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The inhibition difference and mechanism research of N_(2)-water mist two-phase medium on CH_(4),LPG and H_(2) explosion flame acceleration characteristic
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作者 Hang Lyu Bei Pei +5 位作者 Lei zhou Zhiqi Wu Chong Jia Tianxiang Xu Wentao Ji Shiliang Li 《Chinese Journal of Chemical Engineering》 2025年第11期391-404,共14页
To address the critical need for safer and cleaner explosion suppression technologies in industrial settings,the suppression differences and mechanisms of the flame acceleration characteristics of CH_(4),LPG and H_(2)... To address the critical need for safer and cleaner explosion suppression technologies in industrial settings,the suppression differences and mechanisms of the flame acceleration characteristics of CH_(4),LPG and H_(2) explosions by N_(2)-water mist two-phase medium were investigated.The flame acceleration characteristics and suppression mechanism of methane,LPG and H_(2) explosions in N_(2)-water mist twophase medium were studied qualitatively and quantitatively from both experimental and simulation aspects.The experimental results show that compared with single N_(2) or water mist,the N_(2)-water mist two-phase medium is more effective in reducing the flame propagation speed and delaying the formation of flame hydrodynamic structure,thus slowing down the flame acceleration characteristics.The simulation results show that this two-phase medium exhibits a strong inhibitory effect on the thermal diffusion instability of CH_(4) and LPG,and significantly weakens the hydrodynamic instability of CH_(4),LPG,and H_(2) simultaneously.Mechanistic analysis confirms that the N_(2)-water mist two-phase medium has both chemical and physical inhibitory effects,among which the physical inhibition plays a dominant role.In addition,the study reveals a linear correlation between the concentration of H radicals in the three combustible gases and the laminar burning velocity.Moreover,this two-phase medium can significantly reduce the reaction rate of the H radical chain reaction,thereby effectively suppressing the laminar burning velocity. 展开更多
关键词 Gas-liquid two phase Cellular instability Inhibition mechanism Synergistic effect
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Direct Numerical Simulation of Secondary Breakup of Liquid Drops 被引量:9
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作者 刘静 徐旭 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2010年第2期153-161,共9页
This article studies numerically a familiar important phenomenon in spray combustion which is deformation and breakup of liquid drops in gas flow. The SIMPLER method is used to solve the two-dimensional (2D) unstead... This article studies numerically a familiar important phenomenon in spray combustion which is deformation and breakup of liquid drops in gas flow. The SIMPLER method is used to solve the two-dimensional (2D) unsteady axisymmetric Navier-Stokes equations for both the drop and the ambient gas flow. The level set method is applied to capturing the liquid/gas interface. Through calculation are obtained four typical breakup modes--oscillation, bag breakup, sheet stripping breakup and shear breakup governed by four non-dimensional numbers which are gas Weber number (Weg), liquid Reynolds number (Rel), gas Reynolds number (Reg) and density ratio (γ). Their effects upon each mode are analyzed. The results indicate that among the four numbers, Weg is of the highest importance with Rel, Reg and γfollowing up. By widening the range of the density ratio up to 1 000, the breakup mode is discovered to be so complicated that a new one called multimode breakup mode turns up. This mode contains the shearing breakup and piercing breakup, which successively happen. The calculation results agree well with what is observed from the experiments. 展开更多
关键词 two phase flow drop breakup level set method SIMPLER method numerical simulation
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Review of gas-solid two phase flow rate-concentration detection technology 被引量:1
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作者 刘秀 刘吉 +2 位作者 张静 颜兵 史璐璐 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2016年第2期185-192,共8页
The indirect detection method basic principle of rate and concentration,application range and research results on gassolid two phase flow were discussed.The present development situation and the existing problems of r... The indirect detection method basic principle of rate and concentration,application range and research results on gassolid two phase flow were discussed.The present development situation and the existing problems of rate and concentration detection technology were analyzed and summarized.Emphatically analyzed the existing problems in the industrial application and research status of electrostatic method in measuring phase concentration.Design criterion of electrostatic phase concentration sensor is given,the superiority and wide industrial application prospect of the sensor used for phase concentration measurement are clarified. 展开更多
关键词 gas-solid two phase flow rate-concentration electrostatic method
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RESEARCH ON THE PARTICLE DISPERSION IN THE PARTICULATE TWO-PHASE ROUND JET 被引量:1
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作者 林建忠 林江 朱丽兵 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 1999年第5期33-40,共8页
In this paper, the three_dimensional vo rtex filament method was used to simulate the evolution of vortex structures in the axisymmetric round jet. The results agree well with the ones given by Chung and Troutt. The... In this paper, the three_dimensional vo rtex filament method was used to simulate the evolution of vortex structures in the axisymmetric round jet. The results agree well with the ones given by Chung and Troutt. Then one_coupling model was employed to calculate the particle motio n based on the computed flows. The results show that the particle motion is affe cted by flows obviously at the case of particle number St1 and negligibly at St1 ,particles distribute around the vortex structures uniformly at St ~1 . When perturbations with wavenumber 5 are introduced to vortex rings, part icles disperse wider along radial direction, which conforms to the experimental results. The degree of particle dispersion is in the direct ratio to the amplitu de of perturbation. The conclusions given in the paper are useful to the practic e usage. 展开更多
关键词 gas particle two_phase flow round jet large vortex stucture particle dispersion
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Experiments and Numerical Calculations on an Ignition System
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作者 陈朗 冯长根 +2 位作者 张寿齐 王丽琼 向永 《Journal of Beijing Institute of Technology》 EI CAS 1999年第2期8-12,共5页
Aim To present a new kind of rapid ignition tube for igniting the propellant of heavy calibre gun uniformly and synchronistically so as to decrease the pressure wave. Methods Firing tests were carried out. Relationsh... Aim To present a new kind of rapid ignition tube for igniting the propellant of heavy calibre gun uniformly and synchronistically so as to decrease the pressure wave. Methods Firing tests were carried out. Relationships between pressure and time ( p t curves) at different positions of the tube are measured. The mode of igniter tube of quasi one dimensional two phase flow is given. Results\ The test results indicate that the speed of ignition front in the ignition tube is very fast and the pressure distribution within the igniter tube is uniform. Results of experiments and numerical calculations of the combustion in the igniter tube are in reasonable agreement. Conclusion\ The new igniter tubes have a very high velocity of propagation of ignition stimuli and can ignite the propellant bed synchronistically. 展开更多
关键词 GUN IGNITION COMBUSTION two phase flow
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A Model on the Void Fraction in Liquid Slugs for Vertical Slug Flow
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作者 夏国栋 张少华 +2 位作者 魏宸官 周芳德 胡明胜 《Journal of Beijing Institute of Technology》 EI CAS 1999年第1期43-48,共6页
Aim To develop a hydrodynamic model on the void fraction in liquid slugs for gas liquid slug flow in vertical tubes. Methods Developing the model by considering the gas exchange between the Taylor bubble and the fo... Aim To develop a hydrodynamic model on the void fraction in liquid slugs for gas liquid slug flow in vertical tubes. Methods Developing the model by considering the gas exchange between the Taylor bubble and the following liquid slug. Results Some experimental data are obtained to check the model. In comparison with previous published results, the predictions from this model are better and in good agreement with the experimental data. The error is within ±20%. Conclusion The proposed model can correctly predict the void fraction in liquid slugs for gas liquid two phase slug flow in vertical tubes. 展开更多
关键词 gas liquid two phase flow liquid slug void fraction
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APPLICATION POSSIBILITY OF BINARY NONAZEOTROPIC REFRIGERANT IN JET REFRIGERATION *
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作者 张于峰 张利民 +1 位作者 李灿华 孙萍 《Transactions of Tianjin University》 EI CAS 1998年第1期26-30,共5页
This paper analyzes the possibility of applying binary nonazeotropic refrigerants in the jet refrigeration cycle. The thermodynamic cycle performance of two kinds of working pairs (R30/R142b, R30/R124) are calculated ... This paper analyzes the possibility of applying binary nonazeotropic refrigerants in the jet refrigeration cycle. The thermodynamic cycle performance of two kinds of working pairs (R30/R142b, R30/R124) are calculated using the EOS of PR equation of state, and the results are discussed. The theoretical calculations indicate that refrigerating quality can be improved if the binary mixtures evaporate just in the low temperature region. The character of the rejecter to compress two phase medium supports the possibility of this kind of cycle. 展开更多
关键词 jet refrigeration evaporating in low temperature region vapour liquid two phase compression binary nonazeotropic refrigerant
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Characteristics of a Flow Transducer Based on Polarized Charge
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作者 张朴 孔力 黄心汉 《Journal of Southeast University(English Edition)》 EI CAS 2001年第2期36-40,共5页
In this paper we analyze the characteristics of a flow transducer based on polarized charge. The effects of the charged particles in pneumatic pipeline on the measurement pipe potential are discussed in detail and the... In this paper we analyze the characteristics of a flow transducer based on polarized charge. The effects of the charged particles in pneumatic pipeline on the measurement pipe potential are discussed in detail and the equivalent circuits of the potential measurement are presented. On this bases, the relationships between mass flowrate and the electrical potential are obtained for different time constants of the measurement circuit. A satisfactory model is presented based on the characteristics of gas solid two phase flow. The linearity of the model is verified by the experiment results. The transducer, which is coaxially connected with the transport pipeline, does not disturb the flow state and has the features of ruggedness and durability, it is especially suitable for industry process control. 展开更多
关键词 polarized charge gas solid two phase flow measurement model
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RESEARCH ON THE FLOW STABILITY IN A CYLINDRICAL PARTICLE TWO-PHASE BOUNDARY LAYER
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作者 林建忠 聂德明 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2003年第6期631-637,共7页
Based on the momentum and constitutive equations, the modified Orr_Sommerfeld equation describing the flow stability in a cylindrical particle two_phase flow was derived.For a cylindrical particle two_phase boundary l... Based on the momentum and constitutive equations, the modified Orr_Sommerfeld equation describing the flow stability in a cylindrical particle two_phase flow was derived.For a cylindrical particle two_phase boundary layer, the neutral stability curves and critical Reynolds number were given with numerical simulation. The results show that the cylindrical particles have a suppression effect on the flow instability, the larger the particle volume fraction and the particle aspect_ratio are, the more obvious the suppression effect is. 展开更多
关键词 cylindrical particle two_phase flow boundary layer STABILITY
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Numerical Simulation and Experimental Research on the Influence of Solid-phase Characteristics on Centrifugal Pump Performance 被引量:12
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作者 LI Yi ZHU Zuchao +1 位作者 HE Weiqiang HE Zhaohui 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2012年第6期1184-1189,共6页
The law governing the movement of particles in the centrifugal pump channel is complicated; thus, it is difficult to examine the solid-liquid two-phase turbulent flow in the pump. Consequently, the solid-liquid two-ph... The law governing the movement of particles in the centrifugal pump channel is complicated; thus, it is difficult to examine the solid-liquid two-phase turbulent flow in the pump. Consequently, the solid-liquid two-phase pump is designed based only on the unary theory. However, the obvious variety of centrifugal-pump internal flow appears because of the existence of solid phase, thus changing pump performance. Therefore, it is necessary to establish the flow characteristics of the solid-liquid two-phase pump. In the current paper, two-phase numerical simulation and centrifugal pump performance tests are carried out using different solid-particle diameters and two-phase mixture concentration conditions. Inner flow features are revealed by comparing the simulated and experimental results. The comparing results indicate that the influence of the solid-phase characteristics on centrifugal-pump performance is small when the flow rate is low, specifically when it is less than 2 m3/h. The maximum efficiency declines, and the best efficiency point tends toward the low flow-rate direction along with increasing solid-particle diameter and volume fraction, leading to reduced pump steady efficient range. The variation tendency of the pump head is basically consistent with that of the efficiency. The efficiency and head values of the two-phase mixture transportation are even larger than those of pure-water transportation under smaller particle diameter and volume fraction conditions at the low-flow-rate region. The change of the particle volume fraction has a greater effect on the pump performance than the change in the particle diameter. The experimental values are totally smaller than the simulated values. This research provides the theoretical foundation for the optimal design of centrifugal pump. 展开更多
关键词 solid-liquid two phase centrifugal pump performance test numerical simulation
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Influence of baffle position on liquid sloshing during braking and turning of a tank truck 被引量:10
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作者 Ning KANG Kui LIU 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2010年第5期317-324,共8页
The influence of baffle position on liquid sloshing during the braking and turning of a tank truck was studied using a volume of fluid (VOF) model. The forces,their positions and weight distribution during braking and... The influence of baffle position on liquid sloshing during the braking and turning of a tank truck was studied using a volume of fluid (VOF) model. The forces,their positions and weight distribution during braking and the forces and rolling moment during turning were calculated. The reliability of the calculation method was validated by comparisons with experimental results. The results showed that during braking,liquid splashes in the tank and the maximum forces and G (the ratio of weight acting on the front axle to the rear axle) are large when A (the ratio of the arch area above the baffle to the area of cross section)≤0.1. When A≥0.2,as the position of the baffle is lowered,the maximum of Fx (the force in direction x) first decreases then increases,and the maximum of Fy (the force in direction y) and G increase. During turning,liquid splashes in the tank and the maximum forces and M (the rolling moment) are large when D (the ratio of the arch area above the baffle to the area of cross section)≤0.2. When D≥0.3,as the position of the baffle is lowered,the maximums of Fy,Fz (the force in direction z) and M increase. 展开更多
关键词 Tank truck Volume of fluid (VOF) method Liquid sloshing Two phase flow BAFFLE
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Performance of a Horizontally Mounted Venturi in Low-pressure Wet Gas Flow 被引量:9
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作者 方立德 张涛 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2008年第2期320-324,共5页
The performance of a Venturi tube used in wet gas flow have been explored mainly under higher-pressure condition, but very often, low-pressure test exists in some oil and gas fields in Tianjin Dagang Oil and Gas Field... The performance of a Venturi tube used in wet gas flow have been explored mainly under higher-pressure condition, but very often, low-pressure test exists in some oil and gas fields in Tianjin Dagang Oil and Gas Field in China. In this study, the performance of horizontally mounted Venturi meters in low-pressure wet gas flow is discussed. Three 50 mm Venturi meters were tested systematically, with fl values of 0.4048, 0.55 and 0.70, the opera- tion pressure of 0.15 MPa, 0.20 MPa, 0.25 MPa, the gas densiometric Froude number from 0.6 to 2.0, the modified Lockhart-Maretinelli parameter from 0.0022 to 0.06, and the ratio of the gas liquid mass flow rate from 0.5 to 0.99. The effects of modified Lockhart-Maretinelli parameter, pressure, gas densiometric Froude number, diameter ratio, and gas-liquid mass flow rate ratio to the Venturi tube are analyzed with new independent data. Furthermore, low-pressure performance was compared with that under high pressure. 展开更多
关键词 gas-liquid two phase flow wet gas metering Venturi meter over-reading
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NUMERICAL SIMULATION OF CHARGED GAS-LIQUID TWO PHASE JET FLOW IN ELECTROSTATIC SPRAYING 被引量:6
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作者 Wang Ze,Jin Hanhui,Wang Junfeng,Luo Tiqian (School of Energy and Power,Jiangsu University of Science and Technology) 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2001年第3期266-270,共5页
Multi-fluid k-e-kp, two phase turbulence model is used to simulate charged gas-liquid two phase coaxial jet, which is the transorting flow field in electrostatic spraying. Compared with the results of experiment, cha... Multi-fluid k-e-kp, two phase turbulence model is used to simulate charged gas-liquid two phase coaxial jet, which is the transorting flow field in electrostatic spraying. Compared with the results of experiment, charged gas-liquid two-phase turbulence can be well predicted by this model. 展开更多
关键词 ELECTROSTATICS Two phase flow TURBULENCE Numerical simulation
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Effect of hot rolling and annealing temperatures on the microstructure and mechanical properties of SP-700 alloy 被引量:8
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作者 Parnia Parvizian Maryam Morakabati Saeed Sadeghpour 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2020年第3期374-383,共10页
The effect of rolling temperature on both two-and single-phase regions and annealing in a temperature range of 700–950°C on the microstructure and mechanical properties of Ti-5 Al-4 V-2 Fe-1 Mo alloy was investi... The effect of rolling temperature on both two-and single-phase regions and annealing in a temperature range of 700–950°C on the microstructure and mechanical properties of Ti-5 Al-4 V-2 Fe-1 Mo alloy was investigated. The results indicated that the best balance of strength and ductility is obtained by rolling in the two-phase region due to the globularization of the alpha phase and increase in its volume fraction. After rolling in the two-phase region, the ductility of the specimens annealed at 700 to 800°C increased because of the finer size and globularized alpha phase, while the reduction in strength was attributed to a decrease in the alpha phase volume fraction. However, at 950°C, the strength increased and ductility dropped by the formation of acicular alpha phase due to an increase in the phase boundary area. Annealing and aging after rolling in the beta-phase region increased the strength and decreased the ductility, which is attributed to the formation of a secondary alpha phase. A combination of favorable yield strength(1113 MPa) and elongation(13.3%) was obtained through rolling at 850°C followed by annealing at 750°C and aging at 570°C. 展开更多
关键词 beta-rich two phase Ti alloy thermomechanical processing tensile properties MICROSTRUCTURE
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Efficiency of Plate Separators for Dispersed Liquid-Liquid Systems 被引量:5
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作者 唐洪涛 吴剑华 《Transactions of Tianjin University》 EI CAS 2006年第5期313-318,共6页
The basic flow model of laminar flow field and the trajectory model of dispersed phase drops are derived. Based on the comparable volumetric flow rate, the dispersed flow rate can be linearly discretized. Consequently... The basic flow model of laminar flow field and the trajectory model of dispersed phase drops are derived. Based on the comparable volumetric flow rate, the dispersed flow rate can be linearly discretized. Consequently, the trajectory of a droplet in the channel can be tracked, and the trajectories of all drops are observed in order to statistically analyse the drops for capture or entrainment. Therefore, in terms of theoretical model of motion, the stratified two phase flow systems are studied in the mixture of nitrobenzene and concentrated sulfuric acid. The analytical results indicate that the trajectories of droplets of different diameters are different at the same location. The larger droplets can help to promote the efficiency of plate separators. The thickness of trickling film has a significant influence on the efficiency of numerical simulation when the concentration of the dispersed phase is greater than 10%. So the modification of thickness of trickling film can help to get the real flow field efficiency. The low flow rate lowers the average Renolds number so that the lighter phase droplets have sufficient time to interact with the trickling film. It is an indispensable factor for predicting efficiency that coalesced drops flow off inclined plates together with trickling films. A comparison confirms that the simulation results are in good agreement with the experiment results. 展开更多
关键词 EFFICIENCY COALESCENCE SEPARATORS DROPS two phase flow
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Effect of pressurizing speed on filling behavior of gradual expansion structure in low pressure casting of ZL205A alloy 被引量:8
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作者 Shan-guang Liu Chuan-biao Luo +3 位作者 Guo-ai Li Wen-lin Gao Zheng Lu Sheng-long 《China Foundry》 SCIE 2018年第4期276-282,共7页
The mold filling behavior of gradual expansion structure in low pressure casting was studied by two phase flow model using the Volume of Fluid method, and was verified by water simulation with a Plexiglas mold. To get... The mold filling behavior of gradual expansion structure in low pressure casting was studied by two phase flow model using the Volume of Fluid method, and was verified by water simulation with a Plexiglas mold. To get smooth mold filling process and provide a guide for the pressurizing speed design in the producing practice, the mathematical model with the pressurizing speed, expansion angle and height of the gradual expansion structure was established. For validation experiments, ZL205 A alloy castings were produced under two different pressurizing speeds. Weibull probability plots were used to assess the fracture mechanisms under different pressurizing speeds. Mechanical properties of ZL205 A alloy were applied to assess the entrainment of oxide film. The results show that the filling process of a gradual expansion structure in a low pressure casting can be divided into the spreading stage and filling stage by gate velocity. The gate velocity continues to increase in the gradual expansion structure, and increases with the increase of pressurizing speed or expansion angle. Under the effect of the falling fluid raised by the jet flow along the sidewall, the fluid velocity decreases in the jet zone from ingate to free surface. As such, oxide film entrainment does not occur when the gate velocity is greater than the critical velocity, andthe gate velocity no longer reflects the real state of the free surface. The scatter of the mechanical properties is strongly affected by the entrainment of oxide films. 展开更多
关键词 low pressure casting two phase flow water simulation oxide film ZL205A alloy
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Bionic Design and Finite Element Analysis of Elbow in Ice Transportation Cooling System 被引量:5
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作者 Dejun Miao Xiuhua Sui Linjing Xiao 《Journal of Bionic Engineering》 SCIE EI CSCD 2010年第3期301-306,共6页
With the increase in mining depth,mine heat harm has appeared to be more prominent.The mine heat harm could be resolvedor reduced by ice refrigeration.Thus,ice transportation through pipeline becomes a critical proble... With the increase in mining depth,mine heat harm has appeared to be more prominent.The mine heat harm could be resolvedor reduced by ice refrigeration.Thus,ice transportation through pipeline becomes a critical problem;typically flowresistance occurs in the elbow.In the present study,according to the analysis of the surface morphology of fish scale,abiomimetic functional surface structure for the interior wall of elbow is designed.Based on the theory of liquid-solid two phaseflow,a CFD numerical simulation of ice-water mixture flowing through the elbow is carried out using finite element method.Conventional experiments of pressure drop and flow resistance for both bionic and common elbows are conducted to test theeffect of the bionic elbow on flow resistance reduction.It is found that with the increase in the ice mass fraction in the ice-watermixture,the effect of bionic elbow on resistance reduction becomes more obvious. 展开更多
关键词 bionic elbow two phase flow ice transportation flow resistance reduction pressure loss
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Measurement of Two Phase Flow in Porous Medium Using High-resolution Magnetic Resonance Imaging 被引量:4
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作者 蒋兰兰 宋永臣 +4 位作者 刘瑜 杨明军 朱宁军 王晓静 豆斌林 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2013年第1期85-93,共9页
Measurement of two phase flow in porous medium for sequestration was carried out using high-resolution magnetic resonance imaging (MRI) technique. The porous medium was a packed bed of glass beads. Spin echo multi seq... Measurement of two phase flow in porous medium for sequestration was carried out using high-resolution magnetic resonance imaging (MRI) technique. The porous medium was a packed bed of glass beads. Spin echo multi sequence was used to measure the distribution of CO2 and water in the porous medium. The intensity images show that the fluid distribution is non-uniform due to its viscosity and pore structure of porous medium. The velocity distribution of fluids is calculated from the saturation of water and porosity of porous medium. The experimental results show that fluid velocities vary with time and position. The capillary dispersion rate donated the effects of capillary, which was largest at water saturations of 0.45. The displacement process is different between in BZ-02 and BZ-2. The final water residual saturation depends on permeability and porosity. 展开更多
关键词 two phase flow porous medium magnetic resonance imaging SATURATION CO2 velocity DISPLACEMENT
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Effect of grain size reduction on high temperature oxidation of binary two-phase alloys 被引量:5
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作者 李远士 牛焱 +1 位作者 吴维 付广艳 《中国有色金属学会会刊:英文版》 CSCD 2001年第5期644-648,共5页
The effect of grain size reduction on the high temperature oxidation of binary two phase alloys was discussed based on the recent research progress. The results show that for those two phase alloys with coarse grain p... The effect of grain size reduction on the high temperature oxidation of binary two phase alloys was discussed based on the recent research progress. The results show that for those two phase alloys with coarse grain prepared by the conventional methods, complex oxide scales are easily formed after oxidation under high oxygen pressure or under oxygen pressure below the stability limit of the less reactive component oxides. On the contrary, for the nano sized alloys, an exclusive external oxidation of the most reactive component usually occurs during oxidation in air or pure oxygen even for much lower content of the most reactive component. So the gain size reduction is not always beneficial to improve the oxidation resistance of the materials, but exhibits different effects depending mainly on the protective feature of the scales. The transition mechanisms between the different oxidation modes are discussed with respect to the thermodynamic and dynamic aspects. 展开更多
关键词 two phase alloy NANOCRYSTALLIZATION oxidation mode oxidation resistance
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Enhanced conversion of α-cellulose to 5-HMF in aqueous biphasic system catalyzed by FeCl_(3)-CuCl_(2) 被引量:3
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作者 Lilin Zhang Yinbing Tian +1 位作者 Yuanyuan Wang Liyi Dai 《Chinese Chemical Letters》 SCIE CAS CSCD 2021年第7期2233-2238,共6页
This study was to investigate the optimal additions of the cellulose decomposition reaction to obtain the most yield of 5-HMF and other furan derivatives in various biphasic systems with FeCl_(3)-CuCl_(2) mixed cataly... This study was to investigate the optimal additions of the cellulose decomposition reaction to obtain the most yield of 5-HMF and other furan derivatives in various biphasic systems with FeCl_(3)-CuCl_(2) mixed catalysts,and explore its depolymerization kinetics.A series of controllable reactions have been performed under mild environmentally friendly atmosphere.The experiment results showed that49.13 wt%of 5-HMF was the maximum production along with 2.98 wt%other furan derivatives catalyzed by mixed Lewis acid FeCl_(3)-CuCl_(2) under the two phases which included high concentration NaCl aqueous phase and n-butanol organic phase at 190℃for 45 min.The conclusion suggested that two-phase systems benefited the yield of 5-HMF,furan derivatives via extracting the target products from reaction phase to organic phase to avoid rehydration of 5-HMF.The kinetic calculation revealed the conversion with mixed catalysts had lower reaction apparent activation energy(21.65 kJ/mol,190-230℃)and the reaction rate was faster than that with acid-based catalysts.Based on experiment exploration,the probable mechanism of cellulose decomposition with FeCl_(3)-CuCl_(2) was proposed. 展开更多
关键词 CELLULOSE Two phase Mixed catalysts DEPOLYMERIZATION 5-HMF
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