Due to the existence of oxide layer on the surface of Q235 steel,it is difficult to directly achieve metallurgical bonding with tin-lead al-loy,in order to solve this problem,this paper designed and successfully prepa...Due to the existence of oxide layer on the surface of Q235 steel,it is difficult to directly achieve metallurgical bonding with tin-lead al-loy,in order to solve this problem,this paper designed and successfully prepared steel surface activation liquid with the composition of 1 L distilled water,130 g ZnCl_(2),90 g NH_(4)Cl,5 mL 6501,and adding C_(3)H_(6)O_(3)to adjust pH 3.The results show that the activated mol-ten tin-lead alloy has a low wetting angle of 7.5°on the steel surface,which was then successfully plated on the steel surface by hot-dipping.The microstructural analysis of the plating-substrate interface and the thermodynamic calculation of the reaction can be found.The main structure of the interfacial reaction layer isα-Fe/FeSn_(2)/α-Pb+β-Sn.展开更多
基金supported by National Natural Science Foundation of China(Grant No.52305353)Postdoctoral Science Foundation of China(Grant No.2023M7408938).
文摘Due to the existence of oxide layer on the surface of Q235 steel,it is difficult to directly achieve metallurgical bonding with tin-lead al-loy,in order to solve this problem,this paper designed and successfully prepared steel surface activation liquid with the composition of 1 L distilled water,130 g ZnCl_(2),90 g NH_(4)Cl,5 mL 6501,and adding C_(3)H_(6)O_(3)to adjust pH 3.The results show that the activated mol-ten tin-lead alloy has a low wetting angle of 7.5°on the steel surface,which was then successfully plated on the steel surface by hot-dipping.The microstructural analysis of the plating-substrate interface and the thermodynamic calculation of the reaction can be found.The main structure of the interfacial reaction layer isα-Fe/FeSn_(2)/α-Pb+β-Sn.