The geometric structures,electronic absorption spectrum,and thermodynamic pro-perties of 3-（4-N-maleimido）-phenyl-2,4-dihydro-2H-1,3-benzoxazine molecule were studied at the B3LYP/6-311＋G＊ level by density functio...The geometric structures,electronic absorption spectrum,and thermodynamic pro-perties of 3-（4-N-maleimido）-phenyl-2,4-dihydro-2H-1,3-benzoxazine molecule were studied at the B3LYP/6-311＋G＊ level by density functional theory.The results show that three rings of this molecule are in different planes.In gas,absorption wavelength of the lowest energy excitation was obtained at 503 nm,and solvents made it blue-shifted by 3-7 nm,both corresponding to the electron transition of HOMO → LUMO.At 298.15 K,the standard molar formed enthalpy and free energy of the title compound molecule were-549.43 and-273.37 kJ·mol-1,respectively.展开更多
This paper presents the results of the investigations, driven by different techniques, including environmental tracers and geophysical methods, in the aim of better understand the causes of the current salt-water intr...This paper presents the results of the investigations, driven by different techniques, including environmental tracers and geophysical methods, in the aim of better understand the causes of the current salt-water intrusion in the Pontina Plain, in the south of the Lazio Region (Italy). In the last 50 years many investigation campaigns have been carried out to evaluate the evolution of salt-water intrusion. This is an area with a strong man-made residential and tourist impact and, in the some cases, it is characterized by intensive agricultural practices. Therefore, it can be affected not only by salt-water intrusion, but by the salinization of its groundwater also due to other factors. All these factors have led the Pontina Plain to a groundwater situation which makes the groundwater resource management and the planning of their future exploitation very difficult.展开更多
This paper is aimed at verifying utilization possibilities of alkaline modified coal fly ash as cement replacement in the concrete. The influence of alkaline activated coal fly ash originating from Slovakian power pla...This paper is aimed at verifying utilization possibilities of alkaline modified coal fly ash as cement replacement in the concrete. The influence of alkaline activated coal fly ash originating from Slovakian power plant in Novsky （Si/Al = 3,1） as a partial cement replacement in concrete on compressive strength of hardened composites after 28 and 90 days was investigated. Alkaline activation of coal fly ash was realized in an autoclave at 130 ℃ and pressure of 160 kPa during 5 hours and in a reactor under normal conditions （equal temperature during 36 hours） at solid/liquid ratio of 0.5. Coal fly ash/cement mixtures were prepared with 25 % cement replacement by starting and modified coal fly ash and given in forms. Compressive strengths of composites after 28 and 90 days of hardening were compared to referential composite without coal fly ash and evaluated according to the standard of STN EN 450 by the value of relative strength KR （compressive strength of coal fly ash/cement composite to compressive strength of comparative concrete）. The final compressive strengths of hardened composites based on alkaline activated coal fly ash reached values in the range of 6 up to 50 MPa. In the set of experimental composites based on alkaline activated coal fly ashes, the highest value of relative strength after 28- and 90- days of hardening reached composite with cement replacement by coal fly ash zeolitized in autoclave （105% of compressive strength of referential sample）, what is connected with formation of zeolitic phases on surface of coal fly ash particles. The achieved results confirm that alkaline activation of coal fly ash in an autoclave under observed conditions can be successfully used as a partial cement replacement in concrete of C20/25 and C25/30 in accordance with requirements of standards （STN EN 450 and STN EN 206）.展开更多
The issue of the building materials biocorrosion has a significant economic dimension because it results in the costly repair. The start and the course of corrosion are conditioned by many factors which undoubtedly in...The issue of the building materials biocorrosion has a significant economic dimension because it results in the costly repair. The start and the course of corrosion are conditioned by many factors which undoubtedly include biological effects like the influence of vegetation and microorganisms causing the so called microbial corrosion. Microorganisms have also a considerable share in the decay and degradation of different building materials. The activity of sulphuratum is the keystone of many processes in nature and in industry. The sulphuric bacteria oxidize hydrogen sulphide produced by sulphate-reducing bacteria into sulphuric acid resulting in the acid or sulphate corrosion of cement stone. The paper is aimed on evaluation of porosity and roughness of concrete samples surface as elementary characteristics of microbial corrosion. After 4 months exposure to the real conditions in sewers deposition the changes were observed by confocal laser microscopy and consequently analyzed and interpreted.展开更多
Hemodynamics plays a crucial role in the growth of an abdominal aortic aneurysm(AAA)and its possible rupture.Due to the serious consequences that arise from the aneurysm rupture,the ability to predict its evolution an...Hemodynamics plays a crucial role in the growth of an abdominal aortic aneurysm(AAA)and its possible rupture.Due to the serious consequences that arise from the aneurysm rupture,the ability to predict its evolution and the need for surgery are of primary importance in the medical field.Furthermore,the presence of intraluminal thrombus(ILT)strongly affects the evolution of the pathology.In this study,we analyzed the influence of hemodynamics on the growth and possible rupture of AAAs.Numerical investigations of pulsatile non-Newtonian blood flow were performed in six patient-specific AAAs reconstructed from diagnostic images,having different sizes and shapes,and with or without ILT.Wall shear stress and vorticity distribution in the bulge and their evolution during the cardiac cycle were analyzed.The results indicate that blood flow dynamics acts synergistically with atherosclerotic degeneration in the development of the disease.The high surface complexity and tortuosity of the aneurysms significantly affect the blood motion,and the presence of inflection in the aneurysm centerline has a noticeable effect on the vortex dynamics.Links between regions of slow recirculating flows,low values of time-averaged wall shear stress,high values of oscillatory shear index,and zones of ILT deposition were found.In the absence of ILT,possible thrombus accumulation areas and consequent aneurysm growth were identified.The findings of this study highlight the importance of hemodynamics in assessing the vulnerability of the aortic wall and underline the crucial role of patient-specific investigations in predicting the rupture of individual aneurysms.展开更多
In the evaluation of road roughness and its effects on vehicles response in terms of ride quality, loads induced on pavement, drivers＇ comfort, etc., it is very common to generate road profles based on the equation p...In the evaluation of road roughness and its effects on vehicles response in terms of ride quality, loads induced on pavement, drivers＇ comfort, etc., it is very common to generate road profles based on the equation provided by ISO 8608 standard, according to which it is possible to group road surface profiles into eight different classes. However, real profiles are significantly different from the artificial ones because of the non-stationary fea- ture of the first ones and the not full capability of the ISO 8608 equation to correctly describe the frequency content of real road profiles. In this paper, the international roughness index, the frequency-weighted vertical acceleration awz according to ISO 2631, and the dynamic load index are applied both on artificial and real profiles, highlighting the different results obtained. The analysis carried out in this work has highlighted some limitation of the ISO 8608 approach in the description of performance and conditions of real pavement profiles. Furthermore, the different sensitivity of the various indices to the fitted power spectral density parameters is shown, which should be taken into account when performing analysis using artificial profiles.展开更多
The estimate of seismic site effects by experimental approaches is based on different assumptions aimed at simplifying the complex actual site conditions and related uncertainties.However,the reliability of the result...The estimate of seismic site effects by experimental approaches is based on different assumptions aimed at simplifying the complex actual site conditions and related uncertainties.However,the reliability of the results can increase if the experimental data is focused on quite strong seismic sequences and the on-site acquisition of a large number of signals is deemed strategic for the assessment of the expected phenomena.Based on these considerations,the ground motion at the Red Zone sector of Amatrice hill,violently struck by the 2016-2017 Central Italy seismic sequence,was analyzed via an observational approach.A large set of weak motions(moment magnitude Mw 2.5-3.9)was analyzed in this study by means of standard(SSR)and horizontal to vertical(HVSR)spectral ratio techniques.The results from the experimental analysis of the site effects by using weak motion and noise signals show a significant amplification at the top of Amatrice hill with a remarkable polarization of the motion and changes in spectral shapes according to the topographic setting of the relief.展开更多
This paper summarizes the selected results of an extensive investigation of application of two methods （hydrothermal and mechanochemical） assisted by calcination for synthesizing belite cement from reactive mixtures...This paper summarizes the selected results of an extensive investigation of application of two methods （hydrothermal and mechanochemical） assisted by calcination for synthesizing belite cement from reactive mixtures （CaO/SiO2 molar ratio of 2） consisting of various waste kinds from fluidized brown coal combustion in Slovakian power plant and CaO addition. Based on XRD diffraction patterns and infrared spectra ofpre-treatment products, the formation of the new profiles corresponding to CSH phases with low degree of ordering as belite precursors after hydrothermal treatment as well as metastables calcium silicates and aluminosilicates in mechanosynthesized products was confirmed. Calcination of hydrothermally treated products led to transformation of CSH phases to wollastonite （CS）, belite and gehlenite phase, whereas creation oft^- and I^-C2S or wollastonite in milled reactive mixture took place. Differences in phase composition of products before and after calcination depend upon waste quality and precursor＇s synthesis conditions. Bottom ash isn＇t suitable as raw material for synthesizing belite phase because of high CaO content fixed in anhydrite form （44.1%）. Coal fly ash with low CaO content in anhydrite form （4.2%） and its mechanochemical or hydrothermal treatment in combination with subsequent heating offer opportunities for the utilization of coal fly ash as raw material for belite production.展开更多
The analysis of urban drainage networks(UDNs)is one of the most important topics in the study of water systems.The interest in strategies aimed at analyzing the impacts of sewer pipes failure on the urban drainage sys...The analysis of urban drainage networks(UDNs)is one of the most important topics in the study of water systems.The interest in strategies aimed at analyzing the impacts of sewer pipes failure on the urban drainage system operation is growing,and the need of developing methodologies aimed at vulnerability assessment and system management is increasingly important.To this purpose,the present work shows and discusses the use of complex network theory.In particular,the recently developed relevance‐based centrality metrics have been used to classify UDNs and to identify the most critical pipes.First,the relevancebased degree is applied to the direct graph of the drainage network to classify the systems.Afterward,the relevance‐based edge betweenness is used for ranking the importance,that is,the criticality with respect to fluxes,for the pipes.The relevance‐based metrics assign importance to the network elements(pipes and nodes),considering both the intrinsic relevance of nodes and the network connectivity structure.Results provide useful information to support pipe maintenance programs to be prepared for malfunctioning events by means of a criticality analysis in advance.The relevance‐based metrics are presented by using the direct graph of a simple example network,and they are then applied both to a benchmark and a real urban drainage system to show the effectiveness even for real systems.展开更多
Submerged vanes are low-height flow-training structures emerging from the riverbed with a suitable angle of attack to the incoming flow. These structures redirect the stream flow and modify erosion and depositional ra...Submerged vanes are low-height flow-training structures emerging from the riverbed with a suitable angle of attack to the incoming flow. These structures redirect the stream flow and modify erosion and depositional rates in the bottom and in the banks of a river as a result of the secondary currents generated by their installation. For this reason they have many applica- tions in river hydraulics for controlling river bed morphology. An experimental investigation is carried out to compare the effi- ciency of sheet-piling vanes versus thin plane ones in controlling sediment redistribution in the channel bed. In particular, exper- imental tests were carried out within a straight water channel, in conditions of bed load motion. The morphology of the river bed both in the area close to the structure and in the far field was examined at different angles of attack of the vane to the incoming flow and at different values of the submergence parameter, which is the ratio between the height of the water above the structure and the water level. The experimental results show that both the shape of the vanes as well as the angle of attack affect their per- formance in terms of the effects on the bed morphology, especially for greater submergence parameters. Specifically, plane and sheet-piling vanes produce comparable remodelings of the channel bed in the downstream region, but when the attack angle is increased, the thin plane vane causes deeper scour holes close to the structure. This last effect is probably due to the increased erosive capacity of the horseshoe vortex associated with the plane vane, while the uneven surface of the sheet-piling vane miti- gates the erosive strength of that vortex.展开更多
The focus of this study is to explore the statis-tical distribution models of high-speed railway (HSR) train delays. Based on actual HSR operational data, the delay causes and their classification, delay frequency, nu...The focus of this study is to explore the statis-tical distribution models of high-speed railway (HSR) train delays. Based on actual HSR operational data, the delay causes and their classification, delay frequency, number of affected trains, and space–time delay distributions are discussed. Eleven types of delay events are classified, and a detailed analysis of delay distribution for each classifica-tion is presented. Models of delay probability delay prob-ability distribution for each cause are proposed. Different distribution functions, including the lognormal, exponen-tial, gamma, uniform, logistic, and normal distribution, were selected to estimate and model delay patterns. The most appropriate distribution, which can approximate the delay duration corresponding to each cause, is derived. Subsequently, the Kolmogorov–Smirnov (K–S) test was used to test the goodness of fit of different train delay distribution models and the associated parameter values. The test results show that the distribution of the test data is consistent with that of the selected models. The fitting distribution models show the execution effect of the timetable and help in finding out the potential conflicts in real-time train operations.展开更多
In Italy, the writings of Kevin Lynch (1918-1984) have had great influence. However, if The Image of the City (1960, trans. 1964) enjoyed a prolonged success, other texts attracted a fluctuating attention. The reasons...In Italy, the writings of Kevin Lynch (1918-1984) have had great influence. However, if The Image of the City (1960, trans. 1964) enjoyed a prolonged success, other texts attracted a fluctuating attention. The reasons for this variable interest help reflect on the current usability of Lynch’s lesson: the relevance given to social perception;the need to give voice to citizens’ needs;a performance approach to the project as a participatory process. The ability to stimulate a reflective attitude explains why, in Italy, Lynch’s legacy has found its major expression in teaching. Recent experiences at the Universities of Rome and Trieste – also suggested by the Lynch’s centennial – show how his texts still constitute a reference to approach urban analysis and design, being completely involved in the physical perception of the places and listening to the inhabitants’ stories. Didactic activities highlight further exploitation of Lynch’s theory in terms of: the importance of learning by interaction;a better understanding of urban space and social practices;the drawing of projects from mental maps. Nonetheless, when working in the historical parts of Italian cities, the character and uses of urban spaces urge us to adjust Lynch’s categories, thus, in fact, confirming their critical capacity and timeliness.展开更多
The start and the course of bio-corrosion are conditioned by many factors which include biological effects like the influence of vegetation and microorganisms causing the deterioration of materials. The influence of b...The start and the course of bio-corrosion are conditioned by many factors which include biological effects like the influence of vegetation and microorganisms causing the deterioration of materials. The influence of bacteria causing the deterioration of concrete has been linked to the generation of biogenic sulphuric and nitric acids which originate in corrosion process by dissolution of calcium containing minerals from the concrete matrices. This paper primarily focuses on the investigation of influence of sulphur-oxidising bacteria Acidithiobacillus thiooxidans and sulphate-reducing bacteria Desulfovibrio desulfuricans at the resistance degree of cement composites. Various concrete composites with 5% addition of black coal fly ash as cement replacement as well as the reference samples without coal fly ash addition were studied in the experiments environments of sewage system proceeded during 90 days. The The laboratory experiments as well as experiments in situ in real corrosion was manifested by surface changes and weight changes of cement composites samples as well as changes in pH values of leachates. Considerable surface changes were detected in all investigated samples by microscopic methods. Crystals precipitated on concrete samples surface were identified by EDX as mixture of gypsum and ettringite. The roughness increases of surface of cement microscopy. composites were determined by confocal laser scanning展开更多
In this paper, the results of an extensive investigation of hydrothermal pre-treatment for synthesizing belite phase from reactive mixtures （CaO/SiO2 molar ratio of 2） consisting of one waste kinds （bottom ash-BA o...In this paper, the results of an extensive investigation of hydrothermal pre-treatment for synthesizing belite phase from reactive mixtures （CaO/SiO2 molar ratio of 2） consisting of one waste kinds （bottom ash-BA or fly ash-FA） from fluidised brown coal combustion in Slovakian power plant and CaO （analytical grade reagent） addition are summarized. Changes in structure and phase composition of hydrothermally synthesized belite precursors and subsequent calcinated products were compared with those of starting mixtures. Based on XRD diffraction patterns, the formation of the new profiles corresponding to CSH phases with low degree of ordering as belite precursors after hydrothermal treatment was confirmed. Calcination of hydrotermally treated products at 900℃ led to transformation of CSH phases to wollastonite, belite and gehlenite phase. Differences in phase composition of products before and after calcination depend upon waste quality and precursor＇s synthesis conditions. Bottom ash isn＇t suitable as raw material for synthesizing belite phase because of high CaO content fixed in anhydrite form （44.1%）. Coal fly ash with low CaO content in anhydrite form （4.2%） and its hydrothermal treatment in combination with subsequent heating offer opportunities for the utilization of coal fly ash as raw material for belite production.展开更多
In this paper,it presented the results of experimental study of utilization of MgO cement as calcium hydrate replacement in lightweight composites based on hemp shives.The results of selected characteristics(compressi...In this paper,it presented the results of experimental study of utilization of MgO cement as calcium hydrate replacement in lightweight composites based on hemp shives.The results of selected characteristics(compressive strength and coefficient of thermal conductivity)of hardened composites show that MgO cement based on the milled caustic magnesite is suitable alternative in comparison to conventional binders used in hemp concrete.This material leads to new environmentally products as non-load bearing building materials.展开更多
This study explores the essential issues pertaining to a landscape bridge based on a multi-scale methodology,in view of the paucity of design theories for contemporary landscape bridges.We contribute to reinterpret la...This study explores the essential issues pertaining to a landscape bridge based on a multi-scale methodology,in view of the paucity of design theories for contemporary landscape bridges.We contribute to reinterpret landscape bridges on their physical temporal-spatial scales,instead of from perspectives of individual disciplines or their mechanical cooperation.Envisaged in a new systematized framework,we elaborate the dominant and their opposite counterparts of landscape bridges from a binary deconstruction point of view,i.e.,(1)Development and retrogression on the temporal scale,(2)connection and separation on the spatial topographic scale,(3)skyphilia and topophilia on the spatial landscape scale,and(4)extroversion and introversion on the spatial architectural scale.The deconstructed multifaceted scales are instrumental in understanding landscape bridges from various perspectives,with a pyramid model proposed afterward to mediate the discovered oppositions and stimulate the cross-scale interactions.Various possible design paths could be derived from this well-organized and openminded multiple system,which is initially expected in this study to inspire bridge designers with dissimilar backgrounds and calls for a wider ramification.展开更多
Although the construction of block pavements has grown fast in the last decades,there is still a need for simple tools that could be applied to design them.This paper analyzed and verified concrete block pavements for...Although the construction of block pavements has grown fast in the last decades,there is still a need for simple tools that could be applied to design them.This paper analyzed and verified concrete block pavements for urban and local roads composed of rectangular concrete pavers with plane side surfaces(no interlocking effect).The examined blocks were laid on a bedding sand layer,a cement treated base layer and a granular unbound foundation layer.The commercial finite element(FE)software ANSYS?was used to calculate the response of the pavement when subjected to different loading,construction configurations.Three wheel positions,five blocks patterns,three bedding sand thicknesses and joints gaps have been considered to evaluate stress-strain condition on pavement materials.Fatigue and rutting verification was performed respectively for bound and unbound pavement materials using analytical curves available in the literature.At the end of this study,a proposal for a catalogue is presented.It has nine pavement sets,because it takes into account three values of subgrade capacity(30,90,and 150 MPa of resilient modulus)and three levels of traffic(400,000,1,500,000,and 4,000,000 passages of commercial vehicles during the service life).The obtained results provide an inexpensive procedure for the preliminary design of concrete block pavements.展开更多
Home-to-school routes are very sensitive areas: they represent, for children, a learning tool for their everyday activities, but if poorly designed, maintained and equipped they can expose them to traffic risks. Sidew...Home-to-school routes are very sensitive areas: they represent, for children, a learning tool for their everyday activities, but if poorly designed, maintained and equipped they can expose them to traffic risks. Sidewalks' inappropriate level of service and poor maintenance, especially, are main factors contributing to walking unsuitability, thus to poor comfort and safety levels for young pedestrians, and more in general for all the vulnerable non-motorized road users. This paper deals with a methodology specifically developed to highlight the quality of the urban environment where the home-to-school routes are located, according to four main criteria: wellbeing, usage, appearance, and safety and security. Each criterion is associated with a checklist including the most relevant features to assess, with a focus on maintenance as a key parameter to create safe and comfortable routes to school. An application, a case study in Rome, where the lack of regular maintenance results into a network of unsafe sidewalks, is also presented, analyzing three different areas where a number of schools are located. Detours when approaching school premises were surveyed, due to the levels of distresses and linked to the poor comfort and safety levels. As the mutual influence of built environment over road safety and maintenance requirements for home-to-school paths is not largely investigated thus far, the paper's goal is to provide advanced knowledge for studies and applications further afield.展开更多
The attention to road safety-related issues has grown fast in recent decades. The experi- ence gained with these themes reveals the importance of considering these aspects in the resource allocation process for roadsi...The attention to road safety-related issues has grown fast in recent decades. The experi- ence gained with these themes reveals the importance of considering these aspects in the resource allocation process for roadside and guardrail improvement, which is a complex process often involves conflicting objectives. This work consists on defining an innovative methodology, with the objective of calculating and analysing a numerical risk factor of a road. The method considers geometry, accident rate, traffic of the examined road and four categories of elements/defects where the resources can be allocated to improve the road safety （safety barriers, discrete obstacles, continuous obstacles, and water drainage）. The analysis allows the assessment of the hazard index, which could be used in decision- making processes. A case study is presented to analyse roadsides of a 995 km long road network, using the cost-benefit analysis, and to prioritize possible rehabilitation work. The results highlighted that it is suitable to intervene on roads belonging to higher classes of risk, where it is possible to maximize the benefit in terms of safety as consequence of rehabilitation works （i.e., new barrier installation, removal and new barrier installation, and new terminal installation）. The proposed method is quantitative; therefore, it avoids providing weak and far from reliable results; moreover, it guarantees a broad vision for the problem, giving a useful tool for road management body.展开更多
Comfort is a major requirement in planning pedestrian facilities. Pedestrians walk where they feel comfortable and when they do not feel at ease, they walk elsewhere. A typical example is that filthy, distressed, or t...Comfort is a major requirement in planning pedestrian facilities. Pedestrians walk where they feel comfortable and when they do not feel at ease, they walk elsewhere. A typical example is that filthy, distressed, or too narrow sidewalks induce pedestrians to walk on carriageways. This behaviour jeopardizes road safety and highly dangerous to most users, leave them vulnerable. Unsuitable pavements can be the result of irregular maintenance operations to restore evenness after shock damage, weather phenomena, installation of equipment （e.g., posts, fences, urban furniture） with a reduction of walkable surface, or substandard repair work on pavements and patches due to emergency operations. These problems can be solved with an appropriate maintenance management system, which optimizes financial resources to make smart decisions about how to intervene with an adequate and lasting maintenance operation. This paper defines an evaluation index for sidewalk conditions as a part of an efficient set-up of a Sidewalk Management System, which is similar to the better known Road Management System. The study relies on sur- veys, as well as the classification and analysis of sidewalk distresses. The authors adapted an index already standardized by ASTM for roads and airports： the Pavement Condition Index （PCI）. PCI has been modified to consider the specific types on the sidewalks studied within this paper. To validate the method, a case study of a residential district in Rome, Italy, was carried out. The chosen area lacks regular maintenance and has therefore resulted in a network of unsafe sidewalks. Frequent detour routes were surveyed and related to the level of distresses within a general assessment of safety. This study con- centrates on sidewalks with flexible pavements because this type of pavement is the only one adopted in the survey areas and, in general, throughout Italy.展开更多
基金Sponsored by the Supporting Project of Sichuan Province Key Technology Support Program (2011ZG0247)Sichuan Province Education Office Natural Science Foundation (10ZC080)
文摘The geometric structures,electronic absorption spectrum,and thermodynamic pro-perties of 3-（4-N-maleimido）-phenyl-2,4-dihydro-2H-1,3-benzoxazine molecule were studied at the B3LYP/6-311＋G＊ level by density functional theory.The results show that three rings of this molecule are in different planes.In gas,absorption wavelength of the lowest energy excitation was obtained at 503 nm,and solvents made it blue-shifted by 3-7 nm,both corresponding to the electron transition of HOMO → LUMO.At 298.15 K,the standard molar formed enthalpy and free energy of the title compound molecule were-549.43 and-273.37 kJ·mol-1,respectively.
文摘This paper presents the results of the investigations, driven by different techniques, including environmental tracers and geophysical methods, in the aim of better understand the causes of the current salt-water intrusion in the Pontina Plain, in the south of the Lazio Region (Italy). In the last 50 years many investigation campaigns have been carried out to evaluate the evolution of salt-water intrusion. This is an area with a strong man-made residential and tourist impact and, in the some cases, it is characterized by intensive agricultural practices. Therefore, it can be affected not only by salt-water intrusion, but by the salinization of its groundwater also due to other factors. All these factors have led the Pontina Plain to a groundwater situation which makes the groundwater resource management and the planning of their future exploitation very difficult.
文摘This paper is aimed at verifying utilization possibilities of alkaline modified coal fly ash as cement replacement in the concrete. The influence of alkaline activated coal fly ash originating from Slovakian power plant in Novsky （Si/Al = 3,1） as a partial cement replacement in concrete on compressive strength of hardened composites after 28 and 90 days was investigated. Alkaline activation of coal fly ash was realized in an autoclave at 130 ℃ and pressure of 160 kPa during 5 hours and in a reactor under normal conditions （equal temperature during 36 hours） at solid/liquid ratio of 0.5. Coal fly ash/cement mixtures were prepared with 25 % cement replacement by starting and modified coal fly ash and given in forms. Compressive strengths of composites after 28 and 90 days of hardening were compared to referential composite without coal fly ash and evaluated according to the standard of STN EN 450 by the value of relative strength KR （compressive strength of coal fly ash/cement composite to compressive strength of comparative concrete）. The final compressive strengths of hardened composites based on alkaline activated coal fly ash reached values in the range of 6 up to 50 MPa. In the set of experimental composites based on alkaline activated coal fly ashes, the highest value of relative strength after 28- and 90- days of hardening reached composite with cement replacement by coal fly ash zeolitized in autoclave （105% of compressive strength of referential sample）, what is connected with formation of zeolitic phases on surface of coal fly ash particles. The achieved results confirm that alkaline activation of coal fly ash in an autoclave under observed conditions can be successfully used as a partial cement replacement in concrete of C20/25 and C25/30 in accordance with requirements of standards （STN EN 450 and STN EN 206）.
文摘The issue of the building materials biocorrosion has a significant economic dimension because it results in the costly repair. The start and the course of corrosion are conditioned by many factors which undoubtedly include biological effects like the influence of vegetation and microorganisms causing the so called microbial corrosion. Microorganisms have also a considerable share in the decay and degradation of different building materials. The activity of sulphuratum is the keystone of many processes in nature and in industry. The sulphuric bacteria oxidize hydrogen sulphide produced by sulphate-reducing bacteria into sulphuric acid resulting in the acid or sulphate corrosion of cement stone. The paper is aimed on evaluation of porosity and roughness of concrete samples surface as elementary characteristics of microbial corrosion. After 4 months exposure to the real conditions in sewers deposition the changes were observed by confocal laser microscopy and consequently analyzed and interpreted.
文摘Hemodynamics plays a crucial role in the growth of an abdominal aortic aneurysm(AAA)and its possible rupture.Due to the serious consequences that arise from the aneurysm rupture,the ability to predict its evolution and the need for surgery are of primary importance in the medical field.Furthermore,the presence of intraluminal thrombus(ILT)strongly affects the evolution of the pathology.In this study,we analyzed the influence of hemodynamics on the growth and possible rupture of AAAs.Numerical investigations of pulsatile non-Newtonian blood flow were performed in six patient-specific AAAs reconstructed from diagnostic images,having different sizes and shapes,and with or without ILT.Wall shear stress and vorticity distribution in the bulge and their evolution during the cardiac cycle were analyzed.The results indicate that blood flow dynamics acts synergistically with atherosclerotic degeneration in the development of the disease.The high surface complexity and tortuosity of the aneurysms significantly affect the blood motion,and the presence of inflection in the aneurysm centerline has a noticeable effect on the vortex dynamics.Links between regions of slow recirculating flows,low values of time-averaged wall shear stress,high values of oscillatory shear index,and zones of ILT deposition were found.In the absence of ILT,possible thrombus accumulation areas and consequent aneurysm growth were identified.The findings of this study highlight the importance of hemodynamics in assessing the vulnerability of the aortic wall and underline the crucial role of patient-specific investigations in predicting the rupture of individual aneurysms.
文摘In the evaluation of road roughness and its effects on vehicles response in terms of ride quality, loads induced on pavement, drivers＇ comfort, etc., it is very common to generate road profles based on the equation provided by ISO 8608 standard, according to which it is possible to group road surface profiles into eight different classes. However, real profiles are significantly different from the artificial ones because of the non-stationary fea- ture of the first ones and the not full capability of the ISO 8608 equation to correctly describe the frequency content of real road profiles. In this paper, the international roughness index, the frequency-weighted vertical acceleration awz according to ISO 2631, and the dynamic load index are applied both on artificial and real profiles, highlighting the different results obtained. The analysis carried out in this work has highlighted some limitation of the ISO 8608 approach in the description of performance and conditions of real pavement profiles. Furthermore, the different sensitivity of the various indices to the fitted power spectral density parameters is shown, which should be taken into account when performing analysis using artificial profiles.
文摘The estimate of seismic site effects by experimental approaches is based on different assumptions aimed at simplifying the complex actual site conditions and related uncertainties.However,the reliability of the results can increase if the experimental data is focused on quite strong seismic sequences and the on-site acquisition of a large number of signals is deemed strategic for the assessment of the expected phenomena.Based on these considerations,the ground motion at the Red Zone sector of Amatrice hill,violently struck by the 2016-2017 Central Italy seismic sequence,was analyzed via an observational approach.A large set of weak motions(moment magnitude Mw 2.5-3.9)was analyzed in this study by means of standard(SSR)and horizontal to vertical(HVSR)spectral ratio techniques.The results from the experimental analysis of the site effects by using weak motion and noise signals show a significant amplification at the top of Amatrice hill with a remarkable polarization of the motion and changes in spectral shapes according to the topographic setting of the relief.
文摘This paper summarizes the selected results of an extensive investigation of application of two methods （hydrothermal and mechanochemical） assisted by calcination for synthesizing belite cement from reactive mixtures （CaO/SiO2 molar ratio of 2） consisting of various waste kinds from fluidized brown coal combustion in Slovakian power plant and CaO addition. Based on XRD diffraction patterns and infrared spectra ofpre-treatment products, the formation of the new profiles corresponding to CSH phases with low degree of ordering as belite precursors after hydrothermal treatment as well as metastables calcium silicates and aluminosilicates in mechanosynthesized products was confirmed. Calcination of hydrothermally treated products led to transformation of CSH phases to wollastonite （CS）, belite and gehlenite phase, whereas creation oft^- and I^-C2S or wollastonite in milled reactive mixture took place. Differences in phase composition of products before and after calcination depend upon waste quality and precursor＇s synthesis conditions. Bottom ash isn＇t suitable as raw material for synthesizing belite phase because of high CaO content fixed in anhydrite form （44.1%）. Coal fly ash with low CaO content in anhydrite form （4.2%） and its mechanochemical or hydrothermal treatment in combination with subsequent heating offer opportunities for the utilization of coal fly ash as raw material for belite production.
文摘The analysis of urban drainage networks(UDNs)is one of the most important topics in the study of water systems.The interest in strategies aimed at analyzing the impacts of sewer pipes failure on the urban drainage system operation is growing,and the need of developing methodologies aimed at vulnerability assessment and system management is increasingly important.To this purpose,the present work shows and discusses the use of complex network theory.In particular,the recently developed relevance‐based centrality metrics have been used to classify UDNs and to identify the most critical pipes.First,the relevancebased degree is applied to the direct graph of the drainage network to classify the systems.Afterward,the relevance‐based edge betweenness is used for ranking the importance,that is,the criticality with respect to fluxes,for the pipes.The relevance‐based metrics assign importance to the network elements(pipes and nodes),considering both the intrinsic relevance of nodes and the network connectivity structure.Results provide useful information to support pipe maintenance programs to be prepared for malfunctioning events by means of a criticality analysis in advance.The relevance‐based metrics are presented by using the direct graph of a simple example network,and they are then applied both to a benchmark and a real urban drainage system to show the effectiveness even for real systems.
文摘Submerged vanes are low-height flow-training structures emerging from the riverbed with a suitable angle of attack to the incoming flow. These structures redirect the stream flow and modify erosion and depositional rates in the bottom and in the banks of a river as a result of the secondary currents generated by their installation. For this reason they have many applica- tions in river hydraulics for controlling river bed morphology. An experimental investigation is carried out to compare the effi- ciency of sheet-piling vanes versus thin plane ones in controlling sediment redistribution in the channel bed. In particular, exper- imental tests were carried out within a straight water channel, in conditions of bed load motion. The morphology of the river bed both in the area close to the structure and in the far field was examined at different angles of attack of the vane to the incoming flow and at different values of the submergence parameter, which is the ratio between the height of the water above the structure and the water level. The experimental results show that both the shape of the vanes as well as the angle of attack affect their per- formance in terms of the effects on the bed morphology, especially for greater submergence parameters. Specifically, plane and sheet-piling vanes produce comparable remodelings of the channel bed in the downstream region, but when the attack angle is increased, the thin plane vane causes deeper scour holes close to the structure. This last effect is probably due to the increased erosive capacity of the horseshoe vortex associated with the plane vane, while the uneven surface of the sheet-piling vane miti- gates the erosive strength of that vortex.
基金supported by the National Key R&D Plan (No.2017YFB1200701)National Nature Science Foundation of China (No.U1834209 and 71871188)the support of the Railways Technology Development Plan of China Railway Corporation (No.2016X008-J)supported by State Key Lab of Railway Control and Safety Open Topics Fund (No.RCS2019K007)
文摘The focus of this study is to explore the statis-tical distribution models of high-speed railway (HSR) train delays. Based on actual HSR operational data, the delay causes and their classification, delay frequency, number of affected trains, and space–time delay distributions are discussed. Eleven types of delay events are classified, and a detailed analysis of delay distribution for each classifica-tion is presented. Models of delay probability delay prob-ability distribution for each cause are proposed. Different distribution functions, including the lognormal, exponen-tial, gamma, uniform, logistic, and normal distribution, were selected to estimate and model delay patterns. The most appropriate distribution, which can approximate the delay duration corresponding to each cause, is derived. Subsequently, the Kolmogorov–Smirnov (K–S) test was used to test the goodness of fit of different train delay distribution models and the associated parameter values. The test results show that the distribution of the test data is consistent with that of the selected models. The fitting distribution models show the execution effect of the timetable and help in finding out the potential conflicts in real-time train operations.
文摘In Italy, the writings of Kevin Lynch (1918-1984) have had great influence. However, if The Image of the City (1960, trans. 1964) enjoyed a prolonged success, other texts attracted a fluctuating attention. The reasons for this variable interest help reflect on the current usability of Lynch’s lesson: the relevance given to social perception;the need to give voice to citizens’ needs;a performance approach to the project as a participatory process. The ability to stimulate a reflective attitude explains why, in Italy, Lynch’s legacy has found its major expression in teaching. Recent experiences at the Universities of Rome and Trieste – also suggested by the Lynch’s centennial – show how his texts still constitute a reference to approach urban analysis and design, being completely involved in the physical perception of the places and listening to the inhabitants’ stories. Didactic activities highlight further exploitation of Lynch’s theory in terms of: the importance of learning by interaction;a better understanding of urban space and social practices;the drawing of projects from mental maps. Nonetheless, when working in the historical parts of Italian cities, the character and uses of urban spaces urge us to adjust Lynch’s categories, thus, in fact, confirming their critical capacity and timeliness.
文摘The start and the course of bio-corrosion are conditioned by many factors which include biological effects like the influence of vegetation and microorganisms causing the deterioration of materials. The influence of bacteria causing the deterioration of concrete has been linked to the generation of biogenic sulphuric and nitric acids which originate in corrosion process by dissolution of calcium containing minerals from the concrete matrices. This paper primarily focuses on the investigation of influence of sulphur-oxidising bacteria Acidithiobacillus thiooxidans and sulphate-reducing bacteria Desulfovibrio desulfuricans at the resistance degree of cement composites. Various concrete composites with 5% addition of black coal fly ash as cement replacement as well as the reference samples without coal fly ash addition were studied in the experiments environments of sewage system proceeded during 90 days. The The laboratory experiments as well as experiments in situ in real corrosion was manifested by surface changes and weight changes of cement composites samples as well as changes in pH values of leachates. Considerable surface changes were detected in all investigated samples by microscopic methods. Crystals precipitated on concrete samples surface were identified by EDX as mixture of gypsum and ettringite. The roughness increases of surface of cement microscopy. composites were determined by confocal laser scanning
文摘In this paper, the results of an extensive investigation of hydrothermal pre-treatment for synthesizing belite phase from reactive mixtures （CaO/SiO2 molar ratio of 2） consisting of one waste kinds （bottom ash-BA or fly ash-FA） from fluidised brown coal combustion in Slovakian power plant and CaO （analytical grade reagent） addition are summarized. Changes in structure and phase composition of hydrothermally synthesized belite precursors and subsequent calcinated products were compared with those of starting mixtures. Based on XRD diffraction patterns, the formation of the new profiles corresponding to CSH phases with low degree of ordering as belite precursors after hydrothermal treatment was confirmed. Calcination of hydrotermally treated products at 900℃ led to transformation of CSH phases to wollastonite, belite and gehlenite phase. Differences in phase composition of products before and after calcination depend upon waste quality and precursor＇s synthesis conditions. Bottom ash isn＇t suitable as raw material for synthesizing belite phase because of high CaO content fixed in anhydrite form （44.1%）. Coal fly ash with low CaO content in anhydrite form （4.2%） and its hydrothermal treatment in combination with subsequent heating offer opportunities for the utilization of coal fly ash as raw material for belite production.
文摘In this paper,it presented the results of experimental study of utilization of MgO cement as calcium hydrate replacement in lightweight composites based on hemp shives.The results of selected characteristics(compressive strength and coefficient of thermal conductivity)of hardened composites show that MgO cement based on the milled caustic magnesite is suitable alternative in comparison to conventional binders used in hemp concrete.This material leads to new environmentally products as non-load bearing building materials.
基金This work was supported by the Postgraduate Research&Practice Innovation Program of Jiangsu Province,China(KYCX18_0162).
文摘This study explores the essential issues pertaining to a landscape bridge based on a multi-scale methodology,in view of the paucity of design theories for contemporary landscape bridges.We contribute to reinterpret landscape bridges on their physical temporal-spatial scales,instead of from perspectives of individual disciplines or their mechanical cooperation.Envisaged in a new systematized framework,we elaborate the dominant and their opposite counterparts of landscape bridges from a binary deconstruction point of view,i.e.,(1)Development and retrogression on the temporal scale,(2)connection and separation on the spatial topographic scale,(3)skyphilia and topophilia on the spatial landscape scale,and(4)extroversion and introversion on the spatial architectural scale.The deconstructed multifaceted scales are instrumental in understanding landscape bridges from various perspectives,with a pyramid model proposed afterward to mediate the discovered oppositions and stimulate the cross-scale interactions.Various possible design paths could be derived from this well-organized and openminded multiple system,which is initially expected in this study to inspire bridge designers with dissimilar backgrounds and calls for a wider ramification.
文摘Although the construction of block pavements has grown fast in the last decades,there is still a need for simple tools that could be applied to design them.This paper analyzed and verified concrete block pavements for urban and local roads composed of rectangular concrete pavers with plane side surfaces(no interlocking effect).The examined blocks were laid on a bedding sand layer,a cement treated base layer and a granular unbound foundation layer.The commercial finite element(FE)software ANSYS?was used to calculate the response of the pavement when subjected to different loading,construction configurations.Three wheel positions,five blocks patterns,three bedding sand thicknesses and joints gaps have been considered to evaluate stress-strain condition on pavement materials.Fatigue and rutting verification was performed respectively for bound and unbound pavement materials using analytical curves available in the literature.At the end of this study,a proposal for a catalogue is presented.It has nine pavement sets,because it takes into account three values of subgrade capacity(30,90,and 150 MPa of resilient modulus)and three levels of traffic(400,000,1,500,000,and 4,000,000 passages of commercial vehicles during the service life).The obtained results provide an inexpensive procedure for the preliminary design of concrete block pavements.
文摘Home-to-school routes are very sensitive areas: they represent, for children, a learning tool for their everyday activities, but if poorly designed, maintained and equipped they can expose them to traffic risks. Sidewalks' inappropriate level of service and poor maintenance, especially, are main factors contributing to walking unsuitability, thus to poor comfort and safety levels for young pedestrians, and more in general for all the vulnerable non-motorized road users. This paper deals with a methodology specifically developed to highlight the quality of the urban environment where the home-to-school routes are located, according to four main criteria: wellbeing, usage, appearance, and safety and security. Each criterion is associated with a checklist including the most relevant features to assess, with a focus on maintenance as a key parameter to create safe and comfortable routes to school. An application, a case study in Rome, where the lack of regular maintenance results into a network of unsafe sidewalks, is also presented, analyzing three different areas where a number of schools are located. Detours when approaching school premises were surveyed, due to the levels of distresses and linked to the poor comfort and safety levels. As the mutual influence of built environment over road safety and maintenance requirements for home-to-school paths is not largely investigated thus far, the paper's goal is to provide advanced knowledge for studies and applications further afield.
文摘The attention to road safety-related issues has grown fast in recent decades. The experi- ence gained with these themes reveals the importance of considering these aspects in the resource allocation process for roadside and guardrail improvement, which is a complex process often involves conflicting objectives. This work consists on defining an innovative methodology, with the objective of calculating and analysing a numerical risk factor of a road. The method considers geometry, accident rate, traffic of the examined road and four categories of elements/defects where the resources can be allocated to improve the road safety （safety barriers, discrete obstacles, continuous obstacles, and water drainage）. The analysis allows the assessment of the hazard index, which could be used in decision- making processes. A case study is presented to analyse roadsides of a 995 km long road network, using the cost-benefit analysis, and to prioritize possible rehabilitation work. The results highlighted that it is suitable to intervene on roads belonging to higher classes of risk, where it is possible to maximize the benefit in terms of safety as consequence of rehabilitation works （i.e., new barrier installation, removal and new barrier installation, and new terminal installation）. The proposed method is quantitative; therefore, it avoids providing weak and far from reliable results; moreover, it guarantees a broad vision for the problem, giving a useful tool for road management body.
文摘Comfort is a major requirement in planning pedestrian facilities. Pedestrians walk where they feel comfortable and when they do not feel at ease, they walk elsewhere. A typical example is that filthy, distressed, or too narrow sidewalks induce pedestrians to walk on carriageways. This behaviour jeopardizes road safety and highly dangerous to most users, leave them vulnerable. Unsuitable pavements can be the result of irregular maintenance operations to restore evenness after shock damage, weather phenomena, installation of equipment （e.g., posts, fences, urban furniture） with a reduction of walkable surface, or substandard repair work on pavements and patches due to emergency operations. These problems can be solved with an appropriate maintenance management system, which optimizes financial resources to make smart decisions about how to intervene with an adequate and lasting maintenance operation. This paper defines an evaluation index for sidewalk conditions as a part of an efficient set-up of a Sidewalk Management System, which is similar to the better known Road Management System. The study relies on sur- veys, as well as the classification and analysis of sidewalk distresses. The authors adapted an index already standardized by ASTM for roads and airports： the Pavement Condition Index （PCI）. PCI has been modified to consider the specific types on the sidewalks studied within this paper. To validate the method, a case study of a residential district in Rome, Italy, was carried out. The chosen area lacks regular maintenance and has therefore resulted in a network of unsafe sidewalks. Frequent detour routes were surveyed and related to the level of distresses within a general assessment of safety. This study con- centrates on sidewalks with flexible pavements because this type of pavement is the only one adopted in the survey areas and, in general, throughout Italy.
