Integrated sensing and communication(ISAC),assisted by reconfigurable intelligent surface(RIS)has emerged as a breakthrough technology to improve the capacity and reliability of 6G wireless network.However,a significa...Integrated sensing and communication(ISAC),assisted by reconfigurable intelligent surface(RIS)has emerged as a breakthrough technology to improve the capacity and reliability of 6G wireless network.However,a significant challenge in RIS-ISAC systems is the acquisition of channel state information(CSI),largely due to co-channel interference,which hinders meeting the required reliability standards.To address this issue,a minimax-concave penalty(MCP)-based CSI refinement scheme is proposed.This approach utilizes an element-grouping strategy to jointly estimate the ISAC channel and the RIS phase shift matrix.Unlike previous methods,our scheme exploits the inherent sparsity in RIS-assisted ISAC channels to reduce training overhead,and the near-optimal solution is derived for our studied RIS-ISAC scheme.The effectiveness of the element-grouping strategy is validated through simulation experiments,demonstrating superior channel estimation results when compared to existing benchmarks.展开更多
The high-entropy alloy(HEA)superconductor,Ta_(1/6)Nb_(2/6)Hf_(1/6)Zr_(1/6)Ti_(1/6)(Ta-Nb-Hf-Zr-Ti),is systematically studied to examine changes in superconducting critical properties,critical temperature(T_(c)),critic...The high-entropy alloy(HEA)superconductor,Ta_(1/6)Nb_(2/6)Hf_(1/6)Zr_(1/6)Ti_(1/6)(Ta-Nb-Hf-Zr-Ti),is systematically studied to examine changes in superconducting critical properties,critical temperature(T_(c)),critical cur-rent density(J_(c)),and upper critical field(H_(c2)),concerning thermal treatment conditions.Annealing condi-tion affects Jc more significantly than T_(c)and H_(c2),with a large improvement of flux pinning force density(F_(p)).The Jc of bare sample is reduced to 10 A cm^(-2)at an applied magnetic field of approximately 1.5 T,whereas the sample annealed at 550℃for 12 h exhibits J_(c)>100 kA cm^(-2)up to around 4 T.Furthermore,the Vickers hardness(HVIT)of the Ta-Nb-Hf-Zr-Ti HEA superconductor notably increases from∼384 to 528 HVIT following a 24-h annealing at 500℃.These results demonstrate that thermal annealing is a powerful process to optimize both the superconducting and mechanical properties of high-entropy alloy superconductors.展开更多
In order to investigate the influence of different heavy metal ions on the formation of the oxyfluoride glasses and glass ceramics, samples with different Pb F2/Cd F2 ratios have been prepared by the melting quenching...In order to investigate the influence of different heavy metal ions on the formation of the oxyfluoride glasses and glass ceramics, samples with different Pb F2/Cd F2 ratios have been prepared by the melting quenching and thermal treatment method. The different effects of Pb2 tand Cd2ton the glass network structure are investigated by FTIR and Raman spectra. During the formation of glass network structure, Pb2 tprefers to break the Sie Oe Si bond and subsequently bond to F for charge compensation, and Cd2 tprefers to break the SieO eA l bond and is surrounded by O2. Pb2 tand F gather together and form the fluoride nanocrystals,while Cd2 tremains in oxide matrix after thermal treatment. Introduction of proper Cd F2 is important to adjust and control the glass network structure and crystallization process in the fabrication of the transparent glass ceramics.展开更多
The reflectivity of one-dimensional chalcogenide photonic crystal(CGPC) structure with the first order reflection band in near infrared(NIR) region is theoretically studied.Sb-Se and Ge-S chalcogenide glasses are used...The reflectivity of one-dimensional chalcogenide photonic crystal(CGPC) structure with the first order reflection band in near infrared(NIR) region is theoretically studied.Sb-Se and Ge-S chalcogenide glasses are used as high and low refractive index layers respectively,because these materials have zero absorption in NIR region.The transfer matrix method(TMM) is employed to calculate the reflective spectra of the proposed structure.The theoretical results of reflective spectra of bulk chalcogenide materials with the composition of Sb40Se60 and Ge30S70 for 4,8,12 and 15 layers and thicknesses of 117 nm and 183 nm respectively,at normal incidence,are close agreement with the experimental results.Furthermore,by increasing the number of layers of Sb40Se60 and Ge30S70,the reflection bands can be enhanced in the wider range of the NIR region for the polarization at different angles and thus the broadband omnidirectional reflector can be designed.展开更多
We present a detailed analysis on mode evolution of gratingcoupled surface plasmonic polaritons （SPPs） on a conical metal tip based on the guidedwave theory. The eigenvalue equations for SPPs modes are discussed, re...We present a detailed analysis on mode evolution of gratingcoupled surface plasmonic polaritons （SPPs） on a conical metal tip based on the guidedwave theory. The eigenvalue equations for SPPs modes are discussed, revealing that cylindrical metal waveguides only support TM01 and HEm1 surface modes. During propagation on the metal tip, the gratingcoupled SPPs are converted to HE31, HE21, HE11 and TM01 successively, and these modes are sequentially cut off except TM01. The TM01 mode further propagates with drastically increasing effective mode index and is converted to localized surface plasmons （LSPs） at the tip apex, which is responsible for plasmonic nanofocusing. The gapmode plasmons can be excited with the focusing TM01 mode by approaching a metal substrate to the tip apex, resulting in further enhanced electric field and reduced size of the plasmonic focus.展开更多
Developing moisture-sensitive artificial muscles from industrialized natural fibers with large abundance is highly desired for smart textiles that can respond to humidity or temperature change.However,currently most o...Developing moisture-sensitive artificial muscles from industrialized natural fibers with large abundance is highly desired for smart textiles that can respond to humidity or temperature change.However,currently most of fiber artificial muscles are based on non-common industrial textile materials or of a small portion of global textile fiber market.In this paper,we developed moisture-sensitive torsional artificial muscles and textiles based on cotton yarns.It was prepared by twisting the cotton yarn followed by folding in the middle point to form a self-balanced structure.The cotton yarn muscle showed a torsional stroke of 42.55°/mm and a rotational speed of 720 rpm upon exposure to water moisture.Good reversibility and retention of stroke during cyclic exposure and removal of water moisture were obtained.A moisturesensitive smart window that can close when it rains was demonstrated based on the torsional cotton yarn muscles.This twist-based technique combining natural textile fibers provides a new insight for construction of smart textile materials.展开更多
Pests detecting is an important research subject in grain storage field.In the past decades,many edge detection methods have been applied to the edge detection of stored grain pests.Although some of them can realize t...Pests detecting is an important research subject in grain storage field.In the past decades,many edge detection methods have been applied to the edge detection of stored grain pests.Although some of them can realize the stored grain pests detecting,precision and robustness are not good enough.Spectral residual(SR)saliency edge detection defines the logarithmic spectrumof image as novelty part of the image information.The remaining spectrumis converted to the airspace to obtain edge detection results.SR algorithm is completely based on frequency domain processing.It not only can effectively simplify the target detection algorithm,but also can improve the effectiveness of target recognition.The experimental results show that the edge results of stored grain pests detected by SR method are effective and stable.展开更多
Recently, two dimensional In Se attracts great attentions as potential hydrogen production photocatalysts.Here, comprehensive investigations on the hydrogen evolution reaction activity of In Se monolayer with3 d trans...Recently, two dimensional In Se attracts great attentions as potential hydrogen production photocatalysts.Here, comprehensive investigations on the hydrogen evolution reaction activity of In Se monolayer with3 d transition metal doping and biaxial strain were performed based on the density functional theory.Transition metal dopants significantly increase the bonding strength between H and Se, and then adjust the hydrogen adsorption free energy to 0.02 e V by Zn doping. The enhanced hydrogen evolution reaction activity results from less electron occupying H 1 s-Se 4 pzanti-bonding states, which is well correlated with the pzband center level. Importantly, the universal scalling law was proposed to descript the evolution of hydrogen adsorption free energy including both doping and strain effects. Moreover, with appropriate band alignment, optical absorption, and carriers separation ability, Zn doped In Se monolayer is considered as a promising candidate of visible-light photocatalyst for hydrogen production.展开更多
Fe-N thin films were fabricated on both 100Si and NaCl substrates by RF magnetron sputtering under low nitrogen partial pressure.The microstructure and magnetic properties of Fe-N thin films were investigated with the...Fe-N thin films were fabricated on both 100Si and NaCl substrates by RF magnetron sputtering under low nitrogen partial pressure.The microstructure and magnetic properties of Fe-N thin films were investigated with the increase of the substrate temperature(Ts)and the annealing temperature(Ta).It is more difficult for nitrogen atoms to enter the Fe lattice under higher Ts above 150℃.The phase evolution is visible at higher Ta above 200℃.The phase transformation ofα''-Fe16N2 occurred at 400℃.The change of crystal size with Ta was clearly visible from bright and dark field images.The clear high-resolution electron microscope(HREM)images of 110α,111γ',112α'',and 200α''phases were observed.The interplanar distances from TEM(transmission electron microscope)and HREM match the calculated values very well.From the results of the vibrating sample magnetometer(VSM),the good magnetic properties of Fe-N films were obtained at 150℃of Ts and 200℃of Ta,respectively.展开更多
Twisted bilayer graphene(TBG),which has drawn much attention in recent years,arises from van der Waals materials gathering each component together via van der Waals force.It is composed of two sheets of graphene rotat...Twisted bilayer graphene(TBG),which has drawn much attention in recent years,arises from van der Waals materials gathering each component together via van der Waals force.It is composed of two sheets of graphene rotated relatively to each other.Moirépotential,resulting from misorientation between layers,plays an essential role in determining the band structure of TBG,which directly relies on the twist angle.Once the twist angle approaches a certain critical value,flat bands will show up,indicating the suppression of kinetic energy,which significantly enhances the importance of Coulomb interaction between electrons.As a result,correlated states like correlated insulators emerge from TBG.Surprisingly,superconductivity in TBG is also reported in many experiments,which drags researchers into thinking about the underlying mechanism.Recently,the interest in the atomic reconstruction of TBG at small twist angles comes up and reinforces further understandings of properties of TBG.In addition,twisted multilayer graphene receives more and more attention,as they could likely outperform TBG although they are more difficult to handle experimentally.In this review,we mainly introduce theoretical and experimental progress on TBG.Besides the basic knowledge of TBG,we emphasize the essential role of atomic reconstruction in both experimental and theoretical investigations.The consideration of atomic reconstruction in small-twist situations can provide us with another aspect to have an insight into physical mechanism in TBG.In addition,we cover the recent hot topic,twisted multilayer graphene.While the bilayer situation can be relatively easy to resolve,multilayer situations can be really complicated,which could foster more unique and novel properties.Therefore,in the end of the review,we look forward to future development of twisted multilayer graphene.展开更多
Black carbon(BC)is one of the short-lived air pollutants that contributes significantly to aerosol radiative forcing and global climate change.It is emitted by the incomplete combustion of fossil fuels,biofuels,and bi...Black carbon(BC)is one of the short-lived air pollutants that contributes significantly to aerosol radiative forcing and global climate change.It is emitted by the incomplete combustion of fossil fuels,biofuels,and biomass.Urban environments are quite complex and thus,the use of mobile jointly with fixed monitoring provides a better understanding of the dynamics of BC distribution in such areas.The present study addresses the measurement of BC concentration using real-time mobile and ambient monitoring in Barranquilla,an industrialized urban area of the Colombian Caribbean.A microaethalometer(MA200)and an aethalometer(AE33)were used for measuring the BC concentration.The absorption Ångström exponent(AAE)values were determined for the study area,for identifying the BC emission sources.The results of the ambient sampling show that vehicle traffic emissions prevail;however,the influence of biomass burning was also observed.The mean ambient BC concentration was found to be 1.04±1.03μg/m^(3) and varied between 0.5 and 4.0μg/m^(3).From the mobile measurements obtained in real traffic conditions on the road,a much higher average value of 16.1±16.5μg/m^(3) was measured.Many parts of the city showed BC concentrations higher than 20μg/m^(3).The spatial distribution of BC concentration shows that vehicle emissions and traffic jams,a consequence of road and transport infrastructure,are the factors that most affect the BC concentration.A comparison of results obtained from two aethalometers indicates that the concentrations measured by MA200 are 9%lower than those measured by AE33.The AAE obtained was found to vary between 1.1 and 1.6,indicating vehicular emissions as the most crucial source.In addition,it was observed that the BC concentration on working days was 2.5 times higher than on the weekends in the case of mobile monitoring and 1.5 times higher in the case of ambient monitoring.展开更多
Density functional theory was employed to investigate the effect of the hydrogen in the adsorption and direct dissociation of CO on Fe (100) surface. The preadsorption of hydrogen with coverages of 0, 1/3 and 2/3 mono...Density functional theory was employed to investigate the effect of the hydrogen in the adsorption and direct dissociation of CO on Fe (100) surface. The preadsorption of hydrogen with coverages of 0, 1/3 and 2/3 monolayer (ML) was used in the present investigation. In the case of 1/3 ML of hydrogen, two configurations of adsorption were studied. The presence of hydrogen shows a major transference of electronic density from Fe surface to CO adsorbed, increasing the adsorption energy of CO from 2.00 eV in clean surface, to 2.76 eV in 2/3 ML of hydrogen. Furthermore, the activation barrier for direct dissociation of CO was 1.13 eV and for the recombination energy 2.28 eV on clean Fe (100) surface. In the same way, the activation barrier for CO in the presence of coadsorbed hydrogen was slightly affected presenting values of 1.06 eV and 1.16 eV to 1/3 ML configurations and 0.98 eV for 2/3 ML of hydrogen. Finally, the recombination energy decreases to 1.63 eV and 1.49 eV for 1/3 ML configurations and to 1.23 eV for 2/3 ML of coadsorbed hydrogen. These results indicate that the CO adsorption and dissociation are favored in the presence of hydrogenated surfaces.展开更多
Although abundant research on the anisotropy of van der Waals(vd W)materials has been published,we undertake an in-depth study of their optical properties as they have an important guiding role for light control in tw...Although abundant research on the anisotropy of van der Waals(vd W)materials has been published,we undertake an in-depth study of their optical properties as they have an important guiding role for light control in two-dimensional(2D)nanospace.As an example,we study the reflectance of few-layered black phosphorus(BP)in the total internal reflection(TIR)mode in detail.We demonstrate that its optical anisotropy can be changed on a large scale by varying the incident angles,polarization states,and the in-plane rotation angles of the BP samples.Theoretical analysis indicates that the phenomena observed are common to all the atom-thick biaxial crystals,so these conclusions can be widely applied to other anisotropic 2D materials.This research furthers the current understanding of the properties of BP more comprehensively,and provides guidance for developing new optoelectronic applications,especially when BP and other atom-thick biaxial crystals are integrated with TIR devices.展开更多
The general characteristic equation is derived for the helically cladded step-index optical fiber. The dispersion curves are drawn for the different pitch angles Ψ and mode order ν = 1. The effect of helix pitch ang...The general characteristic equation is derived for the helically cladded step-index optical fiber. The dispersion curves are drawn for the different pitch angles Ψ and mode order ν = 1. The effect of helix pitch angle on the dispersion characteristics and also on the modal cut-off condition is examined. Except for the lowest order mode, all the modes appear in pairs. The lowest order mode displays the negative dispersion for the some value of normalized frequency V and depends on the helix pitch angle Ψ.展开更多
TiO2-δ nanoparticles are synthesized by the sol-gel method and annealed under different reducing atmosphere. The x-ray diffraction patterns show that anatase is the dominant phase with small amounts of the futile pha...TiO2-δ nanoparticles are synthesized by the sol-gel method and annealed under different reducing atmosphere. The x-ray diffraction patterns show that anatase is the dominant phase with small amounts of the futile phase of TiO2-δ for all the samples. Magnetic measurements indicate that the samples annealed in reducing atmosphere exhibit unprecedented room-temperature ferromagnetism, in particular, the saturation magnetization Ms is up to about 8.6 × 10^-3 emu/g for the sample annealed in H2/Ar mixture. Analysis of the x-ray photoelectron spectroscopy spectra for the samples processed under different conditions indicates that the amounts of Ti^3＋ or Ti^2＋ cations, namely, the concentration of oxygen vacancies, increase with intensifying reducing atmosphere during processing, which shows that ferromagnetism in this material strongly depends on the concentration of oxygen vacancies. The relationships between the ferromagnetism and the crystal structure as well as the grain size in this material are also discussed.展开更多
Air pollution has become an important issue,especially in Caribbean urban areas,and,particulate matter(PM)emitted by different natural and anthropogenic sources causes environmental and health issues.In this work,we s...Air pollution has become an important issue,especially in Caribbean urban areas,and,particulate matter(PM)emitted by different natural and anthropogenic sources causes environmental and health issues.In this work,we studied the concentrations of PM_(10) and PM_(2.5) sources in an industrial and port urban area in the Caribbean region of Colombia.PM samples were collected within 48-h periods between April and October 2018 by using a Partisol 2000 i-D sampler.Elemental geochemical characterization was performed by X-ray fluorescence(XRF)analysis.Further,ionic species and black carbon(BC)were quantified by ion chromatography and reflectance spectroscopy,respectively.Using the Positive Matrix Factorization(PMF)receptor model,the contributions of PM sources were quantified.The average concentration of PM_(10) was 46.6±16.2μg/m^(3),with high concentrations of Cl and Ca.For PM_(2.5),the average concentration was 12.0±3.2μg/m^(3),and the most abundant components were BC,S,and Cl.The receptor model identified five sources for PM_(10) and PM_(2.5).For both fractions,the contributions of marine sea spray,re-suspended soil,and vehicular traffic were observed.In addition,PM_(2.5) included two mixed sources were found to be fuel oil combustion with fertilizer industry emissions,and secondary aerosol sources with building construction emissions.Further,PM_(10) was found to also include building construction emissions with re-suspended soil,and metallurgical industry emissions.These obtained geochemical atmospheric results are important for the implementation of strategies for the continuous improvement of the air quality of the Caribbean region.展开更多
Perovskite [(Ba0.6Sr0.4)TiO3]-[2SiO2-B2O3]-[K2O]-La2O3 glass was prepared by conventional melt quench method. The differential thermal analysis (DTA) was performed on glass sample in the temperature range from 100℃ t...Perovskite [(Ba0.6Sr0.4)TiO3]-[2SiO2-B2O3]-[K2O]-La2O3 glass was prepared by conventional melt quench method. The differential thermal analysis (DTA) was performed on glass sample in the temperature range from 100℃ to 1000℃ by different heating rate to study the crystallization kinematics. The kinetic parameters characterizing the crystallization have been determined using an Arrhenius model. Glass samples were subjected to appropriate heat treatment schedules for their suitable crystallization. X-ray diffraction analysis (XRD) of glass and glass ceramic samples were done to check the amorphous state and crystalline nature. XRD of glass ceramic sample shows the major perovskite phase of BaTiO3 (BT) along with the formation of secondary phases Ba2TiSi2O8 (BTS) and Ba2Ti2B2O9 (BTB). Scanning electron microscopy (SEM) is also studied to see the morphology of the grains of major and secondary phase formation in BST glass ceramic samples. La2O3 is played an important role to increase the nucleation of the crystallites in the glassy matrix. The addition of La22O3 results in development of well interconnected crystallites formed as major phase of BST. In this paper, we are reporting the crystallization behavior of BST borosilicate glass system and high temperature dielectric characteristics of their glass ceramics.展开更多
A uniformly valid approximate solution of a kind of nonlinear wave equations is studied. The research results indicate that the solution of this kind of equations can be represented by Airy function approximately. The...A uniformly valid approximate solution of a kind of nonlinear wave equations is studied. The research results indicate that the solution of this kind of equations can be represented by Airy function approximately. The usually used W. K. B. approximation is the first order approximation of the present result in the region far away from the turning point of refractivity. At the turning point of refractivity, the present result is still valid.展开更多
Photonic analogs of the moirésuperlattices mediated by interlayer electromagnetic coupling are expected to give rise to rich phenomena,such as nontrivial flatband topology.Here,we propose and demonstrate a scheme...Photonic analogs of the moirésuperlattices mediated by interlayer electromagnetic coupling are expected to give rise to rich phenomena,such as nontrivial flatband topology.Here,we propose and demonstrate a scheme to tune the flatbands in a bilayer moirésuperlattice by employing a band offset.The band offset is changed by fixing the bands of one slab while shifting those of the other slab,which is accomplished by modifying the thickness of the latter slab.Our results show that the band-offset tuning not only makes some flatbands emerge and disappear but also leads to two sets of flatbands that are robustly formed even with the change of band offset over a broad range.These robust flatbands form either at the AA-stack site or at the AB-stack site,and as a result,a single-cell superlattice can support a pair of high-quality localized modes with tunable frequencies.Moreover,we develop a diagrammatic model to provide an intuitive insight into the formation of the robust flatbands.Our work demonstrates a simple yet efficient way to design and control complex moiréflatbands,providing new opportunities to utilize photonic moirésuperlattices for advanced light–matter interaction,including lasing and nonlinear harmonic generation.展开更多
The quantum teleportation with the entangled thermai state is investigated based on the completely anisotropie Heisenberg chain in the presence of the externally inhomogeneous magnetic field. The effects of the anisot...The quantum teleportation with the entangled thermai state is investigated based on the completely anisotropie Heisenberg chain in the presence of the externally inhomogeneous magnetic field. The effects of the anisotropy and magnetic field for the quantum fidelity are studied in detail The zero temperature limit and the features of the nonzero temperature for this nonclassical fdelity are obtained. We find that the quantum teleportation demands more stringent conditions than the therma/ entanglement of the resource by investigating the threshold temperature of the thermal concurrence and the criticai temperature of the maximai teleportation fidelity. The useful quantum teleportation should avoid the point of the phase transition of the system and the anisotropy of the chain and the external magnetic field can control the applicability of the resource in the quantum teleportation.展开更多
基金supported in part by the National Natural Science Foundation of China under Grant 62001171in part by the Natural Science Foundation of Guangdong Province under Grant 2024A1515011172in part by the Henan Science and Technology Research and Development Program Joint Fund under Grant 235200810049。
文摘Integrated sensing and communication(ISAC),assisted by reconfigurable intelligent surface(RIS)has emerged as a breakthrough technology to improve the capacity and reliability of 6G wireless network.However,a significant challenge in RIS-ISAC systems is the acquisition of channel state information(CSI),largely due to co-channel interference,which hinders meeting the required reliability standards.To address this issue,a minimax-concave penalty(MCP)-based CSI refinement scheme is proposed.This approach utilizes an element-grouping strategy to jointly estimate the ISAC channel and the RIS phase shift matrix.Unlike previous methods,our scheme exploits the inherent sparsity in RIS-assisted ISAC channels to reduce training overhead,and the near-optimal solution is derived for our studied RIS-ISAC scheme.The effectiveness of the element-grouping strategy is validated through simulation experiments,demonstrating superior channel estimation results when compared to existing benchmarks.
基金supported by the National Research Foundation of Korea(NRF)grant funded by the Korean government(MIST)(Nos.2021R1A2C2010925,RS-2023-00240326,and RS-2023-00220471)Basic Science Research Program through the NRF of Korea funded by the Ministry of Education(Nos.NRF-2019R1F1A1055284 and NRF-2021R1I1A1A01043885).
文摘The high-entropy alloy(HEA)superconductor,Ta_(1/6)Nb_(2/6)Hf_(1/6)Zr_(1/6)Ti_(1/6)(Ta-Nb-Hf-Zr-Ti),is systematically studied to examine changes in superconducting critical properties,critical temperature(T_(c)),critical cur-rent density(J_(c)),and upper critical field(H_(c2)),concerning thermal treatment conditions.Annealing condi-tion affects Jc more significantly than T_(c)and H_(c2),with a large improvement of flux pinning force density(F_(p)).The Jc of bare sample is reduced to 10 A cm^(-2)at an applied magnetic field of approximately 1.5 T,whereas the sample annealed at 550℃for 12 h exhibits J_(c)>100 kA cm^(-2)up to around 4 T.Furthermore,the Vickers hardness(HVIT)of the Ta-Nb-Hf-Zr-Ti HEA superconductor notably increases from∼384 to 528 HVIT following a 24-h annealing at 500℃.These results demonstrate that thermal annealing is a powerful process to optimize both the superconducting and mechanical properties of high-entropy alloy superconductors.
基金supported by the National Science Fund for Talent Training in Basic Sciences (No. J1103208)
文摘In order to investigate the influence of different heavy metal ions on the formation of the oxyfluoride glasses and glass ceramics, samples with different Pb F2/Cd F2 ratios have been prepared by the melting quenching and thermal treatment method. The different effects of Pb2 tand Cd2ton the glass network structure are investigated by FTIR and Raman spectra. During the formation of glass network structure, Pb2 tprefers to break the Sie Oe Si bond and subsequently bond to F for charge compensation, and Cd2 tprefers to break the SieO eA l bond and is surrounded by O2. Pb2 tand F gather together and form the fluoride nanocrystals,while Cd2 tremains in oxide matrix after thermal treatment. Introduction of proper Cd F2 is important to adjust and control the glass network structure and crystallization process in the fabrication of the transparent glass ceramics.
文摘The reflectivity of one-dimensional chalcogenide photonic crystal(CGPC) structure with the first order reflection band in near infrared(NIR) region is theoretically studied.Sb-Se and Ge-S chalcogenide glasses are used as high and low refractive index layers respectively,because these materials have zero absorption in NIR region.The transfer matrix method(TMM) is employed to calculate the reflective spectra of the proposed structure.The theoretical results of reflective spectra of bulk chalcogenide materials with the composition of Sb40Se60 and Ge30S70 for 4,8,12 and 15 layers and thicknesses of 117 nm and 183 nm respectively,at normal incidence,are close agreement with the experimental results.Furthermore,by increasing the number of layers of Sb40Se60 and Ge30S70,the reflection bands can be enhanced in the wider range of the NIR region for the polarization at different angles and thus the broadband omnidirectional reflector can be designed.
基金This work was financially supported by the National Natural Science Foundation of China （NSFC） （61675169, 61377055 and 11634010）, the National Key R＆D Program of China （2017YFA0303800）, and the Fundamental Research Funds for the Central Universities （3102017zy021, 3102017HQZZ 022）.
文摘We present a detailed analysis on mode evolution of gratingcoupled surface plasmonic polaritons （SPPs） on a conical metal tip based on the guidedwave theory. The eigenvalue equations for SPPs modes are discussed, revealing that cylindrical metal waveguides only support TM01 and HEm1 surface modes. During propagation on the metal tip, the gratingcoupled SPPs are converted to HE31, HE21, HE11 and TM01 successively, and these modes are sequentially cut off except TM01. The TM01 mode further propagates with drastically increasing effective mode index and is converted to localized surface plasmons （LSPs） at the tip apex, which is responsible for plasmonic nanofocusing. The gapmode plasmons can be excited with the focusing TM01 mode by approaching a metal substrate to the tip apex, resulting in further enhanced electric field and reduced size of the plasmonic focus.
基金Project supported by the National Key Research and Development Program of China(Grant No.2017YFB0307001)the National Natural Science Foundation of China(Grant Nos.U1533122 and 51773094)+4 种基金the Natural Science Foundation of Tianjin,China(Grant No.18JCZDJC36800)the Science Foundation for Distinguished Young Scholars of Tianjin,China(Grant No.18JCJQJC46600)the Fundamental Research Funds for the Central Universities,China(Grant No.63171219)Key Laboratory for Medical Data Analysis and Statistical Research of TianjinState Key Laboratory for Modification of Chemical Fibers and Polymer Materials,Donghua University(Grant No.LK1704)。
文摘Developing moisture-sensitive artificial muscles from industrialized natural fibers with large abundance is highly desired for smart textiles that can respond to humidity or temperature change.However,currently most of fiber artificial muscles are based on non-common industrial textile materials or of a small portion of global textile fiber market.In this paper,we developed moisture-sensitive torsional artificial muscles and textiles based on cotton yarns.It was prepared by twisting the cotton yarn followed by folding in the middle point to form a self-balanced structure.The cotton yarn muscle showed a torsional stroke of 42.55°/mm and a rotational speed of 720 rpm upon exposure to water moisture.Good reversibility and retention of stroke during cyclic exposure and removal of water moisture were obtained.A moisturesensitive smart window that can close when it rains was demonstrated based on the torsional cotton yarn muscles.This twist-based technique combining natural textile fibers provides a new insight for construction of smart textile materials.
基金financially supported by National Natural Science Foundation of China(No.61871176)Key Scientific and Technological Project of Science and Technology Department of Henan Province(No.172102210030,182102110099)+2 种基金Key Scientific Research Project Program of Universities of Henan Province(No.18B520025)Open Fund of Key Laboratory of Grain Information Processing and Control(No.KFJJ-2018-102)supported by Collaborative Innovation Center of Grain Storage and Security of Henan Province
文摘Pests detecting is an important research subject in grain storage field.In the past decades,many edge detection methods have been applied to the edge detection of stored grain pests.Although some of them can realize the stored grain pests detecting,precision and robustness are not good enough.Spectral residual(SR)saliency edge detection defines the logarithmic spectrumof image as novelty part of the image information.The remaining spectrumis converted to the airspace to obtain edge detection results.SR algorithm is completely based on frequency domain processing.It not only can effectively simplify the target detection algorithm,but also can improve the effectiveness of target recognition.The experimental results show that the edge results of stored grain pests detected by SR method are effective and stable.
基金supported by the National Natural Science Foundation of China(11804023)the Natural Science Foundation of Tianjin(18JCQNJC02700)。
文摘Recently, two dimensional In Se attracts great attentions as potential hydrogen production photocatalysts.Here, comprehensive investigations on the hydrogen evolution reaction activity of In Se monolayer with3 d transition metal doping and biaxial strain were performed based on the density functional theory.Transition metal dopants significantly increase the bonding strength between H and Se, and then adjust the hydrogen adsorption free energy to 0.02 e V by Zn doping. The enhanced hydrogen evolution reaction activity results from less electron occupying H 1 s-Se 4 pzanti-bonding states, which is well correlated with the pzband center level. Importantly, the universal scalling law was proposed to descript the evolution of hydrogen adsorption free energy including both doping and strain effects. Moreover, with appropriate band alignment, optical absorption, and carriers separation ability, Zn doped In Se monolayer is considered as a promising candidate of visible-light photocatalyst for hydrogen production.
基金supported by the National Natural Science Foundation of China(No.50674071)Tianjin Natural Science Foundation of China(No.06YFJZJC01300)+1 种基金the Program for New Century Excellent Talents in University(NCET-06-0245)the Platform Project of Tianjin for Innovation in Science and Technology and Environmental Construction(No.06TXTJJC13900).
文摘Fe-N thin films were fabricated on both 100Si and NaCl substrates by RF magnetron sputtering under low nitrogen partial pressure.The microstructure and magnetic properties of Fe-N thin films were investigated with the increase of the substrate temperature(Ts)and the annealing temperature(Ta).It is more difficult for nitrogen atoms to enter the Fe lattice under higher Ts above 150℃.The phase evolution is visible at higher Ta above 200℃.The phase transformation ofα''-Fe16N2 occurred at 400℃.The change of crystal size with Ta was clearly visible from bright and dark field images.The clear high-resolution electron microscope(HREM)images of 110α,111γ',112α'',and 200α''phases were observed.The interplanar distances from TEM(transmission electron microscope)and HREM match the calculated values very well.From the results of the vibrating sample magnetometer(VSM),the good magnetic properties of Fe-N films were obtained at 150℃of Ts and 200℃of Ta,respectively.
文摘Twisted bilayer graphene(TBG),which has drawn much attention in recent years,arises from van der Waals materials gathering each component together via van der Waals force.It is composed of two sheets of graphene rotated relatively to each other.Moirépotential,resulting from misorientation between layers,plays an essential role in determining the band structure of TBG,which directly relies on the twist angle.Once the twist angle approaches a certain critical value,flat bands will show up,indicating the suppression of kinetic energy,which significantly enhances the importance of Coulomb interaction between electrons.As a result,correlated states like correlated insulators emerge from TBG.Surprisingly,superconductivity in TBG is also reported in many experiments,which drags researchers into thinking about the underlying mechanism.Recently,the interest in the atomic reconstruction of TBG at small twist angles comes up and reinforces further understandings of properties of TBG.In addition,twisted multilayer graphene receives more and more attention,as they could likely outperform TBG although they are more difficult to handle experimentally.In this review,we mainly introduce theoretical and experimental progress on TBG.Besides the basic knowledge of TBG,we emphasize the essential role of atomic reconstruction in both experimental and theoretical investigations.The consideration of atomic reconstruction in small-twist situations can provide us with another aspect to have an insight into physical mechanism in TBG.In addition,we cover the recent hot topic,twisted multilayer graphene.While the bilayer situation can be relatively easy to resolve,multilayer situations can be really complicated,which could foster more unique and novel properties.Therefore,in the end of the review,we look forward to future development of twisted multilayer graphene.
基金supported by the Department of Civil and Environmental of the Universidad de la Costathe Center for Environmental Technology Research(Centro de Investigación de Tecnologías Ambientales–CITA)+1 种基金the Environmental Management and Sustainability Research Group(Grupo de Investigación de Gestión y Sostenibilidad Ambiental–GESSA)partial financial support from Colciencias Colombia(Project 141180764164,Contract 815-2018)。
文摘Black carbon(BC)is one of the short-lived air pollutants that contributes significantly to aerosol radiative forcing and global climate change.It is emitted by the incomplete combustion of fossil fuels,biofuels,and biomass.Urban environments are quite complex and thus,the use of mobile jointly with fixed monitoring provides a better understanding of the dynamics of BC distribution in such areas.The present study addresses the measurement of BC concentration using real-time mobile and ambient monitoring in Barranquilla,an industrialized urban area of the Colombian Caribbean.A microaethalometer(MA200)and an aethalometer(AE33)were used for measuring the BC concentration.The absorption Ångström exponent(AAE)values were determined for the study area,for identifying the BC emission sources.The results of the ambient sampling show that vehicle traffic emissions prevail;however,the influence of biomass burning was also observed.The mean ambient BC concentration was found to be 1.04±1.03μg/m^(3) and varied between 0.5 and 4.0μg/m^(3).From the mobile measurements obtained in real traffic conditions on the road,a much higher average value of 16.1±16.5μg/m^(3) was measured.Many parts of the city showed BC concentrations higher than 20μg/m^(3).The spatial distribution of BC concentration shows that vehicle emissions and traffic jams,a consequence of road and transport infrastructure,are the factors that most affect the BC concentration.A comparison of results obtained from two aethalometers indicates that the concentrations measured by MA200 are 9%lower than those measured by AE33.The AAE obtained was found to vary between 1.1 and 1.6,indicating vehicular emissions as the most crucial source.In addition,it was observed that the BC concentration on working days was 2.5 times higher than on the weekends in the case of mobile monitoring and 1.5 times higher in the case of ambient monitoring.
文摘Density functional theory was employed to investigate the effect of the hydrogen in the adsorption and direct dissociation of CO on Fe (100) surface. The preadsorption of hydrogen with coverages of 0, 1/3 and 2/3 monolayer (ML) was used in the present investigation. In the case of 1/3 ML of hydrogen, two configurations of adsorption were studied. The presence of hydrogen shows a major transference of electronic density from Fe surface to CO adsorbed, increasing the adsorption energy of CO from 2.00 eV in clean surface, to 2.76 eV in 2/3 ML of hydrogen. Furthermore, the activation barrier for direct dissociation of CO was 1.13 eV and for the recombination energy 2.28 eV on clean Fe (100) surface. In the same way, the activation barrier for CO in the presence of coadsorbed hydrogen was slightly affected presenting values of 1.06 eV and 1.16 eV to 1/3 ML configurations and 0.98 eV for 2/3 ML of hydrogen. Finally, the recombination energy decreases to 1.63 eV and 1.49 eV for 1/3 ML configurations and to 1.23 eV for 2/3 ML of coadsorbed hydrogen. These results indicate that the CO adsorption and dissociation are favored in the presence of hydrogenated surfaces.
基金supported by the K. C. Wong Education Foundation (GJTD-2018-08)the Natural Science Foundation of China (NSFC) (Grants 11804334, 51705192)+1 种基金the China Postdoctoral Science Foundation (2017M611325)the National Postdoctoral Program for Innovative Talents (BX201600064)
文摘Although abundant research on the anisotropy of van der Waals(vd W)materials has been published,we undertake an in-depth study of their optical properties as they have an important guiding role for light control in two-dimensional(2D)nanospace.As an example,we study the reflectance of few-layered black phosphorus(BP)in the total internal reflection(TIR)mode in detail.We demonstrate that its optical anisotropy can be changed on a large scale by varying the incident angles,polarization states,and the in-plane rotation angles of the BP samples.Theoretical analysis indicates that the phenomena observed are common to all the atom-thick biaxial crystals,so these conclusions can be widely applied to other anisotropic 2D materials.This research furthers the current understanding of the properties of BP more comprehensively,and provides guidance for developing new optoelectronic applications,especially when BP and other atom-thick biaxial crystals are integrated with TIR devices.
文摘The general characteristic equation is derived for the helically cladded step-index optical fiber. The dispersion curves are drawn for the different pitch angles Ψ and mode order ν = 1. The effect of helix pitch angle on the dispersion characteristics and also on the modal cut-off condition is examined. Except for the lowest order mode, all the modes appear in pairs. The lowest order mode displays the negative dispersion for the some value of normalized frequency V and depends on the helix pitch angle Ψ.
基金Supported by the National Natural Science Foundation of China under Grant No 50674071, the Tianjin Natural Science Foundation （06YFJZJC01300）, the Programme for New Century Excellent Talents in University （NCET-06-0245）, and the Platform Project of Tianjin for Innovation in Science and Technology and Environmental Construction （06TXTJJC13900）.
文摘TiO2-δ nanoparticles are synthesized by the sol-gel method and annealed under different reducing atmosphere. The x-ray diffraction patterns show that anatase is the dominant phase with small amounts of the futile phase of TiO2-δ for all the samples. Magnetic measurements indicate that the samples annealed in reducing atmosphere exhibit unprecedented room-temperature ferromagnetism, in particular, the saturation magnetization Ms is up to about 8.6 × 10^-3 emu/g for the sample annealed in H2/Ar mixture. Analysis of the x-ray photoelectron spectroscopy spectra for the samples processed under different conditions indicates that the amounts of Ti^3＋ or Ti^2＋ cations, namely, the concentration of oxygen vacancies, increase with intensifying reducing atmosphere during processing, which shows that ferromagnetism in this material strongly depends on the concentration of oxygen vacancies. The relationships between the ferromagnetism and the crystal structure as well as the grain size in this material are also discussed.
基金financial support from the Departamento Administrativo de CienciaTecnología e Innovación(Colciencias)for Project#141180764164,Contract 815-2018。
文摘Air pollution has become an important issue,especially in Caribbean urban areas,and,particulate matter(PM)emitted by different natural and anthropogenic sources causes environmental and health issues.In this work,we studied the concentrations of PM_(10) and PM_(2.5) sources in an industrial and port urban area in the Caribbean region of Colombia.PM samples were collected within 48-h periods between April and October 2018 by using a Partisol 2000 i-D sampler.Elemental geochemical characterization was performed by X-ray fluorescence(XRF)analysis.Further,ionic species and black carbon(BC)were quantified by ion chromatography and reflectance spectroscopy,respectively.Using the Positive Matrix Factorization(PMF)receptor model,the contributions of PM sources were quantified.The average concentration of PM_(10) was 46.6±16.2μg/m^(3),with high concentrations of Cl and Ca.For PM_(2.5),the average concentration was 12.0±3.2μg/m^(3),and the most abundant components were BC,S,and Cl.The receptor model identified five sources for PM_(10) and PM_(2.5).For both fractions,the contributions of marine sea spray,re-suspended soil,and vehicular traffic were observed.In addition,PM_(2.5) included two mixed sources were found to be fuel oil combustion with fertilizer industry emissions,and secondary aerosol sources with building construction emissions.Further,PM_(10) was found to also include building construction emissions with re-suspended soil,and metallurgical industry emissions.These obtained geochemical atmospheric results are important for the implementation of strategies for the continuous improvement of the air quality of the Caribbean region.
文摘Perovskite [(Ba0.6Sr0.4)TiO3]-[2SiO2-B2O3]-[K2O]-La2O3 glass was prepared by conventional melt quench method. The differential thermal analysis (DTA) was performed on glass sample in the temperature range from 100℃ to 1000℃ by different heating rate to study the crystallization kinematics. The kinetic parameters characterizing the crystallization have been determined using an Arrhenius model. Glass samples were subjected to appropriate heat treatment schedules for their suitable crystallization. X-ray diffraction analysis (XRD) of glass and glass ceramic samples were done to check the amorphous state and crystalline nature. XRD of glass ceramic sample shows the major perovskite phase of BaTiO3 (BT) along with the formation of secondary phases Ba2TiSi2O8 (BTS) and Ba2Ti2B2O9 (BTB). Scanning electron microscopy (SEM) is also studied to see the morphology of the grains of major and secondary phase formation in BST glass ceramic samples. La2O3 is played an important role to increase the nucleation of the crystallites in the glassy matrix. The addition of La22O3 results in development of well interconnected crystallites formed as major phase of BST. In this paper, we are reporting the crystallization behavior of BST borosilicate glass system and high temperature dielectric characteristics of their glass ceramics.
文摘A uniformly valid approximate solution of a kind of nonlinear wave equations is studied. The research results indicate that the solution of this kind of equations can be represented by Airy function approximately. The usually used W. K. B. approximation is the first order approximation of the present result in the region far away from the turning point of refractivity. At the turning point of refractivity, the present result is still valid.
基金supported by Sichuan Science and Technology Program(2023NSFSC0460)the Fundamental Research Funds for the Central Universities(Grant No.ZYGX2020J010)+3 种基金the Open Project Funding of the Ministry of Education Key Laboratory of Weak-Light Nonlinear Photonics(Grant No.OS22-1)the Guangxi Natural Science Foundation(Grant No.2020GXNSFAA297041)the National Key R&D Program of China(Grant No.2022YFA1404800)the National Natural Science Foundation of China(Grant No.12134006).
文摘Photonic analogs of the moirésuperlattices mediated by interlayer electromagnetic coupling are expected to give rise to rich phenomena,such as nontrivial flatband topology.Here,we propose and demonstrate a scheme to tune the flatbands in a bilayer moirésuperlattice by employing a band offset.The band offset is changed by fixing the bands of one slab while shifting those of the other slab,which is accomplished by modifying the thickness of the latter slab.Our results show that the band-offset tuning not only makes some flatbands emerge and disappear but also leads to two sets of flatbands that are robustly formed even with the change of band offset over a broad range.These robust flatbands form either at the AA-stack site or at the AB-stack site,and as a result,a single-cell superlattice can support a pair of high-quality localized modes with tunable frequencies.Moreover,we develop a diagrammatic model to provide an intuitive insight into the formation of the robust flatbands.Our work demonstrates a simple yet efficient way to design and control complex moiréflatbands,providing new opportunities to utilize photonic moirésuperlattices for advanced light–matter interaction,including lasing and nonlinear harmonic generation.
基金Supported by the Special Research Fund Provided by the Chonnam National University
文摘The quantum teleportation with the entangled thermai state is investigated based on the completely anisotropie Heisenberg chain in the presence of the externally inhomogeneous magnetic field. The effects of the anisotropy and magnetic field for the quantum fidelity are studied in detail The zero temperature limit and the features of the nonzero temperature for this nonclassical fdelity are obtained. We find that the quantum teleportation demands more stringent conditions than the therma/ entanglement of the resource by investigating the threshold temperature of the thermal concurrence and the criticai temperature of the maximai teleportation fidelity. The useful quantum teleportation should avoid the point of the phase transition of the system and the anisotropy of the chain and the external magnetic field can control the applicability of the resource in the quantum teleportation.
