Persulfate(PS)is a widely used oxidant for the chemical oxidation of organic pollutants.The accurate measurement of PS concentration is crucial for the practical application process.The iodometry is the most recommend...Persulfate(PS)is a widely used oxidant for the chemical oxidation of organic pollutants.The accurate measurement of PS concentration is crucial for the practical application process.The iodometry is the most recommended method for PS determination,and its principle is based on the redox reaction between S_(2)O_(8)^(2−)and iodide ions.However,hydrogen peroxide(H_(2)O_(2)),an important intermediate product in the process of PS use,often leads to abnormally high determination concentrations of PS.Given this,a novel method was developed for the determination of PS based on the principle of the oxidation of chloride ion(Cl^(−)).The concentration of PS is calculated according to the consumption of Cl^(−)concentration,which is not disturbed by H_(2)O_(2).The optimized test conditions were explored as:C(H^(+))=2 mol/L,T=80◦C,C(Cl^(−)):C(PS)=4:1 and t=30 min.Under the optimized conditions,the limit of detection and the limit of quantification of PS concentration determined by this method were 0.26 and 0.85 g/L,respectively.And the linear range of the PS determination was 1–100 g/L with an error of 0.53%-12.06%.The spike recovery rate for determining PS concentration in the actual wastewater ranged from 94.07%-109.52%.Interfering factors such as H_(2)O_(2),Fe^(3+),MnO_(2)and natural organic matter had almost no effect on the results.This method could not only accurately determine the concentration of PS in industrial wastewater,but also determine the purity of PS industrial products.展开更多
The development of highly active carbon material catalysts in catalytic wet air oxidation（CWAO）has attracted a great deal of attention. In this study different carbon material catalysts（multi-walled carbon nanotube...The development of highly active carbon material catalysts in catalytic wet air oxidation（CWAO）has attracted a great deal of attention. In this study different carbon material catalysts（multi-walled carbon nanotubes,carbon fibers and graphite） were developed to enhance the CWAO of phenol in aqueous solution. The functionalized carbon materials exhibited excellent catalytic activity in the CWAO of phenol. After 60 min reaction,the removal of phenol was nearly100% over the functionalized multi-walled carbon,while it was only 14% over the purified multi-walled carbon under the same reaction conditions. Carboxylic acid groups introduced on the surface of the functionalized carbon materials play an important role in the catalytic activity in CWAO. They can promote the production of free radicals,which act as strong oxidants in CWAO. Based on the analysis of the intermediates produced in the CWAO reactions,a new reaction pathway for the CWAO of phenol was proposed in this study. There are some differences between the proposed reaction pathway and that reported in the literature. First,maleic acid is transformed directly into malonic acid. Second,acetic acid is oxidized into an unknown intermediate,which is then oxidized into CO2 and H2O. Finally,formic acid and oxalic acid can mutually interconvert when conditions are favorable.展开更多
The occurrence of antibiotics in the environment has recently raised serious concern regarding their potential threat to aquatic ecosystem and human health. In this study, the magnetic ion exchange（MIEX） resin was a...The occurrence of antibiotics in the environment has recently raised serious concern regarding their potential threat to aquatic ecosystem and human health. In this study, the magnetic ion exchange（MIEX） resin was applied for removing three commonly-used antibiotics, sulfamethoxazole（SMX）, tetracycline（TCN） and amoxicillin（AMX） from water.The results of batch experiments show that the maximum adsorption capacities on the MIEX resin for SMX, TCN and AMX were 789.32, 443.18 and 155.15 μg/m L at 25°C,respectively, which were 2–7 times that for the powdered activated carbon. The adsorption kinetics of antibiotics on the MIEX resin could be simulated by the pseudo-second-order model（R^2= 0.99）, and the adsorption isotherm data were well described by the Langmuir model（R^2= 0.97）. Solution p H exhibited a remarkable impact on the adsorption process and the absorbed concentrations of the tested antibiotics were obtained around the neutral p H.The MIEX resin could be easily regenerated by 2 mol/L Na Cl solution and maintained high adsorption removal for the tested antibiotics after regeneration. Anion exchange mechanism mainly controlled the adsorption of antibiotic and the formation of hydrogen binding between the antibiotic and resin can also result in the increase of adsorption capacity. The high adsorption capacity, fast adsorption rate and prominent reusability make the MIEX resin a potential adsorbent in the application for removing antibiotics from water.展开更多
Ni-P matrix composite coating reinforced by carbon nanotubes (CNTs) was deposit ed by electroless plating. The most important factors that influence the content of carbon nanotubes in deposits,such as agitation,surfac...Ni-P matrix composite coating reinforced by carbon nanotubes (CNTs) was deposit ed by electroless plating. The most important factors that influence the content of carbon nanotubes in deposits,such as agitation,surfactant and carbon nanot ubes concentration in the plating bath were investigated. The surface morphology,structure and properties of the Ni-P-CNTs coating were examined. It is found that the maximum content of carbon nanotubes in the deposits is independent of carbon nanotubes concentration in the plating bath when it is up to 5 mg/L. The test results show that the carbon nanotubes co-deposited do not change the str ucture of the Ni-P matrix of the composite coating,but greatly increase the ha rdness and wear resistance and decrease the friction coefficient of the Ni-P-C NTs composite coating with increasing content of carbon nanotubes in deposits.展开更多
This paper developed a fluorometric method for the sensitive determination of nonylphenol in water samples by preconcentration with zirconium doped titanium dioxide nanotubes solid phase extraction.The parameters on e...This paper developed a fluorometric method for the sensitive determination of nonylphenol in water samples by preconcentration with zirconium doped titanium dioxide nanotubes solid phase extraction.The parameters on extraction that would influence the enrichment performance such as the kind and volume of eluent,sample pH,sample flow rate,and sample volume were optimized in detail.Under the optimal conditions,the proposed method provided an excellent linear range of 1-150 mg/L and good LOD of 0.076 mg/L.The relative standard deviation（RSD,n = 6） was 2.8%.Proposed method was also used for the analysis of real water samples and the spiked recoveries were satisfied in the range of 98.7-103%.展开更多
The develop actuality and direction of FRP(fibre glass reinforced plastics) bolt in the world are analyzed The new type structure of FRP bolt was designed Trial data indicate that, all kinds of capability target o...The develop actuality and direction of FRP(fibre glass reinforced plastics) bolt in the world are analyzed The new type structure of FRP bolt was designed Trial data indicate that, all kinds of capability target of this FRP bolt all achieve and exceed the country standard, substitute present metal bolt,wood bolt and bamboo bolt and other side bolt, it can gain magnitude technology and economy benefit FRP bolt mechanization product line produce efficiency is high, its throughput a day are 750 base, this can meet demand of hit small mining company展开更多
To solve the disability of conventional model used in electrical leak location when measurement electrodes were buried under the liner, a new model of high voltage DC leak detection is developed. For single-liner land...To solve the disability of conventional model used in electrical leak location when measurement electrodes were buried under the liner, a new model of high voltage DC leak detection is developed. For single-liner landfill, the waste material layer, the geomembrane liner and the soil under the liner are simulated with infinite horizontal layers. The leak is regarded as two parts, one being negative current source at the entrance, and the other positive current source of the same size at the exit. Comparisons between the new theoretical model and conventional model show that conventional model is efficient in locating leaks in geomembane liner associating the dipole scanning above the liner but is ineffective when the measurement electrodes were buried under the liner. The new theoretical model data are in excellent agreement with experimental data not only above the liner but also under the liner.展开更多
According to the movement and change rules of mechanical structure of surrounding rock coal mass system during coal excavation, the mechanism of sudden instability and damage was found out. The criterions that disting...According to the movement and change rules of mechanical structure of surrounding rock coal mass system during coal excavation, the mechanism of sudden instability and damage was found out. The criterions that distinguishing the occurring of the pressure bump were put forward. This criteria have been applied successfully in the comprehensive prevent of pressure bumps in Tangshan colliery.展开更多
By employing numerical modeling, similar material simulation and comprehen-sive field observation, investigations were made and patterns were obtained governing surrounding-rock stress distribution and strata behavior...By employing numerical modeling, similar material simulation and comprehen-sive field observation, investigations were made and patterns were obtained governing surrounding-rock stress distribution and strata behaviors. It shows that patterns governing displacement of FMC roadway surrounding rocks and those governing deformation of supports are basically the same along the strike, but the displacements vary greatly. The front stresses affect greater areas than the lateral stresses and their limit widths of equilib-rium zones and K are almost similar. The stress transmits very deep. Our findings offer scientific basis on which to determine parameters for coal pillar retaining and for roadway out-laying, thus increasing the recovery ratio and improving the maintenance of roadway.展开更多
This article set forth two types of destructive form of stopping tunnel coal wall: destructive form in coal and destructive form in interface of coal layer. In addition, the mechanism of destruction in stopping tunnel...This article set forth two types of destructive form of stopping tunnel coal wall: destructive form in coal and destructive form in interface of coal layer. In addition, the mechanism of destruction in stopping tunnel coal wall is analyzed.展开更多
The designing method and the supporting mechanism of both bolt and small cable anchor for full seam roadway in the weaker thick coal seam are systematically analyzed, and the construction technology and the supporting...The designing method and the supporting mechanism of both bolt and small cable anchor for full seam roadway in the weaker thick coal seam are systematically analyzed, and the construction technology and the supporting results are briefly summarized.展开更多
Abstract In the study of sequence stratigraphy and litho-paleogeography, quantitative analysis, precise calculation and detailed comparison of tremendous geological data, such as field profiles, logging records and se...Abstract In the study of sequence stratigraphy and litho-paleogeography, quantitative analysis, precise calculation and detailed comparison of tremendous geological data, such as field profiles, logging records and seismic curves from different areas, are the basic requirements. In order to obtain a more reliable and precise result, this paper presents a novel method that combines spatial database analysis with the single-factor mapping technology to establish sequence stratigraphical succession and to map the Ordovician litho-paleogeography of the Ordos Basin, one of the largest oil-gas bearing basins in North China Platform. By using this method, all of the related basic geological data can be quantitatively analyzed and effectively managed. Various attributes of the basic stratigraphic units and their characters, such as sequence thickness, penecontemporaneous dolostone content, shallow water parget content, and terrigenous material content, can be fully utilized statistically in facies analysis and in mapping. Based on this analysis, this paper has be exerted single-factor isopachous mapping quantitatively for each of the Ordovician sequences in the basin, and finally synthesized multiple factors to reconstruct the litho-paleogeography for each of the sequence intervals. The study shows that the proposed method is quite effective and has a much higher resolution in recognizing litho-paleogeographic subunits compared with traditional ways. For example, in one of the Middle Ordovician sequence intervals （SQ19 in the Lower Majiagou Formation） of the Ordos Basin, the authors have successfully developed a mathematical formula to divide the distribution of various facies units substantially, such as old lands, submarine uplifts, supratidal zones, intertidal zones and subtidal zones.展开更多
The present study is focused on the roadway support in high stress composite soft rock. This paper expounds the two main features of roadway in soft rock, i.e., great deformation of surrounding rock and remarkable rhe...The present study is focused on the roadway support in high stress composite soft rock. This paper expounds the two main features of roadway in soft rock, i.e., great deformation of surrounding rock and remarkable rheological deformation. Furthermore, on the basis of analyzing physico chemical component of surrounding rock and the situation of the damaged roadway, the method of adopting strong bolting and shotcreting mesh for the primary support, bolting and grouting for the secondary support is put forward in light of the on the spot investigation of stress tension, mechanical parameter and engineering geology. The application reveals the method facilitates the continuation of west main roadway and the restoration of shaft station and chambers. Consequently, better techno economic results have been achieved.展开更多
Numerical simulation, which is one of the important methods for tectonic simulation, can be successfully applied into the stability analysis of rock stratum in mining engineering. With numerical simulation, the charac...Numerical simulation, which is one of the important methods for tectonic simulation, can be successfully applied into the stability analysis of rock stratum in mining engineering. With numerical simulation, the characteristics of stress deformation field of the area study can be well discovered, the stress concentration regions can be clearly located and the mechanism and effect of the stress concentration can be analyzed. The results of these studies offer fundamental data for evaluation of the rock stability and prediction of the tunnel wall stability in the working area.展开更多
Membrane distillation(MD)is a promising alternative desalination technology,but the hydrophobic membrane cannot intercept volatile organic compounds(VOCs),resulting in aggravation in the quality of permeate.In term of...Membrane distillation(MD)is a promising alternative desalination technology,but the hydrophobic membrane cannot intercept volatile organic compounds(VOCs),resulting in aggravation in the quality of permeate.In term of this,electro-Fenton(EF)was coupled with sweeping gas membrane distillation(SGMD)in a more efficient way to construct an advanced oxidation barrier at the gas-liquid interface,so that the VOCs could be trapped in this layer to guarantee the water quality of the distillate.During the so-called EF-MD process,an interfacial interception barrier containing hydroxyl radical formed on the hydrophobic membrane surface.It contributed to the high phenol rejection of 90.2% with the permeate phenol concentration lower than 1.50 mg/L.Effective interceptions can be achieved in a wide temperature range,even though the permeate flux of phenol was also intensified.The EF-MD system was robust to high salinity and could electrochemically regenerate ferrous ions,which endowed the long-term stability of the system.This novel EF-MD configuration proposed a valuable strategy to intercept VOCs in MD and will broaden the application of MD in hypersaline wastewater treatment.展开更多
The purpose of this paper is to reveal the stress distribution characteristic along the full length anchor bolt. Based on the mechanic model set up, the author calculated the anchor mechanism of the full length resin ...The purpose of this paper is to reveal the stress distribution characteristic along the full length anchor bolt. Based on the mechanic model set up, the author calculated the anchor mechanism of the full length resin rock bolt. The stress distribution characteristic is different according to different type of surrounding rock. The conclusion is important to optimize the roadway bolt support design.展开更多
Addressing climate change and air pollution exhibits strong synergy,and the Chinese government is actively promoting the integrated management of these two issues.Since 2019,the China Clean Air Policy Partnership has ...Addressing climate change and air pollution exhibits strong synergy,and the Chinese government is actively promoting the integrated management of these two issues.Since 2019,the China Clean Air Policy Partnership has released annual reports on China's progress in climate and air pollution governance.These reports track and analyze the challenges and propose solutions for China's pursuit of carbon neutrality and clean air by developing and monitoring key indicators across five areas.This report is the fourth annual report.Building on previous research,it further refines the collaborative governance monitoring indicator system,including the addition of climate change and extreme weather,atmospheric greenhouse gases,and enhanced efficiency of pollution removal technologies.The report includes the following components:(1)an analysis of the interactions between air pollution and climate change;(2)a discussion of governance systems and practices,with an emphasis on policy implementation and local experiences;(3)coverage of structural changes and emission reduction technologies,including energy and industrial transitions,transportation,low-carbon buildings,carbon capture and storage,and power systems;(4)an overview of atmospheric dynamics and emission pathways,examining emission drivers and offering insights for future coordinated governance;and(5)an evaluation of the health impacts and benefits of joint actions.These efforts underscore China's commitment to integrated control,resulting in slowed carbon emission growth,improved air quality,and enhanced health benefits.展开更多
Influenza A (H1N1) was spread widely between cities and towns by road traffic and had a major impact on public health in China in 2009. Understanding regulation of its transmission is of great significance with urbani...Influenza A (H1N1) was spread widely between cities and towns by road traffic and had a major impact on public health in China in 2009. Understanding regulation of its transmission is of great significance with urbanization ongoing and for mitigation of damage by the epidemic. We analyzed influenza A (H1N1) spatiotemporal transmission and risk factors along roads in Changsha, and combined diffusion velocity and floating population size to construct an epidemic diffusion model to simulate its transmission between cities and towns. The results showed that areas along the highways and road intersections had a higher incidence rate than other areas. Expressways and county roads played an important role in the rapid development stage and the epidemic peak, respectively, and intercity bus stations showed a high risk of disease transmission. The model simulates the intensity and center of disease outbreaks in cities and towns, and provides a more complete simulation of the disease spatiotemporal process than other models.展开更多
The agglomeration characteristics of river sand and wheat stalk ash mixture at various temperatures are investi- gated using a muffle furnace. The surface structural changes, as well as the elemental makeup of the sur...The agglomeration characteristics of river sand and wheat stalk ash mixture at various temperatures are investi- gated using a muffle furnace. The surface structural changes, as well as the elemental makeup of the surface and cross-section of the agglomerates, are analyzed by polarized light microscopy, scanning electron microscopy （SEM）, and energy dispersive X-ray （EDX）. Multi-phase equilibrium calculation is performed with FactSage in identifying the melting behavior of the river sand-wheat stalk ash mixture at high temperatures. No indication of agglomeration is detected below 850~C. At a temperature of 900-1000~C, however, obvious agglomeration is observed and the agglomerates solidify further as temperature increases. The presence of potassium and calcium enrichment causes the formation of a sticky sand surface that induces agglomeration. The main component of the agglomerate surface is KEO-42aO-SiO2, which melts at low temperatures. The formation of molten silicates causes particle cohesion. The main ingredient of the binding phase in the cross-section is K20-SiO2-Na20- Al2Oa--CaO; the agglomeration is not the result of the melting behavior of wheat stalk ash itself but the compre- hensive results of chemical reaction and the melting behavior at high temperatures. The multi-phase equilibrium calculations agree well with the experimental results.展开更多
This research investigates the performances of RuO2/ZrO2-CeO2 in catalytic ozonation for water treatment. The results show that RuO2/ZrO2-CeO2 was active for the catalytic ozonation of oxalic acid and possessed higher...This research investigates the performances of RuO2/ZrO2-CeO2 in catalytic ozonation for water treatment. The results show that RuO2/ZrO2-CeO2 was active for the catalytic ozonation of oxalic acid and possessed higher stability than RuO2/Al2O3 and Ru/AC. In the catalytic ozonation of dimethyl phthalate （DMP）, RuO2/ZrO2-CeO2 did not enhance the DMP degradation rate but significantly improved the total organic carbon （TOC） removal rate. The TOC removal in catalytic ozonation was 56% more than that in noncatalytic ozonation. However this does not mean the catalyst was very active because the contribution of catalysis to the overall TOC removal was only 30%. The adsorption of the intermediates on RuO2/ZrO2-CeO2 played an important role on the overall TOC removal while the adsorption of DMP on it was negligible. This adsorption difference was due to their different ozonation rates. In the catalytic ozonation of disinfection byproduct precursors with RuO2/ZrO2-CeO2, the reductions of the haloacetic acid and trihalomethane formation potentials （HAAFPs and THMFPs） for the natural water samples were 38%–57% and 50%–64%, respectively. The catalyst significantly promoted the reduction of HAAFPs but insignificantly improved the reduction of THMFPs as ozone reacts fast with the THMs precursors. These results illustrate the good promise of RuO2/ZrO2-CeO2 in catalytic ozonation for water treatment.展开更多
基金supported by the National Natural Science Foundation of China(No.21976192).
文摘Persulfate(PS)is a widely used oxidant for the chemical oxidation of organic pollutants.The accurate measurement of PS concentration is crucial for the practical application process.The iodometry is the most recommended method for PS determination,and its principle is based on the redox reaction between S_(2)O_(8)^(2−)and iodide ions.However,hydrogen peroxide(H_(2)O_(2)),an important intermediate product in the process of PS use,often leads to abnormally high determination concentrations of PS.Given this,a novel method was developed for the determination of PS based on the principle of the oxidation of chloride ion(Cl^(−)).The concentration of PS is calculated according to the consumption of Cl^(−)concentration,which is not disturbed by H_(2)O_(2).The optimized test conditions were explored as:C(H^(+))=2 mol/L,T=80◦C,C(Cl^(−)):C(PS)=4:1 and t=30 min.Under the optimized conditions,the limit of detection and the limit of quantification of PS concentration determined by this method were 0.26 and 0.85 g/L,respectively.And the linear range of the PS determination was 1–100 g/L with an error of 0.53%-12.06%.The spike recovery rate for determining PS concentration in the actual wastewater ranged from 94.07%-109.52%.Interfering factors such as H_(2)O_(2),Fe^(3+),MnO_(2)and natural organic matter had almost no effect on the results.This method could not only accurately determine the concentration of PS in industrial wastewater,but also determine the purity of PS industrial products.
基金supported by the National Natural Science Foundation of China (No.51078143)the Fundamental Research Funds for the Central Universities of China
文摘The development of highly active carbon material catalysts in catalytic wet air oxidation（CWAO）has attracted a great deal of attention. In this study different carbon material catalysts（multi-walled carbon nanotubes,carbon fibers and graphite） were developed to enhance the CWAO of phenol in aqueous solution. The functionalized carbon materials exhibited excellent catalytic activity in the CWAO of phenol. After 60 min reaction,the removal of phenol was nearly100% over the functionalized multi-walled carbon,while it was only 14% over the purified multi-walled carbon under the same reaction conditions. Carboxylic acid groups introduced on the surface of the functionalized carbon materials play an important role in the catalytic activity in CWAO. They can promote the production of free radicals,which act as strong oxidants in CWAO. Based on the analysis of the intermediates produced in the CWAO reactions,a new reaction pathway for the CWAO of phenol was proposed in this study. There are some differences between the proposed reaction pathway and that reported in the literature. First,maleic acid is transformed directly into malonic acid. Second,acetic acid is oxidized into an unknown intermediate,which is then oxidized into CO2 and H2O. Finally,formic acid and oxalic acid can mutually interconvert when conditions are favorable.
基金supported by the National Natural Science Foundation of China(No.21107127)the Ministry of Science and Technology of China(No.2012AA062606)
文摘The occurrence of antibiotics in the environment has recently raised serious concern regarding their potential threat to aquatic ecosystem and human health. In this study, the magnetic ion exchange（MIEX） resin was applied for removing three commonly-used antibiotics, sulfamethoxazole（SMX）, tetracycline（TCN） and amoxicillin（AMX） from water.The results of batch experiments show that the maximum adsorption capacities on the MIEX resin for SMX, TCN and AMX were 789.32, 443.18 and 155.15 μg/m L at 25°C,respectively, which were 2–7 times that for the powdered activated carbon. The adsorption kinetics of antibiotics on the MIEX resin could be simulated by the pseudo-second-order model（R^2= 0.99）, and the adsorption isotherm data were well described by the Langmuir model（R^2= 0.97）. Solution p H exhibited a remarkable impact on the adsorption process and the absorbed concentrations of the tested antibiotics were obtained around the neutral p H.The MIEX resin could be easily regenerated by 2 mol/L Na Cl solution and maintained high adsorption removal for the tested antibiotics after regeneration. Anion exchange mechanism mainly controlled the adsorption of antibiotic and the formation of hydrogen binding between the antibiotic and resin can also result in the increase of adsorption capacity. The high adsorption capacity, fast adsorption rate and prominent reusability make the MIEX resin a potential adsorbent in the application for removing antibiotics from water.
文摘Ni-P matrix composite coating reinforced by carbon nanotubes (CNTs) was deposit ed by electroless plating. The most important factors that influence the content of carbon nanotubes in deposits,such as agitation,surfactant and carbon nanot ubes concentration in the plating bath were investigated. The surface morphology,structure and properties of the Ni-P-CNTs coating were examined. It is found that the maximum content of carbon nanotubes in the deposits is independent of carbon nanotubes concentration in the plating bath when it is up to 5 mg/L. The test results show that the carbon nanotubes co-deposited do not change the str ucture of the Ni-P matrix of the composite coating,but greatly increase the ha rdness and wear resistance and decrease the friction coefficient of the Ni-P-C NTs composite coating with increasing content of carbon nanotubes in deposits.
文摘This paper developed a fluorometric method for the sensitive determination of nonylphenol in water samples by preconcentration with zirconium doped titanium dioxide nanotubes solid phase extraction.The parameters on extraction that would influence the enrichment performance such as the kind and volume of eluent,sample pH,sample flow rate,and sample volume were optimized in detail.Under the optimal conditions,the proposed method provided an excellent linear range of 1-150 mg/L and good LOD of 0.076 mg/L.The relative standard deviation（RSD,n = 6） was 2.8%.Proposed method was also used for the analysis of real water samples and the spiked recoveries were satisfied in the range of 98.7-103%.
文摘The develop actuality and direction of FRP(fibre glass reinforced plastics) bolt in the world are analyzed The new type structure of FRP bolt was designed Trial data indicate that, all kinds of capability target of this FRP bolt all achieve and exceed the country standard, substitute present metal bolt,wood bolt and bamboo bolt and other side bolt, it can gain magnitude technology and economy benefit FRP bolt mechanization product line produce efficiency is high, its throughput a day are 750 base, this can meet demand of hit small mining company
基金Project supported by the National High-Technology Research and Development Program of China (Grant No. 863-2001AA644010)
文摘To solve the disability of conventional model used in electrical leak location when measurement electrodes were buried under the liner, a new model of high voltage DC leak detection is developed. For single-liner landfill, the waste material layer, the geomembrane liner and the soil under the liner are simulated with infinite horizontal layers. The leak is regarded as two parts, one being negative current source at the entrance, and the other positive current source of the same size at the exit. Comparisons between the new theoretical model and conventional model show that conventional model is efficient in locating leaks in geomembane liner associating the dipole scanning above the liner but is ineffective when the measurement electrodes were buried under the liner. The new theoretical model data are in excellent agreement with experimental data not only above the liner but also under the liner.
文摘According to the movement and change rules of mechanical structure of surrounding rock coal mass system during coal excavation, the mechanism of sudden instability and damage was found out. The criterions that distinguishing the occurring of the pressure bump were put forward. This criteria have been applied successfully in the comprehensive prevent of pressure bumps in Tangshan colliery.
基金Supported by the Natural Sciences of Anhui Provincial Education Division(2002kj286ZD,01044403)
文摘By employing numerical modeling, similar material simulation and comprehen-sive field observation, investigations were made and patterns were obtained governing surrounding-rock stress distribution and strata behaviors. It shows that patterns governing displacement of FMC roadway surrounding rocks and those governing deformation of supports are basically the same along the strike, but the displacements vary greatly. The front stresses affect greater areas than the lateral stresses and their limit widths of equilib-rium zones and K are almost similar. The stress transmits very deep. Our findings offer scientific basis on which to determine parameters for coal pillar retaining and for roadway out-laying, thus increasing the recovery ratio and improving the maintenance of roadway.
文摘This article set forth two types of destructive form of stopping tunnel coal wall: destructive form in coal and destructive form in interface of coal layer. In addition, the mechanism of destruction in stopping tunnel coal wall is analyzed.
文摘The designing method and the supporting mechanism of both bolt and small cable anchor for full seam roadway in the weaker thick coal seam are systematically analyzed, and the construction technology and the supporting results are briefly summarized.
基金Supported by the National Natural Science Foundation of China for the Innovation Group Project(No. 40621002)
文摘Abstract In the study of sequence stratigraphy and litho-paleogeography, quantitative analysis, precise calculation and detailed comparison of tremendous geological data, such as field profiles, logging records and seismic curves from different areas, are the basic requirements. In order to obtain a more reliable and precise result, this paper presents a novel method that combines spatial database analysis with the single-factor mapping technology to establish sequence stratigraphical succession and to map the Ordovician litho-paleogeography of the Ordos Basin, one of the largest oil-gas bearing basins in North China Platform. By using this method, all of the related basic geological data can be quantitatively analyzed and effectively managed. Various attributes of the basic stratigraphic units and their characters, such as sequence thickness, penecontemporaneous dolostone content, shallow water parget content, and terrigenous material content, can be fully utilized statistically in facies analysis and in mapping. Based on this analysis, this paper has be exerted single-factor isopachous mapping quantitatively for each of the Ordovician sequences in the basin, and finally synthesized multiple factors to reconstruct the litho-paleogeography for each of the sequence intervals. The study shows that the proposed method is quite effective and has a much higher resolution in recognizing litho-paleogeographic subunits compared with traditional ways. For example, in one of the Middle Ordovician sequence intervals （SQ19 in the Lower Majiagou Formation） of the Ordos Basin, the authors have successfully developed a mathematical formula to divide the distribution of various facies units substantially, such as old lands, submarine uplifts, supratidal zones, intertidal zones and subtidal zones.
文摘The present study is focused on the roadway support in high stress composite soft rock. This paper expounds the two main features of roadway in soft rock, i.e., great deformation of surrounding rock and remarkable rheological deformation. Furthermore, on the basis of analyzing physico chemical component of surrounding rock and the situation of the damaged roadway, the method of adopting strong bolting and shotcreting mesh for the primary support, bolting and grouting for the secondary support is put forward in light of the on the spot investigation of stress tension, mechanical parameter and engineering geology. The application reveals the method facilitates the continuation of west main roadway and the restoration of shaft station and chambers. Consequently, better techno economic results have been achieved.
文摘Numerical simulation, which is one of the important methods for tectonic simulation, can be successfully applied into the stability analysis of rock stratum in mining engineering. With numerical simulation, the characteristics of stress deformation field of the area study can be well discovered, the stress concentration regions can be clearly located and the mechanism and effect of the stress concentration can be analyzed. The results of these studies offer fundamental data for evaluation of the rock stability and prediction of the tunnel wall stability in the working area.
基金supported by the National Natural Science Foundation of China(Nos.52200111,51978651,and 51878049)the China Postdoctoral Science Foundation(No.2021M703407)the special fund from the State Key Joint Laboratory of Environment Simulation and Pollution Control(Research Center for Eco-Environmental Sciences,Chinese Academy of Sciences(No.21Z01ESPCR)。
文摘Membrane distillation(MD)is a promising alternative desalination technology,but the hydrophobic membrane cannot intercept volatile organic compounds(VOCs),resulting in aggravation in the quality of permeate.In term of this,electro-Fenton(EF)was coupled with sweeping gas membrane distillation(SGMD)in a more efficient way to construct an advanced oxidation barrier at the gas-liquid interface,so that the VOCs could be trapped in this layer to guarantee the water quality of the distillate.During the so-called EF-MD process,an interfacial interception barrier containing hydroxyl radical formed on the hydrophobic membrane surface.It contributed to the high phenol rejection of 90.2% with the permeate phenol concentration lower than 1.50 mg/L.Effective interceptions can be achieved in a wide temperature range,even though the permeate flux of phenol was also intensified.The EF-MD system was robust to high salinity and could electrochemically regenerate ferrous ions,which endowed the long-term stability of the system.This novel EF-MD configuration proposed a valuable strategy to intercept VOCs in MD and will broaden the application of MD in hypersaline wastewater treatment.
文摘The purpose of this paper is to reveal the stress distribution characteristic along the full length anchor bolt. Based on the mechanic model set up, the author calculated the anchor mechanism of the full length resin rock bolt. The stress distribution characteristic is different according to different type of surrounding rock. The conclusion is important to optimize the roadway bolt support design.
基金supported by the National Natural Science Foundation of China(Grant No.42088101)and the Energy Foundation,China。
文摘Addressing climate change and air pollution exhibits strong synergy,and the Chinese government is actively promoting the integrated management of these two issues.Since 2019,the China Clean Air Policy Partnership has released annual reports on China's progress in climate and air pollution governance.These reports track and analyze the challenges and propose solutions for China's pursuit of carbon neutrality and clean air by developing and monitoring key indicators across five areas.This report is the fourth annual report.Building on previous research,it further refines the collaborative governance monitoring indicator system,including the addition of climate change and extreme weather,atmospheric greenhouse gases,and enhanced efficiency of pollution removal technologies.The report includes the following components:(1)an analysis of the interactions between air pollution and climate change;(2)a discussion of governance systems and practices,with an emphasis on policy implementation and local experiences;(3)coverage of structural changes and emission reduction technologies,including energy and industrial transitions,transportation,low-carbon buildings,carbon capture and storage,and power systems;(4)an overview of atmospheric dynamics and emission pathways,examining emission drivers and offering insights for future coordinated governance;and(5)an evaluation of the health impacts and benefits of joint actions.These efforts underscore China's commitment to integrated control,resulting in slowed carbon emission growth,improved air quality,and enhanced health benefits.
基金supported by the Key Discipline Construction Project in Hunan Province (2008001)the Science and Technology Planning Project of Hunan Province, China (2010SK3007)
文摘Influenza A (H1N1) was spread widely between cities and towns by road traffic and had a major impact on public health in China in 2009. Understanding regulation of its transmission is of great significance with urbanization ongoing and for mitigation of damage by the epidemic. We analyzed influenza A (H1N1) spatiotemporal transmission and risk factors along roads in Changsha, and combined diffusion velocity and floating population size to construct an epidemic diffusion model to simulate its transmission between cities and towns. The results showed that areas along the highways and road intersections had a higher incidence rate than other areas. Expressways and county roads played an important role in the rapid development stage and the epidemic peak, respectively, and intercity bus stations showed a high risk of disease transmission. The model simulates the intensity and center of disease outbreaks in cities and towns, and provides a more complete simulation of the disease spatiotemporal process than other models.
基金supported by National Natural Science Foundation of China(Project Code:50706055)
文摘The agglomeration characteristics of river sand and wheat stalk ash mixture at various temperatures are investi- gated using a muffle furnace. The surface structural changes, as well as the elemental makeup of the surface and cross-section of the agglomerates, are analyzed by polarized light microscopy, scanning electron microscopy （SEM）, and energy dispersive X-ray （EDX）. Multi-phase equilibrium calculation is performed with FactSage in identifying the melting behavior of the river sand-wheat stalk ash mixture at high temperatures. No indication of agglomeration is detected below 850~C. At a temperature of 900-1000~C, however, obvious agglomeration is observed and the agglomerates solidify further as temperature increases. The presence of potassium and calcium enrichment causes the formation of a sticky sand surface that induces agglomeration. The main component of the agglomerate surface is KEO-42aO-SiO2, which melts at low temperatures. The formation of molten silicates causes particle cohesion. The main ingredient of the binding phase in the cross-section is K20-SiO2-Na20- Al2Oa--CaO; the agglomeration is not the result of the melting behavior of wheat stalk ash itself but the compre- hensive results of chemical reaction and the melting behavior at high temperatures. The multi-phase equilibrium calculations agree well with the experimental results.
文摘This research investigates the performances of RuO2/ZrO2-CeO2 in catalytic ozonation for water treatment. The results show that RuO2/ZrO2-CeO2 was active for the catalytic ozonation of oxalic acid and possessed higher stability than RuO2/Al2O3 and Ru/AC. In the catalytic ozonation of dimethyl phthalate （DMP）, RuO2/ZrO2-CeO2 did not enhance the DMP degradation rate but significantly improved the total organic carbon （TOC） removal rate. The TOC removal in catalytic ozonation was 56% more than that in noncatalytic ozonation. However this does not mean the catalyst was very active because the contribution of catalysis to the overall TOC removal was only 30%. The adsorption of the intermediates on RuO2/ZrO2-CeO2 played an important role on the overall TOC removal while the adsorption of DMP on it was negligible. This adsorption difference was due to their different ozonation rates. In the catalytic ozonation of disinfection byproduct precursors with RuO2/ZrO2-CeO2, the reductions of the haloacetic acid and trihalomethane formation potentials （HAAFPs and THMFPs） for the natural water samples were 38%–57% and 50%–64%, respectively. The catalyst significantly promoted the reduction of HAAFPs but insignificantly improved the reduction of THMFPs as ozone reacts fast with the THMs precursors. These results illustrate the good promise of RuO2/ZrO2-CeO2 in catalytic ozonation for water treatment.
