A new triterpenoid saponin, namely unifloroside, together with five known compounds, was isolated from Rhaponticum uniflorum (L.) DC. The structure of the new triterpenoid saponin was elucidated as 3_O_ α_L_arabin...A new triterpenoid saponin, namely unifloroside, together with five known compounds, was isolated from Rhaponticum uniflorum (L.) DC. The structure of the new triterpenoid saponin was elucidated as 3_O_ α_L_arabinopyranosyl_urs_9(11),12_dien_28_oic acid β_D_glucopyranosyl ester mainly by using 1D, 2D_NMR techniques and chemical methods.展开更多
From the roots of Rhaponticum uniflorum a new triterpene was isolated together with ursolic acid(2), 3-oxo-19a-hydroxyurs-12-en-28-oic acid (3), pomolic acid (4), 2a,3a,19a-trihydroxyurs-12-en-28-oic acid (5), arctic ...From the roots of Rhaponticum uniflorum a new triterpene was isolated together with ursolic acid(2), 3-oxo-19a-hydroxyurs-12-en-28-oic acid (3), pomolic acid (4), 2a,3a,19a-trihydroxyurs-12-en-28-oic acid (5), arctic acid (6), catechin (7) and b-sitosterol (8). The structure of the new compound was elucidated as 2a,3a,19a,25-tetrahydroxyurs-12-en-23,28-dioic acid (1) on the basis of spectral and chemical methods.展开更多
An anlytical method for the separation and quantitative determination of three phytoecdysteroids in Rhaponticum uniflorum by high performance liquid chromatography has been developed.Three phytoecdysteroids,ecdysteron...An anlytical method for the separation and quantitative determination of three phytoecdysteroids in Rhaponticum uniflorum by high performance liquid chromatography has been developed.Three phytoecdysteroids,ecdysterone (Ⅰ),rha- pontisterone(Ⅱ) and turkesterone(Ⅲ) were separated and determined quantitatively by using the solvent system MeOH-H_2O(40∶60) at 242 nm with flow rate of 1.5ml/min,the operation can be completed in 10 minutes.Using the external standard method,the content of three phytoecdysteroids in the roots and aerial parts of Rhaponticum uniflorum obtained from dif- ferent localities was determined.It is proved that this method is sensitive and accurate,and with good reproducibility.展开更多
Two new triterpenoid saponins were isolated from the roots ofRhaponticum uniflorum. Their structures were elucidated as 3-O- [β-D-glucopyranosyl]-ilexolic acid-28-O-[β-D-glucopyranosyl] ester 1 and 3-O-[β-D-glucopy...Two new triterpenoid saponins were isolated from the roots ofRhaponticum uniflorum. Their structures were elucidated as 3-O- [β-D-glucopyranosyl]-ilexolic acid-28-O-[β-D-glucopyranosyl] ester 1 and 3-O-[β-D-glucopyranosyl]-urs-12, 19 （29）-dien-oic acid-28-O-[β-b-glucopyranosyl] ester 2 mainly by 1D, 2D NMR techniques and chemical methods.展开更多
文摘A new triterpenoid saponin, namely unifloroside, together with five known compounds, was isolated from Rhaponticum uniflorum (L.) DC. The structure of the new triterpenoid saponin was elucidated as 3_O_ α_L_arabinopyranosyl_urs_9(11),12_dien_28_oic acid β_D_glucopyranosyl ester mainly by using 1D, 2D_NMR techniques and chemical methods.
文摘From the roots of Rhaponticum uniflorum a new triterpene was isolated together with ursolic acid(2), 3-oxo-19a-hydroxyurs-12-en-28-oic acid (3), pomolic acid (4), 2a,3a,19a-trihydroxyurs-12-en-28-oic acid (5), arctic acid (6), catechin (7) and b-sitosterol (8). The structure of the new compound was elucidated as 2a,3a,19a,25-tetrahydroxyurs-12-en-23,28-dioic acid (1) on the basis of spectral and chemical methods.
文摘An anlytical method for the separation and quantitative determination of three phytoecdysteroids in Rhaponticum uniflorum by high performance liquid chromatography has been developed.Three phytoecdysteroids,ecdysterone (Ⅰ),rha- pontisterone(Ⅱ) and turkesterone(Ⅲ) were separated and determined quantitatively by using the solvent system MeOH-H_2O(40∶60) at 242 nm with flow rate of 1.5ml/min,the operation can be completed in 10 minutes.Using the external standard method,the content of three phytoecdysteroids in the roots and aerial parts of Rhaponticum uniflorum obtained from dif- ferent localities was determined.It is proved that this method is sensitive and accurate,and with good reproducibility.
基金supported by the Education Bureau of Fujian Province(No.JS06025)National Natural Sciences Foundation of China(No.29772010)
文摘Two new triterpenoid saponins were isolated from the roots ofRhaponticum uniflorum. Their structures were elucidated as 3-O- [β-D-glucopyranosyl]-ilexolic acid-28-O-[β-D-glucopyranosyl] ester 1 and 3-O-[β-D-glucopyranosyl]-urs-12, 19 （29）-dien-oic acid-28-O-[β-b-glucopyranosyl] ester 2 mainly by 1D, 2D NMR techniques and chemical methods.
文摘A new phytoecdysteroid was isolated from the root of Rhaponticum uniflorum. Its structure has been shown to be 2, 3, 20, 22-diacetonide ajugasterone.
