Conversion of Fischer-Tropsch wax into high quality synthetic crude or finished transportation fuels such as premium diesel has been studied over the past 15 years within BP. Catalyst screening and selection was carri...Conversion of Fischer-Tropsch wax into high quality synthetic crude or finished transportation fuels such as premium diesel has been studied over the past 15 years within BP. Catalyst screening and selection was carried out in dedicated micro-reactors and pilot plants, whose designs are critical to the performance selection. Variation in catalyst composition and defining the gas to oil feed ratios with the operating temperature are a few of the parameters studied. Product selection and maximizing diesel yield combined with stability （catalyst life） were the ultimate drivers. The selected catalyst was then tested under commercial conditions in a dedicated 300 barrel per day demonstration plant. The products were also tested in engines to assess their combustion characteristics.展开更多
This article describes the development of BP's Fischer-Tropsch catalyst, used for the conversion of carbon monoxide and hydrogen into liquid hydrocarbons. It covers the 18 year period from the early eighties, when...This article describes the development of BP's Fischer-Tropsch catalyst, used for the conversion of carbon monoxide and hydrogen into liquid hydrocarbons. It covers the 18 year period from the early eighties, when laboratory scale preparations and micro-reactors were heavily used, right through to the present day with the commercial scale manufacture and proving of the finished catalyst in BP's new ＄86 million gas to liquids demonstration facility in Nikiski, Alaska. Extensive performance testing and scale-up experiments have been successfully carried out, all proof that a laboratory preparation can indeed be translated into a commercial manufacturing process. In addition, the resulting catalyst does not only meet the process design targets, but also exhibits enhanced stability and is tolerant to carbon dioxide. Above all, a commercial scale, fixed bed Fischer-Tropsch catalyst is now available and ready for licensing. Manufacturing procedures and quality control have all been successfully detailed and transferred to the commercial manufacturer.展开更多
Analysis of model test results was carried out to investigate the hydrodynamic interaction between a pair of elastically-supported rigid cylinders of dissimilar diameters in a water flume. The two cylinders are placed...Analysis of model test results was carried out to investigate the hydrodynamic interaction between a pair of elastically-supported rigid cylinders of dissimilar diameters in a water flume. The two cylinders are placed in tandem with one situated in the wake of the other. The diameter of the upstream cylinder is twice as large as that of the downstream cylinder. The spacing between the two cylinders ranges from 1 to 10 times the larger cylinder diameter. The Reynolds numbers are within the sub-critical range. The cylinders are free to oscillate in both the in-line and the cross-flow directions. The reduced velocity ranges from 1 to 10 and the low damping ratio of the model test set-up at 0.006 gives a combined mass-damping parameter of 0.02. It is found that the lift on and the cross-flow motion of the downstream cylinder have the frequency components derived from the upstream cylinder＇s vortex shedding as well as from its own vortex shedding, and the relative importance of the two sources of excitation is influenced by the spacing between the two cylinders. The downstream cylinder＇s VIV response appears to be largely dependent upon the actual reduced velocity of the cylinder.展开更多
文摘Conversion of Fischer-Tropsch wax into high quality synthetic crude or finished transportation fuels such as premium diesel has been studied over the past 15 years within BP. Catalyst screening and selection was carried out in dedicated micro-reactors and pilot plants, whose designs are critical to the performance selection. Variation in catalyst composition and defining the gas to oil feed ratios with the operating temperature are a few of the parameters studied. Product selection and maximizing diesel yield combined with stability （catalyst life） were the ultimate drivers. The selected catalyst was then tested under commercial conditions in a dedicated 300 barrel per day demonstration plant. The products were also tested in engines to assess their combustion characteristics.
文摘This article describes the development of BP's Fischer-Tropsch catalyst, used for the conversion of carbon monoxide and hydrogen into liquid hydrocarbons. It covers the 18 year period from the early eighties, when laboratory scale preparations and micro-reactors were heavily used, right through to the present day with the commercial scale manufacture and proving of the finished catalyst in BP's new ＄86 million gas to liquids demonstration facility in Nikiski, Alaska. Extensive performance testing and scale-up experiments have been successfully carried out, all proof that a laboratory preparation can indeed be translated into a commercial manufacturing process. In addition, the resulting catalyst does not only meet the process design targets, but also exhibits enhanced stability and is tolerant to carbon dioxide. Above all, a commercial scale, fixed bed Fischer-Tropsch catalyst is now available and ready for licensing. Manufacturing procedures and quality control have all been successfully detailed and transferred to the commercial manufacturer.
文摘Analysis of model test results was carried out to investigate the hydrodynamic interaction between a pair of elastically-supported rigid cylinders of dissimilar diameters in a water flume. The two cylinders are placed in tandem with one situated in the wake of the other. The diameter of the upstream cylinder is twice as large as that of the downstream cylinder. The spacing between the two cylinders ranges from 1 to 10 times the larger cylinder diameter. The Reynolds numbers are within the sub-critical range. The cylinders are free to oscillate in both the in-line and the cross-flow directions. The reduced velocity ranges from 1 to 10 and the low damping ratio of the model test set-up at 0.006 gives a combined mass-damping parameter of 0.02. It is found that the lift on and the cross-flow motion of the downstream cylinder have the frequency components derived from the upstream cylinder＇s vortex shedding as well as from its own vortex shedding, and the relative importance of the two sources of excitation is influenced by the spacing between the two cylinders. The downstream cylinder＇s VIV response appears to be largely dependent upon the actual reduced velocity of the cylinder.
