The G ksun Ophiolites in Do an ehir area (Malatya-Southern Turkey) contain corundum mineralizations with significant gem-quality (ruby). Modal mineralogical composition of ruby-bearing rocks consists of hornblende (...The G ksun Ophiolites in Do an ehir area (Malatya-Southern Turkey) contain corundum mineralizations with significant gem-quality (ruby). Modal mineralogical composition of ruby-bearing rocks consists of hornblende (65%-70 %), plagioclase (20%-25%), green garnet (4%-5 %), ruby (2%-3%), and opaque minerals (<1%). Although ruby shows varying colors in the groundmass, it is generally colorless and rarely very pale pink and has high relief. It has no cleavage but rotund fractures. It has highest interference colors and twinning in some poly-prismatic crystals under the microscope. Crystal sizes range from 2x10 mm up to 30x50 mm. The most remarkable properties are red to pink in color, low to medium transparency, medium to big crystal sizes, lamellar and deformation twinning, secondary liquid feathers, hollow tubes, mineral inclusions, asterism, high birefringence and refractive indices and specific gravity. Rubies show crimson red cathodoluminescence colors activated by Cr3+ in the crystal structure, which is confirmed by the Electron Probe Microanalyses (EPMA). Tectonic setting, geological environment, petrographical, mineralogical, geochemical and gemological characteristics of rubies suggest that the Do an ehir ruby mineralization can be classified into the amphibolite-hosted type of corundum deposits of Tanzania.展开更多
Marble that exploited for micronized calcite production in Nigde area (South Central Turkey) occur in the Upper Cretaceous Gümü ler, A gedi i, and Kaleboynu Formations of the Nigde Massif. Although there are...Marble that exploited for micronized calcite production in Nigde area (South Central Turkey) occur in the Upper Cretaceous Gümü ler, A gedi i, and Kaleboynu Formations of the Nigde Massif. Although there are a few marble producing quarries in the area, it is long been known that the marbles of this area are generally highly fractured and don’t yield large blocks or suitable slabs meeting the industrial demands. Thus, most of the production is currently carried out mainly as building stone, crushed stone and micronized calcite. Due mainly to high demand, micronized calcite has been becoming very significant export product to the state’s economy. Because the Nigde marbles are coarse grained with high CaCO3 content, high purity and whiteness, they are considered to be the highest quality micronized calcite quarries in the country. Consequently, the area drew many national and international investors resulting in significant increase in the number and extent of micronized calcite plants in the area. In early 1980’s, the city of Nigde had only one or two plants, it is now well over 5 including foreign investors and joint ventures. Annual production is also considerably increased from 20,000-30,000 tones to almost half a million tones and it is still in increasing trend.展开更多
The Pontide belt in northern Turkey includes three major tectonic terranes,the Strandja Massif（Sj M）,and the Istanbul（ISZ）and Sakarya Zones（SZ）(Fig.1).We present new age and geochemical data from ophiolites and ...The Pontide belt in northern Turkey includes three major tectonic terranes,the Strandja Massif（Sj M）,and the Istanbul（ISZ）and Sakarya Zones（SZ）(Fig.1).We present new age and geochemical data from ophiolites and ophiolitic mélanges within the Sakarya Zone and show that these mafic–ultramafic rocks are the remnants of Tethyan oceanic lithosphere formed in different tectonic settings.The main ophiolite occurrences investigated in this study along the Karakaya Suture（KS）are associated with the latest Triassic Cimmeride orogeny,and in the Küre–Yusufeli ophiolite belt are part of the Alpide orogeny.The Karakaya Suture Zone ophiolites in northern west Turkey are comprised mainly of the Denizgoren（?anakkale）ophiolite,Bo?azk?y（Bursa）,Geyve（Sakarya）,Almac?k（Düzce）and?ele（Bolu）metaophiolites.The Denizg?ren ophiolite largely contains upper mantle peridotites,which are equivalents of the Permo–Triassic Lesvos peridotites and mélange units farther SW in the northern Aegean Sea.The Bo?azk?y ophiolite includes serpentinite and metagabbro,and the Almac?k and Geyve ophiolites display an almost complete Penrose–type sequence consisting of serpentinizeduppermantleperidotites,cumulate ultramafic–mafic rocks,isotropic gabbros,dolerite and plagiogranite dikes,and extrusive rocks.U–Pb zircon dating of plagiogranite dikes from?ele has revealed an igneous age of 260 Ma,and 255,235,227 Ma from Almac?k（Bozkurt et al.,2012a,b）.Consistent with the previouslypublished Permo–Triassic age,we obtained a 268.4±6.3 Ma U–Pb zircon age from a plagiogranite dike within the Almacik ophiolite to the west.This KS ophiolite belt containing the?ele,Almac?k,Geyve ophiolites within the SZ extends westward into the Armutlu Peninsula and then into the Biga Peninsula（i.e.Denizg?ren ophiolite）and most likely connects with the remnants of the Triassic Meliata–Meliac ocean basin（Stampfli and Borel,2002）in the Balkan Peninsula.The KS ophiolites also continue eastward within the Pontide Belt into the Elekda?ophiolite（eastern Kastamonu）and then to the Refahiye ophiolite in NE Anatolia.Triassic granites in the SZ represent a magmatic arc that formed as a result of the northward subduction of the Izmir–Ankara–Erzincan oceanic lithosphere existing during the late Paleozoic through Cretaceous（Sarifakioglu et al.,2014）beneath the Pontides.We obtained a U–Pb zircon age of 231±2 Ma from a metagranitic intrusion into the Variscan basement of the SZ in the Kastamonu region of the central Pontides.This metagranite is enriched in LILE（Rb:63 ppm;Ba:65 ppm;Sr:200 ppm）and depleted in HFSE（Y:12.58 ppm;Yb:1.26 ppm;Ti O2:0.2 wt.%;Nb:7.6 ppm;Hf:3.9 ppm）,characterizing it as subduction–related calc-alkaline pluton.Lead（3.9 ppm）,U（1.6 ppm）and Ce（59 ppm）contents are interpreted as evidence for contamination by continental crust.The Küre basin to the north opened during the late Triassic to Liassic,following a backarc rifting episode in the central Pontides.Metabasic dike intrusions in the Devrekani metamorphic massif represent the first magmatic stage of this backarc rifting event.Whole-rock 40Ar-39Ar dating ofthe metabasic dikes has yielded cooling ages of 160.5±1.2 Ma. We infer that this age was reset due to thermal heating during the emplacement of the Middle Jurassic granitoids as the Küre oceanic basin was closing. The Küre ophiolite contains upper mantle peridotites and oceanic crustal rocks composed mainly of pillow–massive–breccia basalts, dacitic and rhyolitic lavas–tuffs, diabase dyke swarms, massive gabbros and a limited extent mafic cumulates. We obtained 182.6±1.9 Ma as a whole-rock 40Ar-39 Ar age from a pillow basalt and a U–Pb zircon age of 171±1 Ma from the granitic intrusion cross-cutting the peridotites. The easternmost representatives of the Küre ophiolite occur in the Yusufeli（Artvin） area in the eastern part of the Pontide belt. Here, oceanic crustal rocks are tectonically related to metamorphic rocks of the Variscan basement of the SZ. The ophiolitic crustal rocks contain isotropic gabbro and mafic and felsic dikes. Serpentinized upper mantle peridotites are scarce. Pillow lava basalts are overlain by a thick metasandstone–metashale association with locally foliated meta–lava and some manganiferous chert and mudstone interlayers. We obtained a U–Pb zircon age of 172.5±1.4 Ma from the granitic intrusion cross-cutting the Yusufeli ophiolite and of 181.9±0.9 Ma from a felsic dike（plagiogranite） in the Yusufeli ophiolite. The Middle Jurassic granites are related to the closure of the Küre-Yusufeli marginal ocean basin. The Küre and Yusufeli ophiolites have been previously interpreted as the remnants of the Paleotethys or the Intra-Pontide Ocean. However, we posit that these ophiolites represent amarginal, short-lived（;0 Ma） ocean basin, which opened during the late Triassic through Liassic, and then closed in Dogger. This oceanic lithosphere is similar to the Evros ophiolite in the northeastern Greece in terms of its ages and geochemical characteristics.展开更多
Optical cathodoluminescence microscopy (CLM) can provide very useful information both on mineral zoning formed during crystal growth and on variations in chemical composition of sphalerites which is reflected by their...Optical cathodoluminescence microscopy (CLM) can provide very useful information both on mineral zoning formed during crystal growth and on variations in chemical composition of sphalerites which is reflected by their visible colors. Gem quality sphalerite crystals associated with dolomite, calcite and fluorite having 3 different visible colors - green, honey and brown - were studied to compare their mineral chemistry and CL characteristics. Electron microprobe analyses indicated essentially no significant differences in terms of major components. Although the common CL-quencher ferrous iron contents of all three were lower than 0.25 wt %, none of the sphalerites cathodoluminescenced: two (brown and honey) were non-CL, the green sphalerite showed very week CL in faint brown color. Other trace elements that were analyzed include Fe, Cd, Mn, Ag, Hg, In, Bi, Cu, Ge, and Ga. Fe, Cd, Ga and Cu were relatively higher than the others. Most significant differences with respect to the common trace elements include honey colored sphalerites are essentially Fe- and Cd-poor but rich in Ga, green sphalerites are Fe- and Cd- rich but poor in all the others, and brown sphalerites are rich in Cd. No conclusive relation between non-CL behavior of all three sphalerites and their trace element chemistry was established, however; low quantities of common CL activators in sphalerite crystal structures such as Mn, Cu, and In were the main cause of the non-CL behavior.展开更多
文摘The G ksun Ophiolites in Do an ehir area (Malatya-Southern Turkey) contain corundum mineralizations with significant gem-quality (ruby). Modal mineralogical composition of ruby-bearing rocks consists of hornblende (65%-70 %), plagioclase (20%-25%), green garnet (4%-5 %), ruby (2%-3%), and opaque minerals (<1%). Although ruby shows varying colors in the groundmass, it is generally colorless and rarely very pale pink and has high relief. It has no cleavage but rotund fractures. It has highest interference colors and twinning in some poly-prismatic crystals under the microscope. Crystal sizes range from 2x10 mm up to 30x50 mm. The most remarkable properties are red to pink in color, low to medium transparency, medium to big crystal sizes, lamellar and deformation twinning, secondary liquid feathers, hollow tubes, mineral inclusions, asterism, high birefringence and refractive indices and specific gravity. Rubies show crimson red cathodoluminescence colors activated by Cr3+ in the crystal structure, which is confirmed by the Electron Probe Microanalyses (EPMA). Tectonic setting, geological environment, petrographical, mineralogical, geochemical and gemological characteristics of rubies suggest that the Do an ehir ruby mineralization can be classified into the amphibolite-hosted type of corundum deposits of Tanzania.
文摘Marble that exploited for micronized calcite production in Nigde area (South Central Turkey) occur in the Upper Cretaceous Gümü ler, A gedi i, and Kaleboynu Formations of the Nigde Massif. Although there are a few marble producing quarries in the area, it is long been known that the marbles of this area are generally highly fractured and don’t yield large blocks or suitable slabs meeting the industrial demands. Thus, most of the production is currently carried out mainly as building stone, crushed stone and micronized calcite. Due mainly to high demand, micronized calcite has been becoming very significant export product to the state’s economy. Because the Nigde marbles are coarse grained with high CaCO3 content, high purity and whiteness, they are considered to be the highest quality micronized calcite quarries in the country. Consequently, the area drew many national and international investors resulting in significant increase in the number and extent of micronized calcite plants in the area. In early 1980’s, the city of Nigde had only one or two plants, it is now well over 5 including foreign investors and joint ventures. Annual production is also considerably increased from 20,000-30,000 tones to almost half a million tones and it is still in increasing trend.
基金supported by a grant from the General Directorate of Mineral Research and Exploration of Turkey (MTA, Ankara project no: 2009.30.14.09.4+1 种基金 2010.30.14.08.32011.30.14.08.3)
文摘The Pontide belt in northern Turkey includes three major tectonic terranes,the Strandja Massif（Sj M）,and the Istanbul（ISZ）and Sakarya Zones（SZ）(Fig.1).We present new age and geochemical data from ophiolites and ophiolitic mélanges within the Sakarya Zone and show that these mafic–ultramafic rocks are the remnants of Tethyan oceanic lithosphere formed in different tectonic settings.The main ophiolite occurrences investigated in this study along the Karakaya Suture（KS）are associated with the latest Triassic Cimmeride orogeny,and in the Küre–Yusufeli ophiolite belt are part of the Alpide orogeny.The Karakaya Suture Zone ophiolites in northern west Turkey are comprised mainly of the Denizgoren（?anakkale）ophiolite,Bo?azk?y（Bursa）,Geyve（Sakarya）,Almac?k（Düzce）and?ele（Bolu）metaophiolites.The Denizg?ren ophiolite largely contains upper mantle peridotites,which are equivalents of the Permo–Triassic Lesvos peridotites and mélange units farther SW in the northern Aegean Sea.The Bo?azk?y ophiolite includes serpentinite and metagabbro,and the Almac?k and Geyve ophiolites display an almost complete Penrose–type sequence consisting of serpentinizeduppermantleperidotites,cumulate ultramafic–mafic rocks,isotropic gabbros,dolerite and plagiogranite dikes,and extrusive rocks.U–Pb zircon dating of plagiogranite dikes from?ele has revealed an igneous age of 260 Ma,and 255,235,227 Ma from Almac?k（Bozkurt et al.,2012a,b）.Consistent with the previouslypublished Permo–Triassic age,we obtained a 268.4±6.3 Ma U–Pb zircon age from a plagiogranite dike within the Almacik ophiolite to the west.This KS ophiolite belt containing the?ele,Almac?k,Geyve ophiolites within the SZ extends westward into the Armutlu Peninsula and then into the Biga Peninsula（i.e.Denizg?ren ophiolite）and most likely connects with the remnants of the Triassic Meliata–Meliac ocean basin（Stampfli and Borel,2002）in the Balkan Peninsula.The KS ophiolites also continue eastward within the Pontide Belt into the Elekda?ophiolite（eastern Kastamonu）and then to the Refahiye ophiolite in NE Anatolia.Triassic granites in the SZ represent a magmatic arc that formed as a result of the northward subduction of the Izmir–Ankara–Erzincan oceanic lithosphere existing during the late Paleozoic through Cretaceous（Sarifakioglu et al.,2014）beneath the Pontides.We obtained a U–Pb zircon age of 231±2 Ma from a metagranitic intrusion into the Variscan basement of the SZ in the Kastamonu region of the central Pontides.This metagranite is enriched in LILE（Rb:63 ppm;Ba:65 ppm;Sr:200 ppm）and depleted in HFSE（Y:12.58 ppm;Yb:1.26 ppm;Ti O2:0.2 wt.%;Nb:7.6 ppm;Hf:3.9 ppm）,characterizing it as subduction–related calc-alkaline pluton.Lead（3.9 ppm）,U（1.6 ppm）and Ce（59 ppm）contents are interpreted as evidence for contamination by continental crust.The Küre basin to the north opened during the late Triassic to Liassic,following a backarc rifting episode in the central Pontides.Metabasic dike intrusions in the Devrekani metamorphic massif represent the first magmatic stage of this backarc rifting event.Whole-rock 40Ar-39Ar dating ofthe metabasic dikes has yielded cooling ages of 160.5±1.2 Ma. We infer that this age was reset due to thermal heating during the emplacement of the Middle Jurassic granitoids as the Küre oceanic basin was closing. The Küre ophiolite contains upper mantle peridotites and oceanic crustal rocks composed mainly of pillow–massive–breccia basalts, dacitic and rhyolitic lavas–tuffs, diabase dyke swarms, massive gabbros and a limited extent mafic cumulates. We obtained 182.6±1.9 Ma as a whole-rock 40Ar-39 Ar age from a pillow basalt and a U–Pb zircon age of 171±1 Ma from the granitic intrusion cross-cutting the peridotites. The easternmost representatives of the Küre ophiolite occur in the Yusufeli（Artvin） area in the eastern part of the Pontide belt. Here, oceanic crustal rocks are tectonically related to metamorphic rocks of the Variscan basement of the SZ. The ophiolitic crustal rocks contain isotropic gabbro and mafic and felsic dikes. Serpentinized upper mantle peridotites are scarce. Pillow lava basalts are overlain by a thick metasandstone–metashale association with locally foliated meta–lava and some manganiferous chert and mudstone interlayers. We obtained a U–Pb zircon age of 172.5±1.4 Ma from the granitic intrusion cross-cutting the Yusufeli ophiolite and of 181.9±0.9 Ma from a felsic dike（plagiogranite） in the Yusufeli ophiolite. The Middle Jurassic granites are related to the closure of the Küre-Yusufeli marginal ocean basin. The Küre and Yusufeli ophiolites have been previously interpreted as the remnants of the Paleotethys or the Intra-Pontide Ocean. However, we posit that these ophiolites represent amarginal, short-lived（;0 Ma） ocean basin, which opened during the late Triassic through Liassic, and then closed in Dogger. This oceanic lithosphere is similar to the Evros ophiolite in the northeastern Greece in terms of its ages and geochemical characteristics.
文摘Optical cathodoluminescence microscopy (CLM) can provide very useful information both on mineral zoning formed during crystal growth and on variations in chemical composition of sphalerites which is reflected by their visible colors. Gem quality sphalerite crystals associated with dolomite, calcite and fluorite having 3 different visible colors - green, honey and brown - were studied to compare their mineral chemistry and CL characteristics. Electron microprobe analyses indicated essentially no significant differences in terms of major components. Although the common CL-quencher ferrous iron contents of all three were lower than 0.25 wt %, none of the sphalerites cathodoluminescenced: two (brown and honey) were non-CL, the green sphalerite showed very week CL in faint brown color. Other trace elements that were analyzed include Fe, Cd, Mn, Ag, Hg, In, Bi, Cu, Ge, and Ga. Fe, Cd, Ga and Cu were relatively higher than the others. Most significant differences with respect to the common trace elements include honey colored sphalerites are essentially Fe- and Cd-poor but rich in Ga, green sphalerites are Fe- and Cd- rich but poor in all the others, and brown sphalerites are rich in Cd. No conclusive relation between non-CL behavior of all three sphalerites and their trace element chemistry was established, however; low quantities of common CL activators in sphalerite crystal structures such as Mn, Cu, and In were the main cause of the non-CL behavior.
