The solubility and supersolubility of 3,4-bis(3-nitrofurazan-4-yl)furoxan(DNTF) in ethanol + water at different operation were determined by laser monitoring system under atmospheric pressure to study the metastable z...The solubility and supersolubility of 3,4-bis(3-nitrofurazan-4-yl)furoxan(DNTF) in ethanol + water at different operation were determined by laser monitoring system under atmospheric pressure to study the metastable zone width(MSZW). The modified Apelblat equation was adopted to correlate the experimental solubility data, and the correlation result showed perfect consistent with the experimental data. The standard dissolution enthalpy, standard dissolution entropy and Gibbs energy were calculated according to the experimental solubility data. The effect of the cooling rate, stirring rate, temperature and the concentration of ethanol + water on the MSZW was studied. It was found that the MSZW of DNTF increased with the increasing cooling rate, decreasing temperature, decreasing stirring rate and decreasing ratio of water. And the apparent nucleation order of DNTF in ethanol + water was calculated by the relationship between the cooling rate and the MSZW.展开更多
The equilibrium solubility of 2,4-diaminobenzenesulfonic acid and super solubility as well as metastable zone width were measured in(H_(2)SO_(4)+H_(2)O) system by the laser dynamic method at elevate temperature range ...The equilibrium solubility of 2,4-diaminobenzenesulfonic acid and super solubility as well as metastable zone width were measured in(H_(2)SO_(4)+H_(2)O) system by the laser dynamic method at elevate temperature range from 298.15 K to 338.15 K.2,4-Diaminobenzenesulfonic acid solubility dependence on the temperature and solvent composition were correlated by the modified Apelblat equation,(CNIBS)/Redlich-Kister model and Jouyban-Acree model.The correlated results by three correlation models were in good accord with the experimental values according to relative average deviations(RD),root-mean-square deviations(RMSD),and correlation coefficients(R^(2)).The metastable zone width increased with temperature and sulfuric acid content.The dissolution enthalpy,dissolution entropy and the Gibbs energy were calculated from the experimental values,which indicated that dissolution process of the 2,4-diaminobenzenesulfonic acid was endothermic.The solubility and calculation models of 2,4-diaminobenzenesulfonic acid in(sulfuric acid+water)system could provide the basic data to the crystallization and purifying of the 2,4-diaminobenzenesulfonic acid.展开更多
Slow evaporation method was used to grow pure and KCl (10 mol%) doped KAP single crystal. The solubility and metastable zone width of aqueous solutions of pure and KCl (10 mol%) doped KAP crystal were evaluated to ana...Slow evaporation method was used to grow pure and KCl (10 mol%) doped KAP single crystal. The solubility and metastable zone width of aqueous solutions of pure and KCl (10 mol%) doped KAP crystal were evaluated to analyze the crystallization process. Measuring the induction period τ, the critical nucleation parameters like interfacial energy (σ), energy of formation of the critical nucleus (ΔG*) were determined using the classical theory of nucleation. The structural properties and optical constants of the grown crystals have been put to test and observed that the addition of KCl results in an enhancement of properties of the crystal. Grown crystals were characterized by powder X-ray diffraction. FTIR spectra confirmed the presence of KCl in pure KAP crystal. UV- Visible spectroscopic studies revealed that addition of KCl in pure KAP crystal increased transparency from 75% to 80%. The analysis of the optical absorption data revealed the presence of both indirect and direct transitions and both of these band gaps increased with the addition of KCl. The transmittance data was analyzed to calculate the refractive index, oscillator energy, dispersion energy, electric susceptibility, zero-frequency dielectric constant and both the real and imaginary parts of the dielectric permittivity as a function of photon energy. The moments of ε(E) were also determined. The dispersion i.e. spectral dependence of the refractive index was discussed according to the single-effective oscillator model proposed by Wemple and DiDomenico.展开更多
Shielded Metal Arc Welding (SMAW) in Ductile Irons (DI) is often required by foundries for practical manufacturing reasons. The mechanical properties of the welded structures are strongly dependent on their HAZ’s wid...Shielded Metal Arc Welding (SMAW) in Ductile Irons (DI) is often required by foundries for practical manufacturing reasons. The mechanical properties of the welded structures are strongly dependent on their HAZ’s width. A model based on the behaviour of the ferritic matrix of high-Si DIs in order to make an approach in measuring their HAZ’s width is developed in this study. A series of thermal treatments on 3.35 and 3.75 wt% Si as-cast DIs and spot SMAWs is applied on these materials. The applied SMAWs are done on non-preheated and preheated samples (150℃ - 300℃). For welding we modify the amperage (100 - 140A). The micro-hardness Vickers changes in the ferrite of the as-cast samples and inside the HAZ of the welded ones can be attributed to the existence of residual stresses (RS) in the ferritic matrix and assist in estimating the HAZ’s width.展开更多
Overstress in the surrounding rock of the roadway is a key reason that causes failures of deep roadways. Destressing blasting is one of the promising techniques that could improve the supporting quality. If the depth ...Overstress in the surrounding rock of the roadway is a key reason that causes failures of deep roadways. Destressing blasting is one of the promising techniques that could improve the supporting quality. If the depth of the pressure relief blast hole is too shallow, the surrounding rock of the roadway will be broken or even collapsed. If the pressure relief blast hole is too deep, the pressure relief area will be located in the deep part of the surrounding rock of the roadway, which cannot achieve the purpose of releasing the stress in the shallow part of the surrounding rock and cause waste of the blast hole. The width or range of the pressure relief area should just fall in the high stress area of the surrounding rock of the roadway, so the pressure relief blast hole should have a reasonable depth. In order to quantitatively describe the relationship between borehole depth and the width of the stress relief zone, numerical simulations were carried out in ANSYS according to different borehole depths. The results show that the optimal destressing effect is achieved when borehole depth is 4 m. Peak stress of and is significantly reduced by 30.51% and 49.07% after blasting. Meanwhile, the high-stress area shifts about 4.8 m from the roadside to the depth of surrounding rock, thus a 3.8 m wide stress relief zone is formed around the roadside, thus, the aim of quantizing the effects of destress blasting is achieved.展开更多
In this article,we review our previous research for spatial and temporal characterizations of the San Andreas Fault(SAF)at Parkfield,using the fault-zone trapped wave(FZTW)since the middle 1980s.Parkfield,California h...In this article,we review our previous research for spatial and temporal characterizations of the San Andreas Fault(SAF)at Parkfield,using the fault-zone trapped wave(FZTW)since the middle 1980s.Parkfield,California has been taken as a scientific seismic experimental site in the USA since the 1970s,and the SAF is the target fault to investigate earthquake physics and forecasting.More than ten types of field experiments(including seismic,geophysical,geochemical,geodetic and so on)have been carried out at this experimental site since then.In the fall of 2003,a pair of scientific wells were drilled at the San Andreas Fault Observatory at Depth(SAFOD)site;the main-hole(MH)passed a~200-m-wide low-velocity zone(LVZ)with highly fractured rocks of the SAF at a depth of~3.2 km below the wellhead on the ground level(Hickman et al.,2005;Zoback,2007;Lockner et al.,2011).Borehole seismographs were installed in the SAFOD MH in 2004,which were located within the LVZ of the fault at~3-km depth to probe the internal structure and physical properties of the SAF.On September 282004,a M6 earthquake occurred~15 km southeast of the town of Parkfield.The data recorded in the field experiments before and after the 2004 M6 earthquake provided a unique opportunity to monitor the co-mainshock damage and post-seismic heal of the SAF associated with this strong earthquake.This retrospective review of the results from a sequence of our previous experiments at the Parkfield SAF,California,will be valuable for other researchers who are carrying out seismic experiments at the active faults to develop the community seismic wave velocity models,the fault models and the earthquake forecasting models in global seismogenic regions.展开更多
The tunnel subjected to strike-slip fault dislocation exhibits severe and catastrophic damage.The existing analysis models frequently assume uniform fault displacement and fixed fault plane position.In contrast,post-e...The tunnel subjected to strike-slip fault dislocation exhibits severe and catastrophic damage.The existing analysis models frequently assume uniform fault displacement and fixed fault plane position.In contrast,post-earthquake observations indicate that the displacement near the fault zone is typically nonuniform,and the fault plane position is uncertain.In this study,we first established a series of improved governing equations to analyze the mechanical response of tunnels under strike-slip fault dislocation.The proposed methodology incorporated key factors such as nonuniform fault displacement and uncertain fault plane position into the governing equations,thereby significantly enhancing the applicability range and accuracy of the model.In contrast to previous analytical models,the maximum computational error has decreased from 57.1%to 1.1%.Subsequently,we conducted a rigorous validation of the proposed methodology by undertaking a comparative analysis with a 3D finite element numerical model,and the results from both approaches exhibited a high degree of qualitative and quantitative agreement with a maximum error of 9.9%.Finally,the proposed methodology was utilized to perform a parametric analysis to explore the effects of various parameters,such as fault displacement,fault zone width,fault zone strength,the ratio of maximum fault displacement of the hanging wall to the footwall,and fault plane position,on the response of tunnels subjected to strike-slip fault dislocation.The findings indicate a progressive increase in the peak internal forces of the tunnel with the rise in fault displacement and fault zone strength.Conversely,an augmentation in fault zone width is found to contribute to a decrease in the peak internal forces.For example,for a fault zone width of 10 m,the peak values of bending moment,shear force,and axial force are approximately 46.9%,102.4%,and 28.7% higher,respectively,compared to those observed for a fault zone width of 50 m.Furthermore,the position of the peak internal forces is influenced by variations in the ratio of maximum fault displacement of the hanging wall to footwall and the fault plane location,while the peak values of shear force and axial force always align with the fault plane.The maximum peak internal forces are observed when the footwall exclusively bears the entirety of the fault displacement,corresponding to a ratio of 0:1.The peak values of bending moment,shear force,and axial force for the ratio of 0:1 amount to approximately 123.8%,148.6%,and 111.1% of those for the ratio of 0.5:0.5,respectively.展开更多
In this study, we determined fnax from near- field accelerograms of the Lushan earthquake of April 20, 2013 through spectra analysis. The result shows that the values of fmax derived from five different seismography s...In this study, we determined fnax from near- field accelerograms of the Lushan earthquake of April 20, 2013 through spectra analysis. The result shows that the values of fmax derived from five different seismography stations are very close though these stations roughly span about 100 km along the strike. This implies that the cause offmax is mainly the seismic source process rather than the site effect. Moreover, according to the source-cause model of Papageorgiou and Aki （Bull Seism Soc Am 73：693-722, 1983）, we infer that the cohesive zone width of the rupture of the Lushan earthquake is about 204 with an uncertainty of 13 m. We also find that there is a significant bulge between 30 and 45 Hz in the amplitude spectra of accel- erograms of stations 51YAL and 51QLY, and we confirm that it is due to seismic waves＇ reverberation of the sedi- mentary soil layer beneath these stations.展开更多
文摘The solubility and supersolubility of 3,4-bis(3-nitrofurazan-4-yl)furoxan(DNTF) in ethanol + water at different operation were determined by laser monitoring system under atmospheric pressure to study the metastable zone width(MSZW). The modified Apelblat equation was adopted to correlate the experimental solubility data, and the correlation result showed perfect consistent with the experimental data. The standard dissolution enthalpy, standard dissolution entropy and Gibbs energy were calculated according to the experimental solubility data. The effect of the cooling rate, stirring rate, temperature and the concentration of ethanol + water on the MSZW was studied. It was found that the MSZW of DNTF increased with the increasing cooling rate, decreasing temperature, decreasing stirring rate and decreasing ratio of water. And the apparent nucleation order of DNTF in ethanol + water was calculated by the relationship between the cooling rate and the MSZW.
基金supported by Scientific and Technologial Innovation Programs of Higher Education Institutions in Shanxi。
文摘The equilibrium solubility of 2,4-diaminobenzenesulfonic acid and super solubility as well as metastable zone width were measured in(H_(2)SO_(4)+H_(2)O) system by the laser dynamic method at elevate temperature range from 298.15 K to 338.15 K.2,4-Diaminobenzenesulfonic acid solubility dependence on the temperature and solvent composition were correlated by the modified Apelblat equation,(CNIBS)/Redlich-Kister model and Jouyban-Acree model.The correlated results by three correlation models were in good accord with the experimental values according to relative average deviations(RD),root-mean-square deviations(RMSD),and correlation coefficients(R^(2)).The metastable zone width increased with temperature and sulfuric acid content.The dissolution enthalpy,dissolution entropy and the Gibbs energy were calculated from the experimental values,which indicated that dissolution process of the 2,4-diaminobenzenesulfonic acid was endothermic.The solubility and calculation models of 2,4-diaminobenzenesulfonic acid in(sulfuric acid+water)system could provide the basic data to the crystallization and purifying of the 2,4-diaminobenzenesulfonic acid.
文摘Slow evaporation method was used to grow pure and KCl (10 mol%) doped KAP single crystal. The solubility and metastable zone width of aqueous solutions of pure and KCl (10 mol%) doped KAP crystal were evaluated to analyze the crystallization process. Measuring the induction period τ, the critical nucleation parameters like interfacial energy (σ), energy of formation of the critical nucleus (ΔG*) were determined using the classical theory of nucleation. The structural properties and optical constants of the grown crystals have been put to test and observed that the addition of KCl results in an enhancement of properties of the crystal. Grown crystals were characterized by powder X-ray diffraction. FTIR spectra confirmed the presence of KCl in pure KAP crystal. UV- Visible spectroscopic studies revealed that addition of KCl in pure KAP crystal increased transparency from 75% to 80%. The analysis of the optical absorption data revealed the presence of both indirect and direct transitions and both of these band gaps increased with the addition of KCl. The transmittance data was analyzed to calculate the refractive index, oscillator energy, dispersion energy, electric susceptibility, zero-frequency dielectric constant and both the real and imaginary parts of the dielectric permittivity as a function of photon energy. The moments of ε(E) were also determined. The dispersion i.e. spectral dependence of the refractive index was discussed according to the single-effective oscillator model proposed by Wemple and DiDomenico.
文摘Shielded Metal Arc Welding (SMAW) in Ductile Irons (DI) is often required by foundries for practical manufacturing reasons. The mechanical properties of the welded structures are strongly dependent on their HAZ’s width. A model based on the behaviour of the ferritic matrix of high-Si DIs in order to make an approach in measuring their HAZ’s width is developed in this study. A series of thermal treatments on 3.35 and 3.75 wt% Si as-cast DIs and spot SMAWs is applied on these materials. The applied SMAWs are done on non-preheated and preheated samples (150℃ - 300℃). For welding we modify the amperage (100 - 140A). The micro-hardness Vickers changes in the ferrite of the as-cast samples and inside the HAZ of the welded ones can be attributed to the existence of residual stresses (RS) in the ferritic matrix and assist in estimating the HAZ’s width.
文摘Overstress in the surrounding rock of the roadway is a key reason that causes failures of deep roadways. Destressing blasting is one of the promising techniques that could improve the supporting quality. If the depth of the pressure relief blast hole is too shallow, the surrounding rock of the roadway will be broken or even collapsed. If the pressure relief blast hole is too deep, the pressure relief area will be located in the deep part of the surrounding rock of the roadway, which cannot achieve the purpose of releasing the stress in the shallow part of the surrounding rock and cause waste of the blast hole. The width or range of the pressure relief area should just fall in the high stress area of the surrounding rock of the roadway, so the pressure relief blast hole should have a reasonable depth. In order to quantitatively describe the relationship between borehole depth and the width of the stress relief zone, numerical simulations were carried out in ANSYS according to different borehole depths. The results show that the optimal destressing effect is achieved when borehole depth is 4 m. Peak stress of and is significantly reduced by 30.51% and 49.07% after blasting. Meanwhile, the high-stress area shifts about 4.8 m from the roadside to the depth of surrounding rock, thus a 3.8 m wide stress relief zone is formed around the roadside, thus, the aim of quantizing the effects of destress blasting is achieved.
文摘In this article,we review our previous research for spatial and temporal characterizations of the San Andreas Fault(SAF)at Parkfield,using the fault-zone trapped wave(FZTW)since the middle 1980s.Parkfield,California has been taken as a scientific seismic experimental site in the USA since the 1970s,and the SAF is the target fault to investigate earthquake physics and forecasting.More than ten types of field experiments(including seismic,geophysical,geochemical,geodetic and so on)have been carried out at this experimental site since then.In the fall of 2003,a pair of scientific wells were drilled at the San Andreas Fault Observatory at Depth(SAFOD)site;the main-hole(MH)passed a~200-m-wide low-velocity zone(LVZ)with highly fractured rocks of the SAF at a depth of~3.2 km below the wellhead on the ground level(Hickman et al.,2005;Zoback,2007;Lockner et al.,2011).Borehole seismographs were installed in the SAFOD MH in 2004,which were located within the LVZ of the fault at~3-km depth to probe the internal structure and physical properties of the SAF.On September 282004,a M6 earthquake occurred~15 km southeast of the town of Parkfield.The data recorded in the field experiments before and after the 2004 M6 earthquake provided a unique opportunity to monitor the co-mainshock damage and post-seismic heal of the SAF associated with this strong earthquake.This retrospective review of the results from a sequence of our previous experiments at the Parkfield SAF,California,will be valuable for other researchers who are carrying out seismic experiments at the active faults to develop the community seismic wave velocity models,the fault models and the earthquake forecasting models in global seismogenic regions.
基金Projects(52378411,52208404)supported by the National Natural Science Foundation of China。
文摘The tunnel subjected to strike-slip fault dislocation exhibits severe and catastrophic damage.The existing analysis models frequently assume uniform fault displacement and fixed fault plane position.In contrast,post-earthquake observations indicate that the displacement near the fault zone is typically nonuniform,and the fault plane position is uncertain.In this study,we first established a series of improved governing equations to analyze the mechanical response of tunnels under strike-slip fault dislocation.The proposed methodology incorporated key factors such as nonuniform fault displacement and uncertain fault plane position into the governing equations,thereby significantly enhancing the applicability range and accuracy of the model.In contrast to previous analytical models,the maximum computational error has decreased from 57.1%to 1.1%.Subsequently,we conducted a rigorous validation of the proposed methodology by undertaking a comparative analysis with a 3D finite element numerical model,and the results from both approaches exhibited a high degree of qualitative and quantitative agreement with a maximum error of 9.9%.Finally,the proposed methodology was utilized to perform a parametric analysis to explore the effects of various parameters,such as fault displacement,fault zone width,fault zone strength,the ratio of maximum fault displacement of the hanging wall to the footwall,and fault plane position,on the response of tunnels subjected to strike-slip fault dislocation.The findings indicate a progressive increase in the peak internal forces of the tunnel with the rise in fault displacement and fault zone strength.Conversely,an augmentation in fault zone width is found to contribute to a decrease in the peak internal forces.For example,for a fault zone width of 10 m,the peak values of bending moment,shear force,and axial force are approximately 46.9%,102.4%,and 28.7% higher,respectively,compared to those observed for a fault zone width of 50 m.Furthermore,the position of the peak internal forces is influenced by variations in the ratio of maximum fault displacement of the hanging wall to footwall and the fault plane location,while the peak values of shear force and axial force always align with the fault plane.The maximum peak internal forces are observed when the footwall exclusively bears the entirety of the fault displacement,corresponding to a ratio of 0:1.The peak values of bending moment,shear force,and axial force for the ratio of 0:1 amount to approximately 123.8%,148.6%,and 111.1% of those for the ratio of 0.5:0.5,respectively.
基金supported by the National Nature Science Foundation of China(Grant numbers:41090293,41274053)
文摘In this study, we determined fnax from near- field accelerograms of the Lushan earthquake of April 20, 2013 through spectra analysis. The result shows that the values of fmax derived from five different seismography stations are very close though these stations roughly span about 100 km along the strike. This implies that the cause offmax is mainly the seismic source process rather than the site effect. Moreover, according to the source-cause model of Papageorgiou and Aki （Bull Seism Soc Am 73：693-722, 1983）, we infer that the cohesive zone width of the rupture of the Lushan earthquake is about 204 with an uncertainty of 13 m. We also find that there is a significant bulge between 30 and 45 Hz in the amplitude spectra of accel- erograms of stations 51YAL and 51QLY, and we confirm that it is due to seismic waves＇ reverberation of the sedi- mentary soil layer beneath these stations.
