Detonation performance is crucial for evaluating the power of high explosives(HEs),and the equation of state(EOS)that accurately describes the high-temperature,high-pressure,and high-temperature,medium-pressure states...Detonation performance is crucial for evaluating the power of high explosives(HEs),and the equation of state(EOS)that accurately describes the high-temperature,high-pressure,and high-temperature,medium-pressure states of detonation products is key to assessing the damage efficiency of these energetic materials.This article examines the limitations of the VLW EOS in representing the thermodynamic states of explosive detonation gas products under high-temperature and medium-to high-pressure conditions.A new gas EOS for detonation products,called VHL(Virial-Han-Long),is proposed.The accuracy of VHL in describing gas states under high-temperature and medium-to high-pressure conditions is verified,and its performance in evaluating explosive detonation and working capabilities is explored.The results demonstrate that VHL exhibits high precision in calculating detonation performance.Subsequently,the detonation performance of three new HEs(ICM-101,ONC,and TNAZ)was calculated and compared to traditional HEs(TATB,CL-20,and HMX).The results indicate that ONC has superior detonation performance compared to the other explosives,while ICM-101 shows a detonation velocity similar to CL-20 but with slightly lower detonation pressure.The detonation characteristics of TNAZ are comparable to those of the standard HE HMX.From the perspective of products,considering the comprehensive work performance(mechanical work and detonation heat),both ONC and ICM-101demonstrate relatively superior performance.展开更多
The popularity of flexible working hours around the world has slowed down the historical trend of reducing working hours.It even shows signs of regression.Whether and how to guide the cur-rent society with flexible wo...The popularity of flexible working hours around the world has slowed down the historical trend of reducing working hours.It even shows signs of regression.Whether and how to guide the cur-rent society with flexible working hours to return to the historical track of reducing working hours,improve the quality of working hours,and promote a smooth transition from the era of traditional standard work-ing hours to the era of flexible working hours has become a question related to the legal regulation of working hours in the new era.In this regard,although Western countries have proposed new regulatory concepts and carried out legislative practices with distinctive charac-teristics,the limitations of legal regulation capabilities have prevented them from proposing a package of institutional solutions.The advan-tage of China in the ability of legal regulation of working hours has been gradually formed in the legislation on working hours unnder the leadership of the CPC in the past century.It enables China to break through the limitations of the West and propose a Chinese approach to answer the question of the legal regulation of working hours in the new era from three aspects:limiting the extension of working hours,improving the quality of flexible working hours,and optimizing the funnctions of the multi-funnctional regulatory system for working hours.展开更多
Precipitation strengthening has been widely adopted in austenitic low-density steel owing to excellent hardened effects.This approach generally employs the coherentκ′carbides and non-coherent B2 particles.Revealing ...Precipitation strengthening has been widely adopted in austenitic low-density steel owing to excellent hardened effects.This approach generally employs the coherentκ′carbides and non-coherent B2 particles.Revealing the precipitation transformation pathway is decisive for further optimizing the microstructures under specific engineering applications.Herein,the detailed precipitation sequence of Fe-28Mn-11Al-1C-5Ni(wt%)austenitic low-density steel as well as its influence on mechanical prop-erties during aging process is systematically investigated.Our results reveal that nano-sizedκ′carbides domains(2 nm)exist in the solution-treated specimen.During aging at 500℃for 1 h,the cuboidalκ′carbides(15-20 nm)uniformly disperse in austenite matrix.However,after aging at 700℃for 15 min,the coarsenκ′carbides(30-35 nm)inhomogeneously distribute and align preferentially along the〈100〉directions.Further,extending the aging time to 60 min,the needle-type B2 particles replace theκ′carbides due to the enrichment of Ni elements at the phase boundaries among the austenite andκ′carbides.After aging at 900℃,κ′carbides entirely dissolve into the austenite matrix,and the intragranular B2 particles are the sole precipitates in the austenite matrix and follow the K-S orientation relationship with austenite.The work hardening capability seriously deteriorates due to the shearing ofκ′carbides by gliding dislocations.While the intragranular B2 particles preserve excellent work hardening rate by dislocations bow-out mechanism.The present work is meaningful for guiding the design of new generation dual-nano precipitation austenitic lightweight steel.展开更多
Strength-ductility trade-off is usually an inevitable scenario inκ′-carbides strengthened austenitic lightweight steel.The reduction of ductility is primarily attributed to the shearing of coherentκ′-carbides by d...Strength-ductility trade-off is usually an inevitable scenario inκ′-carbides strengthened austenitic lightweight steel.The reduction of ductility is primarily attributed to the shearing of coherentκ′-carbides by dislocations,resulting in strain localization and ultimately leading to a low work hardening rate.Semicoherent B2 particles,on the other hand,effectively enhance the work hardening capability due to the non-shearable feature.However,achieving a large volume fraction and uniform distribution of B2 particles within the austenite matrix,as well as optimizing their morphology as fine particles,remains a challenge for austenitic lightweight steel.In this study,we have addressed the above challenges by implementing the two-step aging process combined with pre-cold rolling process.The pre-cold rolling treatment,performed prior to the initial aging treatment at 900℃,effectively promotes the heterogeneous nucleation of B2 particles by introducing dislocations,resulting in a more uniform distribution of B2 particles and a refinement in size(with an average length of 200–500 nm and a width of 50–80 nm).Furthermore,these intragranular B2 particles exhibit the typical K-S and N-W orientation relationships with the austenite matrix.Subsequently,after the second-step aging process at 450℃,spherical nano-sizedκ′-carbides(5 nm)are homogeneously dispersed within the austenite matrix.The above dual nanoparticles provide an approximate precipitation hardening effect of 400 MPa.Concurrently,the nanoscale“planar slip and dislocation bow-out”multiple deformation mechanisms contribute to an efficient source of work hardening capability,leading to a beneficial synergy of strength-ductility.This promising strategy is expected to expand the applications of dual-nanoprecipitation austenitic low-density steel in various lightweight structural materials.展开更多
基金supported by the National Natural Science Foundation of China(Gant Nos.11372291 and 11902298)。
文摘Detonation performance is crucial for evaluating the power of high explosives(HEs),and the equation of state(EOS)that accurately describes the high-temperature,high-pressure,and high-temperature,medium-pressure states of detonation products is key to assessing the damage efficiency of these energetic materials.This article examines the limitations of the VLW EOS in representing the thermodynamic states of explosive detonation gas products under high-temperature and medium-to high-pressure conditions.A new gas EOS for detonation products,called VHL(Virial-Han-Long),is proposed.The accuracy of VHL in describing gas states under high-temperature and medium-to high-pressure conditions is verified,and its performance in evaluating explosive detonation and working capabilities is explored.The results demonstrate that VHL exhibits high precision in calculating detonation performance.Subsequently,the detonation performance of three new HEs(ICM-101,ONC,and TNAZ)was calculated and compared to traditional HEs(TATB,CL-20,and HMX).The results indicate that ONC has superior detonation performance compared to the other explosives,while ICM-101 shows a detonation velocity similar to CL-20 but with slightly lower detonation pressure.The detonation characteristics of TNAZ are comparable to those of the standard HE HMX.From the perspective of products,considering the comprehensive work performance(mechanical work and detonation heat),both ONC and ICM-101demonstrate relatively superior performance.
基金funded by the National Social Science Fund of China (Western Region Program)“Research on Improving the Quality of Legislation in China on Rest and Vacation from a Global Perspective”(Project Approval Number:19XFX014)。
文摘The popularity of flexible working hours around the world has slowed down the historical trend of reducing working hours.It even shows signs of regression.Whether and how to guide the cur-rent society with flexible working hours to return to the historical track of reducing working hours,improve the quality of working hours,and promote a smooth transition from the era of traditional standard work-ing hours to the era of flexible working hours has become a question related to the legal regulation of working hours in the new era.In this regard,although Western countries have proposed new regulatory concepts and carried out legislative practices with distinctive charac-teristics,the limitations of legal regulation capabilities have prevented them from proposing a package of institutional solutions.The advan-tage of China in the ability of legal regulation of working hours has been gradually formed in the legislation on working hours unnder the leadership of the CPC in the past century.It enables China to break through the limitations of the West and propose a Chinese approach to answer the question of the legal regulation of working hours in the new era from three aspects:limiting the extension of working hours,improving the quality of flexible working hours,and optimizing the funnctions of the multi-funnctional regulatory system for working hours.
基金supported by the National Natural Science Foundation of China(Nos.52171105 and 51871062).
文摘Precipitation strengthening has been widely adopted in austenitic low-density steel owing to excellent hardened effects.This approach generally employs the coherentκ′carbides and non-coherent B2 particles.Revealing the precipitation transformation pathway is decisive for further optimizing the microstructures under specific engineering applications.Herein,the detailed precipitation sequence of Fe-28Mn-11Al-1C-5Ni(wt%)austenitic low-density steel as well as its influence on mechanical prop-erties during aging process is systematically investigated.Our results reveal that nano-sizedκ′carbides domains(2 nm)exist in the solution-treated specimen.During aging at 500℃for 1 h,the cuboidalκ′carbides(15-20 nm)uniformly disperse in austenite matrix.However,after aging at 700℃for 15 min,the coarsenκ′carbides(30-35 nm)inhomogeneously distribute and align preferentially along the〈100〉directions.Further,extending the aging time to 60 min,the needle-type B2 particles replace theκ′carbides due to the enrichment of Ni elements at the phase boundaries among the austenite andκ′carbides.After aging at 900℃,κ′carbides entirely dissolve into the austenite matrix,and the intragranular B2 particles are the sole precipitates in the austenite matrix and follow the K-S orientation relationship with austenite.The work hardening capability seriously deteriorates due to the shearing ofκ′carbides by gliding dislocations.While the intragranular B2 particles preserve excellent work hardening rate by dislocations bow-out mechanism.The present work is meaningful for guiding the design of new generation dual-nano precipitation austenitic lightweight steel.
基金supported by the National Natural Science Foundation of China(Nos.52171105 and 51871062).
文摘Strength-ductility trade-off is usually an inevitable scenario inκ′-carbides strengthened austenitic lightweight steel.The reduction of ductility is primarily attributed to the shearing of coherentκ′-carbides by dislocations,resulting in strain localization and ultimately leading to a low work hardening rate.Semicoherent B2 particles,on the other hand,effectively enhance the work hardening capability due to the non-shearable feature.However,achieving a large volume fraction and uniform distribution of B2 particles within the austenite matrix,as well as optimizing their morphology as fine particles,remains a challenge for austenitic lightweight steel.In this study,we have addressed the above challenges by implementing the two-step aging process combined with pre-cold rolling process.The pre-cold rolling treatment,performed prior to the initial aging treatment at 900℃,effectively promotes the heterogeneous nucleation of B2 particles by introducing dislocations,resulting in a more uniform distribution of B2 particles and a refinement in size(with an average length of 200–500 nm and a width of 50–80 nm).Furthermore,these intragranular B2 particles exhibit the typical K-S and N-W orientation relationships with the austenite matrix.Subsequently,after the second-step aging process at 450℃,spherical nano-sizedκ′-carbides(5 nm)are homogeneously dispersed within the austenite matrix.The above dual nanoparticles provide an approximate precipitation hardening effect of 400 MPa.Concurrently,the nanoscale“planar slip and dislocation bow-out”multiple deformation mechanisms contribute to an efficient source of work hardening capability,leading to a beneficial synergy of strength-ductility.This promising strategy is expected to expand the applications of dual-nanoprecipitation austenitic low-density steel in various lightweight structural materials.
