High-purity indium finds extensive application in the aerospace,electronics,medical,energy,and national defense sectors.Its purity and impurity contents significantly influence its performance in these applications.Hi...High-purity indium finds extensive application in the aerospace,electronics,medical,energy,and national defense sectors.Its purity and impurity contents significantly influence its performance in these applications.High-purity indium was prepared by combining zone refining with vacuum distillation.Results show that the average removal efficiency of impurity Sb can approach 95%,while the removal efficiency of impurities Sn and Bi can reach over 95%,and the removal efficiency of Si,Fe,Ni,and Pb can reach over 85%.Ultimately,the amount of Sn and Sb impurities is reduced to 2.0 and 4.1μg/kg,respectively,and that of most impurities,including Fe,Ni,Pb,and Bi,is reduced to levels below the instrumental detection limit.The average impurity removal efficiency is 90.9%,and the indium purity reaches 7N9.展开更多
Effective distribution coefficients of 9 impurities in 1,2-diphenylethane have been calculated by directional crystallization under different ambient frozen temperature.The effect of varied zone size,temperature diffe...Effective distribution coefficients of 9 impurities in 1,2-diphenylethane have been calculated by directional crystallization under different ambient frozen temperature.The effect of varied zone size,temperature difference between the melt and ambient frozen environment,number of zone on purity of 1,2-diphenylethane have been also investigated during the process of zone refining.The results indicate that the product purity in the intermediate purified region with varied zone size is higher 0.04%–0.2%than that with constant zone size.The product purity increases with temperature difference between the melt and ambient frozen environment.The appropriate temperature difference is adopted 50°C.The product purity in the intermediate region of sample bar with 2 molten zones is higher 0.05%–0.43%than that with 1 molten zone.In addition,the change of enthalpy and entropy between impurities and 1,2-diphenylethane have been determined.展开更多
Three-dimensional thermal a nalysis simulation of a horizontal zone refining system is conducted for germanimn semiconductor materials. The considered geometry includes a g＇ral）hite boat filled with germanium placed...Three-dimensional thermal a nalysis simulation of a horizontal zone refining system is conducted for germanimn semiconductor materials. The considered geometry includes a g＇ral）hite boat filled with germanium placed in a cylindrical quartz tube. A flow of Ar and H2 gas mixture is purged througll the tube. A narrow section of the, boat is assmned to be exposed to a constant heat rate produced b v an rf coil located outside the quartz tube. The results of this analysis provide essential information about various parameters such as the shape of tile molten zone, required power and temperature gradient in the system.展开更多
The effective segregation coefficient K-e of oxygen in terbium metal was deduced from a comparison of the theoretical curves with the concentration distributions found experimentally after a floating zone refining tre...The effective segregation coefficient K-e of oxygen in terbium metal was deduced from a comparison of the theoretical curves with the concentration distributions found experimentally after a floating zone refining treatment. Thp result shows that K-e is equal to 1.2 which is an important parameter for floating zone refining terbium.展开更多
基金National Key Research and Development Program of China(2023YFC2907904)National Natural Science Foundation of China(52374364)。
文摘High-purity indium finds extensive application in the aerospace,electronics,medical,energy,and national defense sectors.Its purity and impurity contents significantly influence its performance in these applications.High-purity indium was prepared by combining zone refining with vacuum distillation.Results show that the average removal efficiency of impurity Sb can approach 95%,while the removal efficiency of impurities Sn and Bi can reach over 95%,and the removal efficiency of Si,Fe,Ni,and Pb can reach over 85%.Ultimately,the amount of Sn and Sb impurities is reduced to 2.0 and 4.1μg/kg,respectively,and that of most impurities,including Fe,Ni,Pb,and Bi,is reduced to levels below the instrumental detection limit.The average impurity removal efficiency is 90.9%,and the indium purity reaches 7N9.
文摘Effective distribution coefficients of 9 impurities in 1,2-diphenylethane have been calculated by directional crystallization under different ambient frozen temperature.The effect of varied zone size,temperature difference between the melt and ambient frozen environment,number of zone on purity of 1,2-diphenylethane have been also investigated during the process of zone refining.The results indicate that the product purity in the intermediate purified region with varied zone size is higher 0.04%–0.2%than that with constant zone size.The product purity increases with temperature difference between the melt and ambient frozen environment.The appropriate temperature difference is adopted 50°C.The product purity in the intermediate region of sample bar with 2 molten zones is higher 0.05%–0.43%than that with 1 molten zone.In addition,the change of enthalpy and entropy between impurities and 1,2-diphenylethane have been determined.
文摘Three-dimensional thermal a nalysis simulation of a horizontal zone refining system is conducted for germanimn semiconductor materials. The considered geometry includes a g＇ral）hite boat filled with germanium placed in a cylindrical quartz tube. A flow of Ar and H2 gas mixture is purged througll the tube. A narrow section of the, boat is assmned to be exposed to a constant heat rate produced b v an rf coil located outside the quartz tube. The results of this analysis provide essential information about various parameters such as the shape of tile molten zone, required power and temperature gradient in the system.
文摘The effective segregation coefficient K-e of oxygen in terbium metal was deduced from a comparison of the theoretical curves with the concentration distributions found experimentally after a floating zone refining treatment. Thp result shows that K-e is equal to 1.2 which is an important parameter for floating zone refining terbium.
