Tunable mid-infrared and far-infrared laser output was demonstrated based on BaGa_(4)Se_(7)crystals and an optical parametric oscillator(OPO).With a 1.06μm Nd:YAG laser and a double-pass singly resonant OPO cavity,a ...Tunable mid-infrared and far-infrared laser output was demonstrated based on BaGa_(4)Se_(7)crystals and an optical parametric oscillator(OPO).With a 1.06μm Nd:YAG laser and a double-pass singly resonant OPO cavity,a laser energy output of 2.2 mJ at 10μm was obtained.By tuning the angle and temperature,a tunable laser output covering the wavelength range from 6μm to 17μm was obtained with a tuning precision better than 3 nm.The corresponding optical-to-optical conversion efficiency was 2.8%,and the slope efficiency was 4.4%.The damage effect of the output laser on detectors was also investigated,and point damage to the detector occurred at an output energy of 16.4μJ.The laser system has the advantages of miniaturization,a wide tuning range,high energy and high tuning resolution.Its broadband laser characteristics make it highly valuable for applications in atmospheric detection,infrared spectroscopy and electro-optical countermeasures.展开更多
Accurate and comprehensive knowledge of the atmospheric environment and its evolution within the coastal ocean boundary layer are necessary for understanding the sources,chemical mechanisms,and transport processes of ...Accurate and comprehensive knowledge of the atmospheric environment and its evolution within the coastal ocean boundary layer are necessary for understanding the sources,chemical mechanisms,and transport processes of air pollution in land,sea,and atmosphere.We present an overview of coastal ocean boundary layer detection technology and equipment in China and summarize the progress and main achievements in recent years.China has developed a series of coastal ocean boundary layer detection technologies,including Light Detection and Ranging(LIDAR),turbulent exchange analyzer,air-sea flux analyzer,stereoscopic remote sensing of air pollutants,and oceanic aerosol detection equipment to address the technical bottleneck caused by harsh environmental conditions in coastal ocean regions.Advances in these technologies and equipment have provided scientific assistance for addressing air pollution issues and understanding land-sea-atmosphere interactions over coastal ocean regions in China.In the future,routine atmospheric observations should cover the coastal ocean boundary layer of China.展开更多
Urban tree species provide various essential ecosystem services in cities,such as regulating urban temperatures,reducing noise,capturing carbon,and mitigating the urban heat island effect.The quality of these services...Urban tree species provide various essential ecosystem services in cities,such as regulating urban temperatures,reducing noise,capturing carbon,and mitigating the urban heat island effect.The quality of these services is influenced by species diversity,tree health,and the distribution and the composition of trees.Traditionally,data on urban trees has been collected through field surveys and manual interpretation of remote sensing images.In this study,we evaluated the effectiveness of multispectral airborne laser scanning(ALS)data in classifying 24 common urban roadside tree species in Espoo,Finland.Tree crown structure information,intensity features,and spectral data were used for classification.Eight different machine learning algorithms were tested,with the extra trees(ET)algorithm performing the best,achieving an overall accuracy of 71.7%using multispectral LiDAR data.This result highlights that integrating structural and spectral information within a single framework can improve the classification accuracy.Future research will focus on identifying the most important features for species classification and developing algorithms with greater efficiency and accuracy.展开更多
Cooperative guidance is a method for achieving combat objectives through information sharing and cooperative effects,and has emerged as a significant research area in the fields of missile guidance and systematic warf...Cooperative guidance is a method for achieving combat objectives through information sharing and cooperative effects,and has emerged as a significant research area in the fields of missile guidance and systematic warfare.This study presents a systematic review and analysis of current research on cooperative guidance.First,a bibliometric analysis is conducted on 513 articles using the Scopus database and CiteSpace software to assess keyword clustering,keyword cooccurrence,and keyword burst,and to later visualize the results.Second,fundamental theories of cooperative guidance,including relative motion modeling methods,algebraic graph theory,and multi-agent consensus theory,are summarized.Subsequently,an overview of current cooperative laws and corresponding analysis methods is provided,with categorization based on the cooperative structure and convergence performance.Finally,we summarize current research developments based on five perspectives and propose a developmental framework based on five layers(cyber,physical,decision,information,and system),discussing potential future advancements in cooperative terminal guidance.This framework emphasizes five key areas of research:networked,heterogeneous,integrated,intelligent,and group cooperations,with the goal of offering trends and insights for futurework.展开更多
A temperature and acoustic impedance simultaneous sensor based on forward stimulated Brillouin scattering(FSBS)in highly nonlinear fiber(HNLF)with high sensitivity and high accuracy is proposed and demonstrated in thi...A temperature and acoustic impedance simultaneous sensor based on forward stimulated Brillouin scattering(FSBS)in highly nonlinear fiber(HNLF)with high sensitivity and high accuracy is proposed and demonstrated in this paper.High-order acoustic modes(HOAMs)are used to achieve individual or simultaneous measurement of the two parameters.Transverse acoustic waves(TAWs)involved in the FSBS process can efficiently sense the mechanical or environmental changes outside the fiber cladding,which will be reflected in a linear shift of the acoustic resonance frequency.By analyzing the frequencies of specific scattering peaks,the temperature and acoustic impedance outside the fiber cladding can be obtained simultaneously.The highest measured temperature and acoustic impedance sensitivities are 184.93 k Hz/℃and444.56 k Hz/MRayl,and the measurement accuracies are 0.09℃and 0.009 MRayl,respectively,which are both at desirable levels.We believe this work can provide potential application solutions for sensing fields involving temperature or acoustic impedance measurements.展开更多
Recent theoretical verification of self-similar and dissipative pure-quartic solitons(PQSs)emphasized the similarity between PQS lasers and conventional fiber lasers,but the unique equilibrium mechanism hinders the fo...Recent theoretical verification of self-similar and dissipative pure-quartic solitons(PQSs)emphasized the similarity between PQS lasers and conventional fiber lasers,but the unique equilibrium mechanism hinders the formation of PQS molecules in normal fourth-order dispersion(FOD)regimes.In this paper,we investigated the effect of filters on shaping PQSs in normal FOD based on a passively mode-locked fiber laser model.A bandpass filter eliminates the time pedestal of dissipative PQSs,thus realizing a multi-pulsing state.When the filter bandwidth is appropriate,the effective spectral filtering effect can lower the pulse splitting threshold and enable the coherent restoration from chaotic PQSs to PQS molecules.Additionally,changing the central wavelength of the filter can generate PQSs and PQS molecules with asymmetric intensity distributions.These results are important guides for the manipulation of PQSs and the construction of high repetition-frequency fiber lasers.展开更多
We demonstrate the growth,thermal,spectroscopy and laser performance of an Er3+doped Gdo.iYo.9AlO3(Er:GYAP)disorder crystal grown by Czochralski method.The crystal with space group Pbnm and lattice parameters of a=0.5...We demonstrate the growth,thermal,spectroscopy and laser performance of an Er3+doped Gdo.iYo.9AlO3(Er:GYAP)disorder crystal grown by Czochralski method.The crystal with space group Pbnm and lattice parameters of a=0.5185 nm,b=0.5327 nm,c=0.7378 nm,α=β=90°and V=0.203784 nm3 are obtained by fitting powder X-ray diffraction data.The Mohr's hardnesses along three axes are 6.94,7.27,and 7.44.The thermal expansion coefficient of b axis is 4.20×10^(-6)k^(-1)and the density is 5.88 g/cm3.The thermal conductivities are characterized as K_(a)=6.24,K_(b)=5.57,and K_(c)=6.83 W/(m·K).Meanwhile,the refractive index,absorption and emission spectra in triaxial di-rections are determined.Besides,level lifetimes of 4l11/2 and 413/2 are 0.86 and 2.83 ms.Finally,the~2.7μm multiwavelength laser outputs are observed with maximum average power of 628 mW and beam quality factors M_(x)^(2)/M_(y)^(2) of 1.42/1.45.The results prove that the Er:GYAP crystal is a promising gain medium for generating mid-infrared lasers.展开更多
The melting process of ice crystal particles has a significant effect on weather forecasting and global climate.Millimeter waveband is an excellent frequency range for exploring the optical characteristics of ice crys...The melting process of ice crystal particles has a significant effect on weather forecasting and global climate.Millimeter waveband is an excellent frequency range for exploring the optical characteristics of ice crystal particles.In this study,a new nonspherical and inhomogeneous ice crystal particle model is built based on the melting process of ice crystal particles.The single-scattering characteristics of ice crystal particles with different frequencies,sizes,shapes and ice crystal content(ICC)are investigated using the discrete dipole approximation(DDA)method.The results show that the single-scattering characteristics of ice crystal particles are closely related to the equivalent radius,frequency,morphology and mixing state.The single-scattering properties of the particles change regularly with the melting process of the ice crystal particles.Specifically,in the early stage of the ice crystal particle melting process,the single-scattering characteristics of ice crystal particles change significantly.With further melting,the change in the single-scattering characteristics of ice crystal particles gradually slows down when the ICC is less than 0.5.The results also show that in the early stage of the melting process,the shape of the ice crystal particles has a huge influence on the single-scattering characteristics of the particles,and in the late stage of the melting process,the single-scattering characteristics of the ice crystal particles are basically independent of the morphology of the ice crystal nuclei.This means that the influence of the morphology of the ice crystal nuclei needs to be considered in phases when simulating the scattering characteristics of the melting ice crystal particles.In summary,the results of this study should improve our understanding of the effect of size parameter,morphology and mixing state on the millimeter-wave scattering characteristics of ice clouds during the melting process and provide a reference for the remote sensing inversion of ice cloud microphysical characteristics.展开更多
We demonstrate few-cycle pulse generation based on double-stage all-fiber nonlinear pulse compression from a thulium-doped fiber laser at a repetition rate of∼199.74 MHz.The homemade laser provides an average power o...We demonstrate few-cycle pulse generation based on double-stage all-fiber nonlinear pulse compression from a thulium-doped fiber laser at a repetition rate of∼199.74 MHz.The homemade laser provides an average power of 130 mW,serving as the seed for subsequent amplification.After amplification,significant spectral broadening to an octave-spanning bandwidth(1.2 to 2.4μm)is attained through self-phase modulation-dominated nonlinear effects in an ultrahigh numerical aperture fiber and a highly nonlinear fiber.Followed by a two-stage nonlinear compressor,the system directly delivers near transform-limited pulses with a pulse duration of 19.8 fs(2.9 cycles at a central wavelength of 2000 nm)and a pulse energy of 3.37 nJ.To the best of our knowledge,this result is the shortest pulse duration directly generated from a thulium-doped fiber laser.This robust and simplified all-fiber system provides a promising route toward practical mid-infrared frequency comb generation and mid-infrared spectroscopy.展开更多
Esterification of acrylic acid（AA） to produce AA esters has widespread application in the chemical industry. A series of water tolerant solid acid catalysts was prepared, and characterized by XRD, nitrogen adsorptio...Esterification of acrylic acid（AA） to produce AA esters has widespread application in the chemical industry. A series of water tolerant solid acid catalysts was prepared, and characterized by XRD, nitrogen adsorption, TGA-DTA, XPS, and ammonia adsorption FTIR. The effects of Si/Al ratio, zirconium sulfate（ZS） loading on HZSM-5 and calcination temperature on the esterification were investigated. When 20% （mass fraction） ZS is loaded on HZSM-5, the conversion of AA reaches 100%. XRD analysis indicates that ZS is highly dispersed on HZSM-5 because no crystalline structure assigned to ZS is found. Catalytic activity and hydrophobicity of ZS supported on HZSM-5 are higher compared with those of parent ZS or HZSM-5. Results show that this kind of novel catalysts is an efficient water tolerant solid acid catalyst for esterification reactions.展开更多
This paper investigates a simplified model for describing the gravitational fields of non- axisymmetric elongated asteroids. The connection between the simplified model and the target aster-oid is built by considering...This paper investigates a simplified model for describing the gravitational fields of non- axisymmetric elongated asteroids. The connection between the simplified model and the target aster-oid is built by considering the positions of equilibrium points. To improve the performance of po-sition matching for the equilibrium points associated with these non-axisymmetric asteroids, a non-axisymmetric triple-particle-linkage model is proposed based on two existing axisymmetric particle- linkage models. The unknown parameters of the simplified model are determined by minimizing the matching error using the nonlinear optimization method. The proposed simplified model is applied for three realistic elongated asteroids, 243 Ida, 433 Eros and （8567） 1996 HW1. The simulation re-sults verify that the current particle-linkage model has better matching accuracy than the two existing particle-linkage models. The comparison, between the simplified model and the polyhedral model, on the topological cases of the equilibrium points and the distribution of gravitational potential further validate the rationality and accuracy of the simplified model.展开更多
In this work,a series of self-activated KYb(MoO_(4))_(2) phosphors with various x at% Er^(3+) doping concentrations(x=0.5,1,3,5,8,10,15) was synthesized by the solid-state reaction method.The phase structure of the as...In this work,a series of self-activated KYb(MoO_(4))_(2) phosphors with various x at% Er^(3+) doping concentrations(x=0.5,1,3,5,8,10,15) was synthesized by the solid-state reaction method.The phase structure of the as-prepared samples was analyzed by X-ray diffraction(XRD),XRD Rietveld refinement and Fourier transform infrared(FT-IR) spectroscopy.The as-prepared samples retain the orthorhombic structure with space group of Pbcn even Er^(3+) doping concentration up to 15 at%.High-purity upconversion(UC) green emission with green to red intensity ratio of 55 is observed from the as-prepared samples upon the excitation of 980 nm semiconductor laser and the optimum doping concentration of Er^(3+) ions in the self-activated KYb(MoO_(4))_(2) host is revealed as 3 at%.The strong green UC emission is confirmed as a two-photon process based on the power-dependent UC spectra.In addition,the fluorescence intensity ratios(FIRs) of the two thermally-coupled energy levels,namely ^(2)H_(11/2) and ^(4)S_(3/2).of Er^(3+) ions were investigated in the temperature region 300-570 K to evaluate the optical temperature sensor behavior of the sample.The maximum relative sensitivity(S_(R)) is determined to be 0.0069 K^(-1) at300 K and the absolute sensitivity(S_(A)) is determined to be 0.0126 K^(-1) at 300 K.The S_(A) of self-activated KYb(MoO_(4))2:Er^(3+)is almost twice that of traditional KY(MoO_(4))2:Er^(3+)/Yb^(3+)codoping phosphor.The results demonstrate that Er^(3+) ions doped self-activated KYb(MoO_(4))2 phosphor has promising application in visible display,trademark security and optical temperature sensors.展开更多
Continuous-wave cavity ring-down spectroscopy(CW-CRDS)is an important technical means to monitor greenhouse gases in atmospheric environment.In this paper,a CW-CRDS system is built to meet the needs of atmospheric met...Continuous-wave cavity ring-down spectroscopy(CW-CRDS)is an important technical means to monitor greenhouse gases in atmospheric environment.In this paper,a CW-CRDS system is built to meet the needs of atmospheric methane monitoring.The problem of mode matching is explained from the perspective of transverse mode and longitudinal mode,and the influence of laser injection efficiency on measurement precision is further analyzed.The results of cavity ring-down time measurement show that the measurement precision is higher when the laser is coupled with the fundamental mode.In the experiment,DFB laser is used to calibrate the system with standard methane concentration,and the measurement residual is less than±4×10^(-4)μs^(-1).The methane concentration in the air is monitored in real time for two days.The results show the consistency of the concentration changes over the two days,which further demonstrates the reliability of the system for the measurement of trace methane.By analyzing the influence of mode matching,it not only assists the adjustment of the optical path,but also further improves the sensitivity of the system measurement.展开更多
The increased capacity and availability of the Intemet has led to a wide variety of applications. Intemet traffic characterization and application identification is important for network management. In this paper, bas...The increased capacity and availability of the Intemet has led to a wide variety of applications. Intemet traffic characterization and application identification is important for network management. In this paper, based on detailed flow data collected from the public networks of Intemet Service Providers, we construct a flow graph to model the interactions among users. Considering traffic from different applications, we analyze the community structure of the flow graph in terms of cormmunity size, degree distribution of the community, community overlap, and overlap modularity. The near linear time community detection algorithm in complex networks, the Label Propagation Algorithm （LPA）, is extended to the flow graph for application identification. We propose a new initialization and label propagation and update scheme. Experimental results show that the proposed algorithm has high accuracy and efficiency.展开更多
In this work,p-type Co3O4 decorated n-type ZnO(Co3O4/ZnO)nanocomposite was designed with the assistance of bacterial cellulose template.Phase composition,morphology and element distribution were investigated by XRD,SE...In this work,p-type Co3O4 decorated n-type ZnO(Co3O4/ZnO)nanocomposite was designed with the assistance of bacterial cellulose template.Phase composition,morphology and element distribution were investigated by XRD,SEM,HRTEM,EDS mapping and XPS.Volatile organic compounds(VOCs)sensing measurements indicated a noticeable improvement of response and decrease of working temperature for Co3O4/ZnO sensor,in comparison with pure ZnO,i.e.,the response towards 100 ppm acetone was 63.7(at a low working temperature of 180℃),which was 26 times higher than pure ZnO(response of 2.3 at 240℃).Excellent VOCs response characteristics could be ascribed to increased surface oxygen vacancy concentration(revealed by defect characterizations),catalytic activity of Co3O4 and the special p-n heterojunction structure,and bacterial cellulose provides a facile template for designing diverse functional heterojunctions for VOCs detection and other applications.展开更多
A good quality(5 at.%Yb:GdScO_(3))single crystal of F30 mm37 mm was grown successfully by the Czochralski method.Its structure is studied by the x-ray diffraction(XRD),and its atomic coordinates are obtained by Rietve...A good quality(5 at.%Yb:GdScO_(3))single crystal of F30 mm37 mm was grown successfully by the Czochralski method.Its structure is studied by the x-ray diffraction(XRD),and its atomic coordinates are obtained by Rietveld refinement.The crystal field energy level splitting of Yb^(3+)in GdScO_(3) is determined by employing the absorption and photoluminescence spectra at 8 K.Only ^(2)F_(7/2)(4)is far from the ground state ^(2)F_(7/2)(1)by 710 cm^(-1) among the crystal field energy levels split from ^(2)F_(7/2),so it is more easier to realize the laser operation of ^(2)F_(5/2)(1)^(2)F_(7/2)(4)with wavelength 1060 nm.The spin–orbit coupling parameters and intrinsic crystal field parameters(CFPs).The intrinsic crystal field parameters¯B k(k=2,4,6)of the crystal were fitted by the superposition model.The CFPs evaluated with¯Bk and coordination factor are taken as the initial parameters to fit the crystal field energy levels of the crystal,and the crystal field parameters B_(q)^(k) are obtained finally with the root-mean-square deviation 9 cm-1.It is suggested that the ligand point charge,covalency and overlap interaction are slightly weaker than charge interpenetration and coulomb exchange interaction for Yb^(3+)in GdScO_(3).The obtained Hamiltonian parameters can be used to calculate crystal field energy levels and wave functions of Yb:GdScO_(3) to analyze the mechanism of the luminescence or laser.展开更多
基金supported by Independent Innovation Science Foundation of National University of Defense Technology(Grant No.23-ZZCX-JDZ-44)。
文摘Tunable mid-infrared and far-infrared laser output was demonstrated based on BaGa_(4)Se_(7)crystals and an optical parametric oscillator(OPO).With a 1.06μm Nd:YAG laser and a double-pass singly resonant OPO cavity,a laser energy output of 2.2 mJ at 10μm was obtained.By tuning the angle and temperature,a tunable laser output covering the wavelength range from 6μm to 17μm was obtained with a tuning precision better than 3 nm.The corresponding optical-to-optical conversion efficiency was 2.8%,and the slope efficiency was 4.4%.The damage effect of the output laser on detectors was also investigated,and point damage to the detector occurred at an output energy of 16.4μJ.The laser system has the advantages of miniaturization,a wide tuning range,high energy and high tuning resolution.Its broadband laser characteristics make it highly valuable for applications in atmospheric detection,infrared spectroscopy and electro-optical countermeasures.
基金supported by the National Key Research and Development Program of China(Nos.2018YFC0213106,2018YFC0213101,2018YFC0213102,2018YFC0213103,2018YFC0213104 and 2018YFC0213105)Anhui Provincial Natural Science Foundation(No.2108085QD177)the CASHIPS Director’s Fund(No.YZJJ2021QN07)。
文摘Accurate and comprehensive knowledge of the atmospheric environment and its evolution within the coastal ocean boundary layer are necessary for understanding the sources,chemical mechanisms,and transport processes of air pollution in land,sea,and atmosphere.We present an overview of coastal ocean boundary layer detection technology and equipment in China and summarize the progress and main achievements in recent years.China has developed a series of coastal ocean boundary layer detection technologies,including Light Detection and Ranging(LIDAR),turbulent exchange analyzer,air-sea flux analyzer,stereoscopic remote sensing of air pollutants,and oceanic aerosol detection equipment to address the technical bottleneck caused by harsh environmental conditions in coastal ocean regions.Advances in these technologies and equipment have provided scientific assistance for addressing air pollution issues and understanding land-sea-atmosphere interactions over coastal ocean regions in China.In the future,routine atmospheric observations should cover the coastal ocean boundary layer of China.
文摘Urban tree species provide various essential ecosystem services in cities,such as regulating urban temperatures,reducing noise,capturing carbon,and mitigating the urban heat island effect.The quality of these services is influenced by species diversity,tree health,and the distribution and the composition of trees.Traditionally,data on urban trees has been collected through field surveys and manual interpretation of remote sensing images.In this study,we evaluated the effectiveness of multispectral airborne laser scanning(ALS)data in classifying 24 common urban roadside tree species in Espoo,Finland.Tree crown structure information,intensity features,and spectral data were used for classification.Eight different machine learning algorithms were tested,with the extra trees(ET)algorithm performing the best,achieving an overall accuracy of 71.7%using multispectral LiDAR data.This result highlights that integrating structural and spectral information within a single framework can improve the classification accuracy.Future research will focus on identifying the most important features for species classification and developing algorithms with greater efficiency and accuracy.
基金supported by the National Natural Science Foundation of China(No.62173274)the National Key R&D Program of China(No.2019YFA0405300)+4 种基金the Natural Science Foundation of Hunan Province of China(Nos.2021JJ10045 and 2025JJ60072)the Open Research Subject of State Key Laboratory of Intelligent Game(No.ZBKF-24-01)the Postdoctoral Fellowship Program of CPSF(No.GZB20240989)the China Postdoctoral Science Foundation(No.2024M754304)the Aeronautical Science Foundation of China(No.2023Z005030001).
文摘Cooperative guidance is a method for achieving combat objectives through information sharing and cooperative effects,and has emerged as a significant research area in the fields of missile guidance and systematic warfare.This study presents a systematic review and analysis of current research on cooperative guidance.First,a bibliometric analysis is conducted on 513 articles using the Scopus database and CiteSpace software to assess keyword clustering,keyword cooccurrence,and keyword burst,and to later visualize the results.Second,fundamental theories of cooperative guidance,including relative motion modeling methods,algebraic graph theory,and multi-agent consensus theory,are summarized.Subsequently,an overview of current cooperative laws and corresponding analysis methods is provided,with categorization based on the cooperative structure and convergence performance.Finally,we summarize current research developments based on five perspectives and propose a developmental framework based on five layers(cyber,physical,decision,information,and system),discussing potential future advancements in cooperative terminal guidance.This framework emphasizes five key areas of research:networked,heterogeneous,integrated,intelligent,and group cooperations,with the goal of offering trends and insights for futurework.
文摘A temperature and acoustic impedance simultaneous sensor based on forward stimulated Brillouin scattering(FSBS)in highly nonlinear fiber(HNLF)with high sensitivity and high accuracy is proposed and demonstrated in this paper.High-order acoustic modes(HOAMs)are used to achieve individual or simultaneous measurement of the two parameters.Transverse acoustic waves(TAWs)involved in the FSBS process can efficiently sense the mechanical or environmental changes outside the fiber cladding,which will be reflected in a linear shift of the acoustic resonance frequency.By analyzing the frequencies of specific scattering peaks,the temperature and acoustic impedance outside the fiber cladding can be obtained simultaneously.The highest measured temperature and acoustic impedance sensitivities are 184.93 k Hz/℃and444.56 k Hz/MRayl,and the measurement accuracies are 0.09℃and 0.009 MRayl,respectively,which are both at desirable levels.We believe this work can provide potential application solutions for sensing fields involving temperature or acoustic impedance measurements.
基金Project supported by the National Natural Science Foundation of China(Grant No.62175116)。
文摘Recent theoretical verification of self-similar and dissipative pure-quartic solitons(PQSs)emphasized the similarity between PQS lasers and conventional fiber lasers,but the unique equilibrium mechanism hinders the formation of PQS molecules in normal fourth-order dispersion(FOD)regimes.In this paper,we investigated the effect of filters on shaping PQSs in normal FOD based on a passively mode-locked fiber laser model.A bandpass filter eliminates the time pedestal of dissipative PQSs,thus realizing a multi-pulsing state.When the filter bandwidth is appropriate,the effective spectral filtering effect can lower the pulse splitting threshold and enable the coherent restoration from chaotic PQSs to PQS molecules.Additionally,changing the central wavelength of the filter can generate PQSs and PQS molecules with asymmetric intensity distributions.These results are important guides for the manipulation of PQSs and the construction of high repetition-frequency fiber lasers.
基金the National Natural Science Foundation of China(52102012)Natural Science Foundation of Anhui Province(2208085QF217)the Fundamental Research Funds for the Central Universities(WK5290000004)。
文摘We demonstrate the growth,thermal,spectroscopy and laser performance of an Er3+doped Gdo.iYo.9AlO3(Er:GYAP)disorder crystal grown by Czochralski method.The crystal with space group Pbnm and lattice parameters of a=0.5185 nm,b=0.5327 nm,c=0.7378 nm,α=β=90°and V=0.203784 nm3 are obtained by fitting powder X-ray diffraction data.The Mohr's hardnesses along three axes are 6.94,7.27,and 7.44.The thermal expansion coefficient of b axis is 4.20×10^(-6)k^(-1)and the density is 5.88 g/cm3.The thermal conductivities are characterized as K_(a)=6.24,K_(b)=5.57,and K_(c)=6.83 W/(m·K).Meanwhile,the refractive index,absorption and emission spectra in triaxial di-rections are determined.Besides,level lifetimes of 4l11/2 and 413/2 are 0.86 and 2.83 ms.Finally,the~2.7μm multiwavelength laser outputs are observed with maximum average power of 628 mW and beam quality factors M_(x)^(2)/M_(y)^(2) of 1.42/1.45.The results prove that the Er:GYAP crystal is a promising gain medium for generating mid-infrared lasers.
基金supported by the National Key Research and Development Program of China(Grant No.2019YFA0706004)the Key Projects of Science and Technology Research of Henan Province(Grant No.222102320087)the Key Scientific Research Project of Colleges and Universities in Henan Province(Grant No.25B170004).
文摘The melting process of ice crystal particles has a significant effect on weather forecasting and global climate.Millimeter waveband is an excellent frequency range for exploring the optical characteristics of ice crystal particles.In this study,a new nonspherical and inhomogeneous ice crystal particle model is built based on the melting process of ice crystal particles.The single-scattering characteristics of ice crystal particles with different frequencies,sizes,shapes and ice crystal content(ICC)are investigated using the discrete dipole approximation(DDA)method.The results show that the single-scattering characteristics of ice crystal particles are closely related to the equivalent radius,frequency,morphology and mixing state.The single-scattering properties of the particles change regularly with the melting process of the ice crystal particles.Specifically,in the early stage of the ice crystal particle melting process,the single-scattering characteristics of ice crystal particles change significantly.With further melting,the change in the single-scattering characteristics of ice crystal particles gradually slows down when the ICC is less than 0.5.The results also show that in the early stage of the melting process,the shape of the ice crystal particles has a huge influence on the single-scattering characteristics of the particles,and in the late stage of the melting process,the single-scattering characteristics of the ice crystal particles are basically independent of the morphology of the ice crystal nuclei.This means that the influence of the morphology of the ice crystal nuclei needs to be considered in phases when simulating the scattering characteristics of the melting ice crystal particles.In summary,the results of this study should improve our understanding of the effect of size parameter,morphology and mixing state on the millimeter-wave scattering characteristics of ice clouds during the melting process and provide a reference for the remote sensing inversion of ice cloud microphysical characteristics.
基金supported by the National Natural Science Foundation of China(Grant Nos.62227821 and 42461050)the Key Project of the National Institute of Metrology,China(Grant Nos.AKYZD2411 and AKYZD2511-2).
文摘We demonstrate few-cycle pulse generation based on double-stage all-fiber nonlinear pulse compression from a thulium-doped fiber laser at a repetition rate of∼199.74 MHz.The homemade laser provides an average power of 130 mW,serving as the seed for subsequent amplification.After amplification,significant spectral broadening to an octave-spanning bandwidth(1.2 to 2.4μm)is attained through self-phase modulation-dominated nonlinear effects in an ultrahigh numerical aperture fiber and a highly nonlinear fiber.Followed by a two-stage nonlinear compressor,the system directly delivers near transform-limited pulses with a pulse duration of 19.8 fs(2.9 cycles at a central wavelength of 2000 nm)and a pulse energy of 3.37 nJ.To the best of our knowledge,this result is the shortest pulse duration directly generated from a thulium-doped fiber laser.This robust and simplified all-fiber system provides a promising route toward practical mid-infrared frequency comb generation and mid-infrared spectroscopy.
基金Supported by the Research Fund for the Doctoral Program of Higher Education(No20050010014)the China Petroleum &Chemical Corporation ( No X503015 )the Key Discipline Construction Foundation of Beijing Education Committee ( NoXK100100643)
文摘Esterification of acrylic acid（AA） to produce AA esters has widespread application in the chemical industry. A series of water tolerant solid acid catalysts was prepared, and characterized by XRD, nitrogen adsorption, TGA-DTA, XPS, and ammonia adsorption FTIR. The effects of Si/Al ratio, zirconium sulfate（ZS） loading on HZSM-5 and calcination temperature on the esterification were investigated. When 20% （mass fraction） ZS is loaded on HZSM-5, the conversion of AA reaches 100%. XRD analysis indicates that ZS is highly dispersed on HZSM-5 because no crystalline structure assigned to ZS is found. Catalytic activity and hydrophobicity of ZS supported on HZSM-5 are higher compared with those of parent ZS or HZSM-5. Results show that this kind of novel catalysts is an efficient water tolerant solid acid catalyst for esterification reactions.
基金supported by the National Natural Science Foundation of China (Grant No.11672126)the Innovation Funded Project of Shanghai Aerospace Science and Technology (Grant Nos.SAST2017032 and SAST2015036)the Scientific Research Foundation for New Staffs of Nanjing University of Aeronautics and Astronautics (Grant No.1011-YAH17071)
文摘This paper investigates a simplified model for describing the gravitational fields of non- axisymmetric elongated asteroids. The connection between the simplified model and the target aster-oid is built by considering the positions of equilibrium points. To improve the performance of po-sition matching for the equilibrium points associated with these non-axisymmetric asteroids, a non-axisymmetric triple-particle-linkage model is proposed based on two existing axisymmetric particle- linkage models. The unknown parameters of the simplified model are determined by minimizing the matching error using the nonlinear optimization method. The proposed simplified model is applied for three realistic elongated asteroids, 243 Ida, 433 Eros and （8567） 1996 HW1. The simulation re-sults verify that the current particle-linkage model has better matching accuracy than the two existing particle-linkage models. The comparison, between the simplified model and the polyhedral model, on the topological cases of the equilibrium points and the distribution of gravitational potential further validate the rationality and accuracy of the simplified model.
基金supported by the National Natural Science Foundation of China (52202001)Open Project of Advanced Laser Technology Laboratory of Anhui Province (AHL2021KF07)+1 种基金Major Science and Technology of Anhui Province(202203a05020002)University Natural Science Research Project of Anhui Province (KJ2021A0388)。
文摘In this work,a series of self-activated KYb(MoO_(4))_(2) phosphors with various x at% Er^(3+) doping concentrations(x=0.5,1,3,5,8,10,15) was synthesized by the solid-state reaction method.The phase structure of the as-prepared samples was analyzed by X-ray diffraction(XRD),XRD Rietveld refinement and Fourier transform infrared(FT-IR) spectroscopy.The as-prepared samples retain the orthorhombic structure with space group of Pbcn even Er^(3+) doping concentration up to 15 at%.High-purity upconversion(UC) green emission with green to red intensity ratio of 55 is observed from the as-prepared samples upon the excitation of 980 nm semiconductor laser and the optimum doping concentration of Er^(3+) ions in the self-activated KYb(MoO_(4))_(2) host is revealed as 3 at%.The strong green UC emission is confirmed as a two-photon process based on the power-dependent UC spectra.In addition,the fluorescence intensity ratios(FIRs) of the two thermally-coupled energy levels,namely ^(2)H_(11/2) and ^(4)S_(3/2).of Er^(3+) ions were investigated in the temperature region 300-570 K to evaluate the optical temperature sensor behavior of the sample.The maximum relative sensitivity(S_(R)) is determined to be 0.0069 K^(-1) at300 K and the absolute sensitivity(S_(A)) is determined to be 0.0126 K^(-1) at 300 K.The S_(A) of self-activated KYb(MoO_(4))2:Er^(3+)is almost twice that of traditional KY(MoO_(4))2:Er^(3+)/Yb^(3+)codoping phosphor.The results demonstrate that Er^(3+) ions doped self-activated KYb(MoO_(4))2 phosphor has promising application in visible display,trademark security and optical temperature sensors.
基金This research is financial supported by the Natural National Science Foundation of China(Grant Nos.11874364,41877311,and 42005107)the National Key Research and Development Program of China(Grant No.2017YFC0805004)the CAS&Bengbu Technology Transfer Project(Grant No.ZKBB202102).
文摘Continuous-wave cavity ring-down spectroscopy(CW-CRDS)is an important technical means to monitor greenhouse gases in atmospheric environment.In this paper,a CW-CRDS system is built to meet the needs of atmospheric methane monitoring.The problem of mode matching is explained from the perspective of transverse mode and longitudinal mode,and the influence of laser injection efficiency on measurement precision is further analyzed.The results of cavity ring-down time measurement show that the measurement precision is higher when the laser is coupled with the fundamental mode.In the experiment,DFB laser is used to calibrate the system with standard methane concentration,and the measurement residual is less than±4×10^(-4)μs^(-1).The methane concentration in the air is monitored in real time for two days.The results show the consistency of the concentration changes over the two days,which further demonstrates the reliability of the system for the measurement of trace methane.By analyzing the influence of mode matching,it not only assists the adjustment of the optical path,but also further improves the sensitivity of the system measurement.
基金the National Natural Science Foundation of China under Grant No.61171098，the Fundamental Research Funds for the Central Universities of China，the 111 Project of China under Grant No.B08004
文摘The increased capacity and availability of the Intemet has led to a wide variety of applications. Intemet traffic characterization and application identification is important for network management. In this paper, based on detailed flow data collected from the public networks of Intemet Service Providers, we construct a flow graph to model the interactions among users. Considering traffic from different applications, we analyze the community structure of the flow graph in terms of cormmunity size, degree distribution of the community, community overlap, and overlap modularity. The near linear time community detection algorithm in complex networks, the Label Propagation Algorithm （LPA）, is extended to the flow graph for application identification. We propose a new initialization and label propagation and update scheme. Experimental results show that the proposed algorithm has high accuracy and efficiency.
文摘In this work,p-type Co3O4 decorated n-type ZnO(Co3O4/ZnO)nanocomposite was designed with the assistance of bacterial cellulose template.Phase composition,morphology and element distribution were investigated by XRD,SEM,HRTEM,EDS mapping and XPS.Volatile organic compounds(VOCs)sensing measurements indicated a noticeable improvement of response and decrease of working temperature for Co3O4/ZnO sensor,in comparison with pure ZnO,i.e.,the response towards 100 ppm acetone was 63.7(at a low working temperature of 180℃),which was 26 times higher than pure ZnO(response of 2.3 at 240℃).Excellent VOCs response characteristics could be ascribed to increased surface oxygen vacancy concentration(revealed by defect characterizations),catalytic activity of Co3O4 and the special p-n heterojunction structure,and bacterial cellulose provides a facile template for designing diverse functional heterojunctions for VOCs detection and other applications.
基金supported by the National Key Research and Development Program of China(Grant Nos.2022YFB3605700 and 2023YFB3507403)the National Natural Science Foundation of China(Grant No.52272011)+2 种基金the Youth Innovation Promotion Association of CAS(Grant No.2023463)Plan for Anhui Major Provincial Science&Technology Project(Grant No.202203a05020002)Open Project of Advanced Laser Technology Laboratory of Anhui Province(Grant No.AHL20220ZR04).
文摘A good quality(5 at.%Yb:GdScO_(3))single crystal of F30 mm37 mm was grown successfully by the Czochralski method.Its structure is studied by the x-ray diffraction(XRD),and its atomic coordinates are obtained by Rietveld refinement.The crystal field energy level splitting of Yb^(3+)in GdScO_(3) is determined by employing the absorption and photoluminescence spectra at 8 K.Only ^(2)F_(7/2)(4)is far from the ground state ^(2)F_(7/2)(1)by 710 cm^(-1) among the crystal field energy levels split from ^(2)F_(7/2),so it is more easier to realize the laser operation of ^(2)F_(5/2)(1)^(2)F_(7/2)(4)with wavelength 1060 nm.The spin–orbit coupling parameters and intrinsic crystal field parameters(CFPs).The intrinsic crystal field parameters¯B k(k=2,4,6)of the crystal were fitted by the superposition model.The CFPs evaluated with¯Bk and coordination factor are taken as the initial parameters to fit the crystal field energy levels of the crystal,and the crystal field parameters B_(q)^(k) are obtained finally with the root-mean-square deviation 9 cm-1.It is suggested that the ligand point charge,covalency and overlap interaction are slightly weaker than charge interpenetration and coulomb exchange interaction for Yb^(3+)in GdScO_(3).The obtained Hamiltonian parameters can be used to calculate crystal field energy levels and wave functions of Yb:GdScO_(3) to analyze the mechanism of the luminescence or laser.
