Based on landscaping practices in the stereo landscape demonstration project of Chongqing Academy of Science and Technology (CAST),current management and maintenance of the stereo landscapes were introduced by analyzi...Based on landscaping practices in the stereo landscape demonstration project of Chongqing Academy of Science and Technology (CAST),current management and maintenance of the stereo landscapes were introduced by analyzing maintenance and management of the plants in the stereo landscape forest.The maintenance and management models were summarized according to the management styles,concrete measures and new technologies were studied,laws and key points for the maintenance and management in different seasons were given,and finally deficiencies and solutions were proposed to improve the future maintenance and management.展开更多
T he residual stray magnetic fields present in ferromagnetic casting slabs were investigated in this work,which result from the magnetic fields generated during the steel casting process.Existing optical detection met...T he residual stray magnetic fields present in ferromagnetic casting slabs were investigated in this work,which result from the magnetic fields generated during the steel casting process.Existing optical detection methods face challenges owing to surface oxide scales,and conventional high-precision magnetic sensors are ineffective at high temperatures.To overcome these limitations,a small coil sensor was employed to measure the residual magnetism strength in oscillation traces,using metal magnetic memory and electromagnetic induction methods,which can carry out detection without an external excitation source.Using this technology,the proposed scheme successfully detects defects at high tempe-ratures(up to 670℃)without a cooling device.The key findings include the ability to detect both surface and near-surface defects,such as cracks and oscillation marks,with an enhanced signal-to-noise ratio(SNR)of 7.2 dB after signal processing.The method’s practicality was validated in a steel mill environment,where testing on casting slabs effectively detected defects,providing a foundation for improving industrial quality control.The proposed detection scheme offers a significant advancement in nondestructive testing(NDT)for high-temperature applications,contributing to more efficient and accurate monitoring of ferromagnetic material integrity.展开更多
Cyclopropenones have been extensively utilized in catalytic ring-opening and ring-expansion reactions for the synthesis of unsaturated carbonyl compounds.The first rhodium-catalyzed ring-opening reaction of aryl-/alky...Cyclopropenones have been extensively utilized in catalytic ring-opening and ring-expansion reactions for the synthesis of unsaturated carbonyl compounds.The first rhodium-catalyzed ring-opening reaction of aryl-/alkyl-substituted cyclopropenones is accomplished,successfully affording acyloin derivatives.This transformation represents a novel reaction pattern involving cyclopropenones.The resulting acyloin products constitute important building blocks in organic synthesis and serve as fundamental structural frameworks in numerous natural products.展开更多
Knowing the precise relationship between fuel loading and reactivity is essential for guiding reactor criticality extrapolation and online refueling in molten salt reactors(MSRs).This study aims to explore and explain...Knowing the precise relationship between fuel loading and reactivity is essential for guiding reactor criticality extrapolation and online refueling in molten salt reactors(MSRs).This study aims to explore and explain the linear relationship between reactivity and the reciprocal of uranium concentration in thermal-spectrum MSRs.By applying neutron balance theory,we analyzed the neutron absorption cross sections of various nuclides in single-lattice models with varying fuel concentrations.Our findings reveal a simple linear correlation between reactivity and the reciprocal of uranium concentration,which can be explained from the perspective of nuclear reaction cross sections that adhere to the 1/v law in the thermal neutron spectrum.Furthermore,we identified that the neutron absorption single-group cross sections of structural materials and carrier salts exhibit an approximately linear relationship with the fission single-group cross section of ^(235) U;similarly,the reciprocal of ^(235)U’s fission cross section exhibits an approximately linear relationship with uranium concentration.This linear relationship deviates as the volume fraction of molten salt increases,due to a greater proportion of neutrons being captured in the resonance energy spectrum.However,it remains valid for molten salt volume fractions up to 25%and demonstrates broad applicability in the physical design and operation of thermal molten salt reactors.展开更多
A novel method called thermomechanical treatment based on impact hydroforming(TTIHF)was proposed.The pre-deformation was achieved by using impact hydroforming(IHF)loading.The strengthening effect and mechanism of 2195...A novel method called thermomechanical treatment based on impact hydroforming(TTIHF)was proposed.The pre-deformation was achieved by using impact hydroforming(IHF)loading.The strengthening effect and mechanism of 2195 Al-Li alloy were investigated under various loading pre-deformation conditions.The results showed that the time for the alloy to reach peak aging was shortened under TTIHF.Compared with those of the pre-deformation method of stamping forming,the yield strength and tensile strength of the Al-Li alloy under TTIHF increased by 18.6%and 18.0%,respectively.The deformation caused by IHF loading resulted in a high density of dislocations,which served as nucleation sites for the precipitation of the T_(1)phase during aging.After TTIHF,the average diameter and thickness of the T_(1)phase in the alloy were smaller than those under other experiment conditions.Moreover,the density and distribution of the T_(1)phase were the highest and the most uniform.展开更多
A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The resu...A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The results show that cold-pressing produces intense plastic deformation near the corrugated surface of the Al plate,which promotes dynamic recrystallization of the Al substrate near the interface during the subsequent hot-pressing.In addition,the initial corrugation on the surface of the Al plate also changes the local stress state near the interface during hot pressing,which has a large effect on the texture components of the substrates near the corrugated interface.The construction of the corrugated interface can greatly enhance the shear strength by 2−4 times due to the increased contact area and the strong“mechanical gearing”effect.Moreover,the mechanical properties are largely depended on the orientation relationship between corrugated direction and loading direction.展开更多
Taking half-tube part with curvature as an example,the Impact Hydroforming(IHF)characteristics were studied by combining the actual forming experiment and numerical simulation.The IHF experiment showed that wrinkles a...Taking half-tube part with curvature as an example,the Impact Hydroforming(IHF)characteristics were studied by combining the actual forming experiment and numerical simulation.The IHF experiment showed that wrinkles appeared at the bottom of the part during single-step forming,but no wrinkles were observed during double-step forming.The thinning rate and deviation of the wall thickness of the part in each area were less than 20%and 2.7 mm,correspondingly,and the drawing depth of the part reached 45.8 mm.The effect of double-step forming was better than that of single-step forming,which was related to the IHF forming law.Besides,the characteristics of the IHF process were studied by numerical simulation.The results indicated that when double-step forming was utilized,there was almost no velocity field in the opposite direction of deformation after the bottom of the part contacted the die,and the existence of stress state at the bottom would restrain and eliminate the wrinkles.The inertia effect evolved with the driving pressure.Specially,the inertia effect can improve the flow of metal and reduce the deviation of the wall thickness of the part under double-step forming.展开更多
This study focused on improving the cathode performance of Ba_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.15)O_(3-δ)(BSCN)-based perovskite materials through molybdenum(Mo)doping.Pure BSCN and Mo-modified-BSCN—Ea_(0.6)Sr_(0.4)Co_(0...This study focused on improving the cathode performance of Ba_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.15)O_(3-δ)(BSCN)-based perovskite materials through molybdenum(Mo)doping.Pure BSCN and Mo-modified-BSCN—Ea_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.1)Mo_(0.05)O_(3-δ)(B S CNM_(0.05)),Ba_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.05)Mo_(0.1)O_(3-δ)(BSCNM_(0.1)),and Ba_(0.6)Sr_(0.4)Co_(0.85)Mo_(0.15)O_(3-δ)(BSCM)—with Mo doping contents of 5mol%,10mol%,and15mol%,respectively,were successfully prepared using the sol-gel method.The effects of Mo doping on the crystal structure,conductivity,thermal expansion coefficient,oxygen reduction reaction(ORR)activity,and electrochemical performance were systematically evaluated using X-ray diffraction analysis,thermally induced characterization,electrochemical impedance spectroscopy,and single-cell performance tests.The results revealed that Mo doping could improve the conductivity of the materials,suppress their thermal expansion effects,and significantly improve the electrochemical performance.Surface chemical state analysis using X-ray photoelectron spectroscopy revealed that 5mol%Mo doping could facilitate a high adsorbed oxygen concentration leading to enhanced ORR activity in the materials.Density functional theory calculations confirmed that Mo doping promoted the ORR activity in the materials.At an operating temperature of 600℃,the BSCNM_(0.05)cathode material exhibited significantly enhanced electrochemical impedance characteristics,with a reduced area specific resistance of 0.048Ω·cm~2,which was lower than that of the undoped BSCN matrix material by 32.39%.At the same operating temperature,an anode-supported single cell using a BSCNM_(0.05)cathode achieved a peak power density of 1477 mW·cm^(-2),which was 30.71%,56.30%,and 171.50%higher than those of BSCN,BSCNM_(0.1),and B SCM,respectively.The improved ORR activity and electrochemical performance of BSCNM_(0.05)indicate that it can be used as a cathode material in low-temperature solid oxide fuel cells.展开更多
Polyethylene oxide(PEO)-based solid polymer electrolytes(SPEs)have long faced limitations due to low ionic conductivity at ambient temperature and poor interfacial stability with lithium metal anodes.Here,we present a...Polyethylene oxide(PEO)-based solid polymer electrolytes(SPEs)have long faced limitations due to low ionic conductivity at ambient temperature and poor interfacial stability with lithium metal anodes.Here,we present a structural engineering strategy to address these challenges through shear-induced crystallization of concentrated PEO-LiTFSI solutions,which self-assemble into flower-like spherulites with radially aligned lamellar crystals.This unique structure creates continuous Li^(+)transport highways through densely packed crystalline domains,achieving a record-high ionic conductivity of 1.70×10^(-4) S/cm at 25℃ for pristine PEO-based systems.Strategic incorporation of lithium montmorillonite(MMTli,10 wt%)further optimizes the composite electrolyte,balancing high ionic conductivity(1.47×10^(-4) S/cm)with enhanced electrochemical stability(4.99 V vs.Li^(+)/Li),elevated Li^(+)transference number(0.62),and mechanical robustness.The composite electrolyte enables stable Li plating/stripping over 800 h in symmetric Li||Li cells and powers LiFePO_(4)||Li solid-state batteries with 82%capacity retention after 200 cycles at 0.2 C under ambient conditions.This work pioneers a scalable processing paradigm for crystalline polymer electrolytes,offering new insights into ion transport mechanisms and validating clay minerals as multifunctional additives for next-generation energy storage systems.展开更多
A limited understanding of the feeding habits of ecosystem service providers is a notable obstacle to the deployment of natural enemies in pest management.Understanding the dietary diversity of predators can enhance c...A limited understanding of the feeding habits of ecosystem service providers is a notable obstacle to the deployment of natural enemies in pest management.Understanding the dietary diversity of predators can enhance conservation strategies and assess their effects on pest populations.In this study,we used metabarcoding of DNA extracted from the gut contents of an artificially released generalist predator,Eocanthecona furcellata,collected from tobacco cultivation fields in Yunnan Province,China.We aimed to investigate prey composition,selectivity,and efficiency of biological control.Among the individuals of E.furcellata,we detected diverse potential prey,comprising 53 insect species across 28 families and seven orders.Several agricultural pests,including Spodoptera exigua,S.litura,Helicoverpa armigera,and Agrotis segetum,were identified.Diptera are important in the diet of E.furcellata,with 22 species from 14 families accounting for 52.2%of the observed predation events.Eocanthecona furcellata consumed certain beneficial predators present in the tobacco fields,such as carabid beetles,hoverflies,wasps,and lacewings,although the incidence was generally low,except for Syrphidae.Our findings revealed previously unidentified trophic linkages involving E.furcellata with pest species and other biological control agents,as well as highlighting the critical role of neutral insects in shaping the dietary spectrum of E.furcellata in tobacco fields.This study establishes an important foundation for integrating metabarcoding technology into biological control research,particularly for elucidating trophic interactions between natural insect enemies and their prey.展开更多
The effective density(ρ_(eff))is a key parameter of black carbon-containing(BCc)particles and is related to their morphologies,deposition processes,and optical properties.In this study,a tandem system was established...The effective density(ρ_(eff))is a key parameter of black carbon-containing(BCc)particles and is related to their morphologies,deposition processes,and optical properties.In this study,a tandem system was established and used to determine theρ_(eff)of ambient BCc particles.The results showed that theρ_(eff)distribution of ambient BCc particles exhibited a bimodal pattern with a left peak located at 0.69 g cm^(-3)and a right peak at 1.45 g cm^(-3).The averageρ_(eff)of BCc particles over the entire observation period was 1.38 g cm^(-3).Theρ_(eff)of BCc particles showed a clear diurnal pattern with a relatively stable distribution at night and large variations during the daytime.Theρ_(eff)value was demonstrated to be a good indicator of BCc particle morphology.BCc particles became more regular with increasingρ_(eff)related to the increasing coating thickness.More coating led to morphological restructuring of BCc particles.The restructuring could be more efficient under high relative humidity conditions.The observed data were further used in a dry deposition scheme,and it was found that the dry deposition velocity of fresh emitted BCc could be largely influenced by its irregular shape.This study reveals the presence of a significant amount of low-density/irregularly shaped black carbon in the environment with rapid morphological changes occurring during the daytime and highlights the need to consider morphological influences in future research on the physicochemical properties of BCc.展开更多
A new multi-detector array named HALIMA(Hybrid Array for LIfetime MeAsurement)has been developed at Lanzhou for nuclear structure studies in fission.The array comprises eight BGO-shielded High-Purity Germanium detecto...A new multi-detector array named HALIMA(Hybrid Array for LIfetime MeAsurement)has been developed at Lanzhou for nuclear structure studies in fission.The array comprises eight BGO-shielded High-Purity Germanium detectors and twenty fast Ce-doped Lanthanum Bromide[LaBr_(3)(Ce)]detectors shielded with CsI(Tl).HALIMA is further complemented by two ancillary detector systems:fission fragment(FF)detectors and β detectors.This configuration enables precise sub-nanosecond lifetime measurements using the fourfold FF/β-Ge-LaBr_(3)(Ce)-LaBr_(3)(Ce)coincidence technique.The performance and specifications of the detectors,associated electronics,and the data acquisition system are presented in detail.The advantage of FF selectivity is emphasized,which significantly enhances sensitivity to specific fission channels.Using this approach,the lifetimes of the nuclear excited states populated in the spontaneous fission of^(252)Cf were measured,showing good agreement with the established literature values.展开更多
Terahertz biotechnology has been increasingly applied in various biomedical fields and has especially shown great potential for application in brain sciences.In this article,we review the development of terahertz biot...Terahertz biotechnology has been increasingly applied in various biomedical fields and has especially shown great potential for application in brain sciences.In this article,we review the development of terahertz biotechnology and its applications in the field of neuropsychiatry.Available evidence indicates promising prospects for the use of terahertz spectroscopy and terahertz imaging techniques in the diagnosis of amyloid disease,cerebrovascular disease,glioma,psychiatric disease,traumatic brain injury,and myelin deficit.In vitro and animal experiments have also demonstrated the potential therapeutic value of terahertz technology in some neuropsychiatric diseases.Although the precise underlying mechanism of the interactions between terahertz electromagnetic waves and the biosystem is not yet fully understood,the research progress in this field shows great potential for biomedical noninvasive diagnostic and therapeutic applications.However,the biosafety of terahertz radiation requires further exploration regarding its two-sided efficacy in practical applications.This review demonstrates that terahertz biotechnology has the potential to be a promising method in the field of neuropsychiatry based on its unique advantages.展开更多
Using the Herschel ATLAS science demonstration phase data cross- identified with SDSS DR7 spectra, we select 297 galaxies with F250μm 〉 5σ. The sample galaxies are classified into five morphological types, and more...Using the Herschel ATLAS science demonstration phase data cross- identified with SDSS DR7 spectra, we select 297 galaxies with F250μm 〉 5σ. The sample galaxies are classified into five morphological types, and more than 40% of the galaxies are peculiar/compact galaxies. The peculiar galaxies show higher far- infrared/submillimeter luminosity-to-mass ratios than the other types. We perform and analyze the correlations of far-infrared/submillimeter and Hα luminosities for differ- ent morphological types and different spectral types. The Spearman rank coefficient decreases and the scatter increases with the wavelength increasing from 100 μm to 500 μm. We conclude that a single Herschel SPIRE band is not good for tracing star formation activities in galaxies. AGNs contribute less to the far-infrared/submillimeter luminosities and do not show a difference from star-forming galaxies. However, the earlier type galaxies present significant deviations from the best fit of star-forming galaxies.展开更多
The Five-hundred-meter Aperture Spherical radio Telescope(FAST) will make contributions to studies of Galactic and extragalactic masers. This telescope, with construction finished and now undergoing commissioning, has...The Five-hundred-meter Aperture Spherical radio Telescope(FAST) will make contributions to studies of Galactic and extragalactic masers. This telescope, with construction finished and now undergoing commissioning, has an innovative design that leads to the highest sensitivity of any single dish radio telescope in the world. FAST's potential for OH megamaser research is discussed, including the sky density of masers detectable in surveys. The scientific impact expected from FAST maser studies is also discussed.展开更多
The affiliations of several authors were modified during the proofing stage at the request of corresponding author Akon Higuchi,without notifying the involved authors and the Editorial Office.After communication with ...The affiliations of several authors were modified during the proofing stage at the request of corresponding author Akon Higuchi,without notifying the involved authors and the Editorial Office.After communication with all authors,all parties involved agreed to publish this erratum to correct the affiliations and authors.展开更多
A nonlinear multi-scale interaction(NMI)model was proposed and developed by the first author for nearly 30 years to represent the evolution of atmospheric blocking.In this review paper,we first review the creation and...A nonlinear multi-scale interaction(NMI)model was proposed and developed by the first author for nearly 30 years to represent the evolution of atmospheric blocking.In this review paper,we first review the creation and development of the NMI model and then emphasize that the NMI model represents a new tool for identifying the basic physics of how climate change influences mid-to-high latitude weather extremes.The building of the NMI model took place over three main periods.In the 1990s,a nonlinear Schr?dinger(NLS)equation model was presented to describe atmospheric blocking as a wave packet;however,it could not depict the lifetime(10-20 days)of atmospheric blocking.In the 2000s,we proposed an NMI model of atmospheric blocking in a uniform basic flow by making a scale-separation assumption and deriving an eddyforced NLS equation.This model succeeded in describing the life cycle of atmospheric blocking.In the 2020s,the NMI model was extended to include the impact of a changing climate mainly by altering the basic zonal winds and the magnitude of the meridional background potential vorticity gradient(PVy).Model results show that when PVy is smaller,blocking has a weaker dispersion and a stronger nonlinearity,so blocking can be more persistent and have a larger zonal scale and weaker eastward movement,thus favoring stronger weather extremes.However,when PVy is much smaller and below a critical threshold under much stronger winter Arctic warming of global warming,atmospheric blocking becomes locally less persistent and shows a much stronger westward movement,which acts to inhibit local cold extremes.Such a case does not happen in summer under global warming because PVy fails to fall below the critical threshold.Thus,our theory indicates that global warming can render summer-blocking anticyclones and mid-to-high latitude heatwaves more persistent,intense,and widespread.展开更多
This study investigates the mineralogy and mineral-chemistry of a newly discovered Au-Ag-Bi-Te mineralization at the Aydindere Fe-Cu skarn deposit,within the Pontides Tectonic Unit,northeastern Turkey.The mineralizati...This study investigates the mineralogy and mineral-chemistry of a newly discovered Au-Ag-Bi-Te mineralization at the Aydindere Fe-Cu skarn deposit,within the Pontides Tectonic Unit,northeastern Turkey.The mineralization is developed in the skarn zone at the contact between Upper Cretaceous andesite-pyroclastic rocks and a Paleocene–Eocene I-type granitoid.The principal ore minerals of the Aydindere Fe-Cu deposit are oxides(magnetite),sulfides(pyrite-chalcopyritegalena-sphalerite),tellurides/sulfotellurides(tetradymite,hessite),sulfosalts(wittichenite,emplectite,aikinite) and native gold-electrum.Skarn minerals include anhydrous phases(garnet) formed in a prograde stage and hydrous phases(amphibole,epidote,chlorite),which were formed in a retrograde stage in association with quartz,adularia,apatite and late calcite.Sulfides,tellurides and sulfosalts are introduced during the retrograde stage.The Au-Ag-Bi-Te mineralization was detected for the first time within the western ore body of the Aydindere deposit,and occurs in calcite-bearing sulfide bodies that cut magnetite-garnet-amphibole-epidote skarns with magnetite ores of different grade,including massive magnetite.Chlorite geothermometry indicates formation of the Au-Ag-BiTe mineralization at temperatures between 300 and 250 ℃,during the retrograde skarn evolution.Assuming the temperature is ~275 ℃,logfS_(2) =-10.5 to-13,logfO_(2) =-37 to-33,and logf Te2 values range from approximately-12 to-8.5 were estimated.The available mineralogical and geological data(presences of magnetite,oxidized-type tellurides/sulfotellurides,and andraditic garnets,and absence of pyrrhotite and arsenopyrite) suggest that Aydindere is an oxidized Au-bearing skarn deposit.The discovery of Au-Ag-Bi-Te mineralization at Aydindere increases its productivity and requires more detailed exploration in the deposit for precious(Au,Ag) and critical(Bi,Te) metals.展开更多
Arsenic(As)pollution seriously threatens human and ecological health.Microalgal cell wall and extracellular polymeric substances(EPS)are known to interactwith As,but their roles in the As resistance,accumulation and s...Arsenic(As)pollution seriously threatens human and ecological health.Microalgal cell wall and extracellular polymeric substances(EPS)are known to interactwith As,but their roles in the As resistance,accumulation and speciation inmicroalgae remain unclear.Here,we used two strains of Chlamydomonas reinhardtii,namely CC-125(wild type)and CC-503(cell walldeficientmutant),to examine the algal growth,EPS synthesis,As adsorption,absorption and transformation under 10–1000μg/L As(III)and As(V)treatments for 96 h.In both strains,the As absorption increased after the EPS removal,but the growth,As adsorption,and transformation of C.reinhardtii declined.The CC-125 strain was more tolerant to As stress and more efficient in EPS production,As accumulation,and redox transformation than CC-503,irrespective of EPS presence or absence.Three-dimension excitation-emission matrix(3DEEM)and attenuated total reflectance infrared spectroscopy(ATR-IR)analyses showed that As was bound with functional groups in the EPS and cell wall,such as-COOH,NH and-OH in proteins,polysaccharides and amino acids.Together,this study demonstrated that EPS and cell wall acted as barriers to lower the As uptake by C.reinhardtii.However,the cell wall mutant strain wasmore susceptible to As toxicity due to lower EPS induction and higher As absorption.展开更多
The design of efficient and cost‐effective bifunctional catalysts, which are capable of driving both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), is of paramount importance for advancing...The design of efficient and cost‐effective bifunctional catalysts, which are capable of driving both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), is of paramount importance for advancing overall water splitting. Here, we developed an innovative heterogeneous interface engineering strategy to boost the electrocatalytic performance of overall water splitting. This approach involves the synergistic integration of ultra‐fine CoMoP nanocrystals coupled with three‐ dimensional (3D) porous C3N4/N‐doped carbon (NC) architectures, constructing a distinctive CoMoP/C3N4/NC heterogeneous interface. The CoMoP/C3N4/NC exhibits distinguished overall water splitting performance. To drive the overall water splitting current of 10 mA cm−2, the CoMoP/C3N4/NC||CoMoP/C3N4/NC electrolysis cell only needs an ultralow cell voltage of 1.496 V. The electronic properties and localized coordination environments characterizations, and density functional theory (DFT) calculations elucidate that the improved catalytic activities of CoMoP/C3N4/NC are primarily attributed to the synergistic interfacial coupling between CoMoP/C3N4/NC heterogeneous interface. A novel multi‐site synergistic catalytic mechanism was revealed by the DFT calculations, in which the optimum H* adsorption site on CoMoP/C3N4/NC for HER is on the cobalt atoms in CoMoP with the ultralow Gibbs free energy of hydrogen bonding (ΔGH*) of 0.018 eV, while for the OER, the optimum intermediates adsorption site of the CoMoP/C3N4/NC is on the carbon atoms in C3N4/NC. Besides, the intricately engineered 3D hierarchical porous framework of the CoMoP/C3N4/NC can facilitate the ion and electron transport and improve mass transfer, which gives rise to enhanced water splitting performance.展开更多
文摘Based on landscaping practices in the stereo landscape demonstration project of Chongqing Academy of Science and Technology (CAST),current management and maintenance of the stereo landscapes were introduced by analyzing maintenance and management of the plants in the stereo landscape forest.The maintenance and management models were summarized according to the management styles,concrete measures and new technologies were studied,laws and key points for the maintenance and management in different seasons were given,and finally deficiencies and solutions were proposed to improve the future maintenance and management.
文摘T he residual stray magnetic fields present in ferromagnetic casting slabs were investigated in this work,which result from the magnetic fields generated during the steel casting process.Existing optical detection methods face challenges owing to surface oxide scales,and conventional high-precision magnetic sensors are ineffective at high temperatures.To overcome these limitations,a small coil sensor was employed to measure the residual magnetism strength in oscillation traces,using metal magnetic memory and electromagnetic induction methods,which can carry out detection without an external excitation source.Using this technology,the proposed scheme successfully detects defects at high tempe-ratures(up to 670℃)without a cooling device.The key findings include the ability to detect both surface and near-surface defects,such as cracks and oscillation marks,with an enhanced signal-to-noise ratio(SNR)of 7.2 dB after signal processing.The method’s practicality was validated in a steel mill environment,where testing on casting slabs effectively detected defects,providing a foundation for improving industrial quality control.The proposed detection scheme offers a significant advancement in nondestructive testing(NDT)for high-temperature applications,contributing to more efficient and accurate monitoring of ferromagnetic material integrity.
基金Project supported by the National Natural Science Foundation of China(Nos.22071242,21871260)。
文摘Cyclopropenones have been extensively utilized in catalytic ring-opening and ring-expansion reactions for the synthesis of unsaturated carbonyl compounds.The first rhodium-catalyzed ring-opening reaction of aryl-/alkyl-substituted cyclopropenones is accomplished,successfully affording acyloin derivatives.This transformation represents a novel reaction pattern involving cyclopropenones.The resulting acyloin products constitute important building blocks in organic synthesis and serve as fundamental structural frameworks in numerous natural products.
基金supported by the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2020261)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA02010000)the Young Potential Program of the Shanghai Institute of Applied Physics,Chinese Academy of Sciences(No.SINAP-YXJH-202412)。
文摘Knowing the precise relationship between fuel loading and reactivity is essential for guiding reactor criticality extrapolation and online refueling in molten salt reactors(MSRs).This study aims to explore and explain the linear relationship between reactivity and the reciprocal of uranium concentration in thermal-spectrum MSRs.By applying neutron balance theory,we analyzed the neutron absorption cross sections of various nuclides in single-lattice models with varying fuel concentrations.Our findings reveal a simple linear correlation between reactivity and the reciprocal of uranium concentration,which can be explained from the perspective of nuclear reaction cross sections that adhere to the 1/v law in the thermal neutron spectrum.Furthermore,we identified that the neutron absorption single-group cross sections of structural materials and carrier salts exhibit an approximately linear relationship with the fission single-group cross section of ^(235) U;similarly,the reciprocal of ^(235)U’s fission cross section exhibits an approximately linear relationship with uranium concentration.This linear relationship deviates as the volume fraction of molten salt increases,due to a greater proportion of neutrons being captured in the resonance energy spectrum.However,it remains valid for molten salt volume fractions up to 25%and demonstrates broad applicability in the physical design and operation of thermal molten salt reactors.
基金financially supported by the National Key R&D Program of China(Nos.2024YFE0108800,T24KITG-014)the International Partnership Program of Chinese Academy of Sciences(No.172GJHZ2022096FN)。
文摘A novel method called thermomechanical treatment based on impact hydroforming(TTIHF)was proposed.The pre-deformation was achieved by using impact hydroforming(IHF)loading.The strengthening effect and mechanism of 2195 Al-Li alloy were investigated under various loading pre-deformation conditions.The results showed that the time for the alloy to reach peak aging was shortened under TTIHF.Compared with those of the pre-deformation method of stamping forming,the yield strength and tensile strength of the Al-Li alloy under TTIHF increased by 18.6%and 18.0%,respectively.The deformation caused by IHF loading resulted in a high density of dislocations,which served as nucleation sites for the precipitation of the T_(1)phase during aging.After TTIHF,the average diameter and thickness of the T_(1)phase in the alloy were smaller than those under other experiment conditions.Moreover,the density and distribution of the T_(1)phase were the highest and the most uniform.
基金supported by Guangdong Major Project of Basic and Applied Basic Research, China (No. 2020B0301030006)Fundamental Research Funds for the Central Universities, China (No. SWU-XDJH202313)+1 种基金Chongqing Postdoctoral Science Foundation Funded Project, China (No. 2112012728014435)the Chongqing Postgraduate Research and Innovation Project, China (No. CYS23197)。
文摘A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The results show that cold-pressing produces intense plastic deformation near the corrugated surface of the Al plate,which promotes dynamic recrystallization of the Al substrate near the interface during the subsequent hot-pressing.In addition,the initial corrugation on the surface of the Al plate also changes the local stress state near the interface during hot pressing,which has a large effect on the texture components of the substrates near the corrugated interface.The construction of the corrugated interface can greatly enhance the shear strength by 2−4 times due to the increased contact area and the strong“mechanical gearing”effect.Moreover,the mechanical properties are largely depended on the orientation relationship between corrugated direction and loading direction.
基金financially supported by the National Key R&D Program of China(No.2024YFE0108800/T24KITG014)the National Natural Science Foundation of China(No:52475411)the International Partnership Program of Chinese Academy of Sciences(No.172GJHZ2022096FN)。
文摘Taking half-tube part with curvature as an example,the Impact Hydroforming(IHF)characteristics were studied by combining the actual forming experiment and numerical simulation.The IHF experiment showed that wrinkles appeared at the bottom of the part during single-step forming,but no wrinkles were observed during double-step forming.The thinning rate and deviation of the wall thickness of the part in each area were less than 20%and 2.7 mm,correspondingly,and the drawing depth of the part reached 45.8 mm.The effect of double-step forming was better than that of single-step forming,which was related to the IHF forming law.Besides,the characteristics of the IHF process were studied by numerical simulation.The results indicated that when double-step forming was utilized,there was almost no velocity field in the opposite direction of deformation after the bottom of the part contacted the die,and the existence of stress state at the bottom would restrain and eliminate the wrinkles.The inertia effect evolved with the driving pressure.Specially,the inertia effect can improve the flow of metal and reduce the deviation of the wall thickness of the part under double-step forming.
基金financially supported by the National Natural Science Foundation of China(No.22309067)the Open Project Program of the State Key Laboratory of Materials-Oriented Chemical Engineering,China(No.KL21-05)the Marine Equipment and Technology Institute,Jiangsu University of Science and Technology,China(No.XTCX202404)。
文摘This study focused on improving the cathode performance of Ba_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.15)O_(3-δ)(BSCN)-based perovskite materials through molybdenum(Mo)doping.Pure BSCN and Mo-modified-BSCN—Ea_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.1)Mo_(0.05)O_(3-δ)(B S CNM_(0.05)),Ba_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.05)Mo_(0.1)O_(3-δ)(BSCNM_(0.1)),and Ba_(0.6)Sr_(0.4)Co_(0.85)Mo_(0.15)O_(3-δ)(BSCM)—with Mo doping contents of 5mol%,10mol%,and15mol%,respectively,were successfully prepared using the sol-gel method.The effects of Mo doping on the crystal structure,conductivity,thermal expansion coefficient,oxygen reduction reaction(ORR)activity,and electrochemical performance were systematically evaluated using X-ray diffraction analysis,thermally induced characterization,electrochemical impedance spectroscopy,and single-cell performance tests.The results revealed that Mo doping could improve the conductivity of the materials,suppress their thermal expansion effects,and significantly improve the electrochemical performance.Surface chemical state analysis using X-ray photoelectron spectroscopy revealed that 5mol%Mo doping could facilitate a high adsorbed oxygen concentration leading to enhanced ORR activity in the materials.Density functional theory calculations confirmed that Mo doping promoted the ORR activity in the materials.At an operating temperature of 600℃,the BSCNM_(0.05)cathode material exhibited significantly enhanced electrochemical impedance characteristics,with a reduced area specific resistance of 0.048Ω·cm~2,which was lower than that of the undoped BSCN matrix material by 32.39%.At the same operating temperature,an anode-supported single cell using a BSCNM_(0.05)cathode achieved a peak power density of 1477 mW·cm^(-2),which was 30.71%,56.30%,and 171.50%higher than those of BSCN,BSCNM_(0.1),and B SCM,respectively.The improved ORR activity and electrochemical performance of BSCNM_(0.05)indicate that it can be used as a cathode material in low-temperature solid oxide fuel cells.
基金supported by the National Natural Science Foundation of China(No.42272044)the High-performance Computing Platform of China University of Geosciences Beijing。
文摘Polyethylene oxide(PEO)-based solid polymer electrolytes(SPEs)have long faced limitations due to low ionic conductivity at ambient temperature and poor interfacial stability with lithium metal anodes.Here,we present a structural engineering strategy to address these challenges through shear-induced crystallization of concentrated PEO-LiTFSI solutions,which self-assemble into flower-like spherulites with radially aligned lamellar crystals.This unique structure creates continuous Li^(+)transport highways through densely packed crystalline domains,achieving a record-high ionic conductivity of 1.70×10^(-4) S/cm at 25℃ for pristine PEO-based systems.Strategic incorporation of lithium montmorillonite(MMTli,10 wt%)further optimizes the composite electrolyte,balancing high ionic conductivity(1.47×10^(-4) S/cm)with enhanced electrochemical stability(4.99 V vs.Li^(+)/Li),elevated Li^(+)transference number(0.62),and mechanical robustness.The composite electrolyte enables stable Li plating/stripping over 800 h in symmetric Li||Li cells and powers LiFePO_(4)||Li solid-state batteries with 82%capacity retention after 200 cycles at 0.2 C under ambient conditions.This work pioneers a scalable processing paradigm for crystalline polymer electrolytes,offering new insights into ion transport mechanisms and validating clay minerals as multifunctional additives for next-generation energy storage systems.
基金supported by the Pests and Diseases Green Prevention and Control Major Special Project(Nos.110202101049[LS-09],110202201018[LS-02])the Key Project of Science and Technology Plan of Yunnan Company of China National Tobacco Corporation(Nos.2022530000241019,2022530000241021)the 2115 Talent Development Program of China Agricultural University.
文摘A limited understanding of the feeding habits of ecosystem service providers is a notable obstacle to the deployment of natural enemies in pest management.Understanding the dietary diversity of predators can enhance conservation strategies and assess their effects on pest populations.In this study,we used metabarcoding of DNA extracted from the gut contents of an artificially released generalist predator,Eocanthecona furcellata,collected from tobacco cultivation fields in Yunnan Province,China.We aimed to investigate prey composition,selectivity,and efficiency of biological control.Among the individuals of E.furcellata,we detected diverse potential prey,comprising 53 insect species across 28 families and seven orders.Several agricultural pests,including Spodoptera exigua,S.litura,Helicoverpa armigera,and Agrotis segetum,were identified.Diptera are important in the diet of E.furcellata,with 22 species from 14 families accounting for 52.2%of the observed predation events.Eocanthecona furcellata consumed certain beneficial predators present in the tobacco fields,such as carabid beetles,hoverflies,wasps,and lacewings,although the incidence was generally low,except for Syrphidae.Our findings revealed previously unidentified trophic linkages involving E.furcellata with pest species and other biological control agents,as well as highlighting the critical role of neutral insects in shaping the dietary spectrum of E.furcellata in tobacco fields.This study establishes an important foundation for integrating metabarcoding technology into biological control research,particularly for elucidating trophic interactions between natural insect enemies and their prey.
基金supported by the National Key Research and Development Program of China(Grant No.2022YFC3701000,Task 4)the National Natural Science Foundation of China(Grant Nos.42207126 and 41877314)。
文摘The effective density(ρ_(eff))is a key parameter of black carbon-containing(BCc)particles and is related to their morphologies,deposition processes,and optical properties.In this study,a tandem system was established and used to determine theρ_(eff)of ambient BCc particles.The results showed that theρ_(eff)distribution of ambient BCc particles exhibited a bimodal pattern with a left peak located at 0.69 g cm^(-3)and a right peak at 1.45 g cm^(-3).The averageρ_(eff)of BCc particles over the entire observation period was 1.38 g cm^(-3).Theρ_(eff)of BCc particles showed a clear diurnal pattern with a relatively stable distribution at night and large variations during the daytime.Theρ_(eff)value was demonstrated to be a good indicator of BCc particle morphology.BCc particles became more regular with increasingρ_(eff)related to the increasing coating thickness.More coating led to morphological restructuring of BCc particles.The restructuring could be more efficient under high relative humidity conditions.The observed data were further used in a dry deposition scheme,and it was found that the dry deposition velocity of fresh emitted BCc could be largely influenced by its irregular shape.This study reveals the presence of a significant amount of low-density/irregularly shaped black carbon in the environment with rapid morphological changes occurring during the daytime and highlights the need to consider morphological influences in future research on the physicochemical properties of BCc.
基金supported by the National Natural Science Foundation of China(Nos.12275321,12121005,12475129,and 12335009)the Natural Science Foundation of Guangdong Province,China(No.2025A1515012112)+6 种基金the International Atomic Energy Agency Coordinated Research Project F41034(No.28649)the computational resources from Sun Yat-sen University the National Supercomputer Center in Guangzhouthe Open Project of Guangxi Key Laboratory of Nuclear Physics and Nuclear Technology(No.NLK2023-08)the Central Government Guidance Funds for Local Scientific and Technological Development,China(No.Guike ZY22096024)the Guangdong Major Project of Basic and Applied Basic Research(No.2021B0301030006)Young Scientists Fund of the National Natural Science Foundation of China(No.12405144)the National Key Research and Development Program(MOST 2022YFA1602304).
文摘A new multi-detector array named HALIMA(Hybrid Array for LIfetime MeAsurement)has been developed at Lanzhou for nuclear structure studies in fission.The array comprises eight BGO-shielded High-Purity Germanium detectors and twenty fast Ce-doped Lanthanum Bromide[LaBr_(3)(Ce)]detectors shielded with CsI(Tl).HALIMA is further complemented by two ancillary detector systems:fission fragment(FF)detectors and β detectors.This configuration enables precise sub-nanosecond lifetime measurements using the fourfold FF/β-Ge-LaBr_(3)(Ce)-LaBr_(3)(Ce)coincidence technique.The performance and specifications of the detectors,associated electronics,and the data acquisition system are presented in detail.The advantage of FF selectivity is emphasized,which significantly enhances sensitivity to specific fission channels.Using this approach,the lifetimes of the nuclear excited states populated in the spontaneous fission of^(252)Cf were measured,showing good agreement with the established literature values.
基金supported by grants from the National Key R&D Program of China,No.2017YFC0909200(to DC)the National Natural Science Foundation of China,No.62075225(to HZ)+1 种基金Zhejiang Provincial Medical Health Science and Technology Project,No.2023XY053(to ZP)Zhejiang Provincial Traditional Chinese Medical Science and Technology Project,No.2023ZL703(to ZP).
文摘Terahertz biotechnology has been increasingly applied in various biomedical fields and has especially shown great potential for application in brain sciences.In this article,we review the development of terahertz biotechnology and its applications in the field of neuropsychiatry.Available evidence indicates promising prospects for the use of terahertz spectroscopy and terahertz imaging techniques in the diagnosis of amyloid disease,cerebrovascular disease,glioma,psychiatric disease,traumatic brain injury,and myelin deficit.In vitro and animal experiments have also demonstrated the potential therapeutic value of terahertz technology in some neuropsychiatric diseases.Although the precise underlying mechanism of the interactions between terahertz electromagnetic waves and the biosystem is not yet fully understood,the research progress in this field shows great potential for biomedical noninvasive diagnostic and therapeutic applications.However,the biosafety of terahertz radiation requires further exploration regarding its two-sided efficacy in practical applications.This review demonstrates that terahertz biotechnology has the potential to be a promising method in the field of neuropsychiatry based on its unique advantages.
基金supported by the Key Laboratory of Optical Astronomy,National Astronomical Observatories,Chinese Academy of Sciencessupported by the National Natural Science Foundation of China (Grant Nos. 11173030,10833006,10773014 and 11078017)partly supported by the China Ministry of Science and Technology under State Key Development Program for Basic Research (2012CB821800)
文摘Using the Herschel ATLAS science demonstration phase data cross- identified with SDSS DR7 spectra, we select 297 galaxies with F250μm 〉 5σ. The sample galaxies are classified into five morphological types, and more than 40% of the galaxies are peculiar/compact galaxies. The peculiar galaxies show higher far- infrared/submillimeter luminosity-to-mass ratios than the other types. We perform and analyze the correlations of far-infrared/submillimeter and Hα luminosities for differ- ent morphological types and different spectral types. The Spearman rank coefficient decreases and the scatter increases with the wavelength increasing from 100 μm to 500 μm. We conclude that a single Herschel SPIRE band is not good for tracing star formation activities in galaxies. AGNs contribute less to the far-infrared/submillimeter luminosities and do not show a difference from star-forming galaxies. However, the earlier type galaxies present significant deviations from the best fit of star-forming galaxies.
基金supported by the China Ministry of Science and Technology under the National Basic Research Program of China (973 program, 2012CB821800)the National Natural Science Foundation of China (Nos. 11473007, 11373038 and 11590782)supported by the Strategic Priority Research Program (No. XDB09000000) from the Chinese Academy of Sciences
文摘The Five-hundred-meter Aperture Spherical radio Telescope(FAST) will make contributions to studies of Galactic and extragalactic masers. This telescope, with construction finished and now undergoing commissioning, has an innovative design that leads to the highest sensitivity of any single dish radio telescope in the world. FAST's potential for OH megamaser research is discussed, including the sky density of masers detectable in surveys. The scientific impact expected from FAST maser studies is also discussed.
文摘The affiliations of several authors were modified during the proofing stage at the request of corresponding author Akon Higuchi,without notifying the involved authors and the Editorial Office.After communication with all authors,all parties involved agreed to publish this erratum to correct the affiliations and authors.
基金supported by the National Natural Science Foundation of China(Grant Nos.42150204 and 2288101)supported by the China National Postdoctoral Program for Innovative Talents(BX20230045)the China Postdoctoral Science Foundation(2023M730279)。
文摘A nonlinear multi-scale interaction(NMI)model was proposed and developed by the first author for nearly 30 years to represent the evolution of atmospheric blocking.In this review paper,we first review the creation and development of the NMI model and then emphasize that the NMI model represents a new tool for identifying the basic physics of how climate change influences mid-to-high latitude weather extremes.The building of the NMI model took place over three main periods.In the 1990s,a nonlinear Schr?dinger(NLS)equation model was presented to describe atmospheric blocking as a wave packet;however,it could not depict the lifetime(10-20 days)of atmospheric blocking.In the 2000s,we proposed an NMI model of atmospheric blocking in a uniform basic flow by making a scale-separation assumption and deriving an eddyforced NLS equation.This model succeeded in describing the life cycle of atmospheric blocking.In the 2020s,the NMI model was extended to include the impact of a changing climate mainly by altering the basic zonal winds and the magnitude of the meridional background potential vorticity gradient(PVy).Model results show that when PVy is smaller,blocking has a weaker dispersion and a stronger nonlinearity,so blocking can be more persistent and have a larger zonal scale and weaker eastward movement,thus favoring stronger weather extremes.However,when PVy is much smaller and below a critical threshold under much stronger winter Arctic warming of global warming,atmospheric blocking becomes locally less persistent and shows a much stronger westward movement,which acts to inhibit local cold extremes.Such a case does not happen in summer under global warming because PVy fails to fall below the critical threshold.Thus,our theory indicates that global warming can render summer-blocking anticyclones and mid-to-high latitude heatwaves more persistent,intense,and widespread.
文摘This study investigates the mineralogy and mineral-chemistry of a newly discovered Au-Ag-Bi-Te mineralization at the Aydindere Fe-Cu skarn deposit,within the Pontides Tectonic Unit,northeastern Turkey.The mineralization is developed in the skarn zone at the contact between Upper Cretaceous andesite-pyroclastic rocks and a Paleocene–Eocene I-type granitoid.The principal ore minerals of the Aydindere Fe-Cu deposit are oxides(magnetite),sulfides(pyrite-chalcopyritegalena-sphalerite),tellurides/sulfotellurides(tetradymite,hessite),sulfosalts(wittichenite,emplectite,aikinite) and native gold-electrum.Skarn minerals include anhydrous phases(garnet) formed in a prograde stage and hydrous phases(amphibole,epidote,chlorite),which were formed in a retrograde stage in association with quartz,adularia,apatite and late calcite.Sulfides,tellurides and sulfosalts are introduced during the retrograde stage.The Au-Ag-Bi-Te mineralization was detected for the first time within the western ore body of the Aydindere deposit,and occurs in calcite-bearing sulfide bodies that cut magnetite-garnet-amphibole-epidote skarns with magnetite ores of different grade,including massive magnetite.Chlorite geothermometry indicates formation of the Au-Ag-BiTe mineralization at temperatures between 300 and 250 ℃,during the retrograde skarn evolution.Assuming the temperature is ~275 ℃,logfS_(2) =-10.5 to-13,logfO_(2) =-37 to-33,and logf Te2 values range from approximately-12 to-8.5 were estimated.The available mineralogical and geological data(presences of magnetite,oxidized-type tellurides/sulfotellurides,and andraditic garnets,and absence of pyrrhotite and arsenopyrite) suggest that Aydindere is an oxidized Au-bearing skarn deposit.The discovery of Au-Ag-Bi-Te mineralization at Aydindere increases its productivity and requires more detailed exploration in the deposit for precious(Au,Ag) and critical(Bi,Te) metals.
基金supported by the National Natural Science Foundation of China(Nos.32171623 and 31770548)the National Key Research and Development Program of China(Nos.2016YFD0800306 and 2017YFD0800305).
文摘Arsenic(As)pollution seriously threatens human and ecological health.Microalgal cell wall and extracellular polymeric substances(EPS)are known to interactwith As,but their roles in the As resistance,accumulation and speciation inmicroalgae remain unclear.Here,we used two strains of Chlamydomonas reinhardtii,namely CC-125(wild type)and CC-503(cell walldeficientmutant),to examine the algal growth,EPS synthesis,As adsorption,absorption and transformation under 10–1000μg/L As(III)and As(V)treatments for 96 h.In both strains,the As absorption increased after the EPS removal,but the growth,As adsorption,and transformation of C.reinhardtii declined.The CC-125 strain was more tolerant to As stress and more efficient in EPS production,As accumulation,and redox transformation than CC-503,irrespective of EPS presence or absence.Three-dimension excitation-emission matrix(3DEEM)and attenuated total reflectance infrared spectroscopy(ATR-IR)analyses showed that As was bound with functional groups in the EPS and cell wall,such as-COOH,NH and-OH in proteins,polysaccharides and amino acids.Together,this study demonstrated that EPS and cell wall acted as barriers to lower the As uptake by C.reinhardtii.However,the cell wall mutant strain wasmore susceptible to As toxicity due to lower EPS induction and higher As absorption.
基金supported by the National Natural Science Foundation of China(Grant No.12375303)the Natural Science Foundation of Guangdong Province(Grants No.2024A1515030034 and 2023A1515140156).
文摘The design of efficient and cost‐effective bifunctional catalysts, which are capable of driving both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), is of paramount importance for advancing overall water splitting. Here, we developed an innovative heterogeneous interface engineering strategy to boost the electrocatalytic performance of overall water splitting. This approach involves the synergistic integration of ultra‐fine CoMoP nanocrystals coupled with three‐ dimensional (3D) porous C3N4/N‐doped carbon (NC) architectures, constructing a distinctive CoMoP/C3N4/NC heterogeneous interface. The CoMoP/C3N4/NC exhibits distinguished overall water splitting performance. To drive the overall water splitting current of 10 mA cm−2, the CoMoP/C3N4/NC||CoMoP/C3N4/NC electrolysis cell only needs an ultralow cell voltage of 1.496 V. The electronic properties and localized coordination environments characterizations, and density functional theory (DFT) calculations elucidate that the improved catalytic activities of CoMoP/C3N4/NC are primarily attributed to the synergistic interfacial coupling between CoMoP/C3N4/NC heterogeneous interface. A novel multi‐site synergistic catalytic mechanism was revealed by the DFT calculations, in which the optimum H* adsorption site on CoMoP/C3N4/NC for HER is on the cobalt atoms in CoMoP with the ultralow Gibbs free energy of hydrogen bonding (ΔGH*) of 0.018 eV, while for the OER, the optimum intermediates adsorption site of the CoMoP/C3N4/NC is on the carbon atoms in C3N4/NC. Besides, the intricately engineered 3D hierarchical porous framework of the CoMoP/C3N4/NC can facilitate the ion and electron transport and improve mass transfer, which gives rise to enhanced water splitting performance.
