Oxygen release and electrolyte decomposition under high voltage endlessly exacerbate interfacial ramifications and structu ral degradation of high energy-density Li-rich layered oxide(LLO),leading to voltage and capac...Oxygen release and electrolyte decomposition under high voltage endlessly exacerbate interfacial ramifications and structu ral degradation of high energy-density Li-rich layered oxide(LLO),leading to voltage and capacity fading.Herein,the dual-strategy of Cr,B complex coating and local gradient doping is simultaneously achieved on LLO surface by a one-step wet chemical reaction at room temperature.Density functional theory(DFT)calculations prove that stable B-O and Cr-O bonds through the local gradient doping can significantly reduce the high-energy O 2p states of interfacial lattice O,which is also effective for the near-surface lattice O,thus greatly stabilizing the LLO surface,Besides,differential electrochemical mass spectrometry(DEMS)indicates that the Cr_(x)B complex coating can adequately inhibit oxygen release and prevents the migration or dissolution of transition metal ions,including allowing speedy Li^(+)migration,The voltage and capacity fading of the modified cathode(LLO-C_(r)B)are adequately suppressed,which are benefited from the uniformly dense cathode electrolyte interface(CEI)composed of balanced organic/inorganic composition.Therefore,the specific capacity of LLO-CrB after 200 cycles at 1C is 209.3 mA h g^(-1)(with a retention rate of 95.1%).This dual-strategy through a one-step wet chemical reaction is expected to be applied in the design and development of other anionic redox cathode materials.展开更多
As the bed depth increases,sintering yield increases,but the productivity decreases.To reveal the reasons for the decrease in productivity and explore targeted solutions,the bed resistance of mixtures,wet zone,and com...As the bed depth increases,sintering yield increases,but the productivity decreases.To reveal the reasons for the decrease in productivity and explore targeted solutions,the bed resistance of mixtures,wet zone,and combustion zone was analyzed in the laboratory.The results showed that the decreased porosity of mixture resulted in the increased bed resistance by 160.56%when the bed depth increased from 600 to 1000 mm.After improving porosity of 1%by adding loosening bars with optimized size and distribution,the bed resistance decreased,and the productivity increased by 5%.The increase in bed depth increased the thickness of the wet zone from 120 to 680 mm and the resistance from 1.56 to 8.83 kPa.By using a three-stage intensive mixer and pre-adding water for granulation,the moisture of mixture was reduced by 0.6%,and the sintering productivity increased by 4%.Besides,the high bed resistance is mainly caused by the increase in the thickness of the combustion zone from 31.9 to 132.7 mm,and the bed resistance increased from 0.70 to 5.62 kPa.The bed resistance of the combustion zone at 900 mm was increased by 90.51%compared to 700 mm.After optimization of the distribution of coke breeze,the thickness of combustion zone at the lower layer decreased from 132.7 to 106.84 mm and permeability improved significantly.展开更多
Forest structure is fundamental in determining ecosystem function,yet the impact of bamboo invasion on these structural characteristics remains unclear.We investigated 219 invasion transects at 41 sites across the dis...Forest structure is fundamental in determining ecosystem function,yet the impact of bamboo invasion on these structural characteristics remains unclear.We investigated 219 invasion transects at 41 sites across the distribution areas of Moso bamboo(Phyllostachys edulis)in China to explore the effects of bamboo invasion on forest structural attributes and diameter–height allometries by comparing paired plots of bamboo,mixed bamboo-tree,and non-bamboo forests along the transects.We found that bamboo invasion decreased the mean and maximum diameter at breast height,maximum height,and total basal area,but increased the mean height,stem density,and scaling exponent for stands.Bamboo also had a higher scaling exponent than tree,particularly in mixed forests,suggesting a greater allocation of biomass to height growth.As invasion intensity increased,bamboo allometry became more plastic and decreased significantly,whereas tree allometry was indirectly promoted by increasing stem density.Additionally,a humid climate may favour the scaling exponents for both bamboo and tree,with only minor contributions from topsoil moisture and nitrogen content.The inherent superiority of diameter–height allometry allows bamboo to outcompete tree and contributes to its invasive success.Our findings provide a theoretical basis for understanding the causes and consequences of bamboo invasion.展开更多
The study focuses on the creep characteristics of significant yellow sandstone for water conservancy, hydropower, and other waterrelated slope excavation unloading rock-graded loading creep characteristics. It conduct...The study focuses on the creep characteristics of significant yellow sandstone for water conservancy, hydropower, and other waterrelated slope excavation unloading rock-graded loading creep characteristics. It conducts a uniaxial graded loading creep test on yellow sandstone under different pre-peak unloading and wetting-drying cycles. The improved nonlinear Nishihara model was obtained by introducing a nonlinear viscous element with an accelerated creep threshold switch. The sensitivity characteristics of the parameters of the improved creep model were analyzed and a nonlinear creep constitutive model was established, considering the unloading-cyclic intrinsic damage induced by water intrusion. The research results show that:(1)With an increase in the unloading point, the porosity of the rock samples initially decreases and then increases. As the number of cyclic water intrusions rises, the porosity of the rock samples gradually increases, reaching a maximum of 9.58% at an unloading point of 70% uniaxial compression stress(0.7 Rc) after five cycles.(2) Total creep deformation increases with the number of cyclic water intrusions;however, with an increase in the unloading ratio, the original samples show an initial decrease, followed by an increase in creep deformation. With a higher unloading ratio and various instances of cyclic water intrusion, the total creep time of the rock samples,compared to the original samples, is reduced by 21.8%and 23.02%. The creep damage mode gradually changes from shear damage to tensile damage.(3) The sensitivity characteristics of the improved creep model parameters show that transient elasticity modulus E1 is affected by the coupling of unloading and cyclic water intrusion. The viscoelastic modulus E2 and viscous coefficient η1 are mainly affected by unloading and cyclic water intrusion.(4) Based on the strain equivalence principle of damage mechanics, the damage treatment of the parameters in the original model is improved to construct a nonlinear creep constitutive model that considers unloading-cyclic water intrusion damage. A parameter inversion and comparison to the traditional Nishihara model reveal an average relative standard deviation of 0.271%,significantly less than 1%, indicating a more accurate nonlinear creep constitutive model. The research results are crucial for analyzing the long-term stability of water-related steep rocky slopes post-excavation and unloading and for preventing and controlling creep-type landslide disasters.展开更多
The wetting behavior of liquid tin(Sn)solder on copper(Cu)substrate at 250℃was investigated by the wetting balance method under the action of direct current(DC).The curves of wetting balance were measured and the mor...The wetting behavior of liquid tin(Sn)solder on copper(Cu)substrate at 250℃was investigated by the wetting balance method under the action of direct current(DC).The curves of wetting balance were measured and the morphology of the intermetallic compound(IMC)precipitated at the interface were observed.Results show that DC has a significant effect on the wettability and IMC.As the current increases,the balance wetting force and the thickness of the IMC layer increase.The direction of the DC also has a certain effect on the balance wetting force and IMC layer.When the current is negative,the final balance wetting force and the thickness of the Cu_(6)Sn_(5) layer are significantly higher than those in the positive current case,which is attributed to electromigration.The IMC precipitation at the interface provides a chemical driving force for the movement of the triple junction.The interaction of the interface atoms and the chemical reaction are enhanced by DC,thereby improving wettability.Meanwhile,the Marangoni convection caused by DC inside liquid Sn solder changes the structure of triple junction,which provides a physical driving force for the spread of the liquid Sn solder on the Cu substrate.展开更多
In this paper,the effect of sodium laurate(SL)on the properties of sodium lauroyl glutamate(SLG),such as surface activity,foam,wetting,emulsification,and resistance to hard water,has been systematically investigated.T...In this paper,the effect of sodium laurate(SL)on the properties of sodium lauroyl glutamate(SLG),such as surface activity,foam,wetting,emulsification,and resistance to hard water,has been systematically investigated.The results showed that the critical micelle concentration(cmc)of SLG was 0.30 mmol/L,and the surface tension at the cmc(γcmc)was 34.95 mN/m.With the increase of SL content,the efficiency of SLG solution in reducing the surface tension was decreased.When the SL content was increased,there was no significant change in the foaming ability and foam stability of SLG solutions.The increase of SL content improved both the emulsification and wettability of SLG,but reduced its water resistance.展开更多
Wet wipes have become an indispensable part of modern life,offering convenience whether used for personal hygiene,baby care,or household cleaning.Wet wipes made of different materials each have their own characteristi...Wet wipes have become an indispensable part of modern life,offering convenience whether used for personal hygiene,baby care,or household cleaning.Wet wipes made of different materials each have their own characteristics,which not only directly affect the comfort and performance during use but are also closely related to environmental protection.Understanding their differences can help consumers make more informed choices—ones that meet daily needs while reducing the environmental burden.展开更多
Wound dressings with tissue adhesion,good mechanical,antioxidant and anti-inflammatory performance are urgently needed.In this work,we present a multifunctional selenium nanoparticles(SeNPs)/citric acid/gelatin/hydrox...Wound dressings with tissue adhesion,good mechanical,antioxidant and anti-inflammatory performance are urgently needed.In this work,we present a multifunctional selenium nanoparticles(SeNPs)/citric acid/gelatin/hydroxysuccinimide-grafted polyacrylic acid nanocomposite hydrogel adhesive(SCA) specifically designed for wound healing applications.The SCA was prepared via a one-pot processing,where SeNPs synthesized via chemical reduction were incorporated.These SeNPs not only endowed SCA with robust wet adhesion ability,excellent stretchability,and skin-matched elasticity modulus by serving as a physical crosslinker to modulate swelling equilibrium and molecular slippage,but also enhanced the biocompatibility and free radical scavenging capacity of SCA.Furthermore,in vivo evaluation of full-thickness cutaneous defects of rats revealed that SCA effectively reduced inflammation,promoted wound closure,and increased collagen deposition.All these results demonstrated that the developed SCA offers a promising therapeutic strategy for wound healing applications.展开更多
An innovative strategy was proposed by integration of membrane contactor(MC)with biphasic solvent for efficient CO_(2) capture from flue gas.The accessible fly ash-based ceramic membrane(CM)underwent hydrophobic modif...An innovative strategy was proposed by integration of membrane contactor(MC)with biphasic solvent for efficient CO_(2) capture from flue gas.The accessible fly ash-based ceramic membrane(CM)underwent hydrophobic modification through silane grafting,followed by fluoroalkylsilane decoration,to prepare the superhydrophobic membrane(CSCM).The CSCM significantly improved resistance to wetting by the biphasic solvent,consisting of amine(DETA)and sulfolane(TMS).Morphological characterizations and chemical analysis revealed the notable enhancements in pore structure and hydrophobic chemical groups for the modified membrane.Predictions of wetting/bubbling behavior based on static wetting theory referred the liquid entry pressure(LEP)of CSCM increased by 20 kPa compared to pristine CM.Compared with traditional amine solvents,the biphasic solvent presented the expected phase separation.Performance experiments demonstrated that the CO_(2) capture efficiency of the biphasic solvent increased by 7%,and the electrical energy required for desorption decreased by 32%.The 60-h continuous testing and supplemental characterization of used membrane confirmed the excellent adaptability and durability of the CSCMs.This study provides a potential approach for accessing hydrophobic ceramic membranes and biphasic solvents for industrial CO_(2) capture.展开更多
The main raw material utilized in wood adhesives comes from petrochemical extractives.However,due to the excessive dependence on petrochemical resources and the adverse impact on the ecosystem and human wellbeing,ther...The main raw material utilized in wood adhesives comes from petrochemical extractives.However,due to the excessive dependence on petrochemical resources and the adverse impact on the ecosystem and human wellbeing,there is an increasing trend to develop byproduct protein-based adhesives in the current global food safety context.In this research,flaxseed meal was subjected to pretreatment,and trimethylolpropane triglycidyl ether(TTE)and ethylenediamine(EN)were utilized as crosslinkers to establish a more compact adhesive layer and to prevent water intrusion.The pretreatment decreased the FM/UB viscosity by 60%compared to FM.The combination of CD analysis indicated that the Urea-NaOH pretreatment effectively stretched the flaxseed meal protein.According to Fourier transform infrared(FTIR)spectroscopy,X-ray diffraction(XRD),and differential scanning calorimetry(DSC)were used to analyze the resulting adhesive’s reaction mechanism and thermal response.Furthermore,the physical properties of the adhesive were characterized using wet shear strength testing and SEM observation.Remarkably,the dry bond strength increased from 0.72 to 2.12 MPa,representing a 194.4%increase.The wet bonding strength of the adhesive was improved from 0.22 to 1.21 MPa,representing a 550%increase compared to the original flaxseed protein-based adhesive,which far exceeded the minimum requirement for plywood of Type II(≥0.7 MPa,by GB/T 9846-2015).This study demonstrated an eco-friendly and sustainable method for the development of protein adhesives as viable substitutes for petrochemical resins.展开更多
Phytoplankton plays a crucial role in the energy flow and nutrient cycling of aquatic ecosystems.To understand the spatial and temporal distribution of phytoplankton in the Wujiang River,Yungui Plateau,SW China,sample...Phytoplankton plays a crucial role in the energy flow and nutrient cycling of aquatic ecosystems.To understand the spatial and temporal distribution of phytoplankton in the Wujiang River,Yungui Plateau,SW China,samples were collected in 12 locations in wet and dry seasons and analyzed.We hypothesized that phytoplankton assemblages would exhibit significant temporal variability,with niche breadths of dominant species fluctuating seasonally,leading to distinct patterns of species association and community stability.Results show differences in community structure between the two seasons,but such changes did not cause non-significant differences inα-diversity.Diatoms were dominant in the assemblages in terms of biomass,while the numerical abundance of Cyanobacteria was highest in the wet season due to their relatively small cells.Rainfall-driven changes in runoff significantly altered nutrient availability,which in turn strongly affected phytoplankton structure.The more intense water flow contributed to a greaterβ-diversity in the wet season,driven primarily by species replacement,with stochastic processes played a more important role during the dry season.In the dry season,dominant species exhibited a broader niche breadth and greater niche overlap,along with more positive species associations,suggesting a more stable and resilient community structure.Conversely,in the wet season,species had narrower niche breadth and less niche overlap,leading to a less stable community.Both negative and positive species associations were observed,indicating a complex balance between environmental filtering and competition within the assemblages.These findings provide important insights into how seasonal environmental changes,particularly water flow and nutrient dynamics,shape phytoplankton communities in aquatic ecosystems.Understanding the mechanisms driving changes in community and stability is critical for predicting the impacts of climate change and managing aquatic biodiversity,as fluctuations in water flow and nutrient input may alter ecosystem functioning and productivity.展开更多
This study tracked the characteristics of atmospheric wet deposition of the toxic element arsenic(As)at both urban(Guangzhou(GZ))and forested(Dinghushan Natural Reserve(DHS))sites within the Pearl River Delta(PRD)regi...This study tracked the characteristics of atmospheric wet deposition of the toxic element arsenic(As)at both urban(Guangzhou(GZ))and forested(Dinghushan Natural Reserve(DHS))sites within the Pearl River Delta(PRD)region between 2016 and 2019,examining its correlation with rainfall patterns.Additionally,by employing backward trajectory analysis and the potential source contribution function(PSCF)in conjunction with pertinent emission inventories,we pinpointed the main pathways of atmospheric arsenic transport and evaluated the emission contributions from priority source areas.The study revealed that the atmospheric arsenic wet deposition fluxes at the GZ and DHS sites exhibited a trend of increase followed by a decrease over the four-year period.Wet season deposition fluxes were more than triple those of the dry season,with urban site showing a difference of over four times.Notably,wet season As deposition at both sites was predominantly affected by heavy rainfall from marine air masses,constituting 31%of the total deposition.The predominant trajectory directions contributing to arsenic deposition at GZ and DHS were northeast(55%)and south(53%),respectively.The primary source areas for both sites were largely outside the PRD region,with the GZ site having 80%to 95%of its source area in the non-PRD region,compared to 69%to 88%at the DHS site.Furthermore,non-PRD areas contributed approximately 65%to arsenic emissions for both sites,with the industrial sector being the dominant emission source,exceeding 97%of the total emissions.展开更多
Antarctica contains numerous scientific mysteries,and the Antarctic ice sheet and its underlying bedrock contain important information about the geological structure of Antarctica and the evolutionary history of the i...Antarctica contains numerous scientific mysteries,and the Antarctic ice sheet and its underlying bedrock contain important information about the geological structure of Antarctica and the evolutionary history of the ice sheet.In order to obtain the focus of these scientific explorations,the Antarctic drilling engineering is constantly developing.The drilling fluid performance directly determines the success or failure of drilling engineering.In order to enhance the poor performance for drilling fluids due to poor dispersion stability and easy settling of organoclay at ultra-low temperatures,the small-molecule wetting agent(HSR)for drilling fluid suitable for Antarctica was prepared by oleic acid,diethanolamine and benzoic acid as raw materials.Its chemical structure,properties and action mechanism were investigated by various experimental methods.The experimental results showed that 2%HSR could improve the colloidal rate for drilling fluid from 6.4%to 84.8%,and the increase rate of yield point was up to 167%.Meanwhile,it also made the drilling fluid excellent in shear dilution and thixotropy.In addition,2%HSR could increase the density from 0.872 to 0.884 g/cm^(3) at-55 ficial.And the drilling fluid with 2%HSR had a good thermal conductivity of 0.1458 W/(m·K)at-55 ficial.This study gives a new direction for the research of drilling fluid treatment agents suitable for the Antarctic region,which will provide strong support for the scientific exploration of the Antarctic region.展开更多
Fins are extensively utilized in heat exchangers and various industrial applications as they are lightweight and can benefit in various systems,including electronic cooling devices and automotive components,owing to t...Fins are extensively utilized in heat exchangers and various industrial applications as they are lightweight and can benefit in various systems,including electronic cooling devices and automotive components,owing to their adaptable design.Furthermore,spine fins are introduced to improve performance in applications such as automotive radiators.They can be shaped in different ways and constructed from a collection of materials.Inspired by this,the present model examines the effects of internal heat generation and radiation-convection on the thermal distribution in a wetted convex-shaped spine fin.Using dimensionless terms,the proposed fin model involving a governing nonlinear ordinary differential equation(ODE)is transformed into a dimensionless form.The study uses the operational matrix with the Charlier polynomial collocation method(OMCCM)to ensure precise and computationally efficient numerical solutions for the dimensionless equation.In order to aid in the analysis of thermal performance,the importance of major parameters on the temperature profile is graphically illustrated.The main outcome of the study reveals that as the radiation-conductive,wet,and convective-conductive parameters increase,the heat transfer rate progressively improves.Conversely,the ambient temperature and internal heat generation parameters show an inverse relationship.展开更多
The extraordinary Super Typhoon(STY)Muifa(2022)made landfall four times and had a significant impact on the coastal regions from south to north of China.Although previous studies have demonstrated the‘pumping effect&...The extraordinary Super Typhoon(STY)Muifa(2022)made landfall four times and had a significant impact on the coastal regions from south to north of China.Although previous studies have demonstrated the‘pumping effect'of typhoons on the enhancement of reactive nitrogen(Nr)wet deposition over the ocean,it is uncertain how Nr deposition is influenced by typhoons thatmake prolonged mechanism due tomultiple landfalls.In this study,theNr wet deposition induced by STYMuifawas investigated fromthe perspective of in-and below-cloud processes based on the Nested Air Quality Prediction Modeling System with an online tracer-tagging module.High volume of Nr wet deposition caused by Muifa migrated from south to north,passing over half of China's coastal cities.Compared to the typhoon generated vicinity,both mean values of the oxidized and reduced nitrogen wet deposition over the Typhoon affected regions were increased about 20.4 and 66.1 times after landfall even with the similar rainfall.Emissions from the four landfall areas of China contributed to the majority of Nr wet deposition with significantly enhanced proportion of in-cloud deposition.The strong pumping effect of typhoon to the Nr deposition along the coastal areas and the risk of ecosystem effects requires further researches and higher demands on the control of nitrogen emissions of National Industrial Park,which usually located in China's coastal cities.展开更多
Hydropol a water-soluble,marine-safe,non-toxic polymer,is set to revolutionize the manufacture of hygiene products,suchas wet wipes and sanitary pads by making them dissolvable,fulyflushable and preventing them from f...Hydropol a water-soluble,marine-safe,non-toxic polymer,is set to revolutionize the manufacture of hygiene products,suchas wet wipes and sanitary pads by making them dissolvable,fulyflushable and preventing them from forming fatbergs in sewers andreleasing harmful microplastics.This is thanks to the developmentof a revolutionary new dissolvable nonwoven material(flat,poroussheets that are made directly from separate filbres or from moltenplastic or plastic film)which uses Hydropol instead of conventionalplastics and helps prevent tonnes of plastic pollution from enteringthe environment.展开更多
The multiscale variability in summer extreme persistent precipitation(SEPP)in China from 1961 to 2020 was investigated via three extreme precipitation indices:consecutive wet days,total precipitation amount,and daily ...The multiscale variability in summer extreme persistent precipitation(SEPP)in China from 1961 to 2020 was investigated via three extreme precipitation indices:consecutive wet days,total precipitation amount,and daily precipitation intensity.The relationships between precursory and concurrent global oceanic modes and SEPP were identified via a generalized linear model(GLM).The influence of oceanic modes on SEPP was finally investigated via numerical simulations.The results revealed that the climatological SEPP(≥14 days)mainly appears across the Tibetan Plateau,Yunnan–Guizhou Plateau,and South China coast.The first EOF mode for all three indices showed strong signals over the Yangtze River.Further analysis via the GLM suggested that the positive phases of the tropical North Atlantic(TNA)in autumn,ENSO in winter,the Indian Ocean Basin(IOB)in spring,and the western North Pacific(WNP)in summer emerged as the most effective precursory factors of SEPP,which could serve as preceding signals for future predictions,contributing 30.2%,36.4%,38.0%,and 55.6%,respectively,to the GLM.Sensitivity experiments revealed that SST forcing in all four seasons contributes to SEPP over China,whereas the winter and summer SST warming over the Pacific and Indian Ocean(IO)contributes the most.Diagnosis of the hydrological cycle suggested that water vapor advection predominantly originates from the western Pacific and IO in summer,driven by the strengthened subtropical high and Asian summer monsoon(ASM).The enhanced vertical water vapor transport is attributed to stronger upward motion across all four seasons.These findings are helpful for better understanding SEPP variabilities and their prediction under SST warming.展开更多
The wetting behavior of slag–coke is a crucial factor influencing the permeability of the lower part of the blast furnace.However,a systematic understanding of the wetting behavior and underlying mechanisms between t...The wetting behavior of slag–coke is a crucial factor influencing the permeability of the lower part of the blast furnace.However,a systematic understanding of the wetting behavior and underlying mechanisms between titanium-containing slag and tuyere coke remains lacking.The sessile drop method was employed to explore the effects of temperature,binary basicity,FeO,and TiO_(2) contents on the wetting behavior of titanium-containing slag and tuyere coke.The results indicate that increasing the temperature enhances the adhesion and wettability of the droplet,reducing the contact angle.Meanwhile,it accelerates the chemical reactions between slag and coke,leading to faster equilibrium.Conversely,increasing slag basicity elevates the contact angle by inhibiting chemical reactions at the slag–coke interface.This inhibition reduces both contact area and depth,thereby hindering slag droplet spreading on the coke surface.The contact angle decreases as the FeO content in the slag increases.Notably,the increase in TiO_(2) content has a dual effect on slag–coke wettability.Initially,it promotes wetting by reducing surface tension and lowering the contact angle.While the TiO_(2) content exceeds 20 wt.%,Ti(C,N)forms a barrier layer at the slag–coke interface,hindering the contact between slag and coke and resulting in an increased contact angle.展开更多
Analyzing the sources of nitrogen and phosphorus pollution in atmospheric deposition is crucial for protecting the surfacewater environment in vulnerable areas.This study focused on the Dahekou Reservoir,Shayuan Distr...Analyzing the sources of nitrogen and phosphorus pollution in atmospheric deposition is crucial for protecting the surfacewater environment in vulnerable areas.This study focused on the Dahekou Reservoir,Shayuan District,Xilin Gol League,Inner Mongolia,China.It established 12 monitoring sites,conducted one-year monitoring,and collected 144 samples.The concentrations of nitrogen,phosphorus,and water-soluble ions in atmospheric wet sedimentation were measured.This study identified atmospheric precipitation types,revealed seasonal variations in nitrogen and phosphorus concentrations,assessed the contribution of atmosphericwet sedimentation to reservoirwater quality.Utilizing the airmass backward trajectory(HYSPLIT)model and PMF model,themain pollution sources were analyzed.The results were as follows.1)During the observation period,the atmospheric precipitation types were nitric acid rain in spring,sulfuric acid rain in winter,and mixed acid rain in summer and autumn.2)The monthly concentrations of nitrogen and phosphorus of various forms varied significantly,with NH_(4)^(+)-N peaking in spring,NO_(3)^(-)-N and DOP in autumn,and DIP and DON in summer.Annual pollution loads of atmospheric nitrogen and phosphorus precipitation into the reservoir were 35.77 and 4.17 t/a,respectively,severely impacting reservoir water quality.3)Precipitation was negatively correlated with TN concentration,particularly with the NO_(3)^(-)-N/TN ratio,and positively correlated with TP and DIP concen-trations.4)The analysis of pollution sources indicated that the sources of atmospheric nitrogen and phosphorus wet deposition pollution in the study area included agricultural,anthropogenic,dust,and coal sources,with contribution rates of 32.4%,25.6%,21.0%,and 21.0%,respectively.展开更多
As a typical sedimentary soft rock,mudstone has the characteristics of being easily softened and disintegrated under the effect of wetting and drying(WD).The first cycle of WD plays an important role in the entire WD ...As a typical sedimentary soft rock,mudstone has the characteristics of being easily softened and disintegrated under the effect of wetting and drying(WD).The first cycle of WD plays an important role in the entire WD cycles.X-ray micro-computed tomography(micro-CT)was used as a non-destructive tool to quantitatively analyze microstructural changes of the mudstone due to the first cycle of WD.The test results show that WD leads to an increase of pore volume and pore connectivity in the mudstone.The porosity and fractal dimension of each slice of mudstone not only increase in value,but also in fluctuation amplitude.The pattern of variation in the frequency distribution of the equivalent radii of connected,isolated pores and pore throats in mudstone under WD effect satisfies the Gaussian distribution.Under the effect of WD,pores and pore throats with relatively small sizes increase the most.The sphericity of the pores in mudstones is positively correlated with the pore radius.The WD effect transforms the originally angular and flat pores into round and regular pores.This paper can provide a reference for the study of the deterioration and catastrophic mechanisms of mudstone under wetting and drying cycles.展开更多
基金financially supported by the National Natural Science Foundation of China(No.12304077)the Natural Science Foundation of Science and Technology Department of Sichuan Province(No.23NSFSC6224)+3 种基金Sichuan Science and Technology Program(No.2024NSFSC0989)the Key Laboratory of Computational Physics of Sichuan Province(No.YBUJSWL-YB-2022-03)the Material Corrosion and Protection Key Laboratory of Sichuan Province(No.2023CL14 and No.2023CL01)the National Innovation Practice Project(No.202411079005S).
文摘Oxygen release and electrolyte decomposition under high voltage endlessly exacerbate interfacial ramifications and structu ral degradation of high energy-density Li-rich layered oxide(LLO),leading to voltage and capacity fading.Herein,the dual-strategy of Cr,B complex coating and local gradient doping is simultaneously achieved on LLO surface by a one-step wet chemical reaction at room temperature.Density functional theory(DFT)calculations prove that stable B-O and Cr-O bonds through the local gradient doping can significantly reduce the high-energy O 2p states of interfacial lattice O,which is also effective for the near-surface lattice O,thus greatly stabilizing the LLO surface,Besides,differential electrochemical mass spectrometry(DEMS)indicates that the Cr_(x)B complex coating can adequately inhibit oxygen release and prevents the migration or dissolution of transition metal ions,including allowing speedy Li^(+)migration,The voltage and capacity fading of the modified cathode(LLO-C_(r)B)are adequately suppressed,which are benefited from the uniformly dense cathode electrolyte interface(CEI)composed of balanced organic/inorganic composition.Therefore,the specific capacity of LLO-CrB after 200 cycles at 1C is 209.3 mA h g^(-1)(with a retention rate of 95.1%).This dual-strategy through a one-step wet chemical reaction is expected to be applied in the design and development of other anionic redox cathode materials.
基金supported by the Basic Science Center Project for the National Natural Science Foundation of China(No.72088101)the S&T Program of Hebei(No.23564101D).
文摘As the bed depth increases,sintering yield increases,but the productivity decreases.To reveal the reasons for the decrease in productivity and explore targeted solutions,the bed resistance of mixtures,wet zone,and combustion zone was analyzed in the laboratory.The results showed that the decreased porosity of mixture resulted in the increased bed resistance by 160.56%when the bed depth increased from 600 to 1000 mm.After improving porosity of 1%by adding loosening bars with optimized size and distribution,the bed resistance decreased,and the productivity increased by 5%.The increase in bed depth increased the thickness of the wet zone from 120 to 680 mm and the resistance from 1.56 to 8.83 kPa.By using a three-stage intensive mixer and pre-adding water for granulation,the moisture of mixture was reduced by 0.6%,and the sintering productivity increased by 4%.Besides,the high bed resistance is mainly caused by the increase in the thickness of the combustion zone from 31.9 to 132.7 mm,and the bed resistance increased from 0.70 to 5.62 kPa.The bed resistance of the combustion zone at 900 mm was increased by 90.51%compared to 700 mm.After optimization of the distribution of coke breeze,the thickness of combustion zone at the lower layer decreased from 132.7 to 106.84 mm and permeability improved significantly.
基金supported by the National Natural Science Foundation of China(No.31988102)Yunnan Province Major Program for Basic Research Project(No.202101BC070002)+1 种基金Yunnan Province Science and Technology Talents and Platform Program(No.202305AA160014)Yunnan Province Key Research and Development Program of China(No.202303AC100009)。
文摘Forest structure is fundamental in determining ecosystem function,yet the impact of bamboo invasion on these structural characteristics remains unclear.We investigated 219 invasion transects at 41 sites across the distribution areas of Moso bamboo(Phyllostachys edulis)in China to explore the effects of bamboo invasion on forest structural attributes and diameter–height allometries by comparing paired plots of bamboo,mixed bamboo-tree,and non-bamboo forests along the transects.We found that bamboo invasion decreased the mean and maximum diameter at breast height,maximum height,and total basal area,but increased the mean height,stem density,and scaling exponent for stands.Bamboo also had a higher scaling exponent than tree,particularly in mixed forests,suggesting a greater allocation of biomass to height growth.As invasion intensity increased,bamboo allometry became more plastic and decreased significantly,whereas tree allometry was indirectly promoted by increasing stem density.Additionally,a humid climate may favour the scaling exponents for both bamboo and tree,with only minor contributions from topsoil moisture and nitrogen content.The inherent superiority of diameter–height allometry allows bamboo to outcompete tree and contributes to its invasive success.Our findings provide a theoretical basis for understanding the causes and consequences of bamboo invasion.
基金We gratefully acknowledge the financial support from the Key Laboratory of Geological Safety of Coastal Urban Underground Space,Ministry of Natural Resources(BHKF2022Y03)Shandong Provincial Colleges and Universities Youth Innovation Technology Support Program,Education Department of Shandong Province(grant number 2023KJ092).
文摘The study focuses on the creep characteristics of significant yellow sandstone for water conservancy, hydropower, and other waterrelated slope excavation unloading rock-graded loading creep characteristics. It conducts a uniaxial graded loading creep test on yellow sandstone under different pre-peak unloading and wetting-drying cycles. The improved nonlinear Nishihara model was obtained by introducing a nonlinear viscous element with an accelerated creep threshold switch. The sensitivity characteristics of the parameters of the improved creep model were analyzed and a nonlinear creep constitutive model was established, considering the unloading-cyclic intrinsic damage induced by water intrusion. The research results show that:(1)With an increase in the unloading point, the porosity of the rock samples initially decreases and then increases. As the number of cyclic water intrusions rises, the porosity of the rock samples gradually increases, reaching a maximum of 9.58% at an unloading point of 70% uniaxial compression stress(0.7 Rc) after five cycles.(2) Total creep deformation increases with the number of cyclic water intrusions;however, with an increase in the unloading ratio, the original samples show an initial decrease, followed by an increase in creep deformation. With a higher unloading ratio and various instances of cyclic water intrusion, the total creep time of the rock samples,compared to the original samples, is reduced by 21.8%and 23.02%. The creep damage mode gradually changes from shear damage to tensile damage.(3) The sensitivity characteristics of the improved creep model parameters show that transient elasticity modulus E1 is affected by the coupling of unloading and cyclic water intrusion. The viscoelastic modulus E2 and viscous coefficient η1 are mainly affected by unloading and cyclic water intrusion.(4) Based on the strain equivalence principle of damage mechanics, the damage treatment of the parameters in the original model is improved to construct a nonlinear creep constitutive model that considers unloading-cyclic water intrusion damage. A parameter inversion and comparison to the traditional Nishihara model reveal an average relative standard deviation of 0.271%,significantly less than 1%, indicating a more accurate nonlinear creep constitutive model. The research results are crucial for analyzing the long-term stability of water-related steep rocky slopes post-excavation and unloading and for preventing and controlling creep-type landslide disasters.
基金Doctoral Research Start-up Fund of Lanzhou University of Arts and Science(2021-9)Innovation Fund for Colleges and Universities of Gansu Province,China(2022B-265)。
文摘The wetting behavior of liquid tin(Sn)solder on copper(Cu)substrate at 250℃was investigated by the wetting balance method under the action of direct current(DC).The curves of wetting balance were measured and the morphology of the intermetallic compound(IMC)precipitated at the interface were observed.Results show that DC has a significant effect on the wettability and IMC.As the current increases,the balance wetting force and the thickness of the IMC layer increase.The direction of the DC also has a certain effect on the balance wetting force and IMC layer.When the current is negative,the final balance wetting force and the thickness of the Cu_(6)Sn_(5) layer are significantly higher than those in the positive current case,which is attributed to electromigration.The IMC precipitation at the interface provides a chemical driving force for the movement of the triple junction.The interaction of the interface atoms and the chemical reaction are enhanced by DC,thereby improving wettability.Meanwhile,the Marangoni convection caused by DC inside liquid Sn solder changes the structure of triple junction,which provides a physical driving force for the spread of the liquid Sn solder on the Cu substrate.
文摘In this paper,the effect of sodium laurate(SL)on the properties of sodium lauroyl glutamate(SLG),such as surface activity,foam,wetting,emulsification,and resistance to hard water,has been systematically investigated.The results showed that the critical micelle concentration(cmc)of SLG was 0.30 mmol/L,and the surface tension at the cmc(γcmc)was 34.95 mN/m.With the increase of SL content,the efficiency of SLG solution in reducing the surface tension was decreased.When the SL content was increased,there was no significant change in the foaming ability and foam stability of SLG solutions.The increase of SL content improved both the emulsification and wettability of SLG,but reduced its water resistance.
文摘Wet wipes have become an indispensable part of modern life,offering convenience whether used for personal hygiene,baby care,or household cleaning.Wet wipes made of different materials each have their own characteristics,which not only directly affect the comfort and performance during use but are also closely related to environmental protection.Understanding their differences can help consumers make more informed choices—ones that meet daily needs while reducing the environmental burden.
基金supported by National Natural Science Foundation of China(No.52403042)China Postdoctoral Science Foundation(No.2023M742472)。
文摘Wound dressings with tissue adhesion,good mechanical,antioxidant and anti-inflammatory performance are urgently needed.In this work,we present a multifunctional selenium nanoparticles(SeNPs)/citric acid/gelatin/hydroxysuccinimide-grafted polyacrylic acid nanocomposite hydrogel adhesive(SCA) specifically designed for wound healing applications.The SCA was prepared via a one-pot processing,where SeNPs synthesized via chemical reduction were incorporated.These SeNPs not only endowed SCA with robust wet adhesion ability,excellent stretchability,and skin-matched elasticity modulus by serving as a physical crosslinker to modulate swelling equilibrium and molecular slippage,but also enhanced the biocompatibility and free radical scavenging capacity of SCA.Furthermore,in vivo evaluation of full-thickness cutaneous defects of rats revealed that SCA effectively reduced inflammation,promoted wound closure,and increased collagen deposition.All these results demonstrated that the developed SCA offers a promising therapeutic strategy for wound healing applications.
基金supported by the National Key R&D Program of China(2023YFF0614301,2023YFC3707004,and 2018YFB0604302)Fundamental Research Funds for the Central Universities(No.2022MS041)+1 种基金National Natural Science Foundation of China(No.22106084)Tsinghua University Initiative Scientific Research Program(2023Z02JMP001).
文摘An innovative strategy was proposed by integration of membrane contactor(MC)with biphasic solvent for efficient CO_(2) capture from flue gas.The accessible fly ash-based ceramic membrane(CM)underwent hydrophobic modification through silane grafting,followed by fluoroalkylsilane decoration,to prepare the superhydrophobic membrane(CSCM).The CSCM significantly improved resistance to wetting by the biphasic solvent,consisting of amine(DETA)and sulfolane(TMS).Morphological characterizations and chemical analysis revealed the notable enhancements in pore structure and hydrophobic chemical groups for the modified membrane.Predictions of wetting/bubbling behavior based on static wetting theory referred the liquid entry pressure(LEP)of CSCM increased by 20 kPa compared to pristine CM.Compared with traditional amine solvents,the biphasic solvent presented the expected phase separation.Performance experiments demonstrated that the CO_(2) capture efficiency of the biphasic solvent increased by 7%,and the electrical energy required for desorption decreased by 32%.The 60-h continuous testing and supplemental characterization of used membrane confirmed the excellent adaptability and durability of the CSCMs.This study provides a potential approach for accessing hydrophobic ceramic membranes and biphasic solvents for industrial CO_(2) capture.
文摘The main raw material utilized in wood adhesives comes from petrochemical extractives.However,due to the excessive dependence on petrochemical resources and the adverse impact on the ecosystem and human wellbeing,there is an increasing trend to develop byproduct protein-based adhesives in the current global food safety context.In this research,flaxseed meal was subjected to pretreatment,and trimethylolpropane triglycidyl ether(TTE)and ethylenediamine(EN)were utilized as crosslinkers to establish a more compact adhesive layer and to prevent water intrusion.The pretreatment decreased the FM/UB viscosity by 60%compared to FM.The combination of CD analysis indicated that the Urea-NaOH pretreatment effectively stretched the flaxseed meal protein.According to Fourier transform infrared(FTIR)spectroscopy,X-ray diffraction(XRD),and differential scanning calorimetry(DSC)were used to analyze the resulting adhesive’s reaction mechanism and thermal response.Furthermore,the physical properties of the adhesive were characterized using wet shear strength testing and SEM observation.Remarkably,the dry bond strength increased from 0.72 to 2.12 MPa,representing a 194.4%increase.The wet bonding strength of the adhesive was improved from 0.22 to 1.21 MPa,representing a 550%increase compared to the original flaxseed protein-based adhesive,which far exceeded the minimum requirement for plywood of Type II(≥0.7 MPa,by GB/T 9846-2015).This study demonstrated an eco-friendly and sustainable method for the development of protein adhesives as viable substitutes for petrochemical resins.
基金Supported by the National Natural Science Foundation of China(No.32060270)the Project for Innovation and Entrepreneurship of High level Overseas Talents in Guizhou(No.(2020)09)。
文摘Phytoplankton plays a crucial role in the energy flow and nutrient cycling of aquatic ecosystems.To understand the spatial and temporal distribution of phytoplankton in the Wujiang River,Yungui Plateau,SW China,samples were collected in 12 locations in wet and dry seasons and analyzed.We hypothesized that phytoplankton assemblages would exhibit significant temporal variability,with niche breadths of dominant species fluctuating seasonally,leading to distinct patterns of species association and community stability.Results show differences in community structure between the two seasons,but such changes did not cause non-significant differences inα-diversity.Diatoms were dominant in the assemblages in terms of biomass,while the numerical abundance of Cyanobacteria was highest in the wet season due to their relatively small cells.Rainfall-driven changes in runoff significantly altered nutrient availability,which in turn strongly affected phytoplankton structure.The more intense water flow contributed to a greaterβ-diversity in the wet season,driven primarily by species replacement,with stochastic processes played a more important role during the dry season.In the dry season,dominant species exhibited a broader niche breadth and greater niche overlap,along with more positive species associations,suggesting a more stable and resilient community structure.Conversely,in the wet season,species had narrower niche breadth and less niche overlap,leading to a less stable community.Both negative and positive species associations were observed,indicating a complex balance between environmental filtering and competition within the assemblages.These findings provide important insights into how seasonal environmental changes,particularly water flow and nutrient dynamics,shape phytoplankton communities in aquatic ecosystems.Understanding the mechanisms driving changes in community and stability is critical for predicting the impacts of climate change and managing aquatic biodiversity,as fluctuations in water flow and nutrient input may alter ecosystem functioning and productivity.
基金supported by the National Natural Science Foundation of China(Nos.42121004,42275107,and 42077205)the National Key Research and Development Plan(No.2023YFC3706202)+1 种基金the Foundational and Applied Basic Research in Guangzhou in 2023(No.2023A04J0251)the Special Fund Project for Science and Technology Innovation Strategy of Guangdong Province(No.2019B121205004)。
文摘This study tracked the characteristics of atmospheric wet deposition of the toxic element arsenic(As)at both urban(Guangzhou(GZ))and forested(Dinghushan Natural Reserve(DHS))sites within the Pearl River Delta(PRD)region between 2016 and 2019,examining its correlation with rainfall patterns.Additionally,by employing backward trajectory analysis and the potential source contribution function(PSCF)in conjunction with pertinent emission inventories,we pinpointed the main pathways of atmospheric arsenic transport and evaluated the emission contributions from priority source areas.The study revealed that the atmospheric arsenic wet deposition fluxes at the GZ and DHS sites exhibited a trend of increase followed by a decrease over the four-year period.Wet season deposition fluxes were more than triple those of the dry season,with urban site showing a difference of over four times.Notably,wet season As deposition at both sites was predominantly affected by heavy rainfall from marine air masses,constituting 31%of the total deposition.The predominant trajectory directions contributing to arsenic deposition at GZ and DHS were northeast(55%)and south(53%),respectively.The primary source areas for both sites were largely outside the PRD region,with the GZ site having 80%to 95%of its source area in the non-PRD region,compared to 69%to 88%at the DHS site.Furthermore,non-PRD areas contributed approximately 65%to arsenic emissions for both sites,with the industrial sector being the dominant emission source,exceeding 97%of the total emissions.
基金financially supported by the National Natural Science Foundation of China(No.52274021)the National Key Research and Development Program of China(No.2021YFA0719102)。
文摘Antarctica contains numerous scientific mysteries,and the Antarctic ice sheet and its underlying bedrock contain important information about the geological structure of Antarctica and the evolutionary history of the ice sheet.In order to obtain the focus of these scientific explorations,the Antarctic drilling engineering is constantly developing.The drilling fluid performance directly determines the success or failure of drilling engineering.In order to enhance the poor performance for drilling fluids due to poor dispersion stability and easy settling of organoclay at ultra-low temperatures,the small-molecule wetting agent(HSR)for drilling fluid suitable for Antarctica was prepared by oleic acid,diethanolamine and benzoic acid as raw materials.Its chemical structure,properties and action mechanism were investigated by various experimental methods.The experimental results showed that 2%HSR could improve the colloidal rate for drilling fluid from 6.4%to 84.8%,and the increase rate of yield point was up to 167%.Meanwhile,it also made the drilling fluid excellent in shear dilution and thixotropy.In addition,2%HSR could increase the density from 0.872 to 0.884 g/cm^(3) at-55 ficial.And the drilling fluid with 2%HSR had a good thermal conductivity of 0.1458 W/(m·K)at-55 ficial.This study gives a new direction for the research of drilling fluid treatment agents suitable for the Antarctic region,which will provide strong support for the scientific exploration of the Antarctic region.
基金the Deanship of Research and Graduate Studies at King Khalid University for funding this work through Large Research Project under grant number RGP2/308/46。
文摘Fins are extensively utilized in heat exchangers and various industrial applications as they are lightweight and can benefit in various systems,including electronic cooling devices and automotive components,owing to their adaptable design.Furthermore,spine fins are introduced to improve performance in applications such as automotive radiators.They can be shaped in different ways and constructed from a collection of materials.Inspired by this,the present model examines the effects of internal heat generation and radiation-convection on the thermal distribution in a wetted convex-shaped spine fin.Using dimensionless terms,the proposed fin model involving a governing nonlinear ordinary differential equation(ODE)is transformed into a dimensionless form.The study uses the operational matrix with the Charlier polynomial collocation method(OMCCM)to ensure precise and computationally efficient numerical solutions for the dimensionless equation.In order to aid in the analysis of thermal performance,the importance of major parameters on the temperature profile is graphically illustrated.The main outcome of the study reveals that as the radiation-conductive,wet,and convective-conductive parameters increase,the heat transfer rate progressively improves.Conversely,the ambient temperature and internal heat generation parameters show an inverse relationship.
基金supported by the National Natural Science Foundation of China(Nos.42122049 and 42377104)the Basic Strengthening Research Program(No.2021-JCJQ-JJ-1058)+1 种基金the Strategy Priority Research Programof Chinese Academy of Sciences(No.XDB0760403)the National Key Scientific and Technological Infrastructure project"Earth System Science Numerical Simulator Facility"(EarthLab)the Innovation Foundation of CPML/CMA(No.2024CPML-C027).
文摘The extraordinary Super Typhoon(STY)Muifa(2022)made landfall four times and had a significant impact on the coastal regions from south to north of China.Although previous studies have demonstrated the‘pumping effect'of typhoons on the enhancement of reactive nitrogen(Nr)wet deposition over the ocean,it is uncertain how Nr deposition is influenced by typhoons thatmake prolonged mechanism due tomultiple landfalls.In this study,theNr wet deposition induced by STYMuifawas investigated fromthe perspective of in-and below-cloud processes based on the Nested Air Quality Prediction Modeling System with an online tracer-tagging module.High volume of Nr wet deposition caused by Muifa migrated from south to north,passing over half of China's coastal cities.Compared to the typhoon generated vicinity,both mean values of the oxidized and reduced nitrogen wet deposition over the Typhoon affected regions were increased about 20.4 and 66.1 times after landfall even with the similar rainfall.Emissions from the four landfall areas of China contributed to the majority of Nr wet deposition with significantly enhanced proportion of in-cloud deposition.The strong pumping effect of typhoon to the Nr deposition along the coastal areas and the risk of ecosystem effects requires further researches and higher demands on the control of nitrogen emissions of National Industrial Park,which usually located in China's coastal cities.
文摘Hydropol a water-soluble,marine-safe,non-toxic polymer,is set to revolutionize the manufacture of hygiene products,suchas wet wipes and sanitary pads by making them dissolvable,fulyflushable and preventing them from forming fatbergs in sewers andreleasing harmful microplastics.This is thanks to the developmentof a revolutionary new dissolvable nonwoven material(flat,poroussheets that are made directly from separate filbres or from moltenplastic or plastic film)which uses Hydropol instead of conventionalplastics and helps prevent tonnes of plastic pollution from enteringthe environment.
基金jointly funded by the National Natural Science Foundation of China(Grant Nos.42122035,42288101,42130605,72293604,42475179,and 42475020)the support of the Guangdong Provincial Observation and Research Station for Tropical Ocean Environment in Western Coastal Waters(GSTOEW)+2 种基金Key Laboratory of Space Ocean Remote Sensing and ApplicationCMAGDOU Joint Laboratory for Marine MeteorologyKey Laboratory of Climate Resources and Environment in Continental Shelf Sea and Deep Ocean(LCRE)。
文摘The multiscale variability in summer extreme persistent precipitation(SEPP)in China from 1961 to 2020 was investigated via three extreme precipitation indices:consecutive wet days,total precipitation amount,and daily precipitation intensity.The relationships between precursory and concurrent global oceanic modes and SEPP were identified via a generalized linear model(GLM).The influence of oceanic modes on SEPP was finally investigated via numerical simulations.The results revealed that the climatological SEPP(≥14 days)mainly appears across the Tibetan Plateau,Yunnan–Guizhou Plateau,and South China coast.The first EOF mode for all three indices showed strong signals over the Yangtze River.Further analysis via the GLM suggested that the positive phases of the tropical North Atlantic(TNA)in autumn,ENSO in winter,the Indian Ocean Basin(IOB)in spring,and the western North Pacific(WNP)in summer emerged as the most effective precursory factors of SEPP,which could serve as preceding signals for future predictions,contributing 30.2%,36.4%,38.0%,and 55.6%,respectively,to the GLM.Sensitivity experiments revealed that SST forcing in all four seasons contributes to SEPP over China,whereas the winter and summer SST warming over the Pacific and Indian Ocean(IO)contributes the most.Diagnosis of the hydrological cycle suggested that water vapor advection predominantly originates from the western Pacific and IO in summer,driven by the strengthened subtropical high and Asian summer monsoon(ASM).The enhanced vertical water vapor transport is attributed to stronger upward motion across all four seasons.These findings are helpful for better understanding SEPP variabilities and their prediction under SST warming.
基金supported by the Postdoctor Project of Hubei Province(2024HBBHCXA074)National Natural Science Foundation of China(51974212)+2 种基金China Baowu Low Carbon Metallurgy Innovation Foundation(BWLCF202116)Foundation of Hubei Provincial Key Laboratory for New Processes of Ironmaking and Steelmaking(NPISlab25-03)Science and Technology Major Project of Wuhan(2023020302020572).
文摘The wetting behavior of slag–coke is a crucial factor influencing the permeability of the lower part of the blast furnace.However,a systematic understanding of the wetting behavior and underlying mechanisms between titanium-containing slag and tuyere coke remains lacking.The sessile drop method was employed to explore the effects of temperature,binary basicity,FeO,and TiO_(2) contents on the wetting behavior of titanium-containing slag and tuyere coke.The results indicate that increasing the temperature enhances the adhesion and wettability of the droplet,reducing the contact angle.Meanwhile,it accelerates the chemical reactions between slag and coke,leading to faster equilibrium.Conversely,increasing slag basicity elevates the contact angle by inhibiting chemical reactions at the slag–coke interface.This inhibition reduces both contact area and depth,thereby hindering slag droplet spreading on the coke surface.The contact angle decreases as the FeO content in the slag increases.Notably,the increase in TiO_(2) content has a dual effect on slag–coke wettability.Initially,it promotes wetting by reducing surface tension and lowering the contact angle.While the TiO_(2) content exceeds 20 wt.%,Ti(C,N)forms a barrier layer at the slag–coke interface,hindering the contact between slag and coke and resulting in an increased contact angle.
基金supported by Inner Mongolia Autonomous Region Department of Education Science and Technology Talent Project(No.NJYT22040)Inner Mongolia Agricultural University Young Teachers'Scientific Research Ability Promotion Project(No.BR220102)+4 种基金the National Natural Science Foundation of China(No.52260029)the National Key R&D Program(No.2019YFC0409204)Inner Mongolia Natural Science Foundation(No.2021MS04013)the Science and Technology Project of Inner Mongolia Autonomous Region(No.2023YFHH0060)Inner Mongolia AutonomousRegion Science and Technology Leading TalentTeam(No.2022LJRC0007).
文摘Analyzing the sources of nitrogen and phosphorus pollution in atmospheric deposition is crucial for protecting the surfacewater environment in vulnerable areas.This study focused on the Dahekou Reservoir,Shayuan District,Xilin Gol League,Inner Mongolia,China.It established 12 monitoring sites,conducted one-year monitoring,and collected 144 samples.The concentrations of nitrogen,phosphorus,and water-soluble ions in atmospheric wet sedimentation were measured.This study identified atmospheric precipitation types,revealed seasonal variations in nitrogen and phosphorus concentrations,assessed the contribution of atmosphericwet sedimentation to reservoirwater quality.Utilizing the airmass backward trajectory(HYSPLIT)model and PMF model,themain pollution sources were analyzed.The results were as follows.1)During the observation period,the atmospheric precipitation types were nitric acid rain in spring,sulfuric acid rain in winter,and mixed acid rain in summer and autumn.2)The monthly concentrations of nitrogen and phosphorus of various forms varied significantly,with NH_(4)^(+)-N peaking in spring,NO_(3)^(-)-N and DOP in autumn,and DIP and DON in summer.Annual pollution loads of atmospheric nitrogen and phosphorus precipitation into the reservoir were 35.77 and 4.17 t/a,respectively,severely impacting reservoir water quality.3)Precipitation was negatively correlated with TN concentration,particularly with the NO_(3)^(-)-N/TN ratio,and positively correlated with TP and DIP concen-trations.4)The analysis of pollution sources indicated that the sources of atmospheric nitrogen and phosphorus wet deposition pollution in the study area included agricultural,anthropogenic,dust,and coal sources,with contribution rates of 32.4%,25.6%,21.0%,and 21.0%,respectively.
基金Project(41877240)supported by the National Natural Science Foundation of China。
文摘As a typical sedimentary soft rock,mudstone has the characteristics of being easily softened and disintegrated under the effect of wetting and drying(WD).The first cycle of WD plays an important role in the entire WD cycles.X-ray micro-computed tomography(micro-CT)was used as a non-destructive tool to quantitatively analyze microstructural changes of the mudstone due to the first cycle of WD.The test results show that WD leads to an increase of pore volume and pore connectivity in the mudstone.The porosity and fractal dimension of each slice of mudstone not only increase in value,but also in fluctuation amplitude.The pattern of variation in the frequency distribution of the equivalent radii of connected,isolated pores and pore throats in mudstone under WD effect satisfies the Gaussian distribution.Under the effect of WD,pores and pore throats with relatively small sizes increase the most.The sphericity of the pores in mudstones is positively correlated with the pore radius.The WD effect transforms the originally angular and flat pores into round and regular pores.This paper can provide a reference for the study of the deterioration and catastrophic mechanisms of mudstone under wetting and drying cycles.
