Lithium-ion batteries(LIBs),while dominant in energy storage due to high energy density and cycling stability,suffer from severe capacity decay,rate capability degradation,and lithium dendrite formation under low-temp...Lithium-ion batteries(LIBs),while dominant in energy storage due to high energy density and cycling stability,suffer from severe capacity decay,rate capability degradation,and lithium dendrite formation under low-temperature(LT)operation.Therefore,a more comprehensive and systematic understanding of LIB behavior at LT is urgently required.This review article comprehensively reviews recent advancements in electrolyte engineering strategies aimed at improving the low-temperature operational capabilities of LIBs.The study methodically examines critical performance-limiting mechanisms through fundamental analysis of four primary challenges:insufficient ionic conductivity under cryogenic conditions,kinetically hindered charge transfer processes,Li+transport limitations across the solidelectrolyte interphase(SEI),and uncontrolled lithium dendrite growth.The work elaborates on innovative optimization approaches encompassing lithium salt molecular design with tailored dissociation characteristics,solvent matrix optimization through dielectric constant and viscosity regulation,interfacial engineering additives for constructing low-impedance SEI layers,and gel-polymer composite electrolyte systems.Notably,particular emphasis is placed on emerging machine learning-guided electrolyte formulation strategies that enable high-throughput virtual screening of constituent combinations and prediction of structure-property relationships.These artificial intelligence-assisted rational design frameworks demonstrate significant potential for accelerating the development of next-generation LT electrolytes by establishing quantitative composition-performance correlations through advanced data-driven methodologies.展开更多
The AC/DC hybrid distribution network is one of the trends in distribution network development, which poses great challenges to the traditional distribution transformer. In this paper, a new topology suitable for AC/D...The AC/DC hybrid distribution network is one of the trends in distribution network development, which poses great challenges to the traditional distribution transformer. In this paper, a new topology suitable for AC/DC hybrid distribution network is put forward according to the demands of power grid, with advantages of accepting DG and DC loads, while clearing DC fault by blocking the clamping double sub-module(CDSM) of input stage. Then, this paper shows the typical structure of AC/DC distribution network that is hand in hand. Based on the new topology, this paper designs the control and modulation strategies of each stage, where the outer loop controller of input stage is emphasized for its twocontrol mode. At last, the rationality of new topology and the validity of control strategies are verified by the steady and dynamic state simulation. At the same time, the simulation results highlight the role of PET in energy regulation.展开更多
This paper introduces the implementation and data analysis associated with a state-wide power quality monitoring and analysis system in China. Corporation specifications on power quality monitors as well as on communi...This paper introduces the implementation and data analysis associated with a state-wide power quality monitoring and analysis system in China. Corporation specifications on power quality monitors as well as on communication protocols are formulated for data transmission. Big data platform and related technologies are utilized for data storage and computation. Compliance verification analysis and a power quality performance assessment are conducted, and a visualization tool for result presentation is finally presented.展开更多
Increasing renewable energy targets globally has raised the requirement for the efficient and profitable operation of solar photovoltaic(PV)systems.In light of this requirement,this paper provides a path for evaluatin...Increasing renewable energy targets globally has raised the requirement for the efficient and profitable operation of solar photovoltaic(PV)systems.In light of this requirement,this paper provides a path for evaluating the operating condition and improving the power output of the PV system in a grid integrated environment.To achieve this,different types of faults in grid-connected PV systems(GCPVs)and their impact on the energy loss associated with the electrical network are analyzed.A data-driven approach using neural networks(NNs)is proposed to achieve root cause analysis and localize the fault to the component level in the system.The localized fault condition is combined with a parallel operation of adaptive neurofuzzy inference units(ANFIUs)to develop a power mismatch-based control unit(PMCU)for improving the power output of the GCPV.To develop the proposed framework,a 10-kW single-phase GCPV is simulated for training the NN-based anomaly detection approach with 14 deviation signals.Further,the developed algorithm is combined with the PMCU implemented with the experimental setup of GCPV.The results identified 98.2%training accuracy and 43000 observations/sec prediction speed for the trained classifier,and improved power output with reduced voltage and current harmonics for the grid-connected PV operation.展开更多
Recently,thick haze and poisonous smoke have cloaked the surrounding air in Malaysia due to the uncontrollable and unethical burning of nearby country.This devastating episode of open burning started in the year 1997 ...Recently,thick haze and poisonous smoke have cloaked the surrounding air in Malaysia due to the uncontrollable and unethical burning of nearby country.This devastating episode of open burning started in the year 1997 in Indonesia which deeply affected most of the ASEAN(association of southeast asian nations)countries especially their neighbour Malaysia and Singapore.The PV(photovoltaic)technology as an alternative means of energy generation experiences such significant energy decrease based on this condition which is due to the shading of sunlight.The 6 h claims of good sunlight has become not more than 2 h and gets worst when the API(air pollution index)struck 200 levels which is at very unhealthy condition.This study embraces some findings from 1 kWp PV generator field data installed in Malaysia reflecting the daily energy decrease operated during this unhealthy weather condition.It is found that,such significant energy decrease with the value of 0.43 W power output per increment of one point API.This value shows such concrete proof of additional factors to be considered in PV modelling in line to support PV technology adaptation in the ASEAN region.展开更多
The triple bond in N_(2)has an extremely high bond energy and is thus difficult to break.N_(2)is commonly converted into NH3 artificially via the Haber-Bosch process,and NH_(3)can be utilized to produce other nitrogen...The triple bond in N_(2)has an extremely high bond energy and is thus difficult to break.N_(2)is commonly converted into NH3 artificially via the Haber-Bosch process,and NH_(3)can be utilized to produce other nitrogen-containing chemicals.Here,we developed an electron catalyzed method to directly fix N_(2)into azos,by pushing and pulling the electron into and from the aromatic halide with the cyclic voltammetry method.The round-trip journey of electron can successfully weaken the triple bond in N_(2)through the electron pushing-induced aryl radical via a“brick trowel”transition state,and then produce the diazonium ions by pulling the electron out from the diazo radical intermediate.Different azos can be synthesized with this developed electron catalyzed approach.This approach provides a novel concept and practical route for the fixation of N_(2)at atmospheric pressure into chemical products valuable for industrial and commercial applications.展开更多
Sodium-ion batteries(SIBs)have attracted significant attention in large-scale energy storage system because of their abundant sodium resource and cost-effectiveness.Layered oxide materials are particularly promising a...Sodium-ion batteries(SIBs)have attracted significant attention in large-scale energy storage system because of their abundant sodium resource and cost-effectiveness.Layered oxide materials are particularly promising as SIBs cathodes due to their high theoretical capacities and facile synthesis.However,their practical applications are hindered by the limitations in energy density and cycling stability.The comprehensive understanding of failure mechanisms within bulk structure and at the cathode/electrolyte interface of cathodes is still lacking.In this review,the issues related to bulk phase degradation and surface degradation,such as irreversible phase transitions,cation migration,transition metal dissolution,air/moisture instability,intergranular cracking,interfacial reactions,and reactive oxygen loss,are discussed.The latest advances and strategies to improve the stability of layered oxide cathodes and full cells are provided,as well as our perspectives on the future development of SIBs.展开更多
The weak adsorption energy of oxygen-containing intermediates on Co center leads to a considerable performance dis-parity between Co-N-C and costly Pt benchmark in catalyzing oxygen reduction reaction(ORR).In this wor...The weak adsorption energy of oxygen-containing intermediates on Co center leads to a considerable performance dis-parity between Co-N-C and costly Pt benchmark in catalyzing oxygen reduction reaction(ORR).In this work,we strategi-cally engineer the active site structure of Co-N-C via B substitution,which is accomplished by the pyrolysis of ammonium borate.During this process,the in-situ generated NH_(3)gas plays a critical role in creating surface defects and boron atoms substituting nitrogen atoms in the carbon structure.The well-designed CoB_(1)N_(3)active site endows Co with higher charge density and stronger adsorption energy toward oxygen species,potentially accelerating ORR kinetics.As expected,the resulting Co-B/N-C catalyst exhibited superior ORR performance over Co-N-C counterpart,with 40 mV,and fivefold en-hancement in half-wave potential and turnover frequency(TOF).More importantly,the excellent ORR performance could be translated into membrane electrode assembly(MEA)in a fuel cell test,delivering an impressive peak power density of 824 mW·cm^(-2),which is currently the best among Co-based catalysts under the same conditions.This work not only demon-strates an effective method for designing advanced catalysts,but also affords a highly promising non-precious metal ORR electrocatalyst for fuel cell applications.展开更多
The unavailability of high-performance and cost-effective electrocatalysts has impeded the large-scale deployment of alkaline water electrolyzers.Professor Zidong Wei's group has focused on resolving critical chal...The unavailability of high-performance and cost-effective electrocatalysts has impeded the large-scale deployment of alkaline water electrolyzers.Professor Zidong Wei's group has focused on resolving critical challenges in industrial alkaline electrolysis,particularly elucidating hydrogen and oxygen evolution reaction(HER/OER)mechanisms while addressing the persistent activity-stability trade-off.This review summarizes their decade-long progress in developing advanced electrodes,analyzing the origins of sluggish alkaline HER kinetics and OER stability limitations.Professor Wei proposes a unifying"12345 Principle"as an optimization framework.For HER electrocatalysts,they have identified that metal/metal oxide interfaces create synergistic"chimney effect"and"local electric field enhancement effect",enhancing selective intermediate adsorption,interfacial water enrichment/reorientation,and mass transport under industrial high-polarization conditions.Regarding OER,innovative strategies,including dual-ligand synergistic modulation,lattice oxygen suppression,and self-repairing surface construction,are demonstrated to balance oxygen species adsorption,optimize spin states,and dynamically reinforce metal-oxygen bonds for concurrent activity-stability enhancement.The review concludes by addressing remaining challenges in long-term industrial durability and suggesting future research priorities.展开更多
LiNi_(0.5)Mn_(1.5)O_4(LNMO) was prepared by a high-temperature solid phase method,and then Al PO_(4)(AP) was coated on the polyhedral LNMO surface by the wet chemical method.The experimental results showed that the LN...LiNi_(0.5)Mn_(1.5)O_4(LNMO) was prepared by a high-temperature solid phase method,and then Al PO_(4)(AP) was coated on the polyhedral LNMO surface by the wet chemical method.The experimental results showed that the LNMO-1%AP|Li cell prepared with a 1%mass ratio of Al PO_(4and) LNMO had better electrochemical performance;after 450 cycles at 1C,its discharge specific capacity maintained 108.78 m Ah·g^(-1),while that of the LNMO|Li cell was only 86.04 m Ah·g^(-1).Especially at the high rates of 5C and 10C,the electrochemical properties of the former were far superior to the latter.This was attributed to the fact that the AP coating made the surface of LNMO in contact with the electrolyte more stable,effectively promoted the Li~+transport,and reduced the polarization voltage of the electrode.展开更多
Solid-state lithium batteries have become a research hotspot in the field of large-scale energy storage due to their excellent safety performance.The development of high-voltage positive electrode materials matched wi...Solid-state lithium batteries have become a research hotspot in the field of large-scale energy storage due to their excellent safety performance.The development of high-voltage positive electrode materials matched with lithium metal anode have advanced the energy density of solid-state lithium batteries close to or even exceeding that of lithium batteries based on a liquid electrolyte,which is expected to be commercialized in the future.However,in high voltage conditions(>4.3 V),the decomposition of electrolyte components,structural degradation,and interface side reactions significantly reduce battery performance and hinder its further development.This review summarizes the latest research progress of inorganic electrolytes,polymer electrolytes,and composite electrolytes in high-voltage solid-state lithium batteries.At the same time,the designs of high-voltage polymer gel electrolyte and high-voltage quasi solid-state electrolyte are introduced in detail.In addition,interface engineering is crucial for improving the overall performance of high-voltage solid-state batteries.Finally,we highlight the challenges faced by high-voltage solid-state lithium batteries and put forward our own views on future research directions.This review offers instructive insights into the advancement of high-voltage solid-state lithium batteries for large-scale energy storage applications.展开更多
P2-type layered oxide cathode materials have attracted extensive attention due to their simple preparation,high specific capacity,adjustable voltage range,and high packing density.However,the harmful phase transitions...P2-type layered oxide cathode materials have attracted extensive attention due to their simple preparation,high specific capacity,adjustable voltage range,and high packing density.However,the harmful phase transitions that occur at high voltage severely limit their practical application.Herein,a novel high-valence tungsten doped P2-Na_(0.67)Ni_(0.33)Mn_(0.67)O_(2)cathode material was prepared using the sol–gel method.Through diffusion kinetics analysis and in situ X-ray diffraction(in situ XRD),it has been proven that W^(6+)not only enhances the Na^(+)diffusion coefficient but also reduces the P2–O2 phase transition.The optimized NNMO-W1%delivers a high discharge specific capacity of 163 mAh·g^(-1)at 0.1C,and the capacity retention rate is as high as 77.6%after 1000 cycles at 10C.This is mainly due to that W^(6+)enters the lattice,optimizing the arrangement of primary particles.This work sheds light on the design and construction of high-performance layered oxides cathode materials.展开更多
Hall thrusters with large height-radius ratio,owing to their unique advantages in compactness,lightweight,and high performance,have progressively emerged as a preferred choice for diverse space propulsion applications...Hall thrusters with large height-radius ratio,owing to their unique advantages in compactness,lightweight,and high performance,have progressively emerged as a preferred choice for diverse space propulsion applications in the future.However,the amplification of the annular effect in structures with a large height-radius ratio poses a practical problem of plume over-focusing,which seriously restricts the further improvement of Hall thruster performance and the extension of its life.In this study,the formation mechanism of over-focused plume is deeply investigated,and it is ascertained that an intensified radial electric field directed towards the inner wall within the channel serves as a key contributing factor.This phenomenon is fundamentally attributed to structural characteristics of large height-radius ratio that induce pronounced inward inclination of field lines within strong magnetic field zone.Based on this,the design concept of focused magnetic field is proposed,wherein straight magnetic field lines are established within the strong magnetic field zone to generate a quasi-axial accelerating electric field.Simultaneously,the symmetrical magnetic field inside the channel ensures ionization concentration near the channel center,thereby achieving optimal matching between the ionization zone and accelerating field.Experimental results demonstrate that employing a focused magnetic field significantly reduces the divergence half-angle of the plume and yields an excellently barrel-shaped focusing plume morphology in HEP-1350PM.Consequently,the total efficiency of the thruster surpasses 60%,while erosion belt on the inner wall is shortened by nearly 50%.These advancements effectively enhance thruster performance and prolong its operational lifespan.This study can not only resolve practical problems associated with plume over-focusing,but also provide a fundamental guiding principle for magnetic field design of Hall thrusters.展开更多
Hot corrosion of the sputtered nanocrystalline coating and its(Al+Y)-modified coating on N5 with and without different preoxidation treatments under 75 wt.%Na_(2)SO_(4)+25 wt.%NaCl molten salts at 900℃was investigate...Hot corrosion of the sputtered nanocrystalline coating and its(Al+Y)-modified coating on N5 with and without different preoxidation treatments under 75 wt.%Na_(2)SO_(4)+25 wt.%NaCl molten salts at 900℃was investigated.The results showed both the nanocrystalline coatings without preoxidation suffered from severe corrosion.No intact protective scale could form on the surface due to the fast penetration of the corrosive media through massive grain boundaries in the coating.The effect of different preoxidation treatments on the corrosion varied for the two coatings.The original nanocrystalline coatings with simi-lar compositions to the substrate N5 after preoxidation showed a low corrosion resistance,with a loose defective oxide scale on the surface and severe internal corrosion in the coating.Ta oxide segregation ru-ined the stability of the preoxide scale and thus accelerated the subsequent corrosion.In comparison,the AlY-modified coating after preoxidation at 1000℃exhibited the best corrosion resistance.Its oxide con-sisted exclusively of the Al_(2)O_(3) scale,and the least internal corrosion occurred in the coating.Co-addition of Al and Y retarded the diffusion of Ta,improved the stability of the scale,and provided a sufficient Al supplement to reform the Al_(2)O_(3) scale in the corrosion process,postponing corrosion destruction of the scale.The AIY-modified coating after preoxidation at 1100℃performed worse than that at 1000℃.The inferior corrosion resistance could be attributed to the more defective preoxide scale caused by higher thermal stress concentration during preoxidation.展开更多
Electrocatalytic oxidation of surplus ethylene glycol(EG)to high-value glycolic acid(GA)represents a promising approach for sustainable resource utilization,though critical challenges persist in developing durable ele...Electrocatalytic oxidation of surplus ethylene glycol(EG)to high-value glycolic acid(GA)represents a promising approach for sustainable resource utilization,though critical challenges persist in developing durable electrocatalysts and achieving effective recovery of the free acid product from its salt derivatives in alkaline electrolytes.In this work,a PdNi/NF catalyst was rationally synthesized via a one-step electrodeposition method.Systematic characterization revealed that the electron transfer from Ni to Pd modulates *OH adsorption to accelerate EG oxidation reaction(EGOR)while preventing Pd deactivation through oxidation.The optimized system demonstrated exceptional alkaline performance with a glycolic acid Faraday efficiencyof 95%and a current density of 666 mA·cm^(-2).When implemented in an asymmetric EGOR||HER flowcell configuration where only the cathodic electrolyte contains alkaline,the system demonstrated exceptional operational stability by sustaining 70 mA·cm^(-2) current density at a low cell voltage of 0.9 V in neutral media for over 100 h,with product glycolic acid requiring no further acidification.This investigation provides a practical framework for designing efficientelectrocatalytic systems that simplifiesproduct separation steps.展开更多
In the past few decades,ion engines have been widely used in deep-space propulsion and satellite station-keeping.The aim of extending the thruster lifetime is still one of the most important parts during the design st...In the past few decades,ion engines have been widely used in deep-space propulsion and satellite station-keeping.The aim of extending the thruster lifetime is still one of the most important parts during the design stage of ion engine.As one of the core components of ion engine,the grid assembly of ion optic systems may experience long-term ion sputtering in extreme electro-thermal environments,which will eventually lead to its structural and electron-backstreaming failures.In this paper,the current studies of the grid assembly erosion process are systematically analyzed from the aspects of sputtering damage process of grid materials,numerical simulations,and measurements of erosion characteristics of grid assembly.The advantages and disadvantages of various erosion prediction models are highlighted,and the key factors and processes affecting the prediction accuracy of grid assembly erosion patterns are analyzed.Three different types of experimental methods of grid assembly erosion patterns are compared.The analysis in this paper is of great importance for selecting the sputter-resistant grid materials,as well as establishing the erosion models and measurement methods to accurately determine the erosion rate and failure modes of grid assembly.Consequently,the working conditions and structure parameters of ion optic systems could be optimized based on erosion models to promote the ion engine lifetime.展开更多
Solid electrolyte interphase(SEI)is widely acknowledged as the most crucial and least comprehended component in secondary batteries.Particularly,fluorinated SEI derived from the decomposition of fluorinated salt/solve...Solid electrolyte interphase(SEI)is widely acknowledged as the most crucial and least comprehended component in secondary batteries.Particularly,fluorinated SEI derived from the decomposition of fluorinated salt/solvent electrolyte or additive has been widely applied to extend the lifespan of Li/Na anodes,and a similar strategy is being implemented for Zn metal electrodes.However,fluorine-containing electrolytes raise concerns regarding cost,toxicity,corrosivity,and environmental contamination.Moreover,the necessity and role of fluorine in the SEI component remain unclear,particularly in the aqueous system.Here,we report a fluorine-free inorganic-rich SEI layer in situ built by introducing a low-cost,low-concentration tetraethyl ammonium iodide(TEAI)into dilute aqueous ZnSO_(4)electrolyte.The TEAI additive is found to simultaneously modulate the Zn^(2+)solvation structure and optimize the chemisorption at the anode/electrolyte interface.The synergistic interaction between the I-/SO_(4)^(2-)anion-involved solvation structure and adsorbed TEA^(+)cations drives the formation of fluorine-free SEI with inorganics(Zn_(3)N_(2),Zn(IO_(3))_(2),Zn S,etc.),which are capable of providing fast Zn^(2+)transport ability,high-flux nucleation site,and preferential Zn(002)deposition.Besides the reductive decomposition with the formation of Irich SEI layer,the redox-active iodine species can rejuvenate inactive byproducts and dead Zn,allowing the interface self-healing and ensuring long-term interfacial stability.The TEAI-formulated electrolyte endows the Zn anode with excellent Zn reversibility by achieving dendrite-free Zn plating/stripping over 6500 h in the Zn||Zn symmetric battery at 1 mA cm^(-2).This study provides new insights into stabilizing Zn metal electrodes via robust fluorine-free interphases.展开更多
LiNO_(3) is known to significantly enhance the reversibility of lithium metal batteries;however,the modification of solvation structures in various solvents and its further impact on the interface have not been fully ...LiNO_(3) is known to significantly enhance the reversibility of lithium metal batteries;however,the modification of solvation structures in various solvents and its further impact on the interface have not been fully revealed.Herein,we systematically studied the evolution of solvation structures with increasing LiNO_(3) concentration in both carbonate and ether electrolytes.The results from molecular dynamics simulations unveil that the Li^(+)solvation structure is less affected in carbonate electrolytes,while in ether electrolytes,there is a significant decrease of solvent molecules in Li^(+)coordination,and a larger average size of Li^(+)solvation structure emerges as LiNO_(3) concentration increases.Notably,the formation of large ion aggregates with size of several nanometers(nano-clusters),is observed in ether-based electrolytes at conventional Li^(+)concentration(1 M)with higher NO_(3)^(-) ratio,which is further proved by infrared spectroscopy and small-angle X-ray scattering experiments.The nano-clusters with abundant anions are endowed with a narrow energy gap of molecular orbitals,contributing to the formation of an inorganic rich electrode/electrolyte interphase that enhances the reversibility of lithium stripping/plating with Coulombic efficiency up to 99.71%.The discovery of nano-clusters elucidates the underlying mechanism linking ions/solvent aggregation states of electrolytes to interfacial stability in advanced battery systems.展开更多
Charge transfer at the liquid(electrolyte)-solid(metal)interfaces is of fundamental importance to metal electrochemical deposition that further determines the reversibility and kinetics of energy-dense rechargeable me...Charge transfer at the liquid(electrolyte)-solid(metal)interfaces is of fundamental importance to metal electrochemical deposition that further determines the reversibility and kinetics of energy-dense rechargeable metal batteries(RMBs).We demonstrate the fast charge transfer at the electrolyte-metal interfaces for lithium metal by designing and synthesizing electrolytes with chiral solvents:R(or S)-1,2-dimethoxy pro pane(R-DMP or S-DMP)and R(or S)-4-methyl-1,3-dioxolane(R-MDOL or S-MDOL).The chiral-induced spin selectivity is considered to produce spin-polarized metal surfaces,enabling the improvement in charge transfer rate and efficiency.The deposited Li metal in chiral electrolytes shows smooth and uniform morphologies,as well as high initial(>95%)and average(~99.2%)Coulombic efficiency for Li metal stripping/plating process,thus prolonging the life-span of batteries using thin lithium anode(50μm)to 400 cycles till 80%capacity retention.This work provides a distinct approach to regulate metal deposition beyond the limitation of ion de-solvation.展开更多
Platinum-ruthenium alloys(PtRu)represent state-of-the-art alkaline hydrogen oxidation reaction(HOR)catalysts,yet the atomic-scale origin of their superiority over pure Pt remains incompletely understood.Here,we employ...Platinum-ruthenium alloys(PtRu)represent state-of-the-art alkaline hydrogen oxidation reaction(HOR)catalysts,yet the atomic-scale origin of their superiority over pure Pt remains incompletely understood.Here,we employ density functional theory calculations,ab initio molecular dynamics simulations,and microkinetic modeling on Pt(111)and PtRu(111)surfaces to systematically investigate the key factors,including active sites distribution,species adsorption,and solvent reorganization,that affect the HOR activity and decouple their contributions.The results reveal that while the moderate hydrogen binding energy and improved hydroxyl(OH)species adsorption both contribute to the enhanced activity,the dominant factor is the substantial reduction in solvent reorganization energy on the PtRu(111).This is facilitated by the spatial separation of active sites:Pt atoms preferentially stabilize adsorbed hydrogen,while Ru atoms strongly bind OH and interfacial water molecules.This configuration increases the probability of hydrogen interacting with OH/water and enhances the fraction of"H-up"water molecules,forming a well-organized hydrogen bond network within the electric double layer.The dynamically compatible interfacial water structure and HOR coordination promote H desorption and proton transfer in the Volmer step,thereby accelerating the HOR kinetics.展开更多
基金the financial support from the Key Project of Shaanxi Provincial Natural Science Foundation-Key Project of Laboratory(2025SYS-SYSZD-117)the Natural Science Basic Research Program of Shaanxi(2025JCYBQN-125)+8 种基金Young Talent Fund of Xi'an Association for Science and Technology(0959202513002)the Key Industrial Chain Technology Research Program of Xi'an(24ZDCYJSGG0048)the Key Research and Development Program of Xianyang(L2023-ZDYF-SF-077)Postdoctoral Fellowship Program of CPSF(GZC20241442)Shaanxi Postdoctoral Science Foundation(2024BSHSDZZ070)Research Funds for the Interdisciplinary Projects,CHU(300104240913)the Fundamental Research Funds for the Central Universities,CHU(300102385739,300102384201,300102384103)the Scientific Innovation Practice Project of Postgraduate of Chang'an University(300103725063)the financial support from the Australian Research Council。
文摘Lithium-ion batteries(LIBs),while dominant in energy storage due to high energy density and cycling stability,suffer from severe capacity decay,rate capability degradation,and lithium dendrite formation under low-temperature(LT)operation.Therefore,a more comprehensive and systematic understanding of LIB behavior at LT is urgently required.This review article comprehensively reviews recent advancements in electrolyte engineering strategies aimed at improving the low-temperature operational capabilities of LIBs.The study methodically examines critical performance-limiting mechanisms through fundamental analysis of four primary challenges:insufficient ionic conductivity under cryogenic conditions,kinetically hindered charge transfer processes,Li+transport limitations across the solidelectrolyte interphase(SEI),and uncontrolled lithium dendrite growth.The work elaborates on innovative optimization approaches encompassing lithium salt molecular design with tailored dissociation characteristics,solvent matrix optimization through dielectric constant and viscosity regulation,interfacial engineering additives for constructing low-impedance SEI layers,and gel-polymer composite electrolyte systems.Notably,particular emphasis is placed on emerging machine learning-guided electrolyte formulation strategies that enable high-throughput virtual screening of constituent combinations and prediction of structure-property relationships.These artificial intelligence-assisted rational design frameworks demonstrate significant potential for accelerating the development of next-generation LT electrolytes by establishing quantitative composition-performance correlations through advanced data-driven methodologies.
基金supported by National Key Research and Development Program of China (2016YFB0900500,2017YFB0903100)the State Grid Science and Technology Project (SGRI-DL-F1-51-011)
文摘The AC/DC hybrid distribution network is one of the trends in distribution network development, which poses great challenges to the traditional distribution transformer. In this paper, a new topology suitable for AC/DC hybrid distribution network is put forward according to the demands of power grid, with advantages of accepting DG and DC loads, while clearing DC fault by blocking the clamping double sub-module(CDSM) of input stage. Then, this paper shows the typical structure of AC/DC distribution network that is hand in hand. Based on the new topology, this paper designs the control and modulation strategies of each stage, where the outer loop controller of input stage is emphasized for its twocontrol mode. At last, the rationality of new topology and the validity of control strategies are verified by the steady and dynamic state simulation. At the same time, the simulation results highlight the role of PET in energy regulation.
基金supported by the State Grid Science and Technology Project (GEIRI-DL-71-17-002)
文摘This paper introduces the implementation and data analysis associated with a state-wide power quality monitoring and analysis system in China. Corporation specifications on power quality monitors as well as on communication protocols are formulated for data transmission. Big data platform and related technologies are utilized for data storage and computation. Compliance verification analysis and a power quality performance assessment are conducted, and a visualization tool for result presentation is finally presented.
基金Funding for this study was received from the Deputyship for Research&Innovation,Ministry of Education in Saudi Arabia through the project number“IFPHI-021–135–2020”and King Abdulaziz University,DSR,Jeddah,Saudi Arabia.
文摘Increasing renewable energy targets globally has raised the requirement for the efficient and profitable operation of solar photovoltaic(PV)systems.In light of this requirement,this paper provides a path for evaluating the operating condition and improving the power output of the PV system in a grid integrated environment.To achieve this,different types of faults in grid-connected PV systems(GCPVs)and their impact on the energy loss associated with the electrical network are analyzed.A data-driven approach using neural networks(NNs)is proposed to achieve root cause analysis and localize the fault to the component level in the system.The localized fault condition is combined with a parallel operation of adaptive neurofuzzy inference units(ANFIUs)to develop a power mismatch-based control unit(PMCU)for improving the power output of the GCPV.To develop the proposed framework,a 10-kW single-phase GCPV is simulated for training the NN-based anomaly detection approach with 14 deviation signals.Further,the developed algorithm is combined with the PMCU implemented with the experimental setup of GCPV.The results identified 98.2%training accuracy and 43000 observations/sec prediction speed for the trained classifier,and improved power output with reduced voltage and current harmonics for the grid-connected PV operation.
文摘Recently,thick haze and poisonous smoke have cloaked the surrounding air in Malaysia due to the uncontrollable and unethical burning of nearby country.This devastating episode of open burning started in the year 1997 in Indonesia which deeply affected most of the ASEAN(association of southeast asian nations)countries especially their neighbour Malaysia and Singapore.The PV(photovoltaic)technology as an alternative means of energy generation experiences such significant energy decrease based on this condition which is due to the shading of sunlight.The 6 h claims of good sunlight has become not more than 2 h and gets worst when the API(air pollution index)struck 200 levels which is at very unhealthy condition.This study embraces some findings from 1 kWp PV generator field data installed in Malaysia reflecting the daily energy decrease operated during this unhealthy weather condition.It is found that,such significant energy decrease with the value of 0.43 W power output per increment of one point API.This value shows such concrete proof of additional factors to be considered in PV modelling in line to support PV technology adaptation in the ASEAN region.
文摘The triple bond in N_(2)has an extremely high bond energy and is thus difficult to break.N_(2)is commonly converted into NH3 artificially via the Haber-Bosch process,and NH_(3)can be utilized to produce other nitrogen-containing chemicals.Here,we developed an electron catalyzed method to directly fix N_(2)into azos,by pushing and pulling the electron into and from the aromatic halide with the cyclic voltammetry method.The round-trip journey of electron can successfully weaken the triple bond in N_(2)through the electron pushing-induced aryl radical via a“brick trowel”transition state,and then produce the diazonium ions by pulling the electron out from the diazo radical intermediate.Different azos can be synthesized with this developed electron catalyzed approach.This approach provides a novel concept and practical route for the fixation of N_(2)at atmospheric pressure into chemical products valuable for industrial and commercial applications.
基金supported by the National Natural Science Foundation of China(Grant No.W2412060,22325902 and 52171215)the State Key Laboratory of Clean Energy Utilization(Open Fund Project No.ZJUCEU2023002)。
文摘Sodium-ion batteries(SIBs)have attracted significant attention in large-scale energy storage system because of their abundant sodium resource and cost-effectiveness.Layered oxide materials are particularly promising as SIBs cathodes due to their high theoretical capacities and facile synthesis.However,their practical applications are hindered by the limitations in energy density and cycling stability.The comprehensive understanding of failure mechanisms within bulk structure and at the cathode/electrolyte interface of cathodes is still lacking.In this review,the issues related to bulk phase degradation and surface degradation,such as irreversible phase transitions,cation migration,transition metal dissolution,air/moisture instability,intergranular cracking,interfacial reactions,and reactive oxygen loss,are discussed.The latest advances and strategies to improve the stability of layered oxide cathodes and full cells are provided,as well as our perspectives on the future development of SIBs.
基金the National Key Research and Development Program of China(2022YFB4004100)National Natural Science Foundation of China(22272161,22179126)+1 种基金the Jilin Province Science and Technology Development Program(YDZJ202202CXJD011,20240101019JC)Jilin Province major science and technology project(222648GX0105103875)for financial supports.
文摘The weak adsorption energy of oxygen-containing intermediates on Co center leads to a considerable performance dis-parity between Co-N-C and costly Pt benchmark in catalyzing oxygen reduction reaction(ORR).In this work,we strategi-cally engineer the active site structure of Co-N-C via B substitution,which is accomplished by the pyrolysis of ammonium borate.During this process,the in-situ generated NH_(3)gas plays a critical role in creating surface defects and boron atoms substituting nitrogen atoms in the carbon structure.The well-designed CoB_(1)N_(3)active site endows Co with higher charge density and stronger adsorption energy toward oxygen species,potentially accelerating ORR kinetics.As expected,the resulting Co-B/N-C catalyst exhibited superior ORR performance over Co-N-C counterpart,with 40 mV,and fivefold en-hancement in half-wave potential and turnover frequency(TOF).More importantly,the excellent ORR performance could be translated into membrane electrode assembly(MEA)in a fuel cell test,delivering an impressive peak power density of 824 mW·cm^(-2),which is currently the best among Co-based catalysts under the same conditions.This work not only demon-strates an effective method for designing advanced catalysts,but also affords a highly promising non-precious metal ORR electrocatalyst for fuel cell applications.
基金the National Key R&D Program of China(2021YFB4000300)National Natural Science Foundation of China(21822803,22408030,22072009,91534205,51072239)National Program on Key Basic Research Project(973 Program,2012CB720303).
文摘The unavailability of high-performance and cost-effective electrocatalysts has impeded the large-scale deployment of alkaline water electrolyzers.Professor Zidong Wei's group has focused on resolving critical challenges in industrial alkaline electrolysis,particularly elucidating hydrogen and oxygen evolution reaction(HER/OER)mechanisms while addressing the persistent activity-stability trade-off.This review summarizes their decade-long progress in developing advanced electrodes,analyzing the origins of sluggish alkaline HER kinetics and OER stability limitations.Professor Wei proposes a unifying"12345 Principle"as an optimization framework.For HER electrocatalysts,they have identified that metal/metal oxide interfaces create synergistic"chimney effect"and"local electric field enhancement effect",enhancing selective intermediate adsorption,interfacial water enrichment/reorientation,and mass transport under industrial high-polarization conditions.Regarding OER,innovative strategies,including dual-ligand synergistic modulation,lattice oxygen suppression,and self-repairing surface construction,are demonstrated to balance oxygen species adsorption,optimize spin states,and dynamically reinforce metal-oxygen bonds for concurrent activity-stability enhancement.The review concludes by addressing remaining challenges in long-term industrial durability and suggesting future research priorities.
文摘LiNi_(0.5)Mn_(1.5)O_4(LNMO) was prepared by a high-temperature solid phase method,and then Al PO_(4)(AP) was coated on the polyhedral LNMO surface by the wet chemical method.The experimental results showed that the LNMO-1%AP|Li cell prepared with a 1%mass ratio of Al PO_(4and) LNMO had better electrochemical performance;after 450 cycles at 1C,its discharge specific capacity maintained 108.78 m Ah·g^(-1),while that of the LNMO|Li cell was only 86.04 m Ah·g^(-1).Especially at the high rates of 5C and 10C,the electrochemical properties of the former were far superior to the latter.This was attributed to the fact that the AP coating made the surface of LNMO in contact with the electrolyte more stable,effectively promoted the Li~+transport,and reduced the polarization voltage of the electrode.
基金supported by the National Key R&D Program of China(2024YFA1211100)the National Natural Science Foundation of China(52301278,22479080,52202254,92372001,22393900,and 92372203)+2 种基金the Natural Science Foundation of Jiangsu Province(BK20230937,BK20220966)the Science and Technology Plans of Tianjin(23JCYBJC00170,24JCJQJC00220,and 24ZXZSSS00390)the Fundamental Research Funds for the Central Universities(02063253167,30922010708)。
文摘Solid-state lithium batteries have become a research hotspot in the field of large-scale energy storage due to their excellent safety performance.The development of high-voltage positive electrode materials matched with lithium metal anode have advanced the energy density of solid-state lithium batteries close to or even exceeding that of lithium batteries based on a liquid electrolyte,which is expected to be commercialized in the future.However,in high voltage conditions(>4.3 V),the decomposition of electrolyte components,structural degradation,and interface side reactions significantly reduce battery performance and hinder its further development.This review summarizes the latest research progress of inorganic electrolytes,polymer electrolytes,and composite electrolytes in high-voltage solid-state lithium batteries.At the same time,the designs of high-voltage polymer gel electrolyte and high-voltage quasi solid-state electrolyte are introduced in detail.In addition,interface engineering is crucial for improving the overall performance of high-voltage solid-state batteries.Finally,we highlight the challenges faced by high-voltage solid-state lithium batteries and put forward our own views on future research directions.This review offers instructive insights into the advancement of high-voltage solid-state lithium batteries for large-scale energy storage applications.
基金supported by the National Natural Science Foundation of China Key Program(No.U22A20420)Changzhou Leading Innovative Talents Introduction and Cultivation Project(No.CQ20230109)the Key Project of Jiangsu Provincial Basic Research Program(No.BK20243032)。
文摘P2-type layered oxide cathode materials have attracted extensive attention due to their simple preparation,high specific capacity,adjustable voltage range,and high packing density.However,the harmful phase transitions that occur at high voltage severely limit their practical application.Herein,a novel high-valence tungsten doped P2-Na_(0.67)Ni_(0.33)Mn_(0.67)O_(2)cathode material was prepared using the sol–gel method.Through diffusion kinetics analysis and in situ X-ray diffraction(in situ XRD),it has been proven that W^(6+)not only enhances the Na^(+)diffusion coefficient but also reduces the P2–O2 phase transition.The optimized NNMO-W1%delivers a high discharge specific capacity of 163 mAh·g^(-1)at 0.1C,and the capacity retention rate is as high as 77.6%after 1000 cycles at 10C.This is mainly due to that W^(6+)enters the lattice,optimizing the arrangement of primary particles.This work sheds light on the design and construction of high-performance layered oxides cathode materials.
基金financial support from the National Key R&D Program of China(No.2022YFE0204100)the National Natural Science Foundation of China(Nos.U23B20152 and 52402479)。
文摘Hall thrusters with large height-radius ratio,owing to their unique advantages in compactness,lightweight,and high performance,have progressively emerged as a preferred choice for diverse space propulsion applications in the future.However,the amplification of the annular effect in structures with a large height-radius ratio poses a practical problem of plume over-focusing,which seriously restricts the further improvement of Hall thruster performance and the extension of its life.In this study,the formation mechanism of over-focused plume is deeply investigated,and it is ascertained that an intensified radial electric field directed towards the inner wall within the channel serves as a key contributing factor.This phenomenon is fundamentally attributed to structural characteristics of large height-radius ratio that induce pronounced inward inclination of field lines within strong magnetic field zone.Based on this,the design concept of focused magnetic field is proposed,wherein straight magnetic field lines are established within the strong magnetic field zone to generate a quasi-axial accelerating electric field.Simultaneously,the symmetrical magnetic field inside the channel ensures ionization concentration near the channel center,thereby achieving optimal matching between the ionization zone and accelerating field.Experimental results demonstrate that employing a focused magnetic field significantly reduces the divergence half-angle of the plume and yields an excellently barrel-shaped focusing plume morphology in HEP-1350PM.Consequently,the total efficiency of the thruster surpasses 60%,while erosion belt on the inner wall is shortened by nearly 50%.These advancements effectively enhance thruster performance and prolong its operational lifespan.This study can not only resolve practical problems associated with plume over-focusing,but also provide a fundamental guiding principle for magnetic field design of Hall thrusters.
基金supported by the National Natural Science Foundation of China under Grant(Nos.51671053 and 51801021)the Fundamental Research Funds for the Central Uni-versities(No.N2302007)the Ministry of Industry and Infor-mation Technology Project(No.MJ-2017-J-99).
文摘Hot corrosion of the sputtered nanocrystalline coating and its(Al+Y)-modified coating on N5 with and without different preoxidation treatments under 75 wt.%Na_(2)SO_(4)+25 wt.%NaCl molten salts at 900℃was investigated.The results showed both the nanocrystalline coatings without preoxidation suffered from severe corrosion.No intact protective scale could form on the surface due to the fast penetration of the corrosive media through massive grain boundaries in the coating.The effect of different preoxidation treatments on the corrosion varied for the two coatings.The original nanocrystalline coatings with simi-lar compositions to the substrate N5 after preoxidation showed a low corrosion resistance,with a loose defective oxide scale on the surface and severe internal corrosion in the coating.Ta oxide segregation ru-ined the stability of the preoxide scale and thus accelerated the subsequent corrosion.In comparison,the AlY-modified coating after preoxidation at 1000℃exhibited the best corrosion resistance.Its oxide con-sisted exclusively of the Al_(2)O_(3) scale,and the least internal corrosion occurred in the coating.Co-addition of Al and Y retarded the diffusion of Ta,improved the stability of the scale,and provided a sufficient Al supplement to reform the Al_(2)O_(3) scale in the corrosion process,postponing corrosion destruction of the scale.The AIY-modified coating after preoxidation at 1100℃performed worse than that at 1000℃.The inferior corrosion resistance could be attributed to the more defective preoxide scale caused by higher thermal stress concentration during preoxidation.
基金financially supported by the National Key Research and Development Program of China(2022YFA1504200)the National Natural Science Foundation of China(22178033 and 22090030)the Fundamental Research Funds for the Central Universities(2024CDJXY010).
文摘Electrocatalytic oxidation of surplus ethylene glycol(EG)to high-value glycolic acid(GA)represents a promising approach for sustainable resource utilization,though critical challenges persist in developing durable electrocatalysts and achieving effective recovery of the free acid product from its salt derivatives in alkaline electrolytes.In this work,a PdNi/NF catalyst was rationally synthesized via a one-step electrodeposition method.Systematic characterization revealed that the electron transfer from Ni to Pd modulates *OH adsorption to accelerate EG oxidation reaction(EGOR)while preventing Pd deactivation through oxidation.The optimized system demonstrated exceptional alkaline performance with a glycolic acid Faraday efficiencyof 95%and a current density of 666 mA·cm^(-2).When implemented in an asymmetric EGOR||HER flowcell configuration where only the cathodic electrolyte contains alkaline,the system demonstrated exceptional operational stability by sustaining 70 mA·cm^(-2) current density at a low cell voltage of 0.9 V in neutral media for over 100 h,with product glycolic acid requiring no further acidification.This investigation provides a practical framework for designing efficientelectrocatalytic systems that simplifiesproduct separation steps.
基金co-supported by the National Key R&D Program of China(No.2022YFB3403500)the National Natural Science Foundation of China(No.NSFC52202460)the China Postdoctoral Science Foundation(Nos.2021M690392,2021TQ0036,and 2023TQ0031)。
文摘In the past few decades,ion engines have been widely used in deep-space propulsion and satellite station-keeping.The aim of extending the thruster lifetime is still one of the most important parts during the design stage of ion engine.As one of the core components of ion engine,the grid assembly of ion optic systems may experience long-term ion sputtering in extreme electro-thermal environments,which will eventually lead to its structural and electron-backstreaming failures.In this paper,the current studies of the grid assembly erosion process are systematically analyzed from the aspects of sputtering damage process of grid materials,numerical simulations,and measurements of erosion characteristics of grid assembly.The advantages and disadvantages of various erosion prediction models are highlighted,and the key factors and processes affecting the prediction accuracy of grid assembly erosion patterns are analyzed.Three different types of experimental methods of grid assembly erosion patterns are compared.The analysis in this paper is of great importance for selecting the sputter-resistant grid materials,as well as establishing the erosion models and measurement methods to accurately determine the erosion rate and failure modes of grid assembly.Consequently,the working conditions and structure parameters of ion optic systems could be optimized based on erosion models to promote the ion engine lifetime.
基金financially supported by the National Natural Science Foundation of China(Grant No.22075331,21905057)。
文摘Solid electrolyte interphase(SEI)is widely acknowledged as the most crucial and least comprehended component in secondary batteries.Particularly,fluorinated SEI derived from the decomposition of fluorinated salt/solvent electrolyte or additive has been widely applied to extend the lifespan of Li/Na anodes,and a similar strategy is being implemented for Zn metal electrodes.However,fluorine-containing electrolytes raise concerns regarding cost,toxicity,corrosivity,and environmental contamination.Moreover,the necessity and role of fluorine in the SEI component remain unclear,particularly in the aqueous system.Here,we report a fluorine-free inorganic-rich SEI layer in situ built by introducing a low-cost,low-concentration tetraethyl ammonium iodide(TEAI)into dilute aqueous ZnSO_(4)electrolyte.The TEAI additive is found to simultaneously modulate the Zn^(2+)solvation structure and optimize the chemisorption at the anode/electrolyte interface.The synergistic interaction between the I-/SO_(4)^(2-)anion-involved solvation structure and adsorbed TEA^(+)cations drives the formation of fluorine-free SEI with inorganics(Zn_(3)N_(2),Zn(IO_(3))_(2),Zn S,etc.),which are capable of providing fast Zn^(2+)transport ability,high-flux nucleation site,and preferential Zn(002)deposition.Besides the reductive decomposition with the formation of Irich SEI layer,the redox-active iodine species can rejuvenate inactive byproducts and dead Zn,allowing the interface self-healing and ensuring long-term interfacial stability.The TEAI-formulated electrolyte endows the Zn anode with excellent Zn reversibility by achieving dendrite-free Zn plating/stripping over 6500 h in the Zn||Zn symmetric battery at 1 mA cm^(-2).This study provides new insights into stabilizing Zn metal electrodes via robust fluorine-free interphases.
基金supported by the National Natural Science Foundation of China(No.22372083,52201259)the National Key R&D Program of China(2021YFB2500300)+2 种基金the Fundamental Research Funds for the Central Universities:Nankai University(63241607)the Natural Science Foundation of Tianjin(No.22JCZDJC00380)the Young Elite Scientist Sponsorship Program by CAST.
文摘LiNO_(3) is known to significantly enhance the reversibility of lithium metal batteries;however,the modification of solvation structures in various solvents and its further impact on the interface have not been fully revealed.Herein,we systematically studied the evolution of solvation structures with increasing LiNO_(3) concentration in both carbonate and ether electrolytes.The results from molecular dynamics simulations unveil that the Li^(+)solvation structure is less affected in carbonate electrolytes,while in ether electrolytes,there is a significant decrease of solvent molecules in Li^(+)coordination,and a larger average size of Li^(+)solvation structure emerges as LiNO_(3) concentration increases.Notably,the formation of large ion aggregates with size of several nanometers(nano-clusters),is observed in ether-based electrolytes at conventional Li^(+)concentration(1 M)with higher NO_(3)^(-) ratio,which is further proved by infrared spectroscopy and small-angle X-ray scattering experiments.The nano-clusters with abundant anions are endowed with a narrow energy gap of molecular orbitals,contributing to the formation of an inorganic rich electrode/electrolyte interphase that enhances the reversibility of lithium stripping/plating with Coulombic efficiency up to 99.71%.The discovery of nano-clusters elucidates the underlying mechanism linking ions/solvent aggregation states of electrolytes to interfacial stability in advanced battery systems.
基金supported by the National Key R&D Program of China(2021YFB2500300)the National Natural Science Foundation of China(22372083,52201259)+1 种基金the Natural Science Foundation of Tianjin(22JCZDJC00380)Young Elite Scientist Sponsorship Program by CAST。
文摘Charge transfer at the liquid(electrolyte)-solid(metal)interfaces is of fundamental importance to metal electrochemical deposition that further determines the reversibility and kinetics of energy-dense rechargeable metal batteries(RMBs).We demonstrate the fast charge transfer at the electrolyte-metal interfaces for lithium metal by designing and synthesizing electrolytes with chiral solvents:R(or S)-1,2-dimethoxy pro pane(R-DMP or S-DMP)and R(or S)-4-methyl-1,3-dioxolane(R-MDOL or S-MDOL).The chiral-induced spin selectivity is considered to produce spin-polarized metal surfaces,enabling the improvement in charge transfer rate and efficiency.The deposited Li metal in chiral electrolytes shows smooth and uniform morphologies,as well as high initial(>95%)and average(~99.2%)Coulombic efficiency for Li metal stripping/plating process,thus prolonging the life-span of batteries using thin lithium anode(50μm)to 400 cycles till 80%capacity retention.This work provides a distinct approach to regulate metal deposition beyond the limitation of ion de-solvation.
文摘Platinum-ruthenium alloys(PtRu)represent state-of-the-art alkaline hydrogen oxidation reaction(HOR)catalysts,yet the atomic-scale origin of their superiority over pure Pt remains incompletely understood.Here,we employ density functional theory calculations,ab initio molecular dynamics simulations,and microkinetic modeling on Pt(111)and PtRu(111)surfaces to systematically investigate the key factors,including active sites distribution,species adsorption,and solvent reorganization,that affect the HOR activity and decouple their contributions.The results reveal that while the moderate hydrogen binding energy and improved hydroxyl(OH)species adsorption both contribute to the enhanced activity,the dominant factor is the substantial reduction in solvent reorganization energy on the PtRu(111).This is facilitated by the spatial separation of active sites:Pt atoms preferentially stabilize adsorbed hydrogen,while Ru atoms strongly bind OH and interfacial water molecules.This configuration increases the probability of hydrogen interacting with OH/water and enhances the fraction of"H-up"water molecules,forming a well-organized hydrogen bond network within the electric double layer.The dynamically compatible interfacial water structure and HOR coordination promote H desorption and proton transfer in the Volmer step,thereby accelerating the HOR kinetics.
