Since their seminal discovery in 2011,two-dimensional(2D)transition metal carbides/nitrides known as MXenes,that constitute a large family of 2D materials,have been targeted toward various applications due to their ou...Since their seminal discovery in 2011,two-dimensional(2D)transition metal carbides/nitrides known as MXenes,that constitute a large family of 2D materials,have been targeted toward various applications due to their outstanding electronic properties.MXenes functioning as co-catalyst in combination with certain photocatalysts have been applied in photocatalytic systems to enhance photogenerated charge separation,suppress rapid charge recombination,and convert solar energy into chemical energy or use it in the degradation of organic compounds.The photocatalytic performance greatly depends on the composition and morphology of the photocatalyst,which,in turn,are determined by the method of preparation used.Here,we review the four different synthesis methods(mechanical mixing,self-assembly,in situ decoration,and oxidation)reported for MXenes in view of their application as co-catalyst in photocatalysis.In addition,the working mechanism for MXenes application in photocatalysis is discussed and an outlook for future research is also provided.展开更多
Metallogenic prognosis of synthetic information uses the geological body and the mineral resource body as a statistical unit to interpret synthetically the information of geology, geophysics, geochemistry and remote s...Metallogenic prognosis of synthetic information uses the geological body and the mineral resource body as a statistical unit to interpret synthetically the information of geology, geophysics, geochemistry and remote sensing from the evolution of geology and puts all the information into one entire system by drawing up digitalized interpretation maps of the synthetic information. On such basis, different grades and types of mineral resource prospecting models and predictive models of synthetic information can be established. Hence, a new integrated prediction system will be formed of metallogenic prognosis (qualitative prediction), mineral resources statistic prediction (determining targets) and mineral resources prediction (determining resources amount).展开更多
One-Way Traffic synthetic assessing can not only determine the assessment method, but can also provide an opportunity for further study of road systems. Comparing three Road Traffic Planning methods, which are Value A...One-Way Traffic synthetic assessing can not only determine the assessment method, but can also provide an opportunity for further study of road systems. Comparing three Road Traffic Planning methods, which are Value Analysis method, Simple Array method and Step Analysis method, this paper concludes that Simple Array method has one prominent merit, avoiding the complicated relationship of various factors and simplifying the complex problem. Therefore Simple Array method is firstly presented in this paper to be the assessing measure to assess the One-Way Traffic Planning project. Although this assessing method cannot wholly give way to man’s will, through consistently testing on qualitative factors and with the decision-making results of a multi-program, this method is still an effective method. Using an example of Harbin One-Way Traffic planning, with seven assessing indexes including economic benefit index, Simple Array method is applied to synthetically assessing the program. This fully reflects the general function of One-Way Traffic planning program and objectively evaluates the program. It also proves that, as the method of One-Way Traffic synthetic assessing, Simple Array method is rational and practical.展开更多
An efficient and practical synthetic process for Daprodustat was developed.Starting with N,N'-dicyclohexylcarbodiimide(DCC)and malonic acid,the key intermediate 1,3-dicyclohexylpyrimidine-2,4,6(1H,3H,5H)-trione wa...An efficient and practical synthetic process for Daprodustat was developed.Starting with N,N'-dicyclohexylcarbodiimide(DCC)and malonic acid,the key intermediate 1,3-dicyclohexylpyrimidine-2,4,6(1H,3H,5H)-trione was synthesized via condensation reaction with 91%yield.Subsequent activation of this intermediate by 1,1'-carbonyldiimidazole(CDI),followed by a one-pot reaction with glycine ethyl ester hydrochloride,directly afforded Daprodustat in 92%yield with>99.8%HPLC purity.The process achieved an overall yield of 84%upon validation at 62-gram scale.Structural confirmation of the key intermediate was accomplished through nuclear magnetic resonance(NMR)spectroscopy and high-resolution mass spectrometry(HRMS).Compared with existing methods,this streamlined protocol demonstrates advantages including simplified operation,reduced reaction time,and lower production costs,offering significant potential for industrial-scale synthesis of Daprodustat.展开更多
Efficient and accurate simulation of unsteady flow presents a significant challenge that needs to be overcome in computational fluid dynamics.Temporal discretization method plays a crucial role in the simulation of un...Efficient and accurate simulation of unsteady flow presents a significant challenge that needs to be overcome in computational fluid dynamics.Temporal discretization method plays a crucial role in the simulation of unsteady flows.To enhance computational efficiency,we propose the Implicit-Explicit Two-Step Runge-Kutta(IMEX-TSRK)time-stepping discretization methods for unsteady flows,and develop a novel adaptive algorithm that correctly partitions spatial regions to apply implicit or explicit methods.The novel adaptive IMEX-TSRK schemes effectively handle the numerical stiffness of the small grid size and improve computational efficiency.Compared to implicit and explicit Runge-Kutta(RK)schemes,the IMEX-TSRK methods achieve the same order of accuracy with fewer first derivative calculations.Numerical case tests demonstrate that the IMEX-TSRK methods maintain numerical stability while enhancing computational efficiency.Specifically,in high Reynolds number flows,the computational efficiency of the IMEX-TSRK methods surpasses that of explicit RK schemes by more than one order of magnitude,and that of implicit RK schemes several times over.展开更多
On-line measurement for dielectric loss angle can effectively monitor the insulation condition of capacitive equipment in power systems. Synthetic relative measuring methods not only markedly overcome the shortcomings...On-line measurement for dielectric loss angle can effectively monitor the insulation condition of capacitive equipment in power systems. Synthetic relative measuring methods not only markedly overcome the shortcomings of traditional absolute measuring methods but also greatly improve the accuracy of dielectric loss angle measurement. However, synthetic relative measuring methods based on two or three pieces of capacitive equipment do not have the characteristic of generality. In this paper, a principle of synthetic relative measuring method is presented. The example of application for synthetic relative methods based on three and four pieces of capacitive equipment running in the same phase is taken to present the failure judgment matrices for N pieces of equipment. According to these matrices, the fault condition of N pieces of capacitive equipment can be watched, which is more general. Then some problems needing to be concerned along with two diagnostic methods used in diagnostic system are introduced. Finally, two programmable flow charts for the two methods are given and corresponding examples demonstrate their feasibility in practice.展开更多
The index system, code system, and weights of indexes are established to assess the effects of green construction. The index system consists of index level, factor level and sub-factor level. The analytic hierarchy pr...The index system, code system, and weights of indexes are established to assess the effects of green construction. The index system consists of index level, factor level and sub-factor level. The analytic hierarchy process is used to determine the weights of indexes, and the consistency test indicate that the weight assignment is reasonable. Using fuzzy synthetic judgment method, the assessment model is built, which includes factor set, weight set and conclusion set. An example is given to demonstrate the assessment procedures.展开更多
4,4'-Oxybis(benzoic acid)(Ⅰ)is an important monomer for making synthetic resin,heat resistant film and liquid crystal fiber,etc.It has been synthesized either by the oxidation of 4,4'-dimethyl diphenyl ether,...4,4'-Oxybis(benzoic acid)(Ⅰ)is an important monomer for making synthetic resin,heat resistant film and liquid crystal fiber,etc.It has been synthesized either by the oxidation of 4,4'-dimethyl diphenyl ether,or by the electrophilic substitution of diphenyl ether,these substituents introduced into the benzene ring can be further transformed into carboxylic groups.Diphenyl ethers are usually prepared from phenols and halobenzenes through Ullmann resction.Due to the high reaction temerature(usually above 200℃),long time heating and the formation of isomers,it is difficult to obtain pure products in high yields.展开更多
The accuracy of background clutter model is a key factor which determines the performance of a constant false alarm rate(CFAR) target detection method. G0 distribution is one of the optimal statistic models in the syn...The accuracy of background clutter model is a key factor which determines the performance of a constant false alarm rate(CFAR) target detection method. G0 distribution is one of the optimal statistic models in the synthetic aperture radar(SAR) image background clutter modeling and can accurately model various complex background clutters in the SAR images. But the application of the distribution is greatly limited by its disadvantages that the parameter estimation is complex and the local detection threshold is difficult to be obtained. In order to solve the above-mentioned problems, an synthetic aperture radar CFAR target detection method using the logarithmic cumulant(Mo LC) + method of moment(Mo M)-based G0 distribution clutter model is proposed. In the method, G0 distribution is used for modeling the background clutters, a new Mo LC+Mo M-based parameter estimation method coupled with a fast iterative algorithm is used for estimating the parameters of G0 distribution and an exquisite dichotomy method is used for obtaining the local detection threshold of CFAR detection, which greatly improves the computational efficiency, detection performance and environmental adaptability of CFAR detection. Experimental results show that the proposed SAR CFAR target detection method has good target detection performance in various complex background clutter environments.展开更多
The synthetic fuzzy assessing method is usually applied to sensory evaluation. The method has simple and reliable virtue, and it is consistent with objective evaluation results. Using this method, system status of pla...The synthetic fuzzy assessing method is usually applied to sensory evaluation. The method has simple and reliable virtue, and it is consistent with objective evaluation results. Using this method, system status of plating solution evaporator is evaluated, and the result is applied to compensate a fuzzy controller. Experimental results have shown the correctness and the validity of the proposed approach.展开更多
Dibenzoyl peroxide undergoes oxidative addition on metallic copper with triphenylphosphine in a mixed solvent(acetone,dichloromethane and trichloromethane),and affords the binuclear copper complex (Cu(C_6H_5COO)_2(OPP...Dibenzoyl peroxide undergoes oxidative addition on metallic copper with triphenylphosphine in a mixed solvent(acetone,dichloromethane and trichloromethane),and affords the binuclear copper complex (Cu(C_6H_5COO)_2(OPPh_3))_2.Crystals are monoclinic,space group A_2/a,with cell parameters,a=24.337(3),b=10.566(1),c=21.579(2),β= 93.18(1)°, V=5540(1)~3,Z=4,R=0.042,and Rw=0.044 for 5872 observed reflections. Each copper ion is coordinated by four bridging benzoato ligands and one triphenylphosphine oxide group to form binuclear complexes.展开更多
Based on the extraction and calculation of the short-term seismic precursory information magnitude from the 114 major precursory observations in the North China region, and together with consideration of factors such ...Based on the extraction and calculation of the short-term seismic precursory information magnitude from the 114 major precursory observations in the North China region, and together with consideration of factors such as geological structure, seismicity, crustal thickness, and in particular, the current geodynamics of the region, the authors studied the time-space evolution characteristics of the short-term earthquake precursory information magnitude and its relationship with earthquakes and proposed the index and method for the short-term synthetic prediction of earthquakes with M S≥5.0 in the North China region. The inspection through R-value shows that the method is effective to a certain extent for earthquake prediction.展开更多
Compositional data, such as relative information, is a crucial aspect of machine learning and other related fields. It is typically recorded as closed data or sums to a constant, like 100%. The statistical linear mode...Compositional data, such as relative information, is a crucial aspect of machine learning and other related fields. It is typically recorded as closed data or sums to a constant, like 100%. The statistical linear model is the most used technique for identifying hidden relationships between underlying random variables of interest. However, data quality is a significant challenge in machine learning, especially when missing data is present. The linear regression model is a commonly used statistical modeling technique used in various applications to find relationships between variables of interest. When estimating linear regression parameters which are useful for things like future prediction and partial effects analysis of independent variables, maximum likelihood estimation (MLE) is the method of choice. However, many datasets contain missing observations, which can lead to costly and time-consuming data recovery. To address this issue, the expectation-maximization (EM) algorithm has been suggested as a solution for situations including missing data. The EM algorithm repeatedly finds the best estimates of parameters in statistical models that depend on variables or data that have not been observed. This is called maximum likelihood or maximum a posteriori (MAP). Using the present estimate as input, the expectation (E) step constructs a log-likelihood function. Finding the parameters that maximize the anticipated log-likelihood, as determined in the E step, is the job of the maximization (M) phase. This study looked at how well the EM algorithm worked on a made-up compositional dataset with missing observations. It used both the robust least square version and ordinary least square regression techniques. The efficacy of the EM algorithm was compared with two alternative imputation techniques, k-Nearest Neighbor (k-NN) and mean imputation (), in terms of Aitchison distances and covariance.展开更多
The main objective of this study is to generate accurate synthetic hourly solar radiation data by using an easily accessible open source data.In this regard,a new approach is proposed for estimation of synthetic hourl...The main objective of this study is to generate accurate synthetic hourly solar radiation data by using an easily accessible open source data.In this regard,a new approach is proposed for estimation of synthetic hourly global solar radiation during the day by utilizing only annual solar energy data.First time in literature,a model has been developed for prediction hourly and daily solar radiation based on annual solar energy parameter in this study.Parameters of the model were generated and tested for Turkey and one of them was presented as a case study within this paper.Long term measured hourly horizontal solar irradiance data from a network of Turkish meteorological stations was used to calibrate the model function.The predictions are compared with the solar data available in literature for Turkey.The advanced simple new model is utilized in open source computer program and has the potential to be adapted to other countries.展开更多
As same as the conventional inverse synthetic aperture radar（ISAR）, the compressed ISAR also requires the echo signal based motion compensation, which consists of the range alignment and the phase autofoeusing. A ph...As same as the conventional inverse synthetic aperture radar（ISAR）, the compressed ISAR also requires the echo signal based motion compensation, which consists of the range alignment and the phase autofoeusing. A phase autofocusing algorithm for compressed ISAR imaging is presented. In the algorithm, phase autofocusing for the sparse ISAR echoes is accomplished using the eigenvector method. Experimental results validate the effectiveness of the algorithm.展开更多
In order to suppress the airwave noise in marine controlled-source electromagnetic （CSEM） data, we propose a 3D deconvolution （3DD） interferometry method with a synthetic aperture source and obtain the relative an...In order to suppress the airwave noise in marine controlled-source electromagnetic （CSEM） data, we propose a 3D deconvolution （3DD） interferometry method with a synthetic aperture source and obtain the relative anomaly coefficient （RAC） of the EM field reflection responses to show the degree for suppressing the airwave. We analyze the potential of the proposed method for suppressing the airwave, and compare the proposed method with traditional methods in their effectiveness. A method to select synthetic source length is derived and the effect of the water depth on RAC is examined via numerical simulations. The results suggest that 3DD interferometry method with a synthetic source can effectively suppress the airwave and enhance the potential of marine CSEM to hydrocarbon exploration.展开更多
Temperature-dependent photoluminescence characteristics of organic-inorganic halide perovskite CH3NH3Pb I3-xClx films prepared using a two-step method on ZnO/FTO substrates were investigated. Surface morphology and ab...Temperature-dependent photoluminescence characteristics of organic-inorganic halide perovskite CH3NH3Pb I3-xClx films prepared using a two-step method on ZnO/FTO substrates were investigated. Surface morphology and absorption characteristics of the films were also studied. Scanning electron microscopy revealed large crystals and substrate coverage. The orthorhombic-to-tetragonal phase transition temperature was-140 K. The films＇ exciton binding energy was 77.6 ± 10.9 meV and the energy of optical phonons was 38.8 ± 2.5 meV. These results suggest that perovskite CH3NH3Pb I（3-x）Clx films have excellent optoelectronic characteristics which further suggests their potential usage in perovskitebased optoelectronic devices.展开更多
To dates,most ship detection approaches for single-pol synthetic aperture radar（SAR） imagery try to ensure a constant false-alarm rate（CFAR）.A high performance ship detector relies on two key components：an accura...To dates,most ship detection approaches for single-pol synthetic aperture radar（SAR） imagery try to ensure a constant false-alarm rate（CFAR）.A high performance ship detector relies on two key components：an accurate estimation to a sea surface distribution and a fine designed CFAR algorithm.First,a novel nonparametric sea surface distribution estimation method is developed based on n-order Bézier curve.To estimate the sea surface distribution using n-order Bézier curve,an explicit analytical solution is derived based on a least square optimization,and the optimal selection also is presented to two essential parameters,the order n of Bézier curve and the number m of sample points.Next,to validate the ship detection performance of the estimated sea surface distribution,the estimated sea surface distribution by n-order Bézier curve is combined with a cell averaging CFAR（CA-CFAR）.To eliminate the possible interfering ship targets in background window,an improved automatic censoring method is applied.Comprehensive experiments prove that in terms of sea surface estimation performance,the proposed method is as good as a traditional nonparametric Parzen window kernel method,and in most cases,outperforms two widely used parametric methods,K and G0 models.In terms of computation speed,a major advantage of the proposed estimation method is the time consuming only depended on the number m of sample points while independent of imagery size,which makes it can achieve a significant speed improvement to the Parzen window kernel method,and in some cases,it is even faster than two parametric methods.In terms of ship detection performance,the experiments show that the ship detector which constructed by the proposed sea surface distribution model and the given CA-CFAR algorithm has wide adaptability to different SAR sensors,resolutions and sea surface homogeneities and obtains a leading performance on the test dataset.展开更多
The distribution of remaining oil is often described qualitatively. The remaining oil distributed in the whole reservoir is calculated according to the characteristics of the space distribution of the saturation of re...The distribution of remaining oil is often described qualitatively. The remaining oil distributed in the whole reservoir is calculated according to the characteristics of the space distribution of the saturation of remaining oil. Logging data are required to accomplish this. However, many such projects cannot be completed. Since the old study of remaining oil distribution could not be quantified efficiently, the ＂dynamic two-step method＂ is presented. Firstly, the water cut of every flow unit in one well at one time is calculated according to the comprehensive water cut of a single well at one time. Secondly, the remaining oil saturation of the flow unit of the well at one time is calculated based on the water cut of the flow unit at a given time. The results show that ＂dynamic two-step method＂ has characteristics of simplicity and convenience, and is especially suitable for the study of remaining oil distribution at high water-cut stage. The distribution of remaining oil presented banding and potato form, remaining oil was relatively concentrated in faultage neighborhood and imperfect well netting position, and the net thickness of the place was great. This proposal can provide an effective way to forecast remaining oil distribution and enhance oil recovery, especially applied at the high water-cut stage.展开更多
ZnO/graphene oxide（ZnO/GO） composite material,in which ZnO nanoparticles were densely coated on the GO nanosheets,was successfully prepared by an improved two-step method and characterized by IR, XRD,TEM,and UV-vis ...ZnO/graphene oxide（ZnO/GO） composite material,in which ZnO nanoparticles were densely coated on the GO nanosheets,was successfully prepared by an improved two-step method and characterized by IR, XRD,TEM,and UV-vis techniques.The improved photocatalytic property of the ZnO/GO composite material,evaluated by the photocatalytic degradation of methyl orange（MO） under UV irradiation,is ascribed to the intimate contact between ZnO and GO,the enhanced adsorption of MO,the quick electron transfer from excited ZnO particles to GO sheets and the activation of MO molecules viaπ-πinteraction between MO and GO.展开更多
基金supported by the National Natural Science Foundation of China(No.11574111 and No.11974129 to X.-F.W.)“the Fundamental Research Funds for the Central Universities.”.
文摘Since their seminal discovery in 2011,two-dimensional(2D)transition metal carbides/nitrides known as MXenes,that constitute a large family of 2D materials,have been targeted toward various applications due to their outstanding electronic properties.MXenes functioning as co-catalyst in combination with certain photocatalysts have been applied in photocatalytic systems to enhance photogenerated charge separation,suppress rapid charge recombination,and convert solar energy into chemical energy or use it in the degradation of organic compounds.The photocatalytic performance greatly depends on the composition and morphology of the photocatalyst,which,in turn,are determined by the method of preparation used.Here,we review the four different synthesis methods(mechanical mixing,self-assembly,in situ decoration,and oxidation)reported for MXenes in view of their application as co-catalyst in photocatalysis.In addition,the working mechanism for MXenes application in photocatalysis is discussed and an outlook for future research is also provided.
文摘Metallogenic prognosis of synthetic information uses the geological body and the mineral resource body as a statistical unit to interpret synthetically the information of geology, geophysics, geochemistry and remote sensing from the evolution of geology and puts all the information into one entire system by drawing up digitalized interpretation maps of the synthetic information. On such basis, different grades and types of mineral resource prospecting models and predictive models of synthetic information can be established. Hence, a new integrated prediction system will be formed of metallogenic prognosis (qualitative prediction), mineral resources statistic prediction (determining targets) and mineral resources prediction (determining resources amount).
文摘One-Way Traffic synthetic assessing can not only determine the assessment method, but can also provide an opportunity for further study of road systems. Comparing three Road Traffic Planning methods, which are Value Analysis method, Simple Array method and Step Analysis method, this paper concludes that Simple Array method has one prominent merit, avoiding the complicated relationship of various factors and simplifying the complex problem. Therefore Simple Array method is firstly presented in this paper to be the assessing measure to assess the One-Way Traffic Planning project. Although this assessing method cannot wholly give way to man’s will, through consistently testing on qualitative factors and with the decision-making results of a multi-program, this method is still an effective method. Using an example of Harbin One-Way Traffic planning, with seven assessing indexes including economic benefit index, Simple Array method is applied to synthetically assessing the program. This fully reflects the general function of One-Way Traffic planning program and objectively evaluates the program. It also proves that, as the method of One-Way Traffic synthetic assessing, Simple Array method is rational and practical.
文摘An efficient and practical synthetic process for Daprodustat was developed.Starting with N,N'-dicyclohexylcarbodiimide(DCC)and malonic acid,the key intermediate 1,3-dicyclohexylpyrimidine-2,4,6(1H,3H,5H)-trione was synthesized via condensation reaction with 91%yield.Subsequent activation of this intermediate by 1,1'-carbonyldiimidazole(CDI),followed by a one-pot reaction with glycine ethyl ester hydrochloride,directly afforded Daprodustat in 92%yield with>99.8%HPLC purity.The process achieved an overall yield of 84%upon validation at 62-gram scale.Structural confirmation of the key intermediate was accomplished through nuclear magnetic resonance(NMR)spectroscopy and high-resolution mass spectrometry(HRMS).Compared with existing methods,this streamlined protocol demonstrates advantages including simplified operation,reduced reaction time,and lower production costs,offering significant potential for industrial-scale synthesis of Daprodustat.
基金supported by the National Natural Science Foundation of China(No.92252201)the Fundamental Research Funds for the Central Universitiesthe Academic Excellence Foundation of Beihang University(BUAA)for PhD Students。
文摘Efficient and accurate simulation of unsteady flow presents a significant challenge that needs to be overcome in computational fluid dynamics.Temporal discretization method plays a crucial role in the simulation of unsteady flows.To enhance computational efficiency,we propose the Implicit-Explicit Two-Step Runge-Kutta(IMEX-TSRK)time-stepping discretization methods for unsteady flows,and develop a novel adaptive algorithm that correctly partitions spatial regions to apply implicit or explicit methods.The novel adaptive IMEX-TSRK schemes effectively handle the numerical stiffness of the small grid size and improve computational efficiency.Compared to implicit and explicit Runge-Kutta(RK)schemes,the IMEX-TSRK methods achieve the same order of accuracy with fewer first derivative calculations.Numerical case tests demonstrate that the IMEX-TSRK methods maintain numerical stability while enhancing computational efficiency.Specifically,in high Reynolds number flows,the computational efficiency of the IMEX-TSRK methods surpasses that of explicit RK schemes by more than one order of magnitude,and that of implicit RK schemes several times over.
文摘On-line measurement for dielectric loss angle can effectively monitor the insulation condition of capacitive equipment in power systems. Synthetic relative measuring methods not only markedly overcome the shortcomings of traditional absolute measuring methods but also greatly improve the accuracy of dielectric loss angle measurement. However, synthetic relative measuring methods based on two or three pieces of capacitive equipment do not have the characteristic of generality. In this paper, a principle of synthetic relative measuring method is presented. The example of application for synthetic relative methods based on three and four pieces of capacitive equipment running in the same phase is taken to present the failure judgment matrices for N pieces of equipment. According to these matrices, the fault condition of N pieces of capacitive equipment can be watched, which is more general. Then some problems needing to be concerned along with two diagnostic methods used in diagnostic system are introduced. Finally, two programmable flow charts for the two methods are given and corresponding examples demonstrate their feasibility in practice.
基金The Doctoral Program of Higher Educa-tion Institution of China (No.20050487017)
文摘The index system, code system, and weights of indexes are established to assess the effects of green construction. The index system consists of index level, factor level and sub-factor level. The analytic hierarchy process is used to determine the weights of indexes, and the consistency test indicate that the weight assignment is reasonable. Using fuzzy synthetic judgment method, the assessment model is built, which includes factor set, weight set and conclusion set. An example is given to demonstrate the assessment procedures.
文摘4,4'-Oxybis(benzoic acid)(Ⅰ)is an important monomer for making synthetic resin,heat resistant film and liquid crystal fiber,etc.It has been synthesized either by the oxidation of 4,4'-dimethyl diphenyl ether,or by the electrophilic substitution of diphenyl ether,these substituents introduced into the benzene ring can be further transformed into carboxylic groups.Diphenyl ethers are usually prepared from phenols and halobenzenes through Ullmann resction.Due to the high reaction temerature(usually above 200℃),long time heating and the formation of isomers,it is difficult to obtain pure products in high yields.
基金Project(61105020)supported by the National Natural Science Foundation of ChinaProject(13zxtk08)supported by the Key Research Platform for Research Projects of Southwest University of Science and Technology,China
文摘The accuracy of background clutter model is a key factor which determines the performance of a constant false alarm rate(CFAR) target detection method. G0 distribution is one of the optimal statistic models in the synthetic aperture radar(SAR) image background clutter modeling and can accurately model various complex background clutters in the SAR images. But the application of the distribution is greatly limited by its disadvantages that the parameter estimation is complex and the local detection threshold is difficult to be obtained. In order to solve the above-mentioned problems, an synthetic aperture radar CFAR target detection method using the logarithmic cumulant(Mo LC) + method of moment(Mo M)-based G0 distribution clutter model is proposed. In the method, G0 distribution is used for modeling the background clutters, a new Mo LC+Mo M-based parameter estimation method coupled with a fast iterative algorithm is used for estimating the parameters of G0 distribution and an exquisite dichotomy method is used for obtaining the local detection threshold of CFAR detection, which greatly improves the computational efficiency, detection performance and environmental adaptability of CFAR detection. Experimental results show that the proposed SAR CFAR target detection method has good target detection performance in various complex background clutter environments.
文摘The synthetic fuzzy assessing method is usually applied to sensory evaluation. The method has simple and reliable virtue, and it is consistent with objective evaluation results. Using this method, system status of plating solution evaporator is evaluated, and the result is applied to compensate a fuzzy controller. Experimental results have shown the correctness and the validity of the proposed approach.
文摘Dibenzoyl peroxide undergoes oxidative addition on metallic copper with triphenylphosphine in a mixed solvent(acetone,dichloromethane and trichloromethane),and affords the binuclear copper complex (Cu(C_6H_5COO)_2(OPPh_3))_2.Crystals are monoclinic,space group A_2/a,with cell parameters,a=24.337(3),b=10.566(1),c=21.579(2),β= 93.18(1)°, V=5540(1)~3,Z=4,R=0.042,and Rw=0.044 for 5872 observed reflections. Each copper ion is coordinated by four bridging benzoato ligands and one triphenylphosphine oxide group to form binuclear complexes.
文摘Based on the extraction and calculation of the short-term seismic precursory information magnitude from the 114 major precursory observations in the North China region, and together with consideration of factors such as geological structure, seismicity, crustal thickness, and in particular, the current geodynamics of the region, the authors studied the time-space evolution characteristics of the short-term earthquake precursory information magnitude and its relationship with earthquakes and proposed the index and method for the short-term synthetic prediction of earthquakes with M S≥5.0 in the North China region. The inspection through R-value shows that the method is effective to a certain extent for earthquake prediction.
文摘Compositional data, such as relative information, is a crucial aspect of machine learning and other related fields. It is typically recorded as closed data or sums to a constant, like 100%. The statistical linear model is the most used technique for identifying hidden relationships between underlying random variables of interest. However, data quality is a significant challenge in machine learning, especially when missing data is present. The linear regression model is a commonly used statistical modeling technique used in various applications to find relationships between variables of interest. When estimating linear regression parameters which are useful for things like future prediction and partial effects analysis of independent variables, maximum likelihood estimation (MLE) is the method of choice. However, many datasets contain missing observations, which can lead to costly and time-consuming data recovery. To address this issue, the expectation-maximization (EM) algorithm has been suggested as a solution for situations including missing data. The EM algorithm repeatedly finds the best estimates of parameters in statistical models that depend on variables or data that have not been observed. This is called maximum likelihood or maximum a posteriori (MAP). Using the present estimate as input, the expectation (E) step constructs a log-likelihood function. Finding the parameters that maximize the anticipated log-likelihood, as determined in the E step, is the job of the maximization (M) phase. This study looked at how well the EM algorithm worked on a made-up compositional dataset with missing observations. It used both the robust least square version and ordinary least square regression techniques. The efficacy of the EM algorithm was compared with two alternative imputation techniques, k-Nearest Neighbor (k-NN) and mean imputation (), in terms of Aitchison distances and covariance.
文摘The main objective of this study is to generate accurate synthetic hourly solar radiation data by using an easily accessible open source data.In this regard,a new approach is proposed for estimation of synthetic hourly global solar radiation during the day by utilizing only annual solar energy data.First time in literature,a model has been developed for prediction hourly and daily solar radiation based on annual solar energy parameter in this study.Parameters of the model were generated and tested for Turkey and one of them was presented as a case study within this paper.Long term measured hourly horizontal solar irradiance data from a network of Turkish meteorological stations was used to calibrate the model function.The predictions are compared with the solar data available in literature for Turkey.The advanced simple new model is utilized in open source computer program and has the potential to be adapted to other countries.
基金Supported by the National Natural Science Foundation of China(61071165)the Program for NewCentury Excellent Talents in University(NCET-09-0069)the Defense Industrial Technology Development Program(B2520110008)~~
文摘As same as the conventional inverse synthetic aperture radar（ISAR）, the compressed ISAR also requires the echo signal based motion compensation, which consists of the range alignment and the phase autofoeusing. A phase autofocusing algorithm for compressed ISAR imaging is presented. In the algorithm, phase autofocusing for the sparse ISAR echoes is accomplished using the eigenvector method. Experimental results validate the effectiveness of the algorithm.
基金supported by the national project"Deep Exploration Technology and Experimentation"(SinoProbe-09-02)
文摘In order to suppress the airwave noise in marine controlled-source electromagnetic （CSEM） data, we propose a 3D deconvolution （3DD） interferometry method with a synthetic aperture source and obtain the relative anomaly coefficient （RAC） of the EM field reflection responses to show the degree for suppressing the airwave. We analyze the potential of the proposed method for suppressing the airwave, and compare the proposed method with traditional methods in their effectiveness. A method to select synthetic source length is derived and the effect of the water depth on RAC is examined via numerical simulations. The results suggest that 3DD interferometry method with a synthetic source can effectively suppress the airwave and enhance the potential of marine CSEM to hydrocarbon exploration.
基金supported by the International Science and Technology Cooperation Program of Science and Technology Bureau of Changchun City,China(Grant No.12ZX68)
文摘Temperature-dependent photoluminescence characteristics of organic-inorganic halide perovskite CH3NH3Pb I3-xClx films prepared using a two-step method on ZnO/FTO substrates were investigated. Surface morphology and absorption characteristics of the films were also studied. Scanning electron microscopy revealed large crystals and substrate coverage. The orthorhombic-to-tetragonal phase transition temperature was-140 K. The films＇ exciton binding energy was 77.6 ± 10.9 meV and the energy of optical phonons was 38.8 ± 2.5 meV. These results suggest that perovskite CH3NH3Pb I（3-x）Clx films have excellent optoelectronic characteristics which further suggests their potential usage in perovskitebased optoelectronic devices.
基金The National Natural Science Foundation of China under contract No.61471024the National Marine Technology Program for Public Welfare under contract No.201505002-1the Beijing Higher Education Young Elite Teacher Project under contract No.YETP0514
文摘To dates,most ship detection approaches for single-pol synthetic aperture radar（SAR） imagery try to ensure a constant false-alarm rate（CFAR）.A high performance ship detector relies on two key components：an accurate estimation to a sea surface distribution and a fine designed CFAR algorithm.First,a novel nonparametric sea surface distribution estimation method is developed based on n-order Bézier curve.To estimate the sea surface distribution using n-order Bézier curve,an explicit analytical solution is derived based on a least square optimization,and the optimal selection also is presented to two essential parameters,the order n of Bézier curve and the number m of sample points.Next,to validate the ship detection performance of the estimated sea surface distribution,the estimated sea surface distribution by n-order Bézier curve is combined with a cell averaging CFAR（CA-CFAR）.To eliminate the possible interfering ship targets in background window,an improved automatic censoring method is applied.Comprehensive experiments prove that in terms of sea surface estimation performance,the proposed method is as good as a traditional nonparametric Parzen window kernel method,and in most cases,outperforms two widely used parametric methods,K and G0 models.In terms of computation speed,a major advantage of the proposed estimation method is the time consuming only depended on the number m of sample points while independent of imagery size,which makes it can achieve a significant speed improvement to the Parzen window kernel method,and in some cases,it is even faster than two parametric methods.In terms of ship detection performance,the experiments show that the ship detector which constructed by the proposed sea surface distribution model and the given CA-CFAR algorithm has wide adaptability to different SAR sensors,resolutions and sea surface homogeneities and obtains a leading performance on the test dataset.
文摘The distribution of remaining oil is often described qualitatively. The remaining oil distributed in the whole reservoir is calculated according to the characteristics of the space distribution of the saturation of remaining oil. Logging data are required to accomplish this. However, many such projects cannot be completed. Since the old study of remaining oil distribution could not be quantified efficiently, the ＂dynamic two-step method＂ is presented. Firstly, the water cut of every flow unit in one well at one time is calculated according to the comprehensive water cut of a single well at one time. Secondly, the remaining oil saturation of the flow unit of the well at one time is calculated based on the water cut of the flow unit at a given time. The results show that ＂dynamic two-step method＂ has characteristics of simplicity and convenience, and is especially suitable for the study of remaining oil distribution at high water-cut stage. The distribution of remaining oil presented banding and potato form, remaining oil was relatively concentrated in faultage neighborhood and imperfect well netting position, and the net thickness of the place was great. This proposal can provide an effective way to forecast remaining oil distribution and enhance oil recovery, especially applied at the high water-cut stage.
基金supported by the Natural Science Foundation of China(No.21174114)the Ministry of Education Plan for Yangtze River Scholar and Innovation Team Development(No.IRT1177)+2 种基金Scientific and Technical Plan Project of Gansu Province(No. 1204GKCA006)the Natural Science Foundation of Gansu Province (No.1010RJZA024)Scientific and Technical Innovation Project of Northwest Normal University(No.nwnu-kjcxgc-03-63)
文摘ZnO/graphene oxide（ZnO/GO） composite material,in which ZnO nanoparticles were densely coated on the GO nanosheets,was successfully prepared by an improved two-step method and characterized by IR, XRD,TEM,and UV-vis techniques.The improved photocatalytic property of the ZnO/GO composite material,evaluated by the photocatalytic degradation of methyl orange（MO） under UV irradiation,is ascribed to the intimate contact between ZnO and GO,the enhanced adsorption of MO,the quick electron transfer from excited ZnO particles to GO sheets and the activation of MO molecules viaπ-πinteraction between MO and GO.
