In order to establish a new method for making cellulose and lignin from Masson pine, a high boiling solvent(HBS) pulping process with an aqueous solvent of 1,4-butanediol was investigated. Masson pine chips were pulpe...In order to establish a new method for making cellulose and lignin from Masson pine, a high boiling solvent(HBS) pulping process with an aqueous solvent of 1,4-butanediol was investigated. Masson pine chips were pulped with a 70%—90% aqueous solution of 1,4-butanediol containing a small amount of a catalyst at 200—220 ℃ for 60—180 min. HBS Masson pine cellulose is suitable for making paper. Water-insoluble HBS lignin was separated from the liquor reaction mixture by water precipitation. The recovered high boiling solvent(RHBS) is able to be recycled as a pulping solvent, indicating that the HBS method is a pulping process of Masson pine which is energy saving, resources saving and pollution free. HBS lignin has a better chemical reactivity and a lower ash content than lignin sulfonate.展开更多
In order to establish a new method for making cellulose and lignin from bamboo, a high boiling solvent (HBS) pulping process with aqueous solvcnt of 1,4-butanediol was investigated. Bamboo chips were pulped with 70～9...In order to establish a new method for making cellulose and lignin from bamboo, a high boiling solvent (HBS) pulping process with aqueous solvcnt of 1,4-butanediol was investigated. Bamboo chips were pulped with 70～90% aqueous solution of 1. 4-butanediol containing a small amount of catalyst at 180～200℃ for 30～90 min. HBS bamboo cellulose is suitable for making paper. Water-insoluble HBS lignin was separated from the liquor reaction mixture by water precipitation. Recovery high boiling solvents (RHBS) is able to recycle as a pulping solvent indicating that the HBS method is a pulping process of bamboo with saving energy, saving resources and non-pollution. HBS lignin has better chemical activity and lower ash content than lignin sulfonate.展开更多
New cyclic peptides 1 and 2 were isolated from the endophytic fungus #2221 fromCastaniopsis fissa on the south China sea coast. By 2D NMR methods and chiral HPLC technique,their structures were elucidated as cyclo (L-...New cyclic peptides 1 and 2 were isolated from the endophytic fungus #2221 fromCastaniopsis fissa on the south China sea coast. By 2D NMR methods and chiral HPLC technique,their structures were elucidated as cyclo (L-Val-L-Leu-L-Val-L-Leu) and cyclo(L-Leu-L-Ala-L-Leu-L-Ala), respectively.展开更多
A new activation method has been developed for electroless copper plating on silicon wafer based on palladium chemisorption on SAMs of APTS without SnCl2 sensitization and roughening condition. A closely packed elect...A new activation method has been developed for electroless copper plating on silicon wafer based on palladium chemisorption on SAMs of APTS without SnCl2 sensitization and roughening condition. A closely packed electroless copper film with strong adhesion is successfully formed by AFM observation. XPS study indicates that palladium chemisorption occurred via palladium chloride bonding to the pendant amino group of the SAMs.展开更多
The structure and mechanism of isomerization of CH3SB have been studied by using DFT method at the B3LYP/6-311G** level. The computational results reveal that the energy of singlet state of CH3SB is lower than that ...The structure and mechanism of isomerization of CH3SB have been studied by using DFT method at the B3LYP/6-311G** level. The computational results reveal that the energy of singlet state of CH3SB is lower than that of triplet state, so the former should be the ground state. Two transition states of isomerization of singlet state of CH3SB have been determined at the B3L-YP/6- 311G** level, too. The methyl linked to sulfur atom is first transferring to the boron atom, to which the hydrogen atom of methyl is then transferring. According to the results of this paper, reaction paths of isomerizations of CH3SB are studied thoroughly with IRC method.展开更多
Photopromoted methoxycarbonylation of olefins with carbon monoxide can be carried out under ambient conditions with non-precious transition metal complexes (such as cobalt complexes) catalysts in DMF. The isotope expe...Photopromoted methoxycarbonylation of olefins with carbon monoxide can be carried out under ambient conditions with non-precious transition metal complexes (such as cobalt complexes) catalysts in DMF. The isotope experiments show that DMF is decomposed under irradiation and is conveniently used as a carbon monoxide source for the reaction.展开更多
Sinenxan A [2α, 5α, 10β, 14β-tetraacetoxytaxa-4(20), 11-diene, 1] was biotransformed by a filamentous fungus, Aspergillus niger JCM 5546, and an unusual taxatetraene [2α, 5α-acetoxytaxa-4(20), 10(11), 12(18), 13...Sinenxan A [2α, 5α, 10β, 14β-tetraacetoxytaxa-4(20), 11-diene, 1] was biotransformed by a filamentous fungus, Aspergillus niger JCM 5546, and an unusual taxatetraene [2α, 5α-acetoxytaxa-4(20), 10(11), 12(18), 13(14)-tetraene, 2], together with two known products, 10β-deacetyl sinenxan A (3) and 10β, 14β-dideacetyl sinenxan A (4) were produced.展开更多
Photopromoted carbonylation of alkyl halides with carbon monoxide can be carried out under ambient conditions with non-precious transition metal complexes (such as cobalt complexes) catalysts. Our preliminary work sh...Photopromoted carbonylation of alkyl halides with carbon monoxide can be carried out under ambient conditions with non-precious transition metal complexes (such as cobalt complexes) catalysts. Our preliminary work showed that alkyl halides can be transformed into alkene and alkane directly under irradiation, but the esters can not be transformed. It is assumed that the carbonylation of alkyl halides may be proceeded in two ways.展开更多
The formation of ( t BuCp) 2ErOEt was discussed. Its single crystal structure was determined by X ray diffraction. The crystal is monoclinic, P 2(1)/ c space group, a =1.0191(2), b =1.6203(5), c ...The formation of ( t BuCp) 2ErOEt was discussed. Its single crystal structure was determined by X ray diffraction. The crystal is monoclinic, P 2(1)/ c space group, a =1.0191(2), b =1.6203(5), c =1.2118(3) nm, β =102.960(10)°, V =1.9500 (nm 3), Z =2, D c=1.566 mg·m -3 , R =0.0450, R w=0.1363. The complex is monomeric and solvent free in the solid state. The erbium ion is coordinated by two tert butyl cyclopentadienyl rings and one oxygen atom of ethoxy group to form a seven coordinated complex.展开更多
The insertion reaction of phenyl isothiocyanate into the Ln S bond was studied. Phenyl isothiocyanate reacted with [(CH 3C 5H 4) 2Sm(SPh)(THF)] 2 to give the title complex, (CH 3C 5H 4) 2Sm[SC(SPh)NPh](THF),...The insertion reaction of phenyl isothiocyanate into the Ln S bond was studied. Phenyl isothiocyanate reacted with [(CH 3C 5H 4) 2Sm(SPh)(THF)] 2 to give the title complex, (CH 3C 5H 4) 2Sm[SC(SPh)NPh](THF), in good yield, which was characterized by elemental analyses, IR, 1H NMR and X ray structural determination. The crystal structure analysis of complex shows that samarium atom is coordinated by two CH 3C 5H 4 groups, one O atom of THF, and N and S atoms from the SC(SPh)NPh ligand to form a distorted trigonal bipyramidal geometry.展开更多
A series of NH_4Cs_(1.5)Fe_(0.08)H_xPVMo_(11)As_aO_y heteropolycompoundcatalysts for the selective oxidation of isobutane, having Keggin structure, were synthesized byusing co-precipitation method. The catalysts were ...A series of NH_4Cs_(1.5)Fe_(0.08)H_xPVMo_(11)As_aO_y heteropolycompoundcatalysts for the selective oxidation of isobutane, having Keggin structure, were synthesized byusing co-precipitation method. The catalysts were characterized by FT-IR, H_2-TPR, TG-DTA, SEM andXRD. Effects of the As content, reaction time, reaction temperature and molar ratio of isobutane tooxygen in feedstock on the activity and selectivity of the catalyst were investigated. Theactivation energy of the catalysts was measured by kinetics researches. Results showed theintroduction of Cs^+ into the catalysts shortened the stable period of them and enhanced theircatalytic activity for the selective oxidation of isobutane. The highest conversion of isobutane andthe total selectivity to liquid products were 18.6% and 81.2%, respectively, which were obtained at380℃ with a space velocity of 975 h^(-1) over the NH_4Cs_(1.5)Fe_(0.08)H_xPVMo_(11) As_(0.3)O_yheteropolycompound catalyst. It is confirmed that completely oxidized products were controlled well.展开更多
This paper described a new immunoassay method by capillary electrophoresis with enhanced chemiluminescence (CL) detection system based on luminol-hydrogen peroxide reaction catalyzed by horseradish peroxides (HRP). Us...This paper described a new immunoassay method by capillary electrophoresis with enhanced chemiluminescence (CL) detection system based on luminol-hydrogen peroxide reaction catalyzed by horseradish peroxides (HRP). Using para-iodophenol as a CL enhancer, the detection limit of about 1×10-12 mol/L for HRP was achieved, which corresponded to 1.32×10-5 U/mL. In optimal conditions, the free HRP-labeled CA125 antibody (Ab*) and the bound enzyme-labeled complex (Ab*-Ag) were well separated by capillary electrophoresis within 4 min. The assay was successfully used to determine the contents of CA125 in human sera, which were associated with ovarian cancer, and the recoveries of the standard addition experiments were 96 to 109 %.展开更多
A new diterpenoid trisaccharide, smithoside A, was isolated from Aster smithianus. Itsstructure was identified as pimar-15 (16)-β-en-3β, 8β, 11α-triol-3-O-β-D-glucopyranosyl (1→3)-[β-glucopyranosyl (1→2)]-β-D...A new diterpenoid trisaccharide, smithoside A, was isolated from Aster smithianus. Itsstructure was identified as pimar-15 (16)-β-en-3β, 8β, 11α-triol-3-O-β-D-glucopyranosyl (1→3)-[β-glucopyranosyl (1→2)]-β-D-glucopyranoside on the basis of the spectral and chemical methods.展开更多
Three chiral N-ferrocenylmethylaminoalcohols were synthesized from readily available natural L-valine, leucine and phenylanine, and used as chiral ligands in the enantioselective addition of diethylzinc to aldehydes.
The lanthanide Schiff base complex [2-OC6H4CHN(2,6-i-Pr2C6H3)]2ErCl(THF) (C42H52ClErN2O3) has been prepared by the reaction of anhydrous LnCl3 with 2 equiv. of the sodium salt of the bidentate Schiff base N-(2,6-diiso...The lanthanide Schiff base complex [2-OC6H4CHN(2,6-i-Pr2C6H3)]2ErCl(THF) (C42H52ClErN2O3) has been prepared by the reaction of anhydrous LnCl3 with 2 equiv. of the sodium salt of the bidentate Schiff base N-(2,6-diisopropylphenyl)salicylaldimine in THF. The crystal structure was determined by X-ray diffraction analysis. The crystal belongs to triclinic, space group P1 with a = 9.200(1), b = 13.637(2), c = 16.705(2) ? a = 74.493(7), b = 77.979(8), g = 81.306(8), V = 1965.2(4) ?, Z = 2, Mr = 835.60, Dc = 1.412 g/cm3, F(000) = 854, T = 193 K, l(MoKa) = 0.7107 ?and m = 22.38 cm-1. The final R = 0.052 and wR = 0.076 for 8386 observed reflections with I ≥ 2s(I).展开更多
The copper(II) complex [Cu(teta)N(CN)2](ClO4)H2O (teta = 5,7,7,12,14,14- hexamethyl-1,4,8,11-tetraazacyclotetradecane) has been synthesized and the crystal structure was determined by single-crystal X-ray diffraction....The copper(II) complex [Cu(teta)N(CN)2](ClO4)H2O (teta = 5,7,7,12,14,14- hexamethyl-1,4,8,11-tetraazacyclotetradecane) has been synthesized and the crystal structure was determined by single-crystal X-ray diffraction. Crystal data: C18H38ClCuN7O5, monoclinic, space group P21/n, a = 8.796(3), b = 11.885(4), c = 23.054(9) , b = 97.540(4)o, V = 2389.3(15) 3, Mr = 531.54, Z = 4, Dc = 1.478 g/cm3, F(000) = 1124, ?= 1.070 mm-1, the final R = 0.0566 and wR = 0.1162 for 4749 observed reflections (I > 2s(I)). The center copper ion is coordinated by five nitrogen atoms in a square pyramidal geometry, with four from the macrocyclic ligand teta and the other one from a nitrile nitrogen atom of dicyanamide which is coordinated to the metal atoms as uni-dentate manner via nitrile nitrogen atom.展开更多
A stable Pd(II) compound Pd(AETYF)Cl2CH2Cl2 (AETYF = 4?5?diaza-9? (4,5-bis(ethylthio)-1,3-dithiole-2-ylidene)-fluorene) has been synthesized and its crystal structure was determined by X-ray crystallography. The cryst...A stable Pd(II) compound Pd(AETYF)Cl2CH2Cl2 (AETYF = 4?5?diaza-9? (4,5-bis(ethylthio)-1,3-dithiole-2-ylidene)-fluorene) has been synthesized and its crystal structure was determined by X-ray crystallography. The crystal is of monoclinic, space group P21/c with a = 15.249(6), b = 8.619(3), c = 19.078(7) ? b = 106.932(8), C19H18Cl4N2PdS4, Mr = 650.79, V = 2398.6(16) 3, Z = 4, Dc = 1.802 g/cm3, F(000) = 1296, m = 1.579 mm-1, Npar = 268, the final R = 0.0538 and wR = 0.1282 for 5068 observed reflections with I > 2s(I). The crystal structure determi- nation shows that the atoms of the molecule, except two ethyl-groups, are conjugated in a quasi- plane and these molecules are further stacked or contacted via plane to plane or edge to edge p-p interactions, forming parallel molecular chains along the b axis.展开更多
N-Phosphoryl peptide libraries were constructed by transformation from homo-oligopeptide libraries, which was synthesized by self-assembly of amino acids with the assistance of phosphorus oxychloride. Electrospray ion...N-Phosphoryl peptide libraries were constructed by transformation from homo-oligopeptide libraries, which was synthesized by self-assembly of amino acids with the assistance of phosphorus oxychloride. Electrospray ionization mass spectrometry (ESI-MS) was used to monitor the reaction.展开更多
The crystal structure of the title compound UO2(NO3)2[CH2(CH2)2CONC8H17] was determined by single-crystal X-ray diffraction. Crystal data: triclinic, space group P , a = 7.456(2), b = 8.371(2), c = 13.470(3) ? ?= 95.6...The crystal structure of the title compound UO2(NO3)2[CH2(CH2)2CONC8H17] was determined by single-crystal X-ray diffraction. Crystal data: triclinic, space group P , a = 7.456(2), b = 8.371(2), c = 13.470(3) ? ?= 95.66(1), ?= 94.64(2), ?= 102.67(2), C24H46N4O10U, Mr = 788.68, V = 811.7(3) ?, Dc = 1.613 g/cm3, Z = 1, F(000) = 390, ?= 5.052 mm-1, the final R = 0.0256 and wR = 0.0568 for 2826 observed reflections (I > 2(I)). The central uranyl ions are coordinated by six oxygen atoms. Two of them are from the carbonyl groups of N-octyl-a-pyrrolidone molecules, and the other four from two nitrate groups.展开更多
基金Supported by the Science and Technology Fund of Fujian Education Departm ent(No.JB 0 2 0 5 8) ,Scientific Develop-ment Fund of Econom y and Trade Comm ission of Fujian Province(No.2 0 0 30 7) ,Science and Technology Department Fund ofFuzhou City(No.
文摘In order to establish a new method for making cellulose and lignin from Masson pine, a high boiling solvent(HBS) pulping process with an aqueous solvent of 1,4-butanediol was investigated. Masson pine chips were pulped with a 70%—90% aqueous solution of 1,4-butanediol containing a small amount of a catalyst at 200—220 ℃ for 60—180 min. HBS Masson pine cellulose is suitable for making paper. Water-insoluble HBS lignin was separated from the liquor reaction mixture by water precipitation. The recovered high boiling solvent(RHBS) is able to be recycled as a pulping solvent, indicating that the HBS method is a pulping process of Masson pine which is energy saving, resources saving and pollution free. HBS lignin has a better chemical reactivity and a lower ash content than lignin sulfonate.
文摘In order to establish a new method for making cellulose and lignin from bamboo, a high boiling solvent (HBS) pulping process with aqueous solvcnt of 1,4-butanediol was investigated. Bamboo chips were pulped with 70～90% aqueous solution of 1. 4-butanediol containing a small amount of catalyst at 180～200℃ for 30～90 min. HBS bamboo cellulose is suitable for making paper. Water-insoluble HBS lignin was separated from the liquor reaction mixture by water precipitation. Recovery high boiling solvents (RHBS) is able to recycle as a pulping solvent indicating that the HBS method is a pulping process of bamboo with saving energy, saving resources and non-pollution. HBS lignin has better chemical activity and lower ash content than lignin sulfonate.
基金This work was supported by the National Natural Science Foundation of China(0072058)863 Foundation of China(2003AA624010)+2 种基金the National Natural Science Foundation of Guangdong Province,China(021732,2003A 3050401)a strategic grant at City University of Hong Kong(7000650)E.B.G.J.acknowledges the Royal Society,U.K.and City University of Hong Kong for the award of the Kan Tong Po Visiting Professorship.
文摘New cyclic peptides 1 and 2 were isolated from the endophytic fungus #2221 fromCastaniopsis fissa on the south China sea coast. By 2D NMR methods and chiral HPLC technique,their structures were elucidated as cyclo (L-Val-L-Leu-L-Val-L-Leu) and cyclo(L-Leu-L-Ala-L-Leu-L-Ala), respectively.
基金This work was supported by the National Natural Science Foundation of China (No.69890220)Promotional Foundation of Ministry of Education of China for excellent youth teacher (2000) Open Project Foundation of Laboratory of Solid State Microstruct
文摘A new activation method has been developed for electroless copper plating on silicon wafer based on palladium chemisorption on SAMs of APTS without SnCl2 sensitization and roughening condition. A closely packed electroless copper film with strong adhesion is successfully formed by AFM observation. XPS study indicates that palladium chemisorption occurred via palladium chloride bonding to the pendant amino group of the SAMs.
文摘The structure and mechanism of isomerization of CH3SB have been studied by using DFT method at the B3LYP/6-311G** level. The computational results reveal that the energy of singlet state of CH3SB is lower than that of triplet state, so the former should be the ground state. Two transition states of isomerization of singlet state of CH3SB have been determined at the B3L-YP/6- 311G** level, too. The methyl linked to sulfur atom is first transferring to the boron atom, to which the hydrogen atom of methyl is then transferring. According to the results of this paper, reaction paths of isomerizations of CH3SB are studied thoroughly with IRC method.
文摘Photopromoted methoxycarbonylation of olefins with carbon monoxide can be carried out under ambient conditions with non-precious transition metal complexes (such as cobalt complexes) catalysts in DMF. The isotope experiments show that DMF is decomposed under irradiation and is conveniently used as a carbon monoxide source for the reaction.
基金supported by the National Natural Science Foundation of China(Project No.30100230)the Japan Society for the Promotion of Science(Project No.1300127).
文摘Sinenxan A [2α, 5α, 10β, 14β-tetraacetoxytaxa-4(20), 11-diene, 1] was biotransformed by a filamentous fungus, Aspergillus niger JCM 5546, and an unusual taxatetraene [2α, 5α-acetoxytaxa-4(20), 10(11), 12(18), 13(14)-tetraene, 2], together with two known products, 10β-deacetyl sinenxan A (3) and 10β, 14β-dideacetyl sinenxan A (4) were produced.
基金We are indebted to the National Natural Science Foundations of China(No.20172010,20242004),for the generous financial support
文摘Photopromoted carbonylation of alkyl halides with carbon monoxide can be carried out under ambient conditions with non-precious transition metal complexes (such as cobalt complexes) catalysts. Our preliminary work showed that alkyl halides can be transformed into alkene and alkane directly under irradiation, but the esters can not be transformed. It is assumed that the carbonylation of alkyl halides may be proceeded in two ways.
基金the Science and Technology Foundation of Shaanxi Key L aboratory of Physico- inorganic Chemistry(No.2 93,2 0 0 1) and the Science and Technology Foundation of the National Defense Key L aboratory ofPropellant and Ex-plosive Combustion of China(No.5 14
文摘The formation of ( t BuCp) 2ErOEt was discussed. Its single crystal structure was determined by X ray diffraction. The crystal is monoclinic, P 2(1)/ c space group, a =1.0191(2), b =1.6203(5), c =1.2118(3) nm, β =102.960(10)°, V =1.9500 (nm 3), Z =2, D c=1.566 mg·m -3 , R =0.0450, R w=0.1363. The complex is monomeric and solvent free in the solid state. The erbium ion is coordinated by two tert butyl cyclopentadienyl rings and one oxygen atom of ethoxy group to form a seven coordinated complex.
文摘The insertion reaction of phenyl isothiocyanate into the Ln S bond was studied. Phenyl isothiocyanate reacted with [(CH 3C 5H 4) 2Sm(SPh)(THF)] 2 to give the title complex, (CH 3C 5H 4) 2Sm[SC(SPh)NPh](THF), in good yield, which was characterized by elemental analyses, IR, 1H NMR and X ray structural determination. The crystal structure analysis of complex shows that samarium atom is coordinated by two CH 3C 5H 4 groups, one O atom of THF, and N and S atoms from the SC(SPh)NPh ligand to form a distorted trigonal bipyramidal geometry.
基金Supported by Scientific Research Fund of Hunnan Provincial Education Department (03C515) Hunan Provincial Natural Science Foundation of China (04jj6003)
文摘A series of NH_4Cs_(1.5)Fe_(0.08)H_xPVMo_(11)As_aO_y heteropolycompoundcatalysts for the selective oxidation of isobutane, having Keggin structure, were synthesized byusing co-precipitation method. The catalysts were characterized by FT-IR, H_2-TPR, TG-DTA, SEM andXRD. Effects of the As content, reaction time, reaction temperature and molar ratio of isobutane tooxygen in feedstock on the activity and selectivity of the catalyst were investigated. Theactivation energy of the catalysts was measured by kinetics researches. Results showed theintroduction of Cs^+ into the catalysts shortened the stable period of them and enhanced theircatalytic activity for the selective oxidation of isobutane. The highest conversion of isobutane andthe total selectivity to liquid products were 18.6% and 81.2%, respectively, which were obtained at380℃ with a space velocity of 975 h^(-1) over the NH_4Cs_(1.5)Fe_(0.08)H_xPVMo_(11) As_(0.3)O_yheteropolycompound catalyst. It is confirmed that completely oxidized products were controlled well.
基金supported by the National Natural Science Foundation of China(No.20271033)the key project of National Natural Science Foundation of China(No.20335020)Natural Science Foundation of Shanghai(No.02ZA14057).
文摘This paper described a new immunoassay method by capillary electrophoresis with enhanced chemiluminescence (CL) detection system based on luminol-hydrogen peroxide reaction catalyzed by horseradish peroxides (HRP). Using para-iodophenol as a CL enhancer, the detection limit of about 1×10-12 mol/L for HRP was achieved, which corresponded to 1.32×10-5 U/mL. In optimal conditions, the free HRP-labeled CA125 antibody (Ab*) and the bound enzyme-labeled complex (Ab*-Ag) were well separated by capillary electrophoresis within 4 min. The assay was successfully used to determine the contents of CA125 in human sera, which were associated with ovarian cancer, and the recoveries of the standard addition experiments were 96 to 109 %.
文摘A new diterpenoid trisaccharide, smithoside A, was isolated from Aster smithianus. Itsstructure was identified as pimar-15 (16)-β-en-3β, 8β, 11α-triol-3-O-β-D-glucopyranosyl (1→3)-[β-glucopyranosyl (1→2)]-β-D-glucopyranoside on the basis of the spectral and chemical methods.
文摘Three chiral N-ferrocenylmethylaminoalcohols were synthesized from readily available natural L-valine, leucine and phenylanine, and used as chiral ligands in the enantioselective addition of diethylzinc to aldehydes.
文摘The lanthanide Schiff base complex [2-OC6H4CHN(2,6-i-Pr2C6H3)]2ErCl(THF) (C42H52ClErN2O3) has been prepared by the reaction of anhydrous LnCl3 with 2 equiv. of the sodium salt of the bidentate Schiff base N-(2,6-diisopropylphenyl)salicylaldimine in THF. The crystal structure was determined by X-ray diffraction analysis. The crystal belongs to triclinic, space group P1 with a = 9.200(1), b = 13.637(2), c = 16.705(2) ? a = 74.493(7), b = 77.979(8), g = 81.306(8), V = 1965.2(4) ?, Z = 2, Mr = 835.60, Dc = 1.412 g/cm3, F(000) = 854, T = 193 K, l(MoKa) = 0.7107 ?and m = 22.38 cm-1. The final R = 0.052 and wR = 0.076 for 8386 observed reflections with I ≥ 2s(I).
基金The project was supported by the Natural Science Foundation of University of Jiangsu Province (No. 03KJB150118) and Funds of Key laboratory of Organic Synthesis of Jiangsu Province
文摘The copper(II) complex [Cu(teta)N(CN)2](ClO4)H2O (teta = 5,7,7,12,14,14- hexamethyl-1,4,8,11-tetraazacyclotetradecane) has been synthesized and the crystal structure was determined by single-crystal X-ray diffraction. Crystal data: C18H38ClCuN7O5, monoclinic, space group P21/n, a = 8.796(3), b = 11.885(4), c = 23.054(9) , b = 97.540(4)o, V = 2389.3(15) 3, Mr = 531.54, Z = 4, Dc = 1.478 g/cm3, F(000) = 1124, ?= 1.070 mm-1, the final R = 0.0566 and wR = 0.1162 for 4749 observed reflections (I > 2s(I)). The center copper ion is coordinated by five nitrogen atoms in a square pyramidal geometry, with four from the macrocyclic ligand teta and the other one from a nitrile nitrogen atom of dicyanamide which is coordinated to the metal atoms as uni-dentate manner via nitrile nitrogen atom.
基金the National Natural Science Foundation of China (20071024 20371033) and Suzhou University
文摘A stable Pd(II) compound Pd(AETYF)Cl2CH2Cl2 (AETYF = 4?5?diaza-9? (4,5-bis(ethylthio)-1,3-dithiole-2-ylidene)-fluorene) has been synthesized and its crystal structure was determined by X-ray crystallography. The crystal is of monoclinic, space group P21/c with a = 15.249(6), b = 8.619(3), c = 19.078(7) ? b = 106.932(8), C19H18Cl4N2PdS4, Mr = 650.79, V = 2398.6(16) 3, Z = 4, Dc = 1.802 g/cm3, F(000) = 1296, m = 1.579 mm-1, Npar = 268, the final R = 0.0538 and wR = 0.1282 for 5068 observed reflections with I > 2s(I). The crystal structure determi- nation shows that the atoms of the molecule, except two ethyl-groups, are conjugated in a quasi- plane and these molecules are further stacked or contacted via plane to plane or edge to edge p-p interactions, forming parallel molecular chains along the b axis.
文摘N-Phosphoryl peptide libraries were constructed by transformation from homo-oligopeptide libraries, which was synthesized by self-assembly of amino acids with the assistance of phosphorus oxychloride. Electrospray ionization mass spectrometry (ESI-MS) was used to monitor the reaction.
基金This work was supported by the National Natural Science Foundation of China and the funds of the Key Laboratory of Organic Syntheses of Jiansu Province
文摘The crystal structure of the title compound UO2(NO3)2[CH2(CH2)2CONC8H17] was determined by single-crystal X-ray diffraction. Crystal data: triclinic, space group P , a = 7.456(2), b = 8.371(2), c = 13.470(3) ? ?= 95.66(1), ?= 94.64(2), ?= 102.67(2), C24H46N4O10U, Mr = 788.68, V = 811.7(3) ?, Dc = 1.613 g/cm3, Z = 1, F(000) = 390, ?= 5.052 mm-1, the final R = 0.0256 and wR = 0.0568 for 2826 observed reflections (I > 2(I)). The central uranyl ions are coordinated by six oxygen atoms. Two of them are from the carbonyl groups of N-octyl-a-pyrrolidone molecules, and the other four from two nitrate groups.
