The high proportion of renewable energy integration and the dynamic changes in grid topology necessitate the enhancement of voltage/var control(VVC)to manage voltage fluctuations more rapidly.Traditional model-based c...The high proportion of renewable energy integration and the dynamic changes in grid topology necessitate the enhancement of voltage/var control(VVC)to manage voltage fluctuations more rapidly.Traditional model-based control algorithms are becoming increasingly incompetent for VVC due to their high model dependence and slow online computation speed.To alleviate these issues,this paper introduces a graph attention network(GAT)based deep reinforcement learning for VVC of topologically variable power system.Firstly,combining the physical information of the actual power grid,a physics-informed GAT is proposed and embedded into the proximal policy optimization(PPO)algorithm.The GAT-PPO algorithm can capture topological and spatial correlations among the node features to tackle topology changes.To address the slow training,the Relief F-S algorithm identifies critical state variables,significantly reducing the dimensionality of state space.Then,the training samples retained in the experience buffer are designed to mitigate the sparse reward issue.Finally,the validation on the modified IEEE 39-bus system and an actual power grid demonstrates superior performance of the proposed algorithm compared with state-of-the-art algorithms,including PPO algorithm and twin delayed deep deterministic policy gradient(TD3)algorithm.The proposed algorithm exhibits enhanced convergence during training,faster solution speed,and improved VVC performance,even in scenarios involving grid topology changes and increased renewable energy integration.Meanwhile,in the adopted cases,the network loss is reduced by 6.9%,10.8%,and 7.7%,respectively,demonstrating favorable economic outcomes.展开更多
The implementation of multifunctional application scenarios for mobile terminal devices has increased the energy density requirements of batteries.Increasing the charging voltage can rapidly increase the specific capa...The implementation of multifunctional application scenarios for mobile terminal devices has increased the energy density requirements of batteries.Increasing the charging voltage can rapidly increase the specific capacity of layered transition metal oxides;however,it also exacerbates the release of lattice oxygen and the contraction of the unit cell.Ternary materials are designed in a secondary particle state to meet the requirements of power battery applications.Therefore,to create ternary materials that can operate under ultrahigh voltages,attention should be given to both surface modification and particle integrity maintenance.By utilizing elemental selenium(Se)with a low melting point,easy sublimation,and multiple variable valence states,deep grain boundary modification was implemented inside the particles.The performance of the cathode material was evaluated through pouch cells,and the improvement mechanism was explored through molecular dynamics simulation calculations.Under the protection of a three-dimensional Se-rich modified layer,LiNi_(1/3)Co_(1/3)Mn_(1/3)O_(2)achieved stable operation at ultrahigh voltages(4.6 V vs.Li/Li^(+));a sacrificial protection mechanism based on the chronic decomposition of the Se-rich layer was proposed to explain the efficacy of Se modification in stabilizing ternary materials.This deep grain boundary modification based on elemental Se provides a new solution for the ultrahigh-voltage operation of transition metal oxides and provides a scientific basis and technical support for solving the interface contact problem of all-solid-state batteries.展开更多
The susceptibility of ore particles to electrical breakdown plays a critical role for high voltage pulse(HVP)breakage,yet its quantitative characterization still lacks deep understanding.Two indicators,namely breakdow...The susceptibility of ore particles to electrical breakdown plays a critical role for high voltage pulse(HVP)breakage,yet its quantitative characterization still lacks deep understanding.Two indicators,namely breakdown delay time(T_(d))and breakdown strength(E_(b))were compared,based on analysis on the two breakdown modes namely wavefront mode and post-wave mode.It was found that T_(d) is more suitable to characterize the susceptibility of ore particles to electrical breakdown in HVP breakage than E_(b).A probabilistic model based on the Weibull distribution is developed to describe the relation of breakdown probability to T_(d).Regression analyses were conducted to investigate how operating parameters and particle properties influence Td and size reduction degree of ore particles in HVP breakage.The regressed models demonstrate potential capability to predict metallic minerals content and HVP breakage degree based on operating parameters and particle properties.展开更多
The integration of a high proportion of renewable energy introduces significant challenges for the adaptability of traditional fault nature identification methods.To address these challenges,this paper presents a nove...The integration of a high proportion of renewable energy introduces significant challenges for the adaptability of traditional fault nature identification methods.To address these challenges,this paper presents a novel fault nature identification method for renewable energy grid-connected interconnection lines,leveraging wavelet packet decomposition and voltage waveform time-frequency morphology comparison algorithms.First,the paper investigates the harmonic injection mechanism during non-full-phase operation following fault isolation in photovoltaic renewable energy systems,and examines the voltage characteristics of faulted phases in renewable energy scenarios.The analysis reveals that substantial differences exist in both the time and frequency domains of phase voltages before and after the extinction of transient faults,whereas permanent faults do not exhibit such variations.Building on this observation,the paper proposes a voltage time-frequency feature extraction method based on wavelet packet decomposition,wherein low-frequency waveform components are selected to characterize fault features.Subsequently,a fault nature identification method is introduced,based on a voltage waveform time-frequency morphology comparison.By employing a windowing technique to quantify waveform differences before and after arc extinction,this method effectively distinguishes between permanent and transient faults and accurately determines the arc extinction time.Finally,a 220 kV renewable energy grid connection line model is developed using PSCAD for verification.The results demonstrate that the proposed method is highly adaptable across various fault locations,transition resistances,and renewable energy control strategies,and can reliably identify fault nature in renewable energy grid connection scenarios.展开更多
Accurate estimation of battery health status plays a crucial role in battery management systems.However,the lack of operational data still affects the accuracy of battery state of health(SOH)estimation.For this reason...Accurate estimation of battery health status plays a crucial role in battery management systems.However,the lack of operational data still affects the accuracy of battery state of health(SOH)estimation.For this reason,a SOH estimation method is proposed based on charging data reconstruction combined with image processing.The charging voltage data is used to train the least squares generative adversarial network(LSGAN),which is validated under different levels of missing data.From a visual perspective,the Gram angle field method is applied to convert one-dimensional time series data into image data.This method fully preserves the time series characteristics and nonlinear evolution patterns,which avoids the difficulties and limited expressive power associated with manual feature extraction.At the same time,the Swin Transformer model is introduced to extract global structures and local details from images,enabling better capture of sequence change trends.Combined with the long short-term memory network(LSTM),this enables accurate estimation of battery SOH.Two different types of batteries are used to validate the test.The experimental results show that the proposed method has good estimation accuracy under different training proportions.展开更多
In position-sensorless brushless direct current(DC)motors(BLDCMs)fed by a four-switch three-phase(FSTP)inverter,only two phases are fully controlled,while the remaining phase is tied to the midpoint of the split DC-li...In position-sensorless brushless direct current(DC)motors(BLDCMs)fed by a four-switch three-phase(FSTP)inverter,only two phases are fully controlled,while the remaining phase is tied to the midpoint of the split DC-link capacitors.The voltage pulses required by inductance-based initial position detection can cause unequal discharge of the series capacitors,shifting the neutral-point voltage away from half of DC-link voltage(U_(dc)/2).This neutral-point drift breaks the spatial symmetry of the inverter voltage vectors,so the 360°electrical period can no longer be evenly partitioned into six sectors during initial rotor position detection.To address this issue,this paper proposes a detection-pulse injection sequence that explicitly accounts for the asymmetric voltage vectors of the FSTP inverter.With the proposed sequence,the initial rotor position can be identified within a 30°electrical sector.The method requires no additional voltage or current sensors,and experimental results confirm its feasibility.展开更多
With the rapid integration of renewable energy sources,modern power systems are increasingly challenged by heightened volatility and uncertainty.Doubly-fed variable-speed pumped storage units(DFVS-PSUs)have emerged as...With the rapid integration of renewable energy sources,modern power systems are increasingly challenged by heightened volatility and uncertainty.Doubly-fed variable-speed pumped storage units(DFVS-PSUs)have emerged as promising technologies for mitigating grid oscillations and enhancing system flexibility.However,the excitation converters in DFVS-PSUs are prone to significant issues such as elevated common-mode voltage(CMV)and neutral-point voltage(NPV)fluctuations,which can lead to electromagnetic interference and degrade transient performance.To address these challenges,an optimized virtual space vector pulse width modulation(OVSVPWM)strategy is proposed,aiming to suppress CMV and NPV simultaneously through coordinated multi-objective control.Specifically,a dynamic feedback mechanism is introduced to adjust the balancing factor of basic vectors in the synthesized virtual small vector in real-time,achieving autonomous balancing of the NPV.To address the excessive switching actions introduced by the OVSVPWM strategy,a phase duty ratio-based sequence reconstruction method is adopted,which reduces the total number of switching actions to half of the original.A zero-level buffering scheme is employed to reconstruct the single-phase voltage-level output sequence,achieving peak CMV suppression down to udc/6.Simulation results demonstrate that the proposed strategy significantly improves electromagnetic compatibility and operational stability while maintaining high power quality.展开更多
The dynamics of network power response play a crucial role in system stability.However,the integration of power electronic equipment leads to amplitude and angular frequency(abbreviated as"frequency")time-va...The dynamics of network power response play a crucial role in system stability.However,the integration of power electronic equipment leads to amplitude and angular frequency(abbreviated as"frequency")time-varying characteristics of the node voltage during dynamic processes.As a result,traditional calcu-lation methods for and characteristics of the power response of the network based on phasor and impe-dance lose their validity.Therefore,this paper undertakes mathematical calculations to reveal the power response of a network under excitation by voltage with time-varying amplitude and frequency(TVAF),relying on the original mathematical relationships and superimposed step response.Then,the multi-timescale characteristics of both the active and reactive power of the network are explored physically.Additionally,this paper reveals a new phenomenon of storing and releasing the active and reactive power of the network.To meet practical engineering requirements,a simplified power expression is presented.Finally,the theoretical analysis is validated through time-domain simulations.展开更多
Electrokinetic(EK)treatment is an effective method in accelerating the consolidation and improving the geotechnical properties of fine-grained soils.This method stabilizes the soil and increases the bearing capacity o...Electrokinetic(EK)treatment is an effective method in accelerating the consolidation and improving the geotechnical properties of fine-grained soils.This method stabilizes the soil and increases the bearing capacity of piles by improving the soil shear strength.Changing the soil p H,due to the occurrence of chemical reactions of electrolysis in the soil,can increase its shear strength.However,the electrodes used in this method corrode due to the change in the soil p H,which in turn reduces the electrical potential.Electrode corrosion and loss of electrical potential can significantly reduce the efficiency of the EK method.In addition,when using the EK method to increase the bearing capacity of piles,changing the p H can cause corrosion and damage to the piles.One of the most important factors influencing the change in the p H of soil is the voltage applied during the EK process.It was reported that increasing the voltage affects the intensity of chemical reactions and electroosmotic flow and thus increases the efficiency of EK.However,very limited research has been conducted on the effect of voltage on the performance of EK method.In the present study,the effects of three voltages on soil p H and corrosion resistance of four types of electrodes including iron(Ir),stainless steel(St),copper(Co),and aluminium(Al)were studied.In addition,the effects of p H variations on the corrosion rate of three types of piles including steel pile(SP),reinforced cement concrete pile(RCCP),and reinforced lime-cement concrete pile(RLCCP)were investigated.It was observed that increasing the voltage from a specific limit had no effect on the intensity of electrolysis reactions and the soil p H adjacent to the electrodes did not change more than a specific limit.Moreover,increasing the voltage to higher than 35 V(i.e.45 V)did not increase the volume of drained water from the soil,but caused more electric current than the allowable current for Ir,St,and Al electrodes,and the corrosion intensity of these electrodes increased significantly.RCCP reduced the soil p H to 2.4 within 7 d of curing due to severe corrosion(13%corrosion rate).The soil p H values adjacent to RCCP and RLCCP within 28 d of curing reduced to 3.7 and 3.8,respectively,but the two piles were not damaged.In general,the results of this research showed that selecting an optimized voltage had a significant effect on the efficiency of EK,and increasing the voltage did not always lead to increase in the efficiency of EK process.展开更多
The influence of additive Nd_2O_3 on varistor voltage and microstructure of ZnO varistor was studied,and its mechanism was proposed from theoretical analysis. The results show that the varistor voltage of ZnO varistor...The influence of additive Nd_2O_3 on varistor voltage and microstructure of ZnO varistor was studied,and its mechanism was proposed from theoretical analysis. The results show that the varistor voltage of ZnO varistor increases with the content of Nd_2O_3 in the range of 0～0.04 (%,mol fraction). However when the content of Nd_2O_3 is more than 0.04 (%,mol fraction),the varistor voltage of ZnO varistor decreases with the content increase. The microstructure analysis indicates that a small amount of new compound with Nd exists at ZnO grain boundary and hinders the movement of grain boundary,which decreases the size of ZnO grain and makes the grain size and distribution homogeneous,as a result,additive (Nd_2O_3) raises the varistor voltage of the varistor greatly.展开更多
Based on the theoretical and experimental investigation of a thin silicon layer（TSL） with linear variable doping（LVD） and further research on the TSL LVD with a multiple step field plate（MSFP）,a breakdown voltag...Based on the theoretical and experimental investigation of a thin silicon layer（TSL） with linear variable doping（LVD） and further research on the TSL LVD with a multiple step field plate（MSFP）,a breakdown voltage（BV） model is proposed and experimentally verified in this paper.With the two-dimensional Poisson equation of the silicon on insulator（SOI） device,the lateral electric field in drift region of the thin silicon layer is assumed to be constant.For the SOI device with LVD in the thin silicon layer,the dependence of the BV on impurity concentration under the drain is investigated by an enhanced dielectric layer field（ENDIF）,from which the reduced surface field（RESURF） condition is deduced.The drain in the centre of the device has a good self-isolation effect,but the problem of the high voltage interconnection（HVI） line will become serious.The two step field plates including the source field plate and gate field plate can be adopted to shield the HVI adverse effect on the device.Based on this model,the TSL LVD SOI n-channel lateral double-diffused MOSFET（nLDMOS） with MSFP is realized.The experimental breakdown voltage（BV） and specific on-resistance（R on,sp） of the TSL LVD SOI device are 694 V and 21.3 ·mm 2 with a drift region length of 60 μm,buried oxide layer of 3 μm,and silicon layer of 0.15 μm,respectively.展开更多
Metal-insulator-metal aluminium electrolytic capacitors(MIM-AECs)combine high capacity-density and high breakdown field strength of solid AECs with high-frequency responsibility,wide workingtemperature window and wate...Metal-insulator-metal aluminium electrolytic capacitors(MIM-AECs)combine high capacity-density and high breakdown field strength of solid AECs with high-frequency responsibility,wide workingtemperature window and waterproof properties of MIM nanocapacitors.However,interfacial atomic diffusion poses a major obstacle,preventing the high-voltage MIM-AECs exploitation and thereby hampering their potential and advantages in high-power and high-energy-density applications.Here,an innovative high-voltage MIM-AECs were fabricated.The AlPO_(4)buffer layer is formed on AlO(OH)/AAO/Al surface by using H_(3)PO_(4)treatment,then a stable van der Waals(vdW)SnO_(2)/AlPO_(4)/AAO/Al multilayer was constructed via atomic layer deposition(ALD)technology.Due to higher diffusion barrier and lower carrier migration of SnO_(2)/AlPO_(4)/AAO interfaces,Sn atom diffusion is inhibited and carrier acceleration by electric field is weakened,guaranteeing high breakdown field strength of dielectric AAO and avoiding local breakdown risks.Through partial etching to hydrated AlO(OH)by H_(3)PO_(4)treatment,the tunnel was further opened up to facilitate subsequent ALD-SnO_(2)entry,thus obtaining a high SnO_(2)coverage.The SnO_(2)/AlPO_(4)/AAO/Al capacitors show a comprehensive performance in high-voltage(260 V),hightemperature(335℃),high-humidity(100%RH)and high-frequency response(100 k Hz),outperforming commercial solid-state AECs,and high-energy density(8.6μWh/cm^(2)),markedly exceeding previously reported MIM capacitors.The work lays the foundation for next-generation capacitors with highvoltage,high-frequency,high-temperature and high-humidity resistance.展开更多
Fluoride-based electrolyte exhibits extraordinarily high oxidative stability in high-voltage lithium metal batteries(h-LMBs) due to the inherent low highest occupied molecular orbital(HOMO) of fiuorinated solvents. Ho...Fluoride-based electrolyte exhibits extraordinarily high oxidative stability in high-voltage lithium metal batteries(h-LMBs) due to the inherent low highest occupied molecular orbital(HOMO) of fiuorinated solvents. However, such fascinating properties do not bring long-term cyclability of h-LMBs. One of critical challenges is the interface instability in contacting with the Li metal anode, as fiuorinated solvents are highly susceptible to exceptionally reductive metallic Li attributed to its low lowest unoccupied molecular orbital(LUMO), which leads to significant consumption of the fiuorinated components upon cycling.Herein, attenuating reductive decomposition of fiuorinated electrolytes is proposed to circumvent rapid electrolyte consumption. Specifically, the vinylene carbonate(VC) is selected to tame the reduction decomposition by preferentially forming protective layer on the Li anode. This work, experimentally and computationally, demonstrates the importance of pre-passivation of Li metal anodes at high voltage to attenuate the decomposition of fiuoroethylene carbonate(FEC). It is expected to enrich the understanding of how VC attenuate the reactivity of FEC, thereby extending the cycle life of fiuorinated electrolytes in high-voltage Li-metal batteries.展开更多
Adopting high-voltage Ni-rich cathodes in halide and sulfide-based all-solid-state lithium batteries(ASSLBs)holds great promise for breaking through the 400 Wh kg^(-1)bottleneck.However,both cell configurations are co...Adopting high-voltage Ni-rich cathodes in halide and sulfide-based all-solid-state lithium batteries(ASSLBs)holds great promise for breaking through the 400 Wh kg^(-1)bottleneck.However,both cell configurations are confronted with intricate interfacial challenges in high-voltage regines(>4.5 V),resulting in inadequate cathode utilization and premature cell degradation.Moreover,contrary to previous studies,coupled with LiNi_(0.85)Co_(0.1)Mn_(0.05)O_(2)cathodes,typical halide(Li_(2)ZrCl_(6))-based cells at 4.5 V feature unlimited interfacial degradation and poor long cycle stability,while typical sulfide(Li_(6)PS_(5)Cl)-based cells feature self-limited interfacial degradation and poor initial cycle stability.Herein,this work addresses the high-voltage limitations of Li_(2)ZrCl_(6)and Li_(6)PS_(5)Cl catholyte-based cells by manipulating electrode mass fraction and tailoring interfacial composition,thereby effectively improving interfacial charge-transfer kinetics and(electro)chemical stability within cathodes.After appropriate interface design,both optimized cells at 4.5 V demonstrate remarkably increased initial discharge capacities(>195 mA h g^(-1)at0.1 C),improved cycle stabilities(>80%after 600 cycles at 0.5 C),and enhanced rate performances(>115 mA h g^(-1)at 1.0 C).This work deepens our understanding of high-voltage applications for halide/sulfide electrolytes and provides generalized interfacial design strategies for advancing high-voltage ASSLBs.展开更多
This article investigates the anti-disturbance and stabilization problems for the nonlinear uncertain permanent magnet synchronous motor(PMSM)with stator voltage saturation and unknown load.A smooth switching mechanis...This article investigates the anti-disturbance and stabilization problems for the nonlinear uncertain permanent magnet synchronous motor(PMSM)with stator voltage saturation and unknown load.A smooth switching mechanism is presented to structure the adaptive integral terminal sliding mode control(SMC)strategy.The control design consists of compensation control and nominal control,which improves the rapidity and accuracy of trajectory tracking.The smooth saturation model based on the error function is applied to approximate the voltage saturation phenomenon.Additionally,to deal with the adverse effects of various unknown disturbances,including model parameter uncertainties and unknown external load disturbances,an improved disturbance observer(DO)is proposed.This observer effectively suppresses the fluctuations caused by fixed gain during the starting period of the system.Finally,the experimental results under different conditions show that the proposed strategy has good tracking and disturbance suppression performances.展开更多
Sodium-ion batteries hold great promise as next-generation energy storage systems.However,the high instability of the electrode/electrolyte interphase during cycling has seriously hindered the development of SIBs.In p...Sodium-ion batteries hold great promise as next-generation energy storage systems.However,the high instability of the electrode/electrolyte interphase during cycling has seriously hindered the development of SIBs.In particular,an unstable cathode–electrolyte interphase(CEI)leads to successive electrolyte side reactions,transition metal leaching and rapid capacity decay,which tends to be exacerbated under high-voltage conditions.Therefore,constructing dense and stable CEIs are crucial for high-performance SIBs.This work reports localized high-concentration electrolyte by incorporating a highly oxidation-resistant sulfolane solvent with non-solvent diluent 1H,1H,5H-octafluoropentyl-1,1,2,2-tetrafluoroethyl ether,which exhibited excellent oxidative stability and was able to form thin,dense and homogeneous CEI.The excellent CEI enabled the O3-type layered oxide cathode NaNi_(1/3)Mn_(1/3)Fe_(1/3)O_(2)(NaNMF)to achieve stable cycling,with a capacity retention of 79.48%after 300 cycles at 1 C and 81.15%after 400 cycles at 2 C with a high charging voltage of 4.2 V.In addition,its nonflammable nature enhances the safety of SIBs.This work provides a viable pathway for the application of sulfolane-based electrolytes on SIBs and the design of next-generation high-voltage electrolytes.展开更多
Fluctuating voltage levels in power grids necessitate automatic voltage regulators(AVRs)to ensure stability.This study examined the modeling and control of AVR in hydroelectric power plants using model predictive cont...Fluctuating voltage levels in power grids necessitate automatic voltage regulators(AVRs)to ensure stability.This study examined the modeling and control of AVR in hydroelectric power plants using model predictive control(MPC),which utilizes an extensive mathe-matical model of the voltage regulation system to optimize the control actions over a defined prediction horizon.This predictive feature enables MPC to minimize voltage deviations while accounting for operational constraints,thereby improving stability and performance under dynamic conditions.Thefindings were compared with those derived from an optimal proportional integral derivative(PID)con-troller designed using the artificial bee colony(ABC)algorithm.Although the ABC-PID method adjusts the PID parameters based on historical data,it may be difficult to adapt to real-time changes in system dynamics under constraints.Comprehensive simulations assessed both frameworks,emphasizing performance metrics such as disturbance rejection,response to load changes,and resilience to uncertainties.The results show that both MPC and ABC-PID methods effectively achieved accurate voltage regulation;however,MPC excelled in controlling overshoot and settling time—recording 0.0%and 0.25 s,respectively.This demonstrates greater robustness compared to conventional control methods that optimize PID parameters based on performance criteria derived from actual system behavior,which exhibited settling times and overshoots exceeding 0.41 s and 5.0%,respectively.The controllers were implemented using MATLAB/Simulink software,indicating a significant advancement for power plant engineers pursuing state-of-the-art automatic voltage regulations.展开更多
基金supported by China Southern Power Grid Co.,Ltd.Yunnan Electric Power Dispatching Control Center(Cyber-physical-based“Source-network-load-storage”Coordinated Dispatch and Control Technologies and Application System Development,sub-project YNKJXM20222463)。
文摘The high proportion of renewable energy integration and the dynamic changes in grid topology necessitate the enhancement of voltage/var control(VVC)to manage voltage fluctuations more rapidly.Traditional model-based control algorithms are becoming increasingly incompetent for VVC due to their high model dependence and slow online computation speed.To alleviate these issues,this paper introduces a graph attention network(GAT)based deep reinforcement learning for VVC of topologically variable power system.Firstly,combining the physical information of the actual power grid,a physics-informed GAT is proposed and embedded into the proximal policy optimization(PPO)algorithm.The GAT-PPO algorithm can capture topological and spatial correlations among the node features to tackle topology changes.To address the slow training,the Relief F-S algorithm identifies critical state variables,significantly reducing the dimensionality of state space.Then,the training samples retained in the experience buffer are designed to mitigate the sparse reward issue.Finally,the validation on the modified IEEE 39-bus system and an actual power grid demonstrates superior performance of the proposed algorithm compared with state-of-the-art algorithms,including PPO algorithm and twin delayed deep deterministic policy gradient(TD3)algorithm.The proposed algorithm exhibits enhanced convergence during training,faster solution speed,and improved VVC performance,even in scenarios involving grid topology changes and increased renewable energy integration.Meanwhile,in the adopted cases,the network loss is reduced by 6.9%,10.8%,and 7.7%,respectively,demonstrating favorable economic outcomes.
基金supported by the National Natural Science Foundation of China (52302259)the China Postdoctoral Science Foundation (CPSF) under Grant Number 2023M741479+4 种基金the Postdoctoral Fellowship Program of CPSF under Grant Number GZB20240280the Jiangxi Provincial Natural Science Foundation (20224ACB218006)the financial support from High-level Talent Research Special Funds of Jiangxi University of Science and Technology (Grant No. 205200100670)the Jiangxi Provincial Key Laboratory of Power Energy Storage Batteries and Materials (2024SSY10011)the Major Scientific and Technological Research R&D Special Project of Jiangxi Province(20244AFI92002)
文摘The implementation of multifunctional application scenarios for mobile terminal devices has increased the energy density requirements of batteries.Increasing the charging voltage can rapidly increase the specific capacity of layered transition metal oxides;however,it also exacerbates the release of lattice oxygen and the contraction of the unit cell.Ternary materials are designed in a secondary particle state to meet the requirements of power battery applications.Therefore,to create ternary materials that can operate under ultrahigh voltages,attention should be given to both surface modification and particle integrity maintenance.By utilizing elemental selenium(Se)with a low melting point,easy sublimation,and multiple variable valence states,deep grain boundary modification was implemented inside the particles.The performance of the cathode material was evaluated through pouch cells,and the improvement mechanism was explored through molecular dynamics simulation calculations.Under the protection of a three-dimensional Se-rich modified layer,LiNi_(1/3)Co_(1/3)Mn_(1/3)O_(2)achieved stable operation at ultrahigh voltages(4.6 V vs.Li/Li^(+));a sacrificial protection mechanism based on the chronic decomposition of the Se-rich layer was proposed to explain the efficacy of Se modification in stabilizing ternary materials.This deep grain boundary modification based on elemental Se provides a new solution for the ultrahigh-voltage operation of transition metal oxides and provides a scientific basis and technical support for solving the interface contact problem of all-solid-state batteries.
基金The financial supports from National Natural Science Foundation of China(Nos.52574313,52204272 and 52074091)to this project。
文摘The susceptibility of ore particles to electrical breakdown plays a critical role for high voltage pulse(HVP)breakage,yet its quantitative characterization still lacks deep understanding.Two indicators,namely breakdown delay time(T_(d))and breakdown strength(E_(b))were compared,based on analysis on the two breakdown modes namely wavefront mode and post-wave mode.It was found that T_(d) is more suitable to characterize the susceptibility of ore particles to electrical breakdown in HVP breakage than E_(b).A probabilistic model based on the Weibull distribution is developed to describe the relation of breakdown probability to T_(d).Regression analyses were conducted to investigate how operating parameters and particle properties influence Td and size reduction degree of ore particles in HVP breakage.The regressed models demonstrate potential capability to predict metallic minerals content and HVP breakage degree based on operating parameters and particle properties.
基金supported by State Grid Sichuan Electric Power Company science and technology project“Research on Key Technologies for Reclosing of High-Ratio New Energy Grid Connection Lines.”(Program No:52199723002Q).
文摘The integration of a high proportion of renewable energy introduces significant challenges for the adaptability of traditional fault nature identification methods.To address these challenges,this paper presents a novel fault nature identification method for renewable energy grid-connected interconnection lines,leveraging wavelet packet decomposition and voltage waveform time-frequency morphology comparison algorithms.First,the paper investigates the harmonic injection mechanism during non-full-phase operation following fault isolation in photovoltaic renewable energy systems,and examines the voltage characteristics of faulted phases in renewable energy scenarios.The analysis reveals that substantial differences exist in both the time and frequency domains of phase voltages before and after the extinction of transient faults,whereas permanent faults do not exhibit such variations.Building on this observation,the paper proposes a voltage time-frequency feature extraction method based on wavelet packet decomposition,wherein low-frequency waveform components are selected to characterize fault features.Subsequently,a fault nature identification method is introduced,based on a voltage waveform time-frequency morphology comparison.By employing a windowing technique to quantify waveform differences before and after arc extinction,this method effectively distinguishes between permanent and transient faults and accurately determines the arc extinction time.Finally,a 220 kV renewable energy grid connection line model is developed using PSCAD for verification.The results demonstrate that the proposed method is highly adaptable across various fault locations,transition resistances,and renewable energy control strategies,and can reliably identify fault nature in renewable energy grid connection scenarios.
基金supported in part by the National Natural Science Foundation of China(under Grant 62473309,62203352)the Shaanxi Outstanding Youth Science Fund Project(under Grant 2024JC-JCQN-68)+1 种基金the Xi’an Science and Technology Plan Project(under Grant 24GXFW0050)the Xi’an Key Laboratory(under Grant 24ZDSY0015).
文摘Accurate estimation of battery health status plays a crucial role in battery management systems.However,the lack of operational data still affects the accuracy of battery state of health(SOH)estimation.For this reason,a SOH estimation method is proposed based on charging data reconstruction combined with image processing.The charging voltage data is used to train the least squares generative adversarial network(LSGAN),which is validated under different levels of missing data.From a visual perspective,the Gram angle field method is applied to convert one-dimensional time series data into image data.This method fully preserves the time series characteristics and nonlinear evolution patterns,which avoids the difficulties and limited expressive power associated with manual feature extraction.At the same time,the Swin Transformer model is introduced to extract global structures and local details from images,enabling better capture of sequence change trends.Combined with the long short-term memory network(LSTM),this enables accurate estimation of battery SOH.Two different types of batteries are used to validate the test.The experimental results show that the proposed method has good estimation accuracy under different training proportions.
基金supported in part by the National Natural Science Foundation of China under Grant 52477060in part by the Tianjin Natural Science Foundation Project under Grant 24JCZDJC00250in part by the Zhejiang Leading Innovation and Entrepreneurship Team Project under Grant 2024R01012.
文摘In position-sensorless brushless direct current(DC)motors(BLDCMs)fed by a four-switch three-phase(FSTP)inverter,only two phases are fully controlled,while the remaining phase is tied to the midpoint of the split DC-link capacitors.The voltage pulses required by inductance-based initial position detection can cause unequal discharge of the series capacitors,shifting the neutral-point voltage away from half of DC-link voltage(U_(dc)/2).This neutral-point drift breaks the spatial symmetry of the inverter voltage vectors,so the 360°electrical period can no longer be evenly partitioned into six sectors during initial rotor position detection.To address this issue,this paper proposes a detection-pulse injection sequence that explicitly accounts for the asymmetric voltage vectors of the FSTP inverter.With the proposed sequence,the initial rotor position can be identified within a 30°electrical sector.The method requires no additional voltage or current sensors,and experimental results confirm its feasibility.
文摘With the rapid integration of renewable energy sources,modern power systems are increasingly challenged by heightened volatility and uncertainty.Doubly-fed variable-speed pumped storage units(DFVS-PSUs)have emerged as promising technologies for mitigating grid oscillations and enhancing system flexibility.However,the excitation converters in DFVS-PSUs are prone to significant issues such as elevated common-mode voltage(CMV)and neutral-point voltage(NPV)fluctuations,which can lead to electromagnetic interference and degrade transient performance.To address these challenges,an optimized virtual space vector pulse width modulation(OVSVPWM)strategy is proposed,aiming to suppress CMV and NPV simultaneously through coordinated multi-objective control.Specifically,a dynamic feedback mechanism is introduced to adjust the balancing factor of basic vectors in the synthesized virtual small vector in real-time,achieving autonomous balancing of the NPV.To address the excessive switching actions introduced by the OVSVPWM strategy,a phase duty ratio-based sequence reconstruction method is adopted,which reduces the total number of switching actions to half of the original.A zero-level buffering scheme is employed to reconstruct the single-phase voltage-level output sequence,achieving peak CMV suppression down to udc/6.Simulation results demonstrate that the proposed strategy significantly improves electromagnetic compatibility and operational stability while maintaining high power quality.
基金supported in part by the National Natural Science Fundation of China(52225704 and 52107096).
文摘The dynamics of network power response play a crucial role in system stability.However,the integration of power electronic equipment leads to amplitude and angular frequency(abbreviated as"frequency")time-varying characteristics of the node voltage during dynamic processes.As a result,traditional calcu-lation methods for and characteristics of the power response of the network based on phasor and impe-dance lose their validity.Therefore,this paper undertakes mathematical calculations to reveal the power response of a network under excitation by voltage with time-varying amplitude and frequency(TVAF),relying on the original mathematical relationships and superimposed step response.Then,the multi-timescale characteristics of both the active and reactive power of the network are explored physically.Additionally,this paper reveals a new phenomenon of storing and releasing the active and reactive power of the network.To meet practical engineering requirements,a simplified power expression is presented.Finally,the theoretical analysis is validated through time-domain simulations.
基金supported by the Laboratory of Soil and Concrete of Abadgaran Negin Jonoobshargh Company(ANJ Co.)Chem Concrete Pty Ltd.Australia(117/3C-1397)。
文摘Electrokinetic(EK)treatment is an effective method in accelerating the consolidation and improving the geotechnical properties of fine-grained soils.This method stabilizes the soil and increases the bearing capacity of piles by improving the soil shear strength.Changing the soil p H,due to the occurrence of chemical reactions of electrolysis in the soil,can increase its shear strength.However,the electrodes used in this method corrode due to the change in the soil p H,which in turn reduces the electrical potential.Electrode corrosion and loss of electrical potential can significantly reduce the efficiency of the EK method.In addition,when using the EK method to increase the bearing capacity of piles,changing the p H can cause corrosion and damage to the piles.One of the most important factors influencing the change in the p H of soil is the voltage applied during the EK process.It was reported that increasing the voltage affects the intensity of chemical reactions and electroosmotic flow and thus increases the efficiency of EK.However,very limited research has been conducted on the effect of voltage on the performance of EK method.In the present study,the effects of three voltages on soil p H and corrosion resistance of four types of electrodes including iron(Ir),stainless steel(St),copper(Co),and aluminium(Al)were studied.In addition,the effects of p H variations on the corrosion rate of three types of piles including steel pile(SP),reinforced cement concrete pile(RCCP),and reinforced lime-cement concrete pile(RLCCP)were investigated.It was observed that increasing the voltage from a specific limit had no effect on the intensity of electrolysis reactions and the soil p H adjacent to the electrodes did not change more than a specific limit.Moreover,increasing the voltage to higher than 35 V(i.e.45 V)did not increase the volume of drained water from the soil,but caused more electric current than the allowable current for Ir,St,and Al electrodes,and the corrosion intensity of these electrodes increased significantly.RCCP reduced the soil p H to 2.4 within 7 d of curing due to severe corrosion(13%corrosion rate).The soil p H values adjacent to RCCP and RLCCP within 28 d of curing reduced to 3.7 and 3.8,respectively,but the two piles were not damaged.In general,the results of this research showed that selecting an optimized voltage had a significant effect on the efficiency of EK,and increasing the voltage did not always lead to increase in the efficiency of EK process.
文摘The influence of additive Nd_2O_3 on varistor voltage and microstructure of ZnO varistor was studied,and its mechanism was proposed from theoretical analysis. The results show that the varistor voltage of ZnO varistor increases with the content of Nd_2O_3 in the range of 0～0.04 (%,mol fraction). However when the content of Nd_2O_3 is more than 0.04 (%,mol fraction),the varistor voltage of ZnO varistor decreases with the content increase. The microstructure analysis indicates that a small amount of new compound with Nd exists at ZnO grain boundary and hinders the movement of grain boundary,which decreases the size of ZnO grain and makes the grain size and distribution homogeneous,as a result,additive (Nd_2O_3) raises the varistor voltage of the varistor greatly.
基金Project supported partially by the National Natural Science Foundation of China (Grant Nos. 60906038 and 61076082)
文摘Based on the theoretical and experimental investigation of a thin silicon layer（TSL） with linear variable doping（LVD） and further research on the TSL LVD with a multiple step field plate（MSFP）,a breakdown voltage（BV） model is proposed and experimentally verified in this paper.With the two-dimensional Poisson equation of the silicon on insulator（SOI） device,the lateral electric field in drift region of the thin silicon layer is assumed to be constant.For the SOI device with LVD in the thin silicon layer,the dependence of the BV on impurity concentration under the drain is investigated by an enhanced dielectric layer field（ENDIF）,from which the reduced surface field（RESURF） condition is deduced.The drain in the centre of the device has a good self-isolation effect,but the problem of the high voltage interconnection（HVI） line will become serious.The two step field plates including the source field plate and gate field plate can be adopted to shield the HVI adverse effect on the device.Based on this model,the TSL LVD SOI n-channel lateral double-diffused MOSFET（nLDMOS） with MSFP is realized.The experimental breakdown voltage（BV） and specific on-resistance（R on,sp） of the TSL LVD SOI device are 694 V and 21.3 ·mm 2 with a drift region length of 60 μm,buried oxide layer of 3 μm,and silicon layer of 0.15 μm,respectively.
基金supported by the National Natural Science Foundation of China(52477221,52202296)the Natural Science Foundation of Shaanxi Province(2023KXJ-246,2022JQ-048)。
文摘Metal-insulator-metal aluminium electrolytic capacitors(MIM-AECs)combine high capacity-density and high breakdown field strength of solid AECs with high-frequency responsibility,wide workingtemperature window and waterproof properties of MIM nanocapacitors.However,interfacial atomic diffusion poses a major obstacle,preventing the high-voltage MIM-AECs exploitation and thereby hampering their potential and advantages in high-power and high-energy-density applications.Here,an innovative high-voltage MIM-AECs were fabricated.The AlPO_(4)buffer layer is formed on AlO(OH)/AAO/Al surface by using H_(3)PO_(4)treatment,then a stable van der Waals(vdW)SnO_(2)/AlPO_(4)/AAO/Al multilayer was constructed via atomic layer deposition(ALD)technology.Due to higher diffusion barrier and lower carrier migration of SnO_(2)/AlPO_(4)/AAO interfaces,Sn atom diffusion is inhibited and carrier acceleration by electric field is weakened,guaranteeing high breakdown field strength of dielectric AAO and avoiding local breakdown risks.Through partial etching to hydrated AlO(OH)by H_(3)PO_(4)treatment,the tunnel was further opened up to facilitate subsequent ALD-SnO_(2)entry,thus obtaining a high SnO_(2)coverage.The SnO_(2)/AlPO_(4)/AAO/Al capacitors show a comprehensive performance in high-voltage(260 V),hightemperature(335℃),high-humidity(100%RH)and high-frequency response(100 k Hz),outperforming commercial solid-state AECs,and high-energy density(8.6μWh/cm^(2)),markedly exceeding previously reported MIM capacitors.The work lays the foundation for next-generation capacitors with highvoltage,high-frequency,high-temperature and high-humidity resistance.
基金supported by the National Natural Science Foundation of China (Nos. 22379121, 62005216)Basic Public Welfare Research Program of Zhejiang (No. LQ22F050013)+1 种基金Zhejiang Province Key Laboratory of Flexible Electronics Open Fund (2023FE005)Shenzhen Foundation Research Program (No. JCYJ20220530112812028)。
文摘Fluoride-based electrolyte exhibits extraordinarily high oxidative stability in high-voltage lithium metal batteries(h-LMBs) due to the inherent low highest occupied molecular orbital(HOMO) of fiuorinated solvents. However, such fascinating properties do not bring long-term cyclability of h-LMBs. One of critical challenges is the interface instability in contacting with the Li metal anode, as fiuorinated solvents are highly susceptible to exceptionally reductive metallic Li attributed to its low lowest unoccupied molecular orbital(LUMO), which leads to significant consumption of the fiuorinated components upon cycling.Herein, attenuating reductive decomposition of fiuorinated electrolytes is proposed to circumvent rapid electrolyte consumption. Specifically, the vinylene carbonate(VC) is selected to tame the reduction decomposition by preferentially forming protective layer on the Li anode. This work, experimentally and computationally, demonstrates the importance of pre-passivation of Li metal anodes at high voltage to attenuate the decomposition of fiuoroethylene carbonate(FEC). It is expected to enrich the understanding of how VC attenuate the reactivity of FEC, thereby extending the cycle life of fiuorinated electrolytes in high-voltage Li-metal batteries.
基金supported by the National Key R&D Program of China(2022YFB3803505)National Natural Scientific Foundation of China(U21A2080&22479009)National Related Project and the Fundamental Research Funds for the Central Universities(FRF-TP-22-01C2)。
文摘Adopting high-voltage Ni-rich cathodes in halide and sulfide-based all-solid-state lithium batteries(ASSLBs)holds great promise for breaking through the 400 Wh kg^(-1)bottleneck.However,both cell configurations are confronted with intricate interfacial challenges in high-voltage regines(>4.5 V),resulting in inadequate cathode utilization and premature cell degradation.Moreover,contrary to previous studies,coupled with LiNi_(0.85)Co_(0.1)Mn_(0.05)O_(2)cathodes,typical halide(Li_(2)ZrCl_(6))-based cells at 4.5 V feature unlimited interfacial degradation and poor long cycle stability,while typical sulfide(Li_(6)PS_(5)Cl)-based cells feature self-limited interfacial degradation and poor initial cycle stability.Herein,this work addresses the high-voltage limitations of Li_(2)ZrCl_(6)and Li_(6)PS_(5)Cl catholyte-based cells by manipulating electrode mass fraction and tailoring interfacial composition,thereby effectively improving interfacial charge-transfer kinetics and(electro)chemical stability within cathodes.After appropriate interface design,both optimized cells at 4.5 V demonstrate remarkably increased initial discharge capacities(>195 mA h g^(-1)at0.1 C),improved cycle stabilities(>80%after 600 cycles at 0.5 C),and enhanced rate performances(>115 mA h g^(-1)at 1.0 C).This work deepens our understanding of high-voltage applications for halide/sulfide electrolytes and provides generalized interfacial design strategies for advancing high-voltage ASSLBs.
基金supported by the National Natural Science Foundation under Grant 62273189the Shandong Province Natural Science Foundation under Grant ZR2021MF005Systems Science Plus Joint Research Program of Qingdao University under Grant XT2024201 of China supporting this research work.
文摘This article investigates the anti-disturbance and stabilization problems for the nonlinear uncertain permanent magnet synchronous motor(PMSM)with stator voltage saturation and unknown load.A smooth switching mechanism is presented to structure the adaptive integral terminal sliding mode control(SMC)strategy.The control design consists of compensation control and nominal control,which improves the rapidity and accuracy of trajectory tracking.The smooth saturation model based on the error function is applied to approximate the voltage saturation phenomenon.Additionally,to deal with the adverse effects of various unknown disturbances,including model parameter uncertainties and unknown external load disturbances,an improved disturbance observer(DO)is proposed.This observer effectively suppresses the fluctuations caused by fixed gain during the starting period of the system.Finally,the experimental results under different conditions show that the proposed strategy has good tracking and disturbance suppression performances.
基金financial support by National Natural Science Foundation(NNSF)of China(Nos.52202269,52002248,U23B2069,22309162)Shenzhen Science and Technology program(No.20220810155330003)+1 种基金Shenzhen Basic Research Project(No.JCYJ20190808163005631)Xiangjiang Lab(22XJ01007).
文摘Sodium-ion batteries hold great promise as next-generation energy storage systems.However,the high instability of the electrode/electrolyte interphase during cycling has seriously hindered the development of SIBs.In particular,an unstable cathode–electrolyte interphase(CEI)leads to successive electrolyte side reactions,transition metal leaching and rapid capacity decay,which tends to be exacerbated under high-voltage conditions.Therefore,constructing dense and stable CEIs are crucial for high-performance SIBs.This work reports localized high-concentration electrolyte by incorporating a highly oxidation-resistant sulfolane solvent with non-solvent diluent 1H,1H,5H-octafluoropentyl-1,1,2,2-tetrafluoroethyl ether,which exhibited excellent oxidative stability and was able to form thin,dense and homogeneous CEI.The excellent CEI enabled the O3-type layered oxide cathode NaNi_(1/3)Mn_(1/3)Fe_(1/3)O_(2)(NaNMF)to achieve stable cycling,with a capacity retention of 79.48%after 300 cycles at 1 C and 81.15%after 400 cycles at 2 C with a high charging voltage of 4.2 V.In addition,its nonflammable nature enhances the safety of SIBs.This work provides a viable pathway for the application of sulfolane-based electrolytes on SIBs and the design of next-generation high-voltage electrolytes.
文摘Fluctuating voltage levels in power grids necessitate automatic voltage regulators(AVRs)to ensure stability.This study examined the modeling and control of AVR in hydroelectric power plants using model predictive control(MPC),which utilizes an extensive mathe-matical model of the voltage regulation system to optimize the control actions over a defined prediction horizon.This predictive feature enables MPC to minimize voltage deviations while accounting for operational constraints,thereby improving stability and performance under dynamic conditions.Thefindings were compared with those derived from an optimal proportional integral derivative(PID)con-troller designed using the artificial bee colony(ABC)algorithm.Although the ABC-PID method adjusts the PID parameters based on historical data,it may be difficult to adapt to real-time changes in system dynamics under constraints.Comprehensive simulations assessed both frameworks,emphasizing performance metrics such as disturbance rejection,response to load changes,and resilience to uncertainties.The results show that both MPC and ABC-PID methods effectively achieved accurate voltage regulation;however,MPC excelled in controlling overshoot and settling time—recording 0.0%and 0.25 s,respectively.This demonstrates greater robustness compared to conventional control methods that optimize PID parameters based on performance criteria derived from actual system behavior,which exhibited settling times and overshoots exceeding 0.41 s and 5.0%,respectively.The controllers were implemented using MATLAB/Simulink software,indicating a significant advancement for power plant engineers pursuing state-of-the-art automatic voltage regulations.
