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THE CONSTRUCTION OF TRANSACTION RULES FOR ENERGY PROPERTY RIGHTS TRANSFER IN THE CONTEXT OF CHINA'S UNIFIED NATIONAL MARKET
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作者 Wu Cuidan 《China Legal Science》 2026年第1期109-133,共25页
I.INTRODUCTION Against the backdrop of profound transformations in the global energy landscape,China,as the world's largest energy producer and consumer,faces multiple challenges,including energy security,energy t... I.INTRODUCTION Against the backdrop of profound transformations in the global energy landscape,China,as the world's largest energy producer and consumer,faces multiple challenges,including energy security,energy transition,and sustainable development.To address these challenges,the Chinese government has formulated a strategic plan to build a unified national energy market and create a new framework for the energy sector.Article 42 of the Energy Law of the People's Republic of China(hereinafter referred to as the Energy Law)explicitly requires the building of a unified national energy trading market and the improvement of transaction mechanisms and rules. 展开更多
关键词 energy landscape energy market energy property rights build unified national energy market unified national market energy transition energy security sustainable developmentto
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Can Life Be Designed?-An Exploration From the Perspective of the Unified Complex Systems Theory
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作者 CUI Weicheng 《Philosophy Study》 2026年第1期58-73,共16页
Human life is not determined by mechanical fatalism or a single material factor;instead,based on the dualistic ontology and active force mechanism in the Unified Complex Systems Theory(UCST),it can be actively designe... Human life is not determined by mechanical fatalism or a single material factor;instead,based on the dualistic ontology and active force mechanism in the Unified Complex Systems Theory(UCST),it can be actively designed under the guidance of mind,in accordance with causal laws,and through systematic interactions.This study integrates the dualistic ontology of UCST,as well as the cooperative mechanism of active force(Fa)and passive force(Fp).Furthermore,by incorporating Master Jiqun’s philosophy of“life design”and the practical principle of“destiny establishment and transformation”from The Four Lessons of Liaofan Yuan,it constructs a three-dimensional framework for life design encompassing the dimensions of science,philosophy,and practice.The significance of this research lies in breaking through the predicament of materialism in the AI(artificial intelligence)era,explaining the autonomy and initiative of life,providing feasible pathways for life design,and ultimately achieving the in-depth integration of scientific rationality and the wisdom of traditional Eastern culture. 展开更多
关键词 life design Unified Complex Systems Theory(UCST) dualistic ontology active force destiny-establishing practice
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基于WinCC Unified的易维护系统在薄膜吹塑机组的应用
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作者 庄志嘉 林洁波 黄瑞雯 《橡塑技术与装备》 2026年第2期33-37,共5页
针对薄膜吹塑机组维护中故障响应滞后、依赖经验、成本高昂及信息孤岛等问题,本文设计了基于WinCC Unified的易维护系统。系统细分机组18个部件的清洁、维护、润滑三类共172项维护项目,以西门子S7-1500 PLC为控制核心,通过TIA Portal开... 针对薄膜吹塑机组维护中故障响应滞后、依赖经验、成本高昂及信息孤岛等问题,本文设计了基于WinCC Unified的易维护系统。系统细分机组18个部件的清洁、维护、润滑三类共172项维护项目,以西门子S7-1500 PLC为控制核心,通过TIA Portal开发计时、报警、人员管理等模块,结合WinCC Unified实现可视化组态与报表生成。应用表明,该系统实现了维护从“被动维修”到“主动维护”的转变,缩短了维护时间,降低了运维成本,提升了机组运行可靠性,为智能制造背景下橡塑机械的高效运维提供了有效方案。 展开更多
关键词 薄膜吹塑机组 WinCC Unified 易维护系统 预测性维护
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Rethinking anti-cancer drug discovery:the evolution from polypharmacy to unified drug units
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作者 Jun He Xinbing Sui 《Cancer Biology & Medicine》 2026年第1期15-20,共6页
Despite advances in current anti-cancer therapies,challenges such as drug resistance,toxicity,and tumor heterogeneity persist.The limitations of traditional single-target drugs and simple combination therapies are bec... Despite advances in current anti-cancer therapies,challenges such as drug resistance,toxicity,and tumor heterogeneity persist.The limitations of traditional single-target drugs and simple combination therapies are becoming increasingly apparent1.To address these issues,a novel treatment strategy,the artificially intelligent synergistic engineered drug(AISED)paradigm,merits further exploration.This paradigm is based on the systematic engineered integration of multiple active ingredients into a unified single entity through artificial intelligence(AI).This strategy is aimed at developing new anti-cancer drug designs involving multiple ingredients,multiple molecular targets,and multiple biological effects,for multiple cancer types,thereby providing a novel theoretical paradigm for overcoming existing treatment bottlenecks. 展开更多
关键词 artificially intelligent synergistic engineered drug aised paradigmmerits treatment strategythe toxicity unified drug units combination therapies drug resistance anti cancer drug discovery POLYPHARMACY
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Hydraulic fracturing of reservoirs containing rough discrete fracture networks:FDEM-UPM approach
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作者 Wanrun Li Zhengzhao Liang Chengye Zhao 《Journal of Rock Mechanics and Geotechnical Engineering》 2026年第2期1368-1389,共22页
Fractures are typically characterized by roughness that significantlyaffects the mechanical and hydraulic characteristics of reservoirs.However,hydraulic fracturing mechanisms under the influenceof fracture morphology... Fractures are typically characterized by roughness that significantlyaffects the mechanical and hydraulic characteristics of reservoirs.However,hydraulic fracturing mechanisms under the influenceof fracture morphology remain largely unexplored.Leveraging the advantages of the finite-discrete element method(FDEM)for explicitly simulating fracture propagation and the strengths of the unifiedpipe model(UPM)for efficientlymodeling dual-permeability seepage,we propose a new hydromechanical(HM)coupling approach for modeling hydraulic fracturing.Validated against benchmark examples,the proposed FDEM-UPM model is further augmented by incorporating a Fourier-based methodology for reconstructing non-planar fractures,enabling quantitative analysis of hydraulic fracturing behavior within rough discrete fracture networks(DFNs).The FDEM-UPM model demonstrates computational advantages in accurately capturing transient hydraulic seepage phenomena,while the asynchronous time-stepping schemes between hydraulic and mechanical analyses substantially enhanced computational efficiencywithout compromising computational accuracy.Our results show that fracture morphology can affect both macroscopic fracture networks and microscopic interaction types between hydraulic fractures(HFs)and natural fractures(NFs).In an isotropic stress field,the initiation azimuth,propagation direction and microcracking mechanism are significantly influencedby fracture roughness.In an anisotropic stress field,HFs invariably propagate parallel to the direction of the maximum principal stress,reducing the overall complexity of the stimulated fracture networks.Additionally,stress concentration and perturbation attributed to fracture morphology tend to be compromised as the leak-off increases,while the breakdown and propagation pressures remain insensitive to fracture morphology.These findingsprovide new insights into the hydraulic fracturing mechanisms of fractured reservoirs containing complex rough DFNs. 展开更多
关键词 Hydraulic fracturing Unified pipe model(UPM) Finite-discrete element method(FDEM) Hydro-mechanical coupling Discrete fracture network(DFN)
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Fuzzy k-Means Clustering-Based Machine Learning Models for LFO Damping in Electric Power System Networks
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作者 Md Shafiullah 《Computer Modeling in Engineering & Sciences》 2026年第2期803-830,共28页
Various factors,including weak tie-lines into the electric power system(EPS)networks,can lead to low-frequency oscillations(LFOs),which are considered an instant,non-threatening situation,but slow-acting and poisonous... Various factors,including weak tie-lines into the electric power system(EPS)networks,can lead to low-frequency oscillations(LFOs),which are considered an instant,non-threatening situation,but slow-acting and poisonous.Considering the challenge mentioned,this article proposes a clustering-based machine learning(ML)framework to enhance the stability of EPS networks by suppressing LFOs through real-time tuning of key power system stabilizer(PSS)parameters.To validate the proposed strategy,two distinct EPS networks are selected:the single-machine infinite-bus(SMIB)with a single-stage PSS and the unified power flow controller(UPFC)coordinated SMIB with a double-stage PSS.To generate data under various loading conditions for both networks,an efficient but offline meta-heuristic algorithm,namely the grey wolf optimizer(GWO),is used,with the loading conditions as inputs and the key PSS parameters as outputs.The generated loading conditions are then clustered using the fuzzy k-means(FKM)clustering method.Finally,the group method of data handling(GMDH)and long short-term memory(LSTM)ML models are developed for clustered data to predict PSS key parameters in real time for any loading condition.A few well-known statistical performance indices(SPI)are considered for validation and robustness of the training and testing procedure of the developed FKM-GMDH and FKM-LSTM models based on the prediction of PSS parameters.The performance of the ML models is also evaluated using three stability indices(i.e.,minimum damping ratio,eigenvalues,and time-domain simulations)after optimally tuned PSS with real-time estimated parameters under changing operating conditions.Besides,the outputs of the offline(GWO-based)metaheuristic model,proposed real-time(FKM-GMDH and FKM-LSTM)machine learning models,and previously reported literature models are compared.According to the results,the proposed methodology outperforms the others in enhancing the stability of the selected EPS networks by damping out the observed unwanted LFOs under various loading conditions. 展开更多
关键词 Fuzzy k-means clustering grey wolf optimizer group method of data handling long short-term memory low-frequency oscillation power system stabilizer single machine infinite bus STABILITY unified power flow controller
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Mission capability assessment of UAV swarms based on UAF and interval-valued spherical fuzzy ANP
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作者 Minghao ZHANG An +2 位作者 BI Wenhao FAN Qiucen YANG Pan 《Journal of Systems Engineering and Electronics》 2026年第1期225-241,共17页
For mission-oriented unmanned aerial vehicle(UAV)swarms,mission capability assessment provides an important reference in the design and development process,and is a precondition for mission success.For this multi-crit... For mission-oriented unmanned aerial vehicle(UAV)swarms,mission capability assessment provides an important reference in the design and development process,and is a precondition for mission success.For this multi-criteria decisionmaking(MCDM)problem,the current literature lacks a way to unambiguously present criteria and the popular fuzzy analytic network process(ANP)approaches neglect the hesitancy of subjective judgments.To fill these research gaps,an MCDM method based on unified architecture framework(UAF)and interval-valued spherical fuzzy ANP(IVSF-ANP)is proposed in this paper.Firstly,selected viewpoints in UAF are extended to construct criteria models with standardized representation.Secondly,interval-valued spherical fuzzy sets are introduced to ANP to weight interdependent criteria,handling fuzziness and hesitancy in pairwise comparisons.A method of adjusting weights of experts based on their decision similarities is also included in this process to reduce ambiguity brought by multiple experts.Next,performance characteristics are non-linearly transformed regarding to expectations to get final results.This proposition is applied to assess the mission capability of UAV swarms to search and strike surface vessels.Comparative analysis shows that the proposed method is valid and reasonable. 展开更多
关键词 unmanned aerial vehicle(UAV)swarm capability assessment multi-criteria decision-making(MCDM) unified architecture framework interval-valued spherical fuzzy set analytical network process(ANP)
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基于UPLC-Q-TOF MS技术结合UNIFI软件快速筛查中药中非法添加调节性功能化合物
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作者 廖敏 王影超 +2 位作者 陈琪 姜莲 王海宁 《质谱学报》 北大核心 2025年第3期370-379,共10页
本研究采用超高效液相色谱-四极杆飞行时间质谱(UPLC-Q-TOF MS)技术结合UNIFI软件,建立了一种快速、准确检测中药中非法添加调节性功能化合物的方法。根据中药剂型的不同选择相应的样品制备方法,使用ACQUITY UPLC HSS T3色谱柱(2.1 mm&#... 本研究采用超高效液相色谱-四极杆飞行时间质谱(UPLC-Q-TOF MS)技术结合UNIFI软件,建立了一种快速、准确检测中药中非法添加调节性功能化合物的方法。根据中药剂型的不同选择相应的样品制备方法,使用ACQUITY UPLC HSS T3色谱柱(2.1 mm×100 mm,1.8μm),以乙腈-0.1%甲酸溶液为流动相进行梯度洗脱;在电喷雾离子源正离子模式下,使用MS^(E)模式采集数据。通过UNIFI软件建立靶向筛查数据库,并参考欧盟SANTE/11312/2021指南设定筛查条件,实现检测结果的自动化筛查。结果表明,本方法能够在12 min内快速筛查31种目标化合物,检出限为0.25~15.00 mg/kg(或mg/L)。在对20批次补肾壮阳类中药样品的检测中发现,7批次样品存在非法添加,其中4批次样品检出标准检测方法以外的化合物。该方法具有快速、准确、覆盖范围广且可灵活扩展的优点,可为中药中非法添加物的监管提供技术支持。 展开更多
关键词 超高效液相色谱-四极杆飞行时间质谱(UPLC-Q-TOF MS) UNIFI软件 中药 非法添加 调节性功能化合物 快速筛查
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UPLC-Q-TOF/MS法分析金雀花总黄酮入血成分 被引量:2
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作者 布比阿加尔·哈依拉提 秦亚迪 +2 位作者 程煜凤 沈静 姚军 《中成药》 北大核心 2025年第1期126-132,共7页
目的建立UPLC-Q-TOF/MS法分析金雀花总黄酮入血成分,探究其药效物质基础。方法分析采用ACQUITY UPLC BEH C 18色谱柱(100 mm×2.1 mm,1.7μm);流动相水(含0.1%甲酸)-乙腈,梯度洗脱;体积流量0.3 mL/min;柱温35℃;进样量5μL;电喷雾... 目的建立UPLC-Q-TOF/MS法分析金雀花总黄酮入血成分,探究其药效物质基础。方法分析采用ACQUITY UPLC BEH C 18色谱柱(100 mm×2.1 mm,1.7μm);流动相水(含0.1%甲酸)-乙腈,梯度洗脱;体积流量0.3 mL/min;柱温35℃;进样量5μL;电喷雾离子源(ESI);正负离子扫描。结合UNIFI平台,对提取物、空白血清和含药血清图谱进行差异分析,解析提取物经大鼠灌胃后血清原型成分和代谢产物。结果含药血清中初步鉴定出78种成分,包括8种原型成分和70种代谢产物。结论本实验可为进一步研究金雀花总黄酮药效物质和作用机制奠定基础。 展开更多
关键词 金雀花 总黄酮 入血成分 UPLC-Q-TOF/MS UNIFI
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基于UPLC-Q-TOF-MS/MS结合UNIFI的珠子参皂苷类化学成分分析及多指标含量测定 被引量:1
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作者 张苡嘉 杨婧潇 +4 位作者 胡新悦 黄嘉诚 王炜 刘乐平 严建业 《天然产物研究与开发》 北大核心 2025年第5期904-917,共14页
对珠子参中皂苷类成分进行定性鉴别分析,建立珠子参皂苷类多成分含量测定方法。采用超高效液相色谱-飞行时间质谱(UPLC-Q-TOF-MS/MS)技术对珠子参进行正、负离子模式扫描,使用UNIFI天然产物信息平台对珠子参所含的化学成分进行定性鉴别... 对珠子参中皂苷类成分进行定性鉴别分析,建立珠子参皂苷类多成分含量测定方法。采用超高效液相色谱-飞行时间质谱(UPLC-Q-TOF-MS/MS)技术对珠子参进行正、负离子模式扫描,使用UNIFI天然产物信息平台对珠子参所含的化学成分进行定性鉴别分析;以0.1%磷酸水-乙腈溶液为流动相进行梯度洗脱,柱温30℃,流速0.3 mL/min,进行珠子参皂苷类多成分含量测定。珠子参中共鉴定出39个化学成分,包括37个皂苷类化合物和2个皂苷母核,并总结了皂苷类化合物的裂解规律,建立了UPLC同时测定珠子参中人参皂苷Rb1、人参皂苷Ro、人参皂苷Rb3、竹节参皂苷IV、竹节参皂苷IVa、人参皂苷Rd、姜状三七皂苷R1和金盏花苷E的多指标含量测定方法,该方法中8个待测成分在检测质量浓度范围内线性关系良好,精密度、重复性、稳定性的相对标准偏差(relative standard deviation,RSD)均小于3.0%,样品中人参皂苷Rb1、人参皂苷Ro、人参皂苷Rb3、竹节参皂苷IV、竹节参皂苷IVa、人参皂苷Rd、姜状三七皂苷R1和金盏花苷E的平均加样回收率分别为102.4%、103.1%、97.97%、99.42%、102.7%、102.1%、95.23%、100.5%,RSD分别为1.0%、0.98%、0.81%、2.3%、0.81%、1.9%、0.96%、1.8%。该研究建立的方法可快速、准确地对珠子参中的皂苷类成分进行定性及定量分析。 展开更多
关键词 珠子参 UPLC-Q-TOF-MS/MS UNIFI 成分分析 含量测定
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An Analysis about the Origin and Essence of Mass Based on Particle-Propagating Model and Wave Equations of Scalar Waves 被引量:1
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作者 Jiang Jian-zhong Chen Xi-qi 《Journal of Environmental Science and Engineering(B)》 2025年第2期65-75,共11页
If the singularity of the cosmic Big Bang is taken as the origin of the reference coordinate system,the surrounding vacuum in the initial moments of it would exhibit radially-outward right-handed spiral motion at ligh... If the singularity of the cosmic Big Bang is taken as the origin of the reference coordinate system,the surrounding vacuum in the initial moments of it would exhibit radially-outward right-handed spiral motion at light speed.Based on this spatial motion hypothesis,we derive a unified field equation and a set of Maxwell’s equations for vacuum SWs(Scalar Waves)generating a huge spiral force field that drives the energy to spiral inwardly and distort,leading to the formation of mass.Furthermore,they also uncover that mass is fundamentally an ultimate expression of energy,manifesting as the result of spiral motion of space at light speed.And then,we indirectly validate the theory that coherent light waves’collision generate SWs and subsequently mass through the experiment verifying the Breit-Wheeler process.The establishment of our theory offers a new analytical tool for the exploration of mass origin,the cosmic Big Bang,unified field theories. 展开更多
关键词 QED(Quantum Electrodynamics) SW mass origin unified field theories
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Design of a Private Cloud Platform for Distributed Logging Big Data Based on a Unified Learning Model of Physics and Data 被引量:1
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作者 Cheng Xi Fu Haicheng Tursyngazy Mahabbat 《Applied Geophysics》 2025年第2期499-510,560,共13页
Well logging technology has accumulated a large amount of historical data through four generations of technological development,which forms the basis of well logging big data and digital assets.However,the value of th... Well logging technology has accumulated a large amount of historical data through four generations of technological development,which forms the basis of well logging big data and digital assets.However,the value of these data has not been well stored,managed and mined.With the development of cloud computing technology,it provides a rare development opportunity for logging big data private cloud.The traditional petrophysical evaluation and interpretation model has encountered great challenges in the face of new evaluation objects.The solution research of logging big data distributed storage,processing and learning functions integrated in logging big data private cloud has not been carried out yet.To establish a distributed logging big-data private cloud platform centered on a unifi ed learning model,which achieves the distributed storage and processing of logging big data and facilitates the learning of novel knowledge patterns via the unifi ed logging learning model integrating physical simulation and data models in a large-scale functional space,thus resolving the geo-engineering evaluation problem of geothermal fi elds.Based on the research idea of“logging big data cloud platform-unifi ed logging learning model-large function space-knowledge learning&discovery-application”,the theoretical foundation of unified learning model,cloud platform architecture,data storage and learning algorithm,arithmetic power allocation and platform monitoring,platform stability,data security,etc.have been carried on analysis.The designed logging big data cloud platform realizes parallel distributed storage and processing of data and learning algorithms.The feasibility of constructing a well logging big data cloud platform based on a unifi ed learning model of physics and data is analyzed in terms of the structure,ecology,management and security of the cloud platform.The case study shows that the logging big data cloud platform has obvious technical advantages over traditional logging evaluation methods in terms of knowledge discovery method,data software and results sharing,accuracy,speed and complexity. 展开更多
关键词 Unified logging learning model logging big data private cloud machine learning
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超高效液相色谱-四极杆-飞行时间高分辨质谱技术结合UNIFI高通量筛查面膜类化妆品中141种非法添加成分
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作者 范晨丽 王海波 +1 位作者 蒋培 申二永 《分析科学学报》 北大核心 2025年第4期405-414,共10页
建立了一种基于超高效液相色谱-四极杆-飞行时间高分辨质谱技术,结合UNIFI软件的高通量筛查方法,用于检测面膜类化妆品中141种非法添加成分。样品经饱和氯化钠溶液溶解后,加入含0.5%甲酸的乙腈进行超声提取,采用Oasis HLB固相萃取小柱... 建立了一种基于超高效液相色谱-四极杆-飞行时间高分辨质谱技术,结合UNIFI软件的高通量筛查方法,用于检测面膜类化妆品中141种非法添加成分。样品经饱和氯化钠溶液溶解后,加入含0.5%甲酸的乙腈进行超声提取,采用Oasis HLB固相萃取小柱净化。使用BEH C18(100 mm×2.1 mm,1.7μm)色谱柱分离,并在电喷雾离子源(ESI)正负扫描模式下,采用MS^(E)模式采集化合物的质谱信息。通过化合物的母离子和二级碎片离子的精准质量数以及保留时间等参数,利用UNIFI软件构建筛查数据库。最终通过基质标曲外标法进行定量分析。141种非法添加成分响应值与浓度呈良好线性关系(R^(2)>0.99),检出限为0.15~1.35 mg/kg;定量限为0.45~4.05 mg/kg。空白基质样品(面贴式乳液剂和涂抹式膏霜剂)中加入3个水平点的平均回收率为63.0%~124.5%;日内、日间相对标准偏差(RSD)分别为1.2%~9.1%(n=6)和1.3%~13.9%(n=3)。采用该方法测定市售86批面膜类产品,检出1批氯倍他索丙酸脂和3批酮康唑,检出含量范围为0.3~561.3 mg/kg。该方法操作简便、高效准确,具有良好的专属性,可实现面膜类化妆品中141种非法添加成分的高通量筛查,为化妆品质量监管提供了可靠的技术支持。 展开更多
关键词 UPLC-Q-TOF-MS^(E) 面膜类化妆品 非法添加成分 UNIFI 高通量筛查
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CHINA SCENE
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《China Standardization》 2025年第5期8-11,共4页
Downloads of national standards exceed 10 million times in the first half of 2025 In response to social needs,State Administration for Market Regulation(SAMR)had steadily promoted the full-text disclosure and free dow... Downloads of national standards exceed 10 million times in the first half of 2025 In response to social needs,State Administration for Market Regulation(SAMR)had steadily promoted the full-text disclosure and free download of over 30,000 national standards that do not adopt international standards since the beginning of this year.In the first half of 2025,downloads exceeded 10 million times,providing strong support for the construction of a unified national market.Social groups accessing national standards for free increased significantly.In the first half of this year,the average monthly downloads of national standards surged tenfold from 190,000 times last year to 2.03 million times.Online reading reached nearly 15 million times,and page views hit 89 million times.The disclosure of national standards for free has effectively broken information barriers in standards,ensuring equal rights for business entities to read and download national standards. 展开更多
关键词 national standards construction unified national downloads market regulation information barriers unified national market
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Towards Efficient Vehicle Recognition:A Unified System for VMMR,ANPR,and Color Classification
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作者 Saad Sadiq Kashif Sultan +2 位作者 Muhammad Sheraz Teong Chee Chuah Muhammad Usman Hashmi 《Computers, Materials & Continua》 2025年第11期3945-3963,共19页
Vehicle recognition plays a vital role in intelligent transportation systems,law enforcement,access control,and security operations—domains that are becoming increasingly dynamic and complex.Despite advancements,most... Vehicle recognition plays a vital role in intelligent transportation systems,law enforcement,access control,and security operations—domains that are becoming increasingly dynamic and complex.Despite advancements,most existing solutions remain siloed,addressing individual tasks such as vehicle make and model recognition(VMMR),automatic number plate recognition(ANPR),and color classification separately.This fragmented approach limits real-world efficiency,leading to slower processing,reduced accuracy,and increased operational costs,particularly in traffic monitoring and surveillance scenarios.To address these limitations,we present a unified framework that consolidates all three recognition tasks into a single,lightweight system.The framework utilizes MobileNetV2 for efficient VMMR,YOLO(You Only Look Once)for accurate license plate detection,and histogram-based clustering in the HSV color space for precise color identification.Rather than optimizing each module in isolation,our approach emphasizes tight integration,enabling improved performance and reliability.The system also features adaptive image calibration and robust algorithmic enhancements to ensure consistent results under varying environmental conditions.Experimental evaluations demonstrate that the proposedmodel achieves a combined accuracy of 93.3%,outperforming traditional methods and offering practical scalability for deployment in real-world transportation infrastructures. 展开更多
关键词 VMMR ANPR unified framework deep learning
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Battery Swapping Emerges as Major Alternative to Charging Electric Vehicles
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作者 Chris Palmer 《Engineering》 2025年第9期6-9,共4页
In March 2025,prominent Chinese automaker NIO(Shanghai,China),the global leader in electric vehicle(EV)battery swapping,and Contemporary Amperex Technology Co.,Ltd.(CATL)(Nindge,China),the world’s biggest manufacture... In March 2025,prominent Chinese automaker NIO(Shanghai,China),the global leader in electric vehicle(EV)battery swapping,and Contemporary Amperex Technology Co.,Ltd.(CATL)(Nindge,China),the world’s biggest manufacturer of EV batteries,announced a strategic partnership to build the world’s largest battery swapping network,while also promoting unified standards and technologies[1].Just weeks later,CATL announced another partnership,this one with Chinese state-owned oil giant Sinopec(Beijing,China)to build 10000 new battery swapping stations in China,at least 500 in 2025[2]. 展开更多
关键词 electric vehicles TECHNOLOGIES standards battery swapping CATL promoting unified standards technologies just NIO SINOPEC
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Unified construction of prenylated and reverse-prenylated oxindoles from isoprene launched by Ni catalysis
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作者 Ying-Ying Liu Ying Li +4 位作者 Xue-Ting Li Su-Yang Xu Ding-Wei Ji Xiang-Ping Hu Qing-An Chen 《Chinese Journal of Catalysis》 2025年第3期444-454,共11页
As important natural and pharmaceutical motifs,the catalytic construction of structurally diverse 3,3-disubstituted oxindoles often requires elaborate synthetic efforts on optimizations.Herein,we developed a simple an... As important natural and pharmaceutical motifs,the catalytic construction of structurally diverse 3,3-disubstituted oxindoles often requires elaborate synthetic efforts on optimizations.Herein,we developed a simple and divergent approach for constructing reverse-prenylated and prenylated oxindoles launched by Ni catalysis with bulk chemical isoprene.Using C3-unsubstituted oxindoles as starting materials,mono reverse-prenylation was demonstrated in high chemo-and regioselectivities facilitated by the combination of Ni(0)and monodentate phosphine ligand.Using the obtained reverse-prenylated oxindoles as versatile synthon,substitutions at the pseudobenzylic position with various electrophiles created vicinal quaternary centers in a concise way.With the help of additives(PPh3 and NaH),air could be directly used as green oxidant to construct prenylated and reverse-prenylatedα-hydroxy-oxindoles divergently from the same substrates.In situ esterification of prenylatedα-hydroxy-oxindoles allowed subsequent Friedel-Crafts substitutions with diverse nucleophiles to deliver prenyl substituted dimeric or spiro-oxindoles.This protocol provides a divergent synthetic approach for the construction of highly functionalized 3,3-disubstituted oxindoles,which have been otherwise difficult to access in a unified approach. 展开更多
关键词 Nickel catalysis Unified construction ISOPRENE (Reverse-)prenylation OXINDOLE
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Ground reaction curves for strain-softening rock masses with ground reinforcement based on unified strength criterion
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作者 CHEN Xuan-hao ZHANG Ding-li +1 位作者 SUN Zhen-yu CHEN Wen-bo 《Journal of Central South University》 2025年第9期3383-3404,共22页
Ground reinforcement is crucial for tunnel construction, especially in soft rock tunnels. Existing analytical models are inadequate for predicting the ground reaction curves (GRCs) for reinforced tunnels in strain-sof... Ground reinforcement is crucial for tunnel construction, especially in soft rock tunnels. Existing analytical models are inadequate for predicting the ground reaction curves (GRCs) for reinforced tunnels in strain-softening (SS) rock masses. This study proposes a novel analytical model to determine the GRCs of SS rock masses, incorporating ground reinforcement and intermediate principal stress (IPS). The SS constitutive model captures the progressive post- peak failure, while the elastic-brittle model simulates reinforced rock masses. Nine combined states are innovatively investigated to analyze plastic zone development in natural and reinforced regions. Each region is analyzed separately, and coupled through boundary conditions at interface. Comparison with three types of existing models indicates that these models overestimate reinforcement effects. The deformation prediction errors of single geological material models may exceed 75%. Furthermore, neglecting softening and residual zones in natural regions could lead to errors over 50%. Considering the IPS can effectively utilize the rock strength to reduce tunnel deformation by at least 30%, thereby saving on reinforcement and support costs. The computational results show a satisfactory agreement with the monitoring data from a model test and two tunnel projects. The proposed model may offer valuable insights into the design and construction of reinforced tunnel engineering. 展开更多
关键词 ground reinforcement STRAIN-SOFTENING unified strength criterion tunnel responses analytical model
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Stress gradient analytic solution and reasonable support prestress of roadway surrounding rock based on unified strength criterion:A case study
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作者 JING Suo-lin WEN Zhi-jie +2 位作者 ZUO Yu-jun LI Qiu-ju HAO Peng 《Journal of Central South University》 2025年第2期449-468,共20页
The stress gradient of surrounding rock and reasonable prestress of support are the keys to ensuring the stability of roadways.The elastic-plastic analytical solution for surrounding rock was derived based on unified ... The stress gradient of surrounding rock and reasonable prestress of support are the keys to ensuring the stability of roadways.The elastic-plastic analytical solution for surrounding rock was derived based on unified strength theory.A model for solving the stress gradient of the surrounding rock with the intermediate principal stress parameter b was established.The correctness and applicability of the solution for the stress gradient in the roadway surrounding rock was verified via multiple methods.Furthermore,the laws of stress,displacement,and the plastic zone of the surrounding rock with different b values and prestresses were revealed.As b increases,the stress gradient in the plastic zone increases,and the displacement and plastic zone radius decrease.As the prestress increases,the peak stress shifts toward the sidewalls,and the stress and stress gradient increments decrease.In addition,the displacement increment and plastic zone increment were proposed to characterize the support effect.The balance point of the plastic zone area appears before that of the displacement zone.The relationship between the stress gradient compensation coefficient and the prestress is obtained.This study provides a research method and idea for determining the reasonable prestress of support in roadways. 展开更多
关键词 PRESTRESS support compensation surrounding rock damage stress gradient analytic solution unified strength theory
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Degradation of natural red mudstone subjected to long-term relative humidity cycles
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作者 Kang Chen Rui Zhang +2 位作者 Shengyang Yuan Jie Ma Huan Wang 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第9期5800-5815,共16页
This paper presents a multi-scale experimental investigation of the weathering degradation of red mudstone.Natural rocks were extracted from the surface ground to 120 m,inwhich three sets of samples were selected to c... This paper presents a multi-scale experimental investigation of the weathering degradation of red mudstone.Natural rocks were extracted from the surface ground to 120 m,inwhich three sets of samples were selected to consider the different initial rock fabrics.The long-term relative humidity(RH)cycles under two amplitudes were imposed on red mudstone to simulate the weathering process.After RH cycles,a series of uniaxial compression tests,Brazilian splitting tests and bender-extender element tests were carried out to examine the reduction in strength and stiffness.The objective of this study is to develop an extended stress-volume framework characterizing the degradation of natural red mudstone both at microscale and macroscale.Accompanied by the irreversible swelling of the rock specimen is the progressive degradation of strength,stiffness and Poisson's ratio.A unified exponential degradation model in terms of the irreversible volumetric strain was thus proposed to capture such a degradation pattern.The effect of the initial rock fabric was evident.The highest degradation rate and potential were identified in slightly weathered specimens.Significant slaking of aggregates and crack propagation were confirmed by scanning electron microscope(SEM)micrographs,which were considered as the main consequence of structure damage leading to degradation of mechanical properties.The structure damage during RH cycles denoted the hysteresis nature in the response to the cycling hydraulic reaction,in turn causing the increase in volumetric strain.Thus,the stress-volume relation rather than the suction relation was found in more reasonable agreement with the experimental results. 展开更多
关键词 Red mudstone Weathering degradation Relative humidity cycles Unified degradation model Microstructure tests
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