Water-soluble organic aerosol(WSOA)plays a significant role in air quality and human health.Here we characterized the chemical properties and molecular compositions of WSOA at a rural site in North China Plain during ...Water-soluble organic aerosol(WSOA)plays a significant role in air quality and human health.Here we characterized the chemical properties and molecular compositions of WSOA at a rural site in North China Plain during winter using a high-resolution aerosol mass spectrometer and electrospray ionization high-resolution orbitrap mass spectrometer(ESI-HRMS).Our results show that the mass concentration of WSOA was significantly higher than that observed in Beijing in winter 2020,contributing about 56%of OA on average.CHO compounds(56%-74%)and CHN compounds(66%-80%)dominated in negative mode and positive mode,respectively,while CHON accounted for 15%-41%across both modes.The chemical characteristics of WSOA varied with polluted levels and between day and night.As pollution intensified,the abundance of CHO-compounds with condensed aromatics increased by 9%and the number of highly oxygenated molecules(HOMs)molecular formula detected in server haze was more than double that of clean days.CHO-compounds with ten carbon atoms(C_(10))were more abundant at night while those with nine carbon atoms(C_(9))were higher during the day.High levels of CHN+compounds were linked to nighttime biomass burning,whereas CHON compounds were more abundant during the day.Increased pollution also led to the formation of more complex CHON-compounds,indicating that organonitrates continue to play a significant role in rural pollution.展开更多
The decoherence of high-dimensional orbital angular momentum(OAM)entanglement in the weak scintillation regime has been investigated.In this study,we simulate atmospheric turbulence by utilizing a multiple-phase scree...The decoherence of high-dimensional orbital angular momentum(OAM)entanglement in the weak scintillation regime has been investigated.In this study,we simulate atmospheric turbulence by utilizing a multiple-phase screen imprinted with anisotropic non-Kolmogorov turbulence.The entanglement negativity and fidelity are introduced to quantify the entanglement of a high-dimensional OAM state.The numerical evaluation results indicate that entanglement negativity and fidelity last longer for a high-dimensional OAM state when the azimuthal mode has a lower value.Additionally,the evolution of higher-dimensional OAM entanglement is significantly influenced by OAM beam parameters and turbulence parameters.Compared to isotropic atmospheric turbulence,anisotropic turbulence has a lesser influence on highdimensional OAM entanglement.展开更多
Ozone production sensitivity is widely used to reveal the chemical dominant precursors of urban ozone rise.Here,we diagnose the impact of the decline in global human production activities level caused by the COVID-19 ...Ozone production sensitivity is widely used to reveal the chemical dominant precursors of urban ozone rise.Here,we diagnose the impact of the decline in global human production activities level caused by the COVID-19 on ozone sensitivity through the ratio of formaldehyde(HCHO)and NO_(2)(FNR=HCHO/NO_(2))observations from the TROPOspheric Monitoring Instrument.We use a relative uncertainty threshold to clean the satellite FNR,and our satellite FNR present a good correlation(R=0.6248)with U.S.Environmental Protection Agency observations.We found that the outbreak of the COVID-19 did not change the pattern of global ozone sensitivity,while the global regimes was transforming or strengthening to VOC-limited regimes due to the significant decline of human production activities levels.During the COVID-19,ozone sensitivity in Eastern China and East Africa continued to shift to VOC-limited regimes,while India,Western Europe and North America first moved to NOx-limited regimes,and then changed to VOC-limited regimes with the resumption of production and the increase in travel.The clustering results tell that urban ozone sensitivity tends to shift towards NOx-limited regimes as economic growing.The ozone formation in cities with lower FNR and per capita gross domestic product(GDP)are more sensitive to changes in VOCs,while cities with higher FNR and per capita GDP are more sensitive to variations in NOx.Cities with intermediate FNR and GDP are good evidence of the existence of transitional regimes.Our study identifies the driving role of urban economics in orienting the evolution of ozone sensitivity regimes.展开更多
By using wave optics numerical simulation, the intensity-hole effect, beam spreading and wandering properties of Gaussian vortex beam propagation in atmospheric turbulence are investigated quantitatively. It is found ...By using wave optics numerical simulation, the intensity-hole effect, beam spreading and wandering properties of Gaussian vortex beam propagation in atmospheric turbulence are investigated quantitatively. It is found that an intensity hole in the center of the beam pattern appears gradually as a Gaussian vortex beam propagates. The size of the intensity hole increases with the increase of the topological charge of the vortex phase. However, the intensity hole could to some extent be filled with optical energy by atmospheric turbulence, especially in strong turbulence. The radius of the intensity hole first decreases and then increases with the growth of turbulence strength. The effective radius of vortex beam with larger topological charge is greater than with a smaller topological charge. But the topological charge has no evident influence on beam wandering.展开更多
The entangled orbital angular momentum（OAM） three photons propagating in Kolmogorov weak turbulence are investigated. Here, the single phase screen model is used to study the entanglement evolution of OAM photons. T...The entangled orbital angular momentum（OAM） three photons propagating in Kolmogorov weak turbulence are investigated. Here, the single phase screen model is used to study the entanglement evolution of OAM photons. The results indicate that the entangled OAM three-qubit state with higher OAM modes will be more robust against turbulence.Furthermore, it is found that the entangled OAM three-qubit state has a higher overall transmission for small OAM values.展开更多
Atmospheric oxidizing capacity(AOC)is the fundamental driving factors of chemistry process(e.g.,the formation of ozone(O_(3))and secondary organic aerosols(SOA))in the troposphere.However,accurate quantification of AO...Atmospheric oxidizing capacity(AOC)is the fundamental driving factors of chemistry process(e.g.,the formation of ozone(O_(3))and secondary organic aerosols(SOA))in the troposphere.However,accurate quantification of AOC still remains uncertainty.In this study,a comprehensive field campaign was conducted during autumn 2019 in downtown of Beijing,where O_(3) and PM_(2.5) episodes had been experienced successively.The observation-based model(OBM)is used to quantify the AOC at O_(3) and PM_(2.5) episodes.The strong intensity of AOC is found at O_(3) and PM2.5 episodes,and hydroxyl radical(OH)is the dominating daytime oxidant for both episodes.The photolysis of O_(3) is main source of OH at O_(3) episode;the photolysis of nitrous acid(HONO)and formaldehyde(HCHO)plays important role in OH formation at PM_(2.5) episode.The radicals loss routines vary according to precursor pollutants,resulting in different types of air pollution.O_(3) budgets and sensitivity analysis indicates that O_(3) production is transition regime(both VOC and NOx-limited)at O3 episode.The heterogeneous reaction of hydroperoxy radicals(HO_(2))on aerosol surfaces has significant influence on OH and O_(3) production rates.The HO_(2) uptake coefficient(γHO_(2))is the determining factor and required accurate measurement in real atmospheric environment.Our findings could provide the important bases for coordinated control of PM_(2.5) and O_(3) pollution.展开更多
To find the optimal location for large-aperture telescopes is a goal of astronomy. Chinese Antarctic astronomy has begun to flourish in recent years, and it is an urgent need in basic astronomical work to measure and ...To find the optimal location for large-aperture telescopes is a goal of astronomy. Chinese Antarctic astronomy has begun to flourish in recent years, and it is an urgent need in basic astronomical work to measure and analyze the optical turbulence spatiotemporal distribution in the Antarctic region. We analyzed turbulence data measured by a mobile atmospheric parameter measurement system from 30 December 2013 to 10 February 2014 at Antarctic Taishan Station. Because there is a discrepancy between the refractive index structure constant Cn2 measured by an ultrasonic anemometer with a single-point temperature structure function method and by micro-thermometer, a new method to measure C,2 with a temperature spectrum method is proposed herein. Through comparing long-term continuous Cn2 data derived from ultrasonic anemometer with those via the new method and micro-thermometer, trend, magnitude and measured weak turbulence of-2× 10-16m-2/3 are generally satisfactory. The reason for the discrepancy in Cn2 measurement between the ultrasonic anemometer with the old method and micro-thermometer is investigated.展开更多
Propagation properties of spatially pseudo-partially coherent Gaussian Schell-model beams through the atmo- spheric turbulence over a long-distance uplink path are studied by numerical simulation. A linear coordinatio...Propagation properties of spatially pseudo-partially coherent Gaussian Schell-model beams through the atmo- spheric turbulence over a long-distance uplink path are studied by numerical simulation. A linear coordination trans- formation is introduced to overcome the window effect and the loss-of-resolution problem. The beam spreading, beam wandering, and intensity scintillation as functions of turbulence strength, source correlation length, and change fre- quency of random phase that models the partial coherence of the source are analyzed. It is found that the beam spreading and the intensity scintillation of the partially coherent beam are less affected by the turbulence than those of the coherent one, but it suffers from a more severe diffractive effect, and the change frequency of random phase has no evident influence on it. The beam wandering is insensitive to the variation of source correlation length, and decreases firstly then goes to a fixed value as the change frequency increases.展开更多
Secondary organic aerosol （SOA） formed from Cl-initiated oxidation of toluene was investigated in a home-made smog chamber. The size distribution and chemical composition of SOA particles were measured using aerodyn...Secondary organic aerosol （SOA） formed from Cl-initiated oxidation of toluene was investigated in a home-made smog chamber. The size distribution and chemical composition of SOA particles were measured using aerodynamic particle sizer spectrometer and the aerosol laser time-of-flight mass spectrometer （ALTOFMS）, respectively. According to a large number of single aerosol diameter and mass spectra, the size distribution and chemical composition of SOA were obtained statistically. Experimental results showed that SOA particles created by Cl-initiated oxidation of toluene is predominantly in the form of fine particles, which have diameters less than 2.5 μm （i.e., PM2.5）, and glyoxal, benzaldehyde, benzyl alcohol, benzoquinone, benzoic acid, benzyl hydroperoxide and benzyl methyl nitrate are the major products components in the SOA. The possible reaction mechanisms leading to these products are also proposed.展开更多
This is the second paper of a series devoted to atmospheric optical turbulence Cn^2 observation using a mobile polar atmospheric parameter measurement system. We present the initial results of Cn^2 measurement at Anta...This is the second paper of a series devoted to atmospheric optical turbulence Cn^2 observation using a mobile polar atmospheric parameter measurement system. We present the initial results of Cn^2 measurement at Antarctic Taishan Station using micro-thermal sensors and a three-dimensional sonic anemometer at height -2.0 m above the snow surface. The site testing experiments were carried out during the 30th Chinese National Antarctic Research Expedition （CH1NARE）. We collected about 1 000 h of data between 30 December 2013 and 10 February 2014. The C,： curve exhibits clear daily structures, with two peaks around midnight and midday and two troughs around 7：30 and 17：00 local time （UTC＋5）. The mean C,2 is 2.7×10^-15 m^-2/3 and the 25th and 75th percentiles of the C,2 cumulative distribution are 9.6×10^-16 m^-2/3 and 6.2×10^-15 m^-2/3, respectively. Meteorological parameters such as temperature, relative humidity, wind speed, and air pressure are also presented.展开更多
Propagation properties of coherent and partially coherent beams in atmospheric turbulence are investigated respectively by using numerical simulation It is found that a partially coherent beam has a spreading larger t...Propagation properties of coherent and partially coherent beams in atmospheric turbulence are investigated respectively by using numerical simulation It is found that a partially coherent beam has a spreading larger than a coherent beam. However, from the point view of relative beam spreading and intensity scintillation, a partially coherent beam is less affected than the corresponding coherent beam, which may be the most important virtue of partially coherent beams that could be utilized to improve the performance of laser engineering. The beam wandering is almost independent of the degree of the source coherence. More aperture averaging occurs when beam becomes more coherent.展开更多
The incineration of sacrificial offerings is a significant widely practiced custom that is also a kind of neglected air pollution source in China.Our results showed that the emission factors of particulate matter,SO_(...The incineration of sacrificial offerings is a significant widely practiced custom that is also a kind of neglected air pollution source in China.Our results showed that the emission factors of particulate matter,SO_(2),CO,NO_(x),and VOCs emitted from the incineration of sacrificial offerings with purification systems were reduced by 95%,19%,9%,82%,and 42%,respectively,compared with those without a purification system,revealing a significant effect of the flue gas purification system on reducing particulate matter and gaseous pollutants.The emission level of air pollutants from the incineration of sacrificial offerings remained stable before 2013 and then showed a remarkable decrease after the implementation of China′s Air Pollution Prevention Action Plan in 2013.The emissions of TSP(total suspended particulate),PM_(10),PM_(2.5),and NO_(x)in 2009 were 8222,6106,5656 and 15,878 ton,respectively,obviously higher than 3434,2551,2305 and 8579 ton in 2019.Such trend was affected by both the quantity of incineration and the installation rate of purification systems after the Emission Standard of Air Pollutants for Crematory(GB 13801-2015)issued in China.Distinct spatial distribution of atmospheric pollutants from incineration of sacrificial offerings was found with higher in the east and south of China than the west and north of China,which is proportional to the regional economy and population.The maximum ground-level concentration typically occurred at 0.12-0.2 km from the pollution source,posing potential health risks to people entering and exiting funeral and burial sites and nearby residents.展开更多
Atmospheric oxidizing capacity(AOC)is an essential driving force of troposphere chemistry and self-cleaning,but the definition of AOC and its quantitative representation remain uncertain.Driven by national demand for ...Atmospheric oxidizing capacity(AOC)is an essential driving force of troposphere chemistry and self-cleaning,but the definition of AOC and its quantitative representation remain uncertain.Driven by national demand for air pollution control in recent years,Chinese scholars have carried out studies on theories of atmospheric chemistry and have made considerable progress in AOC research.This paper will give a brief review of these developments.First,AOC indexes were established that represent apparent atmospheric oxidizing ability(AOIe)and potential atmospheric oxidizing ability(AOIp)based on aspects of macrothermodynamics and microdynamics,respectively.A closed study refined the quantitative contributions of heterogeneous chemistry to AOC in Beijing,and these AOC methods were further applied in Beijing-Tianjin-Hebei and key areas across the country.In addition,the detection of ground or vertical profiles for atmospheric OH·,HO_(2)·,NO_(3)·radicals and reservoir molecules can now be obtained with domestic instruments in diverse environments.Moreover,laboratory smoke chamber simulations revealed heterogeneous processes involving reactions of O_(3)and NO_(2),which are typical oxidants in the surface/interface atmosphere,and the evolutionary and budgetary implications of atmospheric oxidants reacting under multispecies,multiphase and multi-interface conditions were obtained.Finally,based on the GRAPES-CUACE adjoint model improved by Chinese scholars,simulations of key substances affecting atmospheric oxidation and secondary organic and inorganic aerosol formation have been optimized.Normalized numerical simulations of AOIe and AOIp were performed,and regional coordination of AOC was adjusted.An optimized plan for controlling O_(3)and PM2.5was analyzed by scenario simulation.展开更多
The entangled orbital angular momentum(OAM)photons propagating across a weakly turbulent atmosphere are investigated.Here,the paper uses the single-phase screen model based on the Kolmogorov theory of turbulence,and f...The entangled orbital angular momentum(OAM)photons propagating across a weakly turbulent atmosphere are investigated.Here,the paper uses the single-phase screen model based on the Kolmogorov theory of turbulence,and focuses on the influence of the backward scattering on OAM evolution.The results indicate that backward scattering plays an important role in the analysis of OAM entanglement evolution in the turbulent atmosphere.It cannot be negligible especially for higher-order OAM mode.Moreover,when OAM mode is greater than 4,entangled photon pairs composed of higher OAM modes are not more robust in turbulence within the weak scintillation regime.These results will be useful in future investigations of OAM-based optical wave propagation through turbulent atmosphere.展开更多
Random fluctuations of turbulence bring random fluctuations of the refractive index, making the atmosphere a random fluctuation medium that destroys the coherence of light-waves. Research in atmospheric turbulence is ...Random fluctuations of turbulence bring random fluctuations of the refractive index, making the atmosphere a random fluctuation medium that destroys the coherence of light-waves. Research in atmospheric turbulence is actually the investigation of the atmospheric refractive index. The atmospheric structure constant of refractive index, C n 2 , is an important parameter denoting atmospheric turbulence. In this paper, C n 2 is measured during the day and at night and in all four seasons using a high sensitivity micro-thermal meter QHTP-2. The vertical profile of C n 2 in Hefei (0-30 km) is investigated by the analysis of experimental data. The average profile of C n 2 in Hefei exhibits conspicuous day and night differences with increased altitude. The distribution of log(C n 2 ) is nearly normal and has conspicuous seasonal differences.展开更多
The Advanced Geosynchronous Radiation Imager(AGRI)is a mission-critical instrument for the Fengyun series of satellites.AGRI acquires full-disk images every 15 min and views East Asia every 5 min through 14 spectral b...The Advanced Geosynchronous Radiation Imager(AGRI)is a mission-critical instrument for the Fengyun series of satellites.AGRI acquires full-disk images every 15 min and views East Asia every 5 min through 14 spectral bands,enabling the detection of highly variable aerosol optical depth(AOD).Quantitative retrieval of AOD has hitherto been challenging,especially over land.In this study,an AOD retrieval algorithm is proposed that combines deep learning and transfer learning.The algorithm uses core concepts from both the Dark Target(DT)and Deep Blue(DB)algorithms to select features for the machinelearning(ML)algorithm,allowing for AOD retrieval at 550 nm over both dark and bright surfaces.The algorithm consists of two steps:①A baseline deep neural network(DNN)with skip connections is developed using 10 min Advanced Himawari Imager(AHI)AODs as the target variable,and②sunphotometer AODs from 89 ground-based stations are used to fine-tune the DNN parameters.Out-of-station validation shows that the retrieved AOD attains high accuracy,characterized by a coefficient of determination(R2)of 0.70,a mean bias error(MBE)of 0.03,and a percentage of data within the expected error(EE)of 70.7%.A sensitivity study reveals that the top-of-atmosphere reflectance at 650 and 470 nm,as well as the surface reflectance at 650 nm,are the two largest sources of uncertainty impacting the retrieval.In a case study of monitoring an extreme aerosol event,the AGRI AOD is found to be able to capture the detailed temporal evolution of the event.This work demonstrates the superiority of the transfer-learning technique in satellite AOD retrievals and the applicability of the retrieved AGRI AOD in monitoring extreme pollution events.展开更多
Saharan dust represents more than 50%of the total desert dust emitted around the globe and its radiative effect significantly affects the atmospheric circulation at a continental scale.Previous studies on dust vertica...Saharan dust represents more than 50%of the total desert dust emitted around the globe and its radiative effect significantly affects the atmospheric circulation at a continental scale.Previous studies on dust vertical distribution and the Saharan Air Layer(SAL)showed some shortcomings that could be attributed to imperfect representation of the effects of deep convection and scavenging.The authors investigate here the role of deep convective transport and scavenging on the vertical distribution of mineral dust over Western Africa.Using multi-year(2006-2010)simulations performed with the variable-resolution(zoomed)version of the LMDZ climate model.Simulations are compared with aerosol amounts recorded by the Aerosol Robotic Network(AERONET)and with vertical profiles of the Cloud-Aerosol Lidar with Orthogonal Polarization(CALIOP)measurements.LMDZ allows a thorough examination of the respective roles of deep convective transport,convective and stratiform scavenging,boundary layer transport,and advection processes on the vertical mineral dust distribution over Western Africa.The comparison of simulated dust Aerosol Optical Depth(AOD)and distribution with measurements suggest that scavenging in deep convection and subsequent re-evaporation of dusty rainfall in the lower troposphere are critical processes for explaining the vertical distribution of desert dust.These processes play a key role in maintaining a well-defined dust layer with a sharp transition at the top of the SAL and in establishing the seasonal cycle of dust distribution.This vertical distribution is further reshaped offshore in the Inter-Tropical Convergence Zone(ITCZ)over the Atlantic Ocean by marine boundary layer turbulent and convective transport and wet deposition at the surface.展开更多
Currently,over 80%of the international trade volume is carried by sea.Marked by persistent growth,evident atmospheric impacts,intricate mitigation challenges,international shipping has been recognized as one of the m...Currently,over 80%of the international trade volume is carried by sea.Marked by persistent growth,evident atmospheric impacts,intricate mitigation challenges,international shipping has been recognized as one of the most“hard-to-abate”sectors gathering increasing attention from both academic community and governmental sectors in recent years.Against the backdrop of the ambitious climate and clean air objectives,the quantitative shipping emission characterization,impact assessment and policy effectiveness research are not only fundamental to understand the status quo and ramifications of shipping emissions but also beneficial for future emission regulations.Here,we summarized the achievements in shipping emission modelling and impact research in the past two decades,and identified the challenges lying in the transition pathway towards a clean and carbon-neutral shipping.To address the pressing demand for this,we proposed an innovative framework which aims to facilitate emission abatement.Finally,promising directions for future work were delineated,including the indirect effects of shipping emitted aerosols on the climate,the emissions and impacts of novel contaminants,synergies and conflicts among different emission reduction measures,projections on future shipping emission inventories,Arctic shipping emissions,etc.展开更多
One hundred and ten samples of rainwater were collected for chemical analysis at the summit of Huangshan Mountain, a high-altitude site in East China, from July 2010 to June 2011. The volume-weighted-mean （VWM） pH f...One hundred and ten samples of rainwater were collected for chemical analysis at the summit of Huangshan Mountain, a high-altitude site in East China, from July 2010 to June 2011. The volume-weighted-mean （VWM） pH for the whole sampling period was 5.03. SO2- and Ca2＋ were the most abundant anion and cation, respectively. The ionic concentrations varied monthly with the highest concentrations in winter/spring and the lowest in summer. Evident inter-correlations were found among most ions, indicating the common sources for some species and fully mixing characteristics of the alpine precipitation chemistry. The VWM ratio of [SO]-]/[NO3] was 2.54, suggesting the acidity of rainwater comes from both nitric and sulfuric acids. Compared with contemporary observations at other alpine continental sites in China, the precipitation at Huangshan Mountain was the least polluted, with the lowest ionic concentrations. Trajectories to Huangshan Mountain on rainy days could be classified into six groups. The rainwater with influencing air masses originating in Mongolia was the most polluted with limited effect. The emissions of Jiangxi, Anhui, Zhejiang and Jiangsu provinces had a strong influence on the overall rain chemistry at Huangshan Mountain. The rainwater with influencing air masses from Inner Mongolia was heavily polluted by anthropogenic pollutants.展开更多
基金supported by the National Natural Science Foundation of China(No.42307139)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB0760200)。
文摘Water-soluble organic aerosol(WSOA)plays a significant role in air quality and human health.Here we characterized the chemical properties and molecular compositions of WSOA at a rural site in North China Plain during winter using a high-resolution aerosol mass spectrometer and electrospray ionization high-resolution orbitrap mass spectrometer(ESI-HRMS).Our results show that the mass concentration of WSOA was significantly higher than that observed in Beijing in winter 2020,contributing about 56%of OA on average.CHO compounds(56%-74%)and CHN compounds(66%-80%)dominated in negative mode and positive mode,respectively,while CHON accounted for 15%-41%across both modes.The chemical characteristics of WSOA varied with polluted levels and between day and night.As pollution intensified,the abundance of CHO-compounds with condensed aromatics increased by 9%and the number of highly oxygenated molecules(HOMs)molecular formula detected in server haze was more than double that of clean days.CHO-compounds with ten carbon atoms(C_(10))were more abundant at night while those with nine carbon atoms(C_(9))were higher during the day.High levels of CHN+compounds were linked to nighttime biomass burning,whereas CHON compounds were more abundant during the day.Increased pollution also led to the formation of more complex CHON-compounds,indicating that organonitrates continue to play a significant role in rural pollution.
基金supported by the Project of the Hubei Provincial Department of Science and Technology(Grant Nos.2022CFB957,2022CFB475)the National Natural Science Foundation of China(Grant No.11847118)。
文摘The decoherence of high-dimensional orbital angular momentum(OAM)entanglement in the weak scintillation regime has been investigated.In this study,we simulate atmospheric turbulence by utilizing a multiple-phase screen imprinted with anisotropic non-Kolmogorov turbulence.The entanglement negativity and fidelity are introduced to quantify the entanglement of a high-dimensional OAM state.The numerical evaluation results indicate that entanglement negativity and fidelity last longer for a high-dimensional OAM state when the azimuthal mode has a lower value.Additionally,the evolution of higher-dimensional OAM entanglement is significantly influenced by OAM beam parameters and turbulence parameters.Compared to isotropic atmospheric turbulence,anisotropic turbulence has a lesser influence on highdimensional OAM entanglement.
基金supported by the National Key R&D Program(No.2021YFE0117300)the National Natural Science Foundation of China(No.42375090)+6 种基金Shenzhen Key Laboratory of Precision Measurement and Early Warning Technology for Urban Environmental Health Risks(No.ZDSYS20220606100604008)Guangdong Basic and Applied Basic Research Foundation(No.2021A1515110713)Guangdong University Research Project Science Team(No.2021KCXTD004)the Major Talent Project of Guangdong Province(No.2021QN020924)Shandong Provincial Natural Science Foundation,China(No.ZR2020QD012)Shenzhen Science and Technology Program(Nos.KQTD20210811090048025,JCYJ20210324104604012 and JCYJ20220530115404009)supported by the Center for Computational Science and Engineering at Southern University of Science and Technology.
文摘Ozone production sensitivity is widely used to reveal the chemical dominant precursors of urban ozone rise.Here,we diagnose the impact of the decline in global human production activities level caused by the COVID-19 on ozone sensitivity through the ratio of formaldehyde(HCHO)and NO_(2)(FNR=HCHO/NO_(2))observations from the TROPOspheric Monitoring Instrument.We use a relative uncertainty threshold to clean the satellite FNR,and our satellite FNR present a good correlation(R=0.6248)with U.S.Environmental Protection Agency observations.We found that the outbreak of the COVID-19 did not change the pattern of global ozone sensitivity,while the global regimes was transforming or strengthening to VOC-limited regimes due to the significant decline of human production activities levels.During the COVID-19,ozone sensitivity in Eastern China and East Africa continued to shift to VOC-limited regimes,while India,Western Europe and North America first moved to NOx-limited regimes,and then changed to VOC-limited regimes with the resumption of production and the increase in travel.The clustering results tell that urban ozone sensitivity tends to shift towards NOx-limited regimes as economic growing.The ozone formation in cities with lower FNR and per capita gross domestic product(GDP)are more sensitive to changes in VOCs,while cities with higher FNR and per capita GDP are more sensitive to variations in NOx.Cities with intermediate FNR and GDP are good evidence of the existence of transitional regimes.Our study identifies the driving role of urban economics in orienting the evolution of ozone sensitivity regimes.
基金Project supported by the National Natural Science Foundation of China(Grant No.61107066)
文摘By using wave optics numerical simulation, the intensity-hole effect, beam spreading and wandering properties of Gaussian vortex beam propagation in atmospheric turbulence are investigated quantitatively. It is found that an intensity hole in the center of the beam pattern appears gradually as a Gaussian vortex beam propagates. The size of the intensity hole increases with the increase of the topological charge of the vortex phase. However, the intensity hole could to some extent be filled with optical energy by atmospheric turbulence, especially in strong turbulence. The radius of the intensity hole first decreases and then increases with the growth of turbulence strength. The effective radius of vortex beam with larger topological charge is greater than with a smaller topological charge. But the topological charge has no evident influence on beam wandering.
基金supported by the National Defense Innovation Foundation of China,Chinese Academy of Sciences(Grant No.CXJJ-16S080)
文摘The entangled orbital angular momentum（OAM） three photons propagating in Kolmogorov weak turbulence are investigated. Here, the single phase screen model is used to study the entanglement evolution of OAM photons. The results indicate that the entangled OAM three-qubit state with higher OAM modes will be more robust against turbulence.Furthermore, it is found that the entangled OAM three-qubit state has a higher overall transmission for small OAM values.
基金supported by the National Key Research and Development Program of China (No. 2017YFC0210001)the National Natural Science Foundation of China (Nos. 41830106, 42022039)+1 种基金Beijing National Laboratory for Molecular Sciences (No. BNLMS-CXXM-202011)the Youth Innovation Promotion Association CAS (No. 2017042)
文摘Atmospheric oxidizing capacity(AOC)is the fundamental driving factors of chemistry process(e.g.,the formation of ozone(O_(3))and secondary organic aerosols(SOA))in the troposphere.However,accurate quantification of AOC still remains uncertainty.In this study,a comprehensive field campaign was conducted during autumn 2019 in downtown of Beijing,where O_(3) and PM_(2.5) episodes had been experienced successively.The observation-based model(OBM)is used to quantify the AOC at O_(3) and PM_(2.5) episodes.The strong intensity of AOC is found at O_(3) and PM2.5 episodes,and hydroxyl radical(OH)is the dominating daytime oxidant for both episodes.The photolysis of O_(3) is main source of OH at O_(3) episode;the photolysis of nitrous acid(HONO)and formaldehyde(HCHO)plays important role in OH formation at PM_(2.5) episode.The radicals loss routines vary according to precursor pollutants,resulting in different types of air pollution.O_(3) budgets and sensitivity analysis indicates that O_(3) production is transition regime(both VOC and NOx-limited)at O3 episode.The heterogeneous reaction of hydroperoxy radicals(HO_(2))on aerosol surfaces has significant influence on OH and O_(3) production rates.The HO_(2) uptake coefficient(γHO_(2))is the determining factor and required accurate measurement in real atmospheric environment.Our findings could provide the important bases for coordinated control of PM_(2.5) and O_(3) pollution.
基金supported by the National Natural Science Foundation of China (Grant no. 41275020)supported by the Chinese Polar Environment Comprehensive Investigation & Assessment Programs (Grant nos. CHINARE2013-02-03, CHINARE2014-02 -03, and CHINARE201502-03)+1 种基金the Polar Science Innovation Fund for Young Scientists of Polar Research Institute of China (Grant no. CX20130201)the Shanghai Natural Science Foundation (Grant no. 14ZR1444100).
文摘To find the optimal location for large-aperture telescopes is a goal of astronomy. Chinese Antarctic astronomy has begun to flourish in recent years, and it is an urgent need in basic astronomical work to measure and analyze the optical turbulence spatiotemporal distribution in the Antarctic region. We analyzed turbulence data measured by a mobile atmospheric parameter measurement system from 30 December 2013 to 10 February 2014 at Antarctic Taishan Station. Because there is a discrepancy between the refractive index structure constant Cn2 measured by an ultrasonic anemometer with a single-point temperature structure function method and by micro-thermometer, a new method to measure C,2 with a temperature spectrum method is proposed herein. Through comparing long-term continuous Cn2 data derived from ultrasonic anemometer with those via the new method and micro-thermometer, trend, magnitude and measured weak turbulence of-2× 10-16m-2/3 are generally satisfactory. The reason for the discrepancy in Cn2 measurement between the ultrasonic anemometer with the old method and micro-thermometer is investigated.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 61107066 and 40805006)
文摘Propagation properties of spatially pseudo-partially coherent Gaussian Schell-model beams through the atmo- spheric turbulence over a long-distance uplink path are studied by numerical simulation. A linear coordination trans- formation is introduced to overcome the window effect and the loss-of-resolution problem. The beam spreading, beam wandering, and intensity scintillation as functions of turbulence strength, source correlation length, and change fre- quency of random phase that models the partial coherence of the source are analyzed. It is found that the beam spreading and the intensity scintillation of the partially coherent beam are less affected by the turbulence than those of the coherent one, but it suffers from a more severe diffractive effect, and the change frequency of random phase has no evident influence on it. The beam wandering is insensitive to the variation of source correlation length, and decreases firstly then goes to a fixed value as the change frequency increases.
基金supported by the Open Research Fund of Key Laboratory of Atmospheric Composition and Optical Radiation, Chinese Academy of Sciences (No. JJ-10-04)the National Natural Science Foundation of China (No.40975080, 10979061)class A technology fund of Department of Education of Fujian Province (No. JA11290)
文摘Secondary organic aerosol （SOA） formed from Cl-initiated oxidation of toluene was investigated in a home-made smog chamber. The size distribution and chemical composition of SOA particles were measured using aerodynamic particle sizer spectrometer and the aerosol laser time-of-flight mass spectrometer （ALTOFMS）, respectively. According to a large number of single aerosol diameter and mass spectra, the size distribution and chemical composition of SOA were obtained statistically. Experimental results showed that SOA particles created by Cl-initiated oxidation of toluene is predominantly in the form of fine particles, which have diameters less than 2.5 μm （i.e., PM2.5）, and glyoxal, benzaldehyde, benzyl alcohol, benzoquinone, benzoic acid, benzyl hydroperoxide and benzyl methyl nitrate are the major products components in the SOA. The possible reaction mechanisms leading to these products are also proposed.
基金supported by the Chinese Polar Environment Comprehensive Investigation & Assessment Programs (Grant nos. CHINARE-2013-02-03 and CHINARE-2014-02-03)the Polar Science Innovation Fund for Young Scientists of Polar Research Institute of China (Grant no. CX20130201)+1 种基金the Shanghai Natural Science Foundation (Grant no. 14ZR1444100)the National Basic Research Program of China (973 Program, Grant no. 2013CB834905)
文摘This is the second paper of a series devoted to atmospheric optical turbulence Cn^2 observation using a mobile polar atmospheric parameter measurement system. We present the initial results of Cn^2 measurement at Antarctic Taishan Station using micro-thermal sensors and a three-dimensional sonic anemometer at height -2.0 m above the snow surface. The site testing experiments were carried out during the 30th Chinese National Antarctic Research Expedition （CH1NARE）. We collected about 1 000 h of data between 30 December 2013 and 10 February 2014. The C,： curve exhibits clear daily structures, with two peaks around midnight and midday and two troughs around 7：30 and 17：00 local time （UTC＋5）. The mean C,2 is 2.7×10^-15 m^-2/3 and the 25th and 75th percentiles of the C,2 cumulative distribution are 9.6×10^-16 m^-2/3 and 6.2×10^-15 m^-2/3, respectively. Meteorological parameters such as temperature, relative humidity, wind speed, and air pressure are also presented.
基金Supported by the National Natural Science Foundation of China under Grant No 0704071, and the Fund of Anhui Key Laboratory of Optoelectronic Science and Technology.
文摘Propagation properties of coherent and partially coherent beams in atmospheric turbulence are investigated respectively by using numerical simulation It is found that a partially coherent beam has a spreading larger than a coherent beam. However, from the point view of relative beam spreading and intensity scintillation, a partially coherent beam is less affected than the corresponding coherent beam, which may be the most important virtue of partially coherent beams that could be utilized to improve the performance of laser engineering. The beam wandering is almost independent of the degree of the source coherence. More aperture averaging occurs when beam becomes more coherent.
基金supported by the National Natural Science Foundation of China(Nos.21806012,41775127,and 42075112)the Basic Research Fund of CAMS(No.2020Z002)
文摘The incineration of sacrificial offerings is a significant widely practiced custom that is also a kind of neglected air pollution source in China.Our results showed that the emission factors of particulate matter,SO_(2),CO,NO_(x),and VOCs emitted from the incineration of sacrificial offerings with purification systems were reduced by 95%,19%,9%,82%,and 42%,respectively,compared with those without a purification system,revealing a significant effect of the flue gas purification system on reducing particulate matter and gaseous pollutants.The emission level of air pollutants from the incineration of sacrificial offerings remained stable before 2013 and then showed a remarkable decrease after the implementation of China′s Air Pollution Prevention Action Plan in 2013.The emissions of TSP(total suspended particulate),PM_(10),PM_(2.5),and NO_(x)in 2009 were 8222,6106,5656 and 15,878 ton,respectively,obviously higher than 3434,2551,2305 and 8579 ton in 2019.Such trend was affected by both the quantity of incineration and the installation rate of purification systems after the Emission Standard of Air Pollutants for Crematory(GB 13801-2015)issued in China.Distinct spatial distribution of atmospheric pollutants from incineration of sacrificial offerings was found with higher in the east and south of China than the west and north of China,which is proportional to the regional economy and population.The maximum ground-level concentration typically occurred at 0.12-0.2 km from the pollution source,posing potential health risks to people entering and exiting funeral and burial sites and nearby residents.
基金supported by the Ministry of Science and Technology of the People’s Republic of China(No.2017YFC0210000)the Young Talent Project of the Center for Excellence in Regional Atmospheric Environment,CAS(No.CERAE202002)+1 种基金the National Natural Science Foundation of China(No.41705110)Beijing Major Science and Technology Project(No.Z211100004321006)。
文摘Atmospheric oxidizing capacity(AOC)is an essential driving force of troposphere chemistry and self-cleaning,but the definition of AOC and its quantitative representation remain uncertain.Driven by national demand for air pollution control in recent years,Chinese scholars have carried out studies on theories of atmospheric chemistry and have made considerable progress in AOC research.This paper will give a brief review of these developments.First,AOC indexes were established that represent apparent atmospheric oxidizing ability(AOIe)and potential atmospheric oxidizing ability(AOIp)based on aspects of macrothermodynamics and microdynamics,respectively.A closed study refined the quantitative contributions of heterogeneous chemistry to AOC in Beijing,and these AOC methods were further applied in Beijing-Tianjin-Hebei and key areas across the country.In addition,the detection of ground or vertical profiles for atmospheric OH·,HO_(2)·,NO_(3)·radicals and reservoir molecules can now be obtained with domestic instruments in diverse environments.Moreover,laboratory smoke chamber simulations revealed heterogeneous processes involving reactions of O_(3)and NO_(2),which are typical oxidants in the surface/interface atmosphere,and the evolutionary and budgetary implications of atmospheric oxidants reacting under multispecies,multiphase and multi-interface conditions were obtained.Finally,based on the GRAPES-CUACE adjoint model improved by Chinese scholars,simulations of key substances affecting atmospheric oxidation and secondary organic and inorganic aerosol formation have been optimized.Normalized numerical simulations of AOIe and AOIp were performed,and regional coordination of AOC was adjusted.An optimized plan for controlling O_(3)and PM2.5was analyzed by scenario simulation.
基金Project supported by the Major Research Plan of the National Natural Science Foundation of China(Grant No.11847118)。
文摘The entangled orbital angular momentum(OAM)photons propagating across a weakly turbulent atmosphere are investigated.Here,the paper uses the single-phase screen model based on the Kolmogorov theory of turbulence,and focuses on the influence of the backward scattering on OAM evolution.The results indicate that backward scattering plays an important role in the analysis of OAM entanglement evolution in the turbulent atmosphere.It cannot be negligible especially for higher-order OAM mode.Moreover,when OAM mode is greater than 4,entangled photon pairs composed of higher OAM modes are not more robust in turbulence within the weak scintillation regime.These results will be useful in future investigations of OAM-based optical wave propagation through turbulent atmosphere.
基金supported by the National High Technology Research and Development Program of China (GrantNo. 2011AA8061007)
文摘Random fluctuations of turbulence bring random fluctuations of the refractive index, making the atmosphere a random fluctuation medium that destroys the coherence of light-waves. Research in atmospheric turbulence is actually the investigation of the atmospheric refractive index. The atmospheric structure constant of refractive index, C n 2 , is an important parameter denoting atmospheric turbulence. In this paper, C n 2 is measured during the day and at night and in all four seasons using a high sensitivity micro-thermal meter QHTP-2. The vertical profile of C n 2 in Hefei (0-30 km) is investigated by the analysis of experimental data. The average profile of C n 2 in Hefei exhibits conspicuous day and night differences with increased altitude. The distribution of log(C n 2 ) is nearly normal and has conspicuous seasonal differences.
基金supported by the National Natural Science of Foundation of China(41825011,42030608,42105128,and 42075079)the Opening Foundation of Key Laboratory of Atmospheric Sounding,the CMA and the CMA Research Center on Meteorological Observation Engineering Technology(U2021Z03).
文摘The Advanced Geosynchronous Radiation Imager(AGRI)is a mission-critical instrument for the Fengyun series of satellites.AGRI acquires full-disk images every 15 min and views East Asia every 5 min through 14 spectral bands,enabling the detection of highly variable aerosol optical depth(AOD).Quantitative retrieval of AOD has hitherto been challenging,especially over land.In this study,an AOD retrieval algorithm is proposed that combines deep learning and transfer learning.The algorithm uses core concepts from both the Dark Target(DT)and Deep Blue(DB)algorithms to select features for the machinelearning(ML)algorithm,allowing for AOD retrieval at 550 nm over both dark and bright surfaces.The algorithm consists of two steps:①A baseline deep neural network(DNN)with skip connections is developed using 10 min Advanced Himawari Imager(AHI)AODs as the target variable,and②sunphotometer AODs from 89 ground-based stations are used to fine-tune the DNN parameters.Out-of-station validation shows that the retrieved AOD attains high accuracy,characterized by a coefficient of determination(R2)of 0.70,a mean bias error(MBE)of 0.03,and a percentage of data within the expected error(EE)of 70.7%.A sensitivity study reveals that the top-of-atmosphere reflectance at 650 and 470 nm,as well as the surface reflectance at 650 nm,are the two largest sources of uncertainty impacting the retrieval.In a case study of monitoring an extreme aerosol event,the AGRI AOD is found to be able to capture the detailed temporal evolution of the event.This work demonstrates the superiority of the transfer-learning technique in satellite AOD retrievals and the applicability of the retrieved AGRI AOD in monitoring extreme pollution events.
基金The authors wish to thank the Ecosystem Approach to the management of fisheries and the marine environment in the West African Waters(AWA)project.They also acknowledge support from the international joint laboratory ECLAIRS.The Laboratoire de Météorologie Dynamique(LMD)and the Global Challenges Research Fund(GCRF)African Science for Weather Information and Techniques(SWIFT)Programme.NASA,CNES,and ICARE are acknowledged for providing access to CALIOP and Sun photometer AERONET data.
文摘Saharan dust represents more than 50%of the total desert dust emitted around the globe and its radiative effect significantly affects the atmospheric circulation at a continental scale.Previous studies on dust vertical distribution and the Saharan Air Layer(SAL)showed some shortcomings that could be attributed to imperfect representation of the effects of deep convection and scavenging.The authors investigate here the role of deep convective transport and scavenging on the vertical distribution of mineral dust over Western Africa.Using multi-year(2006-2010)simulations performed with the variable-resolution(zoomed)version of the LMDZ climate model.Simulations are compared with aerosol amounts recorded by the Aerosol Robotic Network(AERONET)and with vertical profiles of the Cloud-Aerosol Lidar with Orthogonal Polarization(CALIOP)measurements.LMDZ allows a thorough examination of the respective roles of deep convective transport,convective and stratiform scavenging,boundary layer transport,and advection processes on the vertical mineral dust distribution over Western Africa.The comparison of simulated dust Aerosol Optical Depth(AOD)and distribution with measurements suggest that scavenging in deep convection and subsequent re-evaporation of dusty rainfall in the lower troposphere are critical processes for explaining the vertical distribution of desert dust.These processes play a key role in maintaining a well-defined dust layer with a sharp transition at the top of the SAL and in establishing the seasonal cycle of dust distribution.This vertical distribution is further reshaped offshore in the Inter-Tropical Convergence Zone(ITCZ)over the Atlantic Ocean by marine boundary layer turbulent and convective transport and wet deposition at the surface.
基金supported by National Natural Science Foundation of China(42325505 and U2233203 to H.L.)National Key Research and Development Program of China(2022YFC3704200).
文摘Currently,over 80%of the international trade volume is carried by sea.Marked by persistent growth,evident atmospheric impacts,intricate mitigation challenges,international shipping has been recognized as one of the most“hard-to-abate”sectors gathering increasing attention from both academic community and governmental sectors in recent years.Against the backdrop of the ambitious climate and clean air objectives,the quantitative shipping emission characterization,impact assessment and policy effectiveness research are not only fundamental to understand the status quo and ramifications of shipping emissions but also beneficial for future emission regulations.Here,we summarized the achievements in shipping emission modelling and impact research in the past two decades,and identified the challenges lying in the transition pathway towards a clean and carbon-neutral shipping.To address the pressing demand for this,we proposed an innovative framework which aims to facilitate emission abatement.Finally,promising directions for future work were delineated,including the indirect effects of shipping emitted aerosols on the climate,the emissions and impacts of novel contaminants,synergies and conflicts among different emission reduction measures,projections on future shipping emission inventories,Arctic shipping emissions,etc.
基金supported by funds from the Scientific Research Projects of High-level Talents of the Department of Human Resources and Social Security of Anhui Province (Grant No.2009Z019)the State Key Laboratory of Atmospheric Boundary Physics and Atmospheric Chemistry (Grant No.LAPC-KF-201105)
文摘One hundred and ten samples of rainwater were collected for chemical analysis at the summit of Huangshan Mountain, a high-altitude site in East China, from July 2010 to June 2011. The volume-weighted-mean （VWM） pH for the whole sampling period was 5.03. SO2- and Ca2＋ were the most abundant anion and cation, respectively. The ionic concentrations varied monthly with the highest concentrations in winter/spring and the lowest in summer. Evident inter-correlations were found among most ions, indicating the common sources for some species and fully mixing characteristics of the alpine precipitation chemistry. The VWM ratio of [SO]-]/[NO3] was 2.54, suggesting the acidity of rainwater comes from both nitric and sulfuric acids. Compared with contemporary observations at other alpine continental sites in China, the precipitation at Huangshan Mountain was the least polluted, with the lowest ionic concentrations. Trajectories to Huangshan Mountain on rainy days could be classified into six groups. The rainwater with influencing air masses originating in Mongolia was the most polluted with limited effect. The emissions of Jiangxi, Anhui, Zhejiang and Jiangsu provinces had a strong influence on the overall rain chemistry at Huangshan Mountain. The rainwater with influencing air masses from Inner Mongolia was heavily polluted by anthropogenic pollutants.
