One novel metal-organic framework [Cu2（L）（μ3-OH）]n（1, H3L = [1,1＇：3＇,1＇＇-terphenyl]-4,4＇＇,5＇-tricarboxylic acid） has been synthesized and characterized by single-crystal powder X-ray diffraction, IR and...One novel metal-organic framework [Cu2（L）（μ3-OH）]n（1, H3L = [1,1＇：3＇,1＇＇-terphenyl]-4,4＇＇,5＇-tricarboxylic acid） has been synthesized and characterized by single-crystal powder X-ray diffraction, IR and thermogravimetric analyses. Complex 1 crystallizes in orthorhombic crystal system, space group Pbca with a = 21.573（19）, b = 5.404（5）, c = 33.78（3） ？, C21H（12）O7Cu2, Mr = 503.39, V = 3938（6） A^3, Z = 8, Dc = 1.698 g·cm^-3, μ = 2.202 mm^-1, F（000） = 2016, 1.531〈θ〈25.009°, λ（Mo Kα） = 0.71073 A, T = 293（2） K, the final R = 0.0448 and wR = 0.1002. The structure of complex 1 is a three-dimensional（3D） framework based on infinite rod-shaped secondary building units and can be simplified as kgd topology. The gas adsorption measurements for N2, CO2, H2O, CH3OH and CH3CH2OH have been done. Fortunately, the selective sorption of CO2 over N2 was found at 195 K.展开更多
A series of main chain liquid crystal aromatic copolyesters with X-shaped and rod-shaped mesogenic units were synthesized via solution condensation polymerizations of 4,4'-(alpha,omega-octanedioyloxy)-dibenzoyl di...A series of main chain liquid crystal aromatic copolyesters with X-shaped and rod-shaped mesogenic units were synthesized via solution condensation polymerizations of 4,4'-(alpha,omega-octanedioyloxy)-dibenzoyl dichlorides with 2,5-bis(p-octanoxy benzoyloxy)-hydroquinone and diphenol. All of the copolyesters showed thermotropic liquid crystalline behaviors through observations using DSC, polarized microscopy and X-ray diffraction. The melting point (T-m) and the isotropization temperature (T-i) change regularly with varying the content of diphenol unit in the copolymers.展开更多
A series of liquid crystalline polymers with T-shaped two-dimensional mesogenic unitswere synthesized via low temperature solution polycondensation of 2-(4'-alkoxy-phenyl)hydroquinone with various diacyl dichlorid...A series of liquid crystalline polymers with T-shaped two-dimensional mesogenic unitswere synthesized via low temperature solution polycondensation of 2-(4'-alkoxy-phenyl)hydroquinone with various diacyl dichlorides. The polymers were found to be nematic andshown thermotropic liquid crystalline behaviors through observations using DSC, polarizedmicroscopy and X-ray diffraction. The melting temperature T_m and the isotropizationtemperature T_i of the polymers change regularly with varying of the monomer structures.展开更多
A new series of liquid crystal polyesters with T-shaped two-dimensional mesogenic units weresynthesized by melt polycondensation of the diacetates of 2-(4'-alkoxy -phenyl)-hydroquinones with 4,4'-alkylenedioxy...A new series of liquid crystal polyesters with T-shaped two-dimensional mesogenic units weresynthesized by melt polycondensation of the diacetates of 2-(4'-alkoxy -phenyl)-hydroquinones with 4,4'-alkylenedioxydibenzoic acid. The polymers were characterized by using polarized microscopy, DSC and X-ray diffraction. It was realized that all the polymers have nematic thermotropic liquid crystallinecharacteristics. The melting temperature (T_m) and isotropization temperature (T_i) of the polymers changeregularly with varying lengths of the alkoxy side group and the length of the alkylene group in the main chainin company with an even-odd effect. The mesophase temperature range also varies regularly with the polymerstructure. It is shown that the mesophase range has been widened.展开更多
A novel series of main chain liquid crystalline copolyesters with X-shaped two-dimensional mesogenic unit and crown ether cycle of cis-4,4＇-bis（4-hydroxyphenylazo） dibenzo-18-crown-6 was prepared via solution conde...A novel series of main chain liquid crystalline copolyesters with X-shaped two-dimensional mesogenic unit and crown ether cycle of cis-4,4＇-bis（4-hydroxyphenylazo） dibenzo-18-crown-6 was prepared via solution condensation polymerization from 4,4＇-（a;arhexanedioyloxy） dibenzoyl dichloride （MI）, 2,5-bis（p-octyloxybenzoyloxy） hydro-quinone （M2） and cis-4,4＇-bis（4-hydroxyphenylazo） dibenzo-18-crown-6 （M3）. Monomer MI was synthesized by esterification and substitution of adipoyl chloride with p-hydroxybenzoic acid, monomer M2 was synthesized by esterfication and reduction reaction of 2,5-dihydroxybenzoquinone and p-octanoxybenzoyl chloride and monomer M3 was synthesized by diazotization and coupling reaction of cis-diaminodibenzo-18-crown-6 with phenol. The molecular weights of copolyesters are not high, and the intrinsic viscosity [η] of copolyesters ranges from 0.25-0.35. The monomers＇ structures were identified by using elemental analysis, IR, UV, ^1H-NMR, MS, etc. All the copolyesters are yellowish powders and insoluble in THF and CHC13 at room temperature except cPg. The properties of copolyesters were investigated by using GPC, [η] , DSC, TG, WAXD and POM. It was found that all the copolyesters entered into liquid crystal phase when they were heated to above their melting temperature （Tin）. The typical smectic and nematic phase texture can be observed on POM. Their mesophase transition temperature and thermal stability change regularly with varying the content of cis-4,4＇-bis（4-hydroxyphenylazo） dibenzo-18-crown-6 unit in the copolyesters.展开更多
A novel series of liquid crystalline copolyesters with T-shaped two-dimensional mesogenic unit and crown ether cycle of cis-4,4′-bis(4-hydroxyphenylazo)dibenzo-18-crown-6 was prepared via solution condensation polyme...A novel series of liquid crystalline copolyesters with T-shaped two-dimensional mesogenic unit and crown ether cycle of cis-4,4′-bis(4-hydroxyphenylazo)dibenzo-18-crown-6 was prepared via solution condensation polymerization from 4,4′-(α,ω-hexanedioyloxy)dibenzoyl dichloride(M_1),2-(4′-ethoxyphenyl)hydroquinone(M_2)and cis-4,4′-bis(4- hydroxyphenylazo)dibenzo-18-crown-6(M_3).The molecular weights of copolyesters are not high,and the intrinsic viscosity [η]of copolyesters ranges from 0.29-0.43.The monomers ...展开更多
Two series of new liquid crystalline polymers with T-shaped two-dimensional mesogenic units were synthesized by low temperature solution polycondensations of 4-substituted N-2, 5-dihydroxybenzylidene aniline monomers ...Two series of new liquid crystalline polymers with T-shaped two-dimensional mesogenic units were synthesized by low temperature solution polycondensations of 4-substituted N-2, 5-dihydroxybenzylidene aniline monomers with different diacyl dichlorides. The polymers were found to be nematic and shown liquid crystalline behavior. The melting temperature T-m and the clearing temperature T-i of the polymers change regularly with varying of the monomer structures.展开更多
A portable shape-shifting mobile robot system named as Amoeba Ⅱ（A-Ⅱ） is developed for the urban search and rescue application. It is designed with three degrees of freedom and two tracked drive systems. This robot...A portable shape-shifting mobile robot system named as Amoeba Ⅱ（A-Ⅱ） is developed for the urban search and rescue application. It is designed with three degrees of freedom and two tracked drive systems. This robot consists of two modular mobile units and a joint unit. The mobile unit is a tracked mechanism to enforce the propulsion of robot. And the joint unit can transform the robot shape to get high environment adaptation. A-Ⅱ robot can not only adapt to the environment but also change its body shape according to the locus space. It behaves two work states including the linear state （named as I state） and the parallel state （named as Ⅱ state）. With the linear state the robot can climb upstairs and go through narrow space such as the pipe, cave, etc. The parallel state enables the robot with high mobility on rough ground. Also, the joint unit can propel the robot to roll in sidewise direction. Two modular A-Ⅱ robots can be connected through jointing common interfaces on the joint unit to compose a stronger shape-shifting robot, which can transform the body into four wheels-driven vehicle. The experimental results validate the adaptation and mobility of A-Ⅱ robot.展开更多
The computation model of shape and crown on 4-high CVC mill was established by combining the stream surface strip element method for analyzing three-dimensional plastic deformation of strip and the influence coefficie...The computation model of shape and crown on 4-high CVC mill was established by combining the stream surface strip element method for analyzing three-dimensional plastic deformation of strip and the influence coefficient method for elastic deformation of rolls, and the simulation of the shape and crown control on 4-high CVC hot strip mill was conducted. The simulated results indicate that the influence of the shifting of CVC work roll on shape and crown is very large, and the shifting of work roll can be used to preset shape and crown. The influence of the bending force of work roll on shape and crown is smaller, and it is suitable to use the bending force of work roll for shape and crown adjustment on line. With the increase of strip width, the exit crown of strip increases firstly and decreases then, and the roll gap becomes smoother increasingly. Meanwhile, the transverse difference of front tension stress decreases firstly and increases then.展开更多
Whirling is a cutting process in which a series of cutting edges on whirling ring remove material by turning over a rotating workpiece. In this study static and dynamic stability of whirling unit was estimated by usin...Whirling is a cutting process in which a series of cutting edges on whirling ring remove material by turning over a rotating workpiece. In this study static and dynamic stability of whirling unit was estimated by using ADAMS and NASTRAN softwares. Each maximum force acting on the bearing attached to the spindle assembly and the cutting tool attached to the whirling ring with the rotating speed of 6 000 r/min was 235 N and 902 N respectively. The maximum stress of 0.74 MPa on the base frame is far smaller than the yield strength of 282 MPa. The calculated natural frequency of 148 Hz of the system is far from the frequency of the driving speed of 6 000 r/min. The experimentally obtained maximum cutting force of 792 N is smaller than that of calculated value. And the experimentally obtained natural frequency of 118 Hz is beyond the driving speed of 6000 r/min. From above results it can be judged that the whirling system is statically and dynamically stable.展开更多
The anti-overturning ability and structure safety of jack-up unit in in-place condition are often affected by environment loads, especially wind load. According to the MODU rule, the projected area method is used for ...The anti-overturning ability and structure safety of jack-up unit in in-place condition are often affected by environment loads, especially wind load. According to the MODU rule, the projected area method is used for calculating the wind load. However, the calculated results are conservative and not good for structure optimization design. In this paper, a 400 ft jack-up is studied as an example. Based on the wind tunnel test and numerical simulation method, some key points of wind load calculation, such as shielding effect, lift effect and shape coefficient of component, are discussed. The study shows that the points mentioned above, which are ignored in the MODU rule calculation, result in the conservative result.展开更多
针对传统输电网和主动配电网(active distribution network,ADN)独立的调度方式致使“源-网-荷”各环节资源协同潜力挖掘不充分,难以实现输-配系统经济高效运行的问题,提出了市场环境下考虑配电网络重构和需求响应的输配优化调度方法。...针对传统输电网和主动配电网(active distribution network,ADN)独立的调度方式致使“源-网-荷”各环节资源协同潜力挖掘不充分,难以实现输-配系统经济高效运行的问题,提出了市场环境下考虑配电网络重构和需求响应的输配优化调度方法。首先,剖析电力市场机制下输-配电网间的耦合机理,构建考虑机组组合的输电网市场出清模型,以发挥“源侧”应对电力负荷波动的能力;以节点边际电价为引导信号,提出同时考虑ADN网络重构和需求侧响应的输配协同双层优化模型,旨在挖掘ADN在“网侧”和“荷侧”的双侧协同潜力,从而提高输-配电网中“源-网-荷”各环节资源间的协同能力。其次,针对输-配模型上、下层级的物理特点,采用随机规划L形算法,引入虚拟变量实现输配协同模型的解耦,基于对偶理论,获取反映资源利用情况的对偶乘子集合,进而计算次梯度参数并生成仿射割集,优化输-配耦合变量,加速模型收敛,实现对输-配协同模型的分布式高效求解。最后,以6节点输电网和7节点配电网构成的T6+D7系统和118节点输电网和8个20节点配电网构成的T118+8*D20系统为例,验证所提模型和方法的有效性,研究结果表明:输配系统的整体经济性提升了8.68%,所提模型和方法具有明显优势。展开更多
基金Supported by the Natural Science Foundation of Shandong Province(No.ZR2016BL01)the Talent Introduction Project of Dezhou University(No.320116)
文摘One novel metal-organic framework [Cu2（L）（μ3-OH）]n（1, H3L = [1,1＇：3＇,1＇＇-terphenyl]-4,4＇＇,5＇-tricarboxylic acid） has been synthesized and characterized by single-crystal powder X-ray diffraction, IR and thermogravimetric analyses. Complex 1 crystallizes in orthorhombic crystal system, space group Pbca with a = 21.573（19）, b = 5.404（5）, c = 33.78（3） ？, C21H（12）O7Cu2, Mr = 503.39, V = 3938（6） A^3, Z = 8, Dc = 1.698 g·cm^-3, μ = 2.202 mm^-1, F（000） = 2016, 1.531〈θ〈25.009°, λ（Mo Kα） = 0.71073 A, T = 293（2） K, the final R = 0.0448 and wR = 0.1002. The structure of complex 1 is a three-dimensional（3D） framework based on infinite rod-shaped secondary building units and can be simplified as kgd topology. The gas adsorption measurements for N2, CO2, H2O, CH3OH and CH3CH2OH have been done. Fortunately, the selective sorption of CO2 over N2 was found at 195 K.
基金The work was supported by the National Natural Science Foundation of China.
文摘A series of main chain liquid crystal aromatic copolyesters with X-shaped and rod-shaped mesogenic units were synthesized via solution condensation polymerizations of 4,4'-(alpha,omega-octanedioyloxy)-dibenzoyl dichlorides with 2,5-bis(p-octanoxy benzoyloxy)-hydroquinone and diphenol. All of the copolyesters showed thermotropic liquid crystalline behaviors through observations using DSC, polarized microscopy and X-ray diffraction. The melting point (T-m) and the isotropization temperature (T-i) change regularly with varying the content of diphenol unit in the copolymers.
基金This work was supported by the National Natural Science Foundation of China.
文摘A series of liquid crystalline polymers with T-shaped two-dimensional mesogenic unitswere synthesized via low temperature solution polycondensation of 2-(4'-alkoxy-phenyl)hydroquinone with various diacyl dichlorides. The polymers were found to be nematic andshown thermotropic liquid crystalline behaviors through observations using DSC, polarizedmicroscopy and X-ray diffraction. The melting temperature T_m and the isotropizationtemperature T_i of the polymers change regularly with varying of the monomer structures.
基金This work was supported by the National Natural Science Foundation of China.
文摘A new series of liquid crystal polyesters with T-shaped two-dimensional mesogenic units weresynthesized by melt polycondensation of the diacetates of 2-(4'-alkoxy -phenyl)-hydroquinones with 4,4'-alkylenedioxydibenzoic acid. The polymers were characterized by using polarized microscopy, DSC and X-ray diffraction. It was realized that all the polymers have nematic thermotropic liquid crystallinecharacteristics. The melting temperature (T_m) and isotropization temperature (T_i) of the polymers changeregularly with varying lengths of the alkoxy side group and the length of the alkylene group in the main chainin company with an even-odd effect. The mesophase temperature range also varies regularly with the polymerstructure. It is shown that the mesophase range has been widened.
基金This work was supported by the National Natural Science Foundation of China(No.29974026)the Natural Science Foundation of Henan Province.
文摘A novel series of main chain liquid crystalline copolyesters with X-shaped two-dimensional mesogenic unit and crown ether cycle of cis-4,4＇-bis（4-hydroxyphenylazo） dibenzo-18-crown-6 was prepared via solution condensation polymerization from 4,4＇-（a;arhexanedioyloxy） dibenzoyl dichloride （MI）, 2,5-bis（p-octyloxybenzoyloxy） hydro-quinone （M2） and cis-4,4＇-bis（4-hydroxyphenylazo） dibenzo-18-crown-6 （M3）. Monomer MI was synthesized by esterification and substitution of adipoyl chloride with p-hydroxybenzoic acid, monomer M2 was synthesized by esterfication and reduction reaction of 2,5-dihydroxybenzoquinone and p-octanoxybenzoyl chloride and monomer M3 was synthesized by diazotization and coupling reaction of cis-diaminodibenzo-18-crown-6 with phenol. The molecular weights of copolyesters are not high, and the intrinsic viscosity [η] of copolyesters ranges from 0.25-0.35. The monomers＇ structures were identified by using elemental analysis, IR, UV, ^1H-NMR, MS, etc. All the copolyesters are yellowish powders and insoluble in THF and CHC13 at room temperature except cPg. The properties of copolyesters were investigated by using GPC, [η] , DSC, TG, WAXD and POM. It was found that all the copolyesters entered into liquid crystal phase when they were heated to above their melting temperature （Tin）. The typical smectic and nematic phase texture can be observed on POM. Their mesophase transition temperature and thermal stability change regularly with varying the content of cis-4,4＇-bis（4-hydroxyphenylazo） dibenzo-18-crown-6 unit in the copolyesters.
基金This work was supported by the National Natural Science Foundation of China(No.29974026)the Natural Science Foundation of Henan Province(No.0211021100)the Education Department Foundation of Henan Province(No.20021500004).
文摘A novel series of liquid crystalline copolyesters with T-shaped two-dimensional mesogenic unit and crown ether cycle of cis-4,4′-bis(4-hydroxyphenylazo)dibenzo-18-crown-6 was prepared via solution condensation polymerization from 4,4′-(α,ω-hexanedioyloxy)dibenzoyl dichloride(M_1),2-(4′-ethoxyphenyl)hydroquinone(M_2)and cis-4,4′-bis(4- hydroxyphenylazo)dibenzo-18-crown-6(M_3).The molecular weights of copolyesters are not high,and the intrinsic viscosity [η]of copolyesters ranges from 0.29-0.43.The monomers ...
基金Tins work was supported by the National Natural Science Foundation of China.
文摘Two series of new liquid crystalline polymers with T-shaped two-dimensional mesogenic units were synthesized by low temperature solution polycondensations of 4-substituted N-2, 5-dihydroxybenzylidene aniline monomers with different diacyl dichlorides. The polymers were found to be nematic and shown liquid crystalline behavior. The melting temperature T-m and the clearing temperature T-i of the polymers change regularly with varying of the monomer structures.
基金National Natural Science Foundation of China(No. 60375029)National Hi-tech Research and Development Program of China(863 Program,No.2006AA04Z254)
文摘A portable shape-shifting mobile robot system named as Amoeba Ⅱ（A-Ⅱ） is developed for the urban search and rescue application. It is designed with three degrees of freedom and two tracked drive systems. This robot consists of two modular mobile units and a joint unit. The mobile unit is a tracked mechanism to enforce the propulsion of robot. And the joint unit can transform the robot shape to get high environment adaptation. A-Ⅱ robot can not only adapt to the environment but also change its body shape according to the locus space. It behaves two work states including the linear state （named as I state） and the parallel state （named as Ⅱ state）. With the linear state the robot can climb upstairs and go through narrow space such as the pipe, cave, etc. The parallel state enables the robot with high mobility on rough ground. Also, the joint unit can propel the robot to roll in sidewise direction. Two modular A-Ⅱ robots can be connected through jointing common interfaces on the joint unit to compose a stronger shape-shifting robot, which can transform the body into four wheels-driven vehicle. The experimental results validate the adaptation and mobility of A-Ⅱ robot.
文摘The computation model of shape and crown on 4-high CVC mill was established by combining the stream surface strip element method for analyzing three-dimensional plastic deformation of strip and the influence coefficient method for elastic deformation of rolls, and the simulation of the shape and crown control on 4-high CVC hot strip mill was conducted. The simulated results indicate that the influence of the shifting of CVC work roll on shape and crown is very large, and the shifting of work roll can be used to preset shape and crown. The influence of the bending force of work roll on shape and crown is smaller, and it is suitable to use the bending force of work roll for shape and crown adjustment on line. With the increase of strip width, the exit crown of strip increases firstly and decreases then, and the roll gap becomes smoother increasingly. Meanwhile, the transverse difference of front tension stress decreases firstly and increases then.
文摘Whirling is a cutting process in which a series of cutting edges on whirling ring remove material by turning over a rotating workpiece. In this study static and dynamic stability of whirling unit was estimated by using ADAMS and NASTRAN softwares. Each maximum force acting on the bearing attached to the spindle assembly and the cutting tool attached to the whirling ring with the rotating speed of 6 000 r/min was 235 N and 902 N respectively. The maximum stress of 0.74 MPa on the base frame is far smaller than the yield strength of 282 MPa. The calculated natural frequency of 148 Hz of the system is far from the frequency of the driving speed of 6 000 r/min. The experimentally obtained maximum cutting force of 792 N is smaller than that of calculated value. And the experimentally obtained natural frequency of 118 Hz is beyond the driving speed of 6000 r/min. From above results it can be judged that the whirling system is statically and dynamically stable.
基金supported by the National Natural Science Foundation of China(Grant No.51079034)the Fundamental Research Funds for the Central Universities(Grant No.HEUCFR1003)
文摘The anti-overturning ability and structure safety of jack-up unit in in-place condition are often affected by environment loads, especially wind load. According to the MODU rule, the projected area method is used for calculating the wind load. However, the calculated results are conservative and not good for structure optimization design. In this paper, a 400 ft jack-up is studied as an example. Based on the wind tunnel test and numerical simulation method, some key points of wind load calculation, such as shielding effect, lift effect and shape coefficient of component, are discussed. The study shows that the points mentioned above, which are ignored in the MODU rule calculation, result in the conservative result.
文摘针对传统输电网和主动配电网(active distribution network,ADN)独立的调度方式致使“源-网-荷”各环节资源协同潜力挖掘不充分,难以实现输-配系统经济高效运行的问题,提出了市场环境下考虑配电网络重构和需求响应的输配优化调度方法。首先,剖析电力市场机制下输-配电网间的耦合机理,构建考虑机组组合的输电网市场出清模型,以发挥“源侧”应对电力负荷波动的能力;以节点边际电价为引导信号,提出同时考虑ADN网络重构和需求侧响应的输配协同双层优化模型,旨在挖掘ADN在“网侧”和“荷侧”的双侧协同潜力,从而提高输-配电网中“源-网-荷”各环节资源间的协同能力。其次,针对输-配模型上、下层级的物理特点,采用随机规划L形算法,引入虚拟变量实现输配协同模型的解耦,基于对偶理论,获取反映资源利用情况的对偶乘子集合,进而计算次梯度参数并生成仿射割集,优化输-配耦合变量,加速模型收敛,实现对输-配协同模型的分布式高效求解。最后,以6节点输电网和7节点配电网构成的T6+D7系统和118节点输电网和8个20节点配电网构成的T118+8*D20系统为例,验证所提模型和方法的有效性,研究结果表明:输配系统的整体经济性提升了8.68%,所提模型和方法具有明显优势。
