Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing addit...Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing additive-induced defects,and alleviating residual stress and deformation,all of which are critical for enhancing the mechanical performance of the manufactured parts.Integrating interlayer friction stir processing(FSP)into WAAM significantly enhances the quality of deposited materials.However,numerical simulation research focusing on elucidating the associated thermomechanical coupling mechanisms remains insufficient.A comprehensive numerical model was developed to simulate the thermomechanical coupling behavior in friction stir-assisted WAAM.The influence of post-deposition FSP on the coupled thermomechanical response of the WAAM process was analyzed quantitatively.Moreover,the residual stress distribution and deformation behavior under both single-layer and multilayer deposition conditions were investigated.Thermal analysis of different deposition layers in WAAM and friction stir-assisted WAAM was conducted.Results show that subsequent layer deposition induces partial remelting of the previously solidified layer,whereas FSP does not cause such remelting.Furthermore,thermal stress and deformation analysis confirm that interlayer FSP effectively mitigates residual stresses and distortion in WAAM components,thereby improving their structural integrity and mechanical properties.展开更多
We present the first systematic experimental validation of return-current-driven cylindrical implosion scaling in micrometer-sized Cu and Al wires irradiated by J-class femtosecond laser pulses.Employing XFEL-based im...We present the first systematic experimental validation of return-current-driven cylindrical implosion scaling in micrometer-sized Cu and Al wires irradiated by J-class femtosecond laser pulses.Employing XFEL-based imaging with sub-micrometer spatial and femtosecond temporal resolution,supported by hydrodynamic and particle-in-cell simulations,we reveal how return current density depends precisely on wire diameter,material properties,and incident laser energy.We identify deviations from simple theoretical predictions due to geometrically influenced electron escape dynamics.These results refine and confirm the scaling laws essential for predictive modeling in high-energy-density physics and inertial fusion research.展开更多
In this study,multilayer lamination welding was employed to prepare graphene/copper(Gr/Cu)composite billets from graphene-coated copper foils,followed by multi-pass cold drawing to produce Φ1 mm Gr/Cu composite wires...In this study,multilayer lamination welding was employed to prepare graphene/copper(Gr/Cu)composite billets from graphene-coated copper foils,followed by multi-pass cold drawing to produce Φ1 mm Gr/Cu composite wires.Microstructure and property analyses in both the cold-drawn and annealed states show that the incorporation of graphene significantly improves the ductility and electrical conductivity of the copper wire.After annealing at 350℃ for 30 minutes,the composite wire demonstrates a tensile strength of 270 MPa and an electrical conductivity of 102.74%IACS,both superior to those of pure copper wire under identical conditions.At 150℃,the electrical conductivity of the annealed composite wire reaches 72.60%IACS,notably higher than the 68.19%IACS of pure copper.The results suggest that graphene is uniformly distributed within the composite wire,with minimal impact on conductivity,while effectively refining the copper grain structure to enhance ductility.Moreover,graphene suppresses copper lattice vibrations at elevated temperatures,reducing the rate of conductivity degradation.展开更多
Osmotic energy,existing between the seawater and river water,is a renewable energy source,which can be directly converted into electricity by ion-exchange membranes(IEM).In traditional IEMs,the ion transport channels ...Osmotic energy,existing between the seawater and river water,is a renewable energy source,which can be directly converted into electricity by ion-exchange membranes(IEM).In traditional IEMs,the ion transport channels are formed by nanophase separation of hydrophilic ion carriers and hydrophobic segments.It is difficult to realize high-density ion channels with controlled spatial arrangement and length scale of ion carriers.Herein,we construct high-density 1D ion wires as transmission channels.Through molecular design,hydrophilic imidazole groups and hydrophobic alkyl tails were introduced into the repeat units,which self-assembled into 1D ion transporting core and protecting shell along the main chains.The areal density of the ionic wire arrays is up to~10^(12)cm^(-2),which is the highest value.The ionic wires ensure both high ion flux transport and high selectivity,achieving an ultrahigh-power density of 40.5 W m^(-2)at a 500-fold salinity gradient.Besides,the ionic wire array membrane is well recyclable and antibacterial.The ionic wires provide novel concept for next generation of high-performance membranes.展开更多
Giant magnetoimpedance(GMI)sensors are increasingly employed in modern magnetic sensing technologies.However,improving the GMI performance of magnetic cores remains challenging due to intrinsic limitations in material...Giant magnetoimpedance(GMI)sensors are increasingly employed in modern magnetic sensing technologies.However,improving the GMI performance of magnetic cores remains challenging due to intrinsic limitations in material properties and structural stability.In this work,we explore the use of Joule heating to enhance the GMI response of Fe_(20)Ni_(80)/Cu composite wires.By applying a current of 1.8 A for 10 min,notable improvements in magnetic domain uniformity and a reduction in domain spacing are observed.Under these conditions,GMI ratios reach 1870% in the non-diagonal mode and1147%in the diagonal mode,respectively,highlighting their potential for applications in high-precision weak magnetic field sensing.展开更多
The fabrication of 304L stainless welding wires with a diameter 1.6 mm by using electrochemical cold drawing(ECD)of bars with a diameter of 5.6 mm was investigated,as well as that via traditional cold drawing(TCD)for ...The fabrication of 304L stainless welding wires with a diameter 1.6 mm by using electrochemical cold drawing(ECD)of bars with a diameter of 5.6 mm was investigated,as well as that via traditional cold drawing(TCD)for comparison.The results indicated that the dilute H_(2)SO_(4)aqueous solution was an appropriate electrolyte for ECD,and increasing the H_(2)SO_(4)concentration and current density within a range improved the corrosion rate and uniformity,leading to an easier and more coordinated deformation through uniformly distributing geometrically necessary dislocations and curved large-angle grain boundaries,and decreasing their density,and thus,an enhanced electrochemical plasticization(EP).Under the optimized electrochemical parameters(0.5 mol L^(-1)H_(2)SO_(4)electrolyte and current density of 12.2 mA cm^(-2)),the average cumulative reduction rate required for annealing was up to~34%,obviously higher than~20%of TCD due to the decreased work-hardening from the EP,so that the number of annealing was significantly reduced from 10 of TCD to 5,when the drawing pass was 23.In addition,the surface of the ECD wire was distinctly smoother and brighter than that of the TCD one.These findings confirm the large potential in engineering applications of the ECD technology based on the EP effect.展开更多
Inconel 625 alloy components were fabricated using hot wire laser metal deposition(HW-LMD)through process optimization,achieving a wire deposition rate of 1.72 kg/h.The microstructure and mechanical properties of the ...Inconel 625 alloy components were fabricated using hot wire laser metal deposition(HW-LMD)through process optimization,achieving a wire deposition rate of 1.72 kg/h.The microstructure and mechanical properties of the HW-LMD Inconel 625 alloys were systematically investigated.The results revealed that the microstructure of the HWLMD Inconel 625 alloys consisted of columnar dendrites,characterized by an average grain size of 12.5μm and a strong{100}〈001〉texture.The main phase identified wasγ-Ni,with the precipitation of Laves phase,measuring less than 1μm,observed in the inter-columnar dendritic regions.The average microhardness of the HW-LMD Inconel 625 alloys was HV1.0258.The yield strength and ultimate tensile strength were 493.5 and 837.4 MPa,respectively,with elongation exceeding 50%.Impact absorbing energies at 25 and-78℃were 223.08 and 200.24 J,respectively.Both the tensile and impact fracture surfaces exhibited dimples,indicating a ductile fracture mechanism during the deformation process.展开更多
Objective: To investigate the therapeutic advantages of closed reduction and Kirschner wire fixation versus open reduction and plate fixation in patients with hand surgery fractures. Methods: The sample was collected ...Objective: To investigate the therapeutic advantages of closed reduction and Kirschner wire fixation versus open reduction and plate fixation in patients with hand surgery fractures. Methods: The sample was collected from May 2021 to May 2025, consisting of 80 patients with hand surgery fractures. These patients were randomly divided into two groups using the red and blue ball method: the plate fixation group (40 cases, treated with open reduction and plate fixation) and the Kirschner wire fixation group (40 cases, treated with closed reduction and Kirschner wire fixation). The therapeutic effects between the two groups were randomly compared. Results: The Kirschner wire fixation group outperformed the plate fixation group in all indicators except for hand function scores (p < 0.05). There was no statistically significant difference in hand function scores between the two groups (p > 0.05). Conclusion: Compared with open reduction and plate fixation, closed reduction and Kirschner wire fixation for patients with hand surgery fractures achieves a more pronounced therapeutic effect, with advantages such as less trauma, shorter operation time, less bleeding, and a lower incidence of complications. It is suitable for hand surgery fractures with good stability. Open reduction and plate internal fixation have greater advantages in complex fractures and cases requiring high stability, and are worthy of promotion and application.展开更多
Based on comprehensive observations of 20 wire icing events during winter from 2019 to 2021,we investigated the characteristics of the icing properties,the atmospheric boundary layer structure,the raindrop size distri...Based on comprehensive observations of 20 wire icing events during winter from 2019 to 2021,we investigated the characteristics of the icing properties,the atmospheric boundary layer structure,the raindrop size distribution,and their associated effects on the ice accretion mechanism in the mountainous region of Southwest China.The maximum ice weight was positively correlated with the duration of ice accretion in the mountainous area.The duration of precipitation accounted for less than 20%of the icing period in the mountainous area,with solid-phase hydrometeors being predominant.Icing events,dominated by freezing rain(FR)and mixed rain–graupel(more than 70%),were characterized by glaze or highdensity mixed icing.The relationship between the melting energy and refreezing energy reflected the distribution characteristics of the proportion of FR under mixed-phase precipitation.The intensity of the warm layer and the dominant precipitation phase significantly affected the variations in the microphysical properties of FR.The melting of large dry snowflakes significantly contributed to FR in the mountainous areas,resulting in smaller generalized intercepts and larger mass-weighted mean diameters in the presence of a stronger warm layer.Under a weaker warm layer,the value of the massweighted mean diameter was significantly smaller because of the inability of large solid particles to melt.Finally,FR in the mountainous area dominated the ice weight during the rapid ice accumulation period.A numerical simulation of FR icing on wires effectively revealed the evolution of disaster-causing icing in mountainous areas.展开更多
Wire arc additive manufacturing(WAAM)is one of the most promising approaches to manufacturing large and complex metal components owing to its low cost and high efficiency.However,pores and coarse columnar grains cause...Wire arc additive manufacturing(WAAM)is one of the most promising approaches to manufacturing large and complex metal components owing to its low cost and high efficiency.However,pores and coarse columnar grains caused by thermal accumulation in WAAM significantly decrease the strength and increase the anisotropy,preventing the achievement of both high strength and isotropy.In this study,the strength and anisotropy of AlMg-Sc-Zr alloys were improved by regulating heat input.The results indicated that as the heat input increased from 60 to 99 J/mm,all the components had lower porosity(lower than 0.04%),the size of the Al_(3)(Sc_(1-x),Zr_(x))phases decreased,and the number density increased.The average grain size gradually decreased,and the grain morphologies transformed from coarse equiaxed grain(CEG)+fine equiaxed grain(FEG)to FEG owing to the increase in Al_(3)(Sc_(1-x),Zr_(x))phases with increasing heat input.After heat treatment at 325℃for 6 h,high-density dispersed Al_(3)Sc phases(<10 nm)precipitated.The alloy possessed the highest strength at 79 J/mm,ultimate tensile strength(UTS)of approximately 423±3 MPa,and in-plane anisotropy of approximately 4.3%.At a heat input of 99 J/mm,the in-plane anisotropy decreased to 1.2%and UTS reached 414±5 MPa.The reduction in the CEG prolonged the crack propagation path,which improved the UTS in the vertical direction and reduced the anisotropy.Theoretical calculations indicated that the main strengthening mechanisms were solid solution and precipitation strengthening.This study lays the theoretical foundations for WAAM-processed high-strength and isotropic Al alloy components.展开更多
The feasibility of manufacturing Ti-6Al-4V samples through a combination of laser-aided additive manufacturing with powder(LAAM_(p))and wire(LAAM_(w))was explored.A process study was first conducted to successfully ci...The feasibility of manufacturing Ti-6Al-4V samples through a combination of laser-aided additive manufacturing with powder(LAAM_(p))and wire(LAAM_(w))was explored.A process study was first conducted to successfully circumvent defects in Ti-6Al-4V deposits for LAAM_(p) and LAAM_(w),respectively.With the optimized process parameters,robust interfaces were achieved between powder/wire deposits and the forged substrate,as well as between powder and wire deposits.Microstructure characterization results revealed the epitaxial prior β grains in the deposited Ti-6Al-4V,wherein the powder deposit was dominated by a finerα′microstructure and the wire deposit was characterized by lamellar α phases.The mechanisms of microstructure formation and correlation with mechanical behavior were analyzed and discussed.The mechanical properties of the interfacial samples can meet the requirements of the relevant Aerospace Material Specifications(AMS 6932)even without post heat treatment.No fracture occurred within the interfacial area,further suggesting the robust interface.The findings of this study highlighted the feasibility of combining LAAM_(p) and LAAM_(w) in the direct manufacturing of Ti-6Al-4V parts in accordance with the required dimensional resolution and deposition rate,together with sound strength and ductility balance in the as-built condition.展开更多
Additive manufacturing(AM)technologies,with their high degree of flexibility,enhance material utilization in the fabrication of large magnesium alloy parts,effectively meeting the demands of complex geometries.However...Additive manufacturing(AM)technologies,with their high degree of flexibility,enhance material utilization in the fabrication of large magnesium alloy parts,effectively meeting the demands of complex geometries.However,research on the corrosion resistance of magnesium alloy components produced via AM is currently limited.This study investigates the microstructural and corrosion characteristics of AZ91D magnesium alloy fabricated by wire arc additive manufacturing(WAAM)compared to its cast counterpart.A large-sized AZ91D bulk part was deposited on an AZ31 base plate using a layer-by-layer stacking approach.The results showed that the WAAM AZ91D was featured by obviously refined grains from 228.92μm of the cast one to 52.92μm on the travel direction-through thickness(TD-TT)and 50.07μm on the normal direction-through thickness(ND-TT).The rapid solidification process of WAAM inhibited the formation of β-Mg_(17)Al_(12) phase while promoting the formation of uniformly distributed network of dislocations,the dispersive precipitation of nano Al_(8)Mn_(5) phase,as well as Zn segregation.WAAM AZ91D demonstrated the occurrence of pitting corrosion and inferior corrosion resistance compared to cast AZ91D,attributed to the micro-galvanic corrosion between the α-Mg matrix and Al_(8)Mn_(5) particles and the increased number of grain boundaries.展开更多
Interlayer friction stir processing(FSP)has been proved to be an efective method of enhancing the mechanical properties of wire arc-directed energy deposited(WA-DED)samples.However,the original deposition structure wa...Interlayer friction stir processing(FSP)has been proved to be an efective method of enhancing the mechanical properties of wire arc-directed energy deposited(WA-DED)samples.However,the original deposition structure was still retained in the FSP-WA-DED component besides the processed zone(PZ),thus forming a composite structure.Considering the material utilization and practical service process of the deposited component,more attention should be paid on this special composite structure,but the relevant investigation has not been carried out.In this study,an Al–Mg–Sc alloy was prepared by WA-DED with interlayer FSP treatment,and the composite structure was frstly investigated.Almost all of the pores were eliminated under the pressure efect from the tool shoulder.The grains were further refned with an average size of about 1.2μm in the PZ.Though no severe plastic deformation was involved in the retained WA-DED deposition zone,comparable tensile properties with the PZ sample were obtained in the composite structure.Low ultimate tensile strength(UTS)of 289 MPa and elongation of 3.2%were achieved in the WA-DED sample.After interlayer FSP treatment,the UTS and elongation of the PZ samples were signifcantly increased to 443 MPa and 16.3%,while those in the composite structure remained at relatively high levels of 410 MPa and 13.5%,respectively.Meanwhile,a high fatigue strength of 180 and 130 MPa was obtained in the PZ and composite structure samples,which was clearly higher than that of the WA-DED sample(100 MPa).It is concluded that the defects in traditional WA-DED process can be eliminated in the composite structure after interlayer FSP treatment,resulting in enhanced tensile and fatigue properties,which provides an efective method of improving the mechanical properties of the WA-DED sample.展开更多
The ultrafine copper wire with a diameter of 18μm is prepared via cold drawing process from the single crystal downcast billet(Φ8 mm),taking a drawing strain to 12.19.In this paper,in-depth investigation of the micr...The ultrafine copper wire with a diameter of 18μm is prepared via cold drawing process from the single crystal downcast billet(Φ8 mm),taking a drawing strain to 12.19.In this paper,in-depth investigation of the microstructure feature,texture evolution,mechanical properties,and electrical conductivity of ultrafine wires ranging fromΦ361μm toΦ18μm is performed.Specially,the microstructure feature and texture type covering the whole longitudinal section of ultrafine wires are elaborately characterized.The results show that the average lamella thickness decreases from 1.63μm to 102 nm during the drawing process.Whereas,inhomogeneous texture evolution across different wire sections was observed.The main texture types of copper wires are comprised of<111>,<001>and<112>orientations.Specifically,the peripheral region is primarily dominated by<111>and<112>,while the central region is dominated by<001>and<111>.As the drawing strain increases,the volume fraction of hard orientation<111>with low Schmid factor increases,where notably higher fraction of<111>is resulted from the consumption of<112>and<001>for the wire ofΦ18μm.For drawn copper wire of 18μm,superior properties are obtained with a tensile strength of 729.8 MPa and an electrical conductivity of 86.9%IACS.Furthermore,it is found that grain strengthening,dislocation strengthening,and texture strengthening are three primary strengthening mechanisms of drawn copper wire,while the dislocation density is the main factor on the reducing of conductivity.展开更多
Simultaneously improving the strength and electrical conductivity of conducting metallic materials is of great significance,but it still remains a key challenge as the two properties are often mutually exclusive.In th...Simultaneously improving the strength and electrical conductivity of conducting metallic materials is of great significance,but it still remains a key challenge as the two properties are often mutually exclusive.In this study,we demonstrate a“<111>oriented fibrous grains with ultra-high aspect ratio”strategy for breaking such a conflict in Cu wire,which relies on the distinctive spatial distribution of grain boundaries and the highly consistent hard orientation to play their respective roles in suffering loading and conducting,thereby enabling a separate optimization of both strength and electrical conductivity.Therefore,a processing route was designed,involving directional solidification followed by large drawing deformation,to successfully construct fibrous grains with an ultra-high aspect ratio in 596.7 and ultra-high<111>texture proportion over 97%,which achieves Cu wire with a remarkable combination of yield strength in 482.3 MPa and electrical conductivity in 101.63%IACS.Finally,the mechanisms for high strength and high electrical conductivity were quantitatively discussed.展开更多
The Kirschner wire(K-wire)is widely used in orthopedic external fixation due to its versatility and clinical effectiveness.However,a significant challenge associated with its use is the potential for bacterial migrati...The Kirschner wire(K-wire)is widely used in orthopedic external fixation due to its versatility and clinical effectiveness.However,a significant challenge associated with its use is the potential for bacterial migration,subsequent infection,and dislodgement as the wire penetrates the skin and bone.This study introduces a novel bioactive material,selenium/calcium silicate(Se/β-CS),achieved by integrating selenium-an essential trace element in the human body-into bioceramic calcium silicate.This integration was accomplished using a combined chemical co-deposition method and redox reaction.Furthermore,a uniform and controllable Se/β-CS coating was applied to the K-wire's surface using the Langmuir-Blodgett technique.This coating gradually releases active components-Si,Ca,and Se-that effectively eliminate bacterial infections and promote osteointegration.The findings of this study offer promising opportunities for the use of robust and multifunctional coating materials on implantable devices,particularly within the fields of orthopedics,transplantation,and surgery.展开更多
To investigate the performance of utilizing the shape memory effect of SMA(Shape Memory Alloy)wire to generate recovery stress,this paper performed single heating recovery stress tests and reciprocating heating-coolin...To investigate the performance of utilizing the shape memory effect of SMA(Shape Memory Alloy)wire to generate recovery stress,this paper performed single heating recovery stress tests and reciprocating heating-cooling recovery stress tests on SMA wire under varying initial strain conditions.The effects of various strains and different energized heating methods on the recovery stress of SMA wires were explored in the single heating tests.The SMA wire was strained from 2%to 8%initially,and two distinct heating approaches were employed:one using a large current interval for rapid heating and one using a small current interval for slower heating.The experimental outcomes reveal that during a single heating cycle,the temperature-recovery stress relationship of SMA wire exhibits three distinct stages:the martensite phase stage,the transition stage from martensite to austenite phase,and the austenite phase stage.Notably,the choice of heating method does not influence the maximum recovery stress value,and the correlation between initial strain and maximum recovery stress is predominantly linear.Moreover,conducting the reciprocating temperature rise and fall performance test is important to better simulate the scenario in practical engineering where multiple recovery stress in SMA wires for structural repair.In this test,two temperature cycling methods were studied:interval rise and fall,as well as direct rise and fall.In the case of utilizing the interval temperature rise and fall method,it was observed that the recovery stress associated with cooling was significantly higher than that corresponding to heating at the same temperature.Furthermore,the recovery stress was lower upon subsequent heating than that measured during the previous heating cycle.Based on the experimental results,a prediction model for the temperature-recovery stress relationship has been proposed to simplify numerical calculations.It is hoped that an approximate temperaturerecovery stress curve can be obtained from the parameters of the SMA wire.The calculated values derived from this model show good alignment with the measured values,indicating its reliability.展开更多
Wire rope inspection robot is an important tool for wire rope condition monitoring and maintenance,which can accurately locate and judge the damage of wire rope.In addition,the wire rope inspection robot can also be u...Wire rope inspection robot is an important tool for wire rope condition monitoring and maintenance,which can accurately locate and judge the damage of wire rope.In addition,the wire rope inspection robot can also be used for cable inspection.First,the crawling structure and crawling mode of the wire rope inspection robot are reviewed,and the characteristics and existing problems of each crawling mode are analyzed separately.Next,the drive mode of the wire rope inspection robot is discussed,the types of commonly used motors are introduced,and the advantages and disadvantages of drive motors and the control modes are compared.Then,the method and principle of the non-destructive detection of the wire rope inspection robot are expounded,and the commonly used detection methods and existing deficiencies are compared.After that,the types of communication modes are compared and analyzed,and the types of wireless communication modes are also introduced.Finally,the current difficult problems of the wire rope inspection robot are summarized,and the future development trend of the wire rope inspection robot is prospected.展开更多
The performance and price of copper-based micro linear products are determined by the diameter uniformity.How to accurately detect the wire diameter of long-length copper based micro linear products without cutting or...The performance and price of copper-based micro linear products are determined by the diameter uniformity.How to accurately detect the wire diameter of long-length copper based micro linear products without cutting or damage has always been a technical concern for production enterprises.Herein,a novel approach was developed for nondestructive detection of the average diameter at any given segment of a long copper wire by assessing the adsorption capacity of arginine on its surface.The amount of adsorbent on the surface of the copper wire exhibits a positive correlation with the area,which can be detected by extractive electrospray ionization mass spectrometry(EESI-MS)after online elution with ammonia.The experimental results demonstrated that the analysis can be completed within 15 min,with a good linear relationship between copper wires with different diameters and the adsorption capacity of arginine.The linear correlation coefficient R2was 0.995,the relative standard deviation was 1.10%-2.81%,and the detection limit reached 2.5μm(length of segment=4 cm),showing potential applications for facile measurement of the average diameter of various metal wires.展开更多
Buckling failure in submarine cables presents a prevalent challenge in ocean engineering.This work aims to explore the buckling behavior of umbilical cables with damaged sheaths subjected to compression and bending cy...Buckling failure in submarine cables presents a prevalent challenge in ocean engineering.This work aims to explore the buckling behavior of umbilical cables with damaged sheaths subjected to compression and bending cyclic loads.A finite element model is devised,incorporating a singular armor wire,a rigid core,and a damaged sheath.To scrutinize the buckling progression and corresponding deformation,axial compression and bending cyclic loads are introduced.The observations reveal that a reduction in axial compression results in a larger number of cycles before buckling ensues and progressively shifts the buckling position toward the extrados and fixed end.Decreasing the bending radius precipitates a reduction in the buckling cycle number and minimizes the deformation in the armor wire.Furthermore,an empirical model is presented to predict the occurrence of birdcage buckling,providing a means to anticipate buckling events and to estimate the requisite number of cycles leading to buckling.展开更多
基金National Key Research and Development Program of China(2022YFB4600902)Shandong Provincial Science Foundation for Outstanding Young Scholars(ZR2024YQ020)。
文摘Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing additive-induced defects,and alleviating residual stress and deformation,all of which are critical for enhancing the mechanical performance of the manufactured parts.Integrating interlayer friction stir processing(FSP)into WAAM significantly enhances the quality of deposited materials.However,numerical simulation research focusing on elucidating the associated thermomechanical coupling mechanisms remains insufficient.A comprehensive numerical model was developed to simulate the thermomechanical coupling behavior in friction stir-assisted WAAM.The influence of post-deposition FSP on the coupled thermomechanical response of the WAAM process was analyzed quantitatively.Moreover,the residual stress distribution and deformation behavior under both single-layer and multilayer deposition conditions were investigated.Thermal analysis of different deposition layers in WAAM and friction stir-assisted WAAM was conducted.Results show that subsequent layer deposition induces partial remelting of the previously solidified layer,whereas FSP does not cause such remelting.Furthermore,thermal stress and deformation analysis confirm that interlayer FSP effectively mitigates residual stresses and distortion in WAAM components,thereby improving their structural integrity and mechanical properties.
基金partially supported by the Center for Advanced Systems Understanding(CASUS)financed by Germany’s Federal Ministry of Education and Research(BMBF)+2 种基金the Saxon State Government out of the State Budget approved by the Saxon State Parliamentfunding from the European Union’s Just Transition Fund(JTF)within the project Röntgenlaser-Optimierung der Laserfusion(ROLF),Contract No.5086999001co-financed by the Saxon State Government out of the State Budget approved by the Saxon State Parliament.
文摘We present the first systematic experimental validation of return-current-driven cylindrical implosion scaling in micrometer-sized Cu and Al wires irradiated by J-class femtosecond laser pulses.Employing XFEL-based imaging with sub-micrometer spatial and femtosecond temporal resolution,supported by hydrodynamic and particle-in-cell simulations,we reveal how return current density depends precisely on wire diameter,material properties,and incident laser energy.We identify deviations from simple theoretical predictions due to geometrically influenced electron escape dynamics.These results refine and confirm the scaling laws essential for predictive modeling in high-energy-density physics and inertial fusion research.
基金Funded by Hunan Provincial Natural Science Foundation(No.2023JJ40074)Hunan Provincial Education Department Excellent Youth Project(No.21B0757)Hunan Provincial Engineering Technology Center(No.2022TP2036)。
文摘In this study,multilayer lamination welding was employed to prepare graphene/copper(Gr/Cu)composite billets from graphene-coated copper foils,followed by multi-pass cold drawing to produce Φ1 mm Gr/Cu composite wires.Microstructure and property analyses in both the cold-drawn and annealed states show that the incorporation of graphene significantly improves the ductility and electrical conductivity of the copper wire.After annealing at 350℃ for 30 minutes,the composite wire demonstrates a tensile strength of 270 MPa and an electrical conductivity of 102.74%IACS,both superior to those of pure copper wire under identical conditions.At 150℃,the electrical conductivity of the annealed composite wire reaches 72.60%IACS,notably higher than the 68.19%IACS of pure copper.The results suggest that graphene is uniformly distributed within the composite wire,with minimal impact on conductivity,while effectively refining the copper grain structure to enhance ductility.Moreover,graphene suppresses copper lattice vibrations at elevated temperatures,reducing the rate of conductivity degradation.
基金financially supported by the Key R&D Program of Shandong Province(2022SFGC0801)the National Natural Science Foundation of China(No.22005162 and 22175009)the Natural Science Foundation of Shandong Province(No.ZR2020QE093)。
文摘Osmotic energy,existing between the seawater and river water,is a renewable energy source,which can be directly converted into electricity by ion-exchange membranes(IEM).In traditional IEMs,the ion transport channels are formed by nanophase separation of hydrophilic ion carriers and hydrophobic segments.It is difficult to realize high-density ion channels with controlled spatial arrangement and length scale of ion carriers.Herein,we construct high-density 1D ion wires as transmission channels.Through molecular design,hydrophilic imidazole groups and hydrophobic alkyl tails were introduced into the repeat units,which self-assembled into 1D ion transporting core and protecting shell along the main chains.The areal density of the ionic wire arrays is up to~10^(12)cm^(-2),which is the highest value.The ionic wires ensure both high ion flux transport and high selectivity,achieving an ultrahigh-power density of 40.5 W m^(-2)at a 500-fold salinity gradient.Besides,the ionic wire array membrane is well recyclable and antibacterial.The ionic wires provide novel concept for next generation of high-performance membranes.
基金supported by the State Key Research and Development Program,Special Gravity Wave(Grant No.2023YFC2206003)the Gansu Provincial Science and Technology Program Funding(Grant No.24JRRA499)+1 种基金the Natural Science Foundation of Shandong Province(Grant No.ZR2024QB219)the Lanzhou City Science and Technology Program Project(Grant No.2025-2-47)。
文摘Giant magnetoimpedance(GMI)sensors are increasingly employed in modern magnetic sensing technologies.However,improving the GMI performance of magnetic cores remains challenging due to intrinsic limitations in material properties and structural stability.In this work,we explore the use of Joule heating to enhance the GMI response of Fe_(20)Ni_(80)/Cu composite wires.By applying a current of 1.8 A for 10 min,notable improvements in magnetic domain uniformity and a reduction in domain spacing are observed.Under these conditions,GMI ratios reach 1870% in the non-diagonal mode and1147%in the diagonal mode,respectively,highlighting their potential for applications in high-precision weak magnetic field sensing.
基金supported by Major Science and Technology Project of Gansu Province(Grant No.23ZDGA010)National Natural Science Foundation of China(Grant No.51971105).
文摘The fabrication of 304L stainless welding wires with a diameter 1.6 mm by using electrochemical cold drawing(ECD)of bars with a diameter of 5.6 mm was investigated,as well as that via traditional cold drawing(TCD)for comparison.The results indicated that the dilute H_(2)SO_(4)aqueous solution was an appropriate electrolyte for ECD,and increasing the H_(2)SO_(4)concentration and current density within a range improved the corrosion rate and uniformity,leading to an easier and more coordinated deformation through uniformly distributing geometrically necessary dislocations and curved large-angle grain boundaries,and decreasing their density,and thus,an enhanced electrochemical plasticization(EP).Under the optimized electrochemical parameters(0.5 mol L^(-1)H_(2)SO_(4)electrolyte and current density of 12.2 mA cm^(-2)),the average cumulative reduction rate required for annealing was up to~34%,obviously higher than~20%of TCD due to the decreased work-hardening from the EP,so that the number of annealing was significantly reduced from 10 of TCD to 5,when the drawing pass was 23.In addition,the surface of the ECD wire was distinctly smoother and brighter than that of the TCD one.These findings confirm the large potential in engineering applications of the ECD technology based on the EP effect.
基金supported by the Special Project of Gansu Province,China(Nos.23ZDGA010,22ZD6GA008)the Central Guiding Fund for Local Science and Technology Development Project,China(Nos.24ZYQA054,23ZYQA308)the Key Project of Research and Innovation in Universities,China(No.2024CXPT-06)。
文摘Inconel 625 alloy components were fabricated using hot wire laser metal deposition(HW-LMD)through process optimization,achieving a wire deposition rate of 1.72 kg/h.The microstructure and mechanical properties of the HW-LMD Inconel 625 alloys were systematically investigated.The results revealed that the microstructure of the HWLMD Inconel 625 alloys consisted of columnar dendrites,characterized by an average grain size of 12.5μm and a strong{100}〈001〉texture.The main phase identified wasγ-Ni,with the precipitation of Laves phase,measuring less than 1μm,observed in the inter-columnar dendritic regions.The average microhardness of the HW-LMD Inconel 625 alloys was HV1.0258.The yield strength and ultimate tensile strength were 493.5 and 837.4 MPa,respectively,with elongation exceeding 50%.Impact absorbing energies at 25 and-78℃were 223.08 and 200.24 J,respectively.Both the tensile and impact fracture surfaces exhibited dimples,indicating a ductile fracture mechanism during the deformation process.
文摘Objective: To investigate the therapeutic advantages of closed reduction and Kirschner wire fixation versus open reduction and plate fixation in patients with hand surgery fractures. Methods: The sample was collected from May 2021 to May 2025, consisting of 80 patients with hand surgery fractures. These patients were randomly divided into two groups using the red and blue ball method: the plate fixation group (40 cases, treated with open reduction and plate fixation) and the Kirschner wire fixation group (40 cases, treated with closed reduction and Kirschner wire fixation). The therapeutic effects between the two groups were randomly compared. Results: The Kirschner wire fixation group outperformed the plate fixation group in all indicators except for hand function scores (p < 0.05). There was no statistically significant difference in hand function scores between the two groups (p > 0.05). Conclusion: Compared with open reduction and plate fixation, closed reduction and Kirschner wire fixation for patients with hand surgery fractures achieves a more pronounced therapeutic effect, with advantages such as less trauma, shorter operation time, less bleeding, and a lower incidence of complications. It is suitable for hand surgery fractures with good stability. Open reduction and plate internal fixation have greater advantages in complex fractures and cases requiring high stability, and are worthy of promotion and application.
基金funded by the National Natural Science Foundation of China(Grant No.42325503)the Hubei Provincial Natural Science Foundation and the Meteorological Innovation and Development Project of China(Grant Nos.2023AFD096 and 2022CFD122)+1 种基金the Natural Science Foundation of Wuhan(Grant No.2024020901030454)the Beijige Foundation of NJIAS(Grant No.BJG202304)。
文摘Based on comprehensive observations of 20 wire icing events during winter from 2019 to 2021,we investigated the characteristics of the icing properties,the atmospheric boundary layer structure,the raindrop size distribution,and their associated effects on the ice accretion mechanism in the mountainous region of Southwest China.The maximum ice weight was positively correlated with the duration of ice accretion in the mountainous area.The duration of precipitation accounted for less than 20%of the icing period in the mountainous area,with solid-phase hydrometeors being predominant.Icing events,dominated by freezing rain(FR)and mixed rain–graupel(more than 70%),were characterized by glaze or highdensity mixed icing.The relationship between the melting energy and refreezing energy reflected the distribution characteristics of the proportion of FR under mixed-phase precipitation.The intensity of the warm layer and the dominant precipitation phase significantly affected the variations in the microphysical properties of FR.The melting of large dry snowflakes significantly contributed to FR in the mountainous areas,resulting in smaller generalized intercepts and larger mass-weighted mean diameters in the presence of a stronger warm layer.Under a weaker warm layer,the value of the massweighted mean diameter was significantly smaller because of the inability of large solid particles to melt.Finally,FR in the mountainous area dominated the ice weight during the rapid ice accumulation period.A numerical simulation of FR icing on wires effectively revealed the evolution of disaster-causing icing in mountainous areas.
基金supported by National Key Research and Development Program(Grant No.2024YFB4609700)the National Natural Science Foundation of China(Grant No.52374365)。
文摘Wire arc additive manufacturing(WAAM)is one of the most promising approaches to manufacturing large and complex metal components owing to its low cost and high efficiency.However,pores and coarse columnar grains caused by thermal accumulation in WAAM significantly decrease the strength and increase the anisotropy,preventing the achievement of both high strength and isotropy.In this study,the strength and anisotropy of AlMg-Sc-Zr alloys were improved by regulating heat input.The results indicated that as the heat input increased from 60 to 99 J/mm,all the components had lower porosity(lower than 0.04%),the size of the Al_(3)(Sc_(1-x),Zr_(x))phases decreased,and the number density increased.The average grain size gradually decreased,and the grain morphologies transformed from coarse equiaxed grain(CEG)+fine equiaxed grain(FEG)to FEG owing to the increase in Al_(3)(Sc_(1-x),Zr_(x))phases with increasing heat input.After heat treatment at 325℃for 6 h,high-density dispersed Al_(3)Sc phases(<10 nm)precipitated.The alloy possessed the highest strength at 79 J/mm,ultimate tensile strength(UTS)of approximately 423±3 MPa,and in-plane anisotropy of approximately 4.3%.At a heat input of 99 J/mm,the in-plane anisotropy decreased to 1.2%and UTS reached 414±5 MPa.The reduction in the CEG prolonged the crack propagation path,which improved the UTS in the vertical direction and reduced the anisotropy.Theoretical calculations indicated that the main strengthening mechanisms were solid solution and precipitation strengthening.This study lays the theoretical foundations for WAAM-processed high-strength and isotropic Al alloy components.
基金financially supported by the Agency for Science,Technology and Research(A*Star),Republic of Singapore,under the Aerospace Consortium Cycle 12“Characterization of the Effect of Wire and Powder Deposited Materials”(No.A1815a0078)。
文摘The feasibility of manufacturing Ti-6Al-4V samples through a combination of laser-aided additive manufacturing with powder(LAAM_(p))and wire(LAAM_(w))was explored.A process study was first conducted to successfully circumvent defects in Ti-6Al-4V deposits for LAAM_(p) and LAAM_(w),respectively.With the optimized process parameters,robust interfaces were achieved between powder/wire deposits and the forged substrate,as well as between powder and wire deposits.Microstructure characterization results revealed the epitaxial prior β grains in the deposited Ti-6Al-4V,wherein the powder deposit was dominated by a finerα′microstructure and the wire deposit was characterized by lamellar α phases.The mechanisms of microstructure formation and correlation with mechanical behavior were analyzed and discussed.The mechanical properties of the interfacial samples can meet the requirements of the relevant Aerospace Material Specifications(AMS 6932)even without post heat treatment.No fracture occurred within the interfacial area,further suggesting the robust interface.The findings of this study highlighted the feasibility of combining LAAM_(p) and LAAM_(w) in the direct manufacturing of Ti-6Al-4V parts in accordance with the required dimensional resolution and deposition rate,together with sound strength and ductility balance in the as-built condition.
基金The National Natural Science Foundations of China(Nos.52071191 and 52471080)are acknowledged for providing the financial support.
文摘Additive manufacturing(AM)technologies,with their high degree of flexibility,enhance material utilization in the fabrication of large magnesium alloy parts,effectively meeting the demands of complex geometries.However,research on the corrosion resistance of magnesium alloy components produced via AM is currently limited.This study investigates the microstructural and corrosion characteristics of AZ91D magnesium alloy fabricated by wire arc additive manufacturing(WAAM)compared to its cast counterpart.A large-sized AZ91D bulk part was deposited on an AZ31 base plate using a layer-by-layer stacking approach.The results showed that the WAAM AZ91D was featured by obviously refined grains from 228.92μm of the cast one to 52.92μm on the travel direction-through thickness(TD-TT)and 50.07μm on the normal direction-through thickness(ND-TT).The rapid solidification process of WAAM inhibited the formation of β-Mg_(17)Al_(12) phase while promoting the formation of uniformly distributed network of dislocations,the dispersive precipitation of nano Al_(8)Mn_(5) phase,as well as Zn segregation.WAAM AZ91D demonstrated the occurrence of pitting corrosion and inferior corrosion resistance compared to cast AZ91D,attributed to the micro-galvanic corrosion between the α-Mg matrix and Al_(8)Mn_(5) particles and the increased number of grain boundaries.
基金supported by the National Natural Science Foundation of China(No.U23A20538)the Fundamental Research Funds for the Universities of Liaoning Province,Shenyang U40 Outstanding Youth Foundation(No.RC230864)+1 种基金the Foundation of CAS Henan Industrial Technology Innovation&Incubation Center(No.2024110)the Natural Science Foundation of Liaoning Province(No.2023-BS-016)。
文摘Interlayer friction stir processing(FSP)has been proved to be an efective method of enhancing the mechanical properties of wire arc-directed energy deposited(WA-DED)samples.However,the original deposition structure was still retained in the FSP-WA-DED component besides the processed zone(PZ),thus forming a composite structure.Considering the material utilization and practical service process of the deposited component,more attention should be paid on this special composite structure,but the relevant investigation has not been carried out.In this study,an Al–Mg–Sc alloy was prepared by WA-DED with interlayer FSP treatment,and the composite structure was frstly investigated.Almost all of the pores were eliminated under the pressure efect from the tool shoulder.The grains were further refned with an average size of about 1.2μm in the PZ.Though no severe plastic deformation was involved in the retained WA-DED deposition zone,comparable tensile properties with the PZ sample were obtained in the composite structure.Low ultimate tensile strength(UTS)of 289 MPa and elongation of 3.2%were achieved in the WA-DED sample.After interlayer FSP treatment,the UTS and elongation of the PZ samples were signifcantly increased to 443 MPa and 16.3%,while those in the composite structure remained at relatively high levels of 410 MPa and 13.5%,respectively.Meanwhile,a high fatigue strength of 180 and 130 MPa was obtained in the PZ and composite structure samples,which was clearly higher than that of the WA-DED sample(100 MPa).It is concluded that the defects in traditional WA-DED process can be eliminated in the composite structure after interlayer FSP treatment,resulting in enhanced tensile and fatigue properties,which provides an efective method of improving the mechanical properties of the WA-DED sample.
基金Project supported by“Unveiled the List of Commanders”Key Core Common Technology Projects of Ji’an,ChinaProject(LJKMZ20220591)supported by the Basic Scientific Research Project of the Education Department of Liaoning Province,ChinaProject(CSTB2023NSCQ-LZX0116)supported by the Natural Science Foundation Joint Fund for Innovation and Development Projects of Chongqing,China。
文摘The ultrafine copper wire with a diameter of 18μm is prepared via cold drawing process from the single crystal downcast billet(Φ8 mm),taking a drawing strain to 12.19.In this paper,in-depth investigation of the microstructure feature,texture evolution,mechanical properties,and electrical conductivity of ultrafine wires ranging fromΦ361μm toΦ18μm is performed.Specially,the microstructure feature and texture type covering the whole longitudinal section of ultrafine wires are elaborately characterized.The results show that the average lamella thickness decreases from 1.63μm to 102 nm during the drawing process.Whereas,inhomogeneous texture evolution across different wire sections was observed.The main texture types of copper wires are comprised of<111>,<001>and<112>orientations.Specifically,the peripheral region is primarily dominated by<111>and<112>,while the central region is dominated by<001>and<111>.As the drawing strain increases,the volume fraction of hard orientation<111>with low Schmid factor increases,where notably higher fraction of<111>is resulted from the consumption of<112>and<001>for the wire ofΦ18μm.For drawn copper wire of 18μm,superior properties are obtained with a tensile strength of 729.8 MPa and an electrical conductivity of 86.9%IACS.Furthermore,it is found that grain strengthening,dislocation strengthening,and texture strengthening are three primary strengthening mechanisms of drawn copper wire,while the dislocation density is the main factor on the reducing of conductivity.
基金supported by the National Natural Science Foundation of China(NSFC)under Grant Nos.52001313,52130002,52273322,and 52321001IMR Innovation Fund under Grant No.2023-PY05+3 种基金the Natural Science Foundation of Liaoning Province under Grant No.2022-MS-001the China Postdoctoral Science Foundation under Grant No.GZC20232740the Zhongke Technology Achievement Transfer and Transformation Center of Henan Province under Grant No.2024109the Joint Research Project between Chinese Academy of Sciences(CAS)under Grant No.174321KYSB20210002.
文摘Simultaneously improving the strength and electrical conductivity of conducting metallic materials is of great significance,but it still remains a key challenge as the two properties are often mutually exclusive.In this study,we demonstrate a“<111>oriented fibrous grains with ultra-high aspect ratio”strategy for breaking such a conflict in Cu wire,which relies on the distinctive spatial distribution of grain boundaries and the highly consistent hard orientation to play their respective roles in suffering loading and conducting,thereby enabling a separate optimization of both strength and electrical conductivity.Therefore,a processing route was designed,involving directional solidification followed by large drawing deformation,to successfully construct fibrous grains with an ultra-high aspect ratio in 596.7 and ultra-high<111>texture proportion over 97%,which achieves Cu wire with a remarkable combination of yield strength in 482.3 MPa and electrical conductivity in 101.63%IACS.Finally,the mechanisms for high strength and high electrical conductivity were quantitatively discussed.
基金financially supported by the foundation of the NMPA Key Laboratory for Quality Evaluation of Medical Protective and Implant Devices,the Shandong Provincial Natural Science Foundation(ZR2021MB096)to Huali Niethe Science and Technology Research Project of Shanghai Songjiang District Science and Technology Committee(No.2023SJKWGG063)+4 种基金the Medical Engineering Cross Research Project of Shanghai Jiaotong University(No.YG2022QN074)to Changping Wangthe National Nature Science Foundation of China(No.32371383)the Shanghai 2023“Science and Technology Innovation Action Plan”Biomedical Science and Technology Support Special Project(No.23S31900100)the Foundation of National Center for Translational Medicine(Shanghai)SHU Branch(No.SUITM-202411)to Siyu Nithe Research Center for the Industries of the Future at Westlake University and the Zhejiang Provincial Natural Science Foundation of China(No.2022XHSJJ003)for support.
文摘The Kirschner wire(K-wire)is widely used in orthopedic external fixation due to its versatility and clinical effectiveness.However,a significant challenge associated with its use is the potential for bacterial migration,subsequent infection,and dislodgement as the wire penetrates the skin and bone.This study introduces a novel bioactive material,selenium/calcium silicate(Se/β-CS),achieved by integrating selenium-an essential trace element in the human body-into bioceramic calcium silicate.This integration was accomplished using a combined chemical co-deposition method and redox reaction.Furthermore,a uniform and controllable Se/β-CS coating was applied to the K-wire's surface using the Langmuir-Blodgett technique.This coating gradually releases active components-Si,Ca,and Se-that effectively eliminate bacterial infections and promote osteointegration.The findings of this study offer promising opportunities for the use of robust and multifunctional coating materials on implantable devices,particularly within the fields of orthopedics,transplantation,and surgery.
基金financially supported by National Natural Science Foundation of China(Project No.51878156).
文摘To investigate the performance of utilizing the shape memory effect of SMA(Shape Memory Alloy)wire to generate recovery stress,this paper performed single heating recovery stress tests and reciprocating heating-cooling recovery stress tests on SMA wire under varying initial strain conditions.The effects of various strains and different energized heating methods on the recovery stress of SMA wires were explored in the single heating tests.The SMA wire was strained from 2%to 8%initially,and two distinct heating approaches were employed:one using a large current interval for rapid heating and one using a small current interval for slower heating.The experimental outcomes reveal that during a single heating cycle,the temperature-recovery stress relationship of SMA wire exhibits three distinct stages:the martensite phase stage,the transition stage from martensite to austenite phase,and the austenite phase stage.Notably,the choice of heating method does not influence the maximum recovery stress value,and the correlation between initial strain and maximum recovery stress is predominantly linear.Moreover,conducting the reciprocating temperature rise and fall performance test is important to better simulate the scenario in practical engineering where multiple recovery stress in SMA wires for structural repair.In this test,two temperature cycling methods were studied:interval rise and fall,as well as direct rise and fall.In the case of utilizing the interval temperature rise and fall method,it was observed that the recovery stress associated with cooling was significantly higher than that corresponding to heating at the same temperature.Furthermore,the recovery stress was lower upon subsequent heating than that measured during the previous heating cycle.Based on the experimental results,a prediction model for the temperature-recovery stress relationship has been proposed to simplify numerical calculations.It is hoped that an approximate temperaturerecovery stress curve can be obtained from the parameters of the SMA wire.The calculated values derived from this model show good alignment with the measured values,indicating its reliability.
基金the National Natural Science Foundation of China(No.12072362)the Priority Academic Program Development of Jiangsu Higher Education Institutions。
文摘Wire rope inspection robot is an important tool for wire rope condition monitoring and maintenance,which can accurately locate and judge the damage of wire rope.In addition,the wire rope inspection robot can also be used for cable inspection.First,the crawling structure and crawling mode of the wire rope inspection robot are reviewed,and the characteristics and existing problems of each crawling mode are analyzed separately.Next,the drive mode of the wire rope inspection robot is discussed,the types of commonly used motors are introduced,and the advantages and disadvantages of drive motors and the control modes are compared.Then,the method and principle of the non-destructive detection of the wire rope inspection robot are expounded,and the commonly used detection methods and existing deficiencies are compared.After that,the types of communication modes are compared and analyzed,and the types of wireless communication modes are also introduced.Finally,the current difficult problems of the wire rope inspection robot are summarized,and the future development trend of the wire rope inspection robot is prospected.
基金supported by the National Natural Science Foundation of China(No.22422402)National Key Research and Development Program of China(No.2022YFF0705300)Key Research and Development Program of Jiangxi Province(No.20232BBG70004)。
文摘The performance and price of copper-based micro linear products are determined by the diameter uniformity.How to accurately detect the wire diameter of long-length copper based micro linear products without cutting or damage has always been a technical concern for production enterprises.Herein,a novel approach was developed for nondestructive detection of the average diameter at any given segment of a long copper wire by assessing the adsorption capacity of arginine on its surface.The amount of adsorbent on the surface of the copper wire exhibits a positive correlation with the area,which can be detected by extractive electrospray ionization mass spectrometry(EESI-MS)after online elution with ammonia.The experimental results demonstrated that the analysis can be completed within 15 min,with a good linear relationship between copper wires with different diameters and the adsorption capacity of arginine.The linear correlation coefficient R2was 0.995,the relative standard deviation was 1.10%-2.81%,and the detection limit reached 2.5μm(length of segment=4 cm),showing potential applications for facile measurement of the average diameter of various metal wires.
基金financially supported by the National Natural Science Foundation of China(Grant No.52471301)the Fujian Province Transportation Science and Technology Project(Grant No.JC202302)the Zhejiang Provincial Natural Science Foundation of China(Grant No.LY24E090003).
文摘Buckling failure in submarine cables presents a prevalent challenge in ocean engineering.This work aims to explore the buckling behavior of umbilical cables with damaged sheaths subjected to compression and bending cyclic loads.A finite element model is devised,incorporating a singular armor wire,a rigid core,and a damaged sheath.To scrutinize the buckling progression and corresponding deformation,axial compression and bending cyclic loads are introduced.The observations reveal that a reduction in axial compression results in a larger number of cycles before buckling ensues and progressively shifts the buckling position toward the extrados and fixed end.Decreasing the bending radius precipitates a reduction in the buckling cycle number and minimizes the deformation in the armor wire.Furthermore,an empirical model is presented to predict the occurrence of birdcage buckling,providing a means to anticipate buckling events and to estimate the requisite number of cycles leading to buckling.
