As a complementary analysis tool to conventional high-field nuclear magnetic resonance(NMR),zero-to ultralow-field(ZULF)NMR detects nuclear magnetization signals in the sub-microtesla regime.Spin-exchange relaxation-f...As a complementary analysis tool to conventional high-field nuclear magnetic resonance(NMR),zero-to ultralow-field(ZULF)NMR detects nuclear magnetization signals in the sub-microtesla regime.Spin-exchange relaxation-free(SERF)atomic magnetometers provide a new generation of sensitive detectors for ZULF NMR.Owing to features such as low cost,high resolution,and portability,ZULF NMR has recently attracted considerable attention in chemistry,biology,medicine,and tests of fundamental physics.This review describes the basic principles,methodology,and recent experimental and theoretical development of ZULF NMR as well as its applications in spectroscopy,quantum control,imaging,NMR-based quantum devices,and tests of fundamental physics.The future prospects of ZULF NMR are also discussed.展开更多
Zero-and ultralow-field nuclear magnetic resonance(ZULF NMR)has experienced rapid development and provides an excellent tool for diverse research fields ranging from materials science and quantum information processin...Zero-and ultralow-field nuclear magnetic resonance(ZULF NMR)has experienced rapid development and provides an excellent tool for diverse research fields ranging from materials science and quantum information processing to fundamental physics.The detection of ZULF NMR signals in samples with natural abundance remains a challenging endeavor,due to the limited sensitivity of NMR detectors and thermal polarization.In this work,we demonstrate a femtotesla(fT)Potassium spin-exchange relaxation-free(SERF)magnetometer designed for ZULF NMR detection.A Potassium vapor cell with high buffer gas pressure and high atomic number density is used in the magnetometer.With absorption spectroscopy and SERF effect,the key parameters of the vapor cell are characterized and applied to optimize the magnetometer sensitivity.To combine our SERF magnetometer and ZULF NMR detection,a custom-made vacuum chamber is employed to keep NMR sample close to the magnetometer cell and protect the sample from undesired heating effects.Gradiometric measurement is performed to greatly reduce the magnetic noise.With the phase calibration applied,the gradiometric measurement achieves 7-fold enhancement in magnetic-field sensitivity compared to the single channel and has a magnetic noise floor of 1.2 fT/Hz^(1/2).Our SERF magnetometer exhibits high sensitivity and is promising to realize ZULF NMR detection of samples with natural abundance.展开更多
基金This work was supported by National Key Research and Development Program of China(Grant no.2018YFA0306600)National Natural Science Foun-dation of China(Grants nos.11661161018,11927811)+1 种基金Anhui Initia-tive in Quantum Information Technologies(Grant No.AHY050000)USTC Research Funds of the Double First-Class Initiative(Grant no.YD3540002002).
文摘As a complementary analysis tool to conventional high-field nuclear magnetic resonance(NMR),zero-to ultralow-field(ZULF)NMR detects nuclear magnetization signals in the sub-microtesla regime.Spin-exchange relaxation-free(SERF)atomic magnetometers provide a new generation of sensitive detectors for ZULF NMR.Owing to features such as low cost,high resolution,and portability,ZULF NMR has recently attracted considerable attention in chemistry,biology,medicine,and tests of fundamental physics.This review describes the basic principles,methodology,and recent experimental and theoretical development of ZULF NMR as well as its applications in spectroscopy,quantum control,imaging,NMR-based quantum devices,and tests of fundamental physics.The future prospects of ZULF NMR are also discussed.
基金supported by National Science Foundation of China(Grant Nos.T2388102,11927811,92476204,12150014,12205296,12274395,and 12261160569)Innovation Program for Quantum Science and Technology(Grant No.2021ZD0303205)+1 种基金Youth Innovation Promotion Association(Grant No.2023474)Chinese Academy of Sciences Magnetic Resonance Technology Alliance Research Instrument and Equipment Development/Functional Development(Grant No.2022GZL003).
文摘Zero-and ultralow-field nuclear magnetic resonance(ZULF NMR)has experienced rapid development and provides an excellent tool for diverse research fields ranging from materials science and quantum information processing to fundamental physics.The detection of ZULF NMR signals in samples with natural abundance remains a challenging endeavor,due to the limited sensitivity of NMR detectors and thermal polarization.In this work,we demonstrate a femtotesla(fT)Potassium spin-exchange relaxation-free(SERF)magnetometer designed for ZULF NMR detection.A Potassium vapor cell with high buffer gas pressure and high atomic number density is used in the magnetometer.With absorption spectroscopy and SERF effect,the key parameters of the vapor cell are characterized and applied to optimize the magnetometer sensitivity.To combine our SERF magnetometer and ZULF NMR detection,a custom-made vacuum chamber is employed to keep NMR sample close to the magnetometer cell and protect the sample from undesired heating effects.Gradiometric measurement is performed to greatly reduce the magnetic noise.With the phase calibration applied,the gradiometric measurement achieves 7-fold enhancement in magnetic-field sensitivity compared to the single channel and has a magnetic noise floor of 1.2 fT/Hz^(1/2).Our SERF magnetometer exhibits high sensitivity and is promising to realize ZULF NMR detection of samples with natural abundance.
