Blast-induced dominant vibration frequency （DVF） involves a complex, nonlinear and small sample system considering rock properties, blasting parameters and topography. In this study, a combination of grey relational...Blast-induced dominant vibration frequency （DVF） involves a complex, nonlinear and small sample system considering rock properties, blasting parameters and topography. In this study, a combination of grey relational analysis and dimensional analysis procedures for prediction of dominant vibration frequency are presented. Six factors are selected from extensive effect factor sequences based on grey relational analysis, and then a novel blast-induced dominant vibration frequency prediction is obtained by dimensional analysis. In addition, the prediction is simplified by sensitivity analysis with 195 experimental blast records. Validation is carried out for the proposed formula based on the site test database of the first- period blasting excavation in the Guangdong Lufeng Nuclear Power Plant （GLNPP）. The results show the proposed approach has a higher fitting degree and smaller mean error when compared with traditional predictions.展开更多
The properties of gray cast iron(GCI)are affected by density of matrix,size of flake graphite and primary austenite.In this paper,the Y-type specimen of GCI was prepared by lost foam casting(LFC)with and without vibra...The properties of gray cast iron(GCI)are affected by density of matrix,size of flake graphite and primary austenite.In this paper,the Y-type specimen of GCI was prepared by lost foam casting(LFC)with and without vibration,and the influence of vibration frequency on the density of matrix,size of primary phase,and properties of the GCI was studied.The results show that the length of the flake graphite and the size of the primary austenite in GCI firstly decrease and then increase with the increase of the vibration frequency.With a vibration frequency of 35 Hz,the length of the flake graphite is the shortest,the primary austenite is the finest and the density of the matrix is the highest.In addition,the tensile strength,elongation and hardness of the GCI firstly increase and then decrease with the increase of the vibration frequency,due to the refinement of the primary phase and the increase of the matrix density.In order to analyze the refinement mechanism of the primary phase of the GCI fabricated by the LFC with vibration,the solidification temperature fields of the GCI fabricated by the LFC with the vibration frequency of 0 and 35 Hz were measured.The results show that the vibration reduces the eutectic point of the GCI and increases the supercooling degree during the eutectic transformation.As a result,the length of the flake graphite and the size of the primary austenite in GCI fabricated by LFC with the vibration frequency of 35 Hz decrease.展开更多
A broadband infrared surface sum frequency generation vibrational spectroscopy （SFG-VS） and an in situ UV excitation setup devoted to studying surface photocatalysis have been constructed. With a home-made compact h...A broadband infrared surface sum frequency generation vibrational spectroscopy （SFG-VS） and an in situ UV excitation setup devoted to studying surface photocatalysis have been constructed. With a home-made compact high vacuum cell, organic contaminants on TiO2 thin film surface prepared by RF magnetron sputtering were in situ removed under 266 nm irradiation in 10 kPa 02 atmosphere. We obtained the methanol spectrum in the CH3 stretching vibration region on TiO2 surface with changing the methanol pressure at room temperature. Features of both molecular and dissociative methanol, methoxy, adsorbed on this surface were resolved. The CH3 symmetric stretching vibration frequency and Fermi resonance of molecular methanol is red-shifted by about 6-8 cm-1 from low to high coverage. Moreover, the recombination of dissociative methanol and H on Surfaces in vacuum was also observed. Our results suggest two equilibria exist： between molecular methanol in the gas phase and that on surfaces, and between molecular methanol and dissociative methanol on surfaces.展开更多
Quasi-ultrasonic vibration with a frequency of 15 kHz and a maximum output of 2 kW was imposed on the deep drawing process of AZ31 magnesium alloy sheet at room temperature,in order to reveal the effect of high freque...Quasi-ultrasonic vibration with a frequency of 15 kHz and a maximum output of 2 kW was imposed on the deep drawing process of AZ31 magnesium alloy sheet at room temperature,in order to reveal the effect of high frequency vibration on deformation behavior of AZ31 during the process.From the drawn results and the observation of the microstructure within the large deformation area,high frequency vibration has a great influence on the formability,the forming load and the failure mode of AZ31 sheet during the deep drawing process;the influence is a comprehensive result of so-called "volume effect" and "surface effect",and relies on the vibrating amplitude.Total forming load decreased significantly as soon as the vibration superimposed.According to the tensile test results of AZ31 bars under ultrasonic vibration,the formability of AZ31 sheet increases firstly with the increase of stimulating energy,then decreases and finally becomes brittle.Under the combined influence of "surface effect" and the "softening" in the "volume effect" near the relative low amplitude of 25%A in the experiment(A is the maximum amplitude),the formability of AZ31 reaches the largest value,and the samples possess the same distribution trend of cracks as those added with lubricating oil.With the increase of excitation energy,the "volume effect" gradually becomes apparent,and finally the "hardening" of the "volume effect" occupies a dominant position.展开更多
Low frequency vibrations induced by underground railways have attracted increasing attention in recent years. To obtain the characteristics of low frequency vibrations and the low frequency performance of a floating s...Low frequency vibrations induced by underground railways have attracted increasing attention in recent years. To obtain the characteristics of low frequency vibrations and the low frequency performance of a floating slab track (FST), low frequency vibration tests on an FST in an underground laboratory at Beijing Jiaotong University were carried out. The FST and an unbalanced shaker SBZ30 for dynamic simulation were designed for use in low frequency vibration experiments. Vibration measurements were performed on the bogie of the unbalanced shaker, the rail, the slab, the tunnel invert, the tunnel wall, the tunnel apex, and on the ground surface at distances varying from 0 to 80 m from the track. Measurements were also made on several floors of an adjacent building. Detailed results of low frequency vibration tests were reported. The attenuation of low frequency vibrations with the distance from the track was presented, as well as the responses of different floors of the building. The experimental results could be regarded as a reference for developing methods to control low frequency vibrations and for adopting countermeasures.展开更多
Human motion induced vibration has very low frequency,ranging from 2 Hz to 5 Hz.Traditional vibration isolators are not effective in low-frequency regions due to the trade-off between the low natural frequency and the...Human motion induced vibration has very low frequency,ranging from 2 Hz to 5 Hz.Traditional vibration isolators are not effective in low-frequency regions due to the trade-off between the low natural frequency and the high load capacity.In this paper,inspired by the human spine,we propose a novel bionic human spine inspired quasi-zero stiffness(QZS)vibration isolator which consists of a cascaded multi-stage negative stiffness structure.The force and stiffness characteristics are investigated first,the dynamic model is established by Newton’s second law,and the isolation performance is analyzed by the harmonic balance method(HBM).Numerical results show that the bionic isolator can obtain better low-frequency isolation performance by increasing the number of negative structure stages,and reducing the damping values and external force values can obtain better low-frequency isolation performance.In comparison with the linear structure and existing traditional QZS isolator,the bionic spine isolator has better vibration isolation performance in low-frequency regions.It paves the way for the design of bionic ultra-low-frequency isolators and shows potential in many engineering applications.展开更多
The current research of wheel force transducer （WFT） mainly focuses on test signal processing and decoupling methods based on signal itself, while the WFT structure optimization research related to decreasing the ma...The current research of wheel force transducer （WFT） mainly focuses on test signal processing and decoupling methods based on signal itself, while the WFT structure optimization research related to decreasing the mass and increase the natural frequency and comprehen- sive sensitivity is not enough. In order to improve the WFT test accuracy, a structure optimization method based on natural frequency and comprehensive sensitivity indicators is put forward. The WPT with 8-beam elastic body is used for the finite element modeling （FEM）, in which the fol- lowing variations are taken into consideration： the con- nection type of elastic body with modified rim, the number of connection holes, and the respects of strain beam including the shape, the cross sectional area and the length, etc.. The test results shows that the natural frequency of the connecting block type is increased by 65.5% compared with the connecting seat type of elastic body ＆ modified rim, and the main channel sensitivity is improved as well. The results show that the connecting block type will achieve the best comprehensive performance when the number of connecting holes between the elastic body and the modified rim is 20. And the thinner and longer strain beam with smaller cross section area is preferable within the scope of elastic body mechanical strength. This research proposes a novel structure optimization method for WFT which contributes to improve the measurement performance of WFT.展开更多
In view of the influence and harm of low frequency vibration environment on the structure of spaceflight products,a low frequency dynamic study method for piezoelectric sensor based on the dynamic system of sinusoidal...In view of the influence and harm of low frequency vibration environment on the structure of spaceflight products,a low frequency dynamic study method for piezoelectric sensor based on the dynamic system of sinusoidal pressure is proposed.This method uses a sinusoidal pressure dynamic system with two-way dual channel import and export synchronization technology to study the low frequency characteristics of a piezoelectric sensor of PCB company,and its lower cut-off frequency is 0.26 Hz.It is also studied that when the frequency of the measured vibration or shock signal is 1-200 kHz,the error range of signal positive pressure action time is 4.87%-0.03%.The dynamic compensation for the low frequency of the vibration sensor is carried out,and the compensation effect is good.展开更多
Characterization of real-time and ultrafast motions of the complex molecules at surface and interface is critical to understand how interracial molecules function. It requires to develop surface-sensitive, fast-identi...Characterization of real-time and ultrafast motions of the complex molecules at surface and interface is critical to understand how interracial molecules function. It requires to develop surface-sensitive, fast-identification, and time-resolved techniques. In this study, we employ several key technical procedures and successfully develop a highly sensitive femtosecond time-resolved sum frequency generation vibrational spectroscopy （SFG-VS） system. This system is able to measure the spectra with two polarization combinations （ssp and ppp, or psp and ssp） simultaneously. It takes less than several seconds to collect one spectrum. To the best of our knowledge, it is the fastest speed of collecting SFG spectra reported by now. Using the time-resolved measurement, ultrafast vibrational dynamics of the N-H mode of α-helical peptide at water interface is determined. It is found that the membrane environment does not affect the N-H vibrational relaxation dynamics. It is expected that the time-resolved SFG system will play a vital role in the deep understanding of the dynamics and interaction of the complex molecules at surface and interface. Our method may also provide an important technical proposal for the people who plan to develop time-resolved SFG systems with simultaneous measurement of multiple polarization combinations.展开更多
Molecular structure, vibrational frequency and infrared intensity of UF6 are investigated by using the revised Perdew Burke-Enzerhof function with the triple-zeta polarized basis set. The calculation results are in go...Molecular structure, vibrational frequency and infrared intensity of UF6 are investigated by using the revised Perdew Burke-Enzerhof function with the triple-zeta polarized basis set. The calculation results are in good agreement with the experimental values and indicate the existence of a stable U2F6 molecule with a multiple bonded U2 unit. The calculation results also predict that the D3d symmetry of U2F6 is more stable than D3h. The optimized geometries, vibrational frequencies, and infrared intensities are also reported for U2F6 molecules in D3d symmetry. In addition, the isotopic shift of vibrational frequencies of the two molecules under isotopic substitution of uranium atom are also investigated with the same method. The U2F6 molecule is predicted to be better than UF6 for laser uranic isotope separation.展开更多
Ultrahigh resolution synthetic aperture radar(SAR)imaging for ship targets is significant in SAR imaging,but it suffers from high frequency vibration of the platform,which will induce defocus into SAR imaging results....Ultrahigh resolution synthetic aperture radar(SAR)imaging for ship targets is significant in SAR imaging,but it suffers from high frequency vibration of the platform,which will induce defocus into SAR imaging results.In this paper,a novel compensation method based on the sinusoidal frequency modulation Fourier-Bessel transform(SFMFBT)is proposed,it can estimate the vibration errors,and the phase shift ambiguity can be avoided via extracting the time frequency ridge consequently.By constructing the corresponding compensation function and combined with the inverse SAR(ISAR)technique,well-focused imaging results can be obtained.The simulation imaging results of ship targets demonstrate the validity of the proposed approach.展开更多
Aiming at providing with high-load capability in active vibration control of large-scale rotor system, a new type of active actuator to simultaneously reduce the dangers of low frequency flexural and torsional vibrati...Aiming at providing with high-load capability in active vibration control of large-scale rotor system, a new type of active actuator to simultaneously reduce the dangers of low frequency flexural and torsional vibrations is designed. The actuator employs electro-hydraulic system and can provide a high and circumferential load. To initialize new research, the characteristics of various kinds of active actuators to control rotor shaft vibration are briefly introduced. The purpose of this paper is to introduce the preliminary results via presenting the structure, functions and operating principles, in particular, the working process of the electro-hydraulic system of the new actuator which includes a set of high speed electromagnetic valves and a series of sloping cone-shaped openings, and presenting the transmission relationships among the control parameters from control signals into the valves to active load onto shaft. The course of the work is dynamic, and a series of spatial forces and moments are put on the shaft to get an external resultant force to reduce excitations that induce vibration of shafts. By checking states of vibration, the actuator can control the impulse width and the interval of injection time for applying different control force to a vibration shaft in two circumference directions through the regulating action of a set of combination directional control valves. The results from simulating analysis and experiment show evidence of that this design can satisfy the case of active process of decreasing of flexural and torsional vibrations.展开更多
Determination of molecular structures of organicinorganic hybrid perovskite(OIHP)nanocrystals at the single-nanocrystal and ensemble levels is essential to understanding the mechanisms responsible for their size-depen...Determination of molecular structures of organicinorganic hybrid perovskite(OIHP)nanocrystals at the single-nanocrystal and ensemble levels is essential to understanding the mechanisms responsible for their size-dependent optoelectronic properties and the nanocrystal assembling process,but its detection is still a bit challenging.In this study,we demonstrate that femtosecond sum frequency generation(SFG)vibrational spectroscopy can provide a highly sensitive tool for probing the molecular structures of nanocrystals with a size comparable to the Bohr diameter(∼10 nm)at the single-nanocrystal level.The SFG signals are monitored using the spectral features of the phenyl group in(RMBA)PbBr_(3) and(R-MBA)_(2)PbI_(4) nanocrystals(MBA:methyl-benzyl-ammonium).It is found that the SFG spectra exhibit a strong resonant peak at 3067±3 cm^(−1)(ν2 mode)and a weak shoulder peak at 3045±4 cm^(−1)(ν_(7a) mode)at the ensemble level,whereas a peak of theν2 mode and a peak at 3025±3 cm^(−1)(ν20b mode)at the single-nanocrystal level.The nanocrystals at the single-nanocrystal level tend to lie down on the surface,but stand up as the ensemble number and the averaged sizes increase.This finding may provide valuable information on the structural origins for size-dependent photo-physical properties and photoluminescence blinking dynamics in nanocrystals.展开更多
Purpose–This review aims to give a critical view of the wheel/rail high frequency vibration-induced vibration fatigue in railway bogie.Design/methodology/approach–Vibration fatigue of railway bogie arising from the ...Purpose–This review aims to give a critical view of the wheel/rail high frequency vibration-induced vibration fatigue in railway bogie.Design/methodology/approach–Vibration fatigue of railway bogie arising from the wheel/rail high frequency vibration has become the main concern of railway operators.Previous reviews usually focused on the formation mechanism of wheel/rail high frequency vibration.This paper thus gives a critical review of the vibration fatigue of railway bogie owing to the short-pitch irregularities-induced high frequency vibration,including a brief introduction of short-pitch irregularities,associated high frequency vibration in railway bogie,typical vibration fatigue failure cases of railway bogie and methodologies used for the assessment of vibration fatigue and research gaps.Findings–The results showed that the resulting excitation frequencies of short-pitch irregularity vary substantially due to different track types and formation mechanisms.The axle box-mounted components are much more vulnerable to vibration fatigue compared with other components.The wheel polygonal wear and rail corrugation-induced high frequency vibration is the main driving force of fatigue failure,and the fatigue crack usually initiates from the defect of the weld seam.Vibration spectrum for attachments of railway bogie defined in the standard underestimates the vibration level arising from the short-pitch irregularities.The current investigations on vibration fatigue mainly focus on the methods to improve the accuracy of fatigue damage assessment,and a systematical design method for vibration fatigue remains a huge gap to improve the survival probability when the rail vehicle is subjected to vibration fatigue.Originality/value–The research can facilitate the development of a new methodology to improve the fatigue life of railway vehicles when subjected to wheel/rail high frequency vibration.展开更多
Ethylene carbonate(EC)is an important electrolyte used in lithium-ion batteries due to its excellent electrochemical performance.However,propylene carbonate(PC)differs from EC by only one methyl substituent and exhibi...Ethylene carbonate(EC)is an important electrolyte used in lithium-ion batteries due to its excellent electrochemical performance.However,propylene carbonate(PC)differs from EC by only one methyl substituent and exhibits markedly poorproperties.The EC-PC disparity is still poorly understood at the molecular level.In this study,we demonstrated that femtosecond broadband sum frequency generation vibrational spectroscopy(SFG-VS)with simultaneous measurement of multiple polarization combinations provides a powerful probe for investigating the physicochemical processes at the electrode-electrolyte interface during the charge-discharge cycles of lithium batteries.Using monolayer graphene as the working electrode,we observed the distinct reaction outcomes of EC and PC on the electrode surface.The interfacial reaction of EC occurred only in the first charge-discharge cycle,while the interfacial reaction of PC was ongoing along with the charge-discharge cycles,which explains why EC is a better electrolyte choice than PC.This study provides direct experimental evidence in elucidating the differences in interfacial performance between EC and PC,facilitating a deeper understanding of battery interface reactions and guiding the design of high-performance lithium-ion batteries.展开更多
The vibrational frequency analysis of finite elastic tube filled with compressible viscous fluid has received plenty of attention in recent years. To apply frequency analysis to defect detection for example, it is nec...The vibrational frequency analysis of finite elastic tube filled with compressible viscous fluid has received plenty of attention in recent years. To apply frequency analysis to defect detection for example, it is necessary to investigate the vibrational behavior under appropriate boundary conditions. In this paper, we present a detailed theoretical study of the three dimensional modal analysis of compressible fluid within an elastic cylinder. The dispersion equations of flexura], torsional and longitudinal modes are derived by elastodynamic theory and the unsteady Stokes equation. The symbolic software Mathematica is used in order to find the coupled vibration frequencies. The dispersion equation is deduced and analytically solved. The finite element results are compared with the present method for validation and an acceptable match between them are obtained.展开更多
This report investigated the ordering of the alky chain of sphingomyelin （SMs） monolayers induced by cholesterol at the air/water interface using high-resolution broadband sum frequency generation vibrational spectr...This report investigated the ordering of the alky chain of sphingomyelin （SMs） monolayers induced by cholesterol at the air/water interface using high-resolution broadband sum frequency generation vibrational spectroscopy （HR-BB-SFG-VS）. The SFG spectra of the three nature sphingomyelin/cholesterol mixture monolayers with two concentrations of the cholesterol at the air/water interface are performed under different polarization combination. A new resolved CH2 symmetric stretching （d＋, ~2834 cm-1） and the CH3 symmetric stretching （r＋, ~2874 cm-1） mode are applied to characterize the conformational order in the sphingomyelin/cholesterol mixture monolayers. It was found that the cholesterol make the sphingosine backbones more conformational order. During this process, the conformational order of the N-linked acyl chain remains unaltered. Moreover, the sphingosine backbones of SMs have much larger contributions to gauche defects of SMs than one in the N-linked acyl chain. These results presented here not only shed lights on understanding of the interactions of sphingomyelin molecules with cholesterol molecules at interface but also demonstrates the ability of HR-BB-SFG to probe such complicated molecular systems.展开更多
Based on the magnetoelastic generalized variational principle and Hamilton＇s principle, a dynamic theoretical model characterizing the magnetoelastic interaction of a soft ferromagnetic medium in an applied magnetic ...Based on the magnetoelastic generalized variational principle and Hamilton＇s principle, a dynamic theoretical model characterizing the magnetoelastic interaction of a soft ferromagnetic medium in an applied magnetic field is developed in this paper. From the variational manipulation of magnetic scale potential and elastic displacement, all the fundamental equations for the magnetic field and mechanical deformation, as well as the magnetic body force and magnetic traction for describing magnetoelastic interaction are derived. The theoretical model is applied to a ferromagnetic rod vibrating in an applied magnetic field using a perturbation technique and the Galerkin method. The results show that the magnetic field will change the natural frequencies of the ferromagnetic rod by causing a decrease with the bending motion along the applied magnetic field where the magnetoelastic buckling will take place, and by causing an increase when the bending motion of the rod is perpendicular to the field. The prediction by the mode presented in this paper qualitatively agrees with the natural frequency changes of the ferromagnetic rod observed in the experiment.展开更多
The C-H stretch vibrational spectra of the trisiloxane superspreading surfactant Silwet L-77 （（CH3）3Si- O-Si（CH3）（C3H6）（OCH2CH2）7-8OCH3）-O-Si（CH3）3） at the air/water interface are measured with the surfac...The C-H stretch vibrational spectra of the trisiloxane superspreading surfactant Silwet L-77 （（CH3）3Si- O-Si（CH3）（C3H6）（OCH2CH2）7-8OCH3）-O-Si（CH3）3） at the air/water interface are measured with the surface Sum Frequency Generation Vibrational Spectroscopy （SFG-VS）. The spectra are dominated with the features from the -Si-CH3 groups around 2905 cm^-1 （symmetric stretch or SS mode） and 2957 ^-1 （mostly the asymmetric stretch or AS mode）, and with the weak but apparent contribution from the -O-CH2- groups around 2880 ^-1 （symmetric stretch or SS mode）. Comparison of the polarization dependent SFG spectra below and above the critical aggregate or micelle concentration （CAC） indicates that the molecular orientation of the C-H related molecular groups remained unchanged at different surface densities of the Silwet L-77 surfactant. The SFG-VS adsorption isotherm suggested that there was no sign of Silwet L-77 bilayer structure formation at the air/water interface. The Gibbs adsorption free energy of the Silwet surfactant to the air/water interface is -42.2±0.8kcal/mol, indicating the unusually strong adsorption ability of the Silwet L-77 superspreading surfactant.展开更多
The constructive or destructive spectral interference between the molecular groups oriented up and down at the interface in the sum-frequency generation （SFG） spectra provides a direct measurement of the absolute or...The constructive or destructive spectral interference between the molecular groups oriented up and down at the interface in the sum-frequency generation （SFG） spectra provides a direct measurement of the absolute orientation of these molecular groups. This simple approach can be employed to interrogate absolute molecular orientations other than using the complex absolute phase measurement in the SFG studies. We used the -CN group in the p-cyanophenol （PCP） molecule as the internal phase standard, and we measured the phases of the SFG fields of the -CN groups in the 3,5-dimethyl-4-hydroxy-benzonitrile （35DMHBN） and 2,6-dimethyl-4-hydroxy-benzonitrile （26DMHBN） at the air/water interface by measuring the SFG spectra of the aqueous surfaces of the mixtures of the PCP, 35DMHBN, and 26DMHBN solutions. The results showed that the 35DMHBN had its -CN group pointing into the aqueous phase; while the 26DMHBN, similar to the PCP, had its -CN group pointing away from the aqueous phase. The tilt angles of the -CN group for both the 35DMHBN and 26DMHBN molecules at the air/water interface were around 25°-45° from the interface normal. These results provided insights on the understanding of the detailed balance of the competing factors, such as solvation of the polar head groups, hydrogen bonding and hydrophobic effects, etc., on influencing the absolute molecular orientation at the air/water interface.展开更多
基金National Natural Science Funds for Distinguished Young Scholar under Grant No.51009086Hubei Key Laboratory of Roadway Bridge and Structure Engineering under Grant No.DQJJ201313Major State Basic Research Development Program of China(973 Program)under Grant No.2010CB732001
文摘Blast-induced dominant vibration frequency （DVF） involves a complex, nonlinear and small sample system considering rock properties, blasting parameters and topography. In this study, a combination of grey relational analysis and dimensional analysis procedures for prediction of dominant vibration frequency are presented. Six factors are selected from extensive effect factor sequences based on grey relational analysis, and then a novel blast-induced dominant vibration frequency prediction is obtained by dimensional analysis. In addition, the prediction is simplified by sensitivity analysis with 195 experimental blast records. Validation is carried out for the proposed formula based on the site test database of the first- period blasting excavation in the Guangdong Lufeng Nuclear Power Plant （GLNPP）. The results show the proposed approach has a higher fitting degree and smaller mean error when compared with traditional predictions.
基金financially supported by the National High Technology Research and Development Program of China(No.2007AA03Z113)
文摘The properties of gray cast iron(GCI)are affected by density of matrix,size of flake graphite and primary austenite.In this paper,the Y-type specimen of GCI was prepared by lost foam casting(LFC)with and without vibration,and the influence of vibration frequency on the density of matrix,size of primary phase,and properties of the GCI was studied.The results show that the length of the flake graphite and the size of the primary austenite in GCI firstly decrease and then increase with the increase of the vibration frequency.With a vibration frequency of 35 Hz,the length of the flake graphite is the shortest,the primary austenite is the finest and the density of the matrix is the highest.In addition,the tensile strength,elongation and hardness of the GCI firstly increase and then decrease with the increase of the vibration frequency,due to the refinement of the primary phase and the increase of the matrix density.In order to analyze the refinement mechanism of the primary phase of the GCI fabricated by the LFC with vibration,the solidification temperature fields of the GCI fabricated by the LFC with the vibration frequency of 0 and 35 Hz were measured.The results show that the vibration reduces the eutectic point of the GCI and increases the supercooling degree during the eutectic transformation.As a result,the length of the flake graphite and the size of the primary austenite in GCI fabricated by LFC with the vibration frequency of 35 Hz decrease.
基金This work was supported by the National Ba- sic Research Program of China （No.2013CB834600） and the National Natural Science Foundation of China （No.II27002/B030403, No.II290162/A040106, and No.21322310/B030402）.
文摘A broadband infrared surface sum frequency generation vibrational spectroscopy （SFG-VS） and an in situ UV excitation setup devoted to studying surface photocatalysis have been constructed. With a home-made compact high vacuum cell, organic contaminants on TiO2 thin film surface prepared by RF magnetron sputtering were in situ removed under 266 nm irradiation in 10 kPa 02 atmosphere. We obtained the methanol spectrum in the CH3 stretching vibration region on TiO2 surface with changing the methanol pressure at room temperature. Features of both molecular and dissociative methanol, methoxy, adsorbed on this surface were resolved. The CH3 symmetric stretching vibration frequency and Fermi resonance of molecular methanol is red-shifted by about 6-8 cm-1 from low to high coverage. Moreover, the recombination of dissociative methanol and H on Surfaces in vacuum was also observed. Our results suggest two equilibria exist： between molecular methanol in the gas phase and that on surfaces, and between molecular methanol and dissociative methanol on surfaces.
基金the Fundamental Research Funds for the Central Universities (No.CDJZR10110029)
文摘Quasi-ultrasonic vibration with a frequency of 15 kHz and a maximum output of 2 kW was imposed on the deep drawing process of AZ31 magnesium alloy sheet at room temperature,in order to reveal the effect of high frequency vibration on deformation behavior of AZ31 during the process.From the drawn results and the observation of the microstructure within the large deformation area,high frequency vibration has a great influence on the formability,the forming load and the failure mode of AZ31 sheet during the deep drawing process;the influence is a comprehensive result of so-called "volume effect" and "surface effect",and relies on the vibrating amplitude.Total forming load decreased significantly as soon as the vibration superimposed.According to the tensile test results of AZ31 bars under ultrasonic vibration,the formability of AZ31 sheet increases firstly with the increase of stimulating energy,then decreases and finally becomes brittle.Under the combined influence of "surface effect" and the "softening" in the "volume effect" near the relative low amplitude of 25%A in the experiment(A is the maximum amplitude),the formability of AZ31 reaches the largest value,and the samples possess the same distribution trend of cracks as those added with lubricating oil.With the increase of excitation energy,the "volume effect" gradually becomes apparent,and finally the "hardening" of the "volume effect" occupies a dominant position.
基金Project supported by the National Natural Science Foundation of China (No. 51008017)the Fundamental Research Funds for the Central Universities of China (Nos. 2009JBM074 and 2009JBM075)
文摘Low frequency vibrations induced by underground railways have attracted increasing attention in recent years. To obtain the characteristics of low frequency vibrations and the low frequency performance of a floating slab track (FST), low frequency vibration tests on an FST in an underground laboratory at Beijing Jiaotong University were carried out. The FST and an unbalanced shaker SBZ30 for dynamic simulation were designed for use in low frequency vibration experiments. Vibration measurements were performed on the bogie of the unbalanced shaker, the rail, the slab, the tunnel invert, the tunnel wall, the tunnel apex, and on the ground surface at distances varying from 0 to 80 m from the track. Measurements were also made on several floors of an adjacent building. Detailed results of low frequency vibration tests were reported. The attenuation of low frequency vibrations with the distance from the track was presented, as well as the responses of different floors of the building. The experimental results could be regarded as a reference for developing methods to control low frequency vibrations and for adopting countermeasures.
基金supported by the National Natural Science Foundation of China(No.12072221)the Natural Science Foundation of Liaoning Province of China(No.2019-KF-01-09)。
文摘Human motion induced vibration has very low frequency,ranging from 2 Hz to 5 Hz.Traditional vibration isolators are not effective in low-frequency regions due to the trade-off between the low natural frequency and the high load capacity.In this paper,inspired by the human spine,we propose a novel bionic human spine inspired quasi-zero stiffness(QZS)vibration isolator which consists of a cascaded multi-stage negative stiffness structure.The force and stiffness characteristics are investigated first,the dynamic model is established by Newton’s second law,and the isolation performance is analyzed by the harmonic balance method(HBM).Numerical results show that the bionic isolator can obtain better low-frequency isolation performance by increasing the number of negative structure stages,and reducing the damping values and external force values can obtain better low-frequency isolation performance.In comparison with the linear structure and existing traditional QZS isolator,the bionic spine isolator has better vibration isolation performance in low-frequency regions.It paves the way for the design of bionic ultra-low-frequency isolators and shows potential in many engineering applications.
基金Supported by Anhui Provincal Natural Science Foundation of China (Grant No. 1608085ME109)National Natural Science Foundation of China (Grant Nos. 51675005, 51105001)State Key Laboratory of Automotive Safety and Energy, Tsinghua University, China (Grant No. KF14022)
文摘The current research of wheel force transducer （WFT） mainly focuses on test signal processing and decoupling methods based on signal itself, while the WFT structure optimization research related to decreasing the mass and increase the natural frequency and comprehen- sive sensitivity is not enough. In order to improve the WFT test accuracy, a structure optimization method based on natural frequency and comprehensive sensitivity indicators is put forward. The WPT with 8-beam elastic body is used for the finite element modeling （FEM）, in which the fol- lowing variations are taken into consideration： the con- nection type of elastic body with modified rim, the number of connection holes, and the respects of strain beam including the shape, the cross sectional area and the length, etc.. The test results shows that the natural frequency of the connecting block type is increased by 65.5% compared with the connecting seat type of elastic body ＆ modified rim, and the main channel sensitivity is improved as well. The results show that the connecting block type will achieve the best comprehensive performance when the number of connecting holes between the elastic body and the modified rim is 20. And the thinner and longer strain beam with smaller cross section area is preferable within the scope of elastic body mechanical strength. This research proposes a novel structure optimization method for WFT which contributes to improve the measurement performance of WFT.
文摘In view of the influence and harm of low frequency vibration environment on the structure of spaceflight products,a low frequency dynamic study method for piezoelectric sensor based on the dynamic system of sinusoidal pressure is proposed.This method uses a sinusoidal pressure dynamic system with two-way dual channel import and export synchronization technology to study the low frequency characteristics of a piezoelectric sensor of PCB company,and its lower cut-off frequency is 0.26 Hz.It is also studied that when the frequency of the measured vibration or shock signal is 1-200 kHz,the error range of signal positive pressure action time is 4.87%-0.03%.The dynamic compensation for the low frequency of the vibration sensor is carried out,and the compensation effect is good.
文摘Characterization of real-time and ultrafast motions of the complex molecules at surface and interface is critical to understand how interracial molecules function. It requires to develop surface-sensitive, fast-identification, and time-resolved techniques. In this study, we employ several key technical procedures and successfully develop a highly sensitive femtosecond time-resolved sum frequency generation vibrational spectroscopy （SFG-VS） system. This system is able to measure the spectra with two polarization combinations （ssp and ppp, or psp and ssp） simultaneously. It takes less than several seconds to collect one spectrum. To the best of our knowledge, it is the fastest speed of collecting SFG spectra reported by now. Using the time-resolved measurement, ultrafast vibrational dynamics of the N-H mode of α-helical peptide at water interface is determined. It is found that the membrane environment does not affect the N-H vibrational relaxation dynamics. It is expected that the time-resolved SFG system will play a vital role in the deep understanding of the dynamics and interaction of the complex molecules at surface and interface. Our method may also provide an important technical proposal for the people who plan to develop time-resolved SFG systems with simultaneous measurement of multiple polarization combinations.
基金Project supported by the Natural Science Foundation of Shaanxi Province, China (Grant No. 2009JM1007)
文摘Molecular structure, vibrational frequency and infrared intensity of UF6 are investigated by using the revised Perdew Burke-Enzerhof function with the triple-zeta polarized basis set. The calculation results are in good agreement with the experimental values and indicate the existence of a stable U2F6 molecule with a multiple bonded U2 unit. The calculation results also predict that the D3d symmetry of U2F6 is more stable than D3h. The optimized geometries, vibrational frequencies, and infrared intensities are also reported for U2F6 molecules in D3d symmetry. In addition, the isotopic shift of vibrational frequencies of the two molecules under isotopic substitution of uranium atom are also investigated with the same method. The U2F6 molecule is predicted to be better than UF6 for laser uranic isotope separation.
基金supported by the National Natural Science Foundation of China(61871146)the Fundamental Research Funds for the Central Universities(FRFCU5710093720)。
文摘Ultrahigh resolution synthetic aperture radar(SAR)imaging for ship targets is significant in SAR imaging,but it suffers from high frequency vibration of the platform,which will induce defocus into SAR imaging results.In this paper,a novel compensation method based on the sinusoidal frequency modulation Fourier-Bessel transform(SFMFBT)is proposed,it can estimate the vibration errors,and the phase shift ambiguity can be avoided via extracting the time frequency ridge consequently.By constructing the corresponding compensation function and combined with the inverse SAR(ISAR)technique,well-focused imaging results can be obtained.The simulation imaging results of ship targets demonstrate the validity of the proposed approach.
基金supported by National Natural Science Foundation of China (No.50475112)National Hi-Tech Research and Development Program of China (863 Program,No.2006AA110112).
文摘Aiming at providing with high-load capability in active vibration control of large-scale rotor system, a new type of active actuator to simultaneously reduce the dangers of low frequency flexural and torsional vibrations is designed. The actuator employs electro-hydraulic system and can provide a high and circumferential load. To initialize new research, the characteristics of various kinds of active actuators to control rotor shaft vibration are briefly introduced. The purpose of this paper is to introduce the preliminary results via presenting the structure, functions and operating principles, in particular, the working process of the electro-hydraulic system of the new actuator which includes a set of high speed electromagnetic valves and a series of sloping cone-shaped openings, and presenting the transmission relationships among the control parameters from control signals into the valves to active load onto shaft. The course of the work is dynamic, and a series of spatial forces and moments are put on the shaft to get an external resultant force to reduce excitations that induce vibration of shafts. By checking states of vibration, the actuator can control the impulse width and the interval of injection time for applying different control force to a vibration shaft in two circumference directions through the regulating action of a set of combination directional control valves. The results from simulating analysis and experiment show evidence of that this design can satisfy the case of active process of decreasing of flexural and torsional vibrations.
基金supported by the National Key Research and Development Program of China(No.2017YFA0303500,No.2018YFA0208702)the National Natural Science Foundation of China(No.21925302,No.21873090,and No.21633007)Anhui Initiative in Quantum Information Technologies(No.AHY090000)。
文摘Determination of molecular structures of organicinorganic hybrid perovskite(OIHP)nanocrystals at the single-nanocrystal and ensemble levels is essential to understanding the mechanisms responsible for their size-dependent optoelectronic properties and the nanocrystal assembling process,but its detection is still a bit challenging.In this study,we demonstrate that femtosecond sum frequency generation(SFG)vibrational spectroscopy can provide a highly sensitive tool for probing the molecular structures of nanocrystals with a size comparable to the Bohr diameter(∼10 nm)at the single-nanocrystal level.The SFG signals are monitored using the spectral features of the phenyl group in(RMBA)PbBr_(3) and(R-MBA)_(2)PbI_(4) nanocrystals(MBA:methyl-benzyl-ammonium).It is found that the SFG spectra exhibit a strong resonant peak at 3067±3 cm^(−1)(ν2 mode)and a weak shoulder peak at 3045±4 cm^(−1)(ν_(7a) mode)at the ensemble level,whereas a peak of theν2 mode and a peak at 3025±3 cm^(−1)(ν20b mode)at the single-nanocrystal level.The nanocrystals at the single-nanocrystal level tend to lie down on the surface,but stand up as the ensemble number and the averaged sizes increase.This finding may provide valuable information on the structural origins for size-dependent photo-physical properties and photoluminescence blinking dynamics in nanocrystals.
基金The author sincerely appreciates the help provided by the research team(Wheel/rail interaction,Vibration and Noise Research Team)and CRRC.In addition,this study has also been supported by Science and Technology Research Plan of China Railway General Corporation(No.P2019J002,N2022J009)China Association of Science and Technology Young Talent Support Project(No.2019QNRC001)+1 种基金National Natural Science Foundation(No.U1934203)Sichuan Science and Technology Program(No.2022NSFSC0469,2023NSFSC0374,2023YFH0049).
文摘Purpose–This review aims to give a critical view of the wheel/rail high frequency vibration-induced vibration fatigue in railway bogie.Design/methodology/approach–Vibration fatigue of railway bogie arising from the wheel/rail high frequency vibration has become the main concern of railway operators.Previous reviews usually focused on the formation mechanism of wheel/rail high frequency vibration.This paper thus gives a critical review of the vibration fatigue of railway bogie owing to the short-pitch irregularities-induced high frequency vibration,including a brief introduction of short-pitch irregularities,associated high frequency vibration in railway bogie,typical vibration fatigue failure cases of railway bogie and methodologies used for the assessment of vibration fatigue and research gaps.Findings–The results showed that the resulting excitation frequencies of short-pitch irregularity vary substantially due to different track types and formation mechanisms.The axle box-mounted components are much more vulnerable to vibration fatigue compared with other components.The wheel polygonal wear and rail corrugation-induced high frequency vibration is the main driving force of fatigue failure,and the fatigue crack usually initiates from the defect of the weld seam.Vibration spectrum for attachments of railway bogie defined in the standard underestimates the vibration level arising from the short-pitch irregularities.The current investigations on vibration fatigue mainly focus on the methods to improve the accuracy of fatigue damage assessment,and a systematical design method for vibration fatigue remains a huge gap to improve the survival probability when the rail vehicle is subjected to vibration fatigue.Originality/value–The research can facilitate the development of a new methodology to improve the fatigue life of railway vehicles when subjected to wheel/rail high frequency vibration.
基金supported by the National Natural Science Foundation of China(No.21925302)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0450202).
文摘Ethylene carbonate(EC)is an important electrolyte used in lithium-ion batteries due to its excellent electrochemical performance.However,propylene carbonate(PC)differs from EC by only one methyl substituent and exhibits markedly poorproperties.The EC-PC disparity is still poorly understood at the molecular level.In this study,we demonstrated that femtosecond broadband sum frequency generation vibrational spectroscopy(SFG-VS)with simultaneous measurement of multiple polarization combinations provides a powerful probe for investigating the physicochemical processes at the electrode-electrolyte interface during the charge-discharge cycles of lithium batteries.Using monolayer graphene as the working electrode,we observed the distinct reaction outcomes of EC and PC on the electrode surface.The interfacial reaction of EC occurred only in the first charge-discharge cycle,while the interfacial reaction of PC was ongoing along with the charge-discharge cycles,which explains why EC is a better electrolyte choice than PC.This study provides direct experimental evidence in elucidating the differences in interfacial performance between EC and PC,facilitating a deeper understanding of battery interface reactions and guiding the design of high-performance lithium-ion batteries.
文摘The vibrational frequency analysis of finite elastic tube filled with compressible viscous fluid has received plenty of attention in recent years. To apply frequency analysis to defect detection for example, it is necessary to investigate the vibrational behavior under appropriate boundary conditions. In this paper, we present a detailed theoretical study of the three dimensional modal analysis of compressible fluid within an elastic cylinder. The dispersion equations of flexura], torsional and longitudinal modes are derived by elastodynamic theory and the unsteady Stokes equation. The symbolic software Mathematica is used in order to find the coupled vibration frequencies. The dispersion equation is deduced and analytically solved. The finite element results are compared with the present method for validation and an acceptable match between them are obtained.
基金the National Natural Science Foundation of China(No.21227802)the National Natural Science Foundation of China(Nos. 21503235, 21673251)the ICCAS for Start-up Funding
文摘This report investigated the ordering of the alky chain of sphingomyelin （SMs） monolayers induced by cholesterol at the air/water interface using high-resolution broadband sum frequency generation vibrational spectroscopy （HR-BB-SFG-VS）. The SFG spectra of the three nature sphingomyelin/cholesterol mixture monolayers with two concentrations of the cholesterol at the air/water interface are performed under different polarization combination. A new resolved CH2 symmetric stretching （d＋, ~2834 cm-1） and the CH3 symmetric stretching （r＋, ~2874 cm-1） mode are applied to characterize the conformational order in the sphingomyelin/cholesterol mixture monolayers. It was found that the cholesterol make the sphingosine backbones more conformational order. During this process, the conformational order of the N-linked acyl chain remains unaltered. Moreover, the sphingosine backbones of SMs have much larger contributions to gauche defects of SMs than one in the N-linked acyl chain. These results presented here not only shed lights on understanding of the interactions of sphingomyelin molecules with cholesterol molecules at interface but also demonstrates the ability of HR-BB-SFG to probe such complicated molecular systems.
基金the National Natural Science Foundation of China(No.10502022)theProgram for New Century Excellent Talents in University(NCET-050878)
文摘Based on the magnetoelastic generalized variational principle and Hamilton＇s principle, a dynamic theoretical model characterizing the magnetoelastic interaction of a soft ferromagnetic medium in an applied magnetic field is developed in this paper. From the variational manipulation of magnetic scale potential and elastic displacement, all the fundamental equations for the magnetic field and mechanical deformation, as well as the magnetic body force and magnetic traction for describing magnetoelastic interaction are derived. The theoretical model is applied to a ferromagnetic rod vibrating in an applied magnetic field using a perturbation technique and the Galerkin method. The results show that the magnetic field will change the natural frequencies of the ferromagnetic rod by causing a decrease with the bending motion along the applied magnetic field where the magnetoelastic buckling will take place, and by causing an increase when the bending motion of the rod is perpendicular to the field. The prediction by the mode presented in this paper qualitatively agrees with the natural frequency changes of the ferromagnetic rod observed in the experiment.
文摘The C-H stretch vibrational spectra of the trisiloxane superspreading surfactant Silwet L-77 （（CH3）3Si- O-Si（CH3）（C3H6）（OCH2CH2）7-8OCH3）-O-Si（CH3）3） at the air/water interface are measured with the surface Sum Frequency Generation Vibrational Spectroscopy （SFG-VS）. The spectra are dominated with the features from the -Si-CH3 groups around 2905 cm^-1 （symmetric stretch or SS mode） and 2957 ^-1 （mostly the asymmetric stretch or AS mode）, and with the weak but apparent contribution from the -O-CH2- groups around 2880 ^-1 （symmetric stretch or SS mode）. Comparison of the polarization dependent SFG spectra below and above the critical aggregate or micelle concentration （CAC） indicates that the molecular orientation of the C-H related molecular groups remained unchanged at different surface densities of the Silwet L-77 surfactant. The SFG-VS adsorption isotherm suggested that there was no sign of Silwet L-77 bilayer structure formation at the air/water interface. The Gibbs adsorption free energy of the Silwet surfactant to the air/water interface is -42.2±0.8kcal/mol, indicating the unusually strong adsorption ability of the Silwet L-77 superspreading surfactant.
基金Ⅵ. ACKNOWLEDGMENTS Hong-fei Wang thanks the support by the National Natural Science Foundation of China （No.20373076, No.20425309, and No.20533070） and the Ministry of Science and Technology of China （No.2007CB815205）. Zhi-feng Cui thanks the support by the Natural Science Foundation of China （No.10674002） and the Natural Science Foundation of Anhui Province （No.ZD2007001-1）.
文摘The constructive or destructive spectral interference between the molecular groups oriented up and down at the interface in the sum-frequency generation （SFG） spectra provides a direct measurement of the absolute orientation of these molecular groups. This simple approach can be employed to interrogate absolute molecular orientations other than using the complex absolute phase measurement in the SFG studies. We used the -CN group in the p-cyanophenol （PCP） molecule as the internal phase standard, and we measured the phases of the SFG fields of the -CN groups in the 3,5-dimethyl-4-hydroxy-benzonitrile （35DMHBN） and 2,6-dimethyl-4-hydroxy-benzonitrile （26DMHBN） at the air/water interface by measuring the SFG spectra of the aqueous surfaces of the mixtures of the PCP, 35DMHBN, and 26DMHBN solutions. The results showed that the 35DMHBN had its -CN group pointing into the aqueous phase; while the 26DMHBN, similar to the PCP, had its -CN group pointing away from the aqueous phase. The tilt angles of the -CN group for both the 35DMHBN and 26DMHBN molecules at the air/water interface were around 25°-45° from the interface normal. These results provided insights on the understanding of the detailed balance of the competing factors, such as solvation of the polar head groups, hydrogen bonding and hydrophobic effects, etc., on influencing the absolute molecular orientation at the air/water interface.
