BiVO4, BiVO4@C3N4 and BiVO4@C3N4@GO composite photo-catalysts were synthesized, and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), transmission elec...BiVO4, BiVO4@C3N4 and BiVO4@C3N4@GO composite photo-catalysts were synthesized, and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), transmission electron microscopy (TEM), ultraviolet-visible diffuse reflectance spectroscopy (UV-vis DRS), Fourier transform infrared spectroscopy (FT-IR), and Brunauer-Emmett-Teller (BET) surface area techniques. The photocatalytic activity was evaluated on the degradation of methylene blue (MB) under visible light irradiation, which denoted that the BiVO4@C3N4@GO ternary composite outperformed the binary composite BiVO4@C3N4 and BiVO4. Then the effects of catalyst dosage, initial pH value, and initial methylene blue concentration on the degradation process were investigated systematically. The improvement of visible-light photocatalytic degradation performance was attributed to the enhanced visible light absorption, larger surface area, higher adsorption ability, and prolonged lifetime of photo-generated electron-hole pairs. The recycle experiments results showed that the BiVO4@C3N4@GO composite had excellent photo-stability for MB photocatalytic degradation.展开更多
The influence of the recycle ratio on the removal of coking wastewater has been researched using the anaerobicanoxic-aerobic （A/A/O） biofilm process. The research indicates that the concentrations of chemical oxygen...The influence of the recycle ratio on the removal of coking wastewater has been researched using the anaerobicanoxic-aerobic （A/A/O） biofilm process. The research indicates that the concentrations of chemical oxygen demand （COD） and NO3 -N in the water are the lowest when the recycle ratio is 3：1 ,but the removal efficiency of total cyanide （TCN） is the highest when the recycle ratio is 1： 1. The removal efficiency of NH4^＋ -N is more than 99% at all three different recycle ratios. Compared with Grade A of the National Discharge Standard （GB 8978--1996）, the effluent NH4 -N is standard,but COD and TCN can not meet the requirements and further treatment processes are needed.展开更多
基金the Natural Science Foundation of Heilongjiang Province of China [QC2017005]the Province Postdoctoral Fund [LBH-Z15032]
文摘BiVO4, BiVO4@C3N4 and BiVO4@C3N4@GO composite photo-catalysts were synthesized, and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), transmission electron microscopy (TEM), ultraviolet-visible diffuse reflectance spectroscopy (UV-vis DRS), Fourier transform infrared spectroscopy (FT-IR), and Brunauer-Emmett-Teller (BET) surface area techniques. The photocatalytic activity was evaluated on the degradation of methylene blue (MB) under visible light irradiation, which denoted that the BiVO4@C3N4@GO ternary composite outperformed the binary composite BiVO4@C3N4 and BiVO4. Then the effects of catalyst dosage, initial pH value, and initial methylene blue concentration on the degradation process were investigated systematically. The improvement of visible-light photocatalytic degradation performance was attributed to the enhanced visible light absorption, larger surface area, higher adsorption ability, and prolonged lifetime of photo-generated electron-hole pairs. The recycle experiments results showed that the BiVO4@C3N4@GO composite had excellent photo-stability for MB photocatalytic degradation.
文摘The influence of the recycle ratio on the removal of coking wastewater has been researched using the anaerobicanoxic-aerobic （A/A/O） biofilm process. The research indicates that the concentrations of chemical oxygen demand （COD） and NO3 -N in the water are the lowest when the recycle ratio is 3：1 ,but the removal efficiency of total cyanide （TCN） is the highest when the recycle ratio is 1： 1. The removal efficiency of NH4^＋ -N is more than 99% at all three different recycle ratios. Compared with Grade A of the National Discharge Standard （GB 8978--1996）, the effluent NH4 -N is standard,but COD and TCN can not meet the requirements and further treatment processes are needed.
