Background The effectiveness of life skills-based prevention programs to prevent substance addiction has been underexplored in Türkiye,likely in part due to the lack of validated measurement tools developed speci...Background The effectiveness of life skills-based prevention programs to prevent substance addiction has been underexplored in Türkiye,likely in part due to the lack of validated measurement tools developed specifically for that purpose.Therefore,the aim of this study is to develop a tool to measure life skills for middle school students.The present study aims to test the factorial structure,reliability,convergent and discriminant validity,and measurement invariance across gender and age groups of the Green Crescent Life Skills(GCLS)Scale.Methods The study was conducted in Istanbul with two different sample groups.The first sample consisted of 566 and the second sample consisted of 885 middle school students.In the study,exploratory factor analysis(EFA)was applied to the first sample,and confirmatory factor analysis(CFA)was applied to the second sample to test the factorial structure of the scale.Convergent and discriminant validity were examined to provide evidence for construct-based validity.The reliability of the scale was assessed with Cronbach’sα,composite reliability,McDonald’sω,and test-retest.Results The EFA results showed that the scale consisted of four factors(self-awareness,coping with negative emotions,thinking skills,and peer relations).CFA results also confirmed this structure.The results revealed a significant positive correlation(r=0.52,p<0.01)between life skills and avoidance self-efficacy scores,as well as a significant negative correlation(r=−0.53,p<0.01)between life skills and attitude toward drug use scores.Additionally,it was found that measurement invariances based on gender and age groups were provided.It was determined that all sub-dimensions had sufficient reliability levels.Conclusion The findings of this validation study show that the GCLS Scale,which assesses four skills in a self-reported format,is a valid and reliable scale with considerable potential utility in monitoring life skills in Turkish adolescent populations.展开更多
The nitrogen(N2)-to-ammonia(NH3)fixation driven by renewable energy has an attractive prospect to relieve the global warming and reduce the consumption of fossil fuels.Ideally,photocatalytic,electrochemical,and photoe...The nitrogen(N2)-to-ammonia(NH3)fixation driven by renewable energy has an attractive prospect to relieve the global warming and reduce the consumption of fossil fuels.Ideally,photocatalytic,electrochemical,and photoelectrochemical approaches are developed as the next-generation NH3 synthesis technologies to substitute the Haber–Bosch method.However,the NH3 yield rate of nitrogen reduction reaction(NRR)by green approaches is extremely low,resulting in the current dilemma of NRR and contamination issues.Thus,in this mini review,the past advances on the sustainable NRR are briefly summarized in the three aspects as follows:the selectivity and adjustment of various catalysts,the type of electrolyte/solvent system,and the investigation of reaction conditions.Subsequently,the recent critical activities in the area of sustainable NH3 synthesis are analyzed and discussed deeply,and a perspective for rational and healthy development of this area is provided positively。展开更多
Waste carbon residue(WCR)was efficiently detoxicated and regenerated to high-purity graphite(PGC)used in lithium-ion batteries through the constant-pressure acid leaching technique.The leaching conditions were optimiz...Waste carbon residue(WCR)was efficiently detoxicated and regenerated to high-purity graphite(PGC)used in lithium-ion batteries through the constant-pressure acid leaching technique.The leaching conditions were optimized by the combination of orthogonal and single-factor experiments.Results show that PGC with 99.5%purity is regenerated at temperature of 60℃,initial acid concentration of 12%,leaching time of 180 min,and liquid-to-solid ratio of 25:1,satisfying the requirements of commercial graphite.Meanwhile,the sodium hydroxide precipitation process was designed to recover valuable components from leachate efficiently.Ni,Co,Mn,and Al recoveries reach 96.92%,87.5%,97.83%,and 92.17%,respectively,at pH=11.Moreover,the co-product NaF can be recovered with purity over 99%via evaporative crystallization.The loss rate of fluorine is less than 0.5%,thereby eliminating the pollution risk of fluorine to the environment.The proposed process shows considerable environmental and economic benefits.展开更多
To overcome the dimension limits of immiscible alloys produced by traditional techniques and enhance their mechanical properties,bulk Cu-Fe-based immiscible alloy with abundant nanotwins and stacking faults was succes...To overcome the dimension limits of immiscible alloys produced by traditional techniques and enhance their mechanical properties,bulk Cu-Fe-based immiscible alloy with abundant nanotwins and stacking faults was successfully produced by selective laser melting(SLM).The SLM-produced bulk immiscible alloy displays a heterogeneous microstructure characterized by micro-scaledγ-Fe particles dispersed in fineε-Cu matrix with a high fraction(~92%)of high-angle grain boundaries.Interestingly,abundant nanotwins and stacking faults are generated in the interior of nano-scaledγ-Fe particles embedded withinε-Cu matrix.The heterogeneous interface of soft domains(ε-Cu)and hard domains(γ-Fe)not only induces the geometrically necessary dislocations(GNDs)but also affects the dislocation propagation during plastic deformation.Therefore,the bimodal heterogeneous interface,and the resistance of nanotwins and stacking faults to the propagation of partial dislocation make the bulk immiscible alloy exhibit an enhanced strength of~590 MPa and a good ductility of~8.9%.展开更多
This work reports an improved method for the wet desulfurization of high-sulfur petroleum coke(petcoke)powder based on the combination of pre-calcination,H_(2)O_(2),and ultrasound.The results demonstrated that over 45...This work reports an improved method for the wet desulfurization of high-sulfur petroleum coke(petcoke)powder based on the combination of pre-calcination,H_(2)O_(2),and ultrasound.The results demonstrated that over 45%of the sulfur atoms were efficiently removed from Tianjin coke and Qilu coke(particle size<0.1 mm)by pre-calcination at 800℃ for 6 h followed by desulfurization with HNO3(8 mol/L)and H_(2)O_(2)(2 mol/L)solution at a reaction temperature of 60℃,a reaction time of 6 h,a liquid-to-solid ratio of 10 mL/g,and a 40 kHz ultrasonic power of 400 W.In addition,the specific surface area of the petcoke particles increased from 0.7 to 301.49 m^(2)/g.After desulfurization,the pore size distribution of the petcoke particles was more concentrated on micropores compared with the samples prior to petcoke treatment.Reactive force field molecular dynamics simulation results indicated that HNO_(3) continuously oxidized the carbon atoms adjacent to sulfur atoms in the petcoke macromolecules and promoted sulfur removal from petcoke via the cleavage of C-S bonds.The sulfur transformation mechanism can be summarized as follows:thiophene sulfur→branched chain carbon sulfur→CO_(2)S→C_(2)O_(2)S→C_(2)O_(3)NS→C_(2)O_(4)S→CO_(2)S.展开更多
Teachers voluntarily devote a lot of time to their vocational activates. This can lead to workaholism and may result in stress and job burnout. The main objective of the current study is to examine the relationship of...Teachers voluntarily devote a lot of time to their vocational activates. This can lead to workaholism and may result in stress and job burnout. The main objective of the current study is to examine the relationship of workaholism with stress and job burnout of elementary school teachers in Zahedan. This is a descriptive-correlational study. The sample includes 350 elementary school teachers in Zahedan whom are selected through applying stratified random sampling method and are examined using questionnaires on workaholism, occupational stress, and job burnout. To analyze the obtained data, correlation coefficient and simultaneous multiple regression analysis are applied using SPSS21. Teachers’ mean scores on workaholism, stress and job burnout are higher than the considered theoretical mean. Workaholism and its components (feeling of being driven to work, work involvement, and work enjoyment) are significantly and positively related to job burnout and occupational stress (p ). The results of simultaneous multiple regression analysis indicate that components of workaholism can predict teachers’ occupational stress and job burnout (p ). Considering the results, holding training courses for teachers to become familiar with the phenomena of workaholism, stress, and job burnout, individual and organizational outcomes, methods of dealing with them and managing them effectively is highly recommended.展开更多
This paper focuses on knowledge and attitudes of Grade 8 pupils about HIV/AIDS and opportunistic diseases. In particular, people need to know what it is, how it is transmitted, how to protect themselves from it, and h...This paper focuses on knowledge and attitudes of Grade 8 pupils about HIV/AIDS and opportunistic diseases. In particular, people need to know what it is, how it is transmitted, how to protect themselves from it, and how to relate to people with the disease. According to the National policy for HIV/AIDS, schools are key settings for educating children about HIV/AIDS and for halting further spread of the infection. It has been noticeable that Grade 8 pupils in the rural areas around Mthatha district are particularly at risk of getting HIV. The focus is often more on Grade 11 and 12 pupils, so female Grade 10 pupils look for boys for attention. This resulted for the female pupils to fall pregnant. The fact that some of them are falling pregnant means they are also more vulnerable to contracting HIV. This shows that little information is available for them and this paper is contributing to that body of knowledge. Prevention therefore is the most effective strategy to combat pregnancy and against the spread of HIV/AIDS in schools. Measures should be taken to remove the social, cultural and political barriers that might block access to HIV/AIDS services and programmes. The results showed that while some Grade 8 pupils are aware of HIV/AIDS, there are others who said it does not exist. It has also been highlighted that the phenomenon of pupils having unprotected sex with older men for money, as well as pupils saying they did not have time to use condoms. It is therefore recommended that pupils need to have role models, people they can look up to. In the absence of parents, it should be teachers＇ responsibility to advise the pupils and inform them about Sexually Transmitted Infections （STIs） and HIV/AIDS in schools.展开更多
First principles calculation and quasi-harmonic Debye model were used to obtain more physical properties of zirconium carbide under high temperature and high pressure.The results show that the B1structure of ZrC is en...First principles calculation and quasi-harmonic Debye model were used to obtain more physical properties of zirconium carbide under high temperature and high pressure.The results show that the B1structure of ZrC is energetically more favorable with lower heat of formation than the B2structure,and that mechanical instability and positive heat of formation induce the inexistence of the B2structure at normal pressure.It is also found that the B1structure would transform to the B2structure under high pressure below the critical point of V/V0=0.570.In addition,various thermodynamic and elastic properties of ZrC are obtained within the temperature range of0-3000K and the pressure range of0-100GPa.The calculated results not only are discussed and understood in terms of electronic structures,but also agree well with corresponding experimental data in the literature.展开更多
The aim of this study is to investigate the relationship between life orientation and cognitive emotion regulation with job stress. On this basis, a sample of 100 employees working in Guilan Education Office was used ...The aim of this study is to investigate the relationship between life orientation and cognitive emotion regulation with job stress. On this basis, a sample of 100 employees working in Guilan Education Office was used and research hypotheses were examined by job stress, life orientation and cognitive emotion regulation questionnaires. The results of this study indicate that job stress has a significant relationship with life orientation (-0.32), self-blame (0.25), rumination (-0.36), positive refocusing (0.25), positive refocusing on program (-0.21), positive reappraisal (-0.28), catastrophizing (-0.39) and other blames (-0.25). Furthermore, life orientation and cognitive regulation could explain 22% variances in respondents’ job stress. This finding indicates that more positive life orientation and subsequent decrease of emotion-regulation-related disorders will lead to less job stress.展开更多
The present study aimed to examine the relationship of organizational intelligence with innovation management and career advancement in an organization. Considering its objective, this was a descriptive-correlational ...The present study aimed to examine the relationship of organizational intelligence with innovation management and career advancement in an organization. Considering its objective, this was a descriptive-correlational study. The statistical population included all high school managers in Zahedan at the year 2015. The sample contained 52 male managers and 51 female managers whom were selected through applying stratified random sampling method. To collect data, Organizational Intelligence Questionnaire, Innovation Management Inventory and Questionnaire of Career Advancement were used, the validity of which was assessed through applying the standpoint of a number of university professors and their reliability was obtained 0.74, 0.76, 0.84, respectively, using Cronbach’s alpha coefficient. Results indicated that considering managers’ perspectives, the status of organizational intelligence and career advancement were desirable;however, the status of innovation management was moderate. Moreover, organizational intelligence and its components were significantly and positively correlated with innovation management (r = 0.512, P < 0.01), and there was a significant and positive relationship between organizational intelligence and career advancement (r = 0.334, P < 0.01). Findings demonstrated that components of desire to change, spirit, unity and agreement, application of knowledge, performance pressure were significantly correlated to career advancement. However, components of strategic perspective and common fate were not significantly correlated with career advancement. Additionally, among the components of organizational intelligence, in the first step, application of knowledge and in the second step, desire to change were the best predicators of innovation management (which together could predict 28%). Application of knowledge was the only variable which entered the predictive model and predicted 16% of career advancement. Results of independent t-test indicated that no significant difference was found between male and female managers, considering their organizational intelligence, innovation management and career advancement.展开更多
The present study aims to examine the effectiveness of the combination of solution-focused therapy and narrative therapy in marital adjustment of incompatible women. This research is a pretest-posttest quasi-experimen...The present study aims to examine the effectiveness of the combination of solution-focused therapy and narrative therapy in marital adjustment of incompatible women. This research is a pretest-posttest quasi-experimental study design with a nonequivalent control group. The statistical population comprises all the incompatible women who referred to the counseling clinics of Neyshabour in May 2016 (1500 admission per month). The research sample consists of 24 incompatible women who were selected through Randomand available sampling method. For data collection, Marital Adjustment Scale by Spinner was applied. The data were analyzed using the analysis of covariance test and with the aid of SPSS-22 software. The findings demonstrated that the combination of solution-focused therapy and narrative therapy is significantly effective in marital adjustment of incompatible women (P < 0.05). Thus, it can be stated that the combination of solution-focused therapy and narrative therapy can help to promote adjustment among incompatible women.展开更多
The main goal of this research was the scrutiny of relationship between students’ personality characteristics and mental health at the University of Guilan. The population was the students of the Faculty of Humanitie...The main goal of this research was the scrutiny of relationship between students’ personality characteristics and mental health at the University of Guilan. The population was the students of the Faculty of Humanities in 2009 with 3000 which 196 were selected using Kerjeci & Morgan table and stratified sampling method. They answered to the NEO and GHQ questionnaires. Results showed that there was relationship between personality characteristic of neurotic, openness, extraversion and being conscionable with mental health. Meanwhile, openness had the highest and extraversion with the lowest correlation scale and most of students (65%) had low mental health. Also, there were no significant differences among students with respect to different courses but significant difference with respect to gender and age.展开更多
This is an experimental study conducted on two groups of control and experimental using pretestposttest design, applying psychological intervention on the study sample. The present study aimed to determine the effecti...This is an experimental study conducted on two groups of control and experimental using pretestposttest design, applying psychological intervention on the study sample. The present study aimed to determine the effectiveness of collective education life skills on mental health and resilience of teachers in Zahedan. The population of the study included all teachers at schools with normal students and teachers at schools with exceptional students in Zahedan, among which 60 teachers at normal schools and 20 teachers at exceptional schools were selected and placed in two groups of experimental and control, respectively. Initially, members of the experimental group were taught 10 basic life skills in 10 2-hour sessions. Mental health and resilience questionnaires were distributed and gathered before and after the training sessions. Results indicated the positive effect of life skills training on mental health of teachers at schools with normal students and teachers at schools with exceptional students, which meant that the more the life skills training to teachers at schools with normal students and teachers at schools with exceptional students, the lower their mental health scores would be. Results also indicated the positive effect of life skills training on resilience of teachers at schools with normal students and teachers at schools with exceptional students, which meant that the more the life skills training to teachers at schools with normal students and teachers at schools with exceptional students, the higher their resilience scores would be.展开更多
Introduction: The present study sought to examine the effectiveness of quality of life therapy on increasing happiness among patients with major depression. Methods: The research followed an experimental research desi...Introduction: The present study sought to examine the effectiveness of quality of life therapy on increasing happiness among patients with major depression. Methods: The research followed an experimental research design with an experimental and a control group. To this end, among the statistical population of the study that consisted of all individuals with major depression disorder, 30 individuals were randomly selected and placed in two groups (experimental and control). The experimental group individually received an intervention with a trend based on quality of life improvement for 10 sessions. The control group received no such treatment. Beck’s Depression Inventory and Oxford Happiness Questionnaire were used in two occasions of pretest and posttest. Data analysis was performed using descriptive statistics and multivariate analysis of covariance. Results: The results revealed that quality of life therapy reduced depression and increased happiness among the subjects on the posttest (p < 0.01). Conclusion: This research found two important results. First, it was revealed that quality of life therapy had high efficiency in treating depression considered as a resistant disorder to treatment. Second, it was indicated that focus on happiness in the treatment of major depression disorder can significantly help?patients recover.展开更多
This study aimed to increase the achievement level of college students on math by providing a high level of expectancy,value,interest,and motivation toward math.To be able to achieve this aim,action research was used ...This study aimed to increase the achievement level of college students on math by providing a high level of expectancy,value,interest,and motivation toward math.To be able to achieve this aim,action research was used instead of exploratory studies.Action research is a group of people’s identifying a problem,doing something to solve the problem,seeing how successful they were and if they weren’t satisfied by the results their retrying,and in short learning by doing and living.150 freshmen of a university in Turkey participated in the study.The researcher and a math teacher implemented to the study.Results of the study showed that students’negative beliefs and expectations can change if they get support.According to the beliefs and expectations,grades of students also change and improve since positive perception makes life positive.展开更多
This paper reveals that the implementation of inclusive education is an unfinished challenge,both within the system and for individual self-improvement.This process of changing practices,by continually questioning the...This paper reveals that the implementation of inclusive education is an unfinished challenge,both within the system and for individual self-improvement.This process of changing practices,by continually questioning the school’s responsibility for the(re)production of inequalities,exclusion,and unequal social relations,is riddled with obstacles,unpredictable situations,and strong emotions.In particular,the researchers point out that many systemic mechanisms of school culture contribute to replicating and reifying hierarchical school experiences and exacerbating processes of institutional discrimination against immigrant backgrounds and/or racialized students.The empirical research presented also highlights the school staff’s deficit thinking toward immigrant students and their parents.The results show that staff tend to use linguistic and cultural gaps between students and the school system to explain academic failure.Be that as it may,the researchers as well as the school actors and students interviewed in this paper suggest multiple ways to improve inclusion in the school context,stressing the importance of giving voice to the various actors in order to move toward institutional transformation.展开更多
Single-atom catalysts(SACs)are promising for oxygen reduction reaction(ORR)on account of their excellent catalytic activity and maximum utilization of atoms.However,due to the complicated preparation processes and exp...Single-atom catalysts(SACs)are promising for oxygen reduction reaction(ORR)on account of their excellent catalytic activity and maximum utilization of atoms.However,due to the complicated preparation processes and expensive reagents used,the cost of SACs is usually too high to put into practical application.The development of cost-effective and sustainable SACs remains a great challenge.Herein,a low-cost method employing biomass is designed to prepare efficient single-atom Fe-N-C catalysts(SA-Fe-N-C).Benefiting from the confinement effect of porous carbon support and the coordination effect of glucose,SA-Fe-N-C is derived from cheap flour by the two-step pyrolysis.Atomically dispersed Fe atoms exist in the form of Fe-N_(x),which acts as active sites for ORR.The catalyst shows outstanding activity with a half-wave potential(E_(1/2))of 0.86 V,which is better than that of Pt/C(0.84 V).Additionally,the catalyst also exhibits superior stability.The ORR catalyzed by SA-Fe-N-C proceeds via an efficient 4e transfer pathway.The high performance of SA-Fe-N-C also benefits from its porous structure,extremely high specific surface area(1450.1 m^(2)/g),and abundant micropores,which are conducive to increasing the density of active sites and fully exposing them.This work provides a cost-effective strategy to synthesize SACs from cheap biomass,achieving a balance between performance and cost.展开更多
In Chinese question answering system, because there is more semantic relation in questions than that in query words, the precision can be improved by expanding query while using natural language questions to retrieve ...In Chinese question answering system, because there is more semantic relation in questions than that in query words, the precision can be improved by expanding query while using natural language questions to retrieve documents. This paper proposes a new approach to query expansion based on semantics and statistics Firstly automatic relevance feedback method is used to generate a candidate expansion word set. Then the expanded query words are selected from the set based on the semantic similarity and seman- tic relevancy between the candidate words and the original words. Experiments show the new approach is effective for Web retrieval and out-performs the conventional expansion approaches.展开更多
Objectives: The purpose of this study is to analyse the practical implementation of regional and na-tional policies through the Protocol of Care of Children and Adolescents in School (2010) in Extremadura Region (Spai...Objectives: The purpose of this study is to analyse the practical implementation of regional and na-tional policies through the Protocol of Care of Children and Adolescents in School (2010) in Extremadura Region (Spain), and to compare its contents with the international standards of diabetes care at school defined by American Diabetes Association and International Diabetes Federation. The measures not only affect the security and diabetes care, but also inclusion and the right to health. Methods: A documental comparative analysis between the local and international standards about diabetes care in school setting is carried out. This analysis is framed in a larger project focused on the study of health promoting school and diabetes education, in which perceptions of children and adolescents with diabetes, their parents and school staff were studied. Results: The Protocol of Care of Children and Adolescents in School (2010) contains some international recommendations about the care of T1DM at school, but in other cases the measures are non-specific. The distribution of responsibilities for care at school is unclear and no monitoring and evaluation indicators are defined. Some elements are identified to be implemented in the tool to favour the security, management of T1DM care and wellbeing. In general, these elements refer to school plan for diabetes care, school organization and teachers, and school community training. Conclusion: It is required to develop specific policies and decisive action to ensure the right to health of children with diabetes and the full application of international standards for diabetes care at school.展开更多
基金supported by the Turkish Green Crescent Society under Grant[41402653-160-6/333].
文摘Background The effectiveness of life skills-based prevention programs to prevent substance addiction has been underexplored in Türkiye,likely in part due to the lack of validated measurement tools developed specifically for that purpose.Therefore,the aim of this study is to develop a tool to measure life skills for middle school students.The present study aims to test the factorial structure,reliability,convergent and discriminant validity,and measurement invariance across gender and age groups of the Green Crescent Life Skills(GCLS)Scale.Methods The study was conducted in Istanbul with two different sample groups.The first sample consisted of 566 and the second sample consisted of 885 middle school students.In the study,exploratory factor analysis(EFA)was applied to the first sample,and confirmatory factor analysis(CFA)was applied to the second sample to test the factorial structure of the scale.Convergent and discriminant validity were examined to provide evidence for construct-based validity.The reliability of the scale was assessed with Cronbach’sα,composite reliability,McDonald’sω,and test-retest.Results The EFA results showed that the scale consisted of four factors(self-awareness,coping with negative emotions,thinking skills,and peer relations).CFA results also confirmed this structure.The results revealed a significant positive correlation(r=0.52,p<0.01)between life skills and avoidance self-efficacy scores,as well as a significant negative correlation(r=−0.53,p<0.01)between life skills and attitude toward drug use scores.Additionally,it was found that measurement invariances based on gender and age groups were provided.It was determined that all sub-dimensions had sufficient reliability levels.Conclusion The findings of this validation study show that the GCLS Scale,which assesses four skills in a self-reported format,is a valid and reliable scale with considerable potential utility in monitoring life skills in Turkish adolescent populations.
基金The authors are grateful to the National Natural Science Foundation of China(51402100,21573066,21825201,22075075,21805080,and U19A2017)the Provincial Natural Science Foundation of Hunan(2016JJ1006,2020JJ5044,and 2016TP1009)Australian Research Council(DP180100568 and DP180100731)for financial support of this research.
文摘The nitrogen(N2)-to-ammonia(NH3)fixation driven by renewable energy has an attractive prospect to relieve the global warming and reduce the consumption of fossil fuels.Ideally,photocatalytic,electrochemical,and photoelectrochemical approaches are developed as the next-generation NH3 synthesis technologies to substitute the Haber–Bosch method.However,the NH3 yield rate of nitrogen reduction reaction(NRR)by green approaches is extremely low,resulting in the current dilemma of NRR and contamination issues.Thus,in this mini review,the past advances on the sustainable NRR are briefly summarized in the three aspects as follows:the selectivity and adjustment of various catalysts,the type of electrolyte/solvent system,and the investigation of reaction conditions.Subsequently,the recent critical activities in the area of sustainable NH3 synthesis are analyzed and discussed deeply,and a perspective for rational and healthy development of this area is provided positively。
基金the financial supports from the National Natural Science Foundation of China(Nos.52174338,51904349)the Natural Science Foundation of Hunan Province,China(No.2021JJ30796)。
文摘Waste carbon residue(WCR)was efficiently detoxicated and regenerated to high-purity graphite(PGC)used in lithium-ion batteries through the constant-pressure acid leaching technique.The leaching conditions were optimized by the combination of orthogonal and single-factor experiments.Results show that PGC with 99.5%purity is regenerated at temperature of 60℃,initial acid concentration of 12%,leaching time of 180 min,and liquid-to-solid ratio of 25:1,satisfying the requirements of commercial graphite.Meanwhile,the sodium hydroxide precipitation process was designed to recover valuable components from leachate efficiently.Ni,Co,Mn,and Al recoveries reach 96.92%,87.5%,97.83%,and 92.17%,respectively,at pH=11.Moreover,the co-product NaF can be recovered with purity over 99%via evaporative crystallization.The loss rate of fluorine is less than 0.5%,thereby eliminating the pollution risk of fluorine to the environment.The proposed process shows considerable environmental and economic benefits.
基金financially supported by the Projects of MOE Key Lab of Disaster Forecast and Control in Engineering in Jinan University(No.20200904006)the Guangdong Basic and Applied Basic Research Foundation(No.2020B1515420004)。
文摘To overcome the dimension limits of immiscible alloys produced by traditional techniques and enhance their mechanical properties,bulk Cu-Fe-based immiscible alloy with abundant nanotwins and stacking faults was successfully produced by selective laser melting(SLM).The SLM-produced bulk immiscible alloy displays a heterogeneous microstructure characterized by micro-scaledγ-Fe particles dispersed in fineε-Cu matrix with a high fraction(~92%)of high-angle grain boundaries.Interestingly,abundant nanotwins and stacking faults are generated in the interior of nano-scaledγ-Fe particles embedded withinε-Cu matrix.The heterogeneous interface of soft domains(ε-Cu)and hard domains(γ-Fe)not only induces the geometrically necessary dislocations(GNDs)but also affects the dislocation propagation during plastic deformation.Therefore,the bimodal heterogeneous interface,and the resistance of nanotwins and stacking faults to the propagation of partial dislocation make the bulk immiscible alloy exhibit an enhanced strength of~590 MPa and a good ductility of~8.9%.
基金This work was financially supported by the Scientific Research Project of Hunan Education Department(20C0410)the Fundamental Research Funds for the Central Universities of Central South University.
文摘This work reports an improved method for the wet desulfurization of high-sulfur petroleum coke(petcoke)powder based on the combination of pre-calcination,H_(2)O_(2),and ultrasound.The results demonstrated that over 45%of the sulfur atoms were efficiently removed from Tianjin coke and Qilu coke(particle size<0.1 mm)by pre-calcination at 800℃ for 6 h followed by desulfurization with HNO3(8 mol/L)and H_(2)O_(2)(2 mol/L)solution at a reaction temperature of 60℃,a reaction time of 6 h,a liquid-to-solid ratio of 10 mL/g,and a 40 kHz ultrasonic power of 400 W.In addition,the specific surface area of the petcoke particles increased from 0.7 to 301.49 m^(2)/g.After desulfurization,the pore size distribution of the petcoke particles was more concentrated on micropores compared with the samples prior to petcoke treatment.Reactive force field molecular dynamics simulation results indicated that HNO_(3) continuously oxidized the carbon atoms adjacent to sulfur atoms in the petcoke macromolecules and promoted sulfur removal from petcoke via the cleavage of C-S bonds.The sulfur transformation mechanism can be summarized as follows:thiophene sulfur→branched chain carbon sulfur→CO_(2)S→C_(2)O_(2)S→C_(2)O_(3)NS→C_(2)O_(4)S→CO_(2)S.
文摘Teachers voluntarily devote a lot of time to their vocational activates. This can lead to workaholism and may result in stress and job burnout. The main objective of the current study is to examine the relationship of workaholism with stress and job burnout of elementary school teachers in Zahedan. This is a descriptive-correlational study. The sample includes 350 elementary school teachers in Zahedan whom are selected through applying stratified random sampling method and are examined using questionnaires on workaholism, occupational stress, and job burnout. To analyze the obtained data, correlation coefficient and simultaneous multiple regression analysis are applied using SPSS21. Teachers’ mean scores on workaholism, stress and job burnout are higher than the considered theoretical mean. Workaholism and its components (feeling of being driven to work, work involvement, and work enjoyment) are significantly and positively related to job burnout and occupational stress (p ). The results of simultaneous multiple regression analysis indicate that components of workaholism can predict teachers’ occupational stress and job burnout (p ). Considering the results, holding training courses for teachers to become familiar with the phenomena of workaholism, stress, and job burnout, individual and organizational outcomes, methods of dealing with them and managing them effectively is highly recommended.
文摘This paper focuses on knowledge and attitudes of Grade 8 pupils about HIV/AIDS and opportunistic diseases. In particular, people need to know what it is, how it is transmitted, how to protect themselves from it, and how to relate to people with the disease. According to the National policy for HIV/AIDS, schools are key settings for educating children about HIV/AIDS and for halting further spread of the infection. It has been noticeable that Grade 8 pupils in the rural areas around Mthatha district are particularly at risk of getting HIV. The focus is often more on Grade 11 and 12 pupils, so female Grade 10 pupils look for boys for attention. This resulted for the female pupils to fall pregnant. The fact that some of them are falling pregnant means they are also more vulnerable to contracting HIV. This shows that little information is available for them and this paper is contributing to that body of knowledge. Prevention therefore is the most effective strategy to combat pregnancy and against the spread of HIV/AIDS in schools. Measures should be taken to remove the social, cultural and political barriers that might block access to HIV/AIDS services and programmes. The results showed that while some Grade 8 pupils are aware of HIV/AIDS, there are others who said it does not exist. It has also been highlighted that the phenomenon of pupils having unprotected sex with older men for money, as well as pupils saying they did not have time to use condoms. It is therefore recommended that pupils need to have role models, people they can look up to. In the absence of parents, it should be teachers＇ responsibility to advise the pupils and inform them about Sexually Transmitted Infections （STIs） and HIV/AIDS in schools.
基金Project (2014GB115000) supported by Key Project of ITER of Ministry of Science and Technology of ChinaProject supported by State Key Laboratory of Powder Metallurgy,Central South University,Changsha,China
文摘First principles calculation and quasi-harmonic Debye model were used to obtain more physical properties of zirconium carbide under high temperature and high pressure.The results show that the B1structure of ZrC is energetically more favorable with lower heat of formation than the B2structure,and that mechanical instability and positive heat of formation induce the inexistence of the B2structure at normal pressure.It is also found that the B1structure would transform to the B2structure under high pressure below the critical point of V/V0=0.570.In addition,various thermodynamic and elastic properties of ZrC are obtained within the temperature range of0-3000K and the pressure range of0-100GPa.The calculated results not only are discussed and understood in terms of electronic structures,but also agree well with corresponding experimental data in the literature.
文摘The aim of this study is to investigate the relationship between life orientation and cognitive emotion regulation with job stress. On this basis, a sample of 100 employees working in Guilan Education Office was used and research hypotheses were examined by job stress, life orientation and cognitive emotion regulation questionnaires. The results of this study indicate that job stress has a significant relationship with life orientation (-0.32), self-blame (0.25), rumination (-0.36), positive refocusing (0.25), positive refocusing on program (-0.21), positive reappraisal (-0.28), catastrophizing (-0.39) and other blames (-0.25). Furthermore, life orientation and cognitive regulation could explain 22% variances in respondents’ job stress. This finding indicates that more positive life orientation and subsequent decrease of emotion-regulation-related disorders will lead to less job stress.
文摘The present study aimed to examine the relationship of organizational intelligence with innovation management and career advancement in an organization. Considering its objective, this was a descriptive-correlational study. The statistical population included all high school managers in Zahedan at the year 2015. The sample contained 52 male managers and 51 female managers whom were selected through applying stratified random sampling method. To collect data, Organizational Intelligence Questionnaire, Innovation Management Inventory and Questionnaire of Career Advancement were used, the validity of which was assessed through applying the standpoint of a number of university professors and their reliability was obtained 0.74, 0.76, 0.84, respectively, using Cronbach’s alpha coefficient. Results indicated that considering managers’ perspectives, the status of organizational intelligence and career advancement were desirable;however, the status of innovation management was moderate. Moreover, organizational intelligence and its components were significantly and positively correlated with innovation management (r = 0.512, P < 0.01), and there was a significant and positive relationship between organizational intelligence and career advancement (r = 0.334, P < 0.01). Findings demonstrated that components of desire to change, spirit, unity and agreement, application of knowledge, performance pressure were significantly correlated to career advancement. However, components of strategic perspective and common fate were not significantly correlated with career advancement. Additionally, among the components of organizational intelligence, in the first step, application of knowledge and in the second step, desire to change were the best predicators of innovation management (which together could predict 28%). Application of knowledge was the only variable which entered the predictive model and predicted 16% of career advancement. Results of independent t-test indicated that no significant difference was found between male and female managers, considering their organizational intelligence, innovation management and career advancement.
文摘The present study aims to examine the effectiveness of the combination of solution-focused therapy and narrative therapy in marital adjustment of incompatible women. This research is a pretest-posttest quasi-experimental study design with a nonequivalent control group. The statistical population comprises all the incompatible women who referred to the counseling clinics of Neyshabour in May 2016 (1500 admission per month). The research sample consists of 24 incompatible women who were selected through Randomand available sampling method. For data collection, Marital Adjustment Scale by Spinner was applied. The data were analyzed using the analysis of covariance test and with the aid of SPSS-22 software. The findings demonstrated that the combination of solution-focused therapy and narrative therapy is significantly effective in marital adjustment of incompatible women (P < 0.05). Thus, it can be stated that the combination of solution-focused therapy and narrative therapy can help to promote adjustment among incompatible women.
文摘The main goal of this research was the scrutiny of relationship between students’ personality characteristics and mental health at the University of Guilan. The population was the students of the Faculty of Humanities in 2009 with 3000 which 196 were selected using Kerjeci & Morgan table and stratified sampling method. They answered to the NEO and GHQ questionnaires. Results showed that there was relationship between personality characteristic of neurotic, openness, extraversion and being conscionable with mental health. Meanwhile, openness had the highest and extraversion with the lowest correlation scale and most of students (65%) had low mental health. Also, there were no significant differences among students with respect to different courses but significant difference with respect to gender and age.
文摘This is an experimental study conducted on two groups of control and experimental using pretestposttest design, applying psychological intervention on the study sample. The present study aimed to determine the effectiveness of collective education life skills on mental health and resilience of teachers in Zahedan. The population of the study included all teachers at schools with normal students and teachers at schools with exceptional students in Zahedan, among which 60 teachers at normal schools and 20 teachers at exceptional schools were selected and placed in two groups of experimental and control, respectively. Initially, members of the experimental group were taught 10 basic life skills in 10 2-hour sessions. Mental health and resilience questionnaires were distributed and gathered before and after the training sessions. Results indicated the positive effect of life skills training on mental health of teachers at schools with normal students and teachers at schools with exceptional students, which meant that the more the life skills training to teachers at schools with normal students and teachers at schools with exceptional students, the lower their mental health scores would be. Results also indicated the positive effect of life skills training on resilience of teachers at schools with normal students and teachers at schools with exceptional students, which meant that the more the life skills training to teachers at schools with normal students and teachers at schools with exceptional students, the higher their resilience scores would be.
文摘Introduction: The present study sought to examine the effectiveness of quality of life therapy on increasing happiness among patients with major depression. Methods: The research followed an experimental research design with an experimental and a control group. To this end, among the statistical population of the study that consisted of all individuals with major depression disorder, 30 individuals were randomly selected and placed in two groups (experimental and control). The experimental group individually received an intervention with a trend based on quality of life improvement for 10 sessions. The control group received no such treatment. Beck’s Depression Inventory and Oxford Happiness Questionnaire were used in two occasions of pretest and posttest. Data analysis was performed using descriptive statistics and multivariate analysis of covariance. Results: The results revealed that quality of life therapy reduced depression and increased happiness among the subjects on the posttest (p < 0.01). Conclusion: This research found two important results. First, it was revealed that quality of life therapy had high efficiency in treating depression considered as a resistant disorder to treatment. Second, it was indicated that focus on happiness in the treatment of major depression disorder can significantly help?patients recover.
文摘This study aimed to increase the achievement level of college students on math by providing a high level of expectancy,value,interest,and motivation toward math.To be able to achieve this aim,action research was used instead of exploratory studies.Action research is a group of people’s identifying a problem,doing something to solve the problem,seeing how successful they were and if they weren’t satisfied by the results their retrying,and in short learning by doing and living.150 freshmen of a university in Turkey participated in the study.The researcher and a math teacher implemented to the study.Results of the study showed that students’negative beliefs and expectations can change if they get support.According to the beliefs and expectations,grades of students also change and improve since positive perception makes life positive.
文摘This paper reveals that the implementation of inclusive education is an unfinished challenge,both within the system and for individual self-improvement.This process of changing practices,by continually questioning the school’s responsibility for the(re)production of inequalities,exclusion,and unequal social relations,is riddled with obstacles,unpredictable situations,and strong emotions.In particular,the researchers point out that many systemic mechanisms of school culture contribute to replicating and reifying hierarchical school experiences and exacerbating processes of institutional discrimination against immigrant backgrounds and/or racialized students.The empirical research presented also highlights the school staff’s deficit thinking toward immigrant students and their parents.The results show that staff tend to use linguistic and cultural gaps between students and the school system to explain academic failure.Be that as it may,the researchers as well as the school actors and students interviewed in this paper suggest multiple ways to improve inclusion in the school context,stressing the importance of giving voice to the various actors in order to move toward institutional transformation.
基金Project(52174338)supported by the National Natural Science Foundation of ChinaProjects(2022JJ20086,2021JJ30796)supported by the Natural Science Foundation of Hunan Province,China+1 种基金Project(2023CXQD005)supported by the Central South University Innovation-Driven Research Programme,ChinaProject(23B0841)supported by the Education Department of Hunan Provincial Government,China。
文摘Single-atom catalysts(SACs)are promising for oxygen reduction reaction(ORR)on account of their excellent catalytic activity and maximum utilization of atoms.However,due to the complicated preparation processes and expensive reagents used,the cost of SACs is usually too high to put into practical application.The development of cost-effective and sustainable SACs remains a great challenge.Herein,a low-cost method employing biomass is designed to prepare efficient single-atom Fe-N-C catalysts(SA-Fe-N-C).Benefiting from the confinement effect of porous carbon support and the coordination effect of glucose,SA-Fe-N-C is derived from cheap flour by the two-step pyrolysis.Atomically dispersed Fe atoms exist in the form of Fe-N_(x),which acts as active sites for ORR.The catalyst shows outstanding activity with a half-wave potential(E_(1/2))of 0.86 V,which is better than that of Pt/C(0.84 V).Additionally,the catalyst also exhibits superior stability.The ORR catalyzed by SA-Fe-N-C proceeds via an efficient 4e transfer pathway.The high performance of SA-Fe-N-C also benefits from its porous structure,extremely high specific surface area(1450.1 m^(2)/g),and abundant micropores,which are conducive to increasing the density of active sites and fully exposing them.This work provides a cost-effective strategy to synthesize SACs from cheap biomass,achieving a balance between performance and cost.
基金the Specialized Research Program Fundthe Doctoral Program of Higher Education of China (20050007023)the Natural Science Foundation of Shandong Province(Y2004G04)
文摘In Chinese question answering system, because there is more semantic relation in questions than that in query words, the precision can be improved by expanding query while using natural language questions to retrieve documents. This paper proposes a new approach to query expansion based on semantics and statistics Firstly automatic relevance feedback method is used to generate a candidate expansion word set. Then the expanded query words are selected from the set based on the semantic similarity and seman- tic relevancy between the candidate words and the original words. Experiments show the new approach is effective for Web retrieval and out-performs the conventional expansion approaches.
文摘Objectives: The purpose of this study is to analyse the practical implementation of regional and na-tional policies through the Protocol of Care of Children and Adolescents in School (2010) in Extremadura Region (Spain), and to compare its contents with the international standards of diabetes care at school defined by American Diabetes Association and International Diabetes Federation. The measures not only affect the security and diabetes care, but also inclusion and the right to health. Methods: A documental comparative analysis between the local and international standards about diabetes care in school setting is carried out. This analysis is framed in a larger project focused on the study of health promoting school and diabetes education, in which perceptions of children and adolescents with diabetes, their parents and school staff were studied. Results: The Protocol of Care of Children and Adolescents in School (2010) contains some international recommendations about the care of T1DM at school, but in other cases the measures are non-specific. The distribution of responsibilities for care at school is unclear and no monitoring and evaluation indicators are defined. Some elements are identified to be implemented in the tool to favour the security, management of T1DM care and wellbeing. In general, these elements refer to school plan for diabetes care, school organization and teachers, and school community training. Conclusion: It is required to develop specific policies and decisive action to ensure the right to health of children with diabetes and the full application of international standards for diabetes care at school.
