Based on industrial production with an annual capacity of million tons of methanol,ammonia/urea,etc.,a platform technology is developed for direct,green,efficient,and high-value mega-size utilization of the CO2-rich n...Based on industrial production with an annual capacity of million tons of methanol,ammonia/urea,etc.,a platform technology is developed for direct,green,efficient,and high-value mega-size utilization of the CO2-rich nature gas,which is the technology of CO2-rich natural gas dry reforming and hydrogen reaction.The following technologies are discussed,such as CO2-rich natural gas dry reforming integrated with the Fischer-Tropsch synthesis to olefins(FTO)technology for producing high value-added linear alpha olefins(LAO);CO2-rich natural gas dry reforming integrated with low carbon olefin linear hydroformylation technology to produce higher carbon alcohols;direct methanol production from CO2 and hydrogen;and the new cutting edge technology of photo-catalytic process.In addition,simple techno-economic evaluations of two technologies mentioned above are discussed.The CO2-rich natural gas dry reforming integrated with FTO technology can achieve about 30%of internal rate return(IRR),while the low carbon olefin linear hydroformylation technology could have a static payback period of 2.57 years when the capacity of 2-propylhexanol(2-PH)reaches 100 kt/a.Based on the mega-size green and high-efficient CO2-rich natural gas direct utilization technology,a hybrid energy and chemical production system framework with good prospects is preliminarily designed.A modern industry zone with an annual capacity of more than 10 Mt of CO2 converted to high value-added products is underway.展开更多
Municipal sludge is produced in large amounts and is difficult to treat.Incineration is the most direct and thorough treatment method.In order to study the feasibility of sintering for municipal sludge treatment,the m...Municipal sludge is produced in large amounts and is difficult to treat.Incineration is the most direct and thorough treatment method.In order to study the feasibility of sintering for municipal sludge treatment,the municipal sludge reforming process was studied under high-temperature oxidation conditions.The results showed that the sludge reforming process could be divided into four stages:the precipitation and evaporation of adsorbed water,the precipitation and combustion of the volatile,the combustion of the residual volatile and solid carbon,and the decomposition of salts and the melting of sludge.An increase in the heating rate resulted in more intense sludge combustion and improved the sludge reaction capacity and combustion performance.After burning at 1300℃,Si,Ca,Mg,Al,K,Na,and Cu formed new phases and entered the slag.75%of P remained in the slag.80%of the S formed SO_(2) and entered the flue gas.Cl formed gaseous chlorides like HCl upon combustion and entered the flue gas.As sintering is a feasible method for treating municipal sludge,care must be taken to limit the amount of P that ends up in the ore.展开更多
文摘Based on industrial production with an annual capacity of million tons of methanol,ammonia/urea,etc.,a platform technology is developed for direct,green,efficient,and high-value mega-size utilization of the CO2-rich nature gas,which is the technology of CO2-rich natural gas dry reforming and hydrogen reaction.The following technologies are discussed,such as CO2-rich natural gas dry reforming integrated with the Fischer-Tropsch synthesis to olefins(FTO)technology for producing high value-added linear alpha olefins(LAO);CO2-rich natural gas dry reforming integrated with low carbon olefin linear hydroformylation technology to produce higher carbon alcohols;direct methanol production from CO2 and hydrogen;and the new cutting edge technology of photo-catalytic process.In addition,simple techno-economic evaluations of two technologies mentioned above are discussed.The CO2-rich natural gas dry reforming integrated with FTO technology can achieve about 30%of internal rate return(IRR),while the low carbon olefin linear hydroformylation technology could have a static payback period of 2.57 years when the capacity of 2-propylhexanol(2-PH)reaches 100 kt/a.Based on the mega-size green and high-efficient CO2-rich natural gas direct utilization technology,a hybrid energy and chemical production system framework with good prospects is preliminarily designed.A modern industry zone with an annual capacity of more than 10 Mt of CO2 converted to high value-added products is underway.
基金This work was supported by Ministry of Science and Technology of the People’s Republic of China(2019YFC1904600).
文摘Municipal sludge is produced in large amounts and is difficult to treat.Incineration is the most direct and thorough treatment method.In order to study the feasibility of sintering for municipal sludge treatment,the municipal sludge reforming process was studied under high-temperature oxidation conditions.The results showed that the sludge reforming process could be divided into four stages:the precipitation and evaporation of adsorbed water,the precipitation and combustion of the volatile,the combustion of the residual volatile and solid carbon,and the decomposition of salts and the melting of sludge.An increase in the heating rate resulted in more intense sludge combustion and improved the sludge reaction capacity and combustion performance.After burning at 1300℃,Si,Ca,Mg,Al,K,Na,and Cu formed new phases and entered the slag.75%of P remained in the slag.80%of the S formed SO_(2) and entered the flue gas.Cl formed gaseous chlorides like HCl upon combustion and entered the flue gas.As sintering is a feasible method for treating municipal sludge,care must be taken to limit the amount of P that ends up in the ore.
