A series of fluorinated copolyimides containing phthalazinone moieties were prepared from 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride(6FDA),3,3'4,4'-benzophenone-tetracarboxylic dianhydride(BPDA)...A series of fluorinated copolyimides containing phthalazinone moieties were prepared from 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride(6FDA),3,3'4,4'-benzophenone-tetracarboxylic dianhydride(BPDA)and2-(4-aminophenyl)-4-[4-(4-aminophenoxyl)phenyl]-2,3-phthalazin-1-one(DHPZ-2NH_2)for making polymeric opticalwaveguides.The resulting copolymers containing 0-50 mo1% BPDA/DHPZ-2NH_2 show good solubility and are soluble insome organic polar aprotic solvents.The copolyimides also present excellent thermal stability.These polymers possess highglass transition temperature higher than 603 K and high decomposition temperature above 742 K determined by differentialscanning calorimetry and thennogravimetric analysis,respectively,under a nitrogen atmosphere.Their refractive indicescould be controlled by varying the ratio of 6FDA and BPDA in the copolymer from 0.5 to 1.0,and the in-plane refractiveindices(n_(TE))range from 1.6366 to 1.6668 and the out-of-plane refractive indices(n_(TM))from 1.6024 to 1.6280 at 632.8 nm.The polymers birefringence(0.0342-0.0388)is almost independent of the 6FDA content of copolymer,which indicated thatthe phthalazinone-containing copolyimides could be suitable to fabricate optical waveguides possessing a low polarizationdependent loss(PDL).展开更多
基金This work was supported by the National Natural Science Foundation of China(No.50143013).
文摘A series of fluorinated copolyimides containing phthalazinone moieties were prepared from 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride(6FDA),3,3'4,4'-benzophenone-tetracarboxylic dianhydride(BPDA)and2-(4-aminophenyl)-4-[4-(4-aminophenoxyl)phenyl]-2,3-phthalazin-1-one(DHPZ-2NH_2)for making polymeric opticalwaveguides.The resulting copolymers containing 0-50 mo1% BPDA/DHPZ-2NH_2 show good solubility and are soluble insome organic polar aprotic solvents.The copolyimides also present excellent thermal stability.These polymers possess highglass transition temperature higher than 603 K and high decomposition temperature above 742 K determined by differentialscanning calorimetry and thennogravimetric analysis,respectively,under a nitrogen atmosphere.Their refractive indicescould be controlled by varying the ratio of 6FDA and BPDA in the copolymer from 0.5 to 1.0,and the in-plane refractiveindices(n_(TE))range from 1.6366 to 1.6668 and the out-of-plane refractive indices(n_(TM))from 1.6024 to 1.6280 at 632.8 nm.The polymers birefringence(0.0342-0.0388)is almost independent of the 6FDA content of copolymer,which indicated thatthe phthalazinone-containing copolyimides could be suitable to fabricate optical waveguides possessing a low polarizationdependent loss(PDL).
