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从Gd_2O_3-UO_2燃料中萃取分离铀、钆的试验研究 被引量:1
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作者 李佳 朱常桂 +1 位作者 任萌 刘锦洪 《湿法冶金》 CAS 北大核心 2012年第3期170-174,共5页
研究了以TBP-煤油为萃取剂,从可燃毒性燃料Gd2O3-UO2的HNO3浸出液中萃取分离钆和铀,考察了铀质量浓度、HNO3浓度、相比、有机相中TBP体积分数、温度对铀、钆萃取率及铀、钆分离的影响。试验结果表明:钆萃合物以Gd(NO3)3.3TBP形式为主;... 研究了以TBP-煤油为萃取剂,从可燃毒性燃料Gd2O3-UO2的HNO3浸出液中萃取分离钆和铀,考察了铀质量浓度、HNO3浓度、相比、有机相中TBP体积分数、温度对铀、钆萃取率及铀、钆分离的影响。试验结果表明:钆萃合物以Gd(NO3)3.3TBP形式为主;在铀质量浓度80~100g/L、HNO3浓度4mol/L、相比Vo/Va=1.5/1、有机相中TBP体积分数40%、室温最佳条件下,体系具有较大铀、钆分离系数和铀分配系数;工艺稳定,易于实现。 展开更多
关键词 Gd2O3-UO2燃料 TBP 溶剂萃取 分离
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田湾核电厂铀钆燃料管理的主要安全问题 被引量:1
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作者 周红 王小海 《核安全》 2009年第1期27-30,49+63,共6页
本文针对田湾核电厂铀-钆燃料的燃料管理策略,探讨了相关的主要安全问题。它主要包括燃料管理论证的范围、铀-钆燃料芯块熔化温度的限值、相关的事故分析以及铀-钆燃料设计运行经验。最后指出了对我国压水堆核电厂燃料管理的经验反馈。
关键词 田湾核电厂 燃料管理 铀-钆燃料
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电感耦合等离子体光谱快速自动曲线校正技术测定铀钆氧化物中5种金属杂质 被引量:1
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作者 陈雪旭 陈岚 《化学分析计量》 CAS 2024年第8期62-68,共7页
建立电感耦合等离子体发射光谱快速自动曲线校正技术(FACT)测定铀钆氧化物中微量金属杂质元素的分析方法。通过对分析物谱线、干扰物谱线以及空白谱线的分析,选择元素最佳分析线,利用谱线校正扣减干扰物谱线,实现在高含量钆基体条件下... 建立电感耦合等离子体发射光谱快速自动曲线校正技术(FACT)测定铀钆氧化物中微量金属杂质元素的分析方法。通过对分析物谱线、干扰物谱线以及空白谱线的分析,选择元素最佳分析线,利用谱线校正扣减干扰物谱线,实现在高含量钆基体条件下对目标元素分析线进行干扰校正,准确测定元素含量。样品用硝酸溶解后,以磷酸三丁酯萃淋树脂作为固定相,3 mol/L硝酸溶液为流动相将铀分离。采用标准曲线法,利用FACT模型校正钆基体干扰,准确测量溶液中目标元素的含量。对FACT模型的有效性进行了考察和验证,确定目标元素的测量范围,元素加标回收率为84%~109%,测定结果的相对标准偏差为0.56%~7.07%(n=6)。该方法可用于含钆铀氧化物中微量金属杂质的检测。 展开更多
关键词 自动曲线校正技术 铀钆氧化物 金属杂质
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Core designing of a new type of TVS-2M FAs:neutronics and thermal-hydraulics design basis limits
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作者 Saeed GHAEMI Farshad FAGHIHI 《Frontiers in Energy》 SCIE CSCD 2021年第1期256-278,共23页
One of the most important aims of this study is to improve the core of the current VVER reactors to achieve more burn-up(or more cycle length)and more intrinsic safety.It is an independent study on the Russian new pro... One of the most important aims of this study is to improve the core of the current VVER reactors to achieve more burn-up(or more cycle length)and more intrinsic safety.It is an independent study on the Russian new proposed FAs,called TVS-2M,which would be applied for the future advanced VVERs.Some important aspects of neutronics as well as thermal hydraulics investigations(and analysis)of the new type of Fas are conducted,and results are compared with the standards PWR CDBL.The TVS-2M FA contains gadolinium-oxide which is mixed with UO_(2)(for different Gd densities and U-235 enrichments which are given herein),but the core does not contain BARs.The new type TVS-2M Fas are modeled by the SARCS software package to find the PMAXS format for three states of CZP and HZP as well as HFP,and then the whole core is simulated by the PARCS code to investigate transient conditions.In addition,the WIMS-D5 code is suggested for steady core modeling including TVS-2M FAs and/or TVS FAs.Many neutronics aspects such as the first cycle length(first cycle burn up in terms of MWthd/kgU),the critical concentration of boric acid at the BOC as well as the cycle length,the axial,and radial power peaking factors,differential and integral worthy of the most reactive CPS-CRs,reactivity coefficients of the fuel,moderator,boric acid,and the under-moderation estimation of the core are conducted and benchmarked with the PWR CDBL.Specifically,the burn-up calculations indicate that the 45.6 d increase of the first cycle length(which corresponds to 1.18 MWthd/kgU increase of burnup)is the best improving aim of the new FA type called TVS-2M.Moreover,thermal-hydraulics core design criteria such as MDNBR(based on W3 correlation)and the maximum of fuel and clad temperatures(radially and axially),are investigated,and discussed based on the CDBL. 展开更多
关键词 TVS-2M FAs core design basis limits VVER-1000 analysis mixture of uranium-gadolinium oxides fuels THERMAL-HYDRAULICS PARCS WIMS-D5
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