In this study, sixteen soil and vegetable samples from Tafila district were collected and analyzed from eight locations. Measurements of specific activity of natural gamma emitter radionuclides, 23SU and 235U, in thes...In this study, sixteen soil and vegetable samples from Tafila district were collected and analyzed from eight locations. Measurements of specific activity of natural gamma emitter radionuclides, 23SU and 235U, in these samples using gamma spectrometry, with the help of Genie 2000 software. Measurements were used to calculate the soil-vegetable transfer factor, and then the external radiation dose and internal radiation dose due to radioactivity of the ingested food. The specific activity of238U and 235U in soil were found to vary from （in Bq/kg）： 26-575 and 1.4-35.5, respectively. The specific activity of 238U and 235U in vegetables were found to vary from （in Bq/kg）： 0.019 to 0.632 and 0.0013-0.0375, respectively. The calculated transfer factor of Z3SU and Z35U range from 5.9 × 10^-4to 14.6 × 10^-4 for 238U and 4.9 × 10^-4 to 16.1 × 10^-4 for 235U. External absorbed dose rates were calculated to be in the range from 12.42 to 266.00 nGy/h. The annual effective dose was found to vary from 28.94 to 619.78 μSv/y. The annual internal effective dose due to 23SU and 23SU for fresh weights ofvegetablesl were found to vary from 0.9 × 10^-3 to 35.1 × 10^-3 μSv/y for 238U and 0.61 × 10^-4 to 17.62 × 10^-4 μSv/y for 235U.展开更多
Many cases of toxicity and mortality either due to accidental or deliberate ingestion of hair dyes were reported in Egypt, Sudan, Israel, Morocco, Saudi Arabia, India and Tunisia. In the field of forensic analytical t...Many cases of toxicity and mortality either due to accidental or deliberate ingestion of hair dyes were reported in Egypt, Sudan, Israel, Morocco, Saudi Arabia, India and Tunisia. In the field of forensic analytical toxicology, the identification and quantification of chemicals are essential in deaths related to intoxication. The aim of the present study is to conduct chemico-analytical characterization of para-phenylenediamine (PPD) based hair dye of (Black stone hair dye, SHD) currently used for dying hear in Egypt, to confirm the identification of its components, that may be potentially toxic on oral or dermal exposure, this study uses comparison between different analytical methods. The applied analytical methods were inductively coupled plasma/MS (ICP/MS), witch used to determine the metal components of the dye, high performance liquid chromatography/MS (HPLC/MS) and gas chromatography/mass spectroscopy (GC/MS) were used for qualitative and quantitative analysis of PPD in the dye. A derivatization method was applied by transforming PPD (aromatic amines) into corresponding imine derivatives. This compound was prepared by condensation of 4-methylbenzeneamine with benzaldehyed to give N-benzylidene-4-methylbenzene-amine, which is a very stable internal standard. ICP/MS analysis revealed that most metal components of hair dye are Be, Na, Al, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Cu, and Zr, where HPLC/MS analysis revealed that PPD is the main ingredient of SHD. Derivatization is necessary for accurate determination of PPD in hair dye by GC/MS method and this results could not be obtained by direct injection of dye (without derivatization).展开更多
文摘In this study, sixteen soil and vegetable samples from Tafila district were collected and analyzed from eight locations. Measurements of specific activity of natural gamma emitter radionuclides, 23SU and 235U, in these samples using gamma spectrometry, with the help of Genie 2000 software. Measurements were used to calculate the soil-vegetable transfer factor, and then the external radiation dose and internal radiation dose due to radioactivity of the ingested food. The specific activity of238U and 235U in soil were found to vary from （in Bq/kg）： 26-575 and 1.4-35.5, respectively. The specific activity of 238U and 235U in vegetables were found to vary from （in Bq/kg）： 0.019 to 0.632 and 0.0013-0.0375, respectively. The calculated transfer factor of Z3SU and Z35U range from 5.9 × 10^-4to 14.6 × 10^-4 for 238U and 4.9 × 10^-4 to 16.1 × 10^-4 for 235U. External absorbed dose rates were calculated to be in the range from 12.42 to 266.00 nGy/h. The annual effective dose was found to vary from 28.94 to 619.78 μSv/y. The annual internal effective dose due to 23SU and 23SU for fresh weights ofvegetablesl were found to vary from 0.9 × 10^-3 to 35.1 × 10^-3 μSv/y for 238U and 0.61 × 10^-4 to 17.62 × 10^-4 μSv/y for 235U.
文摘Many cases of toxicity and mortality either due to accidental or deliberate ingestion of hair dyes were reported in Egypt, Sudan, Israel, Morocco, Saudi Arabia, India and Tunisia. In the field of forensic analytical toxicology, the identification and quantification of chemicals are essential in deaths related to intoxication. The aim of the present study is to conduct chemico-analytical characterization of para-phenylenediamine (PPD) based hair dye of (Black stone hair dye, SHD) currently used for dying hear in Egypt, to confirm the identification of its components, that may be potentially toxic on oral or dermal exposure, this study uses comparison between different analytical methods. The applied analytical methods were inductively coupled plasma/MS (ICP/MS), witch used to determine the metal components of the dye, high performance liquid chromatography/MS (HPLC/MS) and gas chromatography/mass spectroscopy (GC/MS) were used for qualitative and quantitative analysis of PPD in the dye. A derivatization method was applied by transforming PPD (aromatic amines) into corresponding imine derivatives. This compound was prepared by condensation of 4-methylbenzeneamine with benzaldehyed to give N-benzylidene-4-methylbenzene-amine, which is a very stable internal standard. ICP/MS analysis revealed that most metal components of hair dye are Be, Na, Al, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Cu, and Zr, where HPLC/MS analysis revealed that PPD is the main ingredient of SHD. Derivatization is necessary for accurate determination of PPD in hair dye by GC/MS method and this results could not be obtained by direct injection of dye (without derivatization).
