In-situ high pressure Raman spectra and electrical conductivity measurements of scheelite-structure compound PbMoO4 are presented. The Raman spectrum of PbMoO4 is determined up to 26.5 GPa on a powdered sample in a di...In-situ high pressure Raman spectra and electrical conductivity measurements of scheelite-structure compound PbMoO4 are presented. The Raman spectrum of PbMoO4 is determined up to 26.5 GPa on a powdered sample in a diamond anvil cell （DAC） under nonhydrostatic conditions. The PbMoO4 gradully experiences the trans- formation from the crystal to amorphous between 9.2 and 12.5 GPa. The crystal to amorphous transition may be due to the mechanical deformation and the crystalographic transformation. Furthermore, the electrical conductivity of PbMoO4 is in situ measured accurately using a microcircuit fabricated on a DAC based on the van der Pauw method. The results show that the electrical conductivity of PbMoO4 increases with increases of pressure and temperature. At 26.5 GPa, the electrical conductivity value of PbMoO4 at 295K is 1.93 - 10-4 S/cm, while it raises by one order of magnitude at 430K and reached 3.33 - 10-3 S/cm. However, at 430K, compared with the electrical conductivity value of PbMoO4 at 26.5 GPa, it drops by about two order magnitude at 7.4 GPa and achieves 2.81 × 10^-5 S/cm. This indicates that the effect of pressure on the electrical conductivity of PbMoO4 is more obvious than that of temperature.展开更多
This article manages Darcy-Forchheimer 3D flow of water based carbon nanomaterial(CNTs).A bidirectional nonlinear stretchable surface has been utilized to make the flow.Disturbance in permeable space has been represen...This article manages Darcy-Forchheimer 3D flow of water based carbon nanomaterial(CNTs).A bidirectional nonlinear stretchable surface has been utilized to make the flow.Disturbance in permeable space has been represented by Darcy Forchheimer(DF)expression.Heat transfer mechanism is explored through convective heating.Outcomes for SWCNT and MWCNT have been displayed and compared.The reduction of partial differential framework into nonlinear common differential framework is made through reasonable variables.Optimal series scheme is utilized for arrangements advancement of associated flow issue.Optimal homotopic solution expressions for velocities and temperature are studied through graphs by considering various estimations of physical variables.Moreover surface drag coefficients and heat transfer rate are analyzed through plots.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos 40473034, 40404007, 10574055 and 50532020, and the National Basic Research Programme of China under Grant No 2005CB724404.
文摘In-situ high pressure Raman spectra and electrical conductivity measurements of scheelite-structure compound PbMoO4 are presented. The Raman spectrum of PbMoO4 is determined up to 26.5 GPa on a powdered sample in a diamond anvil cell （DAC） under nonhydrostatic conditions. The PbMoO4 gradully experiences the trans- formation from the crystal to amorphous between 9.2 and 12.5 GPa. The crystal to amorphous transition may be due to the mechanical deformation and the crystalographic transformation. Furthermore, the electrical conductivity of PbMoO4 is in situ measured accurately using a microcircuit fabricated on a DAC based on the van der Pauw method. The results show that the electrical conductivity of PbMoO4 increases with increases of pressure and temperature. At 26.5 GPa, the electrical conductivity value of PbMoO4 at 295K is 1.93 - 10-4 S/cm, while it raises by one order of magnitude at 430K and reached 3.33 - 10-3 S/cm. However, at 430K, compared with the electrical conductivity value of PbMoO4 at 26.5 GPa, it drops by about two order magnitude at 7.4 GPa and achieves 2.81 × 10^-5 S/cm. This indicates that the effect of pressure on the electrical conductivity of PbMoO4 is more obvious than that of temperature.
文摘This article manages Darcy-Forchheimer 3D flow of water based carbon nanomaterial(CNTs).A bidirectional nonlinear stretchable surface has been utilized to make the flow.Disturbance in permeable space has been represented by Darcy Forchheimer(DF)expression.Heat transfer mechanism is explored through convective heating.Outcomes for SWCNT and MWCNT have been displayed and compared.The reduction of partial differential framework into nonlinear common differential framework is made through reasonable variables.Optimal series scheme is utilized for arrangements advancement of associated flow issue.Optimal homotopic solution expressions for velocities and temperature are studied through graphs by considering various estimations of physical variables.Moreover surface drag coefficients and heat transfer rate are analyzed through plots.
