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Spatiotemporal variations of ozone exposure and its risks to vegetation and human health in Cyprus:an analysis across a gradient of altitudes 被引量:2
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作者 Stefanos Agathokleous Costas JSaitanis +3 位作者 Chrysanthos Savvides Pierre Sicard Evgenios Agathokleous Alessandra De Marco 《Journal of Forestry Research》 SCIE CAS CSCD 2023年第3期579-594,共16页
Ground-level ozone(O_(3)) aff ects vegetation and threatens environmental health when levels exceed critical values,above which adverse eff ects are expected.Cyprus is expected to be a hotspot for O_(3)concentrations ... Ground-level ozone(O_(3)) aff ects vegetation and threatens environmental health when levels exceed critical values,above which adverse eff ects are expected.Cyprus is expected to be a hotspot for O_(3)concentrations due to its unique position in the eastern Mediterranean,receiving air masses from Europe,African,and Asian continents,and experiencing a warm Mediterranean climate.In Cyprus,the spatiotemporal features of O_(3) are poorly understood and the potential risks for forest health have not been explored.We evaluated O_(3) and nitrogen oxides(NO and NO 2)at four regional background stations at different altitudes over 2014−2016.O_(3) risks to vegetation and human health were estimated by calculating accumulated O_(3)exposure over a threshold of 40 nmol mol^(−1)(AOT40)and cumulative exposure to mixing ratios above 35 nmol mol^(−1)(SOMO35)indices.The data reveal that mean O_(3)concentrations follow a seasonal pattern,with higher levels in spring(51.8 nmol mol^(−1))and summer(53.2 nmol mol^(−1))and lower levels in autumn(46.9 nmol mol^(−1))and winter(43.3 nmol mol^(−1)).The highest mean O_(3)exposure(59.5 nmol mol^(−1)) in summer occurred at the high elevation station Mt.Troodos(1819 m a.s.l.).Increasing(decreasing)altitudinal gradients were found for O_(3)(NO x),driven by summer–winter diff erences.The diurnal patterns of O_(3) showed little variation.Only at the lowest altitude O_(3) displayed a typical O_(3) diurnal pattern,with hourly diff erences smaller than 15 nmol mol^(−1).Accumulated O_(3) exposures at all stations and in all years exceeded the European Union’s limits for the protection of vegetation,with average values of 3-month(limit:3000 nmol mol^(−1)h)and 6-month(limit:5000 nmol mol^(−1)h)AOT40 for crops and forests of 16,564 and 31,836 nmol mol^(−1)h,respectively.O_(3) exposures were considerably high for human health,with an average SOMO35 value of 7270 nmol mol^(−1) days across stations and years.The results indicate that O_(3) is a major environmental and public health issue in Cyprus,and policies must be adopted to mitigate O_(3) precursor emissions at local and regional scales. 展开更多
关键词 Air pollution Ozone risk assessment Exposure metrics VEGETATION Human health
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Testing visible ozone injury within a Light Exposed Sampling Site as a proxy for ozone risk assessment for European forests 被引量:1
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作者 Pierre Sicard Yasutomo Hoshika +2 位作者 Elisa Carrari Alessandra De Marco Elena Paoletti 《Journal of Forestry Research》 SCIE CAS CSCD 2021年第4期1351-1359,共9页
Biologically meaningful and cost-effective indicators are needed for assessing and monitoring the impacts of tropospheric ozone(0_(3)) on vegetation and are required in Europe by the National Emission Ceilings Directi... Biologically meaningful and cost-effective indicators are needed for assessing and monitoring the impacts of tropospheric ozone(0_(3)) on vegetation and are required in Europe by the National Emission Ceilings Directive(2016).However,a clear understanding on the best suited indicators is missing.The MOTTLES(MOnitoring ozone injury for seTTing new critical LEvelS) project set up a new generation network for 0_(3) monitoring in forest plots in order to:1) estimate the stomatal 0_(3) fluxes(Phytotoxic Ozone Dose above a threshold Y of uptake,PODY);and 2) collect visible foliar 0_(3) injury,both within the forest plot(ITP) and along the Light Exposed Sampling Site(LESS) along the forest edge.Nine forest sites at high 0_(3) risk were selected across Italy over 2017-2019 and significant correlations(p <0.05) were found between the percentage of symptomatic plant species within the LESS,and POD1(PODY,with Y=1 nmol 0_(3) m^(-2) s^(-1)) calculated for mixed forest species(r=0.53)and with the occurrence and severity of visible foliar 0_(3) injury on the dominant species in the plots(r=0.65).A generic flux-based critical level for mixed forest species was derived within the LESS and it was recommended using11 mmol m^(-2) POD1 as the critical level for forest protection against 0_(3) injury,similar to the critical level obtained in the ITP(12 mmol m^(-2) POD1).It was concluded that the frequency of symptomatic plant species within a LESS is a suitable and effective plant-response indicator of phytotoxic 0_(3) levels in forest monitoring.LESS is a non-destructive,less complex and less time-consuming approach compared to the ITP for monitoring foliar 0_(3) injury in the long term.Assessing visible foliar 0_(3) injury in the ITP might only underestimate the 0_(3) risk assessment at individual sites.These results are biologically meaningful and useful to monitoring experts and environmental policy makers. 展开更多
关键词 Cost-effective indicator Forest monitoring Light-Exposed Sampling Site OZONE Phytotoxic ozone dose Visible injury
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A spectral response approach for detecting dominant phytoplankton size class from satellite remote sensing 被引量:2
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作者 Robert J W Brewin Samantha J Lavender +1 位作者 Nick J Hardman-Mountford Takafumi Hirata 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2010年第2期14-32,共19页
An important goal in ocean colour remote sensing is to accurately detect different phytoplankton groups with the potential uses including the validation of multi-phytoplankton carbon cycle models; synoptically monitor... An important goal in ocean colour remote sensing is to accurately detect different phytoplankton groups with the potential uses including the validation of multi-phytoplankton carbon cycle models; synoptically monitoring the health of our oceans, and improving our understanding of the bio-geochemical interactions between phytoplankton and their environment. In this paper a new algorithm is developed for detecting three dominant phytoplankton size classes based on distinct differences in their optical signatures. The technique is validated against an independent coupled satellite reflectance and in situ pigment dataset and run on the 10-year NASA Sea viewing Wide Field of view Sensor (SeaWiFS) data series. Results indicate that on average 3.6% of the global oceanic surface layer is dominated by microplankton, 18.0% by nanoplankton and 78.4% by pieoplankton. Results, however, are seen to vary depending on season and ocean basin. 展开更多
关键词 phytoplankton size remote sensing ABSORPTION ocean colour SEAWIFS
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Epidemiological derivation of fl ux-based critical levels for visible ozone injury in European forests 被引量:1
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作者 Pierre Sicard Alessandra De Marco +8 位作者 Elisa Carrari Laurence Dalstein-Richier Yasutomo Hoshika Ovidiu Badea Diana Pitar Silvano Fares Adriano Conte Ionel Popa Elena Paoletti 《Journal of Forestry Research》 SCIE CAS CSCD 2020年第5期1509-1519,共11页
The European MOTTLES project set-up a newgeneration network for ozone(O 3)monitoring in 17 plots in France,Italy and Romania.These monitoring stations allowed:(1)estimating the accumulated exposure AOT40 and stomatal ... The European MOTTLES project set-up a newgeneration network for ozone(O 3)monitoring in 17 plots in France,Italy and Romania.These monitoring stations allowed:(1)estimating the accumulated exposure AOT40 and stomatal O 3 fl uxes(PODY)with an hourly threshold of uptake(Y)to represent the detoxifi cation capacity of trees(POD1,with Y=1 nmol O 3 m^−2 s^−1 per leaf area);and(2)collecting data of forest-response indicators,i.e.crown defoliation and visible foliar O 3-like injury over the time period 2017–2019.The soil water content was the most important parameter aff ecting crown defoliation and was a key factor aff ecting the severity of visible foliar O 3-like injury on the dominant tree species in a plot.The soil water content is thus an essential parameter in the PODY estimation,particularly for water-limited environments.An assessment based on stomatal fl ux-based standard and on real plant symptoms is more appropriated than the exposure-based method for protecting vegetation.From fl ux-eff ect relationships,we derived fl ux-based critical levels(CLef)for forest protection against visible foliar O 3-like injury.We recommend CLef of 5 and 12 mmol m^−2 POD1 for broadleaved species and conifers,respectively.Before using PODY as legislative standard in Europe,we recommend using the CLec for≥25%of crown defoliation in a plot:17,000 and 19,000 nmol mol^−1 h AOT40 for conifers and broadleaved species,respectively. 展开更多
关键词 POD Critical levels OZONE Visible injury Epidemiology
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isoAOT40:An improved ozone exposure index based on the Annual Ozone Spectrum Profile(AO3SP) 被引量:1
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作者 Evgenios Agathokleous Costas J.Saitanis +3 位作者 Stefanos Agathokleous Chrysanthos Savvides Vicent Calatayud Pierre Sicard 《Journal of Forestry Research》 SCIE CAS CSCD 2022年第6期1949-1955,共7页
Abstarct In recognition of the rising threats of groundlevel ozone(O_(3))pollution to forests,agricultural crops,and other types of vegetation,accurate and realistic risk assessment is urgently needed.The accumulated ... Abstarct In recognition of the rising threats of groundlevel ozone(O_(3))pollution to forests,agricultural crops,and other types of vegetation,accurate and realistic risk assessment is urgently needed.The accumulated O_(3)exposure over a concentration threshold of 40 nmol mol-1(AOT40)is the most commonly used metric to investigate O3 exposure and its effects on vegetation and to conduct vegetation risk assessment.It is also used by international regulatory authorities for deriving critical levels and setting standards to protect vegetation against surface O_(3).However,fixed periods of the growing season are used universally,yet growing seasons vary with latitudes and elevations,and the periods of plant lifespan also differ among annual species.Here,we propose the concept of the Annual O_(3)Spectrum Profile(AO_(3)SP)and apply it to calculate the profile of AOT40 throughout the year(AAOT40SP,Annual AOT40 Spectrum Profile)using the International Organization for Standardization(ISO)weeks as a shorter window ISO-based accumulated exposure.Using moving time periods of three(for crops)or six(for forests)months,the i so AOT40 behavior throughout the year can be examined as a diagnostic tool for O_(3)risks in the short-or long-term during the lifecycle of local vegetation.From this analysis,AOT40(i so AOT40)that is most representative for the local conditions and specific situations can be identified,depending on the exact growing season and lifecycle of the target vegetation.We applied this novel approach to data from five background monitoring stations located at different elevations in Cyprus.Our results show that the AAOT40SP approach can be used for improved and more realistic assessment of O3 risks to vegetation.The AO_(3)SP approach can also be applied using metrics other than AOT40(exposure-or flux-based),adding a new dimension to the way O_(3)risk to vegetation is assessed. 展开更多
关键词 Air pollution AOT40 index Ozone risk assessment Critical levels Vegetation exposure metric
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Towards an integrative approach to evaluate the environmental ecosystem services provided by urban forest 被引量:1
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作者 Samson Roeland Marco Moretti +11 位作者 Jorge Humberto Amorim Cristina Branquinho Silvano Fares Federico Morelli Ulo Niinemets Elena Paoletti Pedro Pinho Gregorio Sgrigna Vladimir Stojanovski Abhishek Tiwary Pierre Sicard Carlo Calfapietra 《Journal of Forestry Research》 SCIE CAS CSCD 2019年第6期1981-1996,共16页
As a Nature-Based Solution,urban forests deliver a number of environmental ecosystem services(EESs).To quantify these EESs,well-defined,reliable,quantifiable and stable indicators are needed.With literature analysis a... As a Nature-Based Solution,urban forests deliver a number of environmental ecosystem services(EESs).To quantify these EESs,well-defined,reliable,quantifiable and stable indicators are needed.With literature analysis and expert knowledge gathered within COST Action FP1204 GreenInUrbs,we proposed a classification of urban forest EESs into three categories:(A)regulation of air,water,soil and climate;(B)provisioning of habitat quality;and(C)provisioning of other goods and services.Each category is divided into EES types:(a)amelioration of air quality;restoration of soil and water;amelioration of the microclimate;removal of CO2 from the air;(b)provision of habitat for biodiversity;support for resilient urban ecosystems;provision of genetic diversity;and(c)provision of energy and nutrients;provision of grey infrastructure resilience.Each EES type provides one or more benefits.For each of these 12 benefits,we propose a set of indicators to be used when analyzing the impacts on the identified EESs.Around half of the 36 indicators are relevant to more than one single benefit,which highlights complex interrelationships.The indicators of wider applicability are tree and stand characteristics,followed by leaf physical traits and tree species composition.This knowledge is needed for the optimization of the EESs delivered by urban forests,now and in the future. 展开更多
关键词 URBAN FORESTS Environmental ECOSYSTEM services INDICATORS
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Ozone pollution threatens bird populations to collapse:an imminent ecological threat?
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作者 Evgenios Agathokleous Pierre Sicard +1 位作者 Zhaozhong Feng Elena Paoletti 《Journal of Forestry Research》 SCIE CAS CSCD 2023年第6期1653-1656,共4页
While bird populations are declining,the factors associated with this decline are unclear.Based on laboratory experiments,air pollution has long been recognized as a factor causing oxidative stress and adversely aff e... While bird populations are declining,the factors associated with this decline are unclear.Based on laboratory experiments,air pollution has long been recognized as a factor causing oxidative stress and adversely aff ecting bird health.Recently,studies employing an epidemiological approach have reported signifi cant declines in avian populations in Central Europe and the United States due to air pollution,and ozone in particular.We advocate that urgent actions are needed to mitigate these eff ects,which threaten biodiversity and environmental health,and propose a series of measures which can enlighten the path toward mitigating air pollution eff ects on avian populations. 展开更多
关键词 Air pollution BIOSECURITY Bird population BIODIVERSITY ORNITHOLOGY Ozone risk
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Trends in tropospheric ozone concentrations and forest impact metrics in Europe over the time period 2000–2014
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作者 Chiara Proietti Maria Francesca Fornasier +3 位作者 Pierre Sicard Alessandro Anav Elena Paoletti Alessandra De Marco 《Journal of Forestry Research》 SCIE CAS CSCD 2021年第2期543-551,共9页
In Europe,tropospheric ozone pollution appears as a major air quality issue,and ozone concentrations remain potentially harmful to vegetation.In this study we compared the trends of two ozone metrics widely used for f... In Europe,tropospheric ozone pollution appears as a major air quality issue,and ozone concentrations remain potentially harmful to vegetation.In this study we compared the trends of two ozone metrics widely used for forests protection in Europe,the AOT40(Accumulated Ozone over Threshold of 40 ppb)which only depends on surface air ozone concentrations,and the Phytotoxic Ozone Dose which is the accumulated ozone uptake through stomata over the growing season,and above a threshold Y of uptake(PODY).By using a chemistry transport model,we found that European-averaged ground-level ozone concentrations(−2%)and AOT40 metric(−26.5%)significantly declined from 2000 to 2014,due to successful control strategies to reduce the emission of ozone precursors in Europe since the early 1990s.In contrast,the stomatal ozone uptake by forests increased from 17.5 to 26.6 mmol O3 m^(−2)despite the reduction in ozone concentrations,leading to an increase of potential ozone damage on plants in Europe.In a climate change context,a biologically-sound stomatal flux-based standard(PODY)as new European legislative standard is needed. 展开更多
关键词 Tropospheric ozone AOT40 POD Trendm Mann-Kendall test
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Correction To: Epidemiological derivation of flux-based critical levels for visible ozone injury in European forests
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作者 Pierre Sicard Alessandra De Marco +8 位作者 Elisa Carrari Laurence Dalstein-Richier Yasutomo Hoshika Ovidiu Badea Diana Pitar Silvano Fares Adriano Conte Ionel Popa Elena Paoletti 《Journal of Forestry Research》 SCIE CAS CSCD 2022年第5期1703-1703,共1页
Correction to:J.For.Res.https://doi.org/10.1007/s11676-020-01191-x In the Original publication of the article,the authors found an error in the text“We recommend CLef of 5 and 12 mmol m−2 POD1 for broadleaved species... Correction to:J.For.Res.https://doi.org/10.1007/s11676-020-01191-x In the Original publication of the article,the authors found an error in the text“We recommend CLef of 5 and 12 mmol m−2 POD1 for broadleaved species and conifers,respectively”under the section abstract and conclusion. 展开更多
关键词 OZONE VISIBLE DERIVATION
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Practical Method Proposed to Estimate Silting’s Rate in Small and Hillside Dams
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作者 Naima Alahiane Ahmed El Mouden +1 位作者 Abderrahmane Ait Lhaj Said Boutaleb 《Journal of Water Resource and Protection》 2014年第10期930-943,共14页
The construction of small dams and hillside reservoirs is a common practice for dealing with erratic and unevenly distributed rainfalls in arid and semi arid areas. Moreover, these small hydraulics structures are reco... The construction of small dams and hillside reservoirs is a common practice for dealing with erratic and unevenly distributed rainfalls in arid and semi arid areas. Moreover, these small hydraulics structures are recommended as a solution to adapt to climate change in rural areas. They are fundamental for the sustainability of the water resources. However, these dams are potential sinks for upstream sediment. Therefore, it would be useful to monitor and measure the amount of sediments in small dams because it is necessary to understand siltation and better functioning of these vital structures. This control and these measurements require the application of the bathymetry or topography surveys which is too expensive for the responsible of these small dams. In this context, this paper proposes a simple and low cost method called: Triangulation of the estimated silted level. This method is based on direct measurement of the accessible silted level in dam. This new method is compared with another method based on the initial Elevation-Capacity curve of dam, usually used when the bathymetry is not attainable. The results of both of them have been verified with those of the bathymetry and electrical tomography methods and validated the proposal method as the most approximate. Therefore, this method is recommended as a new direct and simple technique to evaluate the amount of silting in small dams and hillside reservoirs. 展开更多
关键词 SMALL DAMS Evaluate Silting BATHYMETRY TRIANGULATION
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ASYMMETRIC SYNTHESIS OF 2-ALKYLALKANOIC ACIDS VIA ALKYLATION OF CHIRAL AMIDE ANIONS
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作者 林国强 HANS-ERIC HGBERG TORBJRN NORIN 《Chinese Science Bulletin》 SCIE EI CAS 1984年第5期632-634,共3页
In connection with the current work on the synthesis of chiral insect pheromones, general methods for the preparation of chiral 2-alkylalkanoic acids were needed. Several such methods have recently been described. Mey... In connection with the current work on the synthesis of chiral insect pheromones, general methods for the preparation of chiral 2-alkylalkanoic acids were needed. Several such methods have recently been described. Meyers found that alkylation of chiral oxazoline anions followed by hydrolysis of the products gave chiral acids. 展开更多
关键词 CHIRAL hydrolysis AMIDE esters ALKYL reagent insect ammonium instead HYDROXIDE
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Bridging experimental and monitoring research for visible foliar injury as bio-indicator of ozone impacts on forests
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作者 Barbara Baesso Moura Elisa Carrari +8 位作者 Laurence Dalstein-Richier Pierre Sicard Stefan Leca Ovidiu Badea Diana Pitar-Silaghi Anumol Shashikumar Marie-Lyne Ciriani Elena Paoletti Yasutomo Hoshika 《Ecosystem Health and Sustainability》 SCIE 2022年第1期295-309,共15页
Tropospheric ozone(O_(3))is a phytotoxic air pollutant and the O_(3)-induced visible foliar injury(O_(3)VFI)is a biomarker.A recently developed Free-air O_(3)eXposure(FO_(3)X)is a promising facility to verify field-ob... Tropospheric ozone(O_(3))is a phytotoxic air pollutant and the O_(3)-induced visible foliar injury(O_(3)VFI)is a biomarker.A recently developed Free-air O_(3)eXposure(FO_(3)X)is a promising facility to verify field-observed“O_(3)-like”VFIs and to establish a flux-based threshold for the O_(3)VFI onset.The present study compared O_(3)-like VFI registered in the southern European forest sites with actual O_(3)VFI observed in a FO_(3)X experiment.The O_(3)-like VFIs were evaluated by eye in forests and thus it was subjective.According to the imaging analysis,we firstly demonstrated that major parts of the colors were similar in the field and the FO_(3)X.The color pallets for O_(3)VFI was species-specific and considered a advanced tool for the O_(3)VFI diagnosis.In addition,we calculated a flux-based threshold for the O_(3)VFI onset at the FO_(3)X based on a Phytotoxic Ozone Dose(POD_(1)),which ranged from 4.9 to 18.1 mmol m^(-2)POD1.This FO_(3)X-derived threshold partly explained but did not necessarily match with the observation for several tree species in actual forests.The multivariate analysis showed that O_(3)VFI was decreased by the presence of various species and suggested the importance of continuous monitoring activities in the field for the further analysis. 展开更多
关键词 OZONE visible foliar injury FO3X MOTTLES forest monitoring
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