Efficient and accurate simulation of unsteady flow presents a significant challenge that needs to be overcome in computational fluid dynamics.Temporal discretization method plays a crucial role in the simulation of un...Efficient and accurate simulation of unsteady flow presents a significant challenge that needs to be overcome in computational fluid dynamics.Temporal discretization method plays a crucial role in the simulation of unsteady flows.To enhance computational efficiency,we propose the Implicit-Explicit Two-Step Runge-Kutta(IMEX-TSRK)time-stepping discretization methods for unsteady flows,and develop a novel adaptive algorithm that correctly partitions spatial regions to apply implicit or explicit methods.The novel adaptive IMEX-TSRK schemes effectively handle the numerical stiffness of the small grid size and improve computational efficiency.Compared to implicit and explicit Runge-Kutta(RK)schemes,the IMEX-TSRK methods achieve the same order of accuracy with fewer first derivative calculations.Numerical case tests demonstrate that the IMEX-TSRK methods maintain numerical stability while enhancing computational efficiency.Specifically,in high Reynolds number flows,the computational efficiency of the IMEX-TSRK methods surpasses that of explicit RK schemes by more than one order of magnitude,and that of implicit RK schemes several times over.展开更多
In this paper,a two-step iteration method is established which can be viewed as a generalization of the existing modulus-based methods for vertical linear complementarity problems given by He and Vong(Appl.Math.Lett.1...In this paper,a two-step iteration method is established which can be viewed as a generalization of the existing modulus-based methods for vertical linear complementarity problems given by He and Vong(Appl.Math.Lett.134:108344,2022).The convergence analysis of the proposed method is established,which can improve the existing results.Numerical examples show that the proposed method is efficient with the two-step technique.展开更多
Tin(Sn)-lead(Pb)mixed halide perovskites have attracted widespread interest due to their wider re-sponse wavelength and lower toxicity than lead halide perovskites,Among the preparation methods,the two-step method mor...Tin(Sn)-lead(Pb)mixed halide perovskites have attracted widespread interest due to their wider re-sponse wavelength and lower toxicity than lead halide perovskites,Among the preparation methods,the two-step method more easily controls the crystallization rate and is suitable for preparing large-area per-ovskite devices.However,the residual low-conductivity iodide layer in the two-step method can affect carrier transport and device stability,and the different crystallization rates of Sn-and Pb-based per-ovskites may result in poor film quality.Therefore,Sn-Pb mixed perovskites are mainly prepared by a one-step method.Herein,a MAPb_(0.5)Sn_(0.5)I_(3)-based self-powered photodetector without a hole transport layer is fabricated by a two-step method.By adjusting the concentration of the ascorbic acid(AA)addi-tive,the final perovskite film exhibited a pure phase without residues,and the optimal device exhibited a high responsivity(0.276 A W^(-1)),large specific detectivity(2.38×10^(12) Jones),and enhanced stability.This enhancement is mainly attributed to the inhibition of Sn2+oxidation,the control of crystal growth,and the sufficient reaction between organic ammonium salts and bottom halides due to the AA-induced pore structure.展开更多
The urgent demand for clean energy solutions has intensified the search for advanced storage materials,with rechargeable alkali-ion batteries(AIBs)playing a pivotal role in electrochemical energy storage.Enhancing ele...The urgent demand for clean energy solutions has intensified the search for advanced storage materials,with rechargeable alkali-ion batteries(AIBs)playing a pivotal role in electrochemical energy storage.Enhancing electrode performance is critical to addressing the increasing need for high-energy and high-power AIBs.Next-generation anode materials face significant challenges,including limited energy storage capacities and complex reaction mechanisms that complicate structural modeling.Sn-based materials have emerged as promising candidates for AIBs due to their inherent advantages.Recent research has increasingly focused on the development of heterojunctions as a strategy to enhance the performance of Sn-based anode materials.Despite significant advances in this field,comprehensive reviews summarizing the latest developments are still sparse.This review provides a detailed overview of recent progress in Sn-based heterojunction-type anode materials.It begins with an explanation of the concept of heterojunctions,including their fabrication,characterization,and classification.Cutting-edge research on Sn-based heterojunction-type anodes for AIBs is highlighted.Finally,the review summarizes the latest advancements in heterojunction technology and discusses future directions for research and development in this area.展开更多
Rechargeable aqueous Zn-ion batteries(AZIBs)are one of the most promising energy storage devices for large-scale energy storage owing to their high specific capacity,eco-friendliness,low cost and high safety.Neverthel...Rechargeable aqueous Zn-ion batteries(AZIBs)are one of the most promising energy storage devices for large-scale energy storage owing to their high specific capacity,eco-friendliness,low cost and high safety.Nevertheless,zinc metal anodes suffer from severe dendrite growth and side reactions,resulting in the inferior electrochemical performance of AZIBs.To address these problems,surface modification of zinc metal anodes is a facile and effective method to regulate the interaction between the zinc anode and an electrolyte.In this review,the current challenges and strategies for zinc metal anodes are presented.Furthermore,recent advances in surface modification strategies to improve their electrochemical performance are concluded and discussed.Finally,challenges and prospects for future development of zinc metal anodes are proposed.We hope this review will be useful for designing and fabricating highperformance AZIBs and boosting their practical applications.展开更多
Temperature-dependent photoluminescence characteristics of organic-inorganic halide perovskite CH3NH3Pb I3-xClx films prepared using a two-step method on ZnO/FTO substrates were investigated. Surface morphology and ab...Temperature-dependent photoluminescence characteristics of organic-inorganic halide perovskite CH3NH3Pb I3-xClx films prepared using a two-step method on ZnO/FTO substrates were investigated. Surface morphology and absorption characteristics of the films were also studied. Scanning electron microscopy revealed large crystals and substrate coverage. The orthorhombic-to-tetragonal phase transition temperature was-140 K. The films＇ exciton binding energy was 77.6 ± 10.9 meV and the energy of optical phonons was 38.8 ± 2.5 meV. These results suggest that perovskite CH3NH3Pb I（3-x）Clx films have excellent optoelectronic characteristics which further suggests their potential usage in perovskitebased optoelectronic devices.展开更多
The distribution of remaining oil is often described qualitatively. The remaining oil distributed in the whole reservoir is calculated according to the characteristics of the space distribution of the saturation of re...The distribution of remaining oil is often described qualitatively. The remaining oil distributed in the whole reservoir is calculated according to the characteristics of the space distribution of the saturation of remaining oil. Logging data are required to accomplish this. However, many such projects cannot be completed. Since the old study of remaining oil distribution could not be quantified efficiently, the ＂dynamic two-step method＂ is presented. Firstly, the water cut of every flow unit in one well at one time is calculated according to the comprehensive water cut of a single well at one time. Secondly, the remaining oil saturation of the flow unit of the well at one time is calculated based on the water cut of the flow unit at a given time. The results show that ＂dynamic two-step method＂ has characteristics of simplicity and convenience, and is especially suitable for the study of remaining oil distribution at high water-cut stage. The distribution of remaining oil presented banding and potato form, remaining oil was relatively concentrated in faultage neighborhood and imperfect well netting position, and the net thickness of the place was great. This proposal can provide an effective way to forecast remaining oil distribution and enhance oil recovery, especially applied at the high water-cut stage.展开更多
SnO2 doped with Y were prepared by co-precipitation method and tested in lithium-ion cells. The structure and morphology of the materials were characterized by X-ray diffraction (XRD) and transmission electron microsc...SnO2 doped with Y were prepared by co-precipitation method and tested in lithium-ion cells. The structure and morphology of the materials were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). XRD patterns presented that the all the as-prepared materials had tetragonal rutile structure but a second phase (Y2O3) was observed when Y content reached 4%. TEM micrograph indicated that Y doped SnO2 had a small particle size ranging from 20 to 25 nm. The electrochemical properties for an anode active material in lithium-ion batteries were investigated at room temperature, including the observed capacity involved in the first-discharge and the reversible capacity values during subsequent charge-discharge cycles. The as-prepared Y-doped SnO2 exhibited promising electrochemical properties as anodes for lithium-ion batteries.展开更多
ZnO/graphene oxide（ZnO/GO） composite material,in which ZnO nanoparticles were densely coated on the GO nanosheets,was successfully prepared by an improved two-step method and characterized by IR, XRD,TEM,and UV-vis ...ZnO/graphene oxide（ZnO/GO） composite material,in which ZnO nanoparticles were densely coated on the GO nanosheets,was successfully prepared by an improved two-step method and characterized by IR, XRD,TEM,and UV-vis techniques.The improved photocatalytic property of the ZnO/GO composite material,evaluated by the photocatalytic degradation of methyl orange（MO） under UV irradiation,is ascribed to the intimate contact between ZnO and GO,the enhanced adsorption of MO,the quick electron transfer from excited ZnO particles to GO sheets and the activation of MO molecules viaπ-πinteraction between MO and GO.展开更多
Metal batteries have attracted considerable attention from researchers because of their low reduction voltage and high specific capacity.However,the reduction in the capacity and lifespan of batteries caused by the de...Metal batteries have attracted considerable attention from researchers because of their low reduction voltage and high specific capacity.However,the reduction in the capacity and lifespan of batteries caused by the dendrite growth of metal anode limits the development of metal batteries.Metal-organic frameworks (MOFs) can be used to protect metal anodes owing to their advantages of ideal specific surface area,tunable porosity,and physiochemical stability in electrolytes.Therefore,MOFs have been extensively investigated in metal batteries.The introduction of MOFs to the metal anode interface can greatly improve the performance of batteries.In this review,the synthesis methods of typical MOFs and their derivatives,their protective mechanism on the metal anode,including Li,Na,K,Zn,and Mg,and their effects on the performance of metal batteries were elucidated.This review would help to design and apply MOFs to the anode interface in metal batteries.展开更多
Under the assumption that the nonlinear operator has Lipschitz continuous divided differences for the first order,we obtain an estimate of the radius of the convergence ball for the two-step secant method.Moreover,we ...Under the assumption that the nonlinear operator has Lipschitz continuous divided differences for the first order,we obtain an estimate of the radius of the convergence ball for the two-step secant method.Moreover,we also provide an error estimate that matches the convergence order of the two-step secant method.At last,we give an application of the proposed theorem.展开更多
We synthesized size-controllable nanoparticles with homogeneous distribution of carbon and Sn/SnO_(2)by a solvothermal method.The effects of different carbon content and hydrothermal time on the composition,morphology...We synthesized size-controllable nanoparticles with homogeneous distribution of carbon and Sn/SnO_(2)by a solvothermal method.The effects of different carbon content and hydrothermal time on the composition,morphology and electrochemical properties of the materials were investigated.Compared with bulk materials,nanoparticles materials not only have high specific surface area,but also can provide abundant reaction sites,thus enhancing the electrochemical activity of electrode materials.More importantly,the optimized microspheres Sn/8C-24 delivers a superior electrochemical performance,achieving a specific discharge capacity of 700.4 mAh·g^(-1)after 150 cycles at 0.5 A·g^(-1),and the Coulomb efficiency reaches 98.65%,which is promising for anode of LIBs.展开更多
Multiplicative noise removal problems have attracted much attention in recent years.Unlike additive noise,multiplicative noise destroys almost all information of the original image,especially for texture images.Motiva...Multiplicative noise removal problems have attracted much attention in recent years.Unlike additive noise,multiplicative noise destroys almost all information of the original image,especially for texture images.Motivated by the TV-Stokes model,we propose a new two-step variational model to denoise the texture images corrupted by multiplicative noise with a good geometry explanation in this paper.In the first step,we convert the multiplicative denoising problem into an additive one by the logarithm transform and propagate the isophote directions in the tangential field smoothing.Once the isophote directions are constructed,an image is restored to fit the constructed directions in the second step.The existence and uniqueness of the solution to the variational problems are proved.In these two steps,we use the gradient descent method and construct finite difference schemes to solve the problems.Especially,the augmented Lagrangian method and the fast Fourier transform are adopted to accelerate the calculation.Experimental results show that the proposed model can remove the multiplicative noise efficiently and protect the texture well.展开更多
The Adomian decomposition method (ADM) can be used to solve a wide range of problems and usually gets the solution in a series form. In this paper, we propose two-step Adomian Decomposition Method (TSAM) for nonlinear...The Adomian decomposition method (ADM) can be used to solve a wide range of problems and usually gets the solution in a series form. In this paper, we propose two-step Adomian Decomposition Method (TSAM) for nonlinear integro-differential equations that will facilitate the calculations. In this modification, compared to the standard Adomian decomposition method, the size of calculations was reduced. This modification also avoids computing Adomian polynomials. Numerical results are given to show the efficiency and performance of this method.展开更多
For present solid oxide fuel cells(SOFCs),rapid performance degradation is observed in the initial aging process,and the dis-cussion of the degradation mechanism necessitates quantitative analysis.Herein,focused ion b...For present solid oxide fuel cells(SOFCs),rapid performance degradation is observed in the initial aging process,and the dis-cussion of the degradation mechanism necessitates quantitative analysis.Herein,focused ion beam-scanning electron microscopy was em-ployed to characterize and reconstruct the ceramic microstructures of SOFC anodes.The lattice Boltzmann method(LBM)simulation of multiphysical and electrochemical processes in the reconstructed models was performed.Two samples collected from industrial-size cells were characterized,including a reduced reference cell and a cell with an initial aging process.Statistical parameters of the reconstructed microstructures revealed a significant decrease in the active triple-phase boundary and Ni connectivity in the aged cell compared with the reference cell.The LBM simulation revealed that activity degradation is dominant compared with microstructural degradation during the initial aging process,and the electrochemical reactions spread to the support layer in the aged cell.The microstructural and activity de-gradations are attributed to Ni migration and coarsening.展开更多
A stacked Si/SiO_(x)/C composite anode material with carbon-coated structure was prepared by sol-gel method combined with carbothermal reduction using organic silicon.The results of X-ray diffractometry, scanning elec...A stacked Si/SiO_(x)/C composite anode material with carbon-coated structure was prepared by sol-gel method combined with carbothermal reduction using organic silicon.The results of X-ray diffractometry, scanning electron microscopy, and elemental analysis show that the Si/SiO_(x)/C material is a secondary particle with a porous micronanostructure, and the presence of nanometer silicon does not affect the carbothermal reduction and carbon coating.Electrochemical test results indicate that the specific capacity and first coulombic efficiency of SiO_(x)/C composite with nanometer silicon can be increased to 1 946.05 mAh/g and 76.49%,respectively.The reversible specific capacity of Si/SiO_(x)/C material blended with graphite is 749.69 mAh/g after 100 cycles at a current density of 0.1 C,and the capacity retention rate is up to 89.03%.Therefore, the composite has excellent electrochemical cycle stability.展开更多
硬炭凭借较高的储钠容量、低电压平台以及优异的循环稳定性成为了钠离子电池(SIBs)最具应用潜力的负极材料。硬炭材料的微观孔隙结构是影响其储钠性能的关键因素之一,合理调控硬炭材料的孔隙结构大小及分布对提升钠离子电池性能至关重...硬炭凭借较高的储钠容量、低电压平台以及优异的循环稳定性成为了钠离子电池(SIBs)最具应用潜力的负极材料。硬炭材料的微观孔隙结构是影响其储钠性能的关键因素之一,合理调控硬炭材料的孔隙结构大小及分布对提升钠离子电池性能至关重要。本文以β-环糊精为碳源,采用NaCl辅助水热法制备了一系列具有不同微观孔隙结构的硬炭材料,考察了NaCl浓度对硬炭微观孔隙结构的影响,研究了硬炭材料的储纳性能。采用非原位X射线衍射仪、拉曼光谱仪及高倍率透射电镜等进行表征,结果表明,调控NaCl浓度能够优化硬炭材料的孔隙结构,提升硬炭材料闭孔体积。当NaCl浓度为2mol L^(-1)时,制备的硬炭材料(CD-2)的无序程度与石墨微晶尺寸最大,具有最大的闭孔体积与梯度孔隙结构。电化学测试表明,在0.02Ag^(-1)的电流密度下,CD-2硬炭材料具有360 mA hg^(-1)的高储钠比容量及90.2%的首次库伦效率。提出的NaCl辅助水热炭化调控硬炭闭孔结构的策略,为硬炭材料孔隙结构的合理设计提供了有效的技术方法,指导了高性能SIBs硬炭负极材料的开发。展开更多
The accelerating factor （AF） method is a simple and appropriate way to investigate the atomic long-time deep diffusion at solid-solid interface. In the framework of AF hyperdynamics （HD） simulation, the relationsh...The accelerating factor （AF） method is a simple and appropriate way to investigate the atomic long-time deep diffusion at solid-solid interface. In the framework of AF hyperdynamics （HD） simulation, the relationship between the diffusion coefficient along the direction of z-axis which is normal to the Mg/Zn interface and temperature was investigated, and the AF＇s impact on the diffusion constant （D0） and activation energy （Q^＊） was studied. Then, two steps were taken to simulate the atomic diffusion process and the formation of new phases： one for acceleration and the other for equilibration. The results show that： the Arrhenius equation works well for the description of Dz with different accelerating factors; the AF has no effect on the diffusion constant Do in the case of no phase transition; and the relationship between Q＊ and Q conforms to Q^＊=Q/A. Then, the new Arrhenius equation for AFHD is successfully constructed as Dz=Doexp[-Q/（ART）]. Meanwhile, the authentic equilibrium conformations at any dynamic moment can only be reproduced by the equilibration simulation of the HD-simulated configurations. Key words： accelerating factor method; Arrhenius equation; two-steps scheme; Mg/Zn interface; hyperdynamic simulation展开更多
基金supported by the National Natural Science Foundation of China(No.92252201)the Fundamental Research Funds for the Central Universitiesthe Academic Excellence Foundation of Beihang University(BUAA)for PhD Students。
文摘Efficient and accurate simulation of unsteady flow presents a significant challenge that needs to be overcome in computational fluid dynamics.Temporal discretization method plays a crucial role in the simulation of unsteady flows.To enhance computational efficiency,we propose the Implicit-Explicit Two-Step Runge-Kutta(IMEX-TSRK)time-stepping discretization methods for unsteady flows,and develop a novel adaptive algorithm that correctly partitions spatial regions to apply implicit or explicit methods.The novel adaptive IMEX-TSRK schemes effectively handle the numerical stiffness of the small grid size and improve computational efficiency.Compared to implicit and explicit Runge-Kutta(RK)schemes,the IMEX-TSRK methods achieve the same order of accuracy with fewer first derivative calculations.Numerical case tests demonstrate that the IMEX-TSRK methods maintain numerical stability while enhancing computational efficiency.Specifically,in high Reynolds number flows,the computational efficiency of the IMEX-TSRK methods surpasses that of explicit RK schemes by more than one order of magnitude,and that of implicit RK schemes several times over.
基金supported by the Scientific Computing Research Innovation Team of Guangdong Province(no.2021KCXTD052)the Science and Technology Development Fund,Macao SAR(no.0096/2022/A,0151/2022/A)+3 种基金University of Macao(no.MYRG2020-00035-FST,MYRG2022-00076-FST)the Guangdong Key Construction Discipline Research Capacity Enhancement Project(no.2022ZDJS049)Technology Planning Project of Shaoguan(no.210716094530390)the ScienceFoundation of Shaoguan University(no.SZ2020KJ01).
文摘In this paper,a two-step iteration method is established which can be viewed as a generalization of the existing modulus-based methods for vertical linear complementarity problems given by He and Vong(Appl.Math.Lett.134:108344,2022).The convergence analysis of the proposed method is established,which can improve the existing results.Numerical examples show that the proposed method is efficient with the two-step technique.
基金supported by the National Natural Science Foun-dation of China(Nos.52025028,52332008,52372214,52202273,and U22A20137)the Priority Academic Program Development(PAPD)of Jiangsu Higher Education Institutions.
文摘Tin(Sn)-lead(Pb)mixed halide perovskites have attracted widespread interest due to their wider re-sponse wavelength and lower toxicity than lead halide perovskites,Among the preparation methods,the two-step method more easily controls the crystallization rate and is suitable for preparing large-area per-ovskite devices.However,the residual low-conductivity iodide layer in the two-step method can affect carrier transport and device stability,and the different crystallization rates of Sn-and Pb-based per-ovskites may result in poor film quality.Therefore,Sn-Pb mixed perovskites are mainly prepared by a one-step method.Herein,a MAPb_(0.5)Sn_(0.5)I_(3)-based self-powered photodetector without a hole transport layer is fabricated by a two-step method.By adjusting the concentration of the ascorbic acid(AA)addi-tive,the final perovskite film exhibited a pure phase without residues,and the optimal device exhibited a high responsivity(0.276 A W^(-1)),large specific detectivity(2.38×10^(12) Jones),and enhanced stability.This enhancement is mainly attributed to the inhibition of Sn2+oxidation,the control of crystal growth,and the sufficient reaction between organic ammonium salts and bottom halides due to the AA-induced pore structure.
文摘The urgent demand for clean energy solutions has intensified the search for advanced storage materials,with rechargeable alkali-ion batteries(AIBs)playing a pivotal role in electrochemical energy storage.Enhancing electrode performance is critical to addressing the increasing need for high-energy and high-power AIBs.Next-generation anode materials face significant challenges,including limited energy storage capacities and complex reaction mechanisms that complicate structural modeling.Sn-based materials have emerged as promising candidates for AIBs due to their inherent advantages.Recent research has increasingly focused on the development of heterojunctions as a strategy to enhance the performance of Sn-based anode materials.Despite significant advances in this field,comprehensive reviews summarizing the latest developments are still sparse.This review provides a detailed overview of recent progress in Sn-based heterojunction-type anode materials.It begins with an explanation of the concept of heterojunctions,including their fabrication,characterization,and classification.Cutting-edge research on Sn-based heterojunction-type anodes for AIBs is highlighted.Finally,the review summarizes the latest advancements in heterojunction technology and discusses future directions for research and development in this area.
基金supported by the National Key Research and Development Program of China(2020YFB1713500)the Chinese 02 Special Fund(2017ZX02408003)+2 种基金the Open Fund of National Joint Engineering Research Center for abrasion control and molding of metal materials(HKDNM201807)the Student Research Training Plan of Henan University of Science and Technology(2020026)the National Undergraduate Innovation and Entrepreneurship Training Program(202010464031,202110464005)。
文摘Rechargeable aqueous Zn-ion batteries(AZIBs)are one of the most promising energy storage devices for large-scale energy storage owing to their high specific capacity,eco-friendliness,low cost and high safety.Nevertheless,zinc metal anodes suffer from severe dendrite growth and side reactions,resulting in the inferior electrochemical performance of AZIBs.To address these problems,surface modification of zinc metal anodes is a facile and effective method to regulate the interaction between the zinc anode and an electrolyte.In this review,the current challenges and strategies for zinc metal anodes are presented.Furthermore,recent advances in surface modification strategies to improve their electrochemical performance are concluded and discussed.Finally,challenges and prospects for future development of zinc metal anodes are proposed.We hope this review will be useful for designing and fabricating highperformance AZIBs and boosting their practical applications.
基金supported by the International Science and Technology Cooperation Program of Science and Technology Bureau of Changchun City,China(Grant No.12ZX68)
文摘Temperature-dependent photoluminescence characteristics of organic-inorganic halide perovskite CH3NH3Pb I3-xClx films prepared using a two-step method on ZnO/FTO substrates were investigated. Surface morphology and absorption characteristics of the films were also studied. Scanning electron microscopy revealed large crystals and substrate coverage. The orthorhombic-to-tetragonal phase transition temperature was-140 K. The films＇ exciton binding energy was 77.6 ± 10.9 meV and the energy of optical phonons was 38.8 ± 2.5 meV. These results suggest that perovskite CH3NH3Pb I（3-x）Clx films have excellent optoelectronic characteristics which further suggests their potential usage in perovskitebased optoelectronic devices.
文摘The distribution of remaining oil is often described qualitatively. The remaining oil distributed in the whole reservoir is calculated according to the characteristics of the space distribution of the saturation of remaining oil. Logging data are required to accomplish this. However, many such projects cannot be completed. Since the old study of remaining oil distribution could not be quantified efficiently, the ＂dynamic two-step method＂ is presented. Firstly, the water cut of every flow unit in one well at one time is calculated according to the comprehensive water cut of a single well at one time. Secondly, the remaining oil saturation of the flow unit of the well at one time is calculated based on the water cut of the flow unit at a given time. The results show that ＂dynamic two-step method＂ has characteristics of simplicity and convenience, and is especially suitable for the study of remaining oil distribution at high water-cut stage. The distribution of remaining oil presented banding and potato form, remaining oil was relatively concentrated in faultage neighborhood and imperfect well netting position, and the net thickness of the place was great. This proposal can provide an effective way to forecast remaining oil distribution and enhance oil recovery, especially applied at the high water-cut stage.
基金NSFC (20471055)Henan Outstanding Youth Science Fund (0612002700)
文摘SnO2 doped with Y were prepared by co-precipitation method and tested in lithium-ion cells. The structure and morphology of the materials were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). XRD patterns presented that the all the as-prepared materials had tetragonal rutile structure but a second phase (Y2O3) was observed when Y content reached 4%. TEM micrograph indicated that Y doped SnO2 had a small particle size ranging from 20 to 25 nm. The electrochemical properties for an anode active material in lithium-ion batteries were investigated at room temperature, including the observed capacity involved in the first-discharge and the reversible capacity values during subsequent charge-discharge cycles. The as-prepared Y-doped SnO2 exhibited promising electrochemical properties as anodes for lithium-ion batteries.
基金supported by the Natural Science Foundation of China(No.21174114)the Ministry of Education Plan for Yangtze River Scholar and Innovation Team Development(No.IRT1177)+2 种基金Scientific and Technical Plan Project of Gansu Province(No. 1204GKCA006)the Natural Science Foundation of Gansu Province (No.1010RJZA024)Scientific and Technical Innovation Project of Northwest Normal University(No.nwnu-kjcxgc-03-63)
文摘ZnO/graphene oxide（ZnO/GO） composite material,in which ZnO nanoparticles were densely coated on the GO nanosheets,was successfully prepared by an improved two-step method and characterized by IR, XRD,TEM,and UV-vis techniques.The improved photocatalytic property of the ZnO/GO composite material,evaluated by the photocatalytic degradation of methyl orange（MO） under UV irradiation,is ascribed to the intimate contact between ZnO and GO,the enhanced adsorption of MO,the quick electron transfer from excited ZnO particles to GO sheets and the activation of MO molecules viaπ-πinteraction between MO and GO.
基金financial support from the National Natural Science Foundation of China (No.61904073)Spring City Plan-Special Program for Young Talents (No.K202005007)+2 种基金Yunnan Local Colleges Applied Basic Research Projects (Nos.202101BA070001-138,2018FH001-016)Yunnan Talents Support Plan for Yong Talents (No.XDYC-QNRC-2022-0482)Frontier Research Team of Kunming University 2023,and Yunnan Provincial Education Department (Nos.2022Y732,2022Y739)。
文摘Metal batteries have attracted considerable attention from researchers because of their low reduction voltage and high specific capacity.However,the reduction in the capacity and lifespan of batteries caused by the dendrite growth of metal anode limits the development of metal batteries.Metal-organic frameworks (MOFs) can be used to protect metal anodes owing to their advantages of ideal specific surface area,tunable porosity,and physiochemical stability in electrolytes.Therefore,MOFs have been extensively investigated in metal batteries.The introduction of MOFs to the metal anode interface can greatly improve the performance of batteries.In this review,the synthesis methods of typical MOFs and their derivatives,their protective mechanism on the metal anode,including Li,Na,K,Zn,and Mg,and their effects on the performance of metal batteries were elucidated.This review would help to design and apply MOFs to the anode interface in metal batteries.
基金supported by National Natural Science Foundation of China(11771393,11371320,11632015)Zhejiang Natural Science Foundation(LZ14A010002,LQ18A010008)Scientific Research Fund of Zhejiang Provincial Education Department(FX2016073)
文摘Under the assumption that the nonlinear operator has Lipschitz continuous divided differences for the first order,we obtain an estimate of the radius of the convergence ball for the two-step secant method.Moreover,we also provide an error estimate that matches the convergence order of the two-step secant method.At last,we give an application of the proposed theorem.
基金Funded by the National Natural Science Foundation of China(No.21676304)。
文摘We synthesized size-controllable nanoparticles with homogeneous distribution of carbon and Sn/SnO_(2)by a solvothermal method.The effects of different carbon content and hydrothermal time on the composition,morphology and electrochemical properties of the materials were investigated.Compared with bulk materials,nanoparticles materials not only have high specific surface area,but also can provide abundant reaction sites,thus enhancing the electrochemical activity of electrode materials.More importantly,the optimized microspheres Sn/8C-24 delivers a superior electrochemical performance,achieving a specific discharge capacity of 700.4 mAh·g^(-1)after 150 cycles at 0.5 A·g^(-1),and the Coulomb efficiency reaches 98.65%,which is promising for anode of LIBs.
文摘Multiplicative noise removal problems have attracted much attention in recent years.Unlike additive noise,multiplicative noise destroys almost all information of the original image,especially for texture images.Motivated by the TV-Stokes model,we propose a new two-step variational model to denoise the texture images corrupted by multiplicative noise with a good geometry explanation in this paper.In the first step,we convert the multiplicative denoising problem into an additive one by the logarithm transform and propagate the isophote directions in the tangential field smoothing.Once the isophote directions are constructed,an image is restored to fit the constructed directions in the second step.The existence and uniqueness of the solution to the variational problems are proved.In these two steps,we use the gradient descent method and construct finite difference schemes to solve the problems.Especially,the augmented Lagrangian method and the fast Fourier transform are adopted to accelerate the calculation.Experimental results show that the proposed model can remove the multiplicative noise efficiently and protect the texture well.
文摘The Adomian decomposition method (ADM) can be used to solve a wide range of problems and usually gets the solution in a series form. In this paper, we propose two-step Adomian Decomposition Method (TSAM) for nonlinear integro-differential equations that will facilitate the calculations. In this modification, compared to the standard Adomian decomposition method, the size of calculations was reduced. This modification also avoids computing Adomian polynomials. Numerical results are given to show the efficiency and performance of this method.
基金the National Key R&D Program of China(No.2018YFB1502201)the Guangdong Basic and Applied Basic Research Foundation,China(No.2020A1515010551).
文摘For present solid oxide fuel cells(SOFCs),rapid performance degradation is observed in the initial aging process,and the dis-cussion of the degradation mechanism necessitates quantitative analysis.Herein,focused ion beam-scanning electron microscopy was em-ployed to characterize and reconstruct the ceramic microstructures of SOFC anodes.The lattice Boltzmann method(LBM)simulation of multiphysical and electrochemical processes in the reconstructed models was performed.Two samples collected from industrial-size cells were characterized,including a reduced reference cell and a cell with an initial aging process.Statistical parameters of the reconstructed microstructures revealed a significant decrease in the active triple-phase boundary and Ni connectivity in the aged cell compared with the reference cell.The LBM simulation revealed that activity degradation is dominant compared with microstructural degradation during the initial aging process,and the electrochemical reactions spread to the support layer in the aged cell.The microstructural and activity de-gradations are attributed to Ni migration and coarsening.
文摘A stacked Si/SiO_(x)/C composite anode material with carbon-coated structure was prepared by sol-gel method combined with carbothermal reduction using organic silicon.The results of X-ray diffractometry, scanning electron microscopy, and elemental analysis show that the Si/SiO_(x)/C material is a secondary particle with a porous micronanostructure, and the presence of nanometer silicon does not affect the carbothermal reduction and carbon coating.Electrochemical test results indicate that the specific capacity and first coulombic efficiency of SiO_(x)/C composite with nanometer silicon can be increased to 1 946.05 mAh/g and 76.49%,respectively.The reversible specific capacity of Si/SiO_(x)/C material blended with graphite is 749.69 mAh/g after 100 cycles at a current density of 0.1 C,and the capacity retention rate is up to 89.03%.Therefore, the composite has excellent electrochemical cycle stability.
文摘硬炭凭借较高的储钠容量、低电压平台以及优异的循环稳定性成为了钠离子电池(SIBs)最具应用潜力的负极材料。硬炭材料的微观孔隙结构是影响其储钠性能的关键因素之一,合理调控硬炭材料的孔隙结构大小及分布对提升钠离子电池性能至关重要。本文以β-环糊精为碳源,采用NaCl辅助水热法制备了一系列具有不同微观孔隙结构的硬炭材料,考察了NaCl浓度对硬炭微观孔隙结构的影响,研究了硬炭材料的储纳性能。采用非原位X射线衍射仪、拉曼光谱仪及高倍率透射电镜等进行表征,结果表明,调控NaCl浓度能够优化硬炭材料的孔隙结构,提升硬炭材料闭孔体积。当NaCl浓度为2mol L^(-1)时,制备的硬炭材料(CD-2)的无序程度与石墨微晶尺寸最大,具有最大的闭孔体积与梯度孔隙结构。电化学测试表明,在0.02Ag^(-1)的电流密度下,CD-2硬炭材料具有360 mA hg^(-1)的高储钠比容量及90.2%的首次库伦效率。提出的NaCl辅助水热炭化调控硬炭闭孔结构的策略,为硬炭材料孔隙结构的合理设计提供了有效的技术方法,指导了高性能SIBs硬炭负极材料的开发。
基金Project (2012CB722805) supported by the National Basic Research Program of ChinaProjects (50974083, 51174131) supported by the National Natural Science Foundation of China+1 种基金Project (50774112) supported by the Joint Fund of NSFC and Baosteel, ChinaProject(07QA4021) supported by the Shanghai "Phosphor" Science Foundation, China
文摘The accelerating factor （AF） method is a simple and appropriate way to investigate the atomic long-time deep diffusion at solid-solid interface. In the framework of AF hyperdynamics （HD） simulation, the relationship between the diffusion coefficient along the direction of z-axis which is normal to the Mg/Zn interface and temperature was investigated, and the AF＇s impact on the diffusion constant （D0） and activation energy （Q^＊） was studied. Then, two steps were taken to simulate the atomic diffusion process and the formation of new phases： one for acceleration and the other for equilibration. The results show that： the Arrhenius equation works well for the description of Dz with different accelerating factors; the AF has no effect on the diffusion constant Do in the case of no phase transition; and the relationship between Q＊ and Q conforms to Q^＊=Q/A. Then, the new Arrhenius equation for AFHD is successfully constructed as Dz=Doexp[-Q/（ART）]. Meanwhile, the authentic equilibrium conformations at any dynamic moment can only be reproduced by the equilibration simulation of the HD-simulated configurations. Key words： accelerating factor method; Arrhenius equation; two-steps scheme; Mg/Zn interface; hyperdynamic simulation
