Visualization of complex geological structures can technically support the accurate prediction and prevention of coal mine disasters.This study proposed a new digital reconstruction method to visualize geological stru...Visualization of complex geological structures can technically support the accurate prediction and prevention of coal mine disasters.This study proposed a new digital reconstruction method to visualize geological structures based on establishing a virtual model in the digital twin system.This methodology for the digital reconstruction of complex fault structures comprises the following four aspects:(1)collection and fdelity of multi-physical feld data of the fault structures,(2)the transmission of multi-physical feld data,(3)the normalization of multi-physical feld data,and(4)digital model reconstruction of fault structures.The key scientifc issues of this methodology to be resolved include in situ fdelity of multi-feld data and normalized programming of multi-source data.In addition,according to the geological background and conditions in Da’anshan coal mine in western Beijing,China,a preliminary attempt is made to reconstruct a digital model of fault and fold structures using the methodology proposed in this study.展开更多
The intricate interplay between rock mechanics and fracture-induced fluid flow during resource extrac-tion exerts profound effects on groundwater systems,posing a pivotal challenge for promoting green and safe develop...The intricate interplay between rock mechanics and fracture-induced fluid flow during resource extrac-tion exerts profound effects on groundwater systems,posing a pivotal challenge for promoting green and safe development in underground engineering.To address this,a novel numerical model with an explicit coupling simulation strategy is presented.This model integrates distinct modules for individual physical mechanisms,ensuring second-order accuracy through shared time integration,thereby overcoming lim-itations in simulating mining-induced strata damage,water flow,and permeability dynamics.A novel mathematical model is incorporated into the mechanical simulation to characterize the abrupt increase in permeability resulting from rock fracture propagation.This increase is quantified by evaluating the plastic damage state of rocks and incorporating a damage coefficient that is intrinsically linked to rock strength.The mechanical model tracks permeability changes due to mining.The flow model simulates aquifer-mine water interactions by calculating hydraulic conductivity and using dynamic zoning,adapt-ing to mining progress.When applied to a case study of a complex mine,this approach significantly improved the accuracy of water inflow rate predictions by 57%.展开更多
This paper reports a five-year computer-mediated intercultural exchange project between Chinese and American university students that explores the use of various social media tools with WeChat application as the main ...This paper reports a five-year computer-mediated intercultural exchange project between Chinese and American university students that explores the use of various social media tools with WeChat application as the main medium in collaborative intercultural assignments. The study combines quantitative and qualitative approaches by using questionnaires and action research, to investigate how Chinese EFL and American CFL learners increase their intercultural communication competence by assessing their knowledge, awareness, attitudes, and skills of discovery and awareness. The findings reveal their changes and progress in the following variables: knowledge about the variety and subtlety of both the home and target cultures, a different worldview, and cultural study methods;awareness of the importance of differences and similarities between the home and target cultures, their negative reactions to these differences(e.g., fear, ridicule, disgust, feeling of superiority, etc.) and therefore, critical evaluation of the target and home cultures;attitudes from excitement or blind admiration of the target culture to confusion, anxiety or frustration about the cultural differences, later to toleration and appreciation of cultural differences, adaptation to the target culture, and eventually to openness and readiness to suspend disbelief about other cultures and belief about one’s own;skills to contrast the target culture with their own, to demonstrate a capacity to interact appropriately in a variety of different social situations in the target culture and resolve cross-cultural conflicts and misunderstandings. This research will serve as a valuable reference for computer-mediated intercultural communication teaching and open up new possibilities to extend classroom teaching by bridging the gap between second-hand knowledge and hands-on experience.展开更多
Rock residual strength,as an important input parameter,plays an indispensable role in proposing the reasonable and scientific scheme about stope design,underground tunnel excavation and stability evaluation of deep ch...Rock residual strength,as an important input parameter,plays an indispensable role in proposing the reasonable and scientific scheme about stope design,underground tunnel excavation and stability evaluation of deep chambers.Therefore,previous residual strength models of rocks established were reviewed.And corresponding related problems were stated.Subsequently,starting from the effects of bedding and whole life-cycle evolution process,series of triaxial mechanical tests of deep bedded sandstone with five bedding angles were conducted under different confining pressures.Then,six residual strength models considering the effects of bedding and whole life-cycle evolution process were established and evaluated.Finally,a cohesion loss model for determining residual strength of deep bedded sandstone was verified.The results showed that the effects of bedding and whole life-cycle evolution process had both significant influences on the evolution characteristic of residual strength of deep bedded sandstone.Additionally,residual strength parameters:residual cohesion and residual internal friction angle of deep bedded sandstone were not constant,which both significantly changed with increasing bedding angle.Besides,the cohesion loss model was the most suitable for determining and estimating the residual strength of bedded rocks,which could provide more accurate theoretical guidance for the stability control of deep chambers.展开更多
In the gas-coal integrated mining field,the conventional design method of pipeline coal pillars leads to a large amount of coal pillars being unrecovered and overlooks the pipeline's safety requirements.Considerin...In the gas-coal integrated mining field,the conventional design method of pipeline coal pillars leads to a large amount of coal pillars being unrecovered and overlooks the pipeline's safety requirements.Considering the coal pillar recovery rate and pipeline's safety requirements,two new shaped coal pillar design approaches for subsurface pipelines were developed.Firstly,the deformation limitations for measuring pipeline safety are categorized into two:no deformation is permitted,and deformation is acceptable within elastic limits.Subsequently,integrating the key stratum theory(KST)and cave angle,a fishbone-shaped coal pillar design approach that does not permit pipeline deformation is established.Meanwhile,combined with the ground subsidence and the pipeline's elastic deformation limit,a grille-shaped coal pillar design approach that accepts deformation pipelines within elastic limits is established.Those two new approaches clarify parameters including mined width,coal pillar width and mined length.Finally,the case study shows that the designed mined width,coal pillar width and mined length of the fishbone-shaped coal pillar are 90,80,and 130 m,while those of the grille-shaped are 320,370,and640 m.Compared with the conventional method,the fishbone-shaped and grille-shaped coal pillar design approaches recovered coal pillar resources of 2.65×10~6and 5.81×10~6t on the premise of meeting the pipeline safety requirements,and the recovery rates increased by 20.5%and 45.0%,with expenditures representing only 56.46%and 20.02%of the respective benefits.These new approaches provide managers with diverse options for protecting pipeline safety while promoting coal pillar recovery,which is conducive to the harmonic mining of gas-coal resources.展开更多
The joint roughness coefficient(JRC) is one of the key parameters for evaluating the shear strength of rock joints.Because of the scale effect in the JRC,reliable JRC values are of great importance for most rock engin...The joint roughness coefficient(JRC) is one of the key parameters for evaluating the shear strength of rock joints.Because of the scale effect in the JRC,reliable JRC values are of great importance for most rock engineering projects.During the collection process of JRC samples,the redundancy or insufficiency of representative rock joint surface topography(RJST) information in serial length JRC samples is the essential reason that affects the reliability of the scale effect results.Therefore,this paper proposes an adaptive sampling method,in which we use the entropy consistency measure Q(a) to evaluate the consistency of the joint morphology information contained in adjacent JRC samples.Then the sampling interval is automatically adjusted according to the threshold Q(at) of the entropy consistency measure to ensure that the degree of change of RJST information between JRC samples is the same,and ultimately makes the representative RJST information in the collected JRC samples more balanced.The application results of actual cases show that the proposed method can obtain the scale effect in the JRC efficiently and reliably.展开更多
Aiming at the problem that the distance between the main roadway and the working face in Hudi Coal Industry Panel was more than 100 m,which was still affected by mining,high stress concentration of the roadway,and dif...Aiming at the problem that the distance between the main roadway and the working face in Hudi Coal Industry Panel was more than 100 m,which was still affected by mining,high stress concentration of the roadway,and difficulty of supporting overall convergence of the section,the mechanical characteristics of the core bearing strata of the overlying rock caving in the working face were studied.The correlation mechanism between the overlying rock caving and the deformation and failure of the roadway was analyzed,and the quantitative evaluation index was established to comprehensively analyze different influencing factors.Based on the key strata theory,the mechanical difference transfer model of working face mining and panel roadway deformation and failure was established.It was considered that the difference in fracture morphology was the key to the far-field stress disturbance.The regional stress control technology was proposed to block or reduce the stress transfer,so that the peak stress of the panel main roadway was reduced,and the deformation of the surrounding rock was significantly reduced,which provides a reference value for the roadway support with serious influence of mining roadway.展开更多
It is of great significance to study the failure mode of mining roadways for safe coal mining.The unconventional asymmetric failure(UAF)phenomenon was discovered in the 9106 ventilation roadway of Wangzhuang coal mine...It is of great significance to study the failure mode of mining roadways for safe coal mining.The unconventional asymmetric failure(UAF)phenomenon was discovered in the 9106 ventilation roadway of Wangzhuang coal mine in Shanxi Province.The main manifestation is that the deformation of the roadway on the coal side is much greater than that on the coal pillar side.A comprehensive study was conducted on on-site detection,theoretical analysis,laboratory tests and numerical simulation of the UAF phenomenon.On-site detection shows that the deformation of the coal sidewall can reach 50–80 cm,and the failure zone depth can reach 3 m.The deformation and fracture depth on the coal pillar side are much smaller than those on the coal side.A calculation model for the principal stress of surrounding rock when the axial direction of the roadway is inconsistent with the in-situ stress field was established.The distribution of the failure zone on both sides of the roadway has been defined by the combined mining induced stress.The true triaxial test studied the mechanical mechanism of rock mass fracture and crack propagation on both sides of the roadway.The research results indicate that the axial direction,stress field distribution,and mining induced stress field distribution of the roadway jointly affect the asymmetric failure mode of the roadway.The angle between the axis direction of the roadway and the maximum horizontal stress field leads to uneven distribution of the principal stress field on both sides.The differential distribution of mining induced stress exacerbates the asymmetric distribution of principal stress in the surrounding rock.The uneven stress distribution on both sides of the roadway is the main cause of UAF formation.The research results can provide mechanical explanations and theoretical support for the control of surrounding rock in roadways with similar failure characteristics.展开更多
Underground coal mining induces significant surface deformation and environmental damage,particularly in deeply buried mining areas with thin bedrock and thick alluvial layers.Based on the case study of the Zhaogu No....Underground coal mining induces significant surface deformation and environmental damage,particularly in deeply buried mining areas with thin bedrock and thick alluvial layers.Based on the case study of the Zhaogu No.2 coal mine in Xinxiang City,Henan Province,China,this study employs a comprehensive research methodology,integrating field investigations,numerical simulations,and theoretical analyses,to explore the surface subsidence features at deeply buried mining areas with thin bedrock and thick alluvial layers,to reveal the effect of alluvial thickness on the surface subsidence characteristics.The findings indicate that the surface subsidence areas span 4.2 km2 with an advanced influence distance of 540 m.The rate of surface subsidence primarily depends on the panel's position and its advancing rate.Moreover,the thickness of the alluvial layer amplifies both the extent and magnitude of surface deformation.The displacement of overlying rock primarily exhibits a two-stage progression:the thin bedrock control stage and the alluvial control stage.In the thin bedrock control stage,surface subsidence initiates with relatively low subsidence values and amplitudes.Subsequently,in the alluvial control stage,surface subsidence accelerates,leading to a rapid increase in both subsidence values and amplitudes.These characteristics of rock formation displacement result in distinct phases of surface subsidence.Furthermore,the paper addresses the utilization of surface subsidence areas and proposes a method for calculating reservoir storage capacity in these areas.According to calculations,the storage capacity amounts to 1.05e7 m^(3).The research findings provide valuable insights into the surface subsidence laws in regions with similar geological conditions and practical implications for the management and utilization of subsided areas.展开更多
Mining-induced surface subsidence often causes buried oil–gas pipelines deform,and the potential leakage risk can pose a safety hazard.In this work,a novel model for predicting the influence range of potential leakag...Mining-induced surface subsidence often causes buried oil–gas pipelines deform,and the potential leakage risk can pose a safety hazard.In this work,a novel model for predicting the influence range of potential leakage risk from deformed pipelines was developed.First,the pipe instability deformation limit was corrected by the multi-indicator optimized screening method proposed in this paper.Then,the leakage risk influence radius of the pipe segment was defined by the failure probability.Next,the pipe segment'deformation and strength were assessed sequentially using the ratio and point methods.Combining the fuzzy logic inference method with the assessment results as input variable,and the failure probabilities as output variable,a quantitative assessment model for the pipeline leakage risk was established.Accordingly,the risk range and level of adjacent coal mines and surfaces were divided,and the verification method and forward countermeasures were proposed.Finally,an engineering case was used for analysis and verification.The results show that the gas pipeline with 650 m length was divided into seven regions and four risk levels.The influence radius of the risk levels from low to high were 12.75 m,25.5 m,38.25 m,and 51 m,and the influence widths on the surface were 25.28 m,49.84 m,76.34 m,and 101.84 m,correspondingly.The nearest distances from the risk area to the mine and village were 212.65 m and 329.08 m.The assessment of potentially threatened areas is significantly simplified by the assessment model combined with pipeline deformation,which has great practical importance for risk management and disaster prevention in adjacent space.展开更多
Rib spalling is a highly severe issue during mining in deep-buried large-mining-height working faces.This study takes Zhaogu No.2 Coal Mine in Jiaozuo Coalfield,China,as the research background and carries out three f...Rib spalling is a highly severe issue during mining in deep-buried large-mining-height working faces.This study takes Zhaogu No.2 Coal Mine in Jiaozuo Coalfield,China,as the research background and carries out three focused works to address this problem.Firstly,field measurements were conducted to clarify rib spalling characteristics:the coal wall is dominated by shear failure,internal cracks are mainly distributed 3–6 m above the coal wall surface,and the maximum depth of crack development reaches 3 m.Secondly,Universal Distinct Element Code(UDEC)numerical simulation software was used to build a rib spalling model,with the Trigon model adopted to divide the coal wall into blocks.Analysis of four key factors shows that increased buried depth and mining height significantly raise the total length of coal wall internal cracks,increasing rib spalling risk,while higher coal body strength and support strength effectively alleviate this phenomenon.Finally,an orthogonal experiment was designed to quantitatively determine the influence degree of the four factors on rib spalling.Results show that coal body strength has the greatest impact,followed by support strength,mining height,and mining depth in order of influence.This study provides valuable theoretical guidance for on-site prevention and control of coal wall rib spalling.展开更多
The proposal of carbon neutrality target makes decarbonization and hydrogenation typical features of future energy development in China.With a wide range of application scenarios,hydrogen energy will experience rapid ...The proposal of carbon neutrality target makes decarbonization and hydrogenation typical features of future energy development in China.With a wide range of application scenarios,hydrogen energy will experience rapid growth in production and consumption.To formulate an effective hydrogen energy development strategy for the future of China,this study employs the departmental scenario analysis method to calculate and evaluate the future consumption of hydrogen energy in China’s heavy industry,transportation,electricity,and other related fields.Multidimensional technical parameters are selected and predicted accurately and reliably in combination with different development scenarios.The findings indicate that the period from 2030 to 2050 will enjoy rapid development of hydrogen energy,having an average annual growth rate of 2%to 4%.The technological progress and breakthroughs scenario has the greatest potential for hydrogen demand scale among the four development scenarios.Under this scenario,the total demand for hydrogen energy is expected to reach 446.37Mt in 2060.Thetransportation sector will be the sector with the greatest potential for hydrogen deployment growth from 2023 to 2060,which is expected to rise from 0.038Mt to about 163.18Mt,with the ambitious growth in the future.Additionally,hydrogen energy has a considerable development potential in the steel sector,and the trend of de-refueling coke by hydrogenation in this sector will be imperative for this energy-intensive industries.展开更多
The Late Paleozoic marked Earth’s most recent icehouse–greenhouse transition,providing valuable insights into future climate and environmental changes.Although the aridification of the North China Craton(NCC)during ...The Late Paleozoic marked Earth’s most recent icehouse–greenhouse transition,providing valuable insights into future climate and environmental changes.Although the aridification of the North China Craton(NCC)during the Late Paleozoic is well established,its pattern and causes remain unclear.Here,we identify four aridification intervals from the late Gzhelian to Lopingian by analyzing continuous records of elemental climate proxies(MgO/CaO,Sr/Cu),a volcanism proxy(Hg/TOC),and spore–pollen assemblages.Interval I(∼303–295 Ma),during which the NCC was located at low paleolatitudes,was characterized by humid conditions and a predominance of ferns,associated with weak volcanism.Interval II(∼295–286 Ma)was subhumid,with increasing gymnosperm presence,and significant climate fluctuations linked to volcanism.CO_(2) emissions from the Tarim LIP and Panjal Traps drove aridification from the late Asselian to late Artinskian,contributing to the decline of the Late Paleozoic Ice Age.As a result,aridification in the NCC lagged behind that of Pangea.Interval III(∼286–280.98 Ma)marked the transition to subarid conditions and the onset of dominance by gymnosperms,associated with a rapid northward drift of the NCC and an increase in atmosphericρCO_(2).Interval IV(∼259.51–251.902 Ma),separated from the underlying Interval III by a major regional unconformity(∼280.98–259.51),coincided with global aridification and intensified volcanism.These findings highlight the significant influences of both tectonic plate motion and volcanism on the climate evolution of the NCC,with shifts in the dominant controlling factors through time.This study provides new insights into the distinct trajectories of global and regional climate dynamics.展开更多
This paper investigates China's coal price volatility spreaders(CPVSs)from the supply side to locate the volatility source since coal price volatility may destabilize many downstream products'prices or even br...This paper investigates China's coal price volatility spreaders(CPVSs)from the supply side to locate the volatility source since coal price volatility may destabilize many downstream products'prices or even bring uncertainties to macroeconomic output.Especially in the carbon neutrality context,China's coal market is being reconstructed and responding to imbalances between supply and demand;identifying the CPVSs helps alleviate rising market instability and prevent energy-induced system risk.To achieve this objective,we explore causalities among 938 weekly coal prices reported by different coal-producing areas of China from 2006.9.4 to 2021.7.12 using the transfer entropy method.Then,coal price volatility influence is quantified to identify the CPVSs by conjointly using complex network theory and a rank aggregation method.The validity test demonstrates that the proposed hybrid method efficiently identifies the CPVSs as it correlates to many price determinants,e.g.,electricity and coal consumption and generation.The empirical results show that causalities among coal prices changed dramatically in 2016,2018,and 2020,affected by coal decapacity and carbon neutrality policies.Before 2018,coal-producing provinces with strong demand for coal and electricity,e.g.,Jiangxi,Chongqing,and Sichuan,were CPVSs;after 2019,those with comparative advantages in coal supply,e.g.,Gansu and Ningxia,were CPVSs.Overall,the coal market is unstable and sensitive to energy policy and external shocks.Policymakers and market participants are recommended to monitor and manage the CPVSs to improve energy security,avoid policy-induced instability and prevent risks caused by coal price fluctuations.展开更多
The negative Poisson’s ratio(NPR)bolt is an innovative support element distinguished by its high strength,elongation,and a slightly negative Poisson’s ratio.Unlike conventional prestressed(PR)bolts with a positive P...The negative Poisson’s ratio(NPR)bolt is an innovative support element distinguished by its high strength,elongation,and a slightly negative Poisson’s ratio.Unlike conventional prestressed(PR)bolts with a positive Poisson’s ratio,the NPR bolt exhibits a quasi-ideal plastic response without a prominent yield platform,enabling it to sustain high prestress with a substantial safety margin,which is particularly advantageous for jointed rock masses.However,investigations into the shear resistance mechanisms of NPR bolts under varying prestress levels remain limited.This study conducted full-scale double shear tests to assess the shear strength,deformation behavior,energy absorption,and failure mechanisms of NPR bolts under different prestress conditions.To ensure a fair comparison with PR bolts,a prestress utilization coefficient(PUC)was introduced.The results reveal that at a PUC of 0.25,the NPR bolt achieved peak axial force,shear displacement,and peak shear force values that are 2.41,1.88,and 2.13 times greater than those of the PR bolt,respectively.Shear performance was optimized at a prestress level of 100 kN,with energy absorption reaching 47.1 kJ,which is 2.8 times that of the PR bolt.Furthermore,the necking ratio was significantly reduced,indicating more distributed plastic deformation and delayed failure.Field applications verified the superior performance,resulting in a 27.4%reduction in roof settlement and enhanced structural integrity.These findings confirm that NPR bolts possess excellent shear resistance,energy absorption,and deformation adaptability,and optimizing prestress significantly enhances their support performance,providing a strong basis for geotechnical engineering applications.展开更多
Heteroatom-doped carbon is considered a promising alternative to commercial Pt/C as an efficient catalyst for the oxygen reduction reaction(ORR).This study presents the synthesis of iron-loaded,sulfur and nitrogen co-...Heteroatom-doped carbon is considered a promising alternative to commercial Pt/C as an efficient catalyst for the oxygen reduction reaction(ORR).This study presents the synthesis of iron-loaded,sulfur and nitrogen co-doped carbon(Fe/SNC)via in situ incorporation of 2-aminothiazole molecules into zeolitic imidazolate framework-8(ZIF-8)through coordination between metal ions and organic ligands.Sulfur and nitrogen doping in carbon supports effectively modulates the electronic structure of the catalyst,increases the Brunauer-Emmett-Teller surface area,and exposes more Fe-N_(x)active centers.Fe-loaded,S and N co-doped carbon with Fe/S molar ratio of 1:10(Fe/SNC-10)exhibits a half-wave potential of 0.902 V vs.RHE.After 5000 cycles of cyclic voltammetry,its half-wave potential decreases by only 20 mV vs.RHE,indicating excellent stability.Due to sulfur s lower electronegativity,the electronic structure of the Fe-N_(x)active center is modulated.Additionally,the larger atomic radius of sulfur introduces defects into the carbon support.As a result,Fe/SNC-10 demonstrates superior ORR activity and stability in alkaline solution compared with Fe-loaded N-doped carbon(Fe/NC).Furthermore,the zinc-air battery assembled with the Fe/SNC-10 catalyst shows enhanced performance relative to those assembled with Fe/NC and Pt/C catalysts.This work offers a novel design strategy for advanced energy storage and conversion applications.展开更多
The weak and broken roof,explosive control and other problems seriously restrict the promotion of non coal pillar self-forming roadway technology.In order to solve such problems,a new method of non coal pillar self-fo...The weak and broken roof,explosive control and other problems seriously restrict the promotion of non coal pillar self-forming roadway technology.In order to solve such problems,a new method of non coal pillar self-forming roadway through non-blasting roof cutting and pressure relief was proposed in this study.A systematic research system of"theoretical analysis-physical experiment-engineering verification"was constructed with the 9103 working face of Longmenta Coal Mine as the research object.Firstly,the theoretical analysis was conducted to reveal the roof cutting mechanics mechanism of rock mass weakened by dense drilling,establish the design criteria for key drilling parameters,and obtain the key design parameters of dense drilling in the test working face.Secondly,the physical model test was conducted to make clear that the dense drilling method can directionally cut off the goaf roof along the set position,reducing the stress and deformation of the roadway surrounding rock.Finally,the field engineering tests were conducted,and monitoring results showed that the pressure relief effect of the dense drilling method was comparable to that of the directional blasting method,achieving non coal pillar self-forming roadway mining under non blasting conditions.展开更多
Aiming at the problem of dynamic instability of hard-brittle jointed rock surrounding in deep tunnel/roadway engineering,combining with the support concepts of"coupling rigidity with flexibility"and"ove...Aiming at the problem of dynamic instability of hard-brittle jointed rock surrounding in deep tunnel/roadway engineering,combining with the support concepts of"coupling rigidity with flexibility"and"overcoming rigidity by flexibility",the prevention and control method with"rigid-flexible coupling(R-F-C)"was put forward.Through numerical simulation calculation,the impact damage process,acoustic emission(AE)evolution characteristics,and element stress/displacement evolution characteristics of unsupported surrounding rock structure model,rigid supporting surrounding rock structure model,and"R-F-C"supporting surrounding rock structure model under horizontal bidirectional impact loading were compared and analyzed.Based on the theory of stress wave propagation,the dynamic instability catastrophe mechanism of three kinds of supporting structure models induced by horizontal bidirectional impact loading was revealed.Based on the Mohr-Coulomb strength theory,the stress discrimination methods of dynamic catastrophe of surrounding rock induced by horizontal bidirectional impact loading under three kinds of supporting structures were proposed.Combined with the above numerical simulation study,the explosion impact physical and mechanical test of"R-F-C"surrounding rock supporting plate structure was further designed and carried out.Finally,combined with the"conceptual model of ball-cliff potential energy instability",the energy driving theory and energy transformation mechanism of impact-induced rockburst under three kinds of supporting structures were discussed deeply.The research results provided a scientific basis for further promoting the effective application of"R-F-C"supporting structure in the prevention and control of dynamic instability of deep tunnel/roadway surrounding rock.展开更多
Automatically formed roadway(AFR)by roof cutting with bolt grouting(RCBG)is a new deep coal mining technology.By using this technology,the broken roadway roof is strengthened,and roof cutting is applied to cut off str...Automatically formed roadway(AFR)by roof cutting with bolt grouting(RCBG)is a new deep coal mining technology.By using this technology,the broken roadway roof is strengthened,and roof cutting is applied to cut off stress transfer between the roadway and gob to ensure the collapse of the overlying strata.The roadway is automatically formed owing to the broken expansion characteristics of the collapsed strata and mining pressure.Taking the Suncun Coal Mine as the engineering background,the control effect of this new technology on roadways was studied.To compare the law of stress evolution and the surrounding rock control mechanisms between AFR and traditional gob-side entry driving,a comparative study of geomechanical model tests on the above methods was carried out.The results showed that the new technology of AFR by RCBG effectively reduced the stress concentration of the roadway compared with gob-side entry driving.The side abutment pressure peak of the solid coal side was reduced by 24.3%,which showed an obvious pressure-releasing effect.Moreover,the position of the side abutment pressure peak was far from the solid coal side,making it more beneficial for roadway stability.The deformation of AFR surrounding rock was also smaller than the deformation of the gob-side entry driving by the overload test.The former was more beneficial for roadway stability than the latter under higher stress conditions.Field application tests showed that the new technology can effectively control roadway deformation.Moreover,the technology reduced roadway excavation and avoided resource waste caused by reserved coal pillars.展开更多
A physical model for the footwall slope of Nanfen open-pit mine, China was established using a selfdeveloped deep geological engineering disaster model test system. A thermosensitive similar material,paraffin, was sel...A physical model for the footwall slope of Nanfen open-pit mine, China was established using a selfdeveloped deep geological engineering disaster model test system. A thermosensitive similar material,paraffin, was selected to simulate a weak structural plane in the slope to reproduce the landslide process.From an experimental perspective, the variation trend of shear strength parameters of weak structural plane and the mechanical support characteristics of NPR(negative Poisson’s ratio) anchor cable under the condition of a large landslide deformation and failure were examined. The results of this model test showed that slope failure has four distinct stages:(1) soil compaction stage,(2) crack generation stage,(3) crack propagation stage, and(4) sliding plane transfixion stage. According to the test results, the rock mechanics parameters of weak surface in the footwall slope of Nanfen open-pit mine were calculated.The cohesion is approximately 1.35×10~5 Pa, and the internal friction angle is approximately 6.33°.During slope failure, the NPR anchor cable experiences a large deformation but no damage occurs, indicating that the NPR anchor cable can be continuously monitored and reinforced during the deformation and failure of landslide. The stress characteristics of NPR anchor cables during the test are consistent with the monitoring results of Newtonian force at the landslide site, proving that NPR anchor cables are effective and reasonable in landslide monitoring and early warning.展开更多
基金This study was financially supported by the Beijing Natural Science Foundation(8202041)National Natural Science Foundation of China(41872205)+1 种基金Yue Qi Young Scholar Project,China University of Mining&Technology,Beijing(2018QN13)the Fundamental Research Funds for the Central Universities(2022YJSLJ08,2021YJSLJ10).
文摘Visualization of complex geological structures can technically support the accurate prediction and prevention of coal mine disasters.This study proposed a new digital reconstruction method to visualize geological structures based on establishing a virtual model in the digital twin system.This methodology for the digital reconstruction of complex fault structures comprises the following four aspects:(1)collection and fdelity of multi-physical feld data of the fault structures,(2)the transmission of multi-physical feld data,(3)the normalization of multi-physical feld data,and(4)digital model reconstruction of fault structures.The key scientifc issues of this methodology to be resolved include in situ fdelity of multi-feld data and normalized programming of multi-source data.In addition,according to the geological background and conditions in Da’anshan coal mine in western Beijing,China,a preliminary attempt is made to reconstruct a digital model of fault and fold structures using the methodology proposed in this study.
基金supported by the National Natural Science Foundation of China (Nos. 42027801, 42072284, and 42372297)the National Key Research and Development Program of China (Nos. 2023YFC3012102 and 2021YFC2902004)the Fundamental Research Funds for the Central Universities (No. 2023ZKPYSH01)
文摘The intricate interplay between rock mechanics and fracture-induced fluid flow during resource extrac-tion exerts profound effects on groundwater systems,posing a pivotal challenge for promoting green and safe development in underground engineering.To address this,a novel numerical model with an explicit coupling simulation strategy is presented.This model integrates distinct modules for individual physical mechanisms,ensuring second-order accuracy through shared time integration,thereby overcoming lim-itations in simulating mining-induced strata damage,water flow,and permeability dynamics.A novel mathematical model is incorporated into the mechanical simulation to characterize the abrupt increase in permeability resulting from rock fracture propagation.This increase is quantified by evaluating the plastic damage state of rocks and incorporating a damage coefficient that is intrinsically linked to rock strength.The mechanical model tracks permeability changes due to mining.The flow model simulates aquifer-mine water interactions by calculating hydraulic conductivity and using dynamic zoning,adapt-ing to mining progress.When applied to a case study of a complex mine,this approach significantly improved the accuracy of water inflow rate predictions by 57%.
文摘This paper reports a five-year computer-mediated intercultural exchange project between Chinese and American university students that explores the use of various social media tools with WeChat application as the main medium in collaborative intercultural assignments. The study combines quantitative and qualitative approaches by using questionnaires and action research, to investigate how Chinese EFL and American CFL learners increase their intercultural communication competence by assessing their knowledge, awareness, attitudes, and skills of discovery and awareness. The findings reveal their changes and progress in the following variables: knowledge about the variety and subtlety of both the home and target cultures, a different worldview, and cultural study methods;awareness of the importance of differences and similarities between the home and target cultures, their negative reactions to these differences(e.g., fear, ridicule, disgust, feeling of superiority, etc.) and therefore, critical evaluation of the target and home cultures;attitudes from excitement or blind admiration of the target culture to confusion, anxiety or frustration about the cultural differences, later to toleration and appreciation of cultural differences, adaptation to the target culture, and eventually to openness and readiness to suspend disbelief about other cultures and belief about one’s own;skills to contrast the target culture with their own, to demonstrate a capacity to interact appropriately in a variety of different social situations in the target culture and resolve cross-cultural conflicts and misunderstandings. This research will serve as a valuable reference for computer-mediated intercultural communication teaching and open up new possibilities to extend classroom teaching by bridging the gap between second-hand knowledge and hands-on experience.
基金Projects(2024YFC3013801,2022YFC3004602)supported by the National Key R&D Program of ChinaProjects(U23B2093,52034009)supported by the National Natural Science Foundation of China。
文摘Rock residual strength,as an important input parameter,plays an indispensable role in proposing the reasonable and scientific scheme about stope design,underground tunnel excavation and stability evaluation of deep chambers.Therefore,previous residual strength models of rocks established were reviewed.And corresponding related problems were stated.Subsequently,starting from the effects of bedding and whole life-cycle evolution process,series of triaxial mechanical tests of deep bedded sandstone with five bedding angles were conducted under different confining pressures.Then,six residual strength models considering the effects of bedding and whole life-cycle evolution process were established and evaluated.Finally,a cohesion loss model for determining residual strength of deep bedded sandstone was verified.The results showed that the effects of bedding and whole life-cycle evolution process had both significant influences on the evolution characteristic of residual strength of deep bedded sandstone.Additionally,residual strength parameters:residual cohesion and residual internal friction angle of deep bedded sandstone were not constant,which both significantly changed with increasing bedding angle.Besides,the cohesion loss model was the most suitable for determining and estimating the residual strength of bedded rocks,which could provide more accurate theoretical guidance for the stability control of deep chambers.
基金funded by the National Natural Science Foundation of China (No.52225402)Inner Mongolia Research Institute,China University of Mining and Technology-Beijing (IMRI23003)。
文摘In the gas-coal integrated mining field,the conventional design method of pipeline coal pillars leads to a large amount of coal pillars being unrecovered and overlooks the pipeline's safety requirements.Considering the coal pillar recovery rate and pipeline's safety requirements,two new shaped coal pillar design approaches for subsurface pipelines were developed.Firstly,the deformation limitations for measuring pipeline safety are categorized into two:no deformation is permitted,and deformation is acceptable within elastic limits.Subsequently,integrating the key stratum theory(KST)and cave angle,a fishbone-shaped coal pillar design approach that does not permit pipeline deformation is established.Meanwhile,combined with the ground subsidence and the pipeline's elastic deformation limit,a grille-shaped coal pillar design approach that accepts deformation pipelines within elastic limits is established.Those two new approaches clarify parameters including mined width,coal pillar width and mined length.Finally,the case study shows that the designed mined width,coal pillar width and mined length of the fishbone-shaped coal pillar are 90,80,and 130 m,while those of the grille-shaped are 320,370,and640 m.Compared with the conventional method,the fishbone-shaped and grille-shaped coal pillar design approaches recovered coal pillar resources of 2.65×10~6and 5.81×10~6t on the premise of meeting the pipeline safety requirements,and the recovery rates increased by 20.5%and 45.0%,with expenditures representing only 56.46%and 20.02%of the respective benefits.These new approaches provide managers with diverse options for protecting pipeline safety while promoting coal pillar recovery,which is conducive to the harmonic mining of gas-coal resources.
基金supported by the National Natural Science Foundation of China(No.42207175)。
文摘The joint roughness coefficient(JRC) is one of the key parameters for evaluating the shear strength of rock joints.Because of the scale effect in the JRC,reliable JRC values are of great importance for most rock engineering projects.During the collection process of JRC samples,the redundancy or insufficiency of representative rock joint surface topography(RJST) information in serial length JRC samples is the essential reason that affects the reliability of the scale effect results.Therefore,this paper proposes an adaptive sampling method,in which we use the entropy consistency measure Q(a) to evaluate the consistency of the joint morphology information contained in adjacent JRC samples.Then the sampling interval is automatically adjusted according to the threshold Q(at) of the entropy consistency measure to ensure that the degree of change of RJST information between JRC samples is the same,and ultimately makes the representative RJST information in the collected JRC samples more balanced.The application results of actual cases show that the proposed method can obtain the scale effect in the JRC efficiently and reliably.
基金Project(2024B03017)supported by the Key Research and Development Program Projects of Xinjiang Uygur Autonomous Region,ChinaProjects(52225404,52394192)supported by the National Natural Science Foundation of China。
文摘Aiming at the problem that the distance between the main roadway and the working face in Hudi Coal Industry Panel was more than 100 m,which was still affected by mining,high stress concentration of the roadway,and difficulty of supporting overall convergence of the section,the mechanical characteristics of the core bearing strata of the overlying rock caving in the working face were studied.The correlation mechanism between the overlying rock caving and the deformation and failure of the roadway was analyzed,and the quantitative evaluation index was established to comprehensively analyze different influencing factors.Based on the key strata theory,the mechanical difference transfer model of working face mining and panel roadway deformation and failure was established.It was considered that the difference in fracture morphology was the key to the far-field stress disturbance.The regional stress control technology was proposed to block or reduce the stress transfer,so that the peak stress of the panel main roadway was reduced,and the deformation of the surrounding rock was significantly reduced,which provides a reference value for the roadway support with serious influence of mining roadway.
基金financially supported by the National Natural Science Foundation of China(Nos.52225404,12532020,52394192 and 42321002)Key Research and Development Program Projects of Xinjiang Uygur Autonomous Region(No.2024B03017)Doctoral Startup Foundation of Fuyang Normal University,China(No.2025KYQD0124)。
文摘It is of great significance to study the failure mode of mining roadways for safe coal mining.The unconventional asymmetric failure(UAF)phenomenon was discovered in the 9106 ventilation roadway of Wangzhuang coal mine in Shanxi Province.The main manifestation is that the deformation of the roadway on the coal side is much greater than that on the coal pillar side.A comprehensive study was conducted on on-site detection,theoretical analysis,laboratory tests and numerical simulation of the UAF phenomenon.On-site detection shows that the deformation of the coal sidewall can reach 50–80 cm,and the failure zone depth can reach 3 m.The deformation and fracture depth on the coal pillar side are much smaller than those on the coal side.A calculation model for the principal stress of surrounding rock when the axial direction of the roadway is inconsistent with the in-situ stress field was established.The distribution of the failure zone on both sides of the roadway has been defined by the combined mining induced stress.The true triaxial test studied the mechanical mechanism of rock mass fracture and crack propagation on both sides of the roadway.The research results indicate that the axial direction,stress field distribution,and mining induced stress field distribution of the roadway jointly affect the asymmetric failure mode of the roadway.The angle between the axis direction of the roadway and the maximum horizontal stress field leads to uneven distribution of the principal stress field on both sides.The differential distribution of mining induced stress exacerbates the asymmetric distribution of principal stress in the surrounding rock.The uneven stress distribution on both sides of the roadway is the main cause of UAF formation.The research results can provide mechanical explanations and theoretical support for the control of surrounding rock in roadways with similar failure characteristics.
基金supported by the National Natural Science Foundation of China(Grant Nos.5193400852374106+5 种基金5220416352404159)China Postdoctoral Science Foundation(Grant no.2024T171006)the Fundamental Research Funds for the Central Universities(Grant Nos.2024ZKPYNY042023ZKPYNY012023YQTD02)。
文摘Underground coal mining induces significant surface deformation and environmental damage,particularly in deeply buried mining areas with thin bedrock and thick alluvial layers.Based on the case study of the Zhaogu No.2 coal mine in Xinxiang City,Henan Province,China,this study employs a comprehensive research methodology,integrating field investigations,numerical simulations,and theoretical analyses,to explore the surface subsidence features at deeply buried mining areas with thin bedrock and thick alluvial layers,to reveal the effect of alluvial thickness on the surface subsidence characteristics.The findings indicate that the surface subsidence areas span 4.2 km2 with an advanced influence distance of 540 m.The rate of surface subsidence primarily depends on the panel's position and its advancing rate.Moreover,the thickness of the alluvial layer amplifies both the extent and magnitude of surface deformation.The displacement of overlying rock primarily exhibits a two-stage progression:the thin bedrock control stage and the alluvial control stage.In the thin bedrock control stage,surface subsidence initiates with relatively low subsidence values and amplitudes.Subsequently,in the alluvial control stage,surface subsidence accelerates,leading to a rapid increase in both subsidence values and amplitudes.These characteristics of rock formation displacement result in distinct phases of surface subsidence.Furthermore,the paper addresses the utilization of surface subsidence areas and proposes a method for calculating reservoir storage capacity in these areas.According to calculations,the storage capacity amounts to 1.05e7 m^(3).The research findings provide valuable insights into the surface subsidence laws in regions with similar geological conditions and practical implications for the management and utilization of subsided areas.
基金funded by the National Natural Science Foundation of China(52225402 and 51874312)the Major scientific and technological innovation project of Shandong Province(2019SDZY01 and 2019SDZY02).
文摘Mining-induced surface subsidence often causes buried oil–gas pipelines deform,and the potential leakage risk can pose a safety hazard.In this work,a novel model for predicting the influence range of potential leakage risk from deformed pipelines was developed.First,the pipe instability deformation limit was corrected by the multi-indicator optimized screening method proposed in this paper.Then,the leakage risk influence radius of the pipe segment was defined by the failure probability.Next,the pipe segment'deformation and strength were assessed sequentially using the ratio and point methods.Combining the fuzzy logic inference method with the assessment results as input variable,and the failure probabilities as output variable,a quantitative assessment model for the pipeline leakage risk was established.Accordingly,the risk range and level of adjacent coal mines and surfaces were divided,and the verification method and forward countermeasures were proposed.Finally,an engineering case was used for analysis and verification.The results show that the gas pipeline with 650 m length was divided into seven regions and four risk levels.The influence radius of the risk levels from low to high were 12.75 m,25.5 m,38.25 m,and 51 m,and the influence widths on the surface were 25.28 m,49.84 m,76.34 m,and 101.84 m,correspondingly.The nearest distances from the risk area to the mine and village were 212.65 m and 329.08 m.The assessment of potentially threatened areas is significantly simplified by the assessment model combined with pipeline deformation,which has great practical importance for risk management and disaster prevention in adjacent space.
基金supported by the National Key Research and Development Program of China(No.2023YFC2907501)the National Natural Science Foundation of China(No.52374106)+1 种基金the China Postdoctoral Science Foundation(Grant no.2024T171006)the National Natural Science Foundation of China(Grant no.52204163).
文摘Rib spalling is a highly severe issue during mining in deep-buried large-mining-height working faces.This study takes Zhaogu No.2 Coal Mine in Jiaozuo Coalfield,China,as the research background and carries out three focused works to address this problem.Firstly,field measurements were conducted to clarify rib spalling characteristics:the coal wall is dominated by shear failure,internal cracks are mainly distributed 3–6 m above the coal wall surface,and the maximum depth of crack development reaches 3 m.Secondly,Universal Distinct Element Code(UDEC)numerical simulation software was used to build a rib spalling model,with the Trigon model adopted to divide the coal wall into blocks.Analysis of four key factors shows that increased buried depth and mining height significantly raise the total length of coal wall internal cracks,increasing rib spalling risk,while higher coal body strength and support strength effectively alleviate this phenomenon.Finally,an orthogonal experiment was designed to quantitatively determine the influence degree of the four factors on rib spalling.Results show that coal body strength has the greatest impact,followed by support strength,mining height,and mining depth in order of influence.This study provides valuable theoretical guidance for on-site prevention and control of coal wall rib spalling.
基金supported by the National Natural Science Foundation of China(No.71704178)Beijing Municipal Excellent Talents Foundation(No.2017000020124G133)Major consulting project of the Chinese Academy of Engineering(Nos.2023-JB-08,2022-PP-03).
文摘The proposal of carbon neutrality target makes decarbonization and hydrogenation typical features of future energy development in China.With a wide range of application scenarios,hydrogen energy will experience rapid growth in production and consumption.To formulate an effective hydrogen energy development strategy for the future of China,this study employs the departmental scenario analysis method to calculate and evaluate the future consumption of hydrogen energy in China’s heavy industry,transportation,electricity,and other related fields.Multidimensional technical parameters are selected and predicted accurately and reliably in combination with different development scenarios.The findings indicate that the period from 2030 to 2050 will enjoy rapid development of hydrogen energy,having an average annual growth rate of 2%to 4%.The technological progress and breakthroughs scenario has the greatest potential for hydrogen demand scale among the four development scenarios.Under this scenario,the total demand for hydrogen energy is expected to reach 446.37Mt in 2060.Thetransportation sector will be the sector with the greatest potential for hydrogen deployment growth from 2023 to 2060,which is expected to rise from 0.038Mt to about 163.18Mt,with the ambitious growth in the future.Additionally,hydrogen energy has a considerable development potential in the steel sector,and the trend of de-refueling coke by hydrogenation in this sector will be imperative for this energy-intensive industries.
基金financially supported by CNPC Innovation Found(2021DQ02-1003)the Fundamental Research Funds for the Central Universities(Ph.D.Top Innovative Talents Fund of CUMTB)(BBJ2025043).
文摘The Late Paleozoic marked Earth’s most recent icehouse–greenhouse transition,providing valuable insights into future climate and environmental changes.Although the aridification of the North China Craton(NCC)during the Late Paleozoic is well established,its pattern and causes remain unclear.Here,we identify four aridification intervals from the late Gzhelian to Lopingian by analyzing continuous records of elemental climate proxies(MgO/CaO,Sr/Cu),a volcanism proxy(Hg/TOC),and spore–pollen assemblages.Interval I(∼303–295 Ma),during which the NCC was located at low paleolatitudes,was characterized by humid conditions and a predominance of ferns,associated with weak volcanism.Interval II(∼295–286 Ma)was subhumid,with increasing gymnosperm presence,and significant climate fluctuations linked to volcanism.CO_(2) emissions from the Tarim LIP and Panjal Traps drove aridification from the late Asselian to late Artinskian,contributing to the decline of the Late Paleozoic Ice Age.As a result,aridification in the NCC lagged behind that of Pangea.Interval III(∼286–280.98 Ma)marked the transition to subarid conditions and the onset of dominance by gymnosperms,associated with a rapid northward drift of the NCC and an increase in atmosphericρCO_(2).Interval IV(∼259.51–251.902 Ma),separated from the underlying Interval III by a major regional unconformity(∼280.98–259.51),coincided with global aridification and intensified volcanism.These findings highlight the significant influences of both tectonic plate motion and volcanism on the climate evolution of the NCC,with shifts in the dominant controlling factors through time.This study provides new insights into the distinct trajectories of global and regional climate dynamics.
基金supported by the National Natural Science Foundation of China(Grant No.72401207 and 42101300)Beijing Municipal Education Commission,China(Grant No.SM202110038001).
文摘This paper investigates China's coal price volatility spreaders(CPVSs)from the supply side to locate the volatility source since coal price volatility may destabilize many downstream products'prices or even bring uncertainties to macroeconomic output.Especially in the carbon neutrality context,China's coal market is being reconstructed and responding to imbalances between supply and demand;identifying the CPVSs helps alleviate rising market instability and prevent energy-induced system risk.To achieve this objective,we explore causalities among 938 weekly coal prices reported by different coal-producing areas of China from 2006.9.4 to 2021.7.12 using the transfer entropy method.Then,coal price volatility influence is quantified to identify the CPVSs by conjointly using complex network theory and a rank aggregation method.The validity test demonstrates that the proposed hybrid method efficiently identifies the CPVSs as it correlates to many price determinants,e.g.,electricity and coal consumption and generation.The empirical results show that causalities among coal prices changed dramatically in 2016,2018,and 2020,affected by coal decapacity and carbon neutrality policies.Before 2018,coal-producing provinces with strong demand for coal and electricity,e.g.,Jiangxi,Chongqing,and Sichuan,were CPVSs;after 2019,those with comparative advantages in coal supply,e.g.,Gansu and Ningxia,were CPVSs.Overall,the coal market is unstable and sensitive to energy policy and external shocks.Policymakers and market participants are recommended to monitor and manage the CPVSs to improve energy security,avoid policy-induced instability and prevent risks caused by coal price fluctuations.
基金supported by the State Key Laboratory of Intelligent Construction and Healthy Operation and Maintenance of Deep Underground Engineering(Grant No.SDGZ2505)the Postdoctoral Fellowship Program of the China Postdoctoral Science Foundation(Grant No.GZB20250742)the General Program of the China Postdoctoral Science Foundation(Grant No.2025M773213).
文摘The negative Poisson’s ratio(NPR)bolt is an innovative support element distinguished by its high strength,elongation,and a slightly negative Poisson’s ratio.Unlike conventional prestressed(PR)bolts with a positive Poisson’s ratio,the NPR bolt exhibits a quasi-ideal plastic response without a prominent yield platform,enabling it to sustain high prestress with a substantial safety margin,which is particularly advantageous for jointed rock masses.However,investigations into the shear resistance mechanisms of NPR bolts under varying prestress levels remain limited.This study conducted full-scale double shear tests to assess the shear strength,deformation behavior,energy absorption,and failure mechanisms of NPR bolts under different prestress conditions.To ensure a fair comparison with PR bolts,a prestress utilization coefficient(PUC)was introduced.The results reveal that at a PUC of 0.25,the NPR bolt achieved peak axial force,shear displacement,and peak shear force values that are 2.41,1.88,and 2.13 times greater than those of the PR bolt,respectively.Shear performance was optimized at a prestress level of 100 kN,with energy absorption reaching 47.1 kJ,which is 2.8 times that of the PR bolt.Furthermore,the necking ratio was significantly reduced,indicating more distributed plastic deformation and delayed failure.Field applications verified the superior performance,resulting in a 27.4%reduction in roof settlement and enhanced structural integrity.These findings confirm that NPR bolts possess excellent shear resistance,energy absorption,and deformation adaptability,and optimizing prestress significantly enhances their support performance,providing a strong basis for geotechnical engineering applications.
基金financial support of the National Natural Science Foundation of China(No.52472271)the National Key Research and Development Program of China(No.2023YFE0115800)。
文摘Heteroatom-doped carbon is considered a promising alternative to commercial Pt/C as an efficient catalyst for the oxygen reduction reaction(ORR).This study presents the synthesis of iron-loaded,sulfur and nitrogen co-doped carbon(Fe/SNC)via in situ incorporation of 2-aminothiazole molecules into zeolitic imidazolate framework-8(ZIF-8)through coordination between metal ions and organic ligands.Sulfur and nitrogen doping in carbon supports effectively modulates the electronic structure of the catalyst,increases the Brunauer-Emmett-Teller surface area,and exposes more Fe-N_(x)active centers.Fe-loaded,S and N co-doped carbon with Fe/S molar ratio of 1:10(Fe/SNC-10)exhibits a half-wave potential of 0.902 V vs.RHE.After 5000 cycles of cyclic voltammetry,its half-wave potential decreases by only 20 mV vs.RHE,indicating excellent stability.Due to sulfur s lower electronegativity,the electronic structure of the Fe-N_(x)active center is modulated.Additionally,the larger atomic radius of sulfur introduces defects into the carbon support.As a result,Fe/SNC-10 demonstrates superior ORR activity and stability in alkaline solution compared with Fe-loaded N-doped carbon(Fe/NC).Furthermore,the zinc-air battery assembled with the Fe/SNC-10 catalyst shows enhanced performance relative to those assembled with Fe/NC and Pt/C catalysts.This work offers a novel design strategy for advanced energy storage and conversion applications.
基金Project(2024YFC2909500)supported by the National Key Research and Development Program of ChinaProjects(42377148,52204164)supported by the National Natural Science Foundation of ChinaProject(2022XJSB03)supported by the Fundamental Research Funds for the Central Universities,China。
文摘The weak and broken roof,explosive control and other problems seriously restrict the promotion of non coal pillar self-forming roadway technology.In order to solve such problems,a new method of non coal pillar self-forming roadway through non-blasting roof cutting and pressure relief was proposed in this study.A systematic research system of"theoretical analysis-physical experiment-engineering verification"was constructed with the 9103 working face of Longmenta Coal Mine as the research object.Firstly,the theoretical analysis was conducted to reveal the roof cutting mechanics mechanism of rock mass weakened by dense drilling,establish the design criteria for key drilling parameters,and obtain the key design parameters of dense drilling in the test working face.Secondly,the physical model test was conducted to make clear that the dense drilling method can directionally cut off the goaf roof along the set position,reducing the stress and deformation of the roadway surrounding rock.Finally,the field engineering tests were conducted,and monitoring results showed that the pressure relief effect of the dense drilling method was comparable to that of the directional blasting method,achieving non coal pillar self-forming roadway mining under non blasting conditions.
基金Project(2023AH051167)supported by the Natural Science Research Project of Anhui Educational Committee,ChinaProject(AHBP2024B-04)supported by the Foundation of Anhui Engineering Research Center of New Explosive Materials and Blasting Technology,China+1 种基金Project(GXZDSYS2023103)supported by the Open Fund for Anhui Key Laboratory of Mining Construction Engineering,ChinaProjects(52274071,52404155)supported by the National Natural Science Foundation of China。
文摘Aiming at the problem of dynamic instability of hard-brittle jointed rock surrounding in deep tunnel/roadway engineering,combining with the support concepts of"coupling rigidity with flexibility"and"overcoming rigidity by flexibility",the prevention and control method with"rigid-flexible coupling(R-F-C)"was put forward.Through numerical simulation calculation,the impact damage process,acoustic emission(AE)evolution characteristics,and element stress/displacement evolution characteristics of unsupported surrounding rock structure model,rigid supporting surrounding rock structure model,and"R-F-C"supporting surrounding rock structure model under horizontal bidirectional impact loading were compared and analyzed.Based on the theory of stress wave propagation,the dynamic instability catastrophe mechanism of three kinds of supporting structure models induced by horizontal bidirectional impact loading was revealed.Based on the Mohr-Coulomb strength theory,the stress discrimination methods of dynamic catastrophe of surrounding rock induced by horizontal bidirectional impact loading under three kinds of supporting structures were proposed.Combined with the above numerical simulation study,the explosion impact physical and mechanical test of"R-F-C"surrounding rock supporting plate structure was further designed and carried out.Finally,combined with the"conceptual model of ball-cliff potential energy instability",the energy driving theory and energy transformation mechanism of impact-induced rockburst under three kinds of supporting structures were discussed deeply.The research results provided a scientific basis for further promoting the effective application of"R-F-C"supporting structure in the prevention and control of dynamic instability of deep tunnel/roadway surrounding rock.
基金This work was supported by the National Natural Science Foundation of China(Nos.51874188,52074164,42077267,and 51927807)the Natural Science Foundation of Shandong Province,China(Nos.2019SDZY04 and ZR2020JQ23)the Project of Shandong Province Higher Educational Youth Innovation Science and Technology Program,China(No.2019KJG013).
文摘Automatically formed roadway(AFR)by roof cutting with bolt grouting(RCBG)is a new deep coal mining technology.By using this technology,the broken roadway roof is strengthened,and roof cutting is applied to cut off stress transfer between the roadway and gob to ensure the collapse of the overlying strata.The roadway is automatically formed owing to the broken expansion characteristics of the collapsed strata and mining pressure.Taking the Suncun Coal Mine as the engineering background,the control effect of this new technology on roadways was studied.To compare the law of stress evolution and the surrounding rock control mechanisms between AFR and traditional gob-side entry driving,a comparative study of geomechanical model tests on the above methods was carried out.The results showed that the new technology of AFR by RCBG effectively reduced the stress concentration of the roadway compared with gob-side entry driving.The side abutment pressure peak of the solid coal side was reduced by 24.3%,which showed an obvious pressure-releasing effect.Moreover,the position of the side abutment pressure peak was far from the solid coal side,making it more beneficial for roadway stability.The deformation of AFR surrounding rock was also smaller than the deformation of the gob-side entry driving by the overload test.The former was more beneficial for roadway stability than the latter under higher stress conditions.Field application tests showed that the new technology can effectively control roadway deformation.Moreover,the technology reduced roadway excavation and avoided resource waste caused by reserved coal pillars.
基金This study was supported by Zhejiang Collaborative Innovation Center for Prevention and Control of Mountain Geologic Hazards(Grant no.PCMGH-2016-Z-02).
文摘A physical model for the footwall slope of Nanfen open-pit mine, China was established using a selfdeveloped deep geological engineering disaster model test system. A thermosensitive similar material,paraffin, was selected to simulate a weak structural plane in the slope to reproduce the landslide process.From an experimental perspective, the variation trend of shear strength parameters of weak structural plane and the mechanical support characteristics of NPR(negative Poisson’s ratio) anchor cable under the condition of a large landslide deformation and failure were examined. The results of this model test showed that slope failure has four distinct stages:(1) soil compaction stage,(2) crack generation stage,(3) crack propagation stage, and(4) sliding plane transfixion stage. According to the test results, the rock mechanics parameters of weak surface in the footwall slope of Nanfen open-pit mine were calculated.The cohesion is approximately 1.35×10~5 Pa, and the internal friction angle is approximately 6.33°.During slope failure, the NPR anchor cable experiences a large deformation but no damage occurs, indicating that the NPR anchor cable can be continuously monitored and reinforced during the deformation and failure of landslide. The stress characteristics of NPR anchor cables during the test are consistent with the monitoring results of Newtonian force at the landslide site, proving that NPR anchor cables are effective and reasonable in landslide monitoring and early warning.
