Oxidation of cyclohexene under 1 atmospheric pressure of molecular oxygen at 70C in the absence of solvent catalyzed by PAMAM-SA-M (Where PAMAM = polyamidoamine; SA = salicyaldehyde; M = metal ions Fe3+, Co2+, Ni2+, M...Oxidation of cyclohexene under 1 atmospheric pressure of molecular oxygen at 70C in the absence of solvent catalyzed by PAMAM-SA-M (Where PAMAM = polyamidoamine; SA = salicyaldehyde; M = metal ions Fe3+, Co2+, Ni2+, Mn2+, Cu2+, Zn2+, respectively) dendrimers, afforded 2-cyclohexen-1-ol 1, 2-cyclohexen-1-one 2, 7-oxabicyclo [4,1,0] heptane 3 and 7-oxabicyl [4,1,0] heptan-2-one 4 as the major products. The factors that affect this reaction are also discussed.展开更多
The transformation from graphite to turbostratic graphite by means of the treatment with high energy ball milling was investigated by X ray powder diffraction method. It is believed that the size effect of nano cry...The transformation from graphite to turbostratic graphite by means of the treatment with high energy ball milling was investigated by X ray powder diffraction method. It is believed that the size effect of nano crystal leads to this transformation. A possible transformation mechanism is proposed from the change of the eletronic structure of the hexagonal plane of the carbon atoms.展开更多
Compression creep tests of a Ti-48%Al (mole fraction) alloy were carried out at 1?150?K with soft-orientated PST crystal. Parallel twinning took place during the creep. Changes in lamellar microstructure caused by the...Compression creep tests of a Ti-48%Al (mole fraction) alloy were carried out at 1?150?K with soft-orientated PST crystal. Parallel twinning took place during the creep. Changes in lamellar microstructure caused by the parallel twinning were investigated, and their effects on creep deformation behavior were discussed. The results show that the parallel twinning occurs in an early stage of creep, and makes significant contribution to creep strain in the domains favorably oriented for the twinning. The nucleation of parallel twins finishes at a strain of about 3%. There is a critical resolved shear stress for parallel twinning, and it is about 50?MPa in the Ti 48%Al PST crystals at 1?150?K. The activity of parallel twinning increases with increasing applied stress or in a coarse lamellar material. The addition of parallel twins reduces the average value of lamellar spacing. In general, the refinement of lamellar structure should improve creep resistance. However the strengthening by parallel twinning is not evident in creep of the soft PST crystals because the soft deformation modes are the dominant deformation mode in the crystals.展开更多
The positron lifetime spectra of severalAl_(93.3-x)Fe_(4.3)V_(0.7)Si_(1.7)Mm_x (x = 0.5%, 1.0%, 3.0%, atom fraction) alloys with differentcontent of misch metal prepared by rapid solidification were measured, and the ...The positron lifetime spectra of severalAl_(93.3-x)Fe_(4.3)V_(0.7)Si_(1.7)Mm_x (x = 0.5%, 1.0%, 3.0%, atom fraction) alloys with differentcontent of misch metal prepared by rapid solidification were measured, and the variations on theinterfacial defects with the content of misch metal were revealed by an analysis of the lifetimeresults. The interface characteristics derived from the lifetime results could be used to give asatisfactory interpretation of the dependence of mechanical properties on the content of mischmetal.展开更多
Based on the Radon transform and fractional Fourier transform we introduce the fractional Radon trans-formation (FRT). We identify the transform kernel for FRT. The FRT of Wigner operator is derived, which naturallyre...Based on the Radon transform and fractional Fourier transform we introduce the fractional Radon trans-formation (FRT). We identify the transform kernel for FRT. The FRT of Wigner operator is derived, which naturallyreduces to the projector of eigenvector of the rotated quadrature in the usual Radon transform case.展开更多
Several aryloxy acetic acids were synthesized under microwave irradiation. The factors, which affect the reaction, were investigated and optimized. It was revealed that the best yields(92.7%—97.4%) were obtained when...Several aryloxy acetic acids were synthesized under microwave irradiation. The factors, which affect the reaction, were investigated and optimized. It was revealed that the best yields(92.7%—97.4%) were obtained when the molar ratio of the reactants was n(ArOH)∶n(NaOH)∶n(ClCH 2CO 2H) =1∶2.5∶1.2 with microwave irradiation power of 640 W for 65—85 s.展开更多
The electron paramagnetic resonance (EPR) parameters (zero-Geld splitting Dand g factors g_‖, g_⊥) of Cr~(4+) ions in Ca_2 GeO_4 crystals have been calculated from thecomplete high-order perturbation formulas of EPR...The electron paramagnetic resonance (EPR) parameters (zero-Geld splitting Dand g factors g_‖, g_⊥) of Cr~(4+) ions in Ca_2 GeO_4 crystals have been calculated from thecomplete high-order perturbation formulas of EPR parameters for a 3d~2 ion in trigonal MX_4clusters. In these formulas, in addition to the contributions to EPR parameters from the widely usedcrystal-field (CF) mechanism, the contributions from the charge-transfer (CT) mechanism (which areoften neglected) are included. From the calculations, it is found that for the high valence state3d~n ions in crystals, the reasonable explanation of EPR parameters (in particular, the g factors)should take both the CF and CT mechanisms into account.展开更多
The g factors g||,g⊥ and hyperfine structure constants A||,A⊥ for two trigonal Co^2+ centers (i.e.,Co^2+ in Cd^2+ (I) and Cd^2+ (Ⅱ) sites) in CsCdCl3:Co^2+ crystals are calculated from the high-order perturbation f...The g factors g||,g⊥ and hyperfine structure constants A||,A⊥ for two trigonal Co^2+ centers (i.e.,Co^2+ in Cd^2+ (I) and Cd^2+ (Ⅱ) sites) in CsCdCl3:Co^2+ crystals are calculated from the high-order perturbation formulas based on the cluster approach.In the calculation,the contributions from covalency effect and configuration interaction effect are considered and the parameters related to both effects are obtained from the optical spectrum and the structure data of the studied system.The results are in good agreement with the observed values.展开更多
With in situ IR, two different CO adsorption bands were detected on various chemical state gold catalysts. One band is attributed to the linear CO on an oxidized gold catalyst(2100 cm -1 ), the other one is as...With in situ IR, two different CO adsorption bands were detected on various chemical state gold catalysts. One band is attributed to the linear CO on an oxidized gold catalyst(2100 cm -1 ), the other one is ascribed to the bridged CO on metallic gold (2085 cm -1 ). CO pulse reaction showed that Au/Fe 2O 3 catalyst had a room temperature activity even in the presence of moisture. The produced CO 2 was detained and more easily desorbed from supported gold catalyst than support oxide. TPD IDT results indicated that the O - 2 superoxide ions are the possible active oxygen species.展开更多
Alloy 718 is a precipitation strengthened nickel-based superalloy based on the precipitation of γ″-Ni3Nb (DO22 structure) and γ′-Ni3(Al,Ti) (L12 structure) phases. Creep crack growth rate (CCGR) was investigated a...Alloy 718 is a precipitation strengthened nickel-based superalloy based on the precipitation of γ″-Ni3Nb (DO22 structure) and γ′-Ni3(Al,Ti) (L12 structure) phases. Creep crack growth rate (CCGR) was investigated after high temperature exposure at 593, 650 and 677℃ for 2000h in Alloy 718. In addition to the coalescence of γ′/ γ″ and the amount increasing of δ phase, the existence of a bcc chromium enriched α-Cr phase was observed by SEM, and the weight fraction of α-Cr and other phases were determined by chemical phase analysis methods. The CCGR behavior and regulation have been analyzed by means of strength and structure analysis approaches. The experimental results show higher the exposure temperature and longer the exposure time, lower the CCGR. This is probably attributed to the interaction of material softening and brittling due to complex structure changes during high temperature exposure. Therefore, despite α-Cr phase formation and amount enhancement were run in this test range. It seems to us a small amount of α-Cr will be not harmful for creep crack propagation resistance, which is critical for disk application in aircraft and land-based gas turbine.展开更多
The effect of annealing treatment on the structure of CdS films was investigated. The cadmium sulfide thin films were prepared by chemical bath deposition, and were annealed at nitrogen atmosphere at different tempera...The effect of annealing treatment on the structure of CdS films was investigated. The cadmium sulfide thin films were prepared by chemical bath deposition, and were annealed at nitrogen atmosphere at different temperatures. The films were characterized by SEM and XPS (X-ray photoelectron spectroscopy). X-ray photoelectron spectroscopy was used to examine the chemical states on the CdS films surface. It was found that thermal annealing could produce large grains of CdS thin films, remove the air contamination and reduce the oxygen content on the CdS films surface. Therefore, the CdS films changed more uniform and smoother surface after thermal annealing.展开更多
文摘Oxidation of cyclohexene under 1 atmospheric pressure of molecular oxygen at 70C in the absence of solvent catalyzed by PAMAM-SA-M (Where PAMAM = polyamidoamine; SA = salicyaldehyde; M = metal ions Fe3+, Co2+, Ni2+, Mn2+, Cu2+, Zn2+, respectively) dendrimers, afforded 2-cyclohexen-1-ol 1, 2-cyclohexen-1-one 2, 7-oxabicyclo [4,1,0] heptane 3 and 7-oxabicyl [4,1,0] heptan-2-one 4 as the major products. The factors that affect this reaction are also discussed.
文摘The transformation from graphite to turbostratic graphite by means of the treatment with high energy ball milling was investigated by X ray powder diffraction method. It is believed that the size effect of nano crystal leads to this transformation. A possible transformation mechanism is proposed from the change of the eletronic structure of the hexagonal plane of the carbon atoms.
文摘Compression creep tests of a Ti-48%Al (mole fraction) alloy were carried out at 1?150?K with soft-orientated PST crystal. Parallel twinning took place during the creep. Changes in lamellar microstructure caused by the parallel twinning were investigated, and their effects on creep deformation behavior were discussed. The results show that the parallel twinning occurs in an early stage of creep, and makes significant contribution to creep strain in the domains favorably oriented for the twinning. The nucleation of parallel twins finishes at a strain of about 3%. There is a critical resolved shear stress for parallel twinning, and it is about 50?MPa in the Ti 48%Al PST crystals at 1?150?K. The activity of parallel twinning increases with increasing applied stress or in a coarse lamellar material. The addition of parallel twins reduces the average value of lamellar spacing. In general, the refinement of lamellar structure should improve creep resistance. However the strengthening by parallel twinning is not evident in creep of the soft PST crystals because the soft deformation modes are the dominant deformation mode in the crystals.
基金This work is supported by the National Natural Science Foundation of China (No. 59771020)
文摘The positron lifetime spectra of severalAl_(93.3-x)Fe_(4.3)V_(0.7)Si_(1.7)Mm_x (x = 0.5%, 1.0%, 3.0%, atom fraction) alloys with differentcontent of misch metal prepared by rapid solidification were measured, and the variations on theinterfacial defects with the content of misch metal were revealed by an analysis of the lifetimeresults. The interface characteristics derived from the lifetime results could be used to give asatisfactory interpretation of the dependence of mechanical properties on the content of mischmetal.
文摘Based on the Radon transform and fractional Fourier transform we introduce the fractional Radon trans-formation (FRT). We identify the transform kernel for FRT. The FRT of Wigner operator is derived, which naturallyreduces to the projector of eigenvector of the rotated quadrature in the usual Radon transform case.
文摘Several aryloxy acetic acids were synthesized under microwave irradiation. The factors, which affect the reaction, were investigated and optimized. It was revealed that the best yields(92.7%—97.4%) were obtained when the molar ratio of the reactants was n(ArOH)∶n(NaOH)∶n(ClCH 2CO 2H) =1∶2.5∶1.2 with microwave irradiation power of 640 W for 65—85 s.
文摘The electron paramagnetic resonance (EPR) parameters (zero-Geld splitting Dand g factors g_‖, g_⊥) of Cr~(4+) ions in Ca_2 GeO_4 crystals have been calculated from thecomplete high-order perturbation formulas of EPR parameters for a 3d~2 ion in trigonal MX_4clusters. In these formulas, in addition to the contributions to EPR parameters from the widely usedcrystal-field (CF) mechanism, the contributions from the charge-transfer (CT) mechanism (which areoften neglected) are included. From the calculations, it is found that for the high valence state3d~n ions in crystals, the reasonable explanation of EPR parameters (in particular, the g factors)should take both the CF and CT mechanisms into account.
文摘The g factors g||,g⊥ and hyperfine structure constants A||,A⊥ for two trigonal Co^2+ centers (i.e.,Co^2+ in Cd^2+ (I) and Cd^2+ (Ⅱ) sites) in CsCdCl3:Co^2+ crystals are calculated from the high-order perturbation formulas based on the cluster approach.In the calculation,the contributions from covalency effect and configuration interaction effect are considered and the parameters related to both effects are obtained from the optical spectrum and the structure data of the studied system.The results are in good agreement with the observed values.
文摘With in situ IR, two different CO adsorption bands were detected on various chemical state gold catalysts. One band is attributed to the linear CO on an oxidized gold catalyst(2100 cm -1 ), the other one is ascribed to the bridged CO on metallic gold (2085 cm -1 ). CO pulse reaction showed that Au/Fe 2O 3 catalyst had a room temperature activity even in the presence of moisture. The produced CO 2 was detained and more easily desorbed from supported gold catalyst than support oxide. TPD IDT results indicated that the O - 2 superoxide ions are the possible active oxygen species.
基金The authors thank Ladish Co.,Inc.to support the test samples for this analysis.And this work was supported by the National Natural Science Foundation of China(No.50171005)the Teaching and Research Award Program for Outstanding Young Teachers in Higher Education Institutions of MOE to support it.
文摘Alloy 718 is a precipitation strengthened nickel-based superalloy based on the precipitation of γ″-Ni3Nb (DO22 structure) and γ′-Ni3(Al,Ti) (L12 structure) phases. Creep crack growth rate (CCGR) was investigated after high temperature exposure at 593, 650 and 677℃ for 2000h in Alloy 718. In addition to the coalescence of γ′/ γ″ and the amount increasing of δ phase, the existence of a bcc chromium enriched α-Cr phase was observed by SEM, and the weight fraction of α-Cr and other phases were determined by chemical phase analysis methods. The CCGR behavior and regulation have been analyzed by means of strength and structure analysis approaches. The experimental results show higher the exposure temperature and longer the exposure time, lower the CCGR. This is probably attributed to the interaction of material softening and brittling due to complex structure changes during high temperature exposure. Therefore, despite α-Cr phase formation and amount enhancement were run in this test range. It seems to us a small amount of α-Cr will be not harmful for creep crack propagation resistance, which is critical for disk application in aircraft and land-based gas turbine.
基金The financial support was provided by the National High Technology Research and Development Program of China(Grant No.2001AA513011).
文摘The effect of annealing treatment on the structure of CdS films was investigated. The cadmium sulfide thin films were prepared by chemical bath deposition, and were annealed at nitrogen atmosphere at different temperatures. The films were characterized by SEM and XPS (X-ray photoelectron spectroscopy). X-ray photoelectron spectroscopy was used to examine the chemical states on the CdS films surface. It was found that thermal annealing could produce large grains of CdS thin films, remove the air contamination and reduce the oxygen content on the CdS films surface. Therefore, the CdS films changed more uniform and smoother surface after thermal annealing.
