We investigated the structural and magnetic properties of Sm（Co0.7Fe0.1Ni0.12Zr0.04B0.04）7.5 melt spun ribbons. Samples were arc melted then melt spun at 37 m/s up to 55 m/s to obtain ribbon for powdering. Annealing...We investigated the structural and magnetic properties of Sm（Co0.7Fe0.1Ni0.12Zr0.04B0.04）7.5 melt spun ribbons. Samples were arc melted then melt spun at 37 m/s up to 55 m/s to obtain ribbon for powdering. Annealing was performed in argon atmosphere for 30- 75 min at 600-870 oC. In as-spun ribbons the hexagonal SmCo7 （TbCu7-type of structure） of crystal structure was determined from x-ray diffraction patterns, while fcc-Co has been identified as a secondary phase. After annealing, the 1：7 phase of the as-spun ribbons transformed into 2：17 and 1：5 phases. X-ray patterns for as-milled powders exhibited very broad peaks making it difficult to identify a precise structure but repre-sented the 1：7 structure after annealing at low temperature （650 oC）. TEM analysis showed a homogeneous nanocrystalline microstructure with average grain size of 30-80 nm. Coercivity values of 15-27 kOe were obtained from hysteresis loops traced up to a field of 5 T. The co-ercivity decreased as temperature increases, but it maintained values higher than 5 kOe at 380 oC. The maximum energy product at room temperature increased, as high as 7.2 MGOe, for melt-spun isotropic ribbons produced at higher wheel speeds. Anisotropic ribbons had a maximum energy product close to 12 MGOe.展开更多
Whether the platinum group elements (PGE) can be taken as the indicators of extraterrestrial materials is a very important and interesting scientific problem. It is discussed on the basis of systematic investigation a...Whether the platinum group elements (PGE) can be taken as the indicators of extraterrestrial materials is a very important and interesting scientific problem. It is discussed on the basis of systematic investigation and study of a great amount of related literature. The following conclusions can be obtained: (ⅰ) extraterrestrial impact event can cause the PGE anomaly; conversely, the PGE anomaly may not represent the existence of extraterrestrial impact event, because the PGE anomaly can be caused by many terrestrial events (e.g. volcanic activity); (ⅱ) the PGE anomaly, especially the global PGE anomaly can inspire us to think it from extraterrestrial event, but it may not be as useful as previously thought as unambiguous identifiers of large extraterrestrial impact event in the earth’s history.展开更多
基金Project supported by HITEMAG European project (G5RD-CT-2000-002B)DARPA Metamaterials program (ADA458377)
文摘We investigated the structural and magnetic properties of Sm（Co0.7Fe0.1Ni0.12Zr0.04B0.04）7.5 melt spun ribbons. Samples were arc melted then melt spun at 37 m/s up to 55 m/s to obtain ribbon for powdering. Annealing was performed in argon atmosphere for 30- 75 min at 600-870 oC. In as-spun ribbons the hexagonal SmCo7 （TbCu7-type of structure） of crystal structure was determined from x-ray diffraction patterns, while fcc-Co has been identified as a secondary phase. After annealing, the 1：7 phase of the as-spun ribbons transformed into 2：17 and 1：5 phases. X-ray patterns for as-milled powders exhibited very broad peaks making it difficult to identify a precise structure but repre-sented the 1：7 structure after annealing at low temperature （650 oC）. TEM analysis showed a homogeneous nanocrystalline microstructure with average grain size of 30-80 nm. Coercivity values of 15-27 kOe were obtained from hysteresis loops traced up to a field of 5 T. The co-ercivity decreased as temperature increases, but it maintained values higher than 5 kOe at 380 oC. The maximum energy product at room temperature increased, as high as 7.2 MGOe, for melt-spun isotropic ribbons produced at higher wheel speeds. Anisotropic ribbons had a maximum energy product close to 12 MGOe.
文摘Whether the platinum group elements (PGE) can be taken as the indicators of extraterrestrial materials is a very important and interesting scientific problem. It is discussed on the basis of systematic investigation and study of a great amount of related literature. The following conclusions can be obtained: (ⅰ) extraterrestrial impact event can cause the PGE anomaly; conversely, the PGE anomaly may not represent the existence of extraterrestrial impact event, because the PGE anomaly can be caused by many terrestrial events (e.g. volcanic activity); (ⅱ) the PGE anomaly, especially the global PGE anomaly can inspire us to think it from extraterrestrial event, but it may not be as useful as previously thought as unambiguous identifiers of large extraterrestrial impact event in the earth’s history.
