Mining activities are often associated with significant environmental degradation,particularly due to the accumulation of mine tailings(MTs).These waste materials are frequently stored in dams or open ponds without ad...Mining activities are often associated with significant environmental degradation,particularly due to the accumulation of mine tailings(MTs).These waste materials are frequently stored in dams or open ponds without adequate treatment,posing serious risk of heavy metals(HMs)contamination to surrounding ecosystems.Given these challenges,restoration of MTs to mitigate their negative impacts has become highly important.This study attempts to compile different types of MTs,their characteristics,and associated issues such as acid mine drainage(AMD)and HMs contamination,along with other environmental impacts.It also explores the fundamentals of phytoremediation,highlighting key processes,recent advancements,benefits,limitations,and strategies for post-harvest management.The findings indicate that MTs are a major source of HM pollution and contribute significantly to environmental deterioration.Phytoremediation has emerged as a promising,cost-effective,and eco-friendly solution for MT restoration.In addition to mitigating contamination,phytoremediation enhances soil quality,prevents erosion,reduces HM leaching into groundwater,and improves the visual appeal of degraded sites.Research suggests that revegetating MT-contaminated soils with specific plant species can effectively remediate these areas,reducing HM leaching risks while improving soil properties.This review serves as a valuable resource for researchers working on MT restoration,offering insights into the latest advancements in phytoremediation technology and its potential to address the environmental challenges posed by MTs.展开更多
In the past decades, two large scale coastal engineering projects have been carried out in the Deep Bay surrounded by Shenzhen City and Hong Kong Special Administrative Region. One project is Shenzhen River channel re...In the past decades, two large scale coastal engineering projects have been carried out in the Deep Bay surrounded by Shenzhen City and Hong Kong Special Administrative Region. One project is Shenzhen River channel regulation and the other is the sea reclamation along the seashore on the Shenzhen side. The two projects are very close to the two national nature reserves, specifically Futian in Shenzhen and Mai Po in Hong Kong, which are important wetland ecosystems worldwide. This paper aims to identify and monitor the mangrove wetland changes with time series of Landsat Thematic Mapper images pre and post to the two engineering projects being launched. Coupled analysis of the image interpretation results and tidal data acquired at the same time in the context of the two works reveals that the mangrove wetland area has increased from year 1989 to 1994, and has changed little from year 1994 to 2002. Binary coding is applied to reveal the distribution image of mangrove at each phase, and the coding image shows that the construction of the two coastal engineering projects has caused frequent changes in mangrove spatial distribution. The study also shows that the change is not significant regarding to the precision of the method and the natural evolution of mangrove wetland, and the projects do not cause apparently influences upon the two national mangrove conservation zones at least for the research time period.展开更多
This work describes the development,optimisation and validation of an analytical method for the rapid determination of 17 priority pharmaceutical compounds and endocrine disrupting chemicals(EDCs).Rather than studying...This work describes the development,optimisation and validation of an analytical method for the rapid determination of 17 priority pharmaceutical compounds and endocrine disrupting chemicals(EDCs).Rather than studying compounds from the same therapeutic class,the analyses aimed to determine target compounds with the highest risk potential(with particular regard to Scotland),providing a tool for further monitoring in different water matrices.Prioritisation was based on a systematic environmental risk assessment approach,using consumption data;wastewater treatment removal efficiency;environmental occurrence;toxicological effects;and pre-existing regulatory indicators.This process highlighted 17 compounds across various therapeutic classes,which were then quantified,at environmentally relevant concentrations,by a single analytical methodology.Analytical determination was achieved using a single-step solid phase extraction(SPE)procedure followed by high-performance liquid chromatography with tandem mass spectrometry(HPLC-MS/MS).The fully optimised method performed well for the majority of target compounds,with recoveries>71%for 15 of 17 analytes.The limits of quantification for most target analytes(14 of 17)ranged from 0.07 ng/L to 1.88 ng/L in river waters.The utility of this method was then demonstrated using real water samples associated with a rural hospital/setting.Eight compounds were targeted and detected,with the highest levels found for the analgesic,paracetamol(at up to 105,910 ng/L in the hospital discharge).This method offers a robust tool to monitor high priority pharmaceutical and EDC levels in various aqueous sample matrices.展开更多
Semiconductor photocatalytic technology has shown great prospects in converting solar energy into chemical energy to mitigate energy crisis and solve environmental pollution problems.The key issue is the development o...Semiconductor photocatalytic technology has shown great prospects in converting solar energy into chemical energy to mitigate energy crisis and solve environmental pollution problems.The key issue is the development of high-efficiency photocatalysts.Various strategies in the state-of-the-art advancements,such as heterostructure construction,heteroatom doping,metal/single atom loading,and defect engineering,have been presented for the graphitic carbon nitride(g-C3N4)-based nanocomposite catalysts to design their surface chemical environments and internal electronic structures to make them more suitable for different photocatalytic applications.In this review,nanoarchitecture design,synthesis methods,photochemical properties,potential photocatalytic applications,and related reaction mechanisms of the modified high-efficiency carbon nitride-based photocatalysts were briefly summarized.The superior photocatalytic performance was identified to be associated with the enhanced visible-light response,fast photoinduced electron-hole separation,efficient charge migration,and increased unsaturated active sites.Moreover,the further advance of the visible-light harvesting and solar-to-energy conversions are proposed.展开更多
Due to high demand and limited availability of rare earth elements (REEs), Europe is unable to meet its industrial needs, especially High Tech needs, today for the manufacturing sector. Therefore, the EU has included ...Due to high demand and limited availability of rare earth elements (REEs), Europe is unable to meet its industrial needs, especially High Tech needs, today for the manufacturing sector. Therefore, the EU has included them in the group of 14 critical minerals. China currently controls completely the mining activity, the enrichment technologies and metallurgy, and end-metal products of rare earths, resulting both Europe and the U.S.A. in full industrial dependency. The exploitation and wide use of REEs in fertilizers have led to accumulation of these elements in soils, resulting in an agriculture field pollution, which affects directly the soil microfauna with a toxic potential effect.展开更多
A hydrocarbon degrading bacterium KL2-13 was isolated from ten sites of oil contaminated soil in the Karamay oilfield. It was identified as the Bacillusfusiformis sp. bacterium based on its morphological and physiolog...A hydrocarbon degrading bacterium KL2-13 was isolated from ten sites of oil contaminated soil in the Karamay oilfield. It was identified as the Bacillusfusiformis sp. bacterium based on its morphological and physiological characteristics and the 16S rDNA sequence analysis. The factors influencing the hydrocarbon degradation by the bacterium KL2-13 were determined. The test results have showed that the hydrocarbon degrading bacterium KL2-13 requires an optimum pH range of 6-8, and the optimum inoculation quantity is 3%. The low-concentration metal ions Fe^2+, Mg^2+ and Ca^2+can improve the degradation ability of the bacteria KL2-13. A too low concentration of Tween-80 does not show obvious promotion to the degrading bacterium KL2-13, and an excessively high concentration can decrease the degradation ability of the bacterium, the best dosage of which is 2%. The hydrocarbon degrading rate reached 59.07%4-0.37% under the optimum culture conditions.展开更多
Lignocellulosic biomass is an abundant and environment-friendly source for renewable energy production.The value and application of biochar,which is obtained from the thermochemical conversion of biomass,is increasing...Lignocellulosic biomass is an abundant and environment-friendly source for renewable energy production.The value and application of biochar,which is obtained from the thermochemical conversion of biomass,is increasing rapidly because of its high carbon content and porosity.The property of biochar,such as surface area,porosity,and number of functional groups,can be improved by controlling the conditions of biomass conversion,biochar activation,and functionalization methods.The production and activation of biochar as well as its potential use for soil remediation,pollutant adsorption,and biorefinery have been reviewed extensively over recent decades.This paper provides a conceptual approach for biochar production and activation together with its application as a catalyst for biorefineries and the removal of environmental contaminants.展开更多
Ti3 AL-Nb-Mo composites were prepared by SHS using initial powder mixtures of Ti-Al-Nb-Mo and their corrosion and mechanical properties were studied to develop bioand environmental materials. The composites reached 99...Ti3 AL-Nb-Mo composites were prepared by SHS using initial powder mixtures of Ti-Al-Nb-Mo and their corrosion and mechanical properties were studied to develop bioand environmental materials. The composites reached 99.8% of theoretical density after the direct consolidation. The composites shows equiaxed primary a2 in a matrix of fine secondary a2 plates and ordered 82 (Bo) forming a basket weave structure. The strain rate sensitivity (m = dlnσ/dlne) at 2% strain is 0.008. Corrosion potential and corrosion rate of the composites formed by SHS were -151. 5m VSHE and 5. 72× 10^(-8)A/cm2 for Ti3 Al-10Nb-1. 5Mo and - 138.4m VSHE and 4. 12×10^(-8)cm2 for Ti3 Al-12Nb-1.5Mo in a 50% NaOH-10%FeCI3 solution, respectively. Corrosion resistance decreased with niobium content in the composites and chloride content in the aqueous solution. Selective corrosion of a2 phase in a matrix occurred in the corrosion environment which suggests that the corrosion potential and rate changes are related to the niobium content and Q2 phase in a matrix.展开更多
The increased use of scarce metals in combination with climate changes pave way for extensive extraction of mineral resources in Greenland. The focus of this study is on environmental ethical aspects of mining activit...The increased use of scarce metals in combination with climate changes pave way for extensive extraction of mineral resources in Greenland. The focus of this study is on environmental ethical aspects of mining activities in a vulnerable and unspoiled arctic nature. Mining can have several economic and social benefits for Greenland. On the other hand, the environmental impacts from mining are well known. Through DPSIR (Drivers, Pressures, States, Impacts, Responses) and Stakeholder analysis, we assess how future mining in Greenland can be sustainably implemented. The analysis revealed that numerous stakeholders have to be taken into consideration with a wide range of different interests. The DPSIR analysis clarified the availability of various potential political responses that could affect the drivers, pressures, states and impacts of mining mainly focused on implementation of effective environmental regulation strategies. Our findings revealed different environmental ethical dilemmas of which the most critical is how Greenland can open up for mining, gain economical revenue while averting destruction of unspoiled regions and aesthetic impairment. We recommend strict environmental legislation involving use of the "polluter pay principle", continuous monitoring of pollution and establishment of an industry-funded catastrophe trust fund. These initiatives can ensure economic benefits while environmental impacts remain negligible.展开更多
The main purpose of this study was to determine the changes in the water quality of Melendiz and Karasu streams, which recharge the Mamasin dam, and to evaluate its environmental impacts on the dam site that provides ...The main purpose of this study was to determine the changes in the water quality of Melendiz and Karasu streams, which recharge the Mamasin dam, and to evaluate its environmental impacts on the dam site that provides drinking water and irrigation demand in Aksaray city in the Central Anatolia of Turkey. The field researches were focused on estimating the main sources of contamination, determining and evaluating the changes in the water quality due to the direct wastewater discharges into the Melendiz and Karasu rivers, which recharge the Mamasin dam sites. During the study, water samples were collected from Melendiz and Karasu stream and Mamasin dam, and then, the physical and chemical analyses of water samples were conducted. The relevant in-situ and laboratory analyses were carried out during the dry and wet seasons. The results of the analyses showed that in term of the surface water quality criteria in terms of NO3-N value of both rivers and dam waters, the water quality is always considered as the 1st class in Melendiz stream, the 2nd class in Karasu stream and the 3rd class in Mamasin dam lake. Whereas, in terms of NO4-N values of both rivers and dam waters, the water quality is always considered as the 1st class in Melendiz stream, the 2nd-3rd class in Karasu stream. The total organic carbon (TOC) range for Karasu river is usually from 20 mg/L to 40 mg/L. The high value of organic matter in the Karasu stream can be explained by the availability of intensive green wetlands around this water resource. Finally, the Ministry of Forest and Water Authority give some suggestions for estimating protection zones of Melendiz stream and Mamasin basin's area, such as using the results of environmental tracers to investigate the agricultural contamination, including more sophisticated applications of multiple-tracer analyses to evaluate the travel time of contaminants and estimate the boundary of protection zones.展开更多
Nitrogen oxides (NO<sub>x</sub>) in urban air close to ground have significant health implications. Restrictions in traffic, mandatory use of catalytic converters on vehicles, and novel photocatalytic coat...Nitrogen oxides (NO<sub>x</sub>) in urban air close to ground have significant health implications. Restrictions in traffic, mandatory use of catalytic converters on vehicles, and novel photocatalytic coatings on surfaces contribute to reducing the level of NO<sub>x</sub> in cities. The aim of this study is to establish environmental profiles of NO<sub>x</sub> removal by a Three-Way Catalyst (TWC) car converter and by a photocatalytic surface coating (for asphalt and concrete pavements) for fostering technological development in reducing the levels of NO<sub>x</sub> in urban air. We assessed the environmental performance for the removal of 1 kg NO<sub>x</sub> by the two technologies with Life Cycle Assessment (LCA;EF.3 impact assessment method). In order to do so, we established Life-Cycle-Inventory (LCI) data representing production, operation and end-of-life of the two technologies based on data from literature and industry. The production of photocatalytic surface coatings, used on concrete and asphalt, has environmental loads two orders of magnitude lower than the environmental benefits of NO<sub>x</sub> reduction expressed as a reduction in Photochemical Ozone Formation (POF), Acidification (A), and Terrestrial Eutrophication (TE). The vehicle catalytic converter shows similar results except that the use of rare earth elements in the production constitutes a significant load to Freshwater Ecotoxicity (FET) and that additional use of fuel during operation induces a modest Climate Change (CC) impact. For both technologies, the environmental benefits of reducing NO<sub>x</sub> far exceed any adverse environmental aspects of the production of the technologies.展开更多
The waters renewal of the fishery harbor of Nea Krini is presented here. The harbor is located at the east Thessaloniki Gulf (NE Thermaikos Gulf, Greece). The main research point is focused on the environmental state ...The waters renewal of the fishery harbor of Nea Krini is presented here. The harbor is located at the east Thessaloniki Gulf (NE Thermaikos Gulf, Greece). The main research point is focused on the environmental state of the harbor which is under construction. Under that point of view, the description of a two-dimensional, depth average, hydrodynamic model follows, in order to simulate the wind generated circulation of waters, initially on the greater area of Thermaikos Gulf and then on the coastal basin of the fishing harbor. The renewal of waters in the harbor’s basin is subsequently studied. Tidal effects on the waters’ renewal are also studied. The calculation of the concentration of Biochemically Oxygen Demand (BOD) in the fishing harbor for the average time of waters’ renewal is then examined for three different cases, concerning the existence and operation of openings on the body of the groins. Finally, the analysis of the results shows a good environmental state of the harbor. It is obvious that the use of numerical models for different scenarios of engineering and design approaches can lead to the prognosis of hydrodynamic and environmental sate of a harbor’s basin so that the best possible technical design can be adopted.展开更多
Seawater desalination stands as an increasingly indispensable solution to address global water scarcity issues.This study conducts a thorough exergoenvironmental analysis of a multi-effect distillation with thermal va...Seawater desalination stands as an increasingly indispensable solution to address global water scarcity issues.This study conducts a thorough exergoenvironmental analysis of a multi-effect distillation with thermal vapor compression(MED-TVC)system,a highly promising desalination technology.The MED-TVC system presents an energy-efficient approach to desalination by harnessing waste heat sources and incorporating thermal vapor compression.The primary objective of this research is to assess the system’s thermodynamic efficiency and environmental impact,considering both energy and exergy aspects.The investigation delves into the intricacies of energy and exergy losses within the MED-TVC process,providing a holistic understanding of its performance.By scrutinizing the distribution and sources of exergy destruction,the study identifies specific areas for enhancement in the system’s design and operation,thereby elevating its overall sustainability.Moreover,the exergoenvironmental analysis quantifies the environmental impact,offering vital insights into the sustainability of seawater desalination technologies.The results underscore the significance of every component in the MED-TVC system for its exergoenvironmental performance.Notably,the thermal vapor compressor emerges as pivotal due to its direct impact on energy efficiency,exergy losses,and the environmental footprint of the process.Consequently,optimizing this particular component becomes imperative for achieving a more sustainable and efficient desalination system.展开更多
The contribution of the use of RE(Renewable Energy)sources in general and wind source in particular in the Albanian electricity sector is very important to strengthen national energy security,diversify energy sources ...The contribution of the use of RE(Renewable Energy)sources in general and wind source in particular in the Albanian electricity sector is very important to strengthen national energy security,diversify energy sources and reduce dependence on imports.It also directly affects economic growth,employment and reduces the release of pollutants into the atmosphere,which are contributing to global warming and the greenhouse effect.The purpose of this paper is to assess the theoretical,technical and economic potential of the wind source in the Synej Area,Kavaja Municipality for electricity production in the absence of field measurements.Calculations of all technical,economic and environmental parameters are performed through the RETScreen Expert program.This analysis is sufficient for pre-implementation studies that do not require very detailed calculations and at the same time facilitates decision-making on project implementation.The study area has considerable technical potential for the use of wind energy.In this area,the analyzed project envisages the installation of 7 turbines of the Vesta 110 type,each with a power of 2 MW.The height of the turbines is 85 m.The total amount of electricity produced by this plant is estimated at 24 GWh/year,at a cost of 0.06€/kWh.The total emission reduction for all proposed projects is 477,500 tCO_(2) per year.The project has a positive net present value and a benefit-cost ratio greater than 1.The payback time is 8 years.展开更多
In the United Republic of Tanzania (URT), all environmental issues related to the mining industry are regulated according to two principle Acts: The Mining Act and the Environmental Management Act, and their respectiv...In the United Republic of Tanzania (URT), all environmental issues related to the mining industry are regulated according to two principle Acts: The Mining Act and the Environmental Management Act, and their respective regulations. The current acts were enacted in 2010 and 2004 respectively. Mineral exploration (that includes all on-site activities performed before a mining project is declared feasible) projects in URT appears to be “unforgotten phenomena” in the two major legislative documents, when it comes to environmental considerations. This phenomenon is believed to be causing detrimental effects to the environment. This paper, therefore, analyzes the current environmental regulatory framework on mineral exploration projects in URT and discusses few examples in which mineral exploration projects have caused damage to the indigenous environment. Furthermore, this study reviews environmental regulatory frameworks from other few countries in comparison with existing environmental regulatory framework prevailing in URT.展开更多
This research aims to study the bio-adsorption process of two dyes,Cibacron Green H3G(CG-H3G)and Terasil Red(TR),in a single system and to bring them closer to the industrial textile discharge by a binary mixture of t...This research aims to study the bio-adsorption process of two dyes,Cibacron Green H3G(CG-H3G)and Terasil Red(TR),in a single system and to bring them closer to the industrial textile discharge by a binary mixture of two dyes(TR+CG-H3G).The Cockle Shell(CS)was used as a natural bio-adsorbent.The characterizations of CS were investigated by Fourier transform infrared(FTIR),X-ray diffraction(XRD),scanning electron microscopy(SEM),energy-dispersive X-ray spectroscopy(EDX)and Brunauer–Emmett–Teller(BET).The adsorption potential of Cockle Shells was tested in two cases(single and binary system)and determined by:contact time(0–60 min),bio-adsorption dose(3–15 g/L),initial concentration(10–300 mg/L),temperature(22–61°C)and pH solution(2–12).The study of bio-adsorption(equilibrium and kinetics)was conducted at 22°C.The kinetic studies demon-strated that a pseudo-second-order adsorption mechanism had a good correlation coefficient(R2≥0.999).The Langmuir isotherm modeling provided a well-defined description of TR and CG-H3G bio-adsorption on cockle shells,exhibiting maximum capacities of 29.41 and 3.69 mg/g respectively at 22°C.The thermodynamic study shows that the reaction between the TR,CG-H3G dyes molecules and the bio-adsorbent is exothermic,spontaneous in the range of 22–31°C with the aleatory character decrease at the solid-liquid interface.The study of selectivity in single and binary systems has been performed under optimal operating conditions using the industrial textile rejection pH(pH=6.04).CG-H3G dye is found to have a higher selectivity than TR in single(0–60 min)and binary systems with a range of 6–45 min,as shown by the selectivity measurement.It was discovered that CS has the capability to remove both CG-H3G and TR dyes in both simple and binary systems,making it a superior bio-adsorbent.展开更多
Water often presents significant challenges in catalysts by deactivating active sites,poisoning the reaction,and even degrading composite structure.These challenges are amplified when the water participates as a react...Water often presents significant challenges in catalysts by deactivating active sites,poisoning the reaction,and even degrading composite structure.These challenges are amplified when the water participates as a reactant and is fed as a liquid phase,such as trickle bed-type reactors in a hydrogen-water isotope exchange(HIE)reaction.The key balance in such multiphase reactions is the precise control of catalyst design to repel bulk liquid water while diffusing water vapor.Herein,a platinum-incorporated metal-organic framework(MIL-101)based bifunctional hydrophobic catalyst functionalized with long alkyl chains(C_(12),dodecylamine)and further manufactured with poly(vinylidene fluoride),Pt@MIL-101-12/PVDF,has been developed which can show dramatically improved catalytic activity under multi-phase reactions involving hydrogen gas and liquid water.Pt@MIL-101-12/PVDF demonstrates enhanced macroscopic water-blocking properties,with a notable reduction of over 65%in water adsorption capacity and newly introduced liquid water repellency.while exhibiting a negligible increase in mass transfer resistance,i.e.,bifunctional hydrophobicity.Excellent catalytic activity,evaluated via HIE reaction,and its durability underscore the impact of bifunctional hydrophobicity.In situ DRIFTS analysis elucidates water adsorption/desorption dynamics within the catalyst composite,highlighting reinforced water diffusion at the microscopic level,affirming the catalyst's bifunctionality in different length scales.With demonstrated radiation resistance,Pt@MIL-101-12/PVDF emerges as a promising candidate for isotope exchange reactions.展开更多
Reports and claims have been made reflecting opinions of the environmental impacts of the Whein Town Landfill Facility on the residents of the Whein Town Community. This study seeks to examine the environmental effect...Reports and claims have been made reflecting opinions of the environmental impacts of the Whein Town Landfill Facility on the residents of the Whein Town Community. This study seeks to examine the environmental effects of the Whein Town Landfill on nearby residents, and the effectiveness of the existing mitigation schemes. This cross-sectional study used 4-point-Likert and 2-point-dichotomous scales questionnaires to collect information from 352 Whein Town community household heads. The findings reveal that “odorous emissions” represent the most critical environmental challenge, severely impacting residents’ well-being and quality of life. By contrast, “garbage spillage along routes” has a minimal impact on residents’ lives, with many residents rating it as “Not Serious”. Six out of eight mitigation implemented schemes achieved a success rate below 25%, one performed at approximately 50%, and only one scheme—the landfill fencing—was effectively implemented, reaching a near-perfect success rate of 99.99%. Therefore, residents of Whein Town are experiencing adverse environmental effects that can be remediated with proper planning and the implementation of existing schemes.展开更多
This study focused on realizing Sustainable Development Goal(SDG)6 for inclusive clean water and sanitation;in particular Target 6.3,which aims to reduce untreated wastewater by 2030 while promoting circular wastewate...This study focused on realizing Sustainable Development Goal(SDG)6 for inclusive clean water and sanitation;in particular Target 6.3,which aims to reduce untreated wastewater by 2030 while promoting circular wastewater reuse and recycling globally.The main objective was to assess the adequacy and efficiency of communal septic tank systems in informal settlements while helping local planners and authorities in their decision-making regarding Target 6.3.Quantitative and qualitative approaches were employed with secondary data from previous researchers,and primary data were collected from field surveys,observations,and interviews with members of the local community.The research was delimited to two village administrative divisions known as Rukun Warga(Village Administrative Division,RW):RW 7 and RW 8 of Lebak Siliwangi Kampung in Coblong District,Bandung,West Java,Indonesia.The findings were also compared with situations in other informal settlements in Brazil,Bangladesh,and Nairobi.The results indicated the inadequacy of communal septic tanks in informal settlements due to factors such as substandard system design,limited support and communication between authorities and residents,and the gap between septic tank availability and capacity vis-a-vis demand.Other limiting factors included limited land availability and irregular geomorphology,the latter of which affected the siting and operation of septic tanks due a lack of room for upgrades or expansion in response to continuous population growth.These findings illustrate the need to complement communal septic systems with flexible centralized or decentralized systems to achieve Target 6.3 of SDG 6.展开更多
Extreme temperature events have intensified across Jordan over the past 40 a,increasing risks to agriculture,water availability,urban infrastructure,and public health.The purpose of this study is to assess the long-te...Extreme temperature events have intensified across Jordan over the past 40 a,increasing risks to agriculture,water availability,urban infrastructure,and public health.The purpose of this study is to assess the long-term spatial trends and regime shifts in extreme temperature indicators across Jordan's climate zones to explore climate adaptation strategies.This study presents a high-resolution and spatially explicit assessment of thermal extremes using daily data from 1982 to 2024 across 45 grid-based study points in Jordan.Thirteen temperature indices,including percentile-based thresholds,duration metrics,and absolute extremes,were computed using RClimDex and analyzed across four Köppen climate zones:hot desert(BWh),hot semi-arid(BSh),cold desert(BWk),and Mediterranean(Csa)climates.The analysis confirmed a statistically significant warming trend:annual mean maximum temperatures increased by 2.198°C,while annual mean minimum temperatures rose by 2.035°C.Cold extremes have sharply declined,with cold days(TX10p)decreasing by 70.0%–80.0%,and the cold spell duration indicator(CSDI)dropping from 12.6 to 4.0 d/a,particularly in the BWk zone.Heat indices intensified across all zones,with warm days(TX90p)increasing by over 300.0%in BWh,warm nights(TN90p)rising by 38.1%,and the warm spell duration indicator(WSDI)extending fourfold,indicating prolonged exposure to heatwaves.Mean value of maximum temperature(TXx)reached 45.600°C in most arid areas,while minimum temperature(TNx)exceeded 31.600°C,highlighting increased nocturnal heat stress.Change-point analysis indicated that 1998 was a pivotal year,marking a structural transition in both cold and warm temperature indices.Subsequent intensifications after 2010 in TN90p,TNx,and mean of daily maximum temperature(Tmaxmean)reflected an ongoing trend toward sustained thermal extremes.In addition to time-series trends,the study employed network-based correlation analysis to explore the coherence among climate indices.Strong positive correlations were observed among TXx,TX90p,and mean of daily minimum temperature(Tminmean)(r≥0.94),as well as among TN90p,Tminmean,and TNx(r≥0.87),indicating a tightly clustered heat subsystem.Duration metrics like the WSDI showed a close alignment with percentile extremes(between WSDI and TX90p;r=0.88),suggesting integrated heatwave behavior.In contrast,cold indices(TX10p,TN90p,frost days,and CSDI)exhibited weak or negative correlations and displayed peripheral positioning in the climate network,indicating their limited role under a warming regime.Absolute extremes showed weak internal linkages,suggesting episodic rather than systemic response characteristics.This structural realignment indicated a shift from a previously balanced thermal profile to a heat-dominated climate system.Regional variations revealed that BWh and BSh were experiencing the steepest warming,while Csa was transitioning more slowly but was showing signs of reduced winter cooling and increased irrigation demands.The findings establish a robust climate baseline for Jordan and offer actionable insights for climate adaptation planning.Recommended measures include precision irrigation,the development of heat-resilient crops,improvements to urban cooling infrastructure,and early warning systems for thermal extremes.By integrating spatial climate zoning,regime shift analysis,and inter-index correlation structures,this study provides a replicable framework for monitoring climatic transformations and informing resilience strategies in arid and semi-arid areas.展开更多
文摘Mining activities are often associated with significant environmental degradation,particularly due to the accumulation of mine tailings(MTs).These waste materials are frequently stored in dams or open ponds without adequate treatment,posing serious risk of heavy metals(HMs)contamination to surrounding ecosystems.Given these challenges,restoration of MTs to mitigate their negative impacts has become highly important.This study attempts to compile different types of MTs,their characteristics,and associated issues such as acid mine drainage(AMD)and HMs contamination,along with other environmental impacts.It also explores the fundamentals of phytoremediation,highlighting key processes,recent advancements,benefits,limitations,and strategies for post-harvest management.The findings indicate that MTs are a major source of HM pollution and contribute significantly to environmental deterioration.Phytoremediation has emerged as a promising,cost-effective,and eco-friendly solution for MT restoration.In addition to mitigating contamination,phytoremediation enhances soil quality,prevents erosion,reduces HM leaching into groundwater,and improves the visual appeal of degraded sites.Research suggests that revegetating MT-contaminated soils with specific plant species can effectively remediate these areas,reducing HM leaching risks while improving soil properties.This review serves as a valuable resource for researchers working on MT restoration,offering insights into the latest advancements in phytoremediation technology and its potential to address the environmental challenges posed by MTs.
文摘In the past decades, two large scale coastal engineering projects have been carried out in the Deep Bay surrounded by Shenzhen City and Hong Kong Special Administrative Region. One project is Shenzhen River channel regulation and the other is the sea reclamation along the seashore on the Shenzhen side. The two projects are very close to the two national nature reserves, specifically Futian in Shenzhen and Mai Po in Hong Kong, which are important wetland ecosystems worldwide. This paper aims to identify and monitor the mangrove wetland changes with time series of Landsat Thematic Mapper images pre and post to the two engineering projects being launched. Coupled analysis of the image interpretation results and tidal data acquired at the same time in the context of the two works reveals that the mangrove wetland area has increased from year 1989 to 1994, and has changed little from year 1994 to 2002. Binary coding is applied to reveal the distribution image of mangrove at each phase, and the coding image shows that the construction of the two coastal engineering projects has caused frequent changes in mangrove spatial distribution. The study also shows that the change is not significant regarding to the precision of the method and the natural evolution of mangrove wetland, and the projects do not cause apparently influences upon the two national mangrove conservation zones at least for the research time period.
文摘This work describes the development,optimisation and validation of an analytical method for the rapid determination of 17 priority pharmaceutical compounds and endocrine disrupting chemicals(EDCs).Rather than studying compounds from the same therapeutic class,the analyses aimed to determine target compounds with the highest risk potential(with particular regard to Scotland),providing a tool for further monitoring in different water matrices.Prioritisation was based on a systematic environmental risk assessment approach,using consumption data;wastewater treatment removal efficiency;environmental occurrence;toxicological effects;and pre-existing regulatory indicators.This process highlighted 17 compounds across various therapeutic classes,which were then quantified,at environmentally relevant concentrations,by a single analytical methodology.Analytical determination was achieved using a single-step solid phase extraction(SPE)procedure followed by high-performance liquid chromatography with tandem mass spectrometry(HPLC-MS/MS).The fully optimised method performed well for the majority of target compounds,with recoveries>71%for 15 of 17 analytes.The limits of quantification for most target analytes(14 of 17)ranged from 0.07 ng/L to 1.88 ng/L in river waters.The utility of this method was then demonstrated using real water samples associated with a rural hospital/setting.Eight compounds were targeted and detected,with the highest levels found for the analgesic,paracetamol(at up to 105,910 ng/L in the hospital discharge).This method offers a robust tool to monitor high priority pharmaceutical and EDC levels in various aqueous sample matrices.
基金supported by the Natural Science Foundation of Anhui Province (No. 1908085ME165)the Anhui Provincial Natural Science Key Foundation (No. 2008085UD07)the Special Funds for the Development of Local Science and Technology from the Central Government in Anhui Province (No. 803214271050)
文摘Semiconductor photocatalytic technology has shown great prospects in converting solar energy into chemical energy to mitigate energy crisis and solve environmental pollution problems.The key issue is the development of high-efficiency photocatalysts.Various strategies in the state-of-the-art advancements,such as heterostructure construction,heteroatom doping,metal/single atom loading,and defect engineering,have been presented for the graphitic carbon nitride(g-C3N4)-based nanocomposite catalysts to design their surface chemical environments and internal electronic structures to make them more suitable for different photocatalytic applications.In this review,nanoarchitecture design,synthesis methods,photochemical properties,potential photocatalytic applications,and related reaction mechanisms of the modified high-efficiency carbon nitride-based photocatalysts were briefly summarized.The superior photocatalytic performance was identified to be associated with the enhanced visible-light response,fast photoinduced electron-hole separation,efficient charge migration,and increased unsaturated active sites.Moreover,the further advance of the visible-light harvesting and solar-to-energy conversions are proposed.
文摘Due to high demand and limited availability of rare earth elements (REEs), Europe is unable to meet its industrial needs, especially High Tech needs, today for the manufacturing sector. Therefore, the EU has included them in the group of 14 critical minerals. China currently controls completely the mining activity, the enrichment technologies and metallurgy, and end-metal products of rare earths, resulting both Europe and the U.S.A. in full industrial dependency. The exploitation and wide use of REEs in fertilizers have led to accumulation of these elements in soils, resulting in an agriculture field pollution, which affects directly the soil microfauna with a toxic potential effect.
基金supports provided by the Science Research and Technology Developing Program, CNPC (2008D-4704-2): "Microbial remediation technology of high-temperature and arid oil polluted soil"
文摘A hydrocarbon degrading bacterium KL2-13 was isolated from ten sites of oil contaminated soil in the Karamay oilfield. It was identified as the Bacillusfusiformis sp. bacterium based on its morphological and physiological characteristics and the 16S rDNA sequence analysis. The factors influencing the hydrocarbon degradation by the bacterium KL2-13 were determined. The test results have showed that the hydrocarbon degrading bacterium KL2-13 requires an optimum pH range of 6-8, and the optimum inoculation quantity is 3%. The low-concentration metal ions Fe^2+, Mg^2+ and Ca^2+can improve the degradation ability of the bacteria KL2-13. A too low concentration of Tween-80 does not show obvious promotion to the degrading bacterium KL2-13, and an excessively high concentration can decrease the degradation ability of the bacterium, the best dosage of which is 2%. The hydrocarbon degrading rate reached 59.07%4-0.37% under the optimum culture conditions.
基金supported by the Technology Development Program to Solve Climate Changes of the National Research Foundation (NRF) funded by the Ministry of Science,ICT(No. 2017MIA2A2086839)supported by Nano-Material Technology Development Program through the National Research Foundation of Korean(NRF) funded by the Ministry of Science,ICT and Future Planning(No.NRF-2015M3A7B4049714)
文摘Lignocellulosic biomass is an abundant and environment-friendly source for renewable energy production.The value and application of biochar,which is obtained from the thermochemical conversion of biomass,is increasing rapidly because of its high carbon content and porosity.The property of biochar,such as surface area,porosity,and number of functional groups,can be improved by controlling the conditions of biomass conversion,biochar activation,and functionalization methods.The production and activation of biochar as well as its potential use for soil remediation,pollutant adsorption,and biorefinery have been reviewed extensively over recent decades.This paper provides a conceptual approach for biochar production and activation together with its application as a catalyst for biorefineries and the removal of environmental contaminants.
文摘Ti3 AL-Nb-Mo composites were prepared by SHS using initial powder mixtures of Ti-Al-Nb-Mo and their corrosion and mechanical properties were studied to develop bioand environmental materials. The composites reached 99.8% of theoretical density after the direct consolidation. The composites shows equiaxed primary a2 in a matrix of fine secondary a2 plates and ordered 82 (Bo) forming a basket weave structure. The strain rate sensitivity (m = dlnσ/dlne) at 2% strain is 0.008. Corrosion potential and corrosion rate of the composites formed by SHS were -151. 5m VSHE and 5. 72× 10^(-8)A/cm2 for Ti3 Al-10Nb-1. 5Mo and - 138.4m VSHE and 4. 12×10^(-8)cm2 for Ti3 Al-12Nb-1.5Mo in a 50% NaOH-10%FeCI3 solution, respectively. Corrosion resistance decreased with niobium content in the composites and chloride content in the aqueous solution. Selective corrosion of a2 phase in a matrix occurred in the corrosion environment which suggests that the corrosion potential and rate changes are related to the niobium content and Q2 phase in a matrix.
文摘The increased use of scarce metals in combination with climate changes pave way for extensive extraction of mineral resources in Greenland. The focus of this study is on environmental ethical aspects of mining activities in a vulnerable and unspoiled arctic nature. Mining can have several economic and social benefits for Greenland. On the other hand, the environmental impacts from mining are well known. Through DPSIR (Drivers, Pressures, States, Impacts, Responses) and Stakeholder analysis, we assess how future mining in Greenland can be sustainably implemented. The analysis revealed that numerous stakeholders have to be taken into consideration with a wide range of different interests. The DPSIR analysis clarified the availability of various potential political responses that could affect the drivers, pressures, states and impacts of mining mainly focused on implementation of effective environmental regulation strategies. Our findings revealed different environmental ethical dilemmas of which the most critical is how Greenland can open up for mining, gain economical revenue while averting destruction of unspoiled regions and aesthetic impairment. We recommend strict environmental legislation involving use of the "polluter pay principle", continuous monitoring of pollution and establishment of an industry-funded catastrophe trust fund. These initiatives can ensure economic benefits while environmental impacts remain negligible.
文摘The main purpose of this study was to determine the changes in the water quality of Melendiz and Karasu streams, which recharge the Mamasin dam, and to evaluate its environmental impacts on the dam site that provides drinking water and irrigation demand in Aksaray city in the Central Anatolia of Turkey. The field researches were focused on estimating the main sources of contamination, determining and evaluating the changes in the water quality due to the direct wastewater discharges into the Melendiz and Karasu rivers, which recharge the Mamasin dam sites. During the study, water samples were collected from Melendiz and Karasu stream and Mamasin dam, and then, the physical and chemical analyses of water samples were conducted. The relevant in-situ and laboratory analyses were carried out during the dry and wet seasons. The results of the analyses showed that in term of the surface water quality criteria in terms of NO3-N value of both rivers and dam waters, the water quality is always considered as the 1st class in Melendiz stream, the 2nd class in Karasu stream and the 3rd class in Mamasin dam lake. Whereas, in terms of NO4-N values of both rivers and dam waters, the water quality is always considered as the 1st class in Melendiz stream, the 2nd-3rd class in Karasu stream. The total organic carbon (TOC) range for Karasu river is usually from 20 mg/L to 40 mg/L. The high value of organic matter in the Karasu stream can be explained by the availability of intensive green wetlands around this water resource. Finally, the Ministry of Forest and Water Authority give some suggestions for estimating protection zones of Melendiz stream and Mamasin basin's area, such as using the results of environmental tracers to investigate the agricultural contamination, including more sophisticated applications of multiple-tracer analyses to evaluate the travel time of contaminants and estimate the boundary of protection zones.
文摘Nitrogen oxides (NO<sub>x</sub>) in urban air close to ground have significant health implications. Restrictions in traffic, mandatory use of catalytic converters on vehicles, and novel photocatalytic coatings on surfaces contribute to reducing the level of NO<sub>x</sub> in cities. The aim of this study is to establish environmental profiles of NO<sub>x</sub> removal by a Three-Way Catalyst (TWC) car converter and by a photocatalytic surface coating (for asphalt and concrete pavements) for fostering technological development in reducing the levels of NO<sub>x</sub> in urban air. We assessed the environmental performance for the removal of 1 kg NO<sub>x</sub> by the two technologies with Life Cycle Assessment (LCA;EF.3 impact assessment method). In order to do so, we established Life-Cycle-Inventory (LCI) data representing production, operation and end-of-life of the two technologies based on data from literature and industry. The production of photocatalytic surface coatings, used on concrete and asphalt, has environmental loads two orders of magnitude lower than the environmental benefits of NO<sub>x</sub> reduction expressed as a reduction in Photochemical Ozone Formation (POF), Acidification (A), and Terrestrial Eutrophication (TE). The vehicle catalytic converter shows similar results except that the use of rare earth elements in the production constitutes a significant load to Freshwater Ecotoxicity (FET) and that additional use of fuel during operation induces a modest Climate Change (CC) impact. For both technologies, the environmental benefits of reducing NO<sub>x</sub> far exceed any adverse environmental aspects of the production of the technologies.
文摘The waters renewal of the fishery harbor of Nea Krini is presented here. The harbor is located at the east Thessaloniki Gulf (NE Thermaikos Gulf, Greece). The main research point is focused on the environmental state of the harbor which is under construction. Under that point of view, the description of a two-dimensional, depth average, hydrodynamic model follows, in order to simulate the wind generated circulation of waters, initially on the greater area of Thermaikos Gulf and then on the coastal basin of the fishing harbor. The renewal of waters in the harbor’s basin is subsequently studied. Tidal effects on the waters’ renewal are also studied. The calculation of the concentration of Biochemically Oxygen Demand (BOD) in the fishing harbor for the average time of waters’ renewal is then examined for three different cases, concerning the existence and operation of openings on the body of the groins. Finally, the analysis of the results shows a good environmental state of the harbor. It is obvious that the use of numerical models for different scenarios of engineering and design approaches can lead to the prognosis of hydrodynamic and environmental sate of a harbor’s basin so that the best possible technical design can be adopted.
基金the Biomaterials and Transport Phenomena Laboratory Agreement No.30303-12-2003,at the University of Medea.
文摘Seawater desalination stands as an increasingly indispensable solution to address global water scarcity issues.This study conducts a thorough exergoenvironmental analysis of a multi-effect distillation with thermal vapor compression(MED-TVC)system,a highly promising desalination technology.The MED-TVC system presents an energy-efficient approach to desalination by harnessing waste heat sources and incorporating thermal vapor compression.The primary objective of this research is to assess the system’s thermodynamic efficiency and environmental impact,considering both energy and exergy aspects.The investigation delves into the intricacies of energy and exergy losses within the MED-TVC process,providing a holistic understanding of its performance.By scrutinizing the distribution and sources of exergy destruction,the study identifies specific areas for enhancement in the system’s design and operation,thereby elevating its overall sustainability.Moreover,the exergoenvironmental analysis quantifies the environmental impact,offering vital insights into the sustainability of seawater desalination technologies.The results underscore the significance of every component in the MED-TVC system for its exergoenvironmental performance.Notably,the thermal vapor compressor emerges as pivotal due to its direct impact on energy efficiency,exergy losses,and the environmental footprint of the process.Consequently,optimizing this particular component becomes imperative for achieving a more sustainable and efficient desalination system.
文摘The contribution of the use of RE(Renewable Energy)sources in general and wind source in particular in the Albanian electricity sector is very important to strengthen national energy security,diversify energy sources and reduce dependence on imports.It also directly affects economic growth,employment and reduces the release of pollutants into the atmosphere,which are contributing to global warming and the greenhouse effect.The purpose of this paper is to assess the theoretical,technical and economic potential of the wind source in the Synej Area,Kavaja Municipality for electricity production in the absence of field measurements.Calculations of all technical,economic and environmental parameters are performed through the RETScreen Expert program.This analysis is sufficient for pre-implementation studies that do not require very detailed calculations and at the same time facilitates decision-making on project implementation.The study area has considerable technical potential for the use of wind energy.In this area,the analyzed project envisages the installation of 7 turbines of the Vesta 110 type,each with a power of 2 MW.The height of the turbines is 85 m.The total amount of electricity produced by this plant is estimated at 24 GWh/year,at a cost of 0.06€/kWh.The total emission reduction for all proposed projects is 477,500 tCO_(2) per year.The project has a positive net present value and a benefit-cost ratio greater than 1.The payback time is 8 years.
文摘In the United Republic of Tanzania (URT), all environmental issues related to the mining industry are regulated according to two principle Acts: The Mining Act and the Environmental Management Act, and their respective regulations. The current acts were enacted in 2010 and 2004 respectively. Mineral exploration (that includes all on-site activities performed before a mining project is declared feasible) projects in URT appears to be “unforgotten phenomena” in the two major legislative documents, when it comes to environmental considerations. This phenomenon is believed to be causing detrimental effects to the environment. This paper, therefore, analyzes the current environmental regulatory framework on mineral exploration projects in URT and discusses few examples in which mineral exploration projects have caused damage to the indigenous environment. Furthermore, this study reviews environmental regulatory frameworks from other few countries in comparison with existing environmental regulatory framework prevailing in URT.
基金supported by the University Salah Boubnider-Constantine 3 (Algeria).
文摘This research aims to study the bio-adsorption process of two dyes,Cibacron Green H3G(CG-H3G)and Terasil Red(TR),in a single system and to bring them closer to the industrial textile discharge by a binary mixture of two dyes(TR+CG-H3G).The Cockle Shell(CS)was used as a natural bio-adsorbent.The characterizations of CS were investigated by Fourier transform infrared(FTIR),X-ray diffraction(XRD),scanning electron microscopy(SEM),energy-dispersive X-ray spectroscopy(EDX)and Brunauer–Emmett–Teller(BET).The adsorption potential of Cockle Shells was tested in two cases(single and binary system)and determined by:contact time(0–60 min),bio-adsorption dose(3–15 g/L),initial concentration(10–300 mg/L),temperature(22–61°C)and pH solution(2–12).The study of bio-adsorption(equilibrium and kinetics)was conducted at 22°C.The kinetic studies demon-strated that a pseudo-second-order adsorption mechanism had a good correlation coefficient(R2≥0.999).The Langmuir isotherm modeling provided a well-defined description of TR and CG-H3G bio-adsorption on cockle shells,exhibiting maximum capacities of 29.41 and 3.69 mg/g respectively at 22°C.The thermodynamic study shows that the reaction between the TR,CG-H3G dyes molecules and the bio-adsorbent is exothermic,spontaneous in the range of 22–31°C with the aleatory character decrease at the solid-liquid interface.The study of selectivity in single and binary systems has been performed under optimal operating conditions using the industrial textile rejection pH(pH=6.04).CG-H3G dye is found to have a higher selectivity than TR in single(0–60 min)and binary systems with a range of 6–45 min,as shown by the selectivity measurement.It was discovered that CS has the capability to remove both CG-H3G and TR dyes in both simple and binary systems,making it a superior bio-adsorbent.
基金supported by grants from the National Research Foundation of Korea(NRF)under grant No.RS-2022-00155422 and No.2021R1C1C102014。
文摘Water often presents significant challenges in catalysts by deactivating active sites,poisoning the reaction,and even degrading composite structure.These challenges are amplified when the water participates as a reactant and is fed as a liquid phase,such as trickle bed-type reactors in a hydrogen-water isotope exchange(HIE)reaction.The key balance in such multiphase reactions is the precise control of catalyst design to repel bulk liquid water while diffusing water vapor.Herein,a platinum-incorporated metal-organic framework(MIL-101)based bifunctional hydrophobic catalyst functionalized with long alkyl chains(C_(12),dodecylamine)and further manufactured with poly(vinylidene fluoride),Pt@MIL-101-12/PVDF,has been developed which can show dramatically improved catalytic activity under multi-phase reactions involving hydrogen gas and liquid water.Pt@MIL-101-12/PVDF demonstrates enhanced macroscopic water-blocking properties,with a notable reduction of over 65%in water adsorption capacity and newly introduced liquid water repellency.while exhibiting a negligible increase in mass transfer resistance,i.e.,bifunctional hydrophobicity.Excellent catalytic activity,evaluated via HIE reaction,and its durability underscore the impact of bifunctional hydrophobicity.In situ DRIFTS analysis elucidates water adsorption/desorption dynamics within the catalyst composite,highlighting reinforced water diffusion at the microscopic level,affirming the catalyst's bifunctionality in different length scales.With demonstrated radiation resistance,Pt@MIL-101-12/PVDF emerges as a promising candidate for isotope exchange reactions.
文摘Reports and claims have been made reflecting opinions of the environmental impacts of the Whein Town Landfill Facility on the residents of the Whein Town Community. This study seeks to examine the environmental effects of the Whein Town Landfill on nearby residents, and the effectiveness of the existing mitigation schemes. This cross-sectional study used 4-point-Likert and 2-point-dichotomous scales questionnaires to collect information from 352 Whein Town community household heads. The findings reveal that “odorous emissions” represent the most critical environmental challenge, severely impacting residents’ well-being and quality of life. By contrast, “garbage spillage along routes” has a minimal impact on residents’ lives, with many residents rating it as “Not Serious”. Six out of eight mitigation implemented schemes achieved a success rate below 25%, one performed at approximately 50%, and only one scheme—the landfill fencing—was effectively implemented, reaching a near-perfect success rate of 99.99%. Therefore, residents of Whein Town are experiencing adverse environmental effects that can be remediated with proper planning and the implementation of existing schemes.
文摘This study focused on realizing Sustainable Development Goal(SDG)6 for inclusive clean water and sanitation;in particular Target 6.3,which aims to reduce untreated wastewater by 2030 while promoting circular wastewater reuse and recycling globally.The main objective was to assess the adequacy and efficiency of communal septic tank systems in informal settlements while helping local planners and authorities in their decision-making regarding Target 6.3.Quantitative and qualitative approaches were employed with secondary data from previous researchers,and primary data were collected from field surveys,observations,and interviews with members of the local community.The research was delimited to two village administrative divisions known as Rukun Warga(Village Administrative Division,RW):RW 7 and RW 8 of Lebak Siliwangi Kampung in Coblong District,Bandung,West Java,Indonesia.The findings were also compared with situations in other informal settlements in Brazil,Bangladesh,and Nairobi.The results indicated the inadequacy of communal septic tanks in informal settlements due to factors such as substandard system design,limited support and communication between authorities and residents,and the gap between septic tank availability and capacity vis-a-vis demand.Other limiting factors included limited land availability and irregular geomorphology,the latter of which affected the siting and operation of septic tanks due a lack of room for upgrades or expansion in response to continuous population growth.These findings illustrate the need to complement communal septic systems with flexible centralized or decentralized systems to achieve Target 6.3 of SDG 6.
文摘Extreme temperature events have intensified across Jordan over the past 40 a,increasing risks to agriculture,water availability,urban infrastructure,and public health.The purpose of this study is to assess the long-term spatial trends and regime shifts in extreme temperature indicators across Jordan's climate zones to explore climate adaptation strategies.This study presents a high-resolution and spatially explicit assessment of thermal extremes using daily data from 1982 to 2024 across 45 grid-based study points in Jordan.Thirteen temperature indices,including percentile-based thresholds,duration metrics,and absolute extremes,were computed using RClimDex and analyzed across four Köppen climate zones:hot desert(BWh),hot semi-arid(BSh),cold desert(BWk),and Mediterranean(Csa)climates.The analysis confirmed a statistically significant warming trend:annual mean maximum temperatures increased by 2.198°C,while annual mean minimum temperatures rose by 2.035°C.Cold extremes have sharply declined,with cold days(TX10p)decreasing by 70.0%–80.0%,and the cold spell duration indicator(CSDI)dropping from 12.6 to 4.0 d/a,particularly in the BWk zone.Heat indices intensified across all zones,with warm days(TX90p)increasing by over 300.0%in BWh,warm nights(TN90p)rising by 38.1%,and the warm spell duration indicator(WSDI)extending fourfold,indicating prolonged exposure to heatwaves.Mean value of maximum temperature(TXx)reached 45.600°C in most arid areas,while minimum temperature(TNx)exceeded 31.600°C,highlighting increased nocturnal heat stress.Change-point analysis indicated that 1998 was a pivotal year,marking a structural transition in both cold and warm temperature indices.Subsequent intensifications after 2010 in TN90p,TNx,and mean of daily maximum temperature(Tmaxmean)reflected an ongoing trend toward sustained thermal extremes.In addition to time-series trends,the study employed network-based correlation analysis to explore the coherence among climate indices.Strong positive correlations were observed among TXx,TX90p,and mean of daily minimum temperature(Tminmean)(r≥0.94),as well as among TN90p,Tminmean,and TNx(r≥0.87),indicating a tightly clustered heat subsystem.Duration metrics like the WSDI showed a close alignment with percentile extremes(between WSDI and TX90p;r=0.88),suggesting integrated heatwave behavior.In contrast,cold indices(TX10p,TN90p,frost days,and CSDI)exhibited weak or negative correlations and displayed peripheral positioning in the climate network,indicating their limited role under a warming regime.Absolute extremes showed weak internal linkages,suggesting episodic rather than systemic response characteristics.This structural realignment indicated a shift from a previously balanced thermal profile to a heat-dominated climate system.Regional variations revealed that BWh and BSh were experiencing the steepest warming,while Csa was transitioning more slowly but was showing signs of reduced winter cooling and increased irrigation demands.The findings establish a robust climate baseline for Jordan and offer actionable insights for climate adaptation planning.Recommended measures include precision irrigation,the development of heat-resilient crops,improvements to urban cooling infrastructure,and early warning systems for thermal extremes.By integrating spatial climate zoning,regime shift analysis,and inter-index correlation structures,this study provides a replicable framework for monitoring climatic transformations and informing resilience strategies in arid and semi-arid areas.