Wetting deformation in earth-rockfill dams is a critical factor influencingdam safety.Although numerous mathematical models have been developed to describe this phenomenon,most of them rely on empirical formulations a...Wetting deformation in earth-rockfill dams is a critical factor influencingdam safety.Although numerous mathematical models have been developed to describe this phenomenon,most of them rely on empirical formulations and lack prior knowledge of model parameters,which is essential for Bayesian parameter inversion to enhance accuracy and reduce uncertainty.This study introduces a datadriven approach to establishing prior knowledge of earth-rockfill dams.Driving factors are utilized to determine the potential range of model parameters,and settlement changes within this range are calculated.The results are iteratively compared with actual monitoring data until the calculated range encompasses the observed data,thereby providing prior knowledge of the model parameters.The proposed method is applied to the right-bank earth-rockfilldam of Danjiangkou.Employing a Gibbs sample size of 30,000,the proposed method effectively calibrates the prior knowledge of the wetting model parameters,achieving a root mean square error(RMSE)of 5.18 mm for the settlement predictions.By comparison,the use of non-informative priors with sample sizes of 30,000 and 50,000 results in significantly larger RMSE values of 11.97 mm and 16.07 mm,respectively.Furthermore,the computational efficiencyof the proposed method is demonstrated by an inversion computation time of 902 s for 30,000 samples,which is notably shorter than the 1026 s and 1558 s required for noninformative priors with 30,000 and 50,000 samples,respectively.These findingsunderscore the superior performance of the proposed approach in terms of both prediction accuracy and computational efficiency.These results demonstrate that the proposed method not only improves the predictive accuracy but also enhances the computational efficiency,enabling optimal parameter identificationwith reduced computational effort.This approach provides a robust and efficientframework for advancing dam safety assessments.展开更多
BACKGROUND Orthopaedic surgical education has traditionally depended on the apprenticeship model of“see one,do one,teach one”.However,reduced operative exposure,stricter work-hour regulations,medicolegal constraints...BACKGROUND Orthopaedic surgical education has traditionally depended on the apprenticeship model of“see one,do one,teach one”.However,reduced operative exposure,stricter work-hour regulations,medicolegal constraints,and patient safety concerns have constrained its practicality.Simulation-based training has become a reliable,safe,and cost-efficient alternative.Dry lab techniques,especially virtual and augmented reality,make up 78%of current dry lab research,whereas wet labs still set the standard for anatomical realism.AIM To evaluate the effectiveness,limitations,and future directions of wet and dry lab simulation in orthopaedic training.METHODS A scoping review was carried out across four databases-PubMed,Cochrane Library,Web of Science,and EBSCOhost-up to 2025.Medical Subject Headings included:"Orthopaedic Education","Wet Lab","Dry Lab","Simulation Training","Virtual Reality",and"Surgical Procedure".Eligible studies focused on orthopaedic or spinal surgical education,employed wet or dry lab techniques,and assessed training effectiveness.Exclusion criteria consisted of non-English publications,abstracts only,non-orthopaedic research,and studies unrelated to simulation.Two reviewers independently screened titles,abstracts,and full texts,resolving discrepancies with a third reviewer.RESULTS From 1851 records,101 studies met inclusion:78 on dry labs,7 on wet labs,4 on both.Virtual reality(VR)simulations were most common,with AI increasingly used for feedback and assessment.Cadaveric training remains the gold standard for accuracy and tactile feedback,while dry labs-especially VR-offer scalability,lower cost(40%-60%savings in five studies),and accessibility for novices.Senior residents prefer wet labs for complex tasks;juniors favour dry labs for basics.Challenges include limited transferability data,lack of standard outcome metrics,and ethical concerns about cadaver use and AI assessment.CONCLUSION Wet and dry labs each have unique strengths in orthopaedic training.A hybrid approach combining both,supported by standardised assessments and outcome studies,is most effective.Future efforts should aim for uniform reporting,integrating new technologies,and policy support for hybrid curricula to enhance skills and patient care.展开更多
To explore mix proportion design of RAC with aggregates tightly packed,the dry and wet packing density of recycled coarse aggregates mixture system and recycled coarse and fine aggregates were tested,then the influenc...To explore mix proportion design of RAC with aggregates tightly packed,the dry and wet packing density of recycled coarse aggregates mixture system and recycled coarse and fine aggregates were tested,then the influence of replacement rate and particle size ratio on the packing density of particle system was explored,the packing density prediction model of recycled coarse aggregates based on particle morphology was constructed,and the mix proportion optimization for recycled aggregate concrete with dry-wet packing model was carried out.The experimental results show that,with the increasing of recycled aggregate replacement rate or fine-grained volume ratio,the dry packing density of recycled coarse aggregates decreases gradually.With the increasing of replacement rate,the particle gradation can be optimized by increasing coarsegrained volume ratio.There is a significant effect for particle morphology parameter K and the particle size ratio on the packing density of the binary mixed system,and the packing density prediction model of recycled coarse aggregates based on particle morphology was constructed.The maximum increase in compressive strength and tensile strength of RAC with mix proportion optimized by the dry-wet packing model are 12.94%and 11.09%,and the cementitious materials is reduced by 21.83%,then the superiority of the mix proportion optimization of RAC with the dry-wet close packing model is confirmed.The results of this paper can provide a theoretical basis for the mix proportion design of RAC.展开更多
In the field of rock engineering,the influence of water is a dynamic process that exhibits varying effects over time and across different locations.To further understand how water influences the mechanical properties ...In the field of rock engineering,the influence of water is a dynamic process that exhibits varying effects over time and across different locations.To further understand how water influences the mechanical properties and acoustic emission(AE)behavior of rocks,this study conducted uniaxial compression experiments on sandstones with varying degrees of wetting under both natural conditions and water-chemical environments.In addition,the study combined AE equipment with digital image correlation(DIC)to monitor the entire failure process.Using the sliding window algorithm,the variation in the variance of AE characteristic parameters during the process of sandstone loading to failure is analyzed from the perspective of critical slowing down.This analysis enables the effective identification of the early warning signal before failure.The experimental findings suggest that an increase in wetting height results in a gradual decrease in peak stress,accompanied by a concomitant increase in the percentage of shear cracks.The characteristic parameters,including energy,amplitude,and ringing count,all exhibit critical slowing phenomena.The waveform of AE characteristic parameters of the same sample is similar,and the mutation time of the precursor signal is roughly the same.All signals appear in the irreversible plastic deformation stage of microcrack initiation.The integration of critical slowing down theory and the b-value early warning method facilitates a more comprehensive evaluation of the stability of rock mass,thereby significantly enhancing the efficiency and safety of disaster prevention measures.展开更多
Alternate wetting and drying irrigation(AWD)significantly influences the cooking and eating quality of rice(Oryza sativa L.).However,the mechanisms by which AWD affects rice cooking and eating quality remain unclear.L...Alternate wetting and drying irrigation(AWD)significantly influences the cooking and eating quality of rice(Oryza sativa L.).However,the mechanisms by which AWD affects rice cooking and eating quality remain unclear.Lipid and free fatty acid contents in grains correlate positively with cooking and eating quality of rice.This study examined Yangdao 6(YD6,a conventional taste indica inbred)and Nanjing 9108(NJ9108,a superior taste japonica inbred)cultivated under conventional irrigation(CI),alternate wetting and moderate drying irrigation(AWMD),and alternate wetting and severe drying irrigation(AWSD)from 10 days after transplanting to maturity.The research investigated the relationship between lipid and free fatty acid biosynthesis in grains and the cooking and eating quality of rice.Compared to CI treatment,AWMD significantly enhanced the contents of lipid,total free fatty acids(TFFAs),free unsaturated fatty acids(FUFAs),linoleic acid,and oleic acid in milled rice by increasing activities of enzymes associated with lipid synthesis,while AWSD produced opposite effects.Correlation analysis revealed that elevated levels of lipid,TFFAs,FUFAs,linoleic acid,and oleic acid contribute to improved rice cooking and eating quality.The findings demonstrate that AWMD enhances cooking and eating quality of milled rice through optimization of lipid and fatty acid synthesis in rice grains.展开更多
Extensive engineering experience and research findings suggest that rock mass instability is typically attributed to human engineering activities and natural disturbances,resulting in general dynamic mechanical proper...Extensive engineering experience and research findings suggest that rock mass instability is typically attributed to human engineering activities and natural disturbances,resulting in general dynamic mechanical properties.This is attributed to external interference resulting from the extensive use of the mechanical and blasting techniques necessary for mineral extraction.Quantifying the impact of dynamic disturbances on rock deformation behavior is essential for comprehending the long-term response of surrounding rock during excavation.This study placed the rock to sustained pressure and investigated the impact of varying hammer heights and dry and wet(W-D)damage on its shear failure behavior.This study investigated the fatigue disturbance studies on W-D damaged sandstone samples via W-D equipment,a disturbance creep device,digital image correlation(DIC),and acoustic emission(AE)technology.The experimental findings suggest that acoustic emission sensors can be utilized to quantify the internal damage of rock samples during cyclic impact,whereas DIC technology(optical measurement)is capable of capturing the surface crack propagation of samples.Under repeated impact and the combined action of W-D conditions,the bearing capacity of sandstone decreases,whereas the deformation capacity increases.Furthermore,the W-D cycles and impact strength are inversely related to the fatigue life.The intensity of W-D damage and disturbances further accelerates the development and propagation of cracks under cyclic disturbances.The research results are of preventive significance to ensure the safety and sustainable development of engineering construction.展开更多
Oxygen release and electrolyte decomposition under high voltage endlessly exacerbate interfacial ramifications and structu ral degradation of high energy-density Li-rich layered oxide(LLO),leading to voltage and capac...Oxygen release and electrolyte decomposition under high voltage endlessly exacerbate interfacial ramifications and structu ral degradation of high energy-density Li-rich layered oxide(LLO),leading to voltage and capacity fading.Herein,the dual-strategy of Cr,B complex coating and local gradient doping is simultaneously achieved on LLO surface by a one-step wet chemical reaction at room temperature.Density functional theory(DFT)calculations prove that stable B-O and Cr-O bonds through the local gradient doping can significantly reduce the high-energy O 2p states of interfacial lattice O,which is also effective for the near-surface lattice O,thus greatly stabilizing the LLO surface,Besides,differential electrochemical mass spectrometry(DEMS)indicates that the Cr_(x)B complex coating can adequately inhibit oxygen release and prevents the migration or dissolution of transition metal ions,including allowing speedy Li^(+)migration,The voltage and capacity fading of the modified cathode(LLO-C_(r)B)are adequately suppressed,which are benefited from the uniformly dense cathode electrolyte interface(CEI)composed of balanced organic/inorganic composition.Therefore,the specific capacity of LLO-CrB after 200 cycles at 1C is 209.3 mA h g^(-1)(with a retention rate of 95.1%).This dual-strategy through a one-step wet chemical reaction is expected to be applied in the design and development of other anionic redox cathode materials.展开更多
As the bed depth increases,sintering yield increases,but the productivity decreases.To reveal the reasons for the decrease in productivity and explore targeted solutions,the bed resistance of mixtures,wet zone,and com...As the bed depth increases,sintering yield increases,but the productivity decreases.To reveal the reasons for the decrease in productivity and explore targeted solutions,the bed resistance of mixtures,wet zone,and combustion zone was analyzed in the laboratory.The results showed that the decreased porosity of mixture resulted in the increased bed resistance by 160.56%when the bed depth increased from 600 to 1000 mm.After improving porosity of 1%by adding loosening bars with optimized size and distribution,the bed resistance decreased,and the productivity increased by 5%.The increase in bed depth increased the thickness of the wet zone from 120 to 680 mm and the resistance from 1.56 to 8.83 kPa.By using a three-stage intensive mixer and pre-adding water for granulation,the moisture of mixture was reduced by 0.6%,and the sintering productivity increased by 4%.Besides,the high bed resistance is mainly caused by the increase in the thickness of the combustion zone from 31.9 to 132.7 mm,and the bed resistance increased from 0.70 to 5.62 kPa.The bed resistance of the combustion zone at 900 mm was increased by 90.51%compared to 700 mm.After optimization of the distribution of coke breeze,the thickness of combustion zone at the lower layer decreased from 132.7 to 106.84 mm and permeability improved significantly.展开更多
Forest structure is fundamental in determining ecosystem function,yet the impact of bamboo invasion on these structural characteristics remains unclear.We investigated 219 invasion transects at 41 sites across the dis...Forest structure is fundamental in determining ecosystem function,yet the impact of bamboo invasion on these structural characteristics remains unclear.We investigated 219 invasion transects at 41 sites across the distribution areas of Moso bamboo(Phyllostachys edulis)in China to explore the effects of bamboo invasion on forest structural attributes and diameter–height allometries by comparing paired plots of bamboo,mixed bamboo-tree,and non-bamboo forests along the transects.We found that bamboo invasion decreased the mean and maximum diameter at breast height,maximum height,and total basal area,but increased the mean height,stem density,and scaling exponent for stands.Bamboo also had a higher scaling exponent than tree,particularly in mixed forests,suggesting a greater allocation of biomass to height growth.As invasion intensity increased,bamboo allometry became more plastic and decreased significantly,whereas tree allometry was indirectly promoted by increasing stem density.Additionally,a humid climate may favour the scaling exponents for both bamboo and tree,with only minor contributions from topsoil moisture and nitrogen content.The inherent superiority of diameter–height allometry allows bamboo to outcompete tree and contributes to its invasive success.Our findings provide a theoretical basis for understanding the causes and consequences of bamboo invasion.展开更多
Volcanic ashes are posing increasingly severer threats to the aviation safety.As the operation temperature of the turbine engine elevates,molten volcanic ash leads to the degradation of the thermal barrier coatings(TB...Volcanic ashes are posing increasingly severer threats to the aviation safety.As the operation temperature of the turbine engine elevates,molten volcanic ash leads to the degradation of the thermal barrier coatings(TBCs)and eventually catastrophic engine failure.However,the physical and chemical properties of volcanic ashes vary due to the distinct chemical compositions,rendering it extremely challenging to evaluate the effects of each ash material on the failure of TBC.Here,we proposed a new metric termed Basicity to investigate the influence of chemical composition on the melting temperature and viscosity of volcanic ashes.Artificial CaO-MgO-Al_(2)O_(3)-SiO_(2) materials(CMAS)were synthesized to simulate the wetting,spreading and corrosion behavior of volcanic ashes at 1300 ℃ on(Gd_(0.9)Yb_(0.1))2Zr_(2)O_(7)(GYbZ),a model TBC material.Our results reveal that the synthetic CMAS does not fully capture the damage caused by volcanic ash due to the difference in compositions.The viscosity and characteristic temperatures decrease as the Basicity value increases,indicating its significant impact on the fusion properties of ashes.Notably,distinct from CMAS,the unexpected presence of Fe_(2)O_(3) in volcanic ashes promotes the formation of garnet phase,conversely impedes the formation of apatite dense layer.These findings provide valuable insights into the corrosion mechanisms caused by TBC and strategies for TBC protection against volcanic ashes.展开更多
The wetting behavior of slag–coke is a crucial factor influencing the permeability of the lower part of the blast furnace.However,a systematic understanding of the wetting behavior and underlying mechanisms between t...The wetting behavior of slag–coke is a crucial factor influencing the permeability of the lower part of the blast furnace.However,a systematic understanding of the wetting behavior and underlying mechanisms between titanium-containing slag and tuyere coke remains lacking.The sessile drop method was employed to explore the effects of temperature,binary basicity,FeO,and TiO_(2) contents on the wetting behavior of titanium-containing slag and tuyere coke.The results indicate that increasing the temperature enhances the adhesion and wettability of the droplet,reducing the contact angle.Meanwhile,it accelerates the chemical reactions between slag and coke,leading to faster equilibrium.Conversely,increasing slag basicity elevates the contact angle by inhibiting chemical reactions at the slag–coke interface.This inhibition reduces both contact area and depth,thereby hindering slag droplet spreading on the coke surface.The contact angle decreases as the FeO content in the slag increases.Notably,the increase in TiO_(2) content has a dual effect on slag–coke wettability.Initially,it promotes wetting by reducing surface tension and lowering the contact angle.While the TiO_(2) content exceeds 20 wt.%,Ti(C,N)forms a barrier layer at the slag–coke interface,hindering the contact between slag and coke and resulting in an increased contact angle.展开更多
The study focuses on the creep characteristics of significant yellow sandstone for water conservancy, hydropower, and other waterrelated slope excavation unloading rock-graded loading creep characteristics. It conduct...The study focuses on the creep characteristics of significant yellow sandstone for water conservancy, hydropower, and other waterrelated slope excavation unloading rock-graded loading creep characteristics. It conducts a uniaxial graded loading creep test on yellow sandstone under different pre-peak unloading and wetting-drying cycles. The improved nonlinear Nishihara model was obtained by introducing a nonlinear viscous element with an accelerated creep threshold switch. The sensitivity characteristics of the parameters of the improved creep model were analyzed and a nonlinear creep constitutive model was established, considering the unloading-cyclic intrinsic damage induced by water intrusion. The research results show that:(1)With an increase in the unloading point, the porosity of the rock samples initially decreases and then increases. As the number of cyclic water intrusions rises, the porosity of the rock samples gradually increases, reaching a maximum of 9.58% at an unloading point of 70% uniaxial compression stress(0.7 Rc) after five cycles.(2) Total creep deformation increases with the number of cyclic water intrusions;however, with an increase in the unloading ratio, the original samples show an initial decrease, followed by an increase in creep deformation. With a higher unloading ratio and various instances of cyclic water intrusion, the total creep time of the rock samples,compared to the original samples, is reduced by 21.8%and 23.02%. The creep damage mode gradually changes from shear damage to tensile damage.(3) The sensitivity characteristics of the improved creep model parameters show that transient elasticity modulus E1 is affected by the coupling of unloading and cyclic water intrusion. The viscoelastic modulus E2 and viscous coefficient η1 are mainly affected by unloading and cyclic water intrusion.(4) Based on the strain equivalence principle of damage mechanics, the damage treatment of the parameters in the original model is improved to construct a nonlinear creep constitutive model that considers unloading-cyclic water intrusion damage. A parameter inversion and comparison to the traditional Nishihara model reveal an average relative standard deviation of 0.271%,significantly less than 1%, indicating a more accurate nonlinear creep constitutive model. The research results are crucial for analyzing the long-term stability of water-related steep rocky slopes post-excavation and unloading and for preventing and controlling creep-type landslide disasters.展开更多
The wetting behavior of liquid tin(Sn)solder on copper(Cu)substrate at 250℃was investigated by the wetting balance method under the action of direct current(DC).The curves of wetting balance were measured and the mor...The wetting behavior of liquid tin(Sn)solder on copper(Cu)substrate at 250℃was investigated by the wetting balance method under the action of direct current(DC).The curves of wetting balance were measured and the morphology of the intermetallic compound(IMC)precipitated at the interface were observed.Results show that DC has a significant effect on the wettability and IMC.As the current increases,the balance wetting force and the thickness of the IMC layer increase.The direction of the DC also has a certain effect on the balance wetting force and IMC layer.When the current is negative,the final balance wetting force and the thickness of the Cu_(6)Sn_(5) layer are significantly higher than those in the positive current case,which is attributed to electromigration.The IMC precipitation at the interface provides a chemical driving force for the movement of the triple junction.The interaction of the interface atoms and the chemical reaction are enhanced by DC,thereby improving wettability.Meanwhile,the Marangoni convection caused by DC inside liquid Sn solder changes the structure of triple junction,which provides a physical driving force for the spread of the liquid Sn solder on the Cu substrate.展开更多
The immense energy potential of natural water vapor cycles,encompassing evaporation,transport,and adsorption,remains substantially underexploited.Recent progress in nanomaterial science and an improved understanding o...The immense energy potential of natural water vapor cycles,encompassing evaporation,transport,and adsorption,remains substantially underexploited.Recent progress in nanomaterial science and an improved understanding of water-surface interactions have shown that because of quantum confinement effects and increased surface reactivity,nanoscale materials have exceptional electrical generation abilities through interfacial dynamics with aqueous phases.Hydrovoltaic technology has emerged as a novel energy conversion method that harnesses liquid-solid interfacial phenomena including surface slippage,frictional contact,evaporation dynamics,and moisture concentration gradients to produce electrical outputs.This review summarizes advances in graphene-based carbon materials for hydrovoltaic applications,addressing four critical aspects:(1)fundamental characteristics of graphene-water interfaces,(2)interfacial charge generation mechanisms at liquid-solid boundaries,(3)three principal electricity generation modes(flow-induced,evaporation-driven,and moisture gradient-enabled power generation),and(4)practical implementation scenarios.We also propose ways to improve the energy conversion efficiency and scale-up of the current technology for its use in self-powered systems,flexible energy storage batteries,humidity sensors,and personal thermal management devices.展开更多
In this paper,the effect of sodium laurate(SL)on the properties of sodium lauroyl glutamate(SLG),such as surface activity,foam,wetting,emulsification,and resistance to hard water,has been systematically investigated.T...In this paper,the effect of sodium laurate(SL)on the properties of sodium lauroyl glutamate(SLG),such as surface activity,foam,wetting,emulsification,and resistance to hard water,has been systematically investigated.The results showed that the critical micelle concentration(cmc)of SLG was 0.30 mmol/L,and the surface tension at the cmc(γcmc)was 34.95 mN/m.With the increase of SL content,the efficiency of SLG solution in reducing the surface tension was decreased.When the SL content was increased,there was no significant change in the foaming ability and foam stability of SLG solutions.The increase of SL content improved both the emulsification and wettability of SLG,but reduced its water resistance.展开更多
Rough micro-nano structures and low surface energy chemical compositions are two essential conditions for constructing superhydrophobic surfaces.However,for low surface tension liquids,which are extremely easy to spre...Rough micro-nano structures and low surface energy chemical compositions are two essential conditions for constructing superhydrophobic surfaces.However,for low surface tension liquids,which are extremely easy to spread and wet on solid surfaces,the design of cantilever structures with internal concavity is the third important parameter to achieve their superomniphobic,whose negative geometrical inflections can effectively lock the solid-liquid-gas three phase contact line,maximize the upward component of capillary force of the suspended droplets,and provide a larger breakthrough pressure for the structured surfaces to avoid the low surface tension liquids from collapsing on the solid surfaces.Based on this,microfabrication was used to prepare mushroom structured surfaces.By precisely controlling the etching parameters,mushroom structures with diameter of 3μm and circular centre distance of 8μm were prepared.The mushroom structure not only achieves super-repellent from high surface tension water(72.8 mN/m)to ultra-low surface tension perfluorohexane(10 mN/m),but also achieves complete rebound even to the high-speed impact of liquid droplets,including water droplets with an impact height of 7.9 cm and perfluorohexane with a height of 3 mm.This fabrication technology helps to build a robust superomniphobic surface for use in harsh environments such as high-speed droplet impacts.展开更多
Rice production,essential for global food security,is increasingly impacted by climate variability and genetic improvements.However,limited research has systematically quantified the individual contributions of climat...Rice production,essential for global food security,is increasingly impacted by climate variability and genetic improvements.However,limited research has systematically quantified the individual contributions of climate change and genetic advancements to rice yield trends,particularly in high-latitude regions such as Harbin city,Heilongjiang Province,China.This study addresses this gap by using the AquaCrop model to partition the effects of climate change and genetic enhancements on rice yields over recent decades.The objectives were to evaluate the relative influences of climate and genotype on yield trends,assess irrigation efficiency under continuous flooding(CF)and alternate wetting and drying(AWD),and identify optimal transplanting dates for yield and water productivity.Four years of paddy field data were used to calibrate and validate AquaCrop for three rice varieties(V_(1),V_(2),and V_3)under CF and AWD irrigation.Historical climate data were sourced for simulations.Key findings indicated that climate change accounts for 60%??70%of yield improvements,while genotype contributes 30%-40%.AWD achieved grain yields within 1%of CF,while improving water productivity by up to 7%in later(V_(2) and V_3)varieties and with delayed transplanting dates.Additionally,15 May was identified as the optimal transplanting date,yielding up to 7.53 t/hm^(2) under CF with biomass reaching 18.35 t/hm^(2).These findings highlight strategies for sustainable rice production in water-scarce regions and emphasize the role of genotype development in climate adaptation.展开更多
Polymer fibers are among the most promising adsorbents in wastewater treatment,while limited by poor adsorption capacity and irreversible pollution.Herein,amine-modified C_(3)N_(4)/TiO_(2)-polyacrylonitrile(PAN)compos...Polymer fibers are among the most promising adsorbents in wastewater treatment,while limited by poor adsorption capacity and irreversible pollution.Herein,amine-modified C_(3)N_(4)/TiO_(2)-polyacrylonitrile(PAN)composite fibers with high absorption ability and photocatalytic self-cleaning properties were fabricated via wet spinning.The introduction of diethylenetriamine(DETA)onto the PAN resulted in the presence of positively charged amino groups,which not only increased the number of adsorption sites for anionic dyes but also facilitated the formation of a sponge-like pore structure.Optimally,the adsorption capacity of the aminated PAN fibers(PD7h)for methyl orange(MO)reached 164.79 mg·g^(-1),which is 39.2 times greater than that of unmodified PAN fibers.Furthermore,the introduction of the C_(3)N_(4)/TiO_(2) heterojunction photocatalyst endowed the fibers with photocatalytic self-cleaning capability by generating active free radicals(hydroxyl radicals(·OH)and superoxide radicals(·O_(2)^(-))that efficiently degraded dye pollutants in situ on the fiber surface.Under irradiation using a 300 W xenon lamp,the aminated C_(3)N_(4)/TiO_(2)^(-)PAN fibers(PDCT-1)removed more than 90%of MO(30 mg·L^(-1))within 120 min.After eight cycles,the pollutant removal rate decreased by only 22.41%,indicating excellent stability.Overall,this work presents an effective,simple and feasible method for preparing polymer fibers with high adsorption and photocatalytic self-cleaning properties via wet spinning for dye wastewater treatment.展开更多
Armored vehicles,to accomplish missions in complex harsh conditions with high mobility,require the transmission system to achieve high energy density and high reliability.The wet multi-disc clutch becomes the perishab...Armored vehicles,to accomplish missions in complex harsh conditions with high mobility,require the transmission system to achieve high energy density and high reliability.The wet multi-disc clutch becomes the perishable component under heavy load,large speed difference,and frequent engagement.Due to the difficulty of maintenance in battlefield,clutch carrying post-buckling separate plate is common,and the clutch working process is obstructed.Therefore,considering the post-buckling plate,the multi-physics thermodynamic model of a wet multi-disc clutch is established to describe the entire engagement and separation process.The influence of the buckling degree on the stress-strain,uniformity of gaps,torque,and temperature characteristics is investigated by the numerical method and testified by bench tests.The results show that with the increasing buckling degree,the clutch engagement and separation times decrease gradually.For the separation process,the non-uniformity of gaps is increased,and gaps are eventually occupied,leading to the continuous rough contact among friction pairs.Therefore,the drag torque is increased.Squeezed by the post-buckling plate,the cooling rates of separate plates are decreased.During repeated engagement-separation,temperatures of plates may reach balance points.Since continuous sliding and temperature concentration,the wear form and degree changes,especially at outer radius.Extra drag torque,heat,and wear threats the friction components which increases the risk of failures of the transmission system and affects the mobility of armored vehicles.展开更多
Wet wipes have become an indispensable part of modern life,offering convenience whether used for personal hygiene,baby care,or household cleaning.Wet wipes made of different materials each have their own characteristi...Wet wipes have become an indispensable part of modern life,offering convenience whether used for personal hygiene,baby care,or household cleaning.Wet wipes made of different materials each have their own characteristics,which not only directly affect the comfort and performance during use but are also closely related to environmental protection.Understanding their differences can help consumers make more informed choices—ones that meet daily needs while reducing the environmental burden.展开更多
基金supported by the National Key R&D Program of China(Grant No.2023YFC3209504)Natural Science Foundation of Wuhan(Grant No.2024040801020271)the Fundamental Research Funds for Central Public Welfare Research Institutes(Grant No.CKSF2025718/YT).
文摘Wetting deformation in earth-rockfill dams is a critical factor influencingdam safety.Although numerous mathematical models have been developed to describe this phenomenon,most of them rely on empirical formulations and lack prior knowledge of model parameters,which is essential for Bayesian parameter inversion to enhance accuracy and reduce uncertainty.This study introduces a datadriven approach to establishing prior knowledge of earth-rockfill dams.Driving factors are utilized to determine the potential range of model parameters,and settlement changes within this range are calculated.The results are iteratively compared with actual monitoring data until the calculated range encompasses the observed data,thereby providing prior knowledge of the model parameters.The proposed method is applied to the right-bank earth-rockfilldam of Danjiangkou.Employing a Gibbs sample size of 30,000,the proposed method effectively calibrates the prior knowledge of the wetting model parameters,achieving a root mean square error(RMSE)of 5.18 mm for the settlement predictions.By comparison,the use of non-informative priors with sample sizes of 30,000 and 50,000 results in significantly larger RMSE values of 11.97 mm and 16.07 mm,respectively.Furthermore,the computational efficiencyof the proposed method is demonstrated by an inversion computation time of 902 s for 30,000 samples,which is notably shorter than the 1026 s and 1558 s required for noninformative priors with 30,000 and 50,000 samples,respectively.These findingsunderscore the superior performance of the proposed approach in terms of both prediction accuracy and computational efficiency.These results demonstrate that the proposed method not only improves the predictive accuracy but also enhances the computational efficiency,enabling optimal parameter identificationwith reduced computational effort.This approach provides a robust and efficientframework for advancing dam safety assessments.
文摘BACKGROUND Orthopaedic surgical education has traditionally depended on the apprenticeship model of“see one,do one,teach one”.However,reduced operative exposure,stricter work-hour regulations,medicolegal constraints,and patient safety concerns have constrained its practicality.Simulation-based training has become a reliable,safe,and cost-efficient alternative.Dry lab techniques,especially virtual and augmented reality,make up 78%of current dry lab research,whereas wet labs still set the standard for anatomical realism.AIM To evaluate the effectiveness,limitations,and future directions of wet and dry lab simulation in orthopaedic training.METHODS A scoping review was carried out across four databases-PubMed,Cochrane Library,Web of Science,and EBSCOhost-up to 2025.Medical Subject Headings included:"Orthopaedic Education","Wet Lab","Dry Lab","Simulation Training","Virtual Reality",and"Surgical Procedure".Eligible studies focused on orthopaedic or spinal surgical education,employed wet or dry lab techniques,and assessed training effectiveness.Exclusion criteria consisted of non-English publications,abstracts only,non-orthopaedic research,and studies unrelated to simulation.Two reviewers independently screened titles,abstracts,and full texts,resolving discrepancies with a third reviewer.RESULTS From 1851 records,101 studies met inclusion:78 on dry labs,7 on wet labs,4 on both.Virtual reality(VR)simulations were most common,with AI increasingly used for feedback and assessment.Cadaveric training remains the gold standard for accuracy and tactile feedback,while dry labs-especially VR-offer scalability,lower cost(40%-60%savings in five studies),and accessibility for novices.Senior residents prefer wet labs for complex tasks;juniors favour dry labs for basics.Challenges include limited transferability data,lack of standard outcome metrics,and ethical concerns about cadaver use and AI assessment.CONCLUSION Wet and dry labs each have unique strengths in orthopaedic training.A hybrid approach combining both,supported by standardised assessments and outcome studies,is most effective.Future efforts should aim for uniform reporting,integrating new technologies,and policy support for hybrid curricula to enhance skills and patient care.
基金Funded by joint Funds of the National Natural Science Foundation of China(No.U1904188)the Key Research Project of Henan Province for Colleges and Universities(No.26A560009)+3 种基金the Jiaozuo City Science and Technology Planning Project(No.2025210099)the Henan Provincial Science and Technology Research Project(No.252102320305)the Natural Science Foundation of Henan Province(No.252300421917)the Project by Key Laboratory of Intelligent Construction and Safety Operation and Maintenance of Underground Engineering in Henan Province(No.KFKT2024-01)。
文摘To explore mix proportion design of RAC with aggregates tightly packed,the dry and wet packing density of recycled coarse aggregates mixture system and recycled coarse and fine aggregates were tested,then the influence of replacement rate and particle size ratio on the packing density of particle system was explored,the packing density prediction model of recycled coarse aggregates based on particle morphology was constructed,and the mix proportion optimization for recycled aggregate concrete with dry-wet packing model was carried out.The experimental results show that,with the increasing of recycled aggregate replacement rate or fine-grained volume ratio,the dry packing density of recycled coarse aggregates decreases gradually.With the increasing of replacement rate,the particle gradation can be optimized by increasing coarsegrained volume ratio.There is a significant effect for particle morphology parameter K and the particle size ratio on the packing density of the binary mixed system,and the packing density prediction model of recycled coarse aggregates based on particle morphology was constructed.The maximum increase in compressive strength and tensile strength of RAC with mix proportion optimized by the dry-wet packing model are 12.94%and 11.09%,and the cementitious materials is reduced by 21.83%,then the superiority of the mix proportion optimization of RAC with the dry-wet close packing model is confirmed.The results of this paper can provide a theoretical basis for the mix proportion design of RAC.
基金support from the National Natural Science Foundation of China(Grant Nos.52104207 and 52374214)the Shandong Provincial Youth Innovation Team Development Program for Higher Education Institutions(Grant No.2023KJ305).
文摘In the field of rock engineering,the influence of water is a dynamic process that exhibits varying effects over time and across different locations.To further understand how water influences the mechanical properties and acoustic emission(AE)behavior of rocks,this study conducted uniaxial compression experiments on sandstones with varying degrees of wetting under both natural conditions and water-chemical environments.In addition,the study combined AE equipment with digital image correlation(DIC)to monitor the entire failure process.Using the sliding window algorithm,the variation in the variance of AE characteristic parameters during the process of sandstone loading to failure is analyzed from the perspective of critical slowing down.This analysis enables the effective identification of the early warning signal before failure.The experimental findings suggest that an increase in wetting height results in a gradual decrease in peak stress,accompanied by a concomitant increase in the percentage of shear cracks.The characteristic parameters,including energy,amplitude,and ringing count,all exhibit critical slowing phenomena.The waveform of AE characteristic parameters of the same sample is similar,and the mutation time of the precursor signal is roughly the same.All signals appear in the irreversible plastic deformation stage of microcrack initiation.The integration of critical slowing down theory and the b-value early warning method facilitates a more comprehensive evaluation of the stability of rock mass,thereby significantly enhancing the efficiency and safety of disaster prevention measures.
基金supported by the Natural Science Foundation of Jiangsu Province,China(BK20241931 and BK 20221371)the National Natural Science Foundation of China(32071943,32372214,and 31901444)the National Key Research and Development Program of China(2022YFD2300304)。
文摘Alternate wetting and drying irrigation(AWD)significantly influences the cooking and eating quality of rice(Oryza sativa L.).However,the mechanisms by which AWD affects rice cooking and eating quality remain unclear.Lipid and free fatty acid contents in grains correlate positively with cooking and eating quality of rice.This study examined Yangdao 6(YD6,a conventional taste indica inbred)and Nanjing 9108(NJ9108,a superior taste japonica inbred)cultivated under conventional irrigation(CI),alternate wetting and moderate drying irrigation(AWMD),and alternate wetting and severe drying irrigation(AWSD)from 10 days after transplanting to maturity.The research investigated the relationship between lipid and free fatty acid biosynthesis in grains and the cooking and eating quality of rice.Compared to CI treatment,AWMD significantly enhanced the contents of lipid,total free fatty acids(TFFAs),free unsaturated fatty acids(FUFAs),linoleic acid,and oleic acid in milled rice by increasing activities of enzymes associated with lipid synthesis,while AWSD produced opposite effects.Correlation analysis revealed that elevated levels of lipid,TFFAs,FUFAs,linoleic acid,and oleic acid contribute to improved rice cooking and eating quality.The findings demonstrate that AWMD enhances cooking and eating quality of milled rice through optimization of lipid and fatty acid synthesis in rice grains.
基金supported by National Natural Science Foundation of China(Grant Nos.52364004 and 52264006)The Youth Talent Growth Project of Guizhou Provincial Department of Education(Grant No.QianJiaoJi[2024]18).
文摘Extensive engineering experience and research findings suggest that rock mass instability is typically attributed to human engineering activities and natural disturbances,resulting in general dynamic mechanical properties.This is attributed to external interference resulting from the extensive use of the mechanical and blasting techniques necessary for mineral extraction.Quantifying the impact of dynamic disturbances on rock deformation behavior is essential for comprehending the long-term response of surrounding rock during excavation.This study placed the rock to sustained pressure and investigated the impact of varying hammer heights and dry and wet(W-D)damage on its shear failure behavior.This study investigated the fatigue disturbance studies on W-D damaged sandstone samples via W-D equipment,a disturbance creep device,digital image correlation(DIC),and acoustic emission(AE)technology.The experimental findings suggest that acoustic emission sensors can be utilized to quantify the internal damage of rock samples during cyclic impact,whereas DIC technology(optical measurement)is capable of capturing the surface crack propagation of samples.Under repeated impact and the combined action of W-D conditions,the bearing capacity of sandstone decreases,whereas the deformation capacity increases.Furthermore,the W-D cycles and impact strength are inversely related to the fatigue life.The intensity of W-D damage and disturbances further accelerates the development and propagation of cracks under cyclic disturbances.The research results are of preventive significance to ensure the safety and sustainable development of engineering construction.
基金financially supported by the National Natural Science Foundation of China(No.12304077)the Natural Science Foundation of Science and Technology Department of Sichuan Province(No.23NSFSC6224)+3 种基金Sichuan Science and Technology Program(No.2024NSFSC0989)the Key Laboratory of Computational Physics of Sichuan Province(No.YBUJSWL-YB-2022-03)the Material Corrosion and Protection Key Laboratory of Sichuan Province(No.2023CL14 and No.2023CL01)the National Innovation Practice Project(No.202411079005S).
文摘Oxygen release and electrolyte decomposition under high voltage endlessly exacerbate interfacial ramifications and structu ral degradation of high energy-density Li-rich layered oxide(LLO),leading to voltage and capacity fading.Herein,the dual-strategy of Cr,B complex coating and local gradient doping is simultaneously achieved on LLO surface by a one-step wet chemical reaction at room temperature.Density functional theory(DFT)calculations prove that stable B-O and Cr-O bonds through the local gradient doping can significantly reduce the high-energy O 2p states of interfacial lattice O,which is also effective for the near-surface lattice O,thus greatly stabilizing the LLO surface,Besides,differential electrochemical mass spectrometry(DEMS)indicates that the Cr_(x)B complex coating can adequately inhibit oxygen release and prevents the migration or dissolution of transition metal ions,including allowing speedy Li^(+)migration,The voltage and capacity fading of the modified cathode(LLO-C_(r)B)are adequately suppressed,which are benefited from the uniformly dense cathode electrolyte interface(CEI)composed of balanced organic/inorganic composition.Therefore,the specific capacity of LLO-CrB after 200 cycles at 1C is 209.3 mA h g^(-1)(with a retention rate of 95.1%).This dual-strategy through a one-step wet chemical reaction is expected to be applied in the design and development of other anionic redox cathode materials.
基金supported by the Basic Science Center Project for the National Natural Science Foundation of China(No.72088101)the S&T Program of Hebei(No.23564101D).
文摘As the bed depth increases,sintering yield increases,but the productivity decreases.To reveal the reasons for the decrease in productivity and explore targeted solutions,the bed resistance of mixtures,wet zone,and combustion zone was analyzed in the laboratory.The results showed that the decreased porosity of mixture resulted in the increased bed resistance by 160.56%when the bed depth increased from 600 to 1000 mm.After improving porosity of 1%by adding loosening bars with optimized size and distribution,the bed resistance decreased,and the productivity increased by 5%.The increase in bed depth increased the thickness of the wet zone from 120 to 680 mm and the resistance from 1.56 to 8.83 kPa.By using a three-stage intensive mixer and pre-adding water for granulation,the moisture of mixture was reduced by 0.6%,and the sintering productivity increased by 4%.Besides,the high bed resistance is mainly caused by the increase in the thickness of the combustion zone from 31.9 to 132.7 mm,and the bed resistance increased from 0.70 to 5.62 kPa.The bed resistance of the combustion zone at 900 mm was increased by 90.51%compared to 700 mm.After optimization of the distribution of coke breeze,the thickness of combustion zone at the lower layer decreased from 132.7 to 106.84 mm and permeability improved significantly.
基金supported by the National Natural Science Foundation of China(No.31988102)Yunnan Province Major Program for Basic Research Project(No.202101BC070002)+1 种基金Yunnan Province Science and Technology Talents and Platform Program(No.202305AA160014)Yunnan Province Key Research and Development Program of China(No.202303AC100009)。
文摘Forest structure is fundamental in determining ecosystem function,yet the impact of bamboo invasion on these structural characteristics remains unclear.We investigated 219 invasion transects at 41 sites across the distribution areas of Moso bamboo(Phyllostachys edulis)in China to explore the effects of bamboo invasion on forest structural attributes and diameter–height allometries by comparing paired plots of bamboo,mixed bamboo-tree,and non-bamboo forests along the transects.We found that bamboo invasion decreased the mean and maximum diameter at breast height,maximum height,and total basal area,but increased the mean height,stem density,and scaling exponent for stands.Bamboo also had a higher scaling exponent than tree,particularly in mixed forests,suggesting a greater allocation of biomass to height growth.As invasion intensity increased,bamboo allometry became more plastic and decreased significantly,whereas tree allometry was indirectly promoted by increasing stem density.Additionally,a humid climate may favour the scaling exponents for both bamboo and tree,with only minor contributions from topsoil moisture and nitrogen content.The inherent superiority of diameter–height allometry allows bamboo to outcompete tree and contributes to its invasive success.Our findings provide a theoretical basis for understanding the causes and consequences of bamboo invasion.
基金financially supported by the Nature Science Foun-dations of China(NSFC)(Nos.52401071 andU21B2052)China National Postdoctoral Program for Innovative Talents(No.BX20240459).
文摘Volcanic ashes are posing increasingly severer threats to the aviation safety.As the operation temperature of the turbine engine elevates,molten volcanic ash leads to the degradation of the thermal barrier coatings(TBCs)and eventually catastrophic engine failure.However,the physical and chemical properties of volcanic ashes vary due to the distinct chemical compositions,rendering it extremely challenging to evaluate the effects of each ash material on the failure of TBC.Here,we proposed a new metric termed Basicity to investigate the influence of chemical composition on the melting temperature and viscosity of volcanic ashes.Artificial CaO-MgO-Al_(2)O_(3)-SiO_(2) materials(CMAS)were synthesized to simulate the wetting,spreading and corrosion behavior of volcanic ashes at 1300 ℃ on(Gd_(0.9)Yb_(0.1))2Zr_(2)O_(7)(GYbZ),a model TBC material.Our results reveal that the synthetic CMAS does not fully capture the damage caused by volcanic ash due to the difference in compositions.The viscosity and characteristic temperatures decrease as the Basicity value increases,indicating its significant impact on the fusion properties of ashes.Notably,distinct from CMAS,the unexpected presence of Fe_(2)O_(3) in volcanic ashes promotes the formation of garnet phase,conversely impedes the formation of apatite dense layer.These findings provide valuable insights into the corrosion mechanisms caused by TBC and strategies for TBC protection against volcanic ashes.
基金supported by the Postdoctor Project of Hubei Province(2024HBBHCXA074)National Natural Science Foundation of China(51974212)+2 种基金China Baowu Low Carbon Metallurgy Innovation Foundation(BWLCF202116)Foundation of Hubei Provincial Key Laboratory for New Processes of Ironmaking and Steelmaking(NPISlab25-03)Science and Technology Major Project of Wuhan(2023020302020572).
文摘The wetting behavior of slag–coke is a crucial factor influencing the permeability of the lower part of the blast furnace.However,a systematic understanding of the wetting behavior and underlying mechanisms between titanium-containing slag and tuyere coke remains lacking.The sessile drop method was employed to explore the effects of temperature,binary basicity,FeO,and TiO_(2) contents on the wetting behavior of titanium-containing slag and tuyere coke.The results indicate that increasing the temperature enhances the adhesion and wettability of the droplet,reducing the contact angle.Meanwhile,it accelerates the chemical reactions between slag and coke,leading to faster equilibrium.Conversely,increasing slag basicity elevates the contact angle by inhibiting chemical reactions at the slag–coke interface.This inhibition reduces both contact area and depth,thereby hindering slag droplet spreading on the coke surface.The contact angle decreases as the FeO content in the slag increases.Notably,the increase in TiO_(2) content has a dual effect on slag–coke wettability.Initially,it promotes wetting by reducing surface tension and lowering the contact angle.While the TiO_(2) content exceeds 20 wt.%,Ti(C,N)forms a barrier layer at the slag–coke interface,hindering the contact between slag and coke and resulting in an increased contact angle.
基金We gratefully acknowledge the financial support from the Key Laboratory of Geological Safety of Coastal Urban Underground Space,Ministry of Natural Resources(BHKF2022Y03)Shandong Provincial Colleges and Universities Youth Innovation Technology Support Program,Education Department of Shandong Province(grant number 2023KJ092).
文摘The study focuses on the creep characteristics of significant yellow sandstone for water conservancy, hydropower, and other waterrelated slope excavation unloading rock-graded loading creep characteristics. It conducts a uniaxial graded loading creep test on yellow sandstone under different pre-peak unloading and wetting-drying cycles. The improved nonlinear Nishihara model was obtained by introducing a nonlinear viscous element with an accelerated creep threshold switch. The sensitivity characteristics of the parameters of the improved creep model were analyzed and a nonlinear creep constitutive model was established, considering the unloading-cyclic intrinsic damage induced by water intrusion. The research results show that:(1)With an increase in the unloading point, the porosity of the rock samples initially decreases and then increases. As the number of cyclic water intrusions rises, the porosity of the rock samples gradually increases, reaching a maximum of 9.58% at an unloading point of 70% uniaxial compression stress(0.7 Rc) after five cycles.(2) Total creep deformation increases with the number of cyclic water intrusions;however, with an increase in the unloading ratio, the original samples show an initial decrease, followed by an increase in creep deformation. With a higher unloading ratio and various instances of cyclic water intrusion, the total creep time of the rock samples,compared to the original samples, is reduced by 21.8%and 23.02%. The creep damage mode gradually changes from shear damage to tensile damage.(3) The sensitivity characteristics of the improved creep model parameters show that transient elasticity modulus E1 is affected by the coupling of unloading and cyclic water intrusion. The viscoelastic modulus E2 and viscous coefficient η1 are mainly affected by unloading and cyclic water intrusion.(4) Based on the strain equivalence principle of damage mechanics, the damage treatment of the parameters in the original model is improved to construct a nonlinear creep constitutive model that considers unloading-cyclic water intrusion damage. A parameter inversion and comparison to the traditional Nishihara model reveal an average relative standard deviation of 0.271%,significantly less than 1%, indicating a more accurate nonlinear creep constitutive model. The research results are crucial for analyzing the long-term stability of water-related steep rocky slopes post-excavation and unloading and for preventing and controlling creep-type landslide disasters.
基金Doctoral Research Start-up Fund of Lanzhou University of Arts and Science(2021-9)Innovation Fund for Colleges and Universities of Gansu Province,China(2022B-265)。
文摘The wetting behavior of liquid tin(Sn)solder on copper(Cu)substrate at 250℃was investigated by the wetting balance method under the action of direct current(DC).The curves of wetting balance were measured and the morphology of the intermetallic compound(IMC)precipitated at the interface were observed.Results show that DC has a significant effect on the wettability and IMC.As the current increases,the balance wetting force and the thickness of the IMC layer increase.The direction of the DC also has a certain effect on the balance wetting force and IMC layer.When the current is negative,the final balance wetting force and the thickness of the Cu_(6)Sn_(5) layer are significantly higher than those in the positive current case,which is attributed to electromigration.The IMC precipitation at the interface provides a chemical driving force for the movement of the triple junction.The interaction of the interface atoms and the chemical reaction are enhanced by DC,thereby improving wettability.Meanwhile,the Marangoni convection caused by DC inside liquid Sn solder changes the structure of triple junction,which provides a physical driving force for the spread of the liquid Sn solder on the Cu substrate.
文摘The immense energy potential of natural water vapor cycles,encompassing evaporation,transport,and adsorption,remains substantially underexploited.Recent progress in nanomaterial science and an improved understanding of water-surface interactions have shown that because of quantum confinement effects and increased surface reactivity,nanoscale materials have exceptional electrical generation abilities through interfacial dynamics with aqueous phases.Hydrovoltaic technology has emerged as a novel energy conversion method that harnesses liquid-solid interfacial phenomena including surface slippage,frictional contact,evaporation dynamics,and moisture concentration gradients to produce electrical outputs.This review summarizes advances in graphene-based carbon materials for hydrovoltaic applications,addressing four critical aspects:(1)fundamental characteristics of graphene-water interfaces,(2)interfacial charge generation mechanisms at liquid-solid boundaries,(3)three principal electricity generation modes(flow-induced,evaporation-driven,and moisture gradient-enabled power generation),and(4)practical implementation scenarios.We also propose ways to improve the energy conversion efficiency and scale-up of the current technology for its use in self-powered systems,flexible energy storage batteries,humidity sensors,and personal thermal management devices.
文摘In this paper,the effect of sodium laurate(SL)on the properties of sodium lauroyl glutamate(SLG),such as surface activity,foam,wetting,emulsification,and resistance to hard water,has been systematically investigated.The results showed that the critical micelle concentration(cmc)of SLG was 0.30 mmol/L,and the surface tension at the cmc(γcmc)was 34.95 mN/m.With the increase of SL content,the efficiency of SLG solution in reducing the surface tension was decreased.When the SL content was increased,there was no significant change in the foaming ability and foam stability of SLG solutions.The increase of SL content improved both the emulsification and wettability of SLG,but reduced its water resistance.
基金funded by the Postdoctoral Fellowship Program of CPSF under Grant Number GZC20233434the Key Cultivation Program of the Harbin Institute of Technology FUEA0400400523.
文摘Rough micro-nano structures and low surface energy chemical compositions are two essential conditions for constructing superhydrophobic surfaces.However,for low surface tension liquids,which are extremely easy to spread and wet on solid surfaces,the design of cantilever structures with internal concavity is the third important parameter to achieve their superomniphobic,whose negative geometrical inflections can effectively lock the solid-liquid-gas three phase contact line,maximize the upward component of capillary force of the suspended droplets,and provide a larger breakthrough pressure for the structured surfaces to avoid the low surface tension liquids from collapsing on the solid surfaces.Based on this,microfabrication was used to prepare mushroom structured surfaces.By precisely controlling the etching parameters,mushroom structures with diameter of 3μm and circular centre distance of 8μm were prepared.The mushroom structure not only achieves super-repellent from high surface tension water(72.8 mN/m)to ultra-low surface tension perfluorohexane(10 mN/m),but also achieves complete rebound even to the high-speed impact of liquid droplets,including water droplets with an impact height of 7.9 cm and perfluorohexane with a height of 3 mm.This fabrication technology helps to build a robust superomniphobic surface for use in harsh environments such as high-speed droplet impacts.
基金supported by the National Key Research and Development Program of China(Grant No.2023YFD200140403)the Major Science and Technology Innovation Projects of Shandong Province,China(Grant No.2022TZXD0038)the Shandong Provincial‘811’Project of First-class Discipline Construction,China。
文摘Rice production,essential for global food security,is increasingly impacted by climate variability and genetic improvements.However,limited research has systematically quantified the individual contributions of climate change and genetic advancements to rice yield trends,particularly in high-latitude regions such as Harbin city,Heilongjiang Province,China.This study addresses this gap by using the AquaCrop model to partition the effects of climate change and genetic enhancements on rice yields over recent decades.The objectives were to evaluate the relative influences of climate and genotype on yield trends,assess irrigation efficiency under continuous flooding(CF)and alternate wetting and drying(AWD),and identify optimal transplanting dates for yield and water productivity.Four years of paddy field data were used to calibrate and validate AquaCrop for three rice varieties(V_(1),V_(2),and V_3)under CF and AWD irrigation.Historical climate data were sourced for simulations.Key findings indicated that climate change accounts for 60%??70%of yield improvements,while genotype contributes 30%-40%.AWD achieved grain yields within 1%of CF,while improving water productivity by up to 7%in later(V_(2) and V_3)varieties and with delayed transplanting dates.Additionally,15 May was identified as the optimal transplanting date,yielding up to 7.53 t/hm^(2) under CF with biomass reaching 18.35 t/hm^(2).These findings highlight strategies for sustainable rice production in water-scarce regions and emphasize the role of genotype development in climate adaptation.
基金supported by the National Natural Science Foundation of China(22408161,21921006)the National Key Research and Development Program(2021YFB3801303)+1 种基金the Key Research and Development Program of Jiangsu Provincial Department of Science and Technology(BE2022033-3)the State Key Laboratory of Materials-Oriented Chemical Engineering(SKL-MCE-22A03)。
文摘Polymer fibers are among the most promising adsorbents in wastewater treatment,while limited by poor adsorption capacity and irreversible pollution.Herein,amine-modified C_(3)N_(4)/TiO_(2)-polyacrylonitrile(PAN)composite fibers with high absorption ability and photocatalytic self-cleaning properties were fabricated via wet spinning.The introduction of diethylenetriamine(DETA)onto the PAN resulted in the presence of positively charged amino groups,which not only increased the number of adsorption sites for anionic dyes but also facilitated the formation of a sponge-like pore structure.Optimally,the adsorption capacity of the aminated PAN fibers(PD7h)for methyl orange(MO)reached 164.79 mg·g^(-1),which is 39.2 times greater than that of unmodified PAN fibers.Furthermore,the introduction of the C_(3)N_(4)/TiO_(2) heterojunction photocatalyst endowed the fibers with photocatalytic self-cleaning capability by generating active free radicals(hydroxyl radicals(·OH)and superoxide radicals(·O_(2)^(-))that efficiently degraded dye pollutants in situ on the fiber surface.Under irradiation using a 300 W xenon lamp,the aminated C_(3)N_(4)/TiO_(2)^(-)PAN fibers(PDCT-1)removed more than 90%of MO(30 mg·L^(-1))within 120 min.After eight cycles,the pollutant removal rate decreased by only 22.41%,indicating excellent stability.Overall,this work presents an effective,simple and feasible method for preparing polymer fibers with high adsorption and photocatalytic self-cleaning properties via wet spinning for dye wastewater treatment.
基金supported by the National Natural Science Foundations of China(Grant Nos.52205047,52175037)Frontier Cross Project of Beijing Institute of Technology(Grant No.2024CX11006)。
文摘Armored vehicles,to accomplish missions in complex harsh conditions with high mobility,require the transmission system to achieve high energy density and high reliability.The wet multi-disc clutch becomes the perishable component under heavy load,large speed difference,and frequent engagement.Due to the difficulty of maintenance in battlefield,clutch carrying post-buckling separate plate is common,and the clutch working process is obstructed.Therefore,considering the post-buckling plate,the multi-physics thermodynamic model of a wet multi-disc clutch is established to describe the entire engagement and separation process.The influence of the buckling degree on the stress-strain,uniformity of gaps,torque,and temperature characteristics is investigated by the numerical method and testified by bench tests.The results show that with the increasing buckling degree,the clutch engagement and separation times decrease gradually.For the separation process,the non-uniformity of gaps is increased,and gaps are eventually occupied,leading to the continuous rough contact among friction pairs.Therefore,the drag torque is increased.Squeezed by the post-buckling plate,the cooling rates of separate plates are decreased.During repeated engagement-separation,temperatures of plates may reach balance points.Since continuous sliding and temperature concentration,the wear form and degree changes,especially at outer radius.Extra drag torque,heat,and wear threats the friction components which increases the risk of failures of the transmission system and affects the mobility of armored vehicles.
文摘Wet wipes have become an indispensable part of modern life,offering convenience whether used for personal hygiene,baby care,or household cleaning.Wet wipes made of different materials each have their own characteristics,which not only directly affect the comfort and performance during use but are also closely related to environmental protection.Understanding their differences can help consumers make more informed choices—ones that meet daily needs while reducing the environmental burden.
