CO_(2)reduction under simulated sunlight over photocatalysts has become an attractive researcher area recently.In this work,carbon nitride compounds modified by TiO_(2)nanoparticles(TNPs)have been used for the photore...CO_(2)reduction under simulated sunlight over photocatalysts has become an attractive researcher area recently.In this work,carbon nitride compounds modified by TiO_(2)nanoparticles(TNPs)have been used for the photoreduction of CO_(2)in the presence of CH_(4)at room temperature.Briefly,a series of noble-metal-free TNP-graphitic-carbon nitride(g-C_(3)N_(4),also abbreviated CN)photocatalysts with different TNPs loadings and calcination temperatures have been synthesized by a wet-chemical method.The characterization results of XRD,FTIR,SEM,TEM,BET,XPS,CO_(2)Adsorption,UV-vis,and PL demonstrate that the BET surface area and CO_(2)adsorption capacity have been improved after the calcination.Besides,the g-C_(3)N_(4)has been successfully coupled with the TNPs and a heterojunction has formed at their interface.These characters contribute to increase the photocatalytic activity of TNPs-CN toward reducing CO_(2)in the presence of CH_(4),and its'performance is better than bare g-C_(3)N_(4),Titania(P_(25))-CN,MgO-CN,or Cu_(2)O-CN.Orthogonal experiments are then carried out to investigate the sensitivity factors and optimum conditions.The sensitivity results show that the reaction pressure makes little difference on the photocatalysis results,which verifies the photoinduced CO_(2)-CH_(4)reaction has a tiny change in gas volume.In addition,under the optimum conditions,the turnover frequency(TOF)of CO after 4 h reaction can reach 9.98μmol g-cat.^(-1)h^(-1),and traces of ethane and ethylene have been detected during the reactions.In addition,surface acetate and carbonaceous deposit are found on the(20)TNPs-CN/450 surface after continuous 24 h irradiation under the optimum conditions,which resulting in the inactivation of the catalyst.Finally,possible reaction mechanisms have been proposed based on the results.展开更多
The objectives of this study are to determine the settlement and leachate generation from landfill lysimeters of municipal solid waste. Two identical lysimeters with a diameter and height of 0.70 m and 2.40 m were pre...The objectives of this study are to determine the settlement and leachate generation from landfill lysimeters of municipal solid waste. Two identical lysimeters with a diameter and height of 0.70 m and 2.40 m were prepared, respectively. The lysimeters were operated with and without leachate recirculation treatment. The settlement and leachate generation were quantified daily. The analysis of settlement was conducted by using hyperbolic function and curve fitting. Based on the experiments result, it is observed that garbage pile settlement in lysimeter treated with leachate recirculation （L-2） is higher than without recirculation treatment （L-1） as showed by the hyperbolic function and curve fitting result. The ultimate settlement （S_wlt） for L-1 and L-2 that used hyperbolic function were 0.487 m and 0.53 m, respectively. Meanwhile （S_wlt） that using curve fitting resulted 0.74 m, and 0.68 m for L-1 and L-2, respectively. The lysimeter which treated with leachate recirculation treatment showed a higher leachate height than without the treatment.展开更多
基金financial support from the National Natural Science Foundation of China(21536003,21938002 and 21776065)Natural Science Foundation of Hunan Province in China(2019JJ20006)。
文摘CO_(2)reduction under simulated sunlight over photocatalysts has become an attractive researcher area recently.In this work,carbon nitride compounds modified by TiO_(2)nanoparticles(TNPs)have been used for the photoreduction of CO_(2)in the presence of CH_(4)at room temperature.Briefly,a series of noble-metal-free TNP-graphitic-carbon nitride(g-C_(3)N_(4),also abbreviated CN)photocatalysts with different TNPs loadings and calcination temperatures have been synthesized by a wet-chemical method.The characterization results of XRD,FTIR,SEM,TEM,BET,XPS,CO_(2)Adsorption,UV-vis,and PL demonstrate that the BET surface area and CO_(2)adsorption capacity have been improved after the calcination.Besides,the g-C_(3)N_(4)has been successfully coupled with the TNPs and a heterojunction has formed at their interface.These characters contribute to increase the photocatalytic activity of TNPs-CN toward reducing CO_(2)in the presence of CH_(4),and its'performance is better than bare g-C_(3)N_(4),Titania(P_(25))-CN,MgO-CN,or Cu_(2)O-CN.Orthogonal experiments are then carried out to investigate the sensitivity factors and optimum conditions.The sensitivity results show that the reaction pressure makes little difference on the photocatalysis results,which verifies the photoinduced CO_(2)-CH_(4)reaction has a tiny change in gas volume.In addition,under the optimum conditions,the turnover frequency(TOF)of CO after 4 h reaction can reach 9.98μmol g-cat.^(-1)h^(-1),and traces of ethane and ethylene have been detected during the reactions.In addition,surface acetate and carbonaceous deposit are found on the(20)TNPs-CN/450 surface after continuous 24 h irradiation under the optimum conditions,which resulting in the inactivation of the catalyst.Finally,possible reaction mechanisms have been proposed based on the results.
文摘The objectives of this study are to determine the settlement and leachate generation from landfill lysimeters of municipal solid waste. Two identical lysimeters with a diameter and height of 0.70 m and 2.40 m were prepared, respectively. The lysimeters were operated with and without leachate recirculation treatment. The settlement and leachate generation were quantified daily. The analysis of settlement was conducted by using hyperbolic function and curve fitting. Based on the experiments result, it is observed that garbage pile settlement in lysimeter treated with leachate recirculation （L-2） is higher than without recirculation treatment （L-1） as showed by the hyperbolic function and curve fitting result. The ultimate settlement （S_wlt） for L-1 and L-2 that used hyperbolic function were 0.487 m and 0.53 m, respectively. Meanwhile （S_wlt） that using curve fitting resulted 0.74 m, and 0.68 m for L-1 and L-2, respectively. The lysimeter which treated with leachate recirculation treatment showed a higher leachate height than without the treatment.
