The wetting behavior of liquid tin(Sn)solder on copper(Cu)substrate at 250℃was investigated by the wetting balance method under the action of direct current(DC).The curves of wetting balance were measured and the mor...The wetting behavior of liquid tin(Sn)solder on copper(Cu)substrate at 250℃was investigated by the wetting balance method under the action of direct current(DC).The curves of wetting balance were measured and the morphology of the intermetallic compound(IMC)precipitated at the interface were observed.Results show that DC has a significant effect on the wettability and IMC.As the current increases,the balance wetting force and the thickness of the IMC layer increase.The direction of the DC also has a certain effect on the balance wetting force and IMC layer.When the current is negative,the final balance wetting force and the thickness of the Cu_(6)Sn_(5) layer are significantly higher than those in the positive current case,which is attributed to electromigration.The IMC precipitation at the interface provides a chemical driving force for the movement of the triple junction.The interaction of the interface atoms and the chemical reaction are enhanced by DC,thereby improving wettability.Meanwhile,the Marangoni convection caused by DC inside liquid Sn solder changes the structure of triple junction,which provides a physical driving force for the spread of the liquid Sn solder on the Cu substrate.展开更多
Rechargeable aqueous Zn-ion batteries(AZIBs)are one of the most promising energy storage devices for large-scale energy storage owing to their high specific capacity,eco-friendliness,low cost and high safety.Neverthel...Rechargeable aqueous Zn-ion batteries(AZIBs)are one of the most promising energy storage devices for large-scale energy storage owing to their high specific capacity,eco-friendliness,low cost and high safety.Nevertheless,zinc metal anodes suffer from severe dendrite growth and side reactions,resulting in the inferior electrochemical performance of AZIBs.To address these problems,surface modification of zinc metal anodes is a facile and effective method to regulate the interaction between the zinc anode and an electrolyte.In this review,the current challenges and strategies for zinc metal anodes are presented.Furthermore,recent advances in surface modification strategies to improve their electrochemical performance are concluded and discussed.Finally,challenges and prospects for future development of zinc metal anodes are proposed.We hope this review will be useful for designing and fabricating highperformance AZIBs and boosting their practical applications.展开更多
The removal of hydrogen sulfide from gas plays an important role in rational utilization of resources and environ- mental protection. In this paper, the process of hydrogen sulfide removal by wet oxidation method in a...The removal of hydrogen sulfide from gas plays an important role in rational utilization of resources and environ- mental protection. In this paper, the process of hydrogen sulfide removal by wet oxidation method in a rotating packed bed was investigated in a scale for treating 10 000 Nm3/h of gas. On the basis of studying the influence of the species and con- centration of alkali source, the liquid/gas volume ratio, the high gravity factor, and the hydrogen sulfide content in feed gas on the desulfurization effect, the suitable technological conditions were obtained. The hydrogen sulfide removal efficiency could reach 98.0% under these conditions. The results of continuous operation of process facilities showed that the high gravity method has many merits including higher desulfurization rate, good stability in operation, lower liquid/gas volume ratio, greater operation elasticity, and apparent energy saving effects.展开更多
An orthogonal method was used to evaluate the effects of Ga, Al, Ag, and Ce multi-additions on the wetting characteristics of Sn-9Zn lead-free solders by wetting balance method. The results show that the optimal loadi...An orthogonal method was used to evaluate the effects of Ga, Al, Ag, and Ce multi-additions on the wetting characteristics of Sn-9Zn lead-free solders by wetting balance method. The results show that the optimal loading of Ga, Al, Ag, and Ce was 0.2 wt.%, 0.002 wt.%, 0.25 wt.%, and 0.15 wt.%, respectively. Intermetallic compounds （IMCs） formed at the interface between Sn-9Zn-0.2Ga-0.002Al-0.25Ag- 0.15Ce solder and Cu substrate were investigated by scanning electron microscope （SEM） and energy dispersive spectroscopy （EDS） analysis. The SEM images illustrate that the IMCs can be divided into two portions from the substrate side to the solder side： a planar CusZns layer and an additional continuous scallop-like AgZn3 layer. The EDS analysis also shows that Ga segregates in the solder abutting upon the interface. X-ray photoelectron spectroscopy （XPS） and Auger electron spectroscopy （AES） of the surface components of Sn-9Zn-0.2Ga-0.002Al- 0.25Ag-0.15Ce solder indicate that Al aggregates at the surface in the form of Al203 protective fdm, which prevents the further oxidation of the solder surface. On the other hand, Ce aggregates at the subsurface, which may reduce the surface tension of the solder and improve the wettability in consequence.展开更多
In order to improve the homogeneous distribution of the TiC particles and facilitate the TiC particles to distribute in the tungsten grain interiors,two kinds of TiCdoped tungsten precursors with a core-shell structur...In order to improve the homogeneous distribution of the TiC particles and facilitate the TiC particles to distribute in the tungsten grain interiors,two kinds of TiCdoped tungsten precursors with a core-shell structure were prepared by an improved wet chemical method at different reaction temperature conditions.Consequently,fine platelike precursor(200-400 nm)and flower-like precursor(approximately 1.25μm)are obtained.After reduction and sintering,the microstructures of the samples were characterized by scanning electron microscopy and transmission electron microscopy.In the sample sintered from the platelike precursor,TiC particles with sizes in the range of40-300 nm and an average size of approximately 80 nm were uniformly distributed in the tungsten matrix with a high share in the grain interiors.However,in the sample sintered from the flower-like precursor,the TiC particles with sizes in the range of 50-700 nm are significantly aggregated and non-uniformly distributed in the tungsten matrix.As a result,the sample sintered from the plate-like precursor achieves higher mechanical properties and a much narrower range of bending strength values than that sintered from the flower-like precursor.The average bending strength of the sample sintered from the plate-like precursor is 655 MPa,which is higher than that of the sample sintered from the flower-like precursor(524 MPa).Different reaction mechanisms and dispersing stabilities of the TiC particles at different temperature conditions should be accounted for the differences between the two samples.展开更多
The significant rise of ultra-violet(UV) radiation and pathogenic infectious bacteria poses a serious threat to global health.Numerous researchers' interests are attracted by novel materials with strong UVblocking...The significant rise of ultra-violet(UV) radiation and pathogenic infectious bacteria poses a serious threat to global health.Numerous researchers' interests are attracted by novel materials with strong UVblocking ability,antibacterial activity and low toxicity to other species.In this case,a simple wet chemical method with different annealing temperatures(400,500,and 600℃) was employed to create highly effective rare earth(Sm)-doped ZnO nanorods.The(101) plane of wurtzite ZnO shifts towards a lower angle with increasing annealing temperature,according to the X-ray diffraction(XRD) study findings,which additionally establishes the consequence of lattice expansion.Occurrence of doublet peaks of Sm 3d(Sm 3d_(5/2) and Sm 3d_(3/2)) in the X-ray photoelectron spectroscopy(XPS) spectrum clearly validates the substitution of Sm^(3+) ions in the 500℃-annealed samples.The 500℃-annealed nanorods exhibit combined performances of the wide band gap,improved UV absorbance,and vivid green luminescent emission(563 nm).Additio nally,the nanorods have favorable UV-blocking execution of 96% for UVA at 360 nm,92% for UVB at 320 nm,and 57% for UVC at 225 nm,which is greater than the majority of ZnO-related materials that have been reported up to this date.Sm doping is also appropriate for improving bacterial inhibition against the two studied strains(Escherichia coli and Staphylococcus aureus),in addition to the intriguing features discussed above.Furthermore,with maximum inhibition zone diameters of 20±0.72 and 18±0.57 mm,respectively,these nanorods exhibit high inhibitory action against E.coli and S.aureus bacterial strains.The rare earth-doped material developed during the current experiment,which was annealed at 500℃,could potentially serve as an effective replacement for UV-blocking and antibacterial material,especially for biomedical applications.展开更多
Assessment of ecological flow or water level for water bodies is important for the protection of de- graded or degrading ecosystems caused by water shortage in arid regions, and it has become a key issue in water reso...Assessment of ecological flow or water level for water bodies is important for the protection of de- graded or degrading ecosystems caused by water shortage in arid regions, and it has become a key issue in water resources planning. In the past several decades, many methods have been proposed to assess ecological flow for rivers and ecological water level for lakes or wetlands. To balance water uses by human and ecosystems, we proposed a general multi-objective programming model to determine minimum ecological flow or water level for inland water bodies, where two objectives are water index for human and habitat index for ecosystems, respectively Using the weighted sum method for multi-objective optimization, minimum ecological flow or water level can be determined from the breakpoint in the water index-habitat index curve, which is similar to the slope method to de- termine minimum ecological flow from wetted perimeter-discharge curve. However, the general multi-objective programming model is superior to the slope method in its physical meaning and calculation method. This model provides a general analysis method for ecological water uses of different inland water bodies, and can be used to define minimum ecological flow or water level by choosing appropriate water and habitat indices. Several com- monly used flow or water level assessment methods were found to be special cases of the general model, including the wetted perimeter method and the multi-objective physical habitat simulation method for ecological river flow, the inundated forest width method for regeneration flow of floodplain forest and the lake surface area method for eco- logical lake level. These methods were applied to determine minimum ecological flow or water level for two repre- sentative rivers and a lake in northern Xinjiang of China, including minimum ecological flow for the Ertix River, minimum regeneration flow for floodplain forest along the midstream of Kaxgar River, and minimum ecological lake level for the Ebinur Lake. The results illustrated the versatility of the general model, and can provide references for water resources planning and ecosystem protection for these rivers and lake.展开更多
This paper elaborates the wet limestone gypsum technology adopted in the flue gasdesulfurization projects of 4×360 MW generating units in Luohuang Power Plant, theimplementation process of Phase II desulfurizatio...This paper elaborates the wet limestone gypsum technology adopted in the flue gasdesulfurization projects of 4×360 MW generating units in Luohuang Power Plant, theimplementation process of Phase II desulfurization project, the technical features and differencesof Phase I and II desulfurization plants, and puts forward some suggestions for FGD projectconstruction.[展开更多
Introduction Cationic starches are a series of products of which various sorts with different properties and usages can all be produced via cationic reactions by using different types of etherification agents under di...Introduction Cationic starches are a series of products of which various sorts with different properties and usages can all be produced via cationic reactions by using different types of etherification agents under different conditions. As an additive and strengthening agent,展开更多
The increased public health awareness in the post corona virus disease 2019 era and the usage of healthcare and cleanroom facilities have contributed to the escalation of the global face mask waste disposal.This study...The increased public health awareness in the post corona virus disease 2019 era and the usage of healthcare and cleanroom facilities have contributed to the escalation of the global face mask waste disposal.This study investigates the catalytic pyrolysis of face mask waste into hydrocarbon-rich gases,which holds significant value as prospective carbonaceous nanomaterial(CNM)precursors.The pyrolysis condition was fixed at 500℃with a heating rate of 20℃/min.The catalyst,Ni/ZSM-5 was produced from different metal impregnation strategies with various metal precursors namely nickel(Ni),magnesium(Mg),and calcium(Ca).Unlike conventional pyrolysis which focuses on liquid yield,the innovative multi-zone pyrolysis reactor with Ni/ZSM-5 produced an impressive gas yield of 47.0%(mass fraction),of which 79.1%was hydrocarbon gas that could be useful for promising CNM production.The crystallinity of Ni/ZSM-5 and the composition of gas product were largely maintained even after regeneration.Individual and mixed polymer kinetics studies were done using the model-free Ozawa-Flynn-Wall(OFW)method to obtained the activation energy,which was reduced by 9.4%when the Ni/ZSM-5 catalyst was introduced.These results indicate that the viability of Ni/ZSM-5 in reducing the reaction activation energy while concurrently improving the gas yield and quality for potential CNM production.This study improves the optimization of catalytic pyrolysis processes for producing high-quality non-condensable hydrocarbon gas,particularly in sustainable material synthesis.展开更多
We successfully synthesize four kinds of ZnO nano/microcrystals including dumbbell microrods, nanoflakes, nanoplates, and microrods by a simple wet chemical method. Growth duration is found to play a crucial role in t...We successfully synthesize four kinds of ZnO nano/microcrystals including dumbbell microrods, nanoflakes, nanoplates, and microrods by a simple wet chemical method. Growth duration is found to play a crucial role in the morphologies of these ZnO nano/microcrystallites. In addition, growth conditions are systematically studied as a function of precursor concentration and temperature. The structural and optical characteristics of the ZnO samples are further investigated by X-ray diffraction, scanning electron microscopy, and photoluminescence spectroscopy.展开更多
The wetted perimeter method(WPM) is used in hydrology and hydraulics to calculate instream flows.The WPM requires few data.It requires only the values of the wetted perimeter,flow and water level,which can be obtained...The wetted perimeter method(WPM) is used in hydrology and hydraulics to calculate instream flows.The WPM requires few data.It requires only the values of the wetted perimeter,flow and water level,which can be obtained from the hydrologic stations of the river in question.In addition,the WPM is not limited by the impacts of human activities on the river runoff.Therefore,this method is generally suitable for the current conditions in China.However,the process of applying the WPM involves two key aspects:how to plot the curve describing the relationship between the wetted perimeter and the discharge and how to confirm the breakpoint of the wetted perimeter-discharge curve.The traditional method is to calculate the curvature or the slope of the wetted perimeter-discharge curve to obtain the minimum flow.According to this method,the minimum flow corresponds to the point of maximum curvature or to the point at which the slope of the curve is equal to 1.The wetted perimeter-discharge curve of a natural river is only part of the complete curve.Thus,the instream flow calculated by the traditional method is the minimum or maximum discharge.The new criterion for defining the breakpoint of the wetted perimeter-discharge curve is that the slope at the breakpoint is a relative maximum,the second-largest slope.The discharges at the breakpoints corresponded to the minimum flow levels required to maintain the ecological function of the river.The minimum instream flow requirements(MIFRs) of four typical reaches,Zhuba,Daofu,Ganzi and Zumuzu hydrological stations on the West Course of the First Stage Project of the South-North Water Transfer Project(WCFSPSNWTP),are calculated using an improved wetted perimeter method(IWPM).The results show that the MIFRs of Zhuba,Daofu,Ganzi and Zumuzu are approximately 9.06-14.5 m 3 s-1,20.7-43.5 m3 s-1,38.8-77.2 m 3 s-1 and 40.4-59.5 m 3 s-1,corresponding to 11.7%-33.9%,14.2%-37.6%,12.4%-28.4% and 17.5%-30.2%,respectively of the annual average flow(AAF).These MIFRs can maintain good ecological function in a river according to the criterion furnished by the Tennant method.展开更多
Interaction between two spheres with an interstitial fluid is crucial in discrete element modeling for simulating the behaviors of ＇wet＇ particulate materials. The normal viscous force of squeeze flow between two ar...Interaction between two spheres with an interstitial fluid is crucial in discrete element modeling for simulating the behaviors of ＇wet＇ particulate materials. The normal viscous force of squeeze flow between two arbitrary rigid spheres with an interstitial HerscheI-Bulkley fluid was studied on the basis of Reynolds＇ lubrication theory, resulting in analytical integral expressions of pressure distribution and the viscous force between the two spheres. According to the variation of shear stress, the fluid was divided into yielding and unyielding regions, followed by a discussion on the thickness of the two regions. The result of this paper could be reduced to either the power-law fluid or the Bingham fluid case.展开更多
Hierarchical 3D flower-like CuO nanostructures on the Cu substrates were synthesized by a wet chem- ical method and subsequent heat treatment. The synthesis, structure and morphologies of obtained samples under differ...Hierarchical 3D flower-like CuO nanostructures on the Cu substrates were synthesized by a wet chem- ical method and subsequent heat treatment. The synthesis, structure and morphologies of obtained samples under different concentrations of NazS203 were investigated in detail and the possible growth mechanisms of the 3D flower-like CuO nanostructures were discussed. Na2S203 plays a key role in the generation of the 3D flower-like CuO nanostructures. When the concentration of Na2S203 is more than 0.4 mol/L, the 3D flower-like CuO nano- structures can be prepared on the Cu foils. The photocatalytic performances were studied by analyzing the degra- dation of methyl orange （MO） in aqueous solution in the presence of hydroxide water （H202）. The 3D flower-like CuO nanostructures exhibit higher photocatalytic activity （96.2% degradation rate） than commercial CuO particles （36.3% degradation rate）. The origin of the higher photocatalytic activity of the 3D flower-like CuO nanostructures was also discussed.展开更多
基金Doctoral Research Start-up Fund of Lanzhou University of Arts and Science(2021-9)Innovation Fund for Colleges and Universities of Gansu Province,China(2022B-265)。
文摘The wetting behavior of liquid tin(Sn)solder on copper(Cu)substrate at 250℃was investigated by the wetting balance method under the action of direct current(DC).The curves of wetting balance were measured and the morphology of the intermetallic compound(IMC)precipitated at the interface were observed.Results show that DC has a significant effect on the wettability and IMC.As the current increases,the balance wetting force and the thickness of the IMC layer increase.The direction of the DC also has a certain effect on the balance wetting force and IMC layer.When the current is negative,the final balance wetting force and the thickness of the Cu_(6)Sn_(5) layer are significantly higher than those in the positive current case,which is attributed to electromigration.The IMC precipitation at the interface provides a chemical driving force for the movement of the triple junction.The interaction of the interface atoms and the chemical reaction are enhanced by DC,thereby improving wettability.Meanwhile,the Marangoni convection caused by DC inside liquid Sn solder changes the structure of triple junction,which provides a physical driving force for the spread of the liquid Sn solder on the Cu substrate.
基金supported by the National Key Research and Development Program of China(2020YFB1713500)the Chinese 02 Special Fund(2017ZX02408003)+2 种基金the Open Fund of National Joint Engineering Research Center for abrasion control and molding of metal materials(HKDNM201807)the Student Research Training Plan of Henan University of Science and Technology(2020026)the National Undergraduate Innovation and Entrepreneurship Training Program(202010464031,202110464005)。
文摘Rechargeable aqueous Zn-ion batteries(AZIBs)are one of the most promising energy storage devices for large-scale energy storage owing to their high specific capacity,eco-friendliness,low cost and high safety.Nevertheless,zinc metal anodes suffer from severe dendrite growth and side reactions,resulting in the inferior electrochemical performance of AZIBs.To address these problems,surface modification of zinc metal anodes is a facile and effective method to regulate the interaction between the zinc anode and an electrolyte.In this review,the current challenges and strategies for zinc metal anodes are presented.Furthermore,recent advances in surface modification strategies to improve their electrochemical performance are concluded and discussed.Finally,challenges and prospects for future development of zinc metal anodes are proposed.We hope this review will be useful for designing and fabricating highperformance AZIBs and boosting their practical applications.
基金the Shanxi Provin-cial Youth Science and Technology Research Fund (No.2008021009-2) for the financial support to this project
文摘The removal of hydrogen sulfide from gas plays an important role in rational utilization of resources and environ- mental protection. In this paper, the process of hydrogen sulfide removal by wet oxidation method in a rotating packed bed was investigated in a scale for treating 10 000 Nm3/h of gas. On the basis of studying the influence of the species and con- centration of alkali source, the liquid/gas volume ratio, the high gravity factor, and the hydrogen sulfide content in feed gas on the desulfurization effect, the suitable technological conditions were obtained. The hydrogen sulfide removal efficiency could reach 98.0% under these conditions. The results of continuous operation of process facilities showed that the high gravity method has many merits including higher desulfurization rate, good stability in operation, lower liquid/gas volume ratio, greater operation elasticity, and apparent energy saving effects.
文摘An orthogonal method was used to evaluate the effects of Ga, Al, Ag, and Ce multi-additions on the wetting characteristics of Sn-9Zn lead-free solders by wetting balance method. The results show that the optimal loading of Ga, Al, Ag, and Ce was 0.2 wt.%, 0.002 wt.%, 0.25 wt.%, and 0.15 wt.%, respectively. Intermetallic compounds （IMCs） formed at the interface between Sn-9Zn-0.2Ga-0.002Al-0.25Ag- 0.15Ce solder and Cu substrate were investigated by scanning electron microscope （SEM） and energy dispersive spectroscopy （EDS） analysis. The SEM images illustrate that the IMCs can be divided into two portions from the substrate side to the solder side： a planar CusZns layer and an additional continuous scallop-like AgZn3 layer. The EDS analysis also shows that Ga segregates in the solder abutting upon the interface. X-ray photoelectron spectroscopy （XPS） and Auger electron spectroscopy （AES） of the surface components of Sn-9Zn-0.2Ga-0.002Al- 0.25Ag-0.15Ce solder indicate that Al aggregates at the surface in the form of Al203 protective fdm, which prevents the further oxidation of the solder surface. On the other hand, Ce aggregates at the subsurface, which may reduce the surface tension of the solder and improve the wettability in consequence.
基金financially supported by the ITER-National Magnetic Confinement Fusion Program(No.2014GB123000)。
文摘In order to improve the homogeneous distribution of the TiC particles and facilitate the TiC particles to distribute in the tungsten grain interiors,two kinds of TiCdoped tungsten precursors with a core-shell structure were prepared by an improved wet chemical method at different reaction temperature conditions.Consequently,fine platelike precursor(200-400 nm)and flower-like precursor(approximately 1.25μm)are obtained.After reduction and sintering,the microstructures of the samples were characterized by scanning electron microscopy and transmission electron microscopy.In the sample sintered from the platelike precursor,TiC particles with sizes in the range of40-300 nm and an average size of approximately 80 nm were uniformly distributed in the tungsten matrix with a high share in the grain interiors.However,in the sample sintered from the flower-like precursor,the TiC particles with sizes in the range of 50-700 nm are significantly aggregated and non-uniformly distributed in the tungsten matrix.As a result,the sample sintered from the plate-like precursor achieves higher mechanical properties and a much narrower range of bending strength values than that sintered from the flower-like precursor.The average bending strength of the sample sintered from the plate-like precursor is 655 MPa,which is higher than that of the sample sintered from the flower-like precursor(524 MPa).Different reaction mechanisms and dispersing stabilities of the TiC particles at different temperature conditions should be accounted for the differences between the two samples.
基金supported by Researchers Supporting Project number (RSP2024R142),King Saud University,Riyadh,Saudi Arabia。
文摘The significant rise of ultra-violet(UV) radiation and pathogenic infectious bacteria poses a serious threat to global health.Numerous researchers' interests are attracted by novel materials with strong UVblocking ability,antibacterial activity and low toxicity to other species.In this case,a simple wet chemical method with different annealing temperatures(400,500,and 600℃) was employed to create highly effective rare earth(Sm)-doped ZnO nanorods.The(101) plane of wurtzite ZnO shifts towards a lower angle with increasing annealing temperature,according to the X-ray diffraction(XRD) study findings,which additionally establishes the consequence of lattice expansion.Occurrence of doublet peaks of Sm 3d(Sm 3d_(5/2) and Sm 3d_(3/2)) in the X-ray photoelectron spectroscopy(XPS) spectrum clearly validates the substitution of Sm^(3+) ions in the 500℃-annealed samples.The 500℃-annealed nanorods exhibit combined performances of the wide band gap,improved UV absorbance,and vivid green luminescent emission(563 nm).Additio nally,the nanorods have favorable UV-blocking execution of 96% for UVA at 360 nm,92% for UVB at 320 nm,and 57% for UVC at 225 nm,which is greater than the majority of ZnO-related materials that have been reported up to this date.Sm doping is also appropriate for improving bacterial inhibition against the two studied strains(Escherichia coli and Staphylococcus aureus),in addition to the intriguing features discussed above.Furthermore,with maximum inhibition zone diameters of 20±0.72 and 18±0.57 mm,respectively,these nanorods exhibit high inhibitory action against E.coli and S.aureus bacterial strains.The rare earth-doped material developed during the current experiment,which was annealed at 500℃,could potentially serve as an effective replacement for UV-blocking and antibacterial material,especially for biomedical applications.
基金supported by the Open Research Fund Program of State key Laboratory of Hydroscience and Engineering, Tsinghua University (sklhse-2013-A-03)the National Natural Science Foundation of China (50879041)
文摘Assessment of ecological flow or water level for water bodies is important for the protection of de- graded or degrading ecosystems caused by water shortage in arid regions, and it has become a key issue in water resources planning. In the past several decades, many methods have been proposed to assess ecological flow for rivers and ecological water level for lakes or wetlands. To balance water uses by human and ecosystems, we proposed a general multi-objective programming model to determine minimum ecological flow or water level for inland water bodies, where two objectives are water index for human and habitat index for ecosystems, respectively Using the weighted sum method for multi-objective optimization, minimum ecological flow or water level can be determined from the breakpoint in the water index-habitat index curve, which is similar to the slope method to de- termine minimum ecological flow from wetted perimeter-discharge curve. However, the general multi-objective programming model is superior to the slope method in its physical meaning and calculation method. This model provides a general analysis method for ecological water uses of different inland water bodies, and can be used to define minimum ecological flow or water level by choosing appropriate water and habitat indices. Several com- monly used flow or water level assessment methods were found to be special cases of the general model, including the wetted perimeter method and the multi-objective physical habitat simulation method for ecological river flow, the inundated forest width method for regeneration flow of floodplain forest and the lake surface area method for eco- logical lake level. These methods were applied to determine minimum ecological flow or water level for two repre- sentative rivers and a lake in northern Xinjiang of China, including minimum ecological flow for the Ertix River, minimum regeneration flow for floodplain forest along the midstream of Kaxgar River, and minimum ecological lake level for the Ebinur Lake. The results illustrated the versatility of the general model, and can provide references for water resources planning and ecosystem protection for these rivers and lake.
文摘This paper elaborates the wet limestone gypsum technology adopted in the flue gasdesulfurization projects of 4×360 MW generating units in Luohuang Power Plant, theimplementation process of Phase II desulfurization project, the technical features and differencesof Phase I and II desulfurization plants, and puts forward some suggestions for FGD projectconstruction.[
文摘Introduction Cationic starches are a series of products of which various sorts with different properties and usages can all be produced via cationic reactions by using different types of etherification agents under different conditions. As an additive and strengthening agent,
基金supported by the Universiti Sains Malaysia under Research University Team(RUTeam)Grant Scheme(No.1001/PJKIMIA/8580061).
文摘The increased public health awareness in the post corona virus disease 2019 era and the usage of healthcare and cleanroom facilities have contributed to the escalation of the global face mask waste disposal.This study investigates the catalytic pyrolysis of face mask waste into hydrocarbon-rich gases,which holds significant value as prospective carbonaceous nanomaterial(CNM)precursors.The pyrolysis condition was fixed at 500℃with a heating rate of 20℃/min.The catalyst,Ni/ZSM-5 was produced from different metal impregnation strategies with various metal precursors namely nickel(Ni),magnesium(Mg),and calcium(Ca).Unlike conventional pyrolysis which focuses on liquid yield,the innovative multi-zone pyrolysis reactor with Ni/ZSM-5 produced an impressive gas yield of 47.0%(mass fraction),of which 79.1%was hydrocarbon gas that could be useful for promising CNM production.The crystallinity of Ni/ZSM-5 and the composition of gas product were largely maintained even after regeneration.Individual and mixed polymer kinetics studies were done using the model-free Ozawa-Flynn-Wall(OFW)method to obtained the activation energy,which was reduced by 9.4%when the Ni/ZSM-5 catalyst was introduced.These results indicate that the viability of Ni/ZSM-5 in reducing the reaction activation energy while concurrently improving the gas yield and quality for potential CNM production.This study improves the optimization of catalytic pyrolysis processes for producing high-quality non-condensable hydrocarbon gas,particularly in sustainable material synthesis.
文摘We successfully synthesize four kinds of ZnO nano/microcrystals including dumbbell microrods, nanoflakes, nanoplates, and microrods by a simple wet chemical method. Growth duration is found to play a crucial role in the morphologies of these ZnO nano/microcrystallites. In addition, growth conditions are systematically studied as a function of precursor concentration and temperature. The structural and optical characteristics of the ZnO samples are further investigated by X-ray diffraction, scanning electron microscopy, and photoluminescence spectroscopy.
基金supported by the National Natural Science Foundation of China (Grant No. 50809027)the Fundamental Research Funds for the Central Universities (Grant No. 11MG15)the Open Research Fund Program of State Key Laboratory of Water Resources and Hydropower Engineering Science (Grant No. 2009B050)
文摘The wetted perimeter method(WPM) is used in hydrology and hydraulics to calculate instream flows.The WPM requires few data.It requires only the values of the wetted perimeter,flow and water level,which can be obtained from the hydrologic stations of the river in question.In addition,the WPM is not limited by the impacts of human activities on the river runoff.Therefore,this method is generally suitable for the current conditions in China.However,the process of applying the WPM involves two key aspects:how to plot the curve describing the relationship between the wetted perimeter and the discharge and how to confirm the breakpoint of the wetted perimeter-discharge curve.The traditional method is to calculate the curvature or the slope of the wetted perimeter-discharge curve to obtain the minimum flow.According to this method,the minimum flow corresponds to the point of maximum curvature or to the point at which the slope of the curve is equal to 1.The wetted perimeter-discharge curve of a natural river is only part of the complete curve.Thus,the instream flow calculated by the traditional method is the minimum or maximum discharge.The new criterion for defining the breakpoint of the wetted perimeter-discharge curve is that the slope at the breakpoint is a relative maximum,the second-largest slope.The discharges at the breakpoints corresponded to the minimum flow levels required to maintain the ecological function of the river.The minimum instream flow requirements(MIFRs) of four typical reaches,Zhuba,Daofu,Ganzi and Zumuzu hydrological stations on the West Course of the First Stage Project of the South-North Water Transfer Project(WCFSPSNWTP),are calculated using an improved wetted perimeter method(IWPM).The results show that the MIFRs of Zhuba,Daofu,Ganzi and Zumuzu are approximately 9.06-14.5 m 3 s-1,20.7-43.5 m3 s-1,38.8-77.2 m 3 s-1 and 40.4-59.5 m 3 s-1,corresponding to 11.7%-33.9%,14.2%-37.6%,12.4%-28.4% and 17.5%-30.2%,respectively of the annual average flow(AAF).These MIFRs can maintain good ecological function in a river according to the criterion furnished by the Tennant method.
基金support from the National Natural Science Foundation of China(grant no.10872214)
文摘Interaction between two spheres with an interstitial fluid is crucial in discrete element modeling for simulating the behaviors of ＇wet＇ particulate materials. The normal viscous force of squeeze flow between two arbitrary rigid spheres with an interstitial HerscheI-Bulkley fluid was studied on the basis of Reynolds＇ lubrication theory, resulting in analytical integral expressions of pressure distribution and the viscous force between the two spheres. According to the variation of shear stress, the fluid was divided into yielding and unyielding regions, followed by a discussion on the thickness of the two regions. The result of this paper could be reduced to either the power-law fluid or the Bingham fluid case.
基金supported by the High-Tech Research and Development Program of China(No.2009AA03Z427)
文摘Hierarchical 3D flower-like CuO nanostructures on the Cu substrates were synthesized by a wet chem- ical method and subsequent heat treatment. The synthesis, structure and morphologies of obtained samples under different concentrations of NazS203 were investigated in detail and the possible growth mechanisms of the 3D flower-like CuO nanostructures were discussed. Na2S203 plays a key role in the generation of the 3D flower-like CuO nanostructures. When the concentration of Na2S203 is more than 0.4 mol/L, the 3D flower-like CuO nano- structures can be prepared on the Cu foils. The photocatalytic performances were studied by analyzing the degra- dation of methyl orange （MO） in aqueous solution in the presence of hydroxide water （H202）. The 3D flower-like CuO nanostructures exhibit higher photocatalytic activity （96.2% degradation rate） than commercial CuO particles （36.3% degradation rate）. The origin of the higher photocatalytic activity of the 3D flower-like CuO nanostructures was also discussed.
