,generalization ability,and robustness,and performs well in small sample situations.The Root Mean Square Error(RMSE)and Mean Absolute Error(MAE)are as low as 0.218%and 0.164%,respectively,which is close to 0.At the same time,R-Square(R^(2))is as high as 0.9948,which is close to 1,indicating that the estimated results in this paper are highly consistent with the actual results.展开更多
Ruthenium(Ru)-based chalcogenide(S,Se)is a promising material in various fields,such as optics,photoelectrodes,and electrocatalysis,owing to its suitable bandgap for generating charge carriers under light illumination...Ruthenium(Ru)-based chalcogenide(S,Se)is a promising material in various fields,such as optics,photoelectrodes,and electrocatalysis,owing to its suitable bandgap for generating charge carriers under light illumination ranging from visible to near-infrared(NIR)and its high absorption coefficient.In this study,we report the synthesis of Ru Se_(2)thin films by chemical vapor deposition(CVD)with a bandgap matching the NIR region at 0.52 e V.Further,we demonstrated Ru S_(2x)Se_(2-2x)alloy films using the post-sulfurization process after CVD Ru Se_(2)with a tunable bandgap from 0.52 to 1.39 e V depending on sulfur composition.Remarkably,Ru S_(2x)Se_(2-2x)alloy film metal–semiconductor–metal(MSM)photodetector sulfurized at 500°C,with a 0.75 e V bandgap,exhibits enhanced broad absorption across NIR spectral ranges,suppressed dark current and high photoresponsivity in NIR wavelengths range even at zero-bias.We believe the bandgaptunable Ru S_(2x)Se_(2-2x)thin film through an efficient deposition method could be suitable for various optoelectronic applications.展开更多
ropic 1:Regarding sustainable development and global public interests,what should international Al standards focus on?James Ong:Since 2019,I have witnessed the evolution of WAIC and found that a consensus on the philo...ropic 1:Regarding sustainable development and global public interests,what should international Al standards focus on?James Ong:Since 2019,I have witnessed the evolution of WAIC and found that a consensus on the philosophical and ethic level on advocating“AI for humanity”is necessary,since ethics factor carries more weight in standards development.I want to emphasize three points:AI assisting sustainable development,AI empowering a balanced global development,and human-AI coordination for preventing AI risks.展开更多
Sea-based rocket launches encounter significant challenges stemming from dynamic marine environmental interactions.During the hot launch phase,characterized by low-velocity ascent,the departure of the rocket from the ...Sea-based rocket launches encounter significant challenges stemming from dynamic marine environmental interactions.During the hot launch phase,characterized by low-velocity ascent,the departure of the rocket from the oscillatory platform exhibits heightened sensitivity to external disturbances.In the development stage,assessing the launch dynamics and the clearance between the rocket and framed launcher are crucial for improving the reliability of sea-based rocket launches in rough sea conditions.This study presents a high-fidelity dynamic model of maritime hot launch system,demonstrating 3.21%prediction error through rigorous validation against experimental datasets from comprehensive modal analyses and the full-scale rocket flight test.To mitigate collision risks,we develop a computational method employing spatial vector analysis for dynamic measurement of rocket-launcher clearance during departure.Systematic investigations reveal that in rough sea conditions,optimal departure dynamics are achieved at θ_(thrust)=270°nozzle azimuth configuration,reducing failure probability compared to conventional orientations.The developed assessment framework not only resolves critical safety challenges in current sea launch systems but also establishes foundational principles for optimizing adapter axial configuration patterns in future designs.展开更多
Foods and animal feeds frequently become contaminated with the nephrotoxic ochratoxin A(OTA).Our prior research has indicated that ursolic acid(UA),which is widely present in fruits and medicinal plants,has the potent...Foods and animal feeds frequently become contaminated with the nephrotoxic ochratoxin A(OTA).Our prior research has indicated that ursolic acid(UA),which is widely present in fruits and medicinal plants,has the potential to alleviate nephrotoxicity triggered by OTA.Additionally,excessive induction of endoplasmic reticulum(ER)-phagy exacerbates OTA-induced apoptosis.Therefore,further investigation is essential to comprehend whether UA can mitigate OTA-induced apoptosis by influencing ER-phagy.This objective is accomplished through a series of experiments involving assessments of cell viability,apoptosis,fluorescence microscopy,and western blot analysis.The outcomes of these experiments reveal that pre-treatment with 4μmol/L UA for 2 h can markedly reverse the elevated apoptotic rate,the co-localization of ER and lysosomes,and the protein expressions of GRP78,p-eIF2α,Chop,Bax,and Bak,as well as the reduced cell viability and the protein expressions of Lonp1,Trap1,p62,Tex264,FAM134B,Bcl-2,and Bcl-xl,all caused by exposure to 1μmol/L OTA for 24 h in human proximal tubule epithelial-originated kidney-2(HK-2)cells(P<0.05).Interestingly,the increased expression of LC3B-II induced by OTA is further amplified by UA pre-treatment(P<0.05).In conclusion,OTA triggers a harmful feedback loop between ER stress(ERS)and excessive ER-phagy,thereby further promoting ERS-and mitochondrial-mediated apoptosis in vitro.However,this effect is significantly mitigated by UA through the inhibition of autophagosome-lysosome fusion,consequently blocking the excessive ER-phagic flux.展开更多
The active equalization of lithium-ion batteries involves transferring energy from high-voltage cells to low-voltage cells,ensuring consistent voltage levels across the battery pack and maintaining safety.This paper p...The active equalization of lithium-ion batteries involves transferring energy from high-voltage cells to low-voltage cells,ensuring consistent voltage levels across the battery pack and maintaining safety.This paper presents a voltage balancing circuit and control method.First,a single capacitor method is used to design the circuit topology for energy transfer.Next,real-time voltage detection and control are employed to balance energy between cells.Finally,simulation and experimental results demonstrate the effectiveness of the proposed method,achieving balanced voltages of 3.97 V from initial voltages of 4.10,3.97,and 3.90 V.The proposed circuit is simple,reliable,and effectively prevents overcharge and overdischarge.展开更多
Objective:To observe the effect of Xipayimaizibizi oral liquid(XP)in an overactive bladder(OAB)experimental rat model and to explore its pharmacological mechanisms.Methods:Network pharmacology was used to explore the ...Objective:To observe the effect of Xipayimaizibizi oral liquid(XP)in an overactive bladder(OAB)experimental rat model and to explore its pharmacological mechanisms.Methods:Network pharmacology was used to explore the potential mechanisms of action of XP.The rats underwent bladder outlet obstruction surgery and were administered the corresponding drug concentrations by gavage for 4 weeks.The study observed the body weight,water intake,bladder and kidney indices(to evaluate their general status),urination behavior pattern(to observe frequency and urgency),and urodynamics(to measure bladder parameters).Hematoxylin and eosin and Masson's trichome staining were used to observe changes in the bladder structure.Enzyme-linked immunosorbent assay was used to measure the levels of nerve growth factor,brain-derived neurotrophic factor,and acetylcholine in the urine.The key targets involved in these mechanisms were validated using reverse transcription-quantitative polymerase chain reaction,immunohistochemistry,and western blot in vivo/vitro experiments.Result:Network pharmacological analysis predicted that XP may alleviate OAB by affecting the cholinergic synapse and calcium signaling pathways.XP treatment significantly reduced the bladder index,improved urine behavior and urodynamic parameters,decreased the neurotransmitters in urine,and reduced the thickness of the bladder wall and collagen ratio.These results indicate that XP can alleviate OAB symptoms and improve the bladder structure.In vivo/vitro experiments further demonstrated that XP can inhibit targets,such as muscarinic acetylcholine receptor 2,and participate in cholinergic synapses to further regulate the parasympathetic nervous system.It can also reduce the overexpression of Ca^(2+) caused by agonists,inhibit targets such as transient receptor potential vanilloid type 1,and participate in calcium signaling pathways to maintain Ca^(2+) homeostasis.Conclusion:These results suggest that XP inhibited bladder overactivity by maintaining Ca^(2+) homeostasis and regulating the parasympathetic nervous system.展开更多
Purpose–This study aims to propose a novel identification method to accurately estimate linear and nonlinear dynamics in permanent magnet synchronous linear motor(PMSLM)based on the time-domain analysis of relay feed...Purpose–This study aims to propose a novel identification method to accurately estimate linear and nonlinear dynamics in permanent magnet synchronous linear motor(PMSLM)based on the time-domain analysis of relay feedback.Design/methodology/approach–A mathematical model of the PMSLM-based servo-mechanical system was first established,incorporating the aforementioned nonlinearities.The model’s velocity response was derived by analyzing its behavior as a first-order system under arbitrary input.To induce oscillatory dynamics,an ideal relay with artificially introduced dead-time components was then integrated into the servo-mechanism.Depending on the oscillations and the time-domain analysis,nonlinear formulas were deduced according to the velocity response of the servo-mechanism.Afterwards,the unknown model parameters can be solved on account of the cost function which utilizes the discrepancy between nominal position characteristics and temporary position characteristics,both of which are extracted from the oscillations.The proposed recognition method was validated through a twostage process:(1)numerical simulation and calculation,followed by(2)real-time experimental verification on a direct-drive servo platform.Subsequently,leveraging the identification results,a novel control strategy was developed and its tracking performance was benchmarked against conventional control schemes.Findings–Simulation results demonstrate that the proposed method achieves estimation accuracy within 8%.Building on this,a novel control strategy is developed by incorporating both friction pulsation and force pulsation identification results into the feedforward compensator.Comparative experiments reveal that this strategy significantly enhances tracking and positioning performance over traditional control schemes.In a word,this new identification method can be used in different process control and servo control systems.Moreover,parameter auto-tuning,feed forward compensation or disturbance observer can be investigated based on the obtained information to improve the system stability and control accuracy.Originality/value–It is of great significance for the performance improvement of rail transit motor control equipment,such as electro-mechanical braking systems.By enhancing the efficiency of motor control,the performance of the product will be more outstanding.展开更多
Shale gas wells often face challenges in maintaining continuous and stable production due to their coexistence with high-and low-pressure wells within the same development block,which leads to issues involving mixed-p...Shale gas wells often face challenges in maintaining continuous and stable production due to their coexistence with high-and low-pressure wells within the same development block,which leads to issues involving mixed-pressure flows.Traditional pipeline optimization methods used in conventional gas well blocks fail to address the unique needs of shale gas wells,such as the precise planning of airflow paths,pressure distribution,and compression.This study proposes a pressure-controlled production optimization strategy specifically designed for shale gas wells operating under mixed-pressure flow conditions.The strategy aims to improve production stability and optimize system efficiency.The decline in production and pressure for individual wells over time is forecasted using a predictive model that accounts for key factors of system optimization,such as reservoir depletion,wellbore conditions,and equipment performance.Additionally,the model predicts the timing and impact of liquid loading,which can significantly affect production.The optimization process involves analyzing the existing gathering pipeline network to determine the most efficient flow directions and compression strategies based on these predictions,while the strategy involves adjusting compressor settings,optimizing flow rates,and planning pressure distribution across the network to maximize productivity while maintaining system stability.By implementing these strategies,this study significantly improves gas well productivity and enhances the adaptability and efficiency of the gathering and transportation system.The proposed approach provides systematic technical solutions and practical guidance for the efficient development and stable production of shale gas fields,ensuring more robust and sustainable pipeline operations.展开更多
This study investigates the design and implementation of Flying Ad Hoc Networks(FANETs),a network architec-ture inspired by the Mobile Ad Hoc Network(MANET)model,specifically tailored to support unmanned aerial vehicl...This study investigates the design and implementation of Flying Ad Hoc Networks(FANETs),a network architec-ture inspired by the Mobile Ad Hoc Network(MANET)model,specifically tailored to support unmanned aerial vehicles(UAVs).As UAVs increasingly contribute to diverse fields,from surveillance to delivery,FANETs have emerged as essential in ensuring stable,dynamic communication channels among drones in flight.This research adopts a dual approach,combining rigorous theoretical analysis with detailed practical simulations to assess the performance,adaptability,and efficiency of FANETs in varying conditions.The findings emphasize the ability of FANETs to manage network congestion effectively in densely populated areas,a critical feature for maintaining reliable communications in complex scenarios.Moreover,FANETs demonstrate high potential to support critical applications,such as emergency response,disaster management,and public safety operations,where quick and coordinated action is paramount.The study also underscores the importance of establishing a hierarchical structure among nodes within the network,which allows for more efficient data exchange and helps optimize the overall network performance.Through this work,significant insights are offered into the design principles that can enhance UAV communication networks,providing a foundation for the development of more resilient,scalable,and efficient technological solutions.These advancements could accelerate the deployment of UAVs across a variety of sectors,including logistics,agriculture,environmental monitoring,and more.As such,this study not only contributes to the field of ad hoc networking but also holds potential for transformative impacts across industries where UAVs play an increasingly central role,promoting greater integration and operational success.展开更多
Purpose–This study aims to implement condition monitoring for urban rail train permanent magnet synchronous motors and inverter systems.Through the construction of a digital twin model,it performs fault diagnosis of ...Purpose–This study aims to implement condition monitoring for urban rail train permanent magnet synchronous motors and inverter systems.Through the construction of a digital twin model,it performs fault diagnosis of potential system failures,enabling rapid fault localization and protection.Design/methodology/approach–This research begins with a brief introduction to the structure and classification of permanent magnet synchronous motors(PMSMs),followed by a detailed analysis of their mathematical model.Subsequently,it thoroughly investigates the working principle of three-phase two-level inverters and the distribution of space voltage vectors.Based on the analysis of the main circuit topology,a digital twin model matching the external characteristics of the physical circuit is established using the model predictive control method,achieving accurate system simulation.Furthermore,through theoretical analysis and simulation verification of phase current characteristics under inverter switch tube faults,general patterns of phase currents under fault conditions are summarized.The established digital twin model is then employed to validate these patterns,confirming the model’s effectiveness in fault diagnosis.Findings–This study proposes a fault diagnosis method based on digital twins.Experimental and simulation results demonstrate that the established digital twin model can accurately simulate the external characteristics of the actual physical circuit,validating its effectiveness in inverter fault diagnosis.This approach offers practical value for condition monitoring in actual urban rail train systems.Originality/value–The study innovatively starts from a mathematical model and simulates the actual physical model through a virtual model,requiring only external characteristics to achieve system fault diagnosis,thereby enhancing diagnostic efficiency.展开更多
Comprehensive studies on CO_(2)breakthrough times and flooding effects are crucial for optimizing CO_(2)flooding strategies.This study utilized numerical simulations to investigate the effects of hydraulic fractures,p...Comprehensive studies on CO_(2)breakthrough times and flooding effects are crucial for optimizing CO_(2)flooding strategies.This study utilized numerical simulations to investigate the effects of hydraulic fractures,permeability,and CO_(2)injection rates on CO_(2)breakthrough times and cumulative oil production.Nonlinear relationships among the respective variables were established,with Sobol method analysis delineating the dominant control factors.The key findings indicate that although hydraulic fracturing shortens CO_(2)breakthrough time,it concurrently enhances cumulative oil production.The orientation of hydraulic fractures emerged as a pivotal factor influencing flooding effectiveness.Furthermore,lower permeability corresponds to lower initial oil production,while higher permeability corresponds to higher initial daily oil production.When reservoir permeability is 1 mD,oil production declines at 1000 days,and at 2 mD,it declines at 700 days.At a surface CO_(2)injection rate of 10,000 m^(3)/d,the daily oil production of a single well is approximately 7.5 m^(3),and this value remains relatively stable over time.The hierarchical order of influence on CO_(2)breakthrough and rapid rise times,from highest to lowest,is permeability,well spacing,CO_(2)injection rate,porosity,and hydraulic fracture conductivity.Similarly,the order of influence on cumulative oil production,from highest to lowest,is well spacing,porosity,permeability,CO_(2)injection rate,and hydraulic fracture conductivity.This paper analyzed the impact of geological and engineering parameters on CO_(2)flooding and oil production and provided insights to optimize CO_(2)injection strategies for enhanced oil recovery.展开更多
Carotenoids are naturally occurring pigments found in various fruits,vegetables,algae,insects,fungi,etc.As nutritional supplements,carotenoids have gained considerable attention for their potential therapeutic and hea...Carotenoids are naturally occurring pigments found in various fruits,vegetables,algae,insects,fungi,etc.As nutritional supplements,carotenoids have gained considerable attention for their potential therapeutic and health-promoting effects,making them significant components of alternative and traditional medicine worldwide.Carotenoids have many health benefits,particularly disease prevention.Carotenoids such as lutein,lycopene,and beta-carotene possess strong antioxidant properties,which help mitigate oxidative stress and reduce the risk of chronic diseases,including cancer,cardiovascular diseases,and eye disorders.Carotenoids play a vital role in various health conditions,including coronavirus disease-19(COVID-19),vision disorders,Alzheimer’s disease,reproductive health,cosmetic applications,diabetes management,infant formula,and animal nutrition.In alternative medicine,carotenoids are valued for enhancing immune function,reducing oxidative damage,and lowering the risk of chronic illnesses.Their benefits extend to improving cognitive function and potentially delaying the progression of Alzheimer’s disease,protecting against age-related macular degeneration and other vision problems,and supporting COVID-19 treatment.In skin care,carotenoids contribute to skin health and beauty,while in diabetes management,they aid in blood glucose regulation.This review especially emphasizes the potential of carotenoids as vital components in health management strategies within alternative medicine and underscores the need for further research to optimize their use in nutraceutical applications.展开更多
Catalytic reduction of nitrate over bimetallic catalysts has emerged as a technology for sustainable treatment of nitrate-containing groundwater.However,the structure of bimetallic has been much less investigated for ...Catalytic reduction of nitrate over bimetallic catalysts has emerged as a technology for sustainable treatment of nitrate-containing groundwater.However,the structure of bimetallic has been much less investigated for catalyst optimization.Herein,two main types of Pd-Cu bimetallic nanocrystal structures,heterostructure and intermetallic,were prepared and characterized using high-resolution transmission electron microscopy(HRTEM),X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XPS).The results show that two individual Pd and Cu nanocrystals with a mixed interface exist in the heterostructure nanocrystals,while Pd and Cu atoms are uniformly distributed across the intermetallic Pd-Cu nanocrystals.The catalytic nitrate reduction experiments were carried out in a semibatch reactor under constant hydrogen flow.The nitrate conversion rate of the heterostructure Pd-Cu nanocrystals supported onα-Al_(2)O_(3),γ-Al_(2)O_(3),SBA-15,and XC-72R exhibited 3.82-,6.76-,4.28-,2.44-fold enhancements relative to the intermetallic nanocrystals,and the nitrogen and nitrite were the main products for the heterostructure and intermetallic Pd-Cu nanocrystals,respectively.This indicates that the catalytic nitrate reduction over Pd-Cu catalyst is sensitive to the bimetallic structures of the catalysts,and heterostructure bimetallic nanocrystals exhibit better catalytic performances on both the activity and selectivity,which may provide new insights into the design and optimization of catalysts to improve catalytic activity and selectivity for nitrate reduction in water.展开更多
基金Key R&D Plan of Liaoning Province(No.202000357-JH13/103):Construction of Liaoning Traditional Chinese Medicine Industry Technology Innovation Research InstituteNational Key Research and Development Plan Special Project(No.2019JH2/10300040)。
文摘The paper is an introduction to the front-end pulse acquisition and the back-end pulse biomimetic reproduction system.This system is capable of faithfully replicating the complete pulse waveform collected at the front end.Traditional Chinese Medicine(TCM)practitioners analyze and diagnose the pulse patterns at the replication end.Meanwhile,the obtained pulse waveforms are analyzed and learnt by a neural network based on key diagnostic points in TCM pulse taking,which enables the determination of the corresponding relationships between different pulse waveforms and various pulse patterns in TCM pulse taking.With the support of clinical samples,an auxiliary diagnostic system for TCM pulse patterns ensures the accuracy of pulse pattern replication.
基金supported by the National Natural Science Foundation of China(Grant No.52404020 and Grant No.U1762216).
文摘Heterogeneity in carbonate formations due to discontinuities(e.g.,fractures and cavities)will bring about distinctive acid stimulation effects.However,the differences in fracturing behavior between homogeneous and heterogeneous carbonate formations remain unclear,complicating the optimization of acid fracturing strategies.In this paper,full-diameter carbonate rock samples with different degrees of discontinuity development are selected to investigate the fracturing behavior under different fluid types and injection schemes.Advanced techniques,including 3D CT scanning and 3D laser scanning,are employed to analyze fracture morphology and etching characteristics,respectively.Experimental results show that the coupled hydraulic-chemical effects play different roles in fracture induction between fracture-cavity developed and undeveloped carbonate rocks.Acid-fracturing stimulation consistently induces multiple types of complex fractures in fracture-cavity carbonate rocks,whereas it results in a single artificial fracture in less fracture-cavity carbonate rocks.Furthermore,localized etching patterns are prevalent in most fracture-cavity carbonate rocks,whereas homogeneous carbonate rocks exhibit regional or global etching characteristics.In both carbonate rocks,the stimulation effect of guar fluid is inferior to that of gelled acid but comparable to self-generating acid.Further findings are that alternating fracturing with guar and acid fluids in fracture-cavity carbonate rocks can sustain or even increase the injection pressure,facilitating the formation of new or depth-penetrating fractures.This phenomenon,however,is not observed in fracture-cavity undeveloped carbonate rocks.Potential interaction modes between induced fracture and natural fractures/cavities under different injection conditions are also identified.Finally,preferred fracturing schemes applicable to different carbonate formations are recommended based on the area,number and roughness of the induced fractures.
文摘The increase in the population as a whole gradually requires solving the issues of continuous development of the agro-industrial complex in all directions and components.This development is accompanied by an increase in energy consumption,in the total balance of which electricity occupies a significant share.The purpose of this study is to develop a mathematical model of the use of infrared means for heating agro-industrial premises,which affects the formation of energy-saving and energy-saving processes of enterprises.The agrarian potential of Ukraine was analyzed and compared with other countries of the world for awareness,analysis and relevant conclusions regarding energy consumption and frugality.This helped,based on calculations and foreign experience,to prove the effectiveness of the proposed mathematical model.And its empiric results of application in the form of the use of a copper plate allowed to prove efficiency due to the reduction of electricity consumption in the conditions of maintaining the temperature regime of industrial-type premises not higher than 22–26°C when the equipment is operating at an output power of 40 W.The results of the research are the development of the existing theoretical foundations of ensuring the effective use of energy resources in agricultural organizations and can be used by economic entities and regional authorities for the purpose of making informed decisions in the field of energy-saving policy development in the agricultural sector.
文摘Challenges in the diagnosis and treatment of Parkinson’s disease:Parkinson’s disease(PD)is an increasingly prevalent neurodegenerative disease,at first sight primarily characterized by motor symptoms,although non-motor symptoms also constitute a major part of the overall phenotype.Clinically,this disease cannot be diagnosed reliably until a large part of the vulnerable dopaminergic neurons has been irretrievably lost,and the disease progresses inexorably.New biological criteria for PD have been proposed recently and might eventually improve early diagnosis,but they require further validation,and their use will initially be restricted to a research environment(Darweesh et al.,2024).
基金supported by State Grid Anhui Electric Power Co.,Ltd.Research Program(B3120923000C).
文摘To adapt to the uncertainty of new energy,increase new energy consumption,and reduce carbon emissions,a high-voltage distribution network energy storage planning model based on robustness-oriented planning and distributed new energy consumption is proposed.Firstly,the spatio-temporal correlation of large-scale wind-photovoltaic energy is modeled based on the Vine Copula model,and the spatial correlation of the generated wind-photovoltaic power generation is corrected to get the spatio-temporal correlation of wind-photovoltaic power generation scenarios.Finally,considering the subsequent development of new energy on demand for high-voltage distribution network peaking margin and the economy of the system peaking,we propose the optimization model of high-voltage distribution network energy storage plant siting and capacity setting for source-storage cooperative peaking.The simulation results show that the proposed energy storage plant planning method can effectively alleviate the branch circuit blockage,promote new energy consumption,reduce the burden of the main grid peak shifting,and leave sufficient peak shifting margin for the subsequent development of a new energy distribution network while ensuring the economy.
基金supported by the Major Project of Philosophy and Social Science Research of Guizhou Province(Grant No.22GZZB07)the Humanities and Social Science Fundamental Research Funds for Central Universities of Nanjing Agricultural University(Grant No.SKCX2023013).
文摘Carbon risk has become the focal point of academic inquiry in the context of intensifying climate change and pursuing dual-carbon targets.This paper synthesizes domestic and international literature to clarify the concept of carbon risk,providing illustrative cases for various definitions.A key observation is the absence of a standardized approach within academia for measuring carbon risk.Notably,carbon emission data disclosed by Chinese enterprises are limited.In response,this study extends beyond traditional enterprise carbon emissions data and compiles current mainstream methodologies for assessing carbon risk.Using data from listed Chinese companies,this study examined the relevance and practicality of each metric.This study offers several recommendations for the future progress of carbon risk analyses in China and other emerging markets.
基金supported by the National Natural Science Foundation of China(Project No.62273176)“Joint Laboratory Project of Intelligent Power and Control Applications”(Project No.1003-KFA24090)the National Key Research and Development Program of China(Project No.2024YFB3311401).
文摘Lithium-ion batteries(LIBs)have been widely used in mobile energy storage systems because of their high energy density,long life,and strong environmental adaptability.Accurately estimating the state of health(SOH)for LIBs is promising and has been extensively studied for many years.However,the current prediction methods are susceptible to noise interference,and the estimation accuracy has room for improvement.Motivated by this,this paper proposes a novel battery SOH estimation method,the Beluga Whale Optimization(BWO)and Noise-Input Gaussian Process(NIGP)Stacked Model(BGNSM).This method integrates the BWO-optimized Gaussian Process Regression(GPR)with the NIGP.It combines their predictions using a stacked GPR model which reduces the problem of large input data noise and improves the prediction accuracy.The experimental results show that the BGNSM method has good accuracy,generalization ability,and robustness,and performs well in small sample situations.The Root Mean Square Error(RMSE)and Mean Absolute Error(MAE)are as low as 0.218%and 0.164%,respectively,which is close to 0.At the same time,R-Square(R^(2))is as high as 0.9948,which is close to 1,indicating that the estimated results in this paper are highly consistent with the actual results.
基金supported by TANAKA KIKINZOKU KOGYO K.Kfinancially supported by the National Research Foundation of Korea(NRF)grant funded by the Korea government(MSIT)(No.NRF-2022R1A2C2006764)the Materials and Components Technology Development Program of MOTIE/KEIT(No.[20012460])。
文摘Ruthenium(Ru)-based chalcogenide(S,Se)is a promising material in various fields,such as optics,photoelectrodes,and electrocatalysis,owing to its suitable bandgap for generating charge carriers under light illumination ranging from visible to near-infrared(NIR)and its high absorption coefficient.In this study,we report the synthesis of Ru Se_(2)thin films by chemical vapor deposition(CVD)with a bandgap matching the NIR region at 0.52 e V.Further,we demonstrated Ru S_(2x)Se_(2-2x)alloy films using the post-sulfurization process after CVD Ru Se_(2)with a tunable bandgap from 0.52 to 1.39 e V depending on sulfur composition.Remarkably,Ru S_(2x)Se_(2-2x)alloy film metal–semiconductor–metal(MSM)photodetector sulfurized at 500°C,with a 0.75 e V bandgap,exhibits enhanced broad absorption across NIR spectral ranges,suppressed dark current and high photoresponsivity in NIR wavelengths range even at zero-bias.We believe the bandgaptunable Ru S_(2x)Se_(2-2x)thin film through an efficient deposition method could be suitable for various optoelectronic applications.
文摘ropic 1:Regarding sustainable development and global public interests,what should international Al standards focus on?James Ong:Since 2019,I have witnessed the evolution of WAIC and found that a consensus on the philosophical and ethic level on advocating“AI for humanity”is necessary,since ethics factor carries more weight in standards development.I want to emphasize three points:AI assisting sustainable development,AI empowering a balanced global development,and human-AI coordination for preventing AI risks.
基金the experimental technology support provided by the China Academy of Launch Vehicle Technology
文摘Sea-based rocket launches encounter significant challenges stemming from dynamic marine environmental interactions.During the hot launch phase,characterized by low-velocity ascent,the departure of the rocket from the oscillatory platform exhibits heightened sensitivity to external disturbances.In the development stage,assessing the launch dynamics and the clearance between the rocket and framed launcher are crucial for improving the reliability of sea-based rocket launches in rough sea conditions.This study presents a high-fidelity dynamic model of maritime hot launch system,demonstrating 3.21%prediction error through rigorous validation against experimental datasets from comprehensive modal analyses and the full-scale rocket flight test.To mitigate collision risks,we develop a computational method employing spatial vector analysis for dynamic measurement of rocket-launcher clearance during departure.Systematic investigations reveal that in rough sea conditions,optimal departure dynamics are achieved at θ_(thrust)=270°nozzle azimuth configuration,reducing failure probability compared to conventional orientations.The developed assessment framework not only resolves critical safety challenges in current sea launch systems but also establishes foundational principles for optimizing adapter axial configuration patterns in future designs.
基金financially supported by the National Natural Science Foundation of China(82060598,32260587)the Natural Science Foundation of Guizhou Province(QKH-J-ZK[2021]181)+4 种基金the Scientific Research Program of Guizhou Provincial Department of Education(QJJ[2023]019)the Science&Technology Program of Guizhou Province(QKHPTRC-CXTD[2022]014)the Excellent Youth Talents of Zunyi Medical University(17zy-006)the Innovation and Entrepreneurship Training Program for College Students of Guizhou Province(S202210661138)the Innovation and Entrepreneurship Training Program for College Students of Zunyi Medical University(ZYDC2021108)。
文摘Foods and animal feeds frequently become contaminated with the nephrotoxic ochratoxin A(OTA).Our prior research has indicated that ursolic acid(UA),which is widely present in fruits and medicinal plants,has the potential to alleviate nephrotoxicity triggered by OTA.Additionally,excessive induction of endoplasmic reticulum(ER)-phagy exacerbates OTA-induced apoptosis.Therefore,further investigation is essential to comprehend whether UA can mitigate OTA-induced apoptosis by influencing ER-phagy.This objective is accomplished through a series of experiments involving assessments of cell viability,apoptosis,fluorescence microscopy,and western blot analysis.The outcomes of these experiments reveal that pre-treatment with 4μmol/L UA for 2 h can markedly reverse the elevated apoptotic rate,the co-localization of ER and lysosomes,and the protein expressions of GRP78,p-eIF2α,Chop,Bax,and Bak,as well as the reduced cell viability and the protein expressions of Lonp1,Trap1,p62,Tex264,FAM134B,Bcl-2,and Bcl-xl,all caused by exposure to 1μmol/L OTA for 24 h in human proximal tubule epithelial-originated kidney-2(HK-2)cells(P<0.05).Interestingly,the increased expression of LC3B-II induced by OTA is further amplified by UA pre-treatment(P<0.05).In conclusion,OTA triggers a harmful feedback loop between ER stress(ERS)and excessive ER-phagy,thereby further promoting ERS-and mitochondrial-mediated apoptosis in vitro.However,this effect is significantly mitigated by UA through the inhibition of autophagosome-lysosome fusion,consequently blocking the excessive ER-phagic flux.
基金funded by the Basic Science(Natural Science)Research Project of Colleges and Universities in Jiangsu Province,Grant Number 22KJD470002.
文摘The active equalization of lithium-ion batteries involves transferring energy from high-voltage cells to low-voltage cells,ensuring consistent voltage levels across the battery pack and maintaining safety.This paper presents a voltage balancing circuit and control method.First,a single capacitor method is used to design the circuit topology for energy transfer.Next,real-time voltage detection and control are employed to balance energy between cells.Finally,simulation and experimental results demonstrate the effectiveness of the proposed method,achieving balanced voltages of 3.97 V from initial voltages of 4.10,3.97,and 3.90 V.The proposed circuit is simple,reliable,and effectively prevents overcharge and overdischarge.
基金supported by the Natural Science Foundation in Xinjiang Uygur Autonomous Region(Urumqi,China,2023D01F38).
文摘Objective:To observe the effect of Xipayimaizibizi oral liquid(XP)in an overactive bladder(OAB)experimental rat model and to explore its pharmacological mechanisms.Methods:Network pharmacology was used to explore the potential mechanisms of action of XP.The rats underwent bladder outlet obstruction surgery and were administered the corresponding drug concentrations by gavage for 4 weeks.The study observed the body weight,water intake,bladder and kidney indices(to evaluate their general status),urination behavior pattern(to observe frequency and urgency),and urodynamics(to measure bladder parameters).Hematoxylin and eosin and Masson's trichome staining were used to observe changes in the bladder structure.Enzyme-linked immunosorbent assay was used to measure the levels of nerve growth factor,brain-derived neurotrophic factor,and acetylcholine in the urine.The key targets involved in these mechanisms were validated using reverse transcription-quantitative polymerase chain reaction,immunohistochemistry,and western blot in vivo/vitro experiments.Result:Network pharmacological analysis predicted that XP may alleviate OAB by affecting the cholinergic synapse and calcium signaling pathways.XP treatment significantly reduced the bladder index,improved urine behavior and urodynamic parameters,decreased the neurotransmitters in urine,and reduced the thickness of the bladder wall and collagen ratio.These results indicate that XP can alleviate OAB symptoms and improve the bladder structure.In vivo/vitro experiments further demonstrated that XP can inhibit targets,such as muscarinic acetylcholine receptor 2,and participate in cholinergic synapses to further regulate the parasympathetic nervous system.It can also reduce the overexpression of Ca^(2+) caused by agonists,inhibit targets such as transient receptor potential vanilloid type 1,and participate in calcium signaling pathways to maintain Ca^(2+) homeostasis.Conclusion:These results suggest that XP inhibited bladder overactivity by maintaining Ca^(2+) homeostasis and regulating the parasympathetic nervous system.
文摘Purpose–This study aims to propose a novel identification method to accurately estimate linear and nonlinear dynamics in permanent magnet synchronous linear motor(PMSLM)based on the time-domain analysis of relay feedback.Design/methodology/approach–A mathematical model of the PMSLM-based servo-mechanical system was first established,incorporating the aforementioned nonlinearities.The model’s velocity response was derived by analyzing its behavior as a first-order system under arbitrary input.To induce oscillatory dynamics,an ideal relay with artificially introduced dead-time components was then integrated into the servo-mechanism.Depending on the oscillations and the time-domain analysis,nonlinear formulas were deduced according to the velocity response of the servo-mechanism.Afterwards,the unknown model parameters can be solved on account of the cost function which utilizes the discrepancy between nominal position characteristics and temporary position characteristics,both of which are extracted from the oscillations.The proposed recognition method was validated through a twostage process:(1)numerical simulation and calculation,followed by(2)real-time experimental verification on a direct-drive servo platform.Subsequently,leveraging the identification results,a novel control strategy was developed and its tracking performance was benchmarked against conventional control schemes.Findings–Simulation results demonstrate that the proposed method achieves estimation accuracy within 8%.Building on this,a novel control strategy is developed by incorporating both friction pulsation and force pulsation identification results into the feedforward compensator.Comparative experiments reveal that this strategy significantly enhances tracking and positioning performance over traditional control schemes.In a word,this new identification method can be used in different process control and servo control systems.Moreover,parameter auto-tuning,feed forward compensation or disturbance observer can be investigated based on the obtained information to improve the system stability and control accuracy.Originality/value–It is of great significance for the performance improvement of rail transit motor control equipment,such as electro-mechanical braking systems.By enhancing the efficiency of motor control,the performance of the product will be more outstanding.
基金supported by the National Natural Science Foundation of China under Grant 52325402,52274057 and 52074340the National Key R&D Program of China under Grant 2023YFB4104200+1 种基金the Major Scientific and Technological Projects of CNOOC under Grant CCL2022RCPS0397RSN111 Project under Grant B08028.
文摘Shale gas wells often face challenges in maintaining continuous and stable production due to their coexistence with high-and low-pressure wells within the same development block,which leads to issues involving mixed-pressure flows.Traditional pipeline optimization methods used in conventional gas well blocks fail to address the unique needs of shale gas wells,such as the precise planning of airflow paths,pressure distribution,and compression.This study proposes a pressure-controlled production optimization strategy specifically designed for shale gas wells operating under mixed-pressure flow conditions.The strategy aims to improve production stability and optimize system efficiency.The decline in production and pressure for individual wells over time is forecasted using a predictive model that accounts for key factors of system optimization,such as reservoir depletion,wellbore conditions,and equipment performance.Additionally,the model predicts the timing and impact of liquid loading,which can significantly affect production.The optimization process involves analyzing the existing gathering pipeline network to determine the most efficient flow directions and compression strategies based on these predictions,while the strategy involves adjusting compressor settings,optimizing flow rates,and planning pressure distribution across the network to maximize productivity while maintaining system stability.By implementing these strategies,this study significantly improves gas well productivity and enhances the adaptability and efficiency of the gathering and transportation system.The proposed approach provides systematic technical solutions and practical guidance for the efficient development and stable production of shale gas fields,ensuring more robust and sustainable pipeline operations.
基金funded by Direccion General de Investigaciones of Universidad Santiago de Cali under call No.01-2024.
文摘This study investigates the design and implementation of Flying Ad Hoc Networks(FANETs),a network architec-ture inspired by the Mobile Ad Hoc Network(MANET)model,specifically tailored to support unmanned aerial vehicles(UAVs).As UAVs increasingly contribute to diverse fields,from surveillance to delivery,FANETs have emerged as essential in ensuring stable,dynamic communication channels among drones in flight.This research adopts a dual approach,combining rigorous theoretical analysis with detailed practical simulations to assess the performance,adaptability,and efficiency of FANETs in varying conditions.The findings emphasize the ability of FANETs to manage network congestion effectively in densely populated areas,a critical feature for maintaining reliable communications in complex scenarios.Moreover,FANETs demonstrate high potential to support critical applications,such as emergency response,disaster management,and public safety operations,where quick and coordinated action is paramount.The study also underscores the importance of establishing a hierarchical structure among nodes within the network,which allows for more efficient data exchange and helps optimize the overall network performance.Through this work,significant insights are offered into the design principles that can enhance UAV communication networks,providing a foundation for the development of more resilient,scalable,and efficient technological solutions.These advancements could accelerate the deployment of UAVs across a variety of sectors,including logistics,agriculture,environmental monitoring,and more.As such,this study not only contributes to the field of ad hoc networking but also holds potential for transformative impacts across industries where UAVs play an increasingly central role,promoting greater integration and operational success.
基金supported by the Fund of China State Railway Group Corporation Limited(L2023J001)the Fund of China Academy of Railway Sciences Corporation Limited(2023YJ247).
文摘Purpose–This study aims to implement condition monitoring for urban rail train permanent magnet synchronous motors and inverter systems.Through the construction of a digital twin model,it performs fault diagnosis of potential system failures,enabling rapid fault localization and protection.Design/methodology/approach–This research begins with a brief introduction to the structure and classification of permanent magnet synchronous motors(PMSMs),followed by a detailed analysis of their mathematical model.Subsequently,it thoroughly investigates the working principle of three-phase two-level inverters and the distribution of space voltage vectors.Based on the analysis of the main circuit topology,a digital twin model matching the external characteristics of the physical circuit is established using the model predictive control method,achieving accurate system simulation.Furthermore,through theoretical analysis and simulation verification of phase current characteristics under inverter switch tube faults,general patterns of phase currents under fault conditions are summarized.The established digital twin model is then employed to validate these patterns,confirming the model’s effectiveness in fault diagnosis.Findings–This study proposes a fault diagnosis method based on digital twins.Experimental and simulation results demonstrate that the established digital twin model can accurately simulate the external characteristics of the actual physical circuit,validating its effectiveness in inverter fault diagnosis.This approach offers practical value for condition monitoring in actual urban rail train systems.Originality/value–The study innovatively starts from a mathematical model and simulates the actual physical model through a virtual model,requiring only external characteristics to achieve system fault diagnosis,thereby enhancing diagnostic efficiency.
基金supported by the China Postdoctoral Science Foundation(No.2024M752803)the National Natural Science Foundation of China(No.52179112)+1 种基金the Open Fund of National Key Laboratory of Oil and Gas Reservoir Geology and Exploitation,Southwest Petroleum University,China(No.PLN2023-02)the Open Fund of Key Laboratory of Deep Geothermal Resources,Ministry of Natural Resources of the People's Republic of China(No.KLDGR2024B01).
文摘Comprehensive studies on CO_(2)breakthrough times and flooding effects are crucial for optimizing CO_(2)flooding strategies.This study utilized numerical simulations to investigate the effects of hydraulic fractures,permeability,and CO_(2)injection rates on CO_(2)breakthrough times and cumulative oil production.Nonlinear relationships among the respective variables were established,with Sobol method analysis delineating the dominant control factors.The key findings indicate that although hydraulic fracturing shortens CO_(2)breakthrough time,it concurrently enhances cumulative oil production.The orientation of hydraulic fractures emerged as a pivotal factor influencing flooding effectiveness.Furthermore,lower permeability corresponds to lower initial oil production,while higher permeability corresponds to higher initial daily oil production.When reservoir permeability is 1 mD,oil production declines at 1000 days,and at 2 mD,it declines at 700 days.At a surface CO_(2)injection rate of 10,000 m^(3)/d,the daily oil production of a single well is approximately 7.5 m^(3),and this value remains relatively stable over time.The hierarchical order of influence on CO_(2)breakthrough and rapid rise times,from highest to lowest,is permeability,well spacing,CO_(2)injection rate,porosity,and hydraulic fracture conductivity.Similarly,the order of influence on cumulative oil production,from highest to lowest,is well spacing,porosity,permeability,CO_(2)injection rate,and hydraulic fracture conductivity.This paper analyzed the impact of geological and engineering parameters on CO_(2)flooding and oil production and provided insights to optimize CO_(2)injection strategies for enhanced oil recovery.
文摘Carotenoids are naturally occurring pigments found in various fruits,vegetables,algae,insects,fungi,etc.As nutritional supplements,carotenoids have gained considerable attention for their potential therapeutic and health-promoting effects,making them significant components of alternative and traditional medicine worldwide.Carotenoids have many health benefits,particularly disease prevention.Carotenoids such as lutein,lycopene,and beta-carotene possess strong antioxidant properties,which help mitigate oxidative stress and reduce the risk of chronic diseases,including cancer,cardiovascular diseases,and eye disorders.Carotenoids play a vital role in various health conditions,including coronavirus disease-19(COVID-19),vision disorders,Alzheimer’s disease,reproductive health,cosmetic applications,diabetes management,infant formula,and animal nutrition.In alternative medicine,carotenoids are valued for enhancing immune function,reducing oxidative damage,and lowering the risk of chronic illnesses.Their benefits extend to improving cognitive function and potentially delaying the progression of Alzheimer’s disease,protecting against age-related macular degeneration and other vision problems,and supporting COVID-19 treatment.In skin care,carotenoids contribute to skin health and beauty,while in diabetes management,they aid in blood glucose regulation.This review especially emphasizes the potential of carotenoids as vital components in health management strategies within alternative medicine and underscores the need for further research to optimize their use in nutraceutical applications.
基金support from the National Natural Science Foundation of China(Nos.52370100,52000146,and 51978098)China Postdoctoral Science Foundation(No.2020M673351).
文摘Catalytic reduction of nitrate over bimetallic catalysts has emerged as a technology for sustainable treatment of nitrate-containing groundwater.However,the structure of bimetallic has been much less investigated for catalyst optimization.Herein,two main types of Pd-Cu bimetallic nanocrystal structures,heterostructure and intermetallic,were prepared and characterized using high-resolution transmission electron microscopy(HRTEM),X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XPS).The results show that two individual Pd and Cu nanocrystals with a mixed interface exist in the heterostructure nanocrystals,while Pd and Cu atoms are uniformly distributed across the intermetallic Pd-Cu nanocrystals.The catalytic nitrate reduction experiments were carried out in a semibatch reactor under constant hydrogen flow.The nitrate conversion rate of the heterostructure Pd-Cu nanocrystals supported onα-Al_(2)O_(3),γ-Al_(2)O_(3),SBA-15,and XC-72R exhibited 3.82-,6.76-,4.28-,2.44-fold enhancements relative to the intermetallic nanocrystals,and the nitrogen and nitrite were the main products for the heterostructure and intermetallic Pd-Cu nanocrystals,respectively.This indicates that the catalytic nitrate reduction over Pd-Cu catalyst is sensitive to the bimetallic structures of the catalysts,and heterostructure bimetallic nanocrystals exhibit better catalytic performances on both the activity and selectivity,which may provide new insights into the design and optimization of catalysts to improve catalytic activity and selectivity for nitrate reduction in water.
