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Facile synthesis of Na_(0.9)Mg_(0.45)Ti_(3.55)O_(8)-Na_(2)Ni_(2)Ti_(6)O_(16)solid solutions for improving photocatalytic CO_(2)reduction
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作者 WANG Jingzhou YAO Chenzhong +2 位作者 ZHANG Xisheng MA Ziwei LI Linfeng 《燃料化学学报(中英文)》 北大核心 2026年第1期15-25,共11页
In this study,a straightforward one-step hydrothermal method was successfully utilized to synthesize the solid solution Na_(0.9)Mg_(0.45)Ti_(3.55)O_(8)-Na_(2)Ni_(2)Ti_(6)O_(16)(NNMTO-x),where x denotes the molar perce... In this study,a straightforward one-step hydrothermal method was successfully utilized to synthesize the solid solution Na_(0.9)Mg_(0.45)Ti_(3.55)O_(8)-Na_(2)Ni_(2)Ti_(6)O_(16)(NNMTO-x),where x denotes the molar percentage of Na_(2)Ni_(2)Ti_(6)O_(16)(NNTO)within Na_(0.9)Mg_(0.45)Ti_(3.55)O_(8)(NMTO),with x values of 10,20,30,40,and 50.Both XPS(X-ray Photoelectron Spectroscopy)and EDX(Energy Dispersive X-ray Spectroscopy)analyses unequivocally validated the formation of the NNMTO-x solid solutions.It was observed that when x is below 40,the NNMTO-x solid solution retains the structural characteristics of the original NMTO.However,beyond this threshold,significant alterations in crystal morphology were noted,accompanied by a noticeable decline in photocatalytic activity.Notably,the absorption edge of NNMTO-x(x<40)exhibited a shift towards the visible-light spectrum,thereby substantially broadening the absorption range.The findings highlight that NNMTO-30 possesses the most pronounced photocatalytic activity for the reduction of CO_(2).Specifically,after a 6 h irradiation period,the production rates of CO and CH_(4)were recorded at 42.38 and 1.47μmol/g,respectively.This investigation provides pivotal insights that are instrumental in the advancement of highly efficient and stable photocatalysts tailored for CO_(2)reduction processes. 展开更多
关键词 photocatalytic conversion hydrothermal method optical response range solid solution charge separation
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Existence,Uniqueness and Stability of Bounded Solutions for Minkowski-Curvature Problems with Asymptotic Boundary Conditions
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作者 Tianlan CHEN Xuying TANG 《Journal of Mathematical Research with Applications》 2026年第1期57-70,共14页
In this article,we show the existence,uniqueness and stability of bounded solutions to the following quasilinear problems with mean curvature operator(φ'(x′(t)))′=f(t,x),t≥t_(0),lim_(t→∞)x(t)=ψ_(0),lim_(t→... In this article,we show the existence,uniqueness and stability of bounded solutions to the following quasilinear problems with mean curvature operator(φ'(x′(t)))′=f(t,x),t≥t_(0),lim_(t→∞)x(t)=ψ_(0),lim_(t→∞)x′(t)e^(t)=0,where t_(0) and ψ_(0) are real constants,φ(s)=s/√1−s^(2),s∈R with s∈(−1,1),f:[t_(0),∞)×R→R satisfies the Lipschitz or Osgood-type conditions. 展开更多
关键词 mean curvature operator UNIQUENESS asymptotic boundary conditions bounded solution
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Asymptotic solution of a weak nonlinear model for the mid-latitude stationary wind field of a two-layer barotropic ocean 被引量:8
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作者 林万涛 张宇 莫嘉琪 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第3期72-78,共7页
A weak nonlinear model of a two-layer barotropic ocean with Rayleigh dissipation is built.The analytic asymptotic solution is derived in the mid-latitude stationary wind field,and the physical meaning of the correspon... A weak nonlinear model of a two-layer barotropic ocean with Rayleigh dissipation is built.The analytic asymptotic solution is derived in the mid-latitude stationary wind field,and the physical meaning of the corresponding problem is discussed. 展开更多
关键词 two-layer barotropic ocean ocean model asymptotic solution
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Second-order random interfacial wave solutions for two-layer fluid with a free surface 被引量:2
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作者 SONG Jinbao SUN Qun 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2006年第1期15-20,共6页
A previous study (Song. 2004. Geophys Res Lett, 31 (15):L15302) of the second-order solutions for random interracial waves is extended in a constant depth, two-layer fluid system with a rigid lid is extended into... A previous study (Song. 2004. Geophys Res Lett, 31 (15):L15302) of the second-order solutions for random interracial waves is extended in a constant depth, two-layer fluid system with a rigid lid is extended into a more general case of two-layer fluid with a top free surface. The rigid boundary condition on the upper surface is replaced by the kinematical and dynamical boundary conditions of a free surface, and the equations describing the random displacements of free surface, density-interface and the associated velocity potentials in the two-layer fluid are solved to the second order using the same expansion technology as that of Song (2004. Geophys Res Lett, 31 (15):L15302). The results show that the interface and the surface will oscillate synchronously, and the wave fields to the first-order both at the free surface and at the density-interface are made up of a linear superposition of many waves with different amplitudes, wave numbers and frequencies. The second-order solutions describe the second-order wave-wave interactions of the surface wave components, the interface wave components and among the surface and the interface wave components. The extended solutions also include special cases obtained by Thorpe for progressive interracial waves (Thorpe. 1968a.Trans R Soc London, 263A:563~614) and standing interracial waves (Thorpe. 1968b. J Fluid Mech, 32:489-528) for the two-layer fluid with a top free surface. Moreover, the solutions reduce to those derived for random surface waves by Sharma and Dean (1979.Ocean Engineering Rep 20) if the density of the upper layer is much smaller than that of the lower layer. 展开更多
关键词 two-layer fluid free surface random interracial waves second-order solutions
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Influence of the earth rotation on the interfacial wave solutions and wave-induced tangential stress in a two-layer fluid system 被引量:1
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作者 SONG Jinbao LIU Yongjun 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2009年第2期115-120,共6页
Interfacial waves and wave-induced tangential stress are studied for geostrophic small amplitude waves of two-layer fluid with a top free surface and a fiat bottom. The solutions were deduced from the general form of ... Interfacial waves and wave-induced tangential stress are studied for geostrophic small amplitude waves of two-layer fluid with a top free surface and a fiat bottom. The solutions were deduced from the general form of linear fluid dynamic equations of two-layer fluid under the f-plane approximation, and wave-induced tangential stress were estimated based on the solutions obtained. As expected, the solutions derived from the present work include as special cases those obtained by Sun et al. (2004. Science in China, Ser. D, 47(12): 1147-1154) for geostrophic small amplitude surface wave solutions and wave-induced tangential stress if the density of the upper layer is much smaller than that of the lower layer. The results show that the interface and the surface will oscillate synchronously, and the influence of the earth's rotation both on the surface wave solutions and the interfacial wave solutions should be considered. 展开更多
关键词 two-layer fluid interfacial waves wave-induced tangential stress earth rotation
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Numerical solutions of rotational normal modes of a triaxial two-layered anelastic Earth
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作者 Wenbin Shen Zhuo Yang +1 位作者 Zhiliang Guo Wenying Zhang 《Geodesy and Geodynamics》 2019年第2期118-129,共12页
The Earth's rotational normal modes depend on Earth model used, including the layer structures,principal inertia moments of different layers and the compliances. This study focuses on providing numerical solution ... The Earth's rotational normal modes depend on Earth model used, including the layer structures,principal inertia moments of different layers and the compliances. This study focuses on providing numerical solution of the rotational normal modes of a triaxial two-layered anelastic Earth model without external forces but with considering the complex forms of compliances and the electromagnetic coupling between the core and mantle. Based on the present knowledge of the Chandler wobble(CW) and Free Core Nutation(FCN), we provide a set of complete compliances which could be used for reference in further investigations. There are eight rotational normal mode solutions, four of which might exist in nature. However, in reality only two of these four solutions correspond to the present motion status of the prograde CW and the retrograde FCN. On one hand, our numerical calculations show that the periods and quality factors(Qs) of CW and FCN are respectively 434.90 and 429.86 mean solar days(d) and 76.56 and 23988.47 under frequency-dependent assumption, and the triaxiality prolongs CW about 0.01 d and has hardly effect on FCN. On the other hand, we analyze the sensibility of compliances and electromagnetic coupling parameter on the periods and Qs of CW and FCN and find the sensitive parameters with respect to them. 展开更多
关键词 EARTH ROTATION TRIAXIAL two-layered anelastic EARTH model Compliances ROTATIONAL normal MODES Numerical solution
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Kangfuxin solution alleviates esophageal stenosis after endoscopic submucosal dissection:A natural ingredient strategy 被引量:1
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作者 Xin Zhou Dan Ma +7 位作者 Yi-Xiang He Jing Jin Hong-Lian Wang Yun-Feng Wang Fan Yang Jian-Qin Liu Jie Chen Zhi Li 《World Journal of Gastroenterology》 SCIE CAS 2025年第1期110-125,共16页
BACKGROUND Esophageal stricture ranks among the most significant complications following endoscopic submucosal dissection(ESD).Excessive fibrotic repair is a typical pathological feature leading to stenosis after ESD.... BACKGROUND Esophageal stricture ranks among the most significant complications following endoscopic submucosal dissection(ESD).Excessive fibrotic repair is a typical pathological feature leading to stenosis after ESD.AIM To examine the effectiveness and underlying mechanism of Kangfuxin solution(KFX)in mitigating excessive fibrotic repair of the esophagus post-ESD.METHODS Pigs received KFX at 0.74 mL/kg/d for 21 days after esophageal full circumferential ESD.Endoscopic examinations occurred on days 7 and 21 post-ESD.In vitro,recombinant transforming growth factor(TGF)-β1(5 ng/mL)induced a fibrotic microenvironment in primary esophageal fibroblasts(pEsF).After 24 hours of KFX treatment(at 1.5%,1%,and 0.5%),expression ofα-smooth muscle actin-2(ACTA2),fibronectin(FN),and type collagen I was assessed.Profibrotic signaling was analyzed,including TGF-β1,Smad2/3,and phosphor-smad2/3(p-Smad2/3).RESULTS Compared to the Control group,the groups treated with KFX and prednisolone exhibited reduced esophageal stenosis,lower weight loss rates,and improved food tolerance 21 d after ESD.After treatment,Masson staining revealed thinner and less dense collagen fibers in the submucosal layer.Additionally,the expression of fibrotic effector molecules was notably inhibited.Mechanistically,KFX downregulated the transduction levels of fibrotic functional molecules such as TGF-β1,Smad2/3,and p-Smad2/3.In vitro,pEsF exposed to TGF-β1-induced fibrotic microenvironment displayed increased fibrotic activity,which was reversed by KFX treatment,leading to reduced activation of ACTA2,FN,and collagen I.The 1.5%KFX treatment group showed decreased expression of p-Smad 2/3 in TGF-β1-activated pEsF.CONCLUSION KFX showed promise as a therapeutic option for post-full circumferential esophageal ESD strictures,potentially by suppressing fibroblast fibrotic activity through modulation of the TGF-β1/Smads signaling pathway. 展开更多
关键词 Kangfuxin solution Natural component Endoscopic submucosal dissection Esophagus stricture Fibrosis
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Bearing capacity prediction of open caissons in two-layered clays using five tree-based machine learning algorithms 被引量:1
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作者 Rungroad Suppakul Kongtawan Sangjinda +3 位作者 Wittaya Jitchaijaroen Natakorn Phuksuksakul Suraparb Keawsawasvong Peem Nuaklong 《Intelligent Geoengineering》 2025年第2期55-65,共11页
Open caissons are widely used in foundation engineering because of their load-bearing efficiency and adaptability in diverse soil conditions.However,accurately predicting their undrained bearing capacity in layered so... Open caissons are widely used in foundation engineering because of their load-bearing efficiency and adaptability in diverse soil conditions.However,accurately predicting their undrained bearing capacity in layered soils remains a complex challenge.This study presents a novel application of five ensemble machine(ML)algorithms-random forest(RF),gradient boosting machine(GBM),extreme gradient boosting(XGBoost),adaptive boosting(AdaBoost),and categorical boosting(CatBoost)-to predict the undrained bearing capacity factor(Nc)of circular open caissons embedded in two-layered clay on the basis of results from finite element limit analysis(FELA).The input dataset consists of 1188 numerical simulations using the Tresca failure criterion,varying in geometrical and soil parameters.The FELA was performed via OptumG2 software with adaptive meshing techniques and verified against existing benchmark studies.The ML models were trained on 70% of the dataset and tested on the remaining 30%.Their performance was evaluated using six statistical metrics:coefficient of determination(R²),mean absolute error(MAE),root mean squared error(RMSE),index of scatter(IOS),RMSE-to-standard deviation ratio(RSR),and variance explained factor(VAF).The results indicate that all the models achieved high accuracy,with R²values exceeding 97.6%and RMSE values below 0.02.Among them,AdaBoost and CatBoost consistently outperformed the other methods across both the training and testing datasets,demonstrating superior generalizability and robustness.The proposed ML framework offers an efficient,accurate,and data-driven alternative to traditional methods for estimating caisson capacity in stratified soils.This approach can aid in reducing computational costs while improving reliability in the early stages of foundation design. 展开更多
关键词 two-layered clay Open caisson Tree-based algorithms FELA Machine learning
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Ascorbic acid-induced porous iodide layer for a high-purity two-step solution-processed tin-lead mixed perovskite photodetector 被引量:2
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作者 Liansong Liu Fengren Cao +3 位作者 Liukang Bian Meng Wang Haoxuan Sun Liang Li 《Journal of Materials Science & Technology》 2025年第7期227-232,共6页
Tin(Sn)-lead(Pb)mixed halide perovskites have attracted widespread interest due to their wider re-sponse wavelength and lower toxicity than lead halide perovskites,Among the preparation methods,the two-step method mor... Tin(Sn)-lead(Pb)mixed halide perovskites have attracted widespread interest due to their wider re-sponse wavelength and lower toxicity than lead halide perovskites,Among the preparation methods,the two-step method more easily controls the crystallization rate and is suitable for preparing large-area per-ovskite devices.However,the residual low-conductivity iodide layer in the two-step method can affect carrier transport and device stability,and the different crystallization rates of Sn-and Pb-based per-ovskites may result in poor film quality.Therefore,Sn-Pb mixed perovskites are mainly prepared by a one-step method.Herein,a MAPb_(0.5)Sn_(0.5)I_(3)-based self-powered photodetector without a hole transport layer is fabricated by a two-step method.By adjusting the concentration of the ascorbic acid(AA)addi-tive,the final perovskite film exhibited a pure phase without residues,and the optimal device exhibited a high responsivity(0.276 A W^(-1)),large specific detectivity(2.38×10^(12) Jones),and enhanced stability.This enhancement is mainly attributed to the inhibition of Sn2+oxidation,the control of crystal growth,and the sufficient reaction between organic ammonium salts and bottom halides due to the AA-induced pore structure. 展开更多
关键词 PEROVSKITE SN-PB PHOTODETECTOR Two-step solution method
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Colorectal cancer early screening:Dilemmas and solutions 被引量:2
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作者 Di Wu Qi-Ying Song +4 位作者 Bai-Shu Dai Jie Li Xin-Xin Wang Jia-Yu Liu Tian-Yu Xie 《World Journal of Gastroenterology》 2025年第9期154-160,共7页
Colorectal cancer(CRC)is a prevalent malignancy worldwide,posing a significant public health concern.Mounting evidence has confirmed that timely early screening facilitates the detection of incipient CRC,thereby enhan... Colorectal cancer(CRC)is a prevalent malignancy worldwide,posing a significant public health concern.Mounting evidence has confirmed that timely early screening facilitates the detection of incipient CRC,thereby enhancing patient prognosis.Obviously,non-participation of asymptomatic individuals in screening programs hampers early diagnosis and may adversely affect long-term outcomes for CRC patients.In this letter,we provide a comprehensive overview of the current status of early screening practices,while also thoroughly examine the dilemmas and potential solutions associated with early screening for CRC.In response to these issues,we proffer a set of recommendations directed at governmental authorities and the general public,which focus on augmenting financial investment,establishing standardized screening protocols,advancing technological capabilities,and bolstering public awareness campaigns.The importance of collaborative efforts from various stakeholders cannot be overstated in the quest to enhance early detection rates and alleviate the societal burden of CRC. 展开更多
关键词 Colorectal cancer Early screening Asymptomatic candidates DILEMMAS solutionS
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Features and classification of solid solution behavior of ternary Mg alloys 被引量:1
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作者 Tao Chen Yuan Yuan +6 位作者 Jun Wang Jiajia Wu Bin Wang Xianhua Chen Nele Moelans Jingfeng Wang Fusheng Pan 《Journal of Magnesium and Alloys》 2025年第6期2522-2539,共18页
The performance of Mg alloys is significantly influenced by the concentrations and solid solution behavior of the alloying elements.In this work,the solid solution behavior of 20 alloying elements in 190 ternary Mg al... The performance of Mg alloys is significantly influenced by the concentrations and solid solution behavior of the alloying elements.In this work,the solid solution behavior of 20 alloying elements in 190 ternary Mg alloy systems at 500℃are systematically investigated.The solid solution behavior of a set of two different alloying elements in Mg alloy systems are suggested to be classified into three categories:inclusivity,exclusivity and proportionality.Inclusivity classification indicates that the two alloying elements are inclusive inα-Mg,increasing the joint solubility of both elements.Exclusivity classification suggests that the two alloying elements have a low joint solid solubility inα-Mg,since they prefer to form stable second phases.For the proportionality classification,the solubility curve of the ternary Mg alloy systems is a straight line connecting the solubility points of the two sub-binary systems.The proposed classification theory was validated by key experiments and the calculation of formation energies.The interaction effects between alloying elements and the preference of formation of second phases are the main factors determining the solid solution behavior classifications.Based on the observed solid solution features of multi-component Mg alloys,principles for alloy design of different types of high-performance Mg alloys were proposed in this work. 展开更多
关键词 Mg alloys solution behavior Phase diagram Alloy design
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Fluid therapy in acute pancreatitis comparing balanced solutions and normal saline:A systematic review,meta-analysis and trial sequential analysis 被引量:1
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作者 Lin Gao Hsiang-Wei Wang +4 位作者 Zi-Rui Liu Yi-Zhen Xu Lu Ke Wei-Qin Li John A Windsor 《Hepatobiliary & Pancreatic Diseases International》 2025年第4期371-380,共10页
Background:Isotonic crystalloids are recommended as the first choice for fluid therapy in acute pan-creatitis(AP),with normal saline(NS)and lactate Ringer’s(LR)used most often.Evidence based recom-mendations on the t... Background:Isotonic crystalloids are recommended as the first choice for fluid therapy in acute pan-creatitis(AP),with normal saline(NS)and lactate Ringer’s(LR)used most often.Evidence based recom-mendations on the type of fluid are conflicting and generally come from small single-center randomized controlled trials(RCTs).We therefore conducted a systematic review and meta-analysis to compare the effect of balanced solutions(BS)versus NS on patient-centered clinical outcomes in AP.Methods:From four databases searched up to October 2024,we included only RCTs of adult patients with AP that compared the use of BS(including LR,acetate Ringer’s,etc.)with NS.The primary out-come was the disease advances from AP to moderately severe and severe AP(MSAP/SAP).Trial sequential analyses(TSA)were conducted to control for type-I and type-II errors and Grading of Recommendations Assessment,Development,and Evaluation(GRADE)was used to assess the quality of evidence.Results:Six RCTs were identified and included,involving 260 patients treated with BS and 298 patients with NS.Patients who received the BS had less MSAP/SAP[odds ratio(OR)=0.50,95%confidence in-terval(CI):0.29 to 0.85,P=0.01,I^(2)=0%;5 studies,299 patients],reduced the need of ICU admission(OR=0.60,95%CI:0.39 to 0.93,P=0.02,I^(2)=0%;5 studies,507 patients)and shorter length of hospital stay[mean difference(MD)=-0.88,95%CI:-1.48 to-0.28,P=0.004,I^(2)=0%;6 studies,558 patients;confirmed by TSA with high certainty]compared with those who received NS.The evidence for most of the clinical outcomes was rated as moderate to low due to the risk of bias,imprecision and inconsistency.Conclusions:BS,compared with NS,was associated with improved clinical outcomes in patients with AP.However,given the moderate to low quality of evidence for most of the outcomes assessed,further trials are warranted. 展开更多
关键词 Acute pancreatitis Fluid therapy Normal saline Balanced solution Systematic review
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V–Ti‑Based Solid Solution Alloys for Solid‑State Hydrogen Storage 被引量:2
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作者 Shaoyang Shen Yongan Li +3 位作者 Liuzhang Ouyang Lan Zhang Min Zhu Zongwen Liu 《Nano-Micro Letters》 2025年第7期453-482,共30页
This review details the advancement in the development of V–Ti-based hydrogen storage materials for using in metal hydride(MH)tanks to supply hydrogen to fuel cells at relatively ambient temperatures and pressures.V... This review details the advancement in the development of V–Ti-based hydrogen storage materials for using in metal hydride(MH)tanks to supply hydrogen to fuel cells at relatively ambient temperatures and pressures.V–Tibased solid solution alloys are excellent hydrogen storage materials among many metal hydrides due to their high reversible hydrogen storage capacity which is over 2 wt%at ambient temperature.The preparation methods,structure characteristics,improvement methods of hydrogen storage performance,and attenuation mechanism are systematically summarized and discussed.The relationships between hydrogen storage properties and alloy compositions as well as phase structures are discussed emphatically.For large-scale applications on MH tanks,it is necessary to develop low-cost and high-performance V–Ti-based solid solution alloys with high reversible hydrogen storage capacity,good cyclic durability,and excellent activation performance. 展开更多
关键词 Hydrogen storage V-Ti-based solid solution alloys Metal hydride tank Hydrogen storage properties Cyclic stability
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Methods for Exact Solutions of Nonlinear Ordinary Differential Equations
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作者 Robert CONTE Micheline MUSETTE +1 位作者 Tuen Wai NG WU Chengfa 《数学进展》 北大核心 2025年第2期379-389,共11页
In order to find closed form solutions of nonintegrable nonlinear ordinary differential equations,numerous tricks have been proposed.The goal of this short review is to explain how a theorem of Eremenko on meromorphic... In order to find closed form solutions of nonintegrable nonlinear ordinary differential equations,numerous tricks have been proposed.The goal of this short review is to explain how a theorem of Eremenko on meromorphic solutions of some nonlinear ODEs together with some classical,19th-century results,can be turned into algorithms(thus avoiding ad hoc assumptions)which provide all(as opposed to some)solutions in a precise class.To illustrate these methods,we present some new such exact solutions,physically relevant. 展开更多
关键词 elliptic solution complex Ginzburg-Landau equation Closed-form solution Nevanlinna theory
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Progress in study of spray pyrolysis technology for chloride salt solutions in rare earth extraction and separation processes 被引量:1
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作者 Ziyi Cheng Xiaowei Huang +5 位作者 Zongyu Feng Jianping Long Hai Yu Meng Wang Juanyu Yang Haiqing Hao 《Journal of Rare Earths》 2025年第10期2053-2064,I0001,共13页
This paper focuses on the preparation of rare earth oxide products from rare earth chloride solutions during the rare earth extraction and separation processes,as well as the recycling of magnesium chloride solutions.... This paper focuses on the preparation of rare earth oxide products from rare earth chloride solutions during the rare earth extraction and separation processes,as well as the recycling of magnesium chloride solutions.It proposes the idea of introducing spray pyrolysis technology into the rare earth extraction and separation processes.This paper briefly describes the development history of chloride spray pyrolysis technology,focusing on the research status and application progress of rare earth chloride solution and magnesium chloride solution spray pyrolysis technology,as well as spray pyrolysis equipment.The paper also analyzes the challenges and technical intricacies associated with applying spray pyrolysis technology to chloride solutions in the rare earth extraction and separation processes.Additionally,it explores future trends and proposes strategies to facilitate the full recycling of acids and bases,streamline the process flow,and enhance the prospects for green and low-carbon rare earth metallurgy. 展开更多
关键词 Rare earths Separation processes Spray pyrolysis technology Chloride salt solutions Green recycling
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Investigation of the formation processes of CO_(2) hydrate films on the interface of liquid carbon dioxide with humic acids solutions 被引量:1
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作者 Aleksey K.Sagidullin Sergey S.Skiba +1 位作者 Tatyana P.Adamova Andrey Y.Manakov 《Chinese Journal of Chemical Engineering》 2025年第3期53-61,共9页
Morphology and growth rate of carbon dioxide hydrate on the interface between liquid carbon dioxide and humic acid solutions were studied in this work.It was found that after the growth of the hydrate film at the inte... Morphology and growth rate of carbon dioxide hydrate on the interface between liquid carbon dioxide and humic acid solutions were studied in this work.It was found that after the growth of the hydrate film at the interface,further growth of hydrate due to the suction of water in the capillary system formed between the wall of the cuvette and the end boundary of the hydrate layer occurs.Most probably,substantial effects on the formation of this capillary system may be caused by variations in reactor wall properties,for example,hydrophobic-hydrophilic balance,roughness,etc.We found,that the rate of CO_(2) hydrate film growth on the surface of the humic acid aqueous solution is 4-fold to lower in comparison with the growth rate on the surface of pure water.We suppose that this is caused by the adsorption of humic acid associates on the surface of hydrate particles and,as a consequence,by the deceleration of the diffusion of dissolved carbon dioxide to the growing hydrate particle. 展开更多
关键词 HYDRATES Carbon dioxide Humic acids solutions Reaction kinetics Liquid liquid reaction Film growth
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Peaked traveling wave solutions of the modified highly nonlinear Novikov equation 被引量:1
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作者 LI Hui-jun WEN Zhen-shu LI Shao-yong 《Applied Mathematics(A Journal of Chinese Universities)》 2025年第2期375-394,共20页
In this paper,we focus on peaked traveling wave solutions of the modified highly nonlinear Novikov equation by dynamical systems approach.We obtain a traveling wave system which is a singular planar dynamical system w... In this paper,we focus on peaked traveling wave solutions of the modified highly nonlinear Novikov equation by dynamical systems approach.We obtain a traveling wave system which is a singular planar dynamical system with three singular straight lines,and derive all possible phase portraits under corresponding parameter conditions.Then we show the existence and dynamics of two types of peaked traveling wave solutions including peakons and periodic cusp wave solutions.The exact explicit expressions of two peakons are given.Besides,we also derive smooth solitary wave solutions,periodic wave solutions,compacton solutions,and kink-like(antikink-like)solutions.Numerical simulations are further performed to verify the correctness of the results.Most importantly,peakons and periodic cusp wave solutions are newly found for the equation,which extends the previous results. 展开更多
关键词 modified highly nonlinear Novikov equation bifurcation dynamics peakons periodic cusp wave solutions
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Normalized Solutions of Nonlinear Choquard Equations with Nonconstant Potential
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作者 LI Nan XU Liping 《应用数学》 北大核心 2025年第1期14-29,共16页
In this paper,we mainly focus on a type of nonlinear Choquard equations with nonconstant potential.Under appropriate hypotheses on potential function and nonlinear terms,we prove that the above Choquard equation with ... In this paper,we mainly focus on a type of nonlinear Choquard equations with nonconstant potential.Under appropriate hypotheses on potential function and nonlinear terms,we prove that the above Choquard equation with prescribed 2-norm has some normalized solutions by introducing variational methods. 展开更多
关键词 Nonlinear Choquard equation Potential function Variational method Normalized solution
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Solution loss behavior of cokes and its kinetics under hydrogen-enriched atmosphere
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作者 YAN Jingchong MA Kaixiang +6 位作者 GE Rong LEI Zhiping LI Zhanku ZHANG Weidong REN Shibiao WANG Zhicai SHUI Hengfu 《燃料化学学报(中英文)》 北大核心 2025年第7期1123-1136,共14页
Hydrogen-enriched ironmaking presents a promising approach to mitigate coke consumption and carbon emission in blast furnace(BF)operations.This work investigated the relationship between the structural features of cok... Hydrogen-enriched ironmaking presents a promising approach to mitigate coke consumption and carbon emission in blast furnace(BF)operations.This work investigated the relationship between the structural features of cokes and their reactivity towards solution loss(SL),especially under hydrogen-enriched atmospheres.Six cokes were characterized,and their SL behaviors were examined under varying atmospheres to elucidate the effects of hydrogen enrichment.The results indicate that an increase in fixed carbon content leads to a decrease in the coke reactivity index(CRI)and an increase in coke strength after reaction(CSR),in the CO_(2) atmosphere,the CSR of coke increases from 35.76%−62.83%,while in the 90CO_(2)/10H_(2) atmosphere,the CSR of coke increases from 65.67%−84.09%.There is a good linear relationship between CRI and microcrystalline structure parameters of coke.Cokes with larger crystalline size,lower amorphous content,and smaller optical texture index(OTI)values show enhanced resistance to degradation and maintain structural integrity in BF.Kinetic analysis performed with the shifted-modified-random pore model(S-MRPM)reveals that alterations in pore structure and intrinsic mineral composition significantly influence the reaction rate.The introduction of a small amount of water vapor raises SL rates,whereas a minor addition of hydrogen(<10%)decelerates SL due to its incomplete conversion to water vapor and the reduced partial pressure of the gasifying agent.Thermodynamic calculations also indicate that the introduced hydrogen does not convert into the same fraction of water vapor.The shift from chemical reaction control to gas diffusion control as the rate-determining step with rising temperatures during SL process was confirmed,and the introduction of hydrogen does not notably alter SL behavior.This result demonstrated that introducing a small amount of hydrogen(<10%)can mitigate SL rates,thereby enhancing coke strength and reducing coke consumption and carbon emissions. 展开更多
关键词 hydrogen-enrichment cokes solution loss KINETICS activation energy
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Periodic Solutions for a Stochastic Stage-structure Predator-prey Model with Impulses
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作者 HOU Meiting QIU Xiaoling 《数学进展》 北大核心 2025年第6期1307-1318,共12页
A stochastic stage-structure predator-prey system with impulsive effect is investigated.First,we build the corresponding system without impulse in order to demonstrate the existence and uniqueness of the global positi... A stochastic stage-structure predator-prey system with impulsive effect is investigated.First,we build the corresponding system without impulse in order to demonstrate the existence and uniqueness of the global positive solution.Second,by selecting an appropriate Lyapunov function,we provide the sufficient condition for the existence of a positive T-periodic solution.Finally,numerical simulations illustrate our theoretical results,which show that the impulse or the white noises can result in the extinction of the predator in a certain condition. 展开更多
关键词 periodic solution stochastic noise IMPULSE
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