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Advances and new perspectives of optical systems and technologies for aerospace applications: a comprehensive review
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作者 Sandro Oliveira Jan Nedoma +1 位作者 Radek Martinek Carlos Marques 《Opto-Electronic Advances》 2025年第8期2-24,共23页
The aerospace industry is a very unforgiving field, where even the smallest error could have catastrophic consequences.To reduce the risk of disaster, multiple systems are put into place to provide accurate informatio... The aerospace industry is a very unforgiving field, where even the smallest error could have catastrophic consequences.To reduce the risk of disaster, multiple systems are put into place to provide accurate information for informed decisionmaking. The field of optics has played a pivotal role in advancing space exploration and technology. From enabling preciseobservations of distant celestial objects to facilitating communication across vast interstellar distances, optics hasbecome an indispensable tool in space science and supported by significant advances in the last few years, new and improvedapplications continue to arise. This review aims to explore the diverse applications of optical systems and technologiesin the aerospace industry, highlighting recent developments regarding navigation, communications, process andstructural health monitoring, as well as the monitorization of astronauts' health. 展开更多
关键词 astronaut well-being structural health monitoring navigation and optical communication in space
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LinguTimeX a Framework for Multilingual CTC Detection Using Explainable AI and Natural Language Processing
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作者 Omar Darwish Shorouq Al-Eidi +4 位作者 Abdallah Al-Shorman Majdi Maabreh Anas Alsobeh Plamen Zahariev Yahya Tashtoush 《Computers, Materials & Continua》 2026年第1期2231-2251,共21页
Covert timing channels(CTC)exploit network resources to establish hidden communication pathways,posing signi cant risks to data security and policy compliance.erefore,detecting such hidden and dangerous threats remain... Covert timing channels(CTC)exploit network resources to establish hidden communication pathways,posing signi cant risks to data security and policy compliance.erefore,detecting such hidden and dangerous threats remains one of the security challenges. is paper proposes LinguTimeX,a new framework that combines natural language processing with arti cial intelligence,along with explainable Arti cial Intelligence(AI)not only to detect CTC but also to provide insights into the decision process.LinguTimeX performs multidimensional feature extraction by fusing linguistic attributes with temporal network patterns to identify covert channels precisely.LinguTimeX demonstrates strong e ectiveness in detecting CTC across multiple languages;namely English,Arabic,and Chinese.Speci cally,the LSTM and RNN models achieved F1 scores of 90%on the English dataset,89%on the Arabic dataset,and 88%on the Chinese dataset,showcasing their superior performance and ability to generalize across multiple languages. is highlights their robustness in detecting CTCs within security systems,regardless of the language or cultural context of the data.In contrast,the DeepForest model produced F1-scores ranging from 86%to 87%across the same datasets,further con rming its e ectiveness in CTC detection.Although other algorithms also showed reasonable accuracy,the LSTM and RNN models consistently outperformed them in multilingual settings,suggesting that deep learning models might be better suited for this particular problem. 展开更多
关键词 Arabic language Chinese language covert timing channel CYBERSECURITY deep learning English language language processing machine learning
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Performance Analysis of Mixed Amplify-and-Forward and Decode-and-Forward Protocol in Underlay Cognitive Networks 被引量:3
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作者 Tran Trung Duy Hyung Yun Kong 《China Communications》 SCIE CSCD 2016年第3期115-126,共12页
In this paper, we propose and evaluate outage performance of a mixed amplify-and-forward(AF) and decode-and-forward(DF) relaying protocol in underlay cognitive radio. Different from the conventional AF and DF protocol... In this paper, we propose and evaluate outage performance of a mixed amplify-and-forward(AF) and decode-and-forward(DF) relaying protocol in underlay cognitive radio. Different from the conventional AF and DF protocols, in the proposed protocol, a secondary source attempts to transmit its signal to a secondary destination with help of two secondary relays. One secondary relay always operates in AF mode, while the remaining one always operates in DF mode. Moreover, we also propose a relay selection method, which relies on the decoding status at the DF relay. For performance evaluation and comparison, we derive the exact and approximate closedform expressions of the outage probability for the proposed protocol over Rayleigh fading channel. Finally, we run Monte Carlo simulations to verify the derivations. Results presented that the proposed protocol obtains a diversity order of three and the outage performance of our scheme is between that of the conventional underlay DF protocol and that of the conventional underlay AF protocol. 展开更多
关键词 underlay cognitive network cooperative communication outage probability mixed AF and DF protocols Rayleigh fading channel
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Effects of sampling frequency on node mobility prediction in dynamic networks: A spectral view 被引量:1
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作者 Peppino Fazio Miralem Mehic Miroslav Voznak 《Digital Communications and Networks》 SCIE CSCD 2023年第4期1009-1022,共14页
The field of mobility prediction has been widely investigated in the recent past,especially the reduction of the coverage radius of cellular networks,which led to an increase in hand-over events.Changing the cell cove... The field of mobility prediction has been widely investigated in the recent past,especially the reduction of the coverage radius of cellular networks,which led to an increase in hand-over events.Changing the cell coverage very frequently,for example,may lead to service disruptions if a predictive approach is not deployed in the system.Although several works examined mobility prediction in the new-generation mobile networks,all of these studies focused on studying the time features of mobility traces,and the spectral content of historical mobility patterns was not considered for prediction purposes as yet.In the present study,we propose a new approach to mobility prediction by analyzing the effects of a proper mobility sampling frequency.The proposed approach lies in the mobility analysis in the frequency domain,to extract hidden features of the mobility process.Thus,we proposed a new methodology to determine the spectral content of mobility traces(considered as signals)and,thus,the appropriate sampling frequency,which can provide numerous advantages.We considered several types of mobility models(e.g.pedestrian,urban,and vehicular),containing important details in the time and frequency domains.Several simulation campaigns were performed to observe and analyze the characteristics of mobility from real traces and to evaluate the effects of sampling frequency on the spectral content. 展开更多
关键词 Mobile networking Frequency domain Mobility spectrum
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A deep learning fusion model for accurate classification of brain tumours in Magnetic Resonance images 被引量:1
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作者 Nechirvan Asaad Zebari Chira Nadheef Mohammed +8 位作者 Dilovan Asaad Zebari Mazin Abed Mohammed Diyar Qader Zeebaree Haydar Abdulameer Marhoon Karrar Hameed Abdulkareem Seifedine Kadry Wattana Viriyasitavat Jan Nedoma Radek Martinek 《CAAI Transactions on Intelligence Technology》 SCIE EI 2024年第4期790-804,共15页
Detecting brain tumours is complex due to the natural variation in their location, shape, and intensity in images. While having accurate detection and segmentation of brain tumours would be beneficial, current methods... Detecting brain tumours is complex due to the natural variation in their location, shape, and intensity in images. While having accurate detection and segmentation of brain tumours would be beneficial, current methods still need to solve this problem despite the numerous available approaches. Precise analysis of Magnetic Resonance Imaging (MRI) is crucial for detecting, segmenting, and classifying brain tumours in medical diagnostics. Magnetic Resonance Imaging is a vital component in medical diagnosis, and it requires precise, efficient, careful, efficient, and reliable image analysis techniques. The authors developed a Deep Learning (DL) fusion model to classify brain tumours reliably. Deep Learning models require large amounts of training data to achieve good results, so the researchers utilised data augmentation techniques to increase the dataset size for training models. VGG16, ResNet50, and convolutional deep belief networks networks extracted deep features from MRI images. Softmax was used as the classifier, and the training set was supplemented with intentionally created MRI images of brain tumours in addition to the genuine ones. The features of two DL models were combined in the proposed model to generate a fusion model, which significantly increased classification accuracy. An openly accessible dataset from the internet was used to test the model's performance, and the experimental results showed that the proposed fusion model achieved a classification accuracy of 98.98%. Finally, the results were compared with existing methods, and the proposed model outperformed them significantly. 展开更多
关键词 brain tumour deep learning feature fusion model MRI images multi‐classification
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Application of the Point-Descriptor-Precedence representation for micro-scale traffic analysis at a non-signalized T-junction
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作者 Amna Qayyum Bernard De Baets +3 位作者 Laure De Cock Frank Witlox Guy De Tré Nico Van de Weghe 《Geo-Spatial Information Science》 SCIE EI CSCD 2023年第3期406-430,共25页
An intersection of two or more roads poses a risk for potential conflicts among vehicles.Often the reasons triggering such conflicts are not clear,as they might be too subtle for the human eye.The environment also pla... An intersection of two or more roads poses a risk for potential conflicts among vehicles.Often the reasons triggering such conflicts are not clear,as they might be too subtle for the human eye.The environment also plays a part in understanding where,when,and why a particular vehicle interaction has occurred in a certain way.Therefore,it is of paramount importance to dive deeper into the vehicle interaction at a micro-scale within the embedded geographical environment,particularly at the intersections.This would in turn assist in evaluating the association of vehicle interactions with conflict risks and near-miss accidents.Moreover,detection of such micro traffic interactions could also be used to improvise the complexity of the already established transport infrastructure.Conversely,traffic at intersections has been explored mainly for flow estimation,capacity and width measurements,and traffic congestion,etc.,whereas the detection of micro-scale traffic interactions at intersections remains relatively under-explored.In this paper,we present a novel approach to retrieve and represent micro-scale traffic movement interactions at a non-signalized T-junction by extending a recently introduced qualitative spatiotemporal Point-Descriptor-Precedence(PDP)representation.We study how the PDP representation offers a fine solution to study the interaction of traffic flows at intersections.This permits tracking the micro-movement of vehicles in much finer detail,which is used later to retrieve movement patterns from a motion dataset.Unlike conventional approaches,we start our approach with the actual movements before modeling the static intersection environment.Additionally,with the aid of illustrative examples,we discuss how the length,width,and speed of the vehicles can be exploited in our approach to detect specific patterns more accurately.Additionally,we address the potential benefits of our approach for traffic safety assessment and how it can be extended to a network of intersections using different transport modes. 展开更多
关键词 Vehicle interaction traffic research pattern identification traffic safety spatiotemporal representation movement pattern
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Natural Rubber Based Composites Comprising Different Types of Carbon-Silica Hybrid Fillers. Comparative Study on Their Electric, Dielectric and Microwave Properties, and Possible Applications 被引量:1
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作者 Ahmed A. Al-Ghamdi Omar A. Al-Hartomy +4 位作者 Falleh R. Al-Solamy Nikolay Dishovsky Mihail Mihaylov Petrunka Malinova Nikolay Atanasov 《Materials Sciences and Applications》 2016年第6期295-306,共12页
The paper presents a comparative study on the electric, dielectric and microwave properties of natural rubber based composites comprising dual phase fillers prepared from furnace carbon black or conductive carbon blac... The paper presents a comparative study on the electric, dielectric and microwave properties of natural rubber based composites comprising dual phase fillers prepared from furnace carbon black or conductive carbon black with a different amount of silica. It has been established that, the specifics of the carbon phase have a marked strong effect upon the properties mentioned above. The interpenetration of the two filler phases and the grade of isolation of the conductive carbon phase by the dielectric one depend on the ratio between them. On the other hand, that leads to a change in all properties of the studied composites, which allows tailoring those characteristics. 展开更多
关键词 Polymer Composites Hybrid Fillers Dielectric Properties Microwave Properties
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Hybrid In-Vehicle Background Noise Reduction for Robust Speech Recognition:The Possibilities of Next Generation 5G Data Networks
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作者 Radek Martinek Jan Baros +2 位作者 Rene Jaros Lukas Danys Jan Nedoma 《Computers, Materials & Continua》 SCIE EI 2022年第6期4659-4676,共18页
This pilot study focuses on employment of hybrid LMS-ICA system for in-vehicle background noise reduction.Modern vehicles are nowadays increasingly supporting voice commands,which are one of the pillars of autonomous ... This pilot study focuses on employment of hybrid LMS-ICA system for in-vehicle background noise reduction.Modern vehicles are nowadays increasingly supporting voice commands,which are one of the pillars of autonomous and SMART vehicles.Robust speaker recognition for context-aware in-vehicle applications is limited to a certain extent by in-vehicle back-ground noise.This article presents the new concept of a hybrid system which is implemented as a virtual instrument.The highly modular concept of the virtual car used in combination with real recordings of various driving scenarios enables effective testing of the investigated methods of in-vehicle background noise reduction.The study also presents a unique concept of an adaptive system using intelligent clusters of distributed next generation 5G data networks,which allows the exchange of interference information and/or optimal hybrid algorithm settings between individual vehicles.On average,the unfiltered voice commands were successfully recognized in 29.34%of all scenarios,while the LMS reached up to 71.81%,and LMS-ICA hybrid improved the performance further to 73.03%. 展开更多
关键词 5G noise reduction hybrid algorithms speech recognition 5G data networks in-vehicle background noise
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Analysis and Improvement of the Real-Time Segmented Pulse Compression-Detection Algorithm
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作者 YANG Jian-xi XU Ping +1 位作者 XIE Xiao-hua MA Ying-jie 《Journal of Donghua University(English Edition)》 EI CAS 2016年第6期928-932,共5页
Real-Time segmented pulse compression-detection is one of the key technologies of space-borne tracking receiver.Its implementation requires an optimized and dedicated hardware.The real-time processing places several c... Real-Time segmented pulse compression-detection is one of the key technologies of space-borne tracking receiver.Its implementation requires an optimized and dedicated hardware.The real-time processing places several constraints such as area occupied,power comumption,and speed.A number of segmented compression techniques have been proposed to overcome these limitations and decrease the processing latency.However,relatively high power loss in the partial field could limit their implementation in many current real-time systems.A good theoretical model was designed with intersection signal accumulation to enhance signal-noise-ratio(SNR)gain of detecting signal in the paper.From the experimental results it is known that this approach works well for pulse compression-detection,which is better suited for implementation in the high performance of current field programmable gate array(FPGA)with dedicated hardware multipliers. 展开更多
关键词 linear frequency modulation(LFM) segmented pulse compression signal-noise-ratio(SNR)gain target detection
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Comparison of Vertical Handover Decision-Based Techniques in Heterogeneous Networks
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作者 Adada Edia Opeyemi Osanaiye +1 位作者 Folayo Aina Olayinka Ogundile 《International Journal of Communications, Network and System Sciences》 2018年第12期239-259,共21页
Industry leaders are currently setting out standards for 5G networks projected for 2020 or even sooner. Future generation networks will be heterogeneous in nature as no single network type will be capable of optimally... Industry leaders are currently setting out standards for 5G networks projected for 2020 or even sooner. Future generation networks will be heterogeneous in nature as no single network type will be capable of optimally meeting all the rapid changes in customer demands. With the advent of multi-homed devices and heterogeneous network (HetNet) solution, great concerns arise in the processes involved for successful handover. Active calls that get dropped or cases of poor quality of service experienced by mobile users can be attributed to the phenomenon of delayed handover (HO) or an outright case of an unsuccessful handover procedure. This work compares multiple criteria handover basis to its traditional single relative signal strength (RSS) base counterpart. It analyses the performance of a fuzzy-based VHO algorithm scheme in a Wi-Fi, WiMAX, UMTS and LTE integrated network using OMNeT++ event simulator. The loose coupling network architecture is adopted and simulation results analysed for the two major categories of handover;the multiple and single criteria. Results obtained show a better overall throughput, better call dropped rate and shorter handover time for the multiple criteria based decision method as compared to the single criteria based technique. This work also highlights current research trends, challenges of seamless handover and initiatives for Next Generation HetNet. 展开更多
关键词 Index Terms-Heterogeneous Network LTE Radio Access Technology RSSI UMTS Wi-Fi WiMAX. Vertical HANDOVER
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Highly Efficient Conversion of Solar Energy by the Photoelectric Converter and a Thermoelectric Converter
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作者 A. M. Kasimakhunova Sh. A. Olimov +2 位作者 R. Nurdinova Tahir Iqbal L. K. Mamadalieva 《Journal of Applied Mathematics and Physics》 2018年第3期520-529,共10页
The analysis of the principle operation of the solar element is given in the work. The efficiency of the creation of combined high-efficiency converters of network energy in electric and thermal is indicated. A method... The analysis of the principle operation of the solar element is given in the work. The efficiency of the creation of combined high-efficiency converters of network energy in electric and thermal is indicated. A method for creating a combined photo thermo converter with a high value of the efficiency of a solar element has been found. A method for separating light from optical lenses is shown. The calculation of the light intensity into diffraction pattern is calculated using the Huygens-Fresnel principle. A new design of a highly efficient combined light-thermal converter into an electrical, with a solar element, operating on selective photoactive radiation is presented. The process of conversion of non-active radiation into electrical radiation by means of a thermo electronic converter is described. The ways of the solution of the problem connected with the reduction of the coefficient of its full effect as a function of temperature and characteristics are indicated. 展开更多
关键词 Photo CONVERTER Spectrum Electrical Energy THERMO CONVERTER Photo-Thermo CONVERTER
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The Effect of Speech Fragmentation and Audio Encodings on Automatic Parkinson’s Disease Recognition
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作者 Dávid Sztahó Attila Zoltán Jenei +1 位作者 István Valálik Klára Vicsi 《Journal of Biomedical Science and Engineering》 2022年第1期6-25,共20页
Parkinson’s disease is a neurological disease which is incurable according to current clinical knowledge. Therefore, early detection and provision of appropriate treatment are of primary importance. Speech is one of ... Parkinson’s disease is a neurological disease which is incurable according to current clinical knowledge. Therefore, early detection and provision of appropriate treatment are of primary importance. Speech is one of the biomarkers that enable the detection of Parkinson’s disease affection. Numerous researches are based on recordings from controlled environments;nonetheless fewer apply real circumstances. In the present study, three objectives were examined: recording fragmentation (paragraph, sentences, time-based), variable encodings (Pulse-Code Modulation [PCM], GSM-Full Rate [FR], G.723.1) and majority voting on 8 kHz records using multiple classifiers. Support Vector Machine (SVM), Long Short-Term Memory (LSTM), i-vector and x-vector classifiers were evaluated in contrast with SVM as baseline. The highest results in accuracy and F1-score were achieved using i-vector models. Although variable encodings generally caused decrease in Parkinson-disease recognition, decline was within 2% - 3% at best. Moreover, fragmentation did not yield a clear outcome though some classifiers performed with the very similar efficiency along the differently fragmented sets. Majority voting did produce a slight increase in classification performance compared to as if no aggregation is used. 展开更多
关键词 Parkinson’s Disease SPEECH Support Vector Machine Neural Network i-Vector x-Vector
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Complex Permittivity and Permeability Studies Viewing Antenna Applications of NBR-Based Composites Comprising Conductive Fillers
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作者 Abdullah G. Al-Sehemi Ahmed A. Al-Ghamdi +2 位作者 Nikolay T. Dishovsky Nikolay T. Atanasov Gabriela L. Atanasova 《Materials Sciences and Applications》 2018年第11期883-899,共17页
The work presents studies on the complex permittivity and permeability of composites based on acrylonitrile butadiene rubber containing combinations of conductive fillers which include carbon black and nickel powder. ... The work presents studies on the complex permittivity and permeability of composites based on acrylonitrile butadiene rubber containing combinations of conductive fillers which include carbon black and nickel powder. The properties of those composites, containing each of the fillers at the same amount were compared. The permittivity and permeability values of the composites are influenced remarkably by their morphology and structure as well as by the morphological and structural specifics of both fillers. As electron scanning microscopy studies confirm, those parameters are predetermined by the nature of the composites studied—particle size, particles arrangement in the matrix and their tendency to clustering. Last but not least matrix-filler interface phenomena also impact the characteristics in question. The possibilities for applications of the composites in antennae have been studied, in particular, as substrates and insulating layers in flexible antennae for body centric communications (BCCs). The research results allow the conclusion that these materials can find such applications indeed. Composites of higher conductivity can be used where surface waves are generated to provide on-body communications, while composites of lower conductivity may be used for antennae that will be on the body of a person and will transmit to and receive from other antennas that are not on the body of the same person (off-body communications). It is clear that one can engineer the properties of antennae substrates at microwave frequencies by adjusting the filler content and the type of filler and thus control and tailor the antenna performance specific for a particular application. 展开更多
关键词 NBR COMPOSITES Conductive FILLERS ANTENNA APPLICATIONS Complex Permittivity and PERMEABILITY
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Optimization of Quantizer’s Segment Threshold Using Spline Approximations for Optimal Compressor Function
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作者 Lazar Velimirovic Zoran Peric +1 位作者 Miomir Stankovic Jelena Nikolic 《Applied Mathematics》 2012年第10期1430-1434,共5页
In this paper, the optimization of quantizer’s segment threshold is done. The quantizer is designed on the basis of approximative spline functions. Coefficients on which we form approximative spline functions are cal... In this paper, the optimization of quantizer’s segment threshold is done. The quantizer is designed on the basis of approximative spline functions. Coefficients on which we form approximative spline functions are calculated by minimization mean square error (MSE). For coefficients determined in this way, spline functions by which optimal compressor function is approximated are obtained. For the quantizer designed on the basis of approximative spline functions, segment threshold is numerically determined depending on maximal value of the signal to quantization noise ratio (SQNR). Thus, quantizer with optimized segment threshold is achieved. It is shown that by quantizer model designed in this way and proposed in this paper, the SQNR that is very close to SQNR of nonlinear optimal companding quantizer is achieved. 展开更多
关键词 Optimization of Quantizer’s Segment Threshold Mean Square Error Second-Degree Spline Functions Compressor Function
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Correlation between Electrical Conductivity and Microwave Shielding Effectiveness of Natural Rubber Based Composites, Containing Different Hybrid Fillers Obtained by Impregnation Technology
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作者 Ahmed A. Al-Ghamdi Omar A. Al-Hartomy +4 位作者 Falleh R. Al-Solamy Nikolay T. Dishovsky Petrunka Malinova Nikolay T. Atanasov Gabriela L. Atanasova 《Materials Sciences and Applications》 2016年第9期496-509,共14页
The paper presents the synthesis and characterization of carbon black/silicone dioxide hybrid fillers obtained by an impregnation technology. The electromagnetic interference shielding effectiveness of the composites ... The paper presents the synthesis and characterization of carbon black/silicone dioxide hybrid fillers obtained by an impregnation technology. The electromagnetic interference shielding effectiveness of the composites filled with carbon black/silicone dioxide hybrid fillers was measured in wide frequency range of 1 - 12 GHz. The dc and ac electrical conductivity of composites also have been investigated. The relationship between electrical (dc and ac) conductivity and shielding effectiveness was analyzed. A positive correlation was found between the absorptive shielding effectiveness and ac conductivity for composites comprising conductive carbon black/silica filler, when the filler loading is above the percolation threshold. 展开更多
关键词 Composite Materials CORRELATION Electrical Conductivity Shielding Effectiveness
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Detection of leaf structures in close-range hyperspectral images using morphological fusion
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作者 Gladys Villegas Wenzhi Liao +2 位作者 Ronald Criollo Wilfried Philips Daniel Ochoa 《Geo-Spatial Information Science》 CSCD 2017年第4期325-332,共8页
Close-range hyperspectral images are a promising source of information in plant biology,in particular,for in vivo study of physiological changes.In this study,we investigate how data fusion can improve the detection o... Close-range hyperspectral images are a promising source of information in plant biology,in particular,for in vivo study of physiological changes.In this study,we investigate how data fusion can improve the detection of leaf elements by combining pixel reflectance and morphological information.The detection of image regions associated to the leaf structures is the first step toward quantitative analysis on the physical effects that genetic manipulation,disease infections,and environmental conditions have in plants.We tested our fusion approach on Musa acuminata (banana) leaf images and compared its discriminant capability to similar techniques used in remote sensing.Experimental results demonstrate the efficiency of our fusion approach,with significant improvements over some conventional methods. 展开更多
关键词 HYPERSPECTRAL FUSION MORPHOLOGY PLANT BIOLOGY
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数字图像识别在混合油类三维荧光光谱分析中的应用 被引量:9
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作者 孔德明 崔耀耀 +2 位作者 孔令富 王书涛 史慧超 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2019年第11期3407-3413,共7页
海上溢油已成为全球环境污染的重要问题之一,溢油严重破坏了海洋生态的平衡,并导致人类健康受到危害。因此,研究高效的溢油检测方法对保护海洋生态环境具有重要意义。三维荧光光谱技术因能获得溢油的“指纹”图谱而成为溢油鉴别领域的... 海上溢油已成为全球环境污染的重要问题之一,溢油严重破坏了海洋生态的平衡,并导致人类健康受到危害。因此,研究高效的溢油检测方法对保护海洋生态环境具有重要意义。三维荧光光谱技术因能获得溢油的“指纹”图谱而成为溢油鉴别领域的有效分析手段,其与平行因子分析算法相结合获得了良好的溢油鉴别效果。但平行因子算法在使用过程中需要确定不同石油产品本身所适用的浓度范围,且其对预估计组分数敏感,组分数选择是否准确直接影响最终定性定量结果,这些问题都会对油类检测造成使用上的限制。油类组分极为复杂,其中各组分间不存在统一的线性浓度范围,其相互之间还受到荧光猝灭效应的影响。直接对未经稀释的油类样本进行光谱数据采集,所获得的三维荧光光谱会因样本中组分的种类及其含量不同而存在较大差异,导致对三维荧光光谱数据进行解析的平行因子分析算法不再适用。但组分的种类及含量相近的油样其光谱特征相似度较高,并且随着特定组分及其含量的改变,其光谱形状的变化规律也较为明显。基于此,将三维荧光光谱和数字图像识别相结合,提出一种针对混合油类样本的辨识方法。首先,利用五种矿物油(汽油、柴油、航空煤油、机油和润滑油)配制三类混合油样本,其中每类混合油是用其中两种不同矿物油以不同体积比直接混合配制而成;然后利用FS920荧光光谱仪获取样本的三维荧光光谱数据,并对该数据进行求导及灰度化预处理,进而得到三维荧光导数光谱灰度图;其次提取样本三维荧光导数光谱灰度图的颜色、纹理和形状等数字图像特征;最后,通过Fisher判别分析建立样本的分类模型,采用逐步回归建立混合油样本各组分相对体积的定量模型。分类模型对三类混合油样本的分类及识别效果良好。所建立的定量模型的线性相关性R大于0.99,显著性检验p值小于0.05。研究结果表明,三维荧光光谱的数字图像特征可以被本文所述方法有效提取并用于对油类样本的定性定量分析。该研究为海面溢油检测提供了一种简单、可靠的识别方法。 展开更多
关键词 溢油检测 三维荧光光谱 数字图像识别 FISHER判别 逐步回归
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海面溢油三维荧光光谱消除瑞利散射方法的研究 被引量:10
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作者 孔德明 李雨蒙 +2 位作者 崔耀耀 张春祥 王书涛 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2020年第9期2791-2797,共7页
三维荧光光谱分析法以其灵敏度高、选择性好、操作简单和可用于多组分混合物分析等优点成为诸多研究者在海面溢油鉴别中的热点选择。但三维荧光光谱中存在的瑞利散射会对光谱的准确检测产生较大的影响,因此有效地消除瑞利散射对后续光... 三维荧光光谱分析法以其灵敏度高、选择性好、操作简单和可用于多组分混合物分析等优点成为诸多研究者在海面溢油鉴别中的热点选择。但三维荧光光谱中存在的瑞利散射会对光谱的准确检测产生较大的影响,因此有效地消除瑞利散射对后续光谱的定性鉴别和定量分析具有重要意义。采用仪器校正法、空白扣除法、 Delaunay三角形内插值法和缺损数据重构(MDR)法对海面溢油三维荧光光谱中的瑞利散射进行校正。首先以海水的SDS胶束溶液作为溶剂,将航空煤油和润滑油按不同相对体积分数比配制8个校正样本和3个测试样本;然后利用FS920稳态荧光光谱仪采集11个样本的三维荧光光谱数据,并分别采用仪器校正法、空白扣除法、 Delaunay三角形内插值法和缺损数据重构(MDR)法消除瑞利散射的干扰;再利用核一致诊断法估计出最佳的组分数;最后利用平行因子分析(PARAFAC)对混合油样本的三维荧光光谱数据进行定性鉴别和定量分析。研究结果表明:采用发射波长滞后激发波长以消除瑞利散射的仪器校正法会丢失部分有效光谱信息;采用空白扣除法无法彻底消除瑞利散射,在光谱中仍然存在散射干扰,利用PARAFAC解析后得到的激发、发射光谱会出现失真,且预测的浓度值偏差较大;采用Delaunay三角形内插值法消除瑞利散射后,利用PARAFAC解析所得到的激发、发射光谱与真实光谱吻合度较高,且预测的浓度值偏差较小;而采用MDR消除瑞利散射后,利用PARAFAC解析所获得的激发、发射光谱与真实光谱吻合度最高,且相较于其他几种方法预测的浓度值偏差最小,得到的样本回收率为98.9%和100%,预测均方根误差均小于等于0.130。根据定性鉴别、定量分析的结果, MDR能够在保证原有特征光谱不失真的基础上有效消除瑞利散射带来的影响,是一种消除三维荧光光谱数据中瑞利散射较为理想的方法。 展开更多
关键词 三维荧光光谱 瑞利散射 空白扣除法 Delaunay三角形内插值法 缺损数据重构法
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结合平行因子分析算法和模式识别方法的三维荧光光谱技术用于石油类污染物的检测 被引量:8
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作者 孔德明 宋乐乐 +2 位作者 崔耀耀 张春祥 王书涛 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2020年第9期2798-2803,共6页
随着海洋中石油资源的不断开发,泄漏到海洋环境中的石油也日益增多,它不仅威胁着海洋生态环境,同时也严重影响着人们的身体健康。因此,快速、有效地检测出海洋环境中的石油类污染物对于保护海洋生态环境和人类健康具有重要意义。石油产... 随着海洋中石油资源的不断开发,泄漏到海洋环境中的石油也日益增多,它不仅威胁着海洋生态环境,同时也严重影响着人们的身体健康。因此,快速、有效地检测出海洋环境中的石油类污染物对于保护海洋生态环境和人类健康具有重要意义。石油产品中含有大量的多环芳烃,其具有较强的荧光特性。因此,荧光光谱技术成为检测石油类污染物的重要手段之一。利用三维荧光光谱技术结合平行因子分析算法和模式识别方法,对石油类污染物进行表征和分类。首先,以海水和十二烷基硫酸钠(SDS)配制的胶束溶液作为溶剂,分别配制不同浓度的柴油、航空煤油、汽油和润滑油溶液,最终得到80个实验样本;然后,利用FLS920型荧光光谱仪采集实验样本的三维荧光光谱数据,并通过Delaunay三角形内插值法对所获得的三维荧光光谱数据进行去散射处理;其次,利用平行因子分析(PARAFAC)算法分解去散射后的三维荧光光谱数据,通过运用核一致诊断法和残差分析法对组分数进行估计;最后,为了建立稳健的分类模型,利用Kennard-Stone算法将80个实验样本分为60个训练集样本和20个测试集样本,运用K最近邻(KNN)算法、主成分判别分析(PCA-LDA)算法以及偏最小二乘判别分析(PLS-DA)算法分别建立分类模型,并利用灵敏度、特异性和准确率对分类效果进行评估。研究结果表明:三种分类模型对测试集中样本的识别准确率分别为85%, 90%和94%,其中, PLS-DA分类模型对测试集样本的识别准确率最高,具有最佳的分类效果。因此,在利用平行因子分析算法提取石油类污染物荧光光谱数据的基础上,结合模式识别方法可以很好的对不同种类油品进行分类研究。利用三维荧光光谱技术结合平行因子分析算法和模式识别方法快速、有效地检测油类污染物,为石油类污染物的快速检测提供了一种新的研究思路和重要参考。 展开更多
关键词 光谱学 石油类污染物 三维荧光光谱 平行因子分析 模式识别
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基于三维荧光光谱技术结合交替加权残差约束四线性分解的不同盐度条件下混合油液检测 被引量:4
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作者 孔德明 董瑞 +1 位作者 崔耀耀 王书涛 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2020年第6期1769-1774,共6页
石油作为一种重要的化石能源,是人类社会生产活动中不可缺少的一部分。石油在被人们开采、使用的过程中不可避免地会发生泄漏,泄漏的石油会给生态环境带来严重的威胁。因此,在石油泄漏后需要及时对其进行处理,而其前提是能够准确识别石... 石油作为一种重要的化石能源,是人类社会生产活动中不可缺少的一部分。石油在被人们开采、使用的过程中不可避免地会发生泄漏,泄漏的石油会给生态环境带来严重的威胁。因此,在石油泄漏后需要及时对其进行处理,而其前提是能够准确识别石油种类。由于石油中多种物质具有荧光特性,因此应用荧光光谱法可对石油进行有效检测。但石油所含组分较多,使得其光谱信息重叠严重,识别困难。而三阶校正方法具有"三阶优势",可以分辨高共线性、高噪声水平下的数据。其中,三阶校正中的交替加权残差约束四线性分解(AWRCQLD)算法具有收敛速度快、对组分数不敏感等优点;因此,利用三维荧光光谱技术结合AWRCQLD算法,对混合油液进行检测。首先,配制3种盐度条件下的十二烷基硫酸钠(SDS)溶剂;并在每种盐度条件下分别将航空煤油和润滑油按照不同浓度比混合,最终得到24个校正样本和9个预测样本。然后,使用FLS920荧光光谱仪对实验样本进行光谱数据采集。其次,使用扣除空白法去除光谱中的散射,并通过核一致诊断法判断混合油中的组分数。最后,用AWRCQLD算法对四维光谱矩阵进行解析。研究结果表明,在0~20盐度范围内,随着盐度的增加,航空煤油的荧光强度先减小后增大,润滑油的荧光强度先增大后减小;混合油解析光谱曲线分别与航空煤油及润滑油的实际光谱曲线重合度良好;经AWRCQLD算法解析后得到的航空煤油的回收率范围为100.2%~109%,均方根误差为0.0021 mg·mL^-1;润滑油的回收率范围为91.8%~109.3%,均方根误差为0.0048 mg·mL^-1。通过引入盐度作为新一维度的数据,从而将三维光谱数据阵扩展到相应的四维光谱数据阵。并利用AWRCQLD算法对四维光谱数据阵进行了解析,实现了在不同盐度条件下对混合油的定性和定量分析。同时,为不同盐度条件下的混合油液检测提供了参考。 展开更多
关键词 三维荧光光谱 AWRCQLD 海水盐度 混合油检测
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