This study presents a novel approach to enhance silicon anode performance through barium titanate(BTO)incorporation,with the establishment of a force-electric coupling model.By introducing piezoelectric BTO into silic...This study presents a novel approach to enhance silicon anode performance through barium titanate(BTO)incorporation,with the establishment of a force-electric coupling model.By introducing piezoelectric BTO into silicon matrices,we successfully improved both the mechanical stability and electrochemical kinetics of the anode.The developed force-electric coupling model explains how BTO mitigates stress accumulation during lithiation while optimizing the kinetics of Li^(+)and electron transfer.Experimental verification and multiphysical simulation indicate that Si@BTO effectively eliminates structural degradation during the cycling process and significantly reduces the charge transfer resistance.The force-electric coupling mechanism further facilitates stable solid electrolyte interphase(SEI)formation.When paired with LiFePO_(4)cathodes,Si@BTO maintains 76% capacity retention after 500 cycles at a 10 C rate.This work establishes a basic force-electric coupling model framework and offers insights into the development of advanced silicon anode batteries with exceptional performance.展开更多
In this paper, the notion of limit random logarithmic likelihood ratio of stochastic se-quences,as a measure of "dissimilarity" between their joint distributions and the product of theirmarginals,is introduc...In this paper, the notion of limit random logarithmic likelihood ratio of stochastic se-quences,as a measure of "dissimilarity" between their joint distributions and the product of theirmarginals,is introduced. Construct a. s. convergence supermartingale by means of truncation methodand under suitable restrict Chung-Teicher type conditions,some strong deviation theorems for arbi-trary discrete stochastic sequence are obtained.展开更多
Alternative switch combustion mode of air and gas is adopted on the two sides of the regenerative furnace, its temperature is in uncontrolled state in the switching process and the switch period is generally 3 ～ 5 mi...Alternative switch combustion mode of air and gas is adopted on the two sides of the regenerative furnace, its temperature is in uncontrolled state in the switching process and the switch period is generally 3 ～ 5 min. Thus, the conventional bi-cross limited combustion control method is no longer applicable to the object. This paper makes use of neutral network algorithm to adjust the static operating point. On this basis, fuzzy control strategy is used for the furnace temperature control. The actual application result shows that the control strategy is effective to solve the problem of the combustion control for regenerative furnace.展开更多
The microstructure, substructure, and wear characteristic of cobalt-basedalloy coatings obtained by plasma transferred arc (PTA) process were investigated using opticalmetallurgical microscope, X-ray diffraction (XRD)...The microstructure, substructure, and wear characteristic of cobalt-basedalloy coatings obtained by plasma transferred arc (PTA) process were investigated using opticalmetallurgical microscope, X-ray diffraction (XRD), scanning electron microscope (SEM), transmissionelectron microscope (TEM), and dry sand abrasion tester (DSAT). The aging effect on the structureand wear resistance of the cobalt-based PTA coating was also studied. The results show that theas-welded coating consists of cobalt-based solid solution with face-centered cubic structure andhexagonal (Cr,Fe)_7C_3. There are a lot of stacking faults existing in the cobalt-based solidsolution. After aging at 600 deg C for 60 h, the microstructure becomes coarse, and another carbide(Cr,Fe)_(23)C_6 precipitates. As a result, the wear mass loss of the aged sample is higher than thatof the as-welded sample.展开更多
According to the principle of damage mechanics, the damage characteristics of ferrite nodular cast iron under uniaxial stress were studied by measuring electric resistance. The results show that the damage in nodular ...According to the principle of damage mechanics, the damage characteristics of ferrite nodular cast iron under uniaxial stress were studied by measuring electric resistance. The results show that the damage in nodular cast iron occurs when the applied stress is more than a certain extent, and the damage variable increases with stress. The evolutional law of damage variable as a function of stress was obtained. The damage threshold of nodular cast iron increases with nodularity, but it is below the yield strength, which provides reference significance to the design of machinery structure and the choice of materials. The critical damage variable is not related to the nodularity, which is about 0 060-0 068.展开更多
The effects of gas composition, temperature, ore to coke ratio and prereduction rate of ore on coke degradation were studied. The results showed that 1% increment in solution loss of coke reduces coke strength by 0.6%...The effects of gas composition, temperature, ore to coke ratio and prereduction rate of ore on coke degradation were studied. The results showed that 1% increment in solution loss of coke reduces coke strength by 0.6%, and the coke degradation is accelerated with the temperature. The higher the temperature, the more coke surface is involved in reactions, and the less negative effect on coke strength is. Hydrogen exerts stronger effect on coke degradation than CO at high temperature. The coke degradation is decreased with the reduction of ore to coke ratio and increase of ore prereduction rate.展开更多
In this paper the nonnegative classical solutions of a parabolic system with nonlinear boundary conditions are discussed. The existence and uniqueness of a nonnegative classical solution are proved. And some sufficien...In this paper the nonnegative classical solutions of a parabolic system with nonlinear boundary conditions are discussed. The existence and uniqueness of a nonnegative classical solution are proved. And some sufficient conditions to ensure the global existence and nonexistence of nonnegative classical solution to this problem are given. MR Subject Classification 35B40 - 35K55 Keywords nonnegative solution - blow up - nonlinear boundary conditions - parabolic system Supported by the Natural Science Foundation of the Education Department of Anhui Province (2001kj038zc).展开更多
A C-iso-butyl-cavitand bowl with trimethyl and methylol groups was isolated from the acetoxymethyl hydrolysis of mono-methylbromo-cavitand in THF. The molecular structure of the present cavitand compound was determi...A C-iso-butyl-cavitand bowl with trimethyl and methylol groups was isolated from the acetoxymethyl hydrolysis of mono-methylbromo-cavitand in THF. The molecular structure of the present cavitand compound was determined by single-crystal X-ray diffraction. The compound (C56H70N2O9) crystallizes in orthorhombic, space group Pnma with a = 19.5060(15), b = 19.8136(15), c = 12.9508(10) ?, V = 5005.3(7) ?3, Z = 4, Mr = 915.14, Dc = 1.214 g/cm3, F(000) = 1968, μ = 0.081 mm?1, S = 1.012, the final R = 0.0789 and wR = 0.1488 for 2298 observed reflections with I > 2σ(I) and 322 variable parameters. The structure exhibits a rigid bowl-cavity with an available functional hydroxyl group. The bowl of cavitand contains a CH3CN solvent molecule, and the depth of the bowl-shaped cavity is ca. 2.42 ?.展开更多
X-ray crystal structures of co-crystals involving tetra-iso-butyl-resorcin[4]arene 1 with both acetone and acetonitrile solvents were reported. The component 1?2(CH3)2CO 2 assembles such that the resorcin[4]arene adop...X-ray crystal structures of co-crystals involving tetra-iso-butyl-resorcin[4]arene 1 with both acetone and acetonitrile solvents were reported. The component 1?2(CH3)2CO 2 assembles such that the resorcin[4]arene adopts a C2v conformation and the acetone serves as hydrogen bond acceptors, forming a 1D hydrogen-bonded polymer. 2 (C50H68O10) crystallizes in the triclinic, space group P1 with a = 10.0440(7), b = 13.7498(9), c = 17.6374(12) ?, α = 77.726(2), β = 86.733(2), γ = 88.634(2)o, V = 2376.1(3) ?3, Dc = 1.159 g/cm3, and Z = 2. The assembly process of component 1?2CH3CN?H2O 3 yields a 2D hydrogen-bonded polymer formed by intermolecular hydrogen bonds between resorcin[4]arene and water molecules. In the case of component 3, the acetonitrile molecule serves as vip inside the bowl of resorcin[4]arene host. 3 (C48H64N2O9) crystallizes in the monoclinic, space group P2/n with a = 13.7570(18), b = 9.0961(12), c = 19.453(3) ?, β = 103.017(3)o, V = 2371.7(5) ?3, Dc = 1.138 g/cm3, and Z = 2.展开更多
Silicon fines, boron acid solid powders and microfine SiO 2 as sintering agents were incorporated into Al 2O 3-SiC-C ramming mix in order to investigated their effects on the microstructure, mechanical properties a...Silicon fines, boron acid solid powders and microfine SiO 2 as sintering agents were incorporated into Al 2O 3-SiC-C ramming mix in order to investigated their effects on the microstructure, mechanical properties and sintering behavior of the ramming mix. Results show that all the three agents could improved both densification and mehanical properties markedly, compared to that of non-agent specimens and the effect of the composite of boron acid solid powders and microfine SiO 2 is the best. The oxidation resistance increased with the addition of agents, which is supported by densification. Microstructures showed that agent powders could fill pores or produce liquid phases at high temperature, therefore, improve the sintering of the ramming mix.展开更多
Boehmite sol is synthesized via sol-gel process using Al 2(SO 4) 3·18H 2O and (CH 2) 6N 4 as starting materials, then adding silica sol into boehmite sol to prepare mullite precursor gels. XRD studies are ...Boehmite sol is synthesized via sol-gel process using Al 2(SO 4) 3·18H 2O and (CH 2) 6N 4 as starting materials, then adding silica sol into boehmite sol to prepare mullite precursor gels. XRD studies are performed to characterize the gels. It is found that the gel can be transformed into mullite when calcined at 1100℃ and completed at 1300℃. Corundum-mullite firebricks with different additions of the mullite precursor gel are made by mixing, semi-dry pressing and then sintering at 1520℃. Apparent porosity, bulk density, flexural strength and thermal shock resistance are measured. Results show that the mullite gel can improve densification and strength of corundum-mullite firebricks, especially enhance the thermal shock resistance. SEM micrographs show that the gel added can be formed into needlelike and elongated mullite in the matrix, whose micromorphology can enhance the strength and thermal shock resistance of the samples.展开更多
The aim of this experimental work was to investigate the Theological and adhesive performance of gunning mix suspensions. The results of rheological tests indicate that: the rheological curve of gunning mix bonded by ...The aim of this experimental work was to investigate the Theological and adhesive performance of gunning mix suspensions. The results of rheological tests indicate that: the rheological curve of gunning mix bonded by high-alumina cement (HACG) is Bingham type ; the rheological curve of low cement gunning mix (LCG) bonded by mi-crosilica is characterized by pseudo-plasticity fluid with yielding stress ; and the rheological property of low-cement gunning mix bonded by microsilica is proved to be better than that of gunning mix bonded by cement. Meanwhile as indicated by the adhesive tests: the better the rheological properties of gunning mix suspension , the better the repair effect would be.展开更多
The paper describes the recent developing situation and the latest research achievements of refractory for hot metal pretreatment. The relationship among desiliconization, dephosphorization and desulphurization techni...The paper describes the recent developing situation and the latest research achievements of refractory for hot metal pretreatment. The relationship among desiliconization, dephosphorization and desulphurization techniques and the main corrosion reactions by various treating agents is analyzed. Some improving measures for several problems in practice are put forward while we anticipate the future developing direction of refractory for hot metal pretreatment.展开更多
In this paper, a strong limit theorem on gambling strategy for binary Bernoulli sequence, (i.e.) irregularity theorem, is extended to random selection for dependent m-valued random variables, via using a new method-di...In this paper, a strong limit theorem on gambling strategy for binary Bernoulli sequence, (i.e.) irregularity theorem, is extended to random selection for dependent m-valued random variables, via using a new method-differentiability on net. Furthermore, by allowing the selection function to take value in finite interval [-M,M], the conception of random selection is generalized.展开更多
基金the financial support of the National Natural Science Foundation of China(NSFC,No.12074093)。
文摘This study presents a novel approach to enhance silicon anode performance through barium titanate(BTO)incorporation,with the establishment of a force-electric coupling model.By introducing piezoelectric BTO into silicon matrices,we successfully improved both the mechanical stability and electrochemical kinetics of the anode.The developed force-electric coupling model explains how BTO mitigates stress accumulation during lithiation while optimizing the kinetics of Li^(+)and electron transfer.Experimental verification and multiphysical simulation indicate that Si@BTO effectively eliminates structural degradation during the cycling process and significantly reduces the charge transfer resistance.The force-electric coupling mechanism further facilitates stable solid electrolyte interphase(SEI)formation.When paired with LiFePO_(4)cathodes,Si@BTO maintains 76% capacity retention after 500 cycles at a 10 C rate.This work establishes a basic force-electric coupling model framework and offers insights into the development of advanced silicon anode batteries with exceptional performance.
文摘In this paper, the notion of limit random logarithmic likelihood ratio of stochastic se-quences,as a measure of "dissimilarity" between their joint distributions and the product of theirmarginals,is introduced. Construct a. s. convergence supermartingale by means of truncation methodand under suitable restrict Chung-Teicher type conditions,some strong deviation theorems for arbi-trary discrete stochastic sequence are obtained.
文摘Alternative switch combustion mode of air and gas is adopted on the two sides of the regenerative furnace, its temperature is in uncontrolled state in the switching process and the switch period is generally 3 ～ 5 min. Thus, the conventional bi-cross limited combustion control method is no longer applicable to the object. This paper makes use of neutral network algorithm to adjust the static operating point. On this basis, fuzzy control strategy is used for the furnace temperature control. The actual application result shows that the control strategy is effective to solve the problem of the combustion control for regenerative furnace.
文摘The microstructure, substructure, and wear characteristic of cobalt-basedalloy coatings obtained by plasma transferred arc (PTA) process were investigated using opticalmetallurgical microscope, X-ray diffraction (XRD), scanning electron microscope (SEM), transmissionelectron microscope (TEM), and dry sand abrasion tester (DSAT). The aging effect on the structureand wear resistance of the cobalt-based PTA coating was also studied. The results show that theas-welded coating consists of cobalt-based solid solution with face-centered cubic structure andhexagonal (Cr,Fe)_7C_3. There are a lot of stacking faults existing in the cobalt-based solidsolution. After aging at 600 deg C for 60 h, the microstructure becomes coarse, and another carbide(Cr,Fe)_(23)C_6 precipitates. As a result, the wear mass loss of the aged sample is higher than thatof the as-welded sample.
基金Item Sponsored by Scientific and Technological Brainstorm Project for Ninth Five-Year Plan of China(97-225-02-02-11)
文摘According to the principle of damage mechanics, the damage characteristics of ferrite nodular cast iron under uniaxial stress were studied by measuring electric resistance. The results show that the damage in nodular cast iron occurs when the applied stress is more than a certain extent, and the damage variable increases with stress. The evolutional law of damage variable as a function of stress was obtained. The damage threshold of nodular cast iron increases with nodularity, but it is below the yield strength, which provides reference significance to the design of machinery structure and the choice of materials. The critical damage variable is not related to the nodularity, which is about 0 060-0 068.
文摘The effects of gas composition, temperature, ore to coke ratio and prereduction rate of ore on coke degradation were studied. The results showed that 1% increment in solution loss of coke reduces coke strength by 0.6%, and the coke degradation is accelerated with the temperature. The higher the temperature, the more coke surface is involved in reactions, and the less negative effect on coke strength is. Hydrogen exerts stronger effect on coke degradation than CO at high temperature. The coke degradation is decreased with the reduction of ore to coke ratio and increase of ore prereduction rate.
基金Supported by the Natural Science Foundation of the Education Department of Anhui Province( 2 0 0 1 kj0 38zc)
文摘In this paper the nonnegative classical solutions of a parabolic system with nonlinear boundary conditions are discussed. The existence and uniqueness of a nonnegative classical solution are proved. And some sufficient conditions to ensure the global existence and nonexistence of nonnegative classical solution to this problem are given. MR Subject Classification 35B40 - 35K55 Keywords nonnegative solution - blow up - nonlinear boundary conditions - parabolic system Supported by the Natural Science Foundation of the Education Department of Anhui Province (2001kj038zc).
基金This project was supported by the Key Scientific Research Foundation of State Education Ministry of China (No. 204067)
文摘A C-iso-butyl-cavitand bowl with trimethyl and methylol groups was isolated from the acetoxymethyl hydrolysis of mono-methylbromo-cavitand in THF. The molecular structure of the present cavitand compound was determined by single-crystal X-ray diffraction. The compound (C56H70N2O9) crystallizes in orthorhombic, space group Pnma with a = 19.5060(15), b = 19.8136(15), c = 12.9508(10) ?, V = 5005.3(7) ?3, Z = 4, Mr = 915.14, Dc = 1.214 g/cm3, F(000) = 1968, μ = 0.081 mm?1, S = 1.012, the final R = 0.0789 and wR = 0.1488 for 2298 observed reflections with I > 2σ(I) and 322 variable parameters. The structure exhibits a rigid bowl-cavity with an available functional hydroxyl group. The bowl of cavitand contains a CH3CN solvent molecule, and the depth of the bowl-shaped cavity is ca. 2.42 ?.
基金This project was supported by the Key Scientific Research Foundation of State Education Ministry of China (No. 204067)
文摘X-ray crystal structures of co-crystals involving tetra-iso-butyl-resorcin[4]arene 1 with both acetone and acetonitrile solvents were reported. The component 1?2(CH3)2CO 2 assembles such that the resorcin[4]arene adopts a C2v conformation and the acetone serves as hydrogen bond acceptors, forming a 1D hydrogen-bonded polymer. 2 (C50H68O10) crystallizes in the triclinic, space group P1 with a = 10.0440(7), b = 13.7498(9), c = 17.6374(12) ?, α = 77.726(2), β = 86.733(2), γ = 88.634(2)o, V = 2376.1(3) ?3, Dc = 1.159 g/cm3, and Z = 2. The assembly process of component 1?2CH3CN?H2O 3 yields a 2D hydrogen-bonded polymer formed by intermolecular hydrogen bonds between resorcin[4]arene and water molecules. In the case of component 3, the acetonitrile molecule serves as vip inside the bowl of resorcin[4]arene host. 3 (C48H64N2O9) crystallizes in the monoclinic, space group P2/n with a = 13.7570(18), b = 9.0961(12), c = 19.453(3) ?, β = 103.017(3)o, V = 2371.7(5) ?3, Dc = 1.138 g/cm3, and Z = 2.
文摘Silicon fines, boron acid solid powders and microfine SiO 2 as sintering agents were incorporated into Al 2O 3-SiC-C ramming mix in order to investigated their effects on the microstructure, mechanical properties and sintering behavior of the ramming mix. Results show that all the three agents could improved both densification and mehanical properties markedly, compared to that of non-agent specimens and the effect of the composite of boron acid solid powders and microfine SiO 2 is the best. The oxidation resistance increased with the addition of agents, which is supported by densification. Microstructures showed that agent powders could fill pores or produce liquid phases at high temperature, therefore, improve the sintering of the ramming mix.
文摘Boehmite sol is synthesized via sol-gel process using Al 2(SO 4) 3·18H 2O and (CH 2) 6N 4 as starting materials, then adding silica sol into boehmite sol to prepare mullite precursor gels. XRD studies are performed to characterize the gels. It is found that the gel can be transformed into mullite when calcined at 1100℃ and completed at 1300℃. Corundum-mullite firebricks with different additions of the mullite precursor gel are made by mixing, semi-dry pressing and then sintering at 1520℃. Apparent porosity, bulk density, flexural strength and thermal shock resistance are measured. Results show that the mullite gel can improve densification and strength of corundum-mullite firebricks, especially enhance the thermal shock resistance. SEM micrographs show that the gel added can be formed into needlelike and elongated mullite in the matrix, whose micromorphology can enhance the strength and thermal shock resistance of the samples.
文摘The aim of this experimental work was to investigate the Theological and adhesive performance of gunning mix suspensions. The results of rheological tests indicate that: the rheological curve of gunning mix bonded by high-alumina cement (HACG) is Bingham type ; the rheological curve of low cement gunning mix (LCG) bonded by mi-crosilica is characterized by pseudo-plasticity fluid with yielding stress ; and the rheological property of low-cement gunning mix bonded by microsilica is proved to be better than that of gunning mix bonded by cement. Meanwhile as indicated by the adhesive tests: the better the rheological properties of gunning mix suspension , the better the repair effect would be.
文摘The paper describes the recent developing situation and the latest research achievements of refractory for hot metal pretreatment. The relationship among desiliconization, dephosphorization and desulphurization techniques and the main corrosion reactions by various treating agents is analyzed. Some improving measures for several problems in practice are put forward while we anticipate the future developing direction of refractory for hot metal pretreatment.
文摘In this paper, a strong limit theorem on gambling strategy for binary Bernoulli sequence, (i.e.) irregularity theorem, is extended to random selection for dependent m-valued random variables, via using a new method-differentiability on net. Furthermore, by allowing the selection function to take value in finite interval [-M,M], the conception of random selection is generalized.
