Collision-induced re-laxation process of CH(X^(2)Π,v=0)radical in various bath gases He,Ar,and N_(2)has been investigated ex-perimentally under low-temperature(26-52 K)supersonic flow conditions.The CH radicals were ...Collision-induced re-laxation process of CH(X^(2)Π,v=0)radical in various bath gases He,Ar,and N_(2)has been investigated ex-perimentally under low-temperature(26-52 K)supersonic flow conditions.The CH radicals were generat-ed with internal excitation by multiphoton photolysis of CHBr_(3)at 248 nm,and its rotational temperature was found to relax to the flow temperature in a few microseconds by colliding with bath gas.The relaxation rate coefficients for CH(X^(2)Π,v=0)radical in He,Ar,and N_(2)flow were obtained by time-resolved laser-induced fluorescence measurements,ranging from 10^(-12)cm^(3)·molecule^(-1)·s^(-1)to 10^(-11)cm^(3)·molecule^(-1)·s^(-1).The N_(2)flow exhibits the highest relax-ation rate for CH(X^(2)Π)radical due to its additional rovibrational levels,which allow for more efficient energy dissipation during collisions compared to monoatomic gases.The Ar flow shows a larger relaxation rate than He flow due to its greater polarizability and stronger long-range interaction with the CH(X^(2)Π)radical.展开更多
It is highly challenging to precisely compare the impacts of anthropogenic pollutants on the photooxidation of isomeric volatile organic compounds with respect to molecular compositions and particle number/mass concen...It is highly challenging to precisely compare the impacts of anthropogenic pollutants on the photooxidation of isomeric volatile organic compounds with respect to molecular compositions and particle number/mass concentrations of secondary organic aerosols(SOAs).In this study,we conducted a series of well-defined indoor chamber experiments to compare the effects of NO_(x)(NO and NO_(2))on the photooxidation of isomeric monoterpenes ofβ-pinene and limonene.For the photooxidation ofβ-pinene with NO_(x),the increase of the initial concentrations of NO([NO]_(0))shows a monotonous suppression of the particle mass concentration,whereas the increase of[NO_(2)]_(0) shows a monotonous enhancement of the particle mass concentration.For the photooxidation of limonene with NO_(x),the increase of[NO]_(0) exhibits a monotonous suppression of the particle mass concentration,whereas the increase of[NO_(2)]_(0) shows a parabolic trend of the particle mass concentration.Utilizing a newly developed vacuum ultraviolet free electron laser(VUV-FEL),the online threshold photoionization mass spectrometry reveals a series of novel compounds at molecular weight(MW)=232 and 306 for theβ-pinene+NO_(x) system and MW=187,261,280,and 306 for the limonene+NO_(x) system.The molecular structures and formation pathways of these species were inferred,which led to the prediction of the diversity and difference of SOA products(i.e.,ester and peroxide accretion products)formed from different monoterpene precursors.To improve the predictions of future air quality,it is recommended that climate models should incorporate the NO_(x)-driven diurnal photooxidation of monoterpenes for SOA formation mechanisms.展开更多
Histidine(His),as the most chemically active and versatile member among the 20 natural amino acids,plays a key role in the coordination of copper(II)(Cu(II))in biological systems.Cu(II)-His species are ubiquitous in m...Histidine(His),as the most chemically active and versatile member among the 20 natural amino acids,plays a key role in the coordination of copper(II)(Cu(II))in biological systems.Cu(II)-His species are ubiquitous in metalloenzymes and proteins associated with various neurodegenerative diseases,where they regulate catalytic activity and mediate intracellular copper transport.While the steric influence of His is known to dictate donor group selection in Cu(II)coordination,the extent of these constraints on peptide complexes remains unclear.In this study,we employed a multi-spectroscopic approach(FTIR,2D IR,UV-Vis,EPR,and NMR)to systematically investigate pH-dependent Cu(II)coordination in three tripeptides.Our results demonstrate that Cu(II)coordination geometries are cooperatively determined by both the protonation state of the N-terminus and the steric constraints imposed by the His residue.展开更多
We investigate the influence of Doppler broadening on absorption-dispersion properties in a four-level atomic system that can evolve from a normal dispersion to an anomalous dispersion. Our results show that the absor...We investigate the influence of Doppler broadening on absorption-dispersion properties in a four-level atomic system that can evolve from a normal dispersion to an anomalous dispersion. Our results show that the absorption-dispersion properties become strongly dependent on the propagation directions of the applied fields if Doppler broadening is taken into account. Especially, the switchover in the sign of the dispersion is still achievable even in the presence of Doppler broadening if properly arranging the propagation directions of the applied fields, which is in contrast with the otherwise behaviours in some other configurations.展开更多
Two different poling techniques-corona poling and contact poling in the backdrop of electro-optic （EO） polymer modulators are compared. A 3-layer structure EO polymer modulator is prepared for the poling. The poling...Two different poling techniques-corona poling and contact poling in the backdrop of electro-optic （EO） polymer modulators are compared. A 3-layer structure EO polymer modulator is prepared for the poling. The poling setups and procedures of these two different methods are given. It is found that a well-controlled precure step is very critical, otherwise it will result in either lower poling efficiency or damaged film. Experimental results show that contact poling does not create severe surface damage as corona poling and poling voltage is much lower, but corona poling provides higher EO effect than contact poling. Besides, contact poling can provide poling size as large as the substrate size.展开更多
This paper reports that the ultraviolet and visible upconversion luminescence from the ^4S3/2, ^2G9/2 and ^2P3/2 levels have been observed in Er^3＋：YAG following 647.2 nm excitation of the ^4F9/2 multiple. Upconvers...This paper reports that the ultraviolet and visible upconversion luminescence from the ^4S3/2, ^2G9/2 and ^2P3/2 levels have been observed in Er^3＋：YAG following 647.2 nm excitation of the ^4F9/2 multiple. Upconversion luminescence intensity dependence on pump power was recorded. The measured decay profiles were theoretically fitted by kinetics theory and the basically good agreements were achieved. The results indicate that some energy transfer processes proposed to explain the observed upconversion phenomena are reasonable.展开更多
A four-level atomic system with a closed interaction loop connected by two coherent driving fields and a microwave field is investigated. The results show that inversionless gain can be achieved on a higher frequency ...A four-level atomic system with a closed interaction loop connected by two coherent driving fields and a microwave field is investigated. The results show that inversionless gain can be achieved on a higher frequency transition outside the closed interaction loop, and the gain behaviour can be modulated by the phase of the closed loop as well as the amplitude of the microwave field. The phase sensitivity property in such a scheme is similar to that in an analogous configuration with spontaneously generated coherence, but it is beyond the rigorous condition of near-degenerate levels with non-orthogonal dipole moments. Therefore this scheme is much more convenient in experimental realization.展开更多
The stratospheric worm pools, called the 4-day wave also, are mainly the temperature anomalies in the polar regions of winter hemisphere. It will be shown that their occurrence, propagation speed and specific structur...The stratospheric worm pools, called the 4-day wave also, are mainly the temperature anomalies in the polar regions of winter hemisphere. It will be shown that their occurrence, propagation speed and specific structure can be explained by the lower frequency coherent heating resulting from the wave interaction in the breaking layers of the stratosphere. Although their vertical phase slope is negligibly small, the warm pools cannot be considered as a barotropic anomaly.展开更多
In the new era of railways, infrastructure, trains and travelers will be interconnected. In order to realize a seamless high-data rate wireless connectivity, up to dozens of GHz bandwidth is required. This motivates t...In the new era of railways, infrastructure, trains and travelers will be interconnected. In order to realize a seamless high-data rate wireless connectivity, up to dozens of GHz bandwidth is required. This motivates the exploration of the underutilized millimeter wave （mmWave） as well as the largely unexplored THz band. In this paper, we first identify relevant communication scenarios for railway applications. Then the specific challenges and estimates of the bandwidth requirements for high-data rate railway connec-tivity in these communication scenarios are described. Finally, we outline the major challenges on propagation channel modeling and provide a technical route for further studies.展开更多
Features of structure and propagation of the 30 to SO day atmospheric oscillations are investigated using the ECMWF analysis of 1980-1983. Evidence is provided to confirm the characteristics of the oscillation in the ...Features of structure and propagation of the 30 to SO day atmospheric oscillations are investigated using the ECMWF analysis of 1980-1983. Evidence is provided to confirm the characteristics of the oscillation in the equatorial region. Those in the mid-high latitudes, however, are revealed to be very different from the tropics and pose a strong barotropic structure. Horizontal coherence shows teleconnection patterns which can be identified as EAP and PNA. The wind field of the specified time scale of the oscillation appears as long-lived vortices and vortex pairs. Mid-latitude perturbations propagate clearly westwards, especially during the winter season. In the high latitudes, they propagate westwards in the winter but eastwards in the summer. Meridional propagations are rather different from region to region.展开更多
We present a theoretical study of an optical cavity coupled with single four-level atoms in closed loop formed via applied control lasers. The transmitted probe field from the cavity is analyzed. We show that the elec...We present a theoretical study of an optical cavity coupled with single four-level atoms in closed loop formed via applied control lasers. The transmitted probe field from the cavity is analyzed. We show that the electromagnetically induced transparency（EIT） in the cavity and the normal mode splitting will be very different with changing the closed interaction phase and the intensity of the free-space control laser. This coupled cavity-atom system presents a variational double-EIT that comes from modulating the splitting of the dark state, which means that we could realize the gradual transfer between one EIT peak and two EIT peaks by adjusting the applied control lasers, and the normal mode splitting sidebands will shift slightly by changing the free-space control laser. This means that we could control the output cavity probe field more freely and it is easer to realize optical switch controlled by more parameters. We also depict the angular dispersion of the intracavity probe field in different free-space control laser. The large phase shift（-π → π） of the reflected intracavity probe field will be very useful for optical temporal differentiation and quantum phase gate.展开更多
The violet and green fluorescence spectra and the kinetics of fluorescence decay in Er^3＋ ：YAG crystal under 408.6 nm excitation were investigated by the time-resolved laser-induced fluorescence technique. The influ...The violet and green fluorescence spectra and the kinetics of fluorescence decay in Er^3＋ ：YAG crystal under 408.6 nm excitation were investigated by the time-resolved laser-induced fluorescence technique. The influence of multiphonon and energy transfer on the fluorescence decay of the ^4S3/2 rnultiplet were theoretically analyzed. A good agreement of the measured and the simulated decay curves was achieved. The continuous profile variety of the decay curves in the region from 548 to 561.2 nrn is found and it originates from the fluorescence overlap of ^2G9/2 and ^4S3/2 and the intensity ratio dominates the profile.展开更多
Natural radiative lifetimes of five higher-lying odd-parity levels 5pTs ^3P1^0, 5p5d 1P1^0, 5p6d 3F2^0, 3D1^0 and 3F3^0 in neutral tin are measured by the time-resolved laser-induced fluorescence （TR-LIF） technique ...Natural radiative lifetimes of five higher-lying odd-parity levels 5pTs ^3P1^0, 5p5d 1P1^0, 5p6d 3F2^0, 3D1^0 and 3F3^0 in neutral tin are measured by the time-resolved laser-induced fluorescence （TR-LIF） technique and the atomic beam method. All these lifetimes are not longer than 100 ns and they are found to be shorter than the lifetimes of evenparity levels in the same energy region. The results reported in this paper provide important transition parameters for highly-excited atomic Sn, which may be useful for theoretically calculating excited heavy atoms.展开更多
A theoretical model to simulate an end-pumped CW Nd^3＋：GdVO4 laser at 1063 nm is presented. Its essence is to use the propagation equations to demonstrate the spatial evolutions of the pump and the laser powers in t...A theoretical model to simulate an end-pumped CW Nd^3＋：GdVO4 laser at 1063 nm is presented. Its essence is to use the propagation equations to demonstrate the spatial evolutions of the pump and the laser powers in the cavity, hence it is applicable to both low and high gain lasers. The simulation results obtained by this model are in good agreement with the experimental observations reported in the literature for a Ti：sapphlre-pumped Nd^3＋：GdVO4 laser. Moreover, some parameters, such as the reflectivity of output coupler, the spot size of laser beam and the crystal length, are discussed with a view to optimizing the laser performance.展开更多
The luminescence of Er^3＋：YAlO3 in ultraviolet visible and infrared ranges under the 518 nm excitation of the multiples ^2H11/2 have been investigated. Ultraviolet （275 nm and 318 nm）, violet （405 nm and 413 nm）...The luminescence of Er^3＋：YAlO3 in ultraviolet visible and infrared ranges under the 518 nm excitation of the multiples ^2H11/2 have been investigated. Ultraviolet （275 nm and 318 nm）, violet （405 nm and 413 nm） and blue （474 nm） upconversion and infrared downconversion luminescence has been observed. By means of measuring the fluorescence decay curves and using the theory of rate equations, the luminescence kinetics was studied in detail and the processes of energy transfer upconversion （ETU） and excitation state absorption （ESA） were proposed to explain the upconversion phenomena.展开更多
This paper analyzes the energy levels along the even-parity J = 1 and 2 Rydberg series of Sn I by multichannel quantum defect theory. A good agreement between theoretical and experimental energy levels was achieved. B...This paper analyzes the energy levels along the even-parity J = 1 and 2 Rydberg series of Sn I by multichannel quantum defect theory. A good agreement between theoretical and experimental energy levels was achieved. Below 59198 cm^-1, a total of 85 and 23 new energy levels, respectively, in the J = 1 and J = 2 series, which cannot be measured previously by experiments, are predicted in this work. Based on the calculated admixture coefficients of each channel, interchannel interactions were discussed in detail. The results are helpful to understand the characteristics of configuration interaction among even-parity levels in Sn I.展开更多
One piece of single-mode silica fibre is used to study of temperature characteristics of stimulated Raman scattering （SRS）, additional peaks （double-humped） are observed at both sides of pump light and 1 St-order ...One piece of single-mode silica fibre is used to study of temperature characteristics of stimulated Raman scattering （SRS）, additional peaks （double-humped） are observed at both sides of pump light and 1 St-order Stokes light in the experiment. The frequency shift of the double-humped is calculated by stimulated Four-Photon mixing （SFPM） phase matching theory, the result is consistent with the frequency shift of this experiment. Simultaneously, the experimental conditions accord with the theoretical calculation of effective coherence length. We indicate that the double-bumped phenomenon is caused by SFPM. The intensity of double-humped is first increased, then decreased and finally disappeared as the temperature increases. This phenomenon has been explained theoretically.展开更多
基金supported by the National Natural Science Foundation of China(No.22273103)the National Natural Science Foundation of China(NSFC Center for Chemical Dynamics)(No.22288201)+1 种基金Dalian Institute of Chemical Physics(DICP I202230)the Scientific Instrument Developing Project of the Chinese Academy of Sciences(grant GJJSTD20220001)。
文摘Collision-induced re-laxation process of CH(X^(2)Π,v=0)radical in various bath gases He,Ar,and N_(2)has been investigated ex-perimentally under low-temperature(26-52 K)supersonic flow conditions.The CH radicals were generat-ed with internal excitation by multiphoton photolysis of CHBr_(3)at 248 nm,and its rotational temperature was found to relax to the flow temperature in a few microseconds by colliding with bath gas.The relaxation rate coefficients for CH(X^(2)Π,v=0)radical in He,Ar,and N_(2)flow were obtained by time-resolved laser-induced fluorescence measurements,ranging from 10^(-12)cm^(3)·molecule^(-1)·s^(-1)to 10^(-11)cm^(3)·molecule^(-1)·s^(-1).The N_(2)flow exhibits the highest relax-ation rate for CH(X^(2)Π)radical due to its additional rovibrational levels,which allow for more efficient energy dissipation during collisions compared to monoatomic gases.The Ar flow shows a larger relaxation rate than He flow due to its greater polarizability and stronger long-range interaction with the CH(X^(2)Π)radical.
基金supported by the National Natural Science Foundation of China(Nos.22125303,92361302,92061203,22103082,22273101,22288201,and 21327901)the National Key Research and Development Program of China(No.2021YFA1400501)+3 种基金the Innovation Program for Quantum Science and Technology(No.2021ZD0303304)Dalian Institute of Chemical Physics(No.DICPI202437)Chinese Academy of Sciences(No.GJJSTD20220001)the International Partnership Program of CAS(No.121421KYSB20170012)。
文摘It is highly challenging to precisely compare the impacts of anthropogenic pollutants on the photooxidation of isomeric volatile organic compounds with respect to molecular compositions and particle number/mass concentrations of secondary organic aerosols(SOAs).In this study,we conducted a series of well-defined indoor chamber experiments to compare the effects of NO_(x)(NO and NO_(2))on the photooxidation of isomeric monoterpenes ofβ-pinene and limonene.For the photooxidation ofβ-pinene with NO_(x),the increase of the initial concentrations of NO([NO]_(0))shows a monotonous suppression of the particle mass concentration,whereas the increase of[NO_(2)]_(0) shows a monotonous enhancement of the particle mass concentration.For the photooxidation of limonene with NO_(x),the increase of[NO]_(0) exhibits a monotonous suppression of the particle mass concentration,whereas the increase of[NO_(2)]_(0) shows a parabolic trend of the particle mass concentration.Utilizing a newly developed vacuum ultraviolet free electron laser(VUV-FEL),the online threshold photoionization mass spectrometry reveals a series of novel compounds at molecular weight(MW)=232 and 306 for theβ-pinene+NO_(x) system and MW=187,261,280,and 306 for the limonene+NO_(x) system.The molecular structures and formation pathways of these species were inferred,which led to the prediction of the diversity and difference of SOA products(i.e.,ester and peroxide accretion products)formed from different monoterpene precursors.To improve the predictions of future air quality,it is recommended that climate models should incorporate the NO_(x)-driven diurnal photooxidation of monoterpenes for SOA formation mechanisms.
基金supported by the National Natural Science Foundation of China(No.22403012 to Chunyang Wang,Wenzhe Zhou,and Xin-Xing Zhang,Nos.22241304 and 22225303 to Kaijun Yuan)the Strategic Priority Research Program of the Chinese Academy of Sciences(Nos.XDB0970000 and XDB0970200).
文摘Histidine(His),as the most chemically active and versatile member among the 20 natural amino acids,plays a key role in the coordination of copper(II)(Cu(II))in biological systems.Cu(II)-His species are ubiquitous in metalloenzymes and proteins associated with various neurodegenerative diseases,where they regulate catalytic activity and mediate intracellular copper transport.While the steric influence of His is known to dictate donor group selection in Cu(II)coordination,the extent of these constraints on peptide complexes remains unclear.In this study,we employed a multi-spectroscopic approach(FTIR,2D IR,UV-Vis,EPR,and NMR)to systematically investigate pH-dependent Cu(II)coordination in three tripeptides.Our results demonstrate that Cu(II)coordination geometries are cooperatively determined by both the protonation state of the N-terminus and the steric constraints imposed by the His residue.
文摘We investigate the influence of Doppler broadening on absorption-dispersion properties in a four-level atomic system that can evolve from a normal dispersion to an anomalous dispersion. Our results show that the absorption-dispersion properties become strongly dependent on the propagation directions of the applied fields if Doppler broadening is taken into account. Especially, the switchover in the sign of the dispersion is still achievable even in the presence of Doppler broadening if properly arranging the propagation directions of the applied fields, which is in contrast with the otherwise behaviours in some other configurations.
文摘Two different poling techniques-corona poling and contact poling in the backdrop of electro-optic （EO） polymer modulators are compared. A 3-layer structure EO polymer modulator is prepared for the poling. The poling setups and procedures of these two different methods are given. It is found that a well-controlled precure step is very critical, otherwise it will result in either lower poling efficiency or damaged film. Experimental results show that contact poling does not create severe surface damage as corona poling and poling voltage is much lower, but corona poling provides higher EO effect than contact poling. Besides, contact poling can provide poling size as large as the substrate size.
基金Project supported by the National Natural Science Foundation of China （Grant No 10074020）.Acknowledgement The authors would like to thank Professor Siyuan Zhang for providing Er^3＋：YAG crystal.
文摘This paper reports that the ultraviolet and visible upconversion luminescence from the ^4S3/2, ^2G9/2 and ^2P3/2 levels have been observed in Er^3＋：YAG following 647.2 nm excitation of the ^4F9/2 multiple. Upconversion luminescence intensity dependence on pump power was recorded. The measured decay profiles were theoretically fitted by kinetics theory and the basically good agreements were achieved. The results indicate that some energy transfer processes proposed to explain the observed upconversion phenomena are reasonable.
基金Project supported by the Natural Science Foundation of Guangdong Province （Grant No 05301018）, the Research and Development Fund of Shenzhen University, China （Grant No 200549）, and the National Natural Science Foundation of China （Grant Nos 10334010 and 10404009）.
文摘A four-level atomic system with a closed interaction loop connected by two coherent driving fields and a microwave field is investigated. The results show that inversionless gain can be achieved on a higher frequency transition outside the closed interaction loop, and the gain behaviour can be modulated by the phase of the closed loop as well as the amplitude of the microwave field. The phase sensitivity property in such a scheme is similar to that in an analogous configuration with spontaneously generated coherence, but it is beyond the rigorous condition of near-degenerate levels with non-orthogonal dipole moments. Therefore this scheme is much more convenient in experimental realization.
文摘The stratospheric worm pools, called the 4-day wave also, are mainly the temperature anomalies in the polar regions of winter hemisphere. It will be shown that their occurrence, propagation speed and specific structure can be explained by the lower frequency coherent heating resulting from the wave interaction in the breaking layers of the stratosphere. Although their vertical phase slope is negligibly small, the warm pools cannot be considered as a barotropic anomaly.
文摘In the new era of railways, infrastructure, trains and travelers will be interconnected. In order to realize a seamless high-data rate wireless connectivity, up to dozens of GHz bandwidth is required. This motivates the exploration of the underutilized millimeter wave （mmWave） as well as the largely unexplored THz band. In this paper, we first identify relevant communication scenarios for railway applications. Then the specific challenges and estimates of the bandwidth requirements for high-data rate railway connec-tivity in these communication scenarios are described. Finally, we outline the major challenges on propagation channel modeling and provide a technical route for further studies.
文摘Features of structure and propagation of the 30 to SO day atmospheric oscillations are investigated using the ECMWF analysis of 1980-1983. Evidence is provided to confirm the characteristics of the oscillation in the equatorial region. Those in the mid-high latitudes, however, are revealed to be very different from the tropics and pose a strong barotropic structure. Horizontal coherence shows teleconnection patterns which can be identified as EAP and PNA. The wind field of the specified time scale of the oscillation appears as long-lived vortices and vortex pairs. Mid-latitude perturbations propagate clearly westwards, especially during the winter season. In the high latitudes, they propagate westwards in the winter but eastwards in the summer. Meridional propagations are rather different from region to region.
基金Project supported by the National Natural Science Foundation of China(Grant No.11174109)
文摘We present a theoretical study of an optical cavity coupled with single four-level atoms in closed loop formed via applied control lasers. The transmitted probe field from the cavity is analyzed. We show that the electromagnetically induced transparency（EIT） in the cavity and the normal mode splitting will be very different with changing the closed interaction phase and the intensity of the free-space control laser. This coupled cavity-atom system presents a variational double-EIT that comes from modulating the splitting of the dark state, which means that we could realize the gradual transfer between one EIT peak and two EIT peaks by adjusting the applied control lasers, and the normal mode splitting sidebands will shift slightly by changing the free-space control laser. This means that we could control the output cavity probe field more freely and it is easer to realize optical switch controlled by more parameters. We also depict the angular dispersion of the intracavity probe field in different free-space control laser. The large phase shift（-π → π） of the reflected intracavity probe field will be very useful for optical temporal differentiation and quantum phase gate.
基金Project supported bythe National Natural Science Foundation of China (10074020)
文摘The violet and green fluorescence spectra and the kinetics of fluorescence decay in Er^3＋ ：YAG crystal under 408.6 nm excitation were investigated by the time-resolved laser-induced fluorescence technique. The influence of multiphonon and energy transfer on the fluorescence decay of the ^4S3/2 rnultiplet were theoretically analyzed. A good agreement of the measured and the simulated decay curves was achieved. The continuous profile variety of the decay curves in the region from 548 to 561.2 nrn is found and it originates from the fluorescence overlap of ^2G9/2 and ^4S3/2 and the intensity ratio dominates the profile.
基金supported by the National Natural Science Foundation of China (Grant No 10574056)the program for New Century Excellent Talents in University,China (Grant No NCET-05-0302)
文摘Natural radiative lifetimes of five higher-lying odd-parity levels 5pTs ^3P1^0, 5p5d 1P1^0, 5p6d 3F2^0, 3D1^0 and 3F3^0 in neutral tin are measured by the time-resolved laser-induced fluorescence （TR-LIF） technique and the atomic beam method. All these lifetimes are not longer than 100 ns and they are found to be shorter than the lifetimes of evenparity levels in the same energy region. The results reported in this paper provide important transition parameters for highly-excited atomic Sn, which may be useful for theoretically calculating excited heavy atoms.
基金supported by the National Natural Science Foundation of China (Grant No 10104009)
文摘A theoretical model to simulate an end-pumped CW Nd^3＋：GdVO4 laser at 1063 nm is presented. Its essence is to use the propagation equations to demonstrate the spatial evolutions of the pump and the laser powers in the cavity, hence it is applicable to both low and high gain lasers. The simulation results obtained by this model are in good agreement with the experimental observations reported in the literature for a Ti：sapphlre-pumped Nd^3＋：GdVO4 laser. Moreover, some parameters, such as the reflectivity of output coupler, the spot size of laser beam and the crystal length, are discussed with a view to optimizing the laser performance.
基金Project supported by the National Natural Science Foundation of China （Grant No 10074020）.
文摘The luminescence of Er^3＋：YAlO3 in ultraviolet visible and infrared ranges under the 518 nm excitation of the multiples ^2H11/2 have been investigated. Ultraviolet （275 nm and 318 nm）, violet （405 nm and 413 nm） and blue （474 nm） upconversion and infrared downconversion luminescence has been observed. By means of measuring the fluorescence decay curves and using the theory of rate equations, the luminescence kinetics was studied in detail and the processes of energy transfer upconversion （ETU） and excitation state absorption （ESA） were proposed to explain the upconversion phenomena.
基金Project supported by the National Natural Science Foundation of China (Grant No 10574056)the Program for New Century Excellent Talents in University (China)
文摘This paper analyzes the energy levels along the even-parity J = 1 and 2 Rydberg series of Sn I by multichannel quantum defect theory. A good agreement between theoretical and experimental energy levels was achieved. Below 59198 cm^-1, a total of 85 and 23 new energy levels, respectively, in the J = 1 and J = 2 series, which cannot be measured previously by experiments, are predicted in this work. Based on the calculated admixture coefficients of each channel, interchannel interactions were discussed in detail. The results are helpful to understand the characteristics of configuration interaction among even-parity levels in Sn I.
基金Supported by the National Natural Science Foundation of China under Grant No 10774057.
文摘One piece of single-mode silica fibre is used to study of temperature characteristics of stimulated Raman scattering （SRS）, additional peaks （double-humped） are observed at both sides of pump light and 1 St-order Stokes light in the experiment. The frequency shift of the double-humped is calculated by stimulated Four-Photon mixing （SFPM） phase matching theory, the result is consistent with the frequency shift of this experiment. Simultaneously, the experimental conditions accord with the theoretical calculation of effective coherence length. We indicate that the double-bumped phenomenon is caused by SFPM. The intensity of double-humped is first increased, then decreased and finally disappeared as the temperature increases. This phenomenon has been explained theoretically.
