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Temperature-dependent photoluminescence on organic inorganic metal halide perovskite CH_3NH_3Pb I_(3-)Cl_ prepared on ZnO/FTO substrates using a two-step method 被引量:4
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作者 Shiwei Zhuang Deqian Xu +6 位作者 Jiaxin Xu Bin Wu Yuantao Zhang Xin Dong Guoxing Li Baolin Zhang Guotong Du 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第1期482-487,共6页
Temperature-dependent photoluminescence characteristics of organic-inorganic halide perovskite CH3NH3Pb I3-xClx films prepared using a two-step method on ZnO/FTO substrates were investigated. Surface morphology and ab... Temperature-dependent photoluminescence characteristics of organic-inorganic halide perovskite CH3NH3Pb I3-xClx films prepared using a two-step method on ZnO/FTO substrates were investigated. Surface morphology and absorption characteristics of the films were also studied. Scanning electron microscopy revealed large crystals and substrate coverage. The orthorhombic-to-tetragonal phase transition temperature was-140 K. The films' exciton binding energy was 77.6 ± 10.9 meV and the energy of optical phonons was 38.8 ± 2.5 meV. These results suggest that perovskite CH3NH3Pb I(3-x)Clx films have excellent optoelectronic characteristics which further suggests their potential usage in perovskitebased optoelectronic devices. 展开更多
关键词 PEROVSKITE temperature-dependent photoluminescence two-step method ZNO
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Applying the Dynamic Two-Step Method to Forecast Remaining Oil Distribution of Lower Series ,Xiaermen Oilfield 被引量:2
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作者 周红 汤传意 李增辉 《Journal of China University of Geosciences》 SCIE CSCD 2006年第1期65-70,共6页
The distribution of remaining oil is often described qualitatively. The remaining oil distributed in the whole reservoir is calculated according to the characteristics of the space distribution of the saturation of re... The distribution of remaining oil is often described qualitatively. The remaining oil distributed in the whole reservoir is calculated according to the characteristics of the space distribution of the saturation of remaining oil. Logging data are required to accomplish this. However, many such projects cannot be completed. Since the old study of remaining oil distribution could not be quantified efficiently, the "dynamic two-step method" is presented. Firstly, the water cut of every flow unit in one well at one time is calculated according to the comprehensive water cut of a single well at one time. Secondly, the remaining oil saturation of the flow unit of the well at one time is calculated based on the water cut of the flow unit at a given time. The results show that "dynamic two-step method" has characteristics of simplicity and convenience, and is especially suitable for the study of remaining oil distribution at high water-cut stage. The distribution of remaining oil presented banding and potato form, remaining oil was relatively concentrated in faultage neighborhood and imperfect well netting position, and the net thickness of the place was great. This proposal can provide an effective way to forecast remaining oil distribution and enhance oil recovery, especially applied at the high water-cut stage. 展开更多
关键词 dynamic two-step method flow unit quantitative forecast remaining oil
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Preparation of ZnO/GO composite material with highly photocatalytic performance via an improved two-step method 被引量:4
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作者 Ya-Li Chen Chun-E.Zhang +3 位作者 Chao Deng Peng Fei Ming Zhong Bi-Tao Su 《Chinese Chemical Letters》 SCIE CAS CSCD 2013年第6期518-520,共3页
ZnO/graphene oxide(ZnO/GO) composite material,in which ZnO nanoparticles were densely coated on the GO nanosheets,was successfully prepared by an improved two-step method and characterized by IR, XRD,TEM,and UV-vis ... ZnO/graphene oxide(ZnO/GO) composite material,in which ZnO nanoparticles were densely coated on the GO nanosheets,was successfully prepared by an improved two-step method and characterized by IR, XRD,TEM,and UV-vis techniques.The improved photocatalytic property of the ZnO/GO composite material,evaluated by the photocatalytic degradation of methyl orange(MO) under UV irradiation,is ascribed to the intimate contact between ZnO and GO,the enhanced adsorption of MO,the quick electron transfer from excited ZnO particles to GO sheets and the activation of MO molecules viaπ-πinteraction between MO and GO. 展开更多
关键词 ZnO/GO composite material Improved two-step method Characterization Enhanced adsorptive and photocatalytic property
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Effects of Ni doping contents on photocatalytic activity of B-BiVO_4 synthesized through sol-gel and impregnation two-step method 被引量:10
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作者 Min WANG Guang-jun YANG +4 位作者 Mei-yan YOU Yuan-hua XIE You-zhao WANG Jin HAN Tong ZHU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2017年第9期2022-2030,共9页
To enhance the photocatalytic activity of B-BiVO4,Ni-doped B?BiVO4photocatalyst(Ni-B-BiVO4)was synthesized through sol-gel and impregnation method.The photocatalysts were characterized by XPS,XRD,SEM,EDS,BET and UV-Vi... To enhance the photocatalytic activity of B-BiVO4,Ni-doped B?BiVO4photocatalyst(Ni-B-BiVO4)was synthesized through sol-gel and impregnation method.The photocatalysts were characterized by XPS,XRD,SEM,EDS,BET and UV-Vis DRS techniques.The results showed that single or double doping did not change the crystalline structure and morphology,but the particle size decreased with Ni doping.The band gap energy absorption edge of Ni-B-BiVO4shifted to a longer wavelength compared with undoped,B or Ni single doped BiVO4.More V4+and surface hydroxyl oxygen were observed in BiVO4after Ni-B co-doping.When the optimal mass fraction of Ni is0.30%,the degradation rate of MO in50min is95%for0.3Ni-B-BiVO4sample which also can effectively degrade methyl blue(MB),acid orange(AOII)II and rhodamine B(RhB).The enhanced photocatalytic activity is attributed to the synergistic effects of B and Ni doping. 展开更多
关键词 CO-DOPING Ni doping BIVO4 PHOTOCATALYST sol.gel method impregnation method
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Ag-doped ZnO nanorods synthesized by two-step method
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作者 陈先梅 冀勇 +1 位作者 郜小勇 赵显伟 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第11期373-377,共5页
A two-step method is adopted to synthesize Ag-doped ZnO nanorods. A ZnO seed layer is first prepared on a glass substrate by thermal decomposition of zinc acetate. Ag-doped ZnO nanorods are then assembled on the ZnO s... A two-step method is adopted to synthesize Ag-doped ZnO nanorods. A ZnO seed layer is first prepared on a glass substrate by thermal decomposition of zinc acetate. Ag-doped ZnO nanorods are then assembled on the ZnO seed layer using the hydrothermal method. The influences of the molar percentage of Ag ions to Zn ions (RAg/zn) on the structural and optical properties of the ZnO nanorods obtained are carefully studied using X-ray diffractometry, scanning electron microscopy and spectrophotometry. Results indicate that Ag ions enter into the crystal lattice through the substitution of Zn ions. The (002) c-axis-preferred orientation of the ZnO nanorods decreases as RAg/Zn increases. At RAg/Zn 〉 1.0%, ZnO nanorods lose their c-axis-preferred orientation and generate Ag precipitates from the ZnO crystal lattice. The average transmissivity in the visible region first increases and then decreases as RAg/Zn increases. The absorption edge is first blue shifted and then red shifted. The influence of Ag doping on the average head face, and axial dimensions of the ZnO nanorods may be optimized to improve the average transmissivity at RAg/Zn 〈 1.0%. 展开更多
关键词 ZnO nanorods Ag doping thermal decomposition of zinc acetate hydrothermal method
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Novel adaptive IMEX two-step Runge-Kutta temporal discretization methods for unsteady flows
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作者 Xueyu QIN Jian YU +2 位作者 Xin ZHANG Zhenhua JIANG Chao YAN 《Chinese Journal of Aeronautics》 2025年第8期142-153,共12页
Efficient and accurate simulation of unsteady flow presents a significant challenge that needs to be overcome in computational fluid dynamics.Temporal discretization method plays a crucial role in the simulation of un... Efficient and accurate simulation of unsteady flow presents a significant challenge that needs to be overcome in computational fluid dynamics.Temporal discretization method plays a crucial role in the simulation of unsteady flows.To enhance computational efficiency,we propose the Implicit-Explicit Two-Step Runge-Kutta(IMEX-TSRK)time-stepping discretization methods for unsteady flows,and develop a novel adaptive algorithm that correctly partitions spatial regions to apply implicit or explicit methods.The novel adaptive IMEX-TSRK schemes effectively handle the numerical stiffness of the small grid size and improve computational efficiency.Compared to implicit and explicit Runge-Kutta(RK)schemes,the IMEX-TSRK methods achieve the same order of accuracy with fewer first derivative calculations.Numerical case tests demonstrate that the IMEX-TSRK methods maintain numerical stability while enhancing computational efficiency.Specifically,in high Reynolds number flows,the computational efficiency of the IMEX-TSRK methods surpasses that of explicit RK schemes by more than one order of magnitude,and that of implicit RK schemes several times over. 展开更多
关键词 Implicit-explicit temporal methods two-step Runge-Kutta methods Adaptive algorithm Unsteady flows Navier-Stokes equations
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A New Inversion-free Iterative Method for Solving the Nonlinear Matrix Equation and Its Application in Optimal Control
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作者 GAO Xiangyu XIE Weiwei ZHANG Lina 《应用数学》 北大核心 2026年第1期143-150,共8页
In this paper,we consider the maximal positive definite solution of the nonlinear matrix equation.By using the idea of Algorithm 2.1 in ZHANG(2013),a new inversion-free method with a stepsize parameter is proposed to ... In this paper,we consider the maximal positive definite solution of the nonlinear matrix equation.By using the idea of Algorithm 2.1 in ZHANG(2013),a new inversion-free method with a stepsize parameter is proposed to obtain the maximal positive definite solution of nonlinear matrix equation X+A^(*)X|^(-α)A=Q with the case 0<α≤1.Based on this method,a new iterative algorithm is developed,and its convergence proof is given.Finally,two numerical examples are provided to show the effectiveness of the proposed method. 展开更多
关键词 Nonlinear matrix equation Maximal positive definite solution Inversion-free iterative method Optimal control
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Centralized Circumcentered-Reection Method for Solving the Convex Feasibility Problem in Sparse Signal Recovery
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作者 Chunmei LI Bangjun CHEN Xuefeng DUAN 《Journal of Mathematical Research with Applications》 2026年第1期119-133,共15页
Convex feasibility problems are widely used in image reconstruction,sparse signal recovery,and other areas.This paper is devoted to considering a class of convex feasibility problem arising from sparse signal recovery... Convex feasibility problems are widely used in image reconstruction,sparse signal recovery,and other areas.This paper is devoted to considering a class of convex feasibility problem arising from sparse signal recovery.We rst derive the projection formulas for a vector onto the feasible sets.The centralized circumcentered-reection method is designed to solve the convex feasibility problem.Some numerical experiments demonstrate the feasibility and e ectiveness of the proposed algorithm,showing superior performance compared to conventional alternating projection methods. 展开更多
关键词 convex feasibility problem centralized circumcentered-re ection method sparse signal recovery compressed sensing
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Numerical Simulation of the Welding Deformation of Marine Thin Plates Based on a Temperature Gradient-thermal Strain Method
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作者 Lin Wang Yugang Miao +3 位作者 Zhenjian Zhuo Chunxiang Lin Benshun Zhang Duanfeng Han 《哈尔滨工程大学学报(英文版)》 2026年第1期122-135,共14页
Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The t... Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The traditional thermal elastic-plastic finite element method(TEP-FEM)can accurately predict welding deformation.However,its efficiency is low because of the complex nonlinear transient computation,making it difficult to meet the needs of rapid engineering evaluation.To address this challenge,this study proposes an efficient prediction method for welding deformation in marine thin plate butt welds.This method is based on the coupled temperature gradient-thermal strain method(TG-TSM)that integrates inherent strain theory with a shell element finite element model.The proposed method first extracts the distribution pattern and characteristic value of welding-induced inherent strain through TEP-FEM analysis.This strain is then converted into the equivalent thermal load applied to the shell element model for rapid computation.The proposed method-particularly,the gradual temperature gradient-thermal strain method(GTG-TSM)-achieved improved computational efficiency and consistent precision.Furthermore,the proposed method required much less computation time than the traditional TEP-FEM.Thus,this study lays the foundation for future prediction of welding deformation in more complex marine thin plates. 展开更多
关键词 Marine thin plate Welding deformation Numerical simulation Temperature gradient-thermal strain method Shell element
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A two-step method for estimating high-dimensional Gaussian graphical models
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作者 Yuehan Yang Ji Zhu 《Science China Mathematics》 SCIE CSCD 2020年第6期1203-1218,共16页
The problem of estimating high-dimensional Gaussian graphical models has gained much attention in recent years. Most existing methods can be considered as one-step approaches, being either regression-based or likeliho... The problem of estimating high-dimensional Gaussian graphical models has gained much attention in recent years. Most existing methods can be considered as one-step approaches, being either regression-based or likelihood-based. In this paper, we propose a two-step method for estimating the high-dimensional Gaussian graphical model. Specifically, the first step serves as a screening step, in which many entries of the concentration matrix are identified as zeros and thus removed from further consideration. Then in the second step, we focus on the remaining entries of the concentration matrix and perform selection and estimation for nonzero entries of the concentration matrix. Since the dimension of the parameter space is effectively reduced by the screening step,the estimation accuracy of the estimated concentration matrix can be potentially improved. We show that the proposed method enjoys desirable asymptotic properties. Numerical comparisons of the proposed method with several existing methods indicate that the proposed method works well. We also apply the proposed method to a breast cancer microarray data set and obtain some biologically meaningful results. 展开更多
关键词 covariance estimation graphical model penalized likelihood sparse regression two-step method
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A Two-Step Modulus-Based Matrix Splitting Iteration Method Without Auxiliary Variables for Solving Vertical Linear Complementarity Problems 被引量:1
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作者 Hua Zheng Xiaoping Lu Seakweng Vong 《Communications on Applied Mathematics and Computation》 2024年第4期2475-2492,共18页
In this paper,a two-step iteration method is established which can be viewed as a generalization of the existing modulus-based methods for vertical linear complementarity problems given by He and Vong(Appl.Math.Lett.1... In this paper,a two-step iteration method is established which can be viewed as a generalization of the existing modulus-based methods for vertical linear complementarity problems given by He and Vong(Appl.Math.Lett.134:108344,2022).The convergence analysis of the proposed method is established,which can improve the existing results.Numerical examples show that the proposed method is efficient with the two-step technique. 展开更多
关键词 Vertical linear complementarity problem Modulus-based matrix splitting two-step method
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Cryopreservation of Gametophytes of Laminaria japonica (Phaeophyta) Using Encapsulation-Dehydration with Two-Step Cooling Method 被引量:10
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作者 ZHANG Quansheng CONG Yizhou +2 位作者 QU Shancun LUO Shiju YANG Guanpin 《Journal of Ocean University of China》 SCIE CAS 2008年第1期65-71,共7页
Gametophytes of Laminaria japonica were cryopreserved in liquid nitrogen using encapsulation-dehydration with two-step cooling method. Gametophytes cultured at 10℃ and under continuous irradiance of 30 μmol m^-2 s^-... Gametophytes of Laminaria japonica were cryopreserved in liquid nitrogen using encapsulation-dehydration with two-step cooling method. Gametophytes cultured at 10℃ and under continuous irradiance of 30 μmol m^-2 s^-1 for 3 weeks were encapsulated in calcium alginate beads. The beads were dehydrated in 0.4 molLl sucrose prepared with seawater for 6 h, desiccated in an incubator set at 10℃ and 70% relative humidity for 4 h, pre-frozen at either -40℃ or -60℃ for 30 min, and stored in liquid nitrogen for 〉24 h. As high as 43% of survival rate was observed when gametophytes were thawed by placing the beads in 40℃ seawater and re-hydrated in 0.05 molL^-1 citrate sodium prepared using 30‰ NaCl 7 d later. More cells of male gametophytes survived the whole procedure in comparison with female gametophytes. The cells of gametophytes surviving the preservation were able to grow asexually and produce morphologically normal sporophytes. 展开更多
关键词 Laminaria japonica gametophyte encapsulation-dehydration with two-step cooling CRYOPRESERVATION
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Influence of two-step cooling method on magnetic properties of Fe_(82)Mo_7B_(10)Cu_1 nanocrystalline alloy 被引量:1
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作者 彭坤 周灵平 +2 位作者 胡爱平 朱家俊 李德意 《中国有色金属学会会刊:英文版》 EI CSCD 2008年第4期852-856,共5页
Soft magnetic properties of Fe82Mo7B10Cu1 nanocrystalline alloy were studied as a function of cooling condition. The results show that higher permeability and relaxation frequency can be obtained by the two-step cooli... Soft magnetic properties of Fe82Mo7B10Cu1 nanocrystalline alloy were studied as a function of cooling condition. The results show that higher permeability and relaxation frequency can be obtained by the two-step cooling method, and the pinning field of the sample obtained by this method is smaller than that of the furnace-cooled and water-quenched samples. This phenomenon was interpreted in terms of internal stress and the magnetic ordering of the residual amorphous phase. The two-step cooling treatment is an effective way to improve the soft magnetic properties of Fe82Mo7B10Cu1 nanocrystalline alloy. 展开更多
关键词 纳米晶合金 两步冷却法 磁性 铁钼硼铜合金
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A simulation study comparing the Texas two-step and the multistage consecutive fracturing method 被引量:3
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作者 Wan Cheng Guo-Sheng Jiang +3 位作者 Jing-Yu Xie Zi-Jun Wei Zhi-Dong Zhou Xiao-Dong Li 《Petroleum Science》 SCIE CAS CSCD 2019年第5期1121-1133,共13页
Multistage hydraulic fracturing in horizontal wells is a critical technique for developing unconventional oil and gas resources.Stress interactions among neighboring fractures cause immature fracture development.The T... Multistage hydraulic fracturing in horizontal wells is a critical technique for developing unconventional oil and gas resources.Stress interactions among neighboring fractures cause immature fracture development.The Texas two-step fracturing(TTSF)method is a new technique that aims to enhance fracture complexity and conductivity.This paper compares the fracture development of consecutive fracturing and the TTSF.The fracturing sequence in the multistage fracturing method has a significant effect on the fracture length,fracture width and injection pres sure.The consecutive fracturing results in relatively uneven fracture length and width.Certain fractures in consecutive fracturing are restrained to be closed due to the strong stress shadowing effect.In contrast,TTSF has considerable potential for alleviating the negative effects of stress interactions and producing a larger stimulated reservoir volume. 展开更多
关键词 Horizontal well Consecutive fracturing Texas two-step fracturing Hydraulic fracturing
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A two-step unconditionally stable explicit method with controllable numerical dissipations 被引量:2
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作者 Li Jinze Yu Kaiping Li Xiangyang 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2019年第2期285-299,共15页
A family of unconditionally stable direct integration algorithm with controllable numerical dissipations is proposed. The numerical properties of the new algorithms are controlled by three parameters α, β and γ. By... A family of unconditionally stable direct integration algorithm with controllable numerical dissipations is proposed. The numerical properties of the new algorithms are controlled by three parameters α, β and γ. By the consistent and stability analysis, the proposed algorithms achieve the second-order accuracy and are unconditionally stable under the condition that α≥-0.5, β≤ 0.5 and γ≥-(1+α)/2. Compared with other unconditionally stable algorithms, such as Chang's algorithms and CR algorithm, the proposed algorithms are found to be superior in terms of the controllable numerical damping ratios. The unconditional stability and numerical damping ratios of the proposed algorithms are examined by three numerical examples. The results demonstrate that the proposed algorithms have a superior performance and can be used expediently in solving linear elastic dynamics problems. 展开更多
关键词 DIRECT INTEGRATION method unconditional STABILITY NUMERICAL DISSIPATION dynamic analysis
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Synthesis and thermal characterization of the C-S-H/paraffin composite phase change material utilizing a discontinuous two-step nucleation method 被引量:1
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作者 Shen Xuyan Feng Pan Zhang Qi 《Journal of Southeast University(English Edition)》 EI CAS 2024年第4期327-335,共9页
The novel calcium-silicate-hydrate(C-S-H)/paraffin composite phase change materials were synthesized using a discontinuous two-step nucleation method.Initially,the C-S-H precursor is separated and dried,followed by im... The novel calcium-silicate-hydrate(C-S-H)/paraffin composite phase change materials were synthesized using a discontinuous two-step nucleation method.Initially,the C-S-H precursor is separated and dried,followed by immersion in an aqueous environment to transform it into C-S-H.This two-step nucleation approach results in C-S-H with a specific surface area of 497.2 m^(2)/g,achieved by preventing C-S-H foil overlapping and refining its pore structure.When impregnated with paraffin,the novel C-S-H/paraffin composite exhibits superior thermal properties,such as a higher potential heat value of 148.3 J/g and an encapsulation efficiency of 81.6%,outperforming conventional C-S-H.Moreover,the composite material demonstrates excellent cyclic performance,indicating its potential for building thermal storage compared to other paraffin-based composites.Compared with the conventional method,this simple technology,which only adds conversion and centrifugation steps,does not negatively impact preparation costs,the environment,and resource consumption.This study provides valuable theoretical insights for designing thermal storage concrete materials and advancing building heat management. 展开更多
关键词 two-step nucleation C-S-H PARAFFIN phase change materials composite building thermal management
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Preparation of Bi_2Sr_2Ca_2Cu_3O_y superconductors by two-step method and its chemical kinetic study
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作者 汪浩 高孝恢 《Chinese Science Bulletin》 SCIE EI CAS 1995年第2期128-132,共5页
It is well known that in the Bi-series superconductors, low temperature phases, such as 2201, 2212 phases, always coexist with 2223 phase to some extent, which makes it difficult to prepare high-T_c 2223 phase samples... It is well known that in the Bi-series superconductors, low temperature phases, such as 2201, 2212 phases, always coexist with 2223 phase to some extent, which makes it difficult to prepare high-T_c 2223 phase samples. Doping of Pb and F can help the forming of 2223 phase and the superconductors with zero resistance temperature 107 K and 118 K can be obtained. But so far most experimental results have pointed out that it is difficult to 展开更多
关键词 PREPARATION of Bi2Sr2Ca2Cu3Oy by two-step method the content of 2223 phase (84%) CHEMICAL kinetic study.
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The convergence ball and error analysis of the two-step Secant method
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作者 LIN Rong-fei WU Qing-biao +2 位作者 CHEN Min-hong KHAN Yasir LIU Lu 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2017年第4期397-406,共10页
Under the assumption that the nonlinear operator has Lipschitz continuous divided differences for the first order,we obtain an estimate of the radius of the convergence ball for the two-step secant method.Moreover,we ... Under the assumption that the nonlinear operator has Lipschitz continuous divided differences for the first order,we obtain an estimate of the radius of the convergence ball for the two-step secant method.Moreover,we also provide an error estimate that matches the convergence order of the two-step secant method.At last,we give an application of the proposed theorem. 展开更多
关键词 two-step secant method estimate of radius convergence ball Lipschitz continuous
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Two-Step Hybrid Block Method for Solving Nonlinear Jerk Equations 被引量:1
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作者 Bothayna S. H. Kashkari Sadeem Alqarni 《Journal of Applied Mathematics and Physics》 2019年第8期1893-1910,共18页
In this paper, a block method with one hybrid point for solving Jerk equations is presented. The hybrid point is chosen to optimize the local truncation errors of the main formulas for the solution and the derivative ... In this paper, a block method with one hybrid point for solving Jerk equations is presented. The hybrid point is chosen to optimize the local truncation errors of the main formulas for the solution and the derivative at the end of the block. Analysis of the method is discussed, and some numerical examples show that the proposed method is efficient and accurate. 展开更多
关键词 NONLINEAR JERK EQUATIONS HYBRID Block method Zero Stable Consistent CONVERGENT
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Ascorbic acid-induced porous iodide layer for a high-purity two-step solution-processed tin-lead mixed perovskite photodetector 被引量:2
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作者 Liansong Liu Fengren Cao +3 位作者 Liukang Bian Meng Wang Haoxuan Sun Liang Li 《Journal of Materials Science & Technology》 2025年第7期227-232,共6页
Tin(Sn)-lead(Pb)mixed halide perovskites have attracted widespread interest due to their wider re-sponse wavelength and lower toxicity than lead halide perovskites,Among the preparation methods,the two-step method mor... Tin(Sn)-lead(Pb)mixed halide perovskites have attracted widespread interest due to their wider re-sponse wavelength and lower toxicity than lead halide perovskites,Among the preparation methods,the two-step method more easily controls the crystallization rate and is suitable for preparing large-area per-ovskite devices.However,the residual low-conductivity iodide layer in the two-step method can affect carrier transport and device stability,and the different crystallization rates of Sn-and Pb-based per-ovskites may result in poor film quality.Therefore,Sn-Pb mixed perovskites are mainly prepared by a one-step method.Herein,a MAPb_(0.5)Sn_(0.5)I_(3)-based self-powered photodetector without a hole transport layer is fabricated by a two-step method.By adjusting the concentration of the ascorbic acid(AA)addi-tive,the final perovskite film exhibited a pure phase without residues,and the optimal device exhibited a high responsivity(0.276 A W^(-1)),large specific detectivity(2.38×10^(12) Jones),and enhanced stability.This enhancement is mainly attributed to the inhibition of Sn2+oxidation,the control of crystal growth,and the sufficient reaction between organic ammonium salts and bottom halides due to the AA-induced pore structure. 展开更多
关键词 PEROVSKITE SN-PB PHOTODETECTOR two-step solution method
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