As emerging two-dimensional(2D)materials,carbides and nitrides(MXenes)could be solid solutions or organized structures made up of multi-atomic layers.With remarkable and adjustable electrical,optical,mechanical,and el...As emerging two-dimensional(2D)materials,carbides and nitrides(MXenes)could be solid solutions or organized structures made up of multi-atomic layers.With remarkable and adjustable electrical,optical,mechanical,and electrochemical characteristics,MXenes have shown great potential in brain-inspired neuromorphic computing electronics,including neuromorphic gas sensors,pressure sensors and photodetectors.This paper provides a forward-looking review of the research progress regarding MXenes in the neuromorphic sensing domain and discussed the critical challenges that need to be resolved.Key bottlenecks such as insufficient long-term stability under environmental exposure,high costs,scalability limitations in large-scale production,and mechanical mismatch in wearable integration hinder their practical deployment.Furthermore,unresolved issues like interfacial compatibility in heterostructures and energy inefficiency in neu-romorphic signal conversion demand urgent attention.The review offers insights into future research directions enhance the fundamental understanding of MXene properties and promote further integration into neuromorphic computing applications through the convergence with various emerging technologies.展开更多
Superconductivity in two-dimensional(2D)materials has attracted considerable attention due to their unique physical properties and potential for high-temperature operation.Boron-based 2D compounds are particularly pro...Superconductivity in two-dimensional(2D)materials has attracted considerable attention due to their unique physical properties and potential for high-temperature operation.Boron-based 2D compounds are particularly promising,thanks to their structural flexibility and the emergence of strong electron-phonon coupling(EPC)associated with light elements.While most previous studies have focused on stabilizing boron sheets through metal incorporation,we propose an alternative approach based on multicenter bonding enabled by group-IV non-metallic elements(Si,Ge,Sn).The resulting XB_(2)(X=Si,Ge,Sn)monolayers,which adopt a MgB_(2)-like monolayer configuration,are stabilized by a seven-center two-electron(7c-2e)bonding network between the X atoms and the boron honeycomb lattice.This bonding lowers the energy of the B-p_(z)orbitals and enhances lattice stability.The superconducting transition temperature(T_(c))increases significantly with the atomic number of X—from 4.7 K in SiB_(2)to 13.3 K in GeB_(2)and 24.9 K in SnB_(2)—driven by an increased carrier density near the Fermi level(E_(F))and softening of the high-frequency E_(2)phonon mode.Furthermore,we design a SnB_4 monolayer,in which a Sn layer is sandwiched between the two boron layers.This structure enriches in-plane phonon modes and strengthens EPC,yielding a T_(c)of 38 K,close to the McMillan limit.These findings highlight the critical role of multicenter bonding and targeted phonon engineering in enabling high-T_(c)2D boron-based superconductors.展开更多
Two-dimensional(2D)multilayer kagome materials hold significant research value for regulating kagome-related physical properties and exploring quantum effects.However,their development is hindered by the scarcity of a...Two-dimensional(2D)multilayer kagome materials hold significant research value for regulating kagome-related physical properties and exploring quantum effects.However,their development is hindered by the scarcity of available material systems,making the identification of novel 2D multilayer kagome candidates particularly important.In this work,three types of 2D materials with trilayer kagome lattices,namely Sc_(6)S_(5)X_(6)(X=Cl,Br,I),are predicted based on first-principles calculations.These 2D materials feature two kagome lattices composed of Sc atoms and one kagome lattice composed of S atoms.Stability analysis indicates that these materials can exist as free-standing 2D materials.Electronic structure calculations reveal that Sc_(6)S_(5)X_(6)are narrow-bandgap semiconductors(0.76–0.95 e V),with their band structures exhibiting flat bands contributed by Sc-based kagome lattices and Dirac band gaps resulting from symmetry breaking.The sulfur-based kagome lattice in the central layer contributes an independent flat band below the Fermi level.Additionally,Sc_(6)S_(5)X_(6)exhibit high carrier mobility,with hole and electron mobilities reaching up to 10^(3)cm^(2)·V^(-1)·s^(-1),indicating potential applications in low-dimensional electronic devices.This work provides an excellent example for the development of novel multilayer 2D kagome materials.展开更多
A two-dimensional nonlinear sloshing problem is analyzed by means of the fully nonlinear theory and time domain second order theory of water waves. Liquid sloshing in a rectangular container Subjected to a horizontal ...A two-dimensional nonlinear sloshing problem is analyzed by means of the fully nonlinear theory and time domain second order theory of water waves. Liquid sloshing in a rectangular container Subjected to a horizontal excitation is simulated by the finite element method. Comparisons between the two theories are made based on their numerical results. It is found that good agreement is obtained for the case of small amplitude oscillation and obvious differences occur for large amplitude excitation. Even though, the second order solution can still exhibit typical nonlinear features of nonlinear wave and can be used instead of the fully nonlinear theory.展开更多
Smoothed particle hydrodynamics（SPH） is a mesh-free adaptive Lagrangian particle method with attractive features for dealing with the free surface flow.This paper applies the SPH method to simulate the large-amplitu...Smoothed particle hydrodynamics（SPH） is a mesh-free adaptive Lagrangian particle method with attractive features for dealing with the free surface flow.This paper applies the SPH method to simulate the large-amplitude lateral sloshing both with and without a floating body,and the vertical parametrically-excited sloshing in a two-dimensional tank.The numerical results show that the SPH approach has an obvious advantage over conventional mesh-based methods in handling nonlinear sloshing problems such as violent fluid-solid interaction,and flow separation and wave-breaking on the free fluid surface.The SPH method provides a new alternative and an effective way to solve these special strong nonlinear sloshing problems.展开更多
In this research, liquid sloshing behavior in a 2-D rectangular tank was simulated using ANSYS-FLUENT software subject to single or multiple-coupled external excitations （such as sway coupled with roll, and sway and ...In this research, liquid sloshing behavior in a 2-D rectangular tank was simulated using ANSYS-FLUENT software subject to single or multiple-coupled external excitations （such as sway coupled with roll, and sway and roll coupled with heave）. The volume of fluid （VOF） method was used to track the free surface of sloshing. External excitation was imposed through the motion of the tank by using the dynamic mesh technique. The study shows that if the tank is subjected to multiple coupled excitations and resonant excitation frequencies, liquid sloshing will become violent and sloshing loads, including impact on the top wall, will be intensified.展开更多
Numerical simulation of a two-dimensional nonlinear sloshing problem is preceded by the finite element method. Two theories are used. One is fully nonlinear theory; the other is time domain second order theory. A liqu...Numerical simulation of a two-dimensional nonlinear sloshing problem is preceded by the finite element method. Two theories are used. One is fully nonlinear theory; the other is time domain second order theory. A liquid sloshing in a rectangular container subjected to a horizontal excitation is simulated using these two theories. Numerical results are obtained and comparisons are made. It is found that a good agreement is obtained for the case of small amplitude oscillation. For the situation of large amplitude excitation, although the differences between using the two theories are obvious the second order solution can still exhibit typical nonlinear features of nonlinear wave.展开更多
The proliferation of wearable biodevices has boosted the development of soft,innovative,and multifunctional materials for human health monitoring.The integration of wearable sensors with intelligent systems is an over...The proliferation of wearable biodevices has boosted the development of soft,innovative,and multifunctional materials for human health monitoring.The integration of wearable sensors with intelligent systems is an overwhelming tendency,providing powerful tools for remote health monitoring and personal health management.Among many candidates,two-dimensional(2D)materials stand out due to several exotic mechanical,electrical,optical,and chemical properties that can be efficiently integrated into atomic-thin films.While previous reviews on 2D materials for biodevices primarily focus on conventional configurations and materials like graphene,the rapid development of new 2D materials with exotic properties has opened up novel applications,particularly in smart interaction and integrated functionalities.This review aims to consolidate recent progress,highlight the unique advantages of 2D materials,and guide future research by discussing existing challenges and opportunities in applying 2D materials for smart wearable biodevices.We begin with an in-depth analysis of the advantages,sensing mechanisms,and potential applications of 2D materials in wearable biodevice fabrication.Following this,we systematically discuss state-of-the-art biodevices based on 2D materials for monitoring various physiological signals within the human body.Special attention is given to showcasing the integration of multi-functionality in 2D smart devices,mainly including self-power supply,integrated diagnosis/treatment,and human–machine interaction.Finally,the review concludes with a concise summary of existing challenges and prospective solutions concerning the utilization of2D materials for advanced biodevices.展开更多
A functional interlayer based on two-dimensional(2D)porous modified vermiculite nanosheets(PVS)was obtained by acid-etching vermiculite nanosheets.The as-obtained 2D porous nanosheets exhibited a high specific surface...A functional interlayer based on two-dimensional(2D)porous modified vermiculite nanosheets(PVS)was obtained by acid-etching vermiculite nanosheets.The as-obtained 2D porous nanosheets exhibited a high specific surface area of 427 m^(2)·g^(-1)and rich surface active sites,which help restrain polysulfides(LiPSs)through good physi-cal and chemical adsorption,while simultaneously accelerating the nucleation and dissolution kinetics of Li_(2)S,effec-tively suppressing the shuttle effect.The assembled lithium-sulfur batteries(LSBs)employing the PVS-based inter-layer delivered a high initial discharge capacity of 1386 mAh·g^(-1)at 0.1C(167.5 mAh·g^(-1)),long-term cycling stabil-ity,and good rate property.展开更多
This paper investigates ruin,capital injection,and dividends for a two-dimensional risk model.The model posits that surplus levels of insurance companies are governed by a perturbed composite Poisson risk model.This m...This paper investigates ruin,capital injection,and dividends for a two-dimensional risk model.The model posits that surplus levels of insurance companies are governed by a perturbed composite Poisson risk model.This model introduces a dependence between the two surplus levels,present in both the associated perturbations and the claims resulting from common shocks.Critical levels of capital injection and dividends are established for each of the two risks.The surplus levels are observed discretely at fixed intervals,guiding decisions on capital injection,dividends,and ruin at these junctures.This study employs a two-dimensional Fourier cosine series expansion method to approximate the finite time expected discounted operating cost until ruin.The ensuing approximation error is also quantified.The validity and accuracy of the method are corroborated through numerical examples.Furthermore,the research delves into the optimal capital allocation problem.展开更多
Lithium-sulfur(Li-S)batteries with high energy density and capacity have garnered significant research attention among various energy storage devices.However,the shuttle effect of polysulfides(LiPSs)remains a major ch...Lithium-sulfur(Li-S)batteries with high energy density and capacity have garnered significant research attention among various energy storage devices.However,the shuttle effect of polysulfides(LiPSs)remains a major challenge for their practical application.The design of battery separators has become a key aspect in addressing the challenge.MXenes,a promising two-dimensional(2D)material,offer exceptional conductivity,large surface area,high mechanical strength,and active sites for surface reactions.When assembled into layered films,MXenes form highly tunable two-dimensional channels ranging from a few angstroms to over 1 nm.These nanoconfined channels are instrumental in facilitating lithium-ion transport while effectively impeding the shuttle effect of LiPSs,which are essential for improving the specific capacity and cyclic stability of Li-S batteries.Substantial progress has been made in developing MXenes-based separators for Li-S batteries,yet there remains a research gap in summarizing advancements from the perspective of interlayer engineering.This entails maintaining the 2D nanochannels of layered MXenes-based separators while modulating the physicochemical environment within the MXenes interlayers through targeted modifications.This review highlights advancements in in situ modification of MXenes and their integration with 0D,1D,and 2D materials to construct laminated nanocomposite separators for Li-S batteries.The future development directions of MXenes-based materials in Li-S energy storage devices are also outlined,to drive further advancements in MXenes for Li-S battery separators.展开更多
The growing demand for ocean space has generated significant interest in multi-body floating systems,where gap resonance in confined regions plays a critical role in ensuring the safety of offshore operations.This stu...The growing demand for ocean space has generated significant interest in multi-body floating systems,where gap resonance in confined regions plays a critical role in ensuring the safety of offshore operations.This study develops a numerical tank model using the Smoothed Particle Hydrodynamics(SPH)method,implemented through the open-source code DualSPHysics,to investigate hydrodynamic resonance in a twin-floater system and to examine the influence of internal tank sloshing on its hydrodynamic characteristics.The hydrodynamic behavior of the gap flow between a fixed twin-floater system in the numerical tank is validated through systematic comparison with experimental data.Subsequently,the wave-induced motions and forces on a twin-floater system are compared with those on a single floater.Furthermore,the effects of internal tank sloshing on the hydrodynamic response of the twin-floater system are explored.A parametric study is conducted to analyze the influence of incident wave frequency on floater motion and tank sloshing dynamics.The results show that the presence of an internal tank can significantly reduce pitch motion and vertical forces on the floating body,while exerting minimal influence on heave motion and horizontal forces.The findings provide new insights into the hydrodynamic performance of twin-floater systems and their interaction with internal sloshing phenomena.展开更多
This paper presents a numerical investigation of nonlinear sloshing in a prismatic tank.A three-dimensional,twophase flow model based on Cartesian grid is developed to simulate the phenomenon.The model solves incompre...This paper presents a numerical investigation of nonlinear sloshing in a prismatic tank.A three-dimensional,twophase flow model based on Cartesian grid is developed to simulate the phenomenon.The model solves incompressible Navier-Stokes equations,utilizing the fractional step method for velocity-pressure decoupling.The finite difference method discretizes spatial derivatives,with specific schemes implemented to enhance model robustness.Model validation involves simulating benchmark cases,and comparing wave profiles and pressure results with published experimental data and numerical findings.The model demonstrates robustness and accuracy in simulating violent sloshing.The validated model examines sloshing in a partially filled prismatic tank under combined surge and roll excitations.The study employs eight frequencies encompassing the natural frequencies of tank roll and surge motions.Roll motion excitation is fixed at 2°,while surge motion considers three excitation amplitudes(0.0 m,0.01 m,and 0.02m).Analysis reveals the effects of surge amplitude and excitation frequency on wave patterns,amplitudes,and pressure peaks.Results indicate the presence of multi-component waves,including transverse,diagonal,and longitudinal waves.Furthermore,the findings demonstrate a reduction in the natural frequency for surge motion through pressure peak analysis.展开更多
The coupling effect between ship motion and liquid sloshing in a beam sea is investigated,with a focus on the influence of liquid types,namely,water and liquefied natural gas(LNG),on the coupling dynamics.A hybrid num...The coupling effect between ship motion and liquid sloshing in a beam sea is investigated,with a focus on the influence of liquid types,namely,water and liquefied natural gas(LNG),on the coupling dynamics.A hybrid numerical model,combining a potential flow model and computational fluid dynamics methods,is employed to simulate these interactions.Numerical validation is performed using experimental data from water sloshing tests.Comparisons between water and LNG reveal that liquid type has minimal effects on the ship’s roll motion response in a beam sea,provided the total liquid masses are the same.Regarding sloshing impact pressure,although differences between LNG and water results are minor,substituting LNG with water in physical experiments is shown to yield reliable results.展开更多
In recent years,tuned liquid dampers(TLDs)have emerged as a focal point of research due to their remarkable potential for structural vibration mitigation.Yet,progress in this field remains constrained by an incomplete...In recent years,tuned liquid dampers(TLDs)have emerged as a focal point of research due to their remarkable potential for structural vibration mitigation.Yet,progress in this field remains constrained by an incomplete understanding of the fundamental mechanisms governing sloshing-induced loads in liquid-filled containers.Aqueducts present a distinctive case,as the capacity of their contained water to function effectively as a TLD remains uncertain.To address this gap,the present study investigates the generation mechanisms of sloshing loads under non-resonant cases through a two-dimensional(2D)computational fluid dynamics(CFD)model developed in ANSYS Fluent.The incompressible Reynolds-Averaged Navier–Stokes(RANS)equations are solved,while the Volume of Fluid(VOF)method captures the evolution of the air–water interface.Turbulent flow behavior is modeled using the RNG-approach.The ensuing results reveal the dynamic characteristics of the horizontal force(fℎ)and the fluctuating component of the vertical force(Fof).Fh is predominantly governed by the inertia of the deep-water region and its phase varies coherently with the aqueduct’s acceleration.With increasing excitation amplitude(A)and frequency(f),the contribution of deep-water inertia to𝐹ℎintensifies markedly,accounting for 82.6–92.1%of the total horizontal load at an excitation amplitude of 0.15 m and frequencies of 1.0–1.6 Hz.The extreme values of Fof arise primarily from asymmetric static pressures induced by free-surface fluctuations,which are further amplified when wall gaps appear at large amplitudes(A≥10 cm)and high frequencies(f≥1.4 Hz).Unlike resonant cases dominated by free-surface resonance,non-resonant sloshing loads are principally driven by deep-water inertia and motion-induced surface asymmetry.展开更多
Titanium dioxide(TiO_(2))has been an important protective ingredient in mineral-based sunscreens since the 1990s.However,traditional TiO_(2)nanoparticle formulations have seen little improvement over the past decades ...Titanium dioxide(TiO_(2))has been an important protective ingredient in mineral-based sunscreens since the 1990s.However,traditional TiO_(2)nanoparticle formulations have seen little improvement over the past decades and continue to face persistent challenges related to light transmission,biosafety,and visual appearance.Here,we report the discovery of two-dimensional(2D)TiO_(2),characterized by a micro-sized lateral dimension(~1.6μm)and atomic-scale thickness,which fundamentally resolves these long-standing issues.The 2D structure enables exceptional light management,achieving 80%visible light transparency—rendering it nearly invisible on the skin—while maintaining UV-blocking performance comparable to unmodified rutile TiO_(2)nanoparticles.Its larger lateral size results in a two-orders-of-magnitude reduction in skin penetration(0.96 w/w%),significantly enhancing biosafety.Moreover,the unique layered architecture inherently suppresses the generation of reactive oxygen species(ROS)under sunlight exposure,reducing the ROS generation rate by 50-fold compared to traditional TiO_(2)nanoparticles.Through precise metal element modulation,we further developed the first customizable sunscreen material capable of tuning UV protection ranges and automatically matching diverse skin tones.The 2D TiO_(2)offers a potentially transformative approach to modern sunscreen formulation,combining superior UV protection,enhanced safety and a natural appearance.展开更多
In recent years,tuned liquid dampers(TLDs)have attracted significant research interest;however,overall progress has been limited due to insufficient understanding of the mechanisms governing sloshing-induced loads.In ...In recent years,tuned liquid dampers(TLDs)have attracted significant research interest;however,overall progress has been limited due to insufficient understanding of the mechanisms governing sloshing-induced loads.In particular,it remains unclear whether the water in aqueducts—common water-diversion structures in many countries—can serve as an effective TLD.This study investigates the generation mechanisms of sloshing loads during the first-order transverse resonance of water in a U-shaped aqueduct using a two-dimensional(2D)numerical model.The results reveal that,at the equilibrium position,the free surface difference between the left and right walls,the horizontal force on the aqueduct,and the fluctuating component of the vertical force all reach their maxima,with energy predominantly stored as potential energy.At the maximum displacement position,the surface difference and horizontal force drop to zero,while the fluctuating vertical force attains its minimum and energy shifts primarily to kinetic form.At this stage,static pressure is governed solely by the vertical convective acceleration,whereas at equilibrium it is closely linked to both the free surface difference and vertical local acceleration of the water.This dynamic energy exchange generates vertical force oscillations even when the free surface appears nearly symmetric.展开更多
Owing to their rolling friction,two-dimensional piston pumps are highly suitable as power components for electro-hydrostatic actuators(EHAs).These pumps are particularly advantageous for applications requiring high ef...Owing to their rolling friction,two-dimensional piston pumps are highly suitable as power components for electro-hydrostatic actuators(EHAs).These pumps are particularly advantageous for applications requiring high efficiency and reliability.However,the ambiguity surrounding the output flow characteristics of individual two-dimensional pumps poses a significant challenge in achieving precise closed-loop control of the EHA positions.To address this issue,this study established a comprehensive numerical model that included gap leakage to analyze the impact of leakage on the output flow characteristics of a two-dimensional piston pump.The validity of the numerical analysis was indirectly confirmed through meticulous measurements of the leakage and volumetric efficiency,ensuring robust results.The research findings indicated that,at lower pump speeds,leakage significantly affected the output flow rate,leading to potential inefficiencies in the system.Conversely,at higher rotational speeds,the impact of leakage was less pronounced,implying that the influence of leakage on the pump outlet flow must be carefully considered and managed for EHAs to perform position servo control.Additionally,the research demonstrates that two-dimensional motion does not have a unique or additional effect on pump leakage,thus simplifying the design considerations.Finally,the study concluded that maintaining an oil-filled leakage environment is beneficial because it helps reduce the impact of leakage and enhances the overall volumetric efficiency of the pump system.展开更多
Environmental catalysis has been considered one of the important research topics.Some technologies(e.g.,photocatalysis and electrocatalysis)have been intensively developed with the advance of synthetic technologies of...Environmental catalysis has been considered one of the important research topics.Some technologies(e.g.,photocatalysis and electrocatalysis)have been intensively developed with the advance of synthetic technologies of catalytical materials.In 2019,we discussed the development trend of this field,and wrote a roadmap on this topic in Chinese Chemical Letters(30(2019)2065-2088).Nowadays,we discuss it again from a new viewpoint along this road.In this paper,several subtopics are discussed,e.g.,photocatalysis based on titanium dioxide,violet phosphorus,graphitic carbon and covalent organic frameworks,electrocatalysts based on carbon,metal-and covalent-organic framework.Finally,we hope that this roadmap can enrich the development of two-dimensional materials in environmental catalysis with novel understanding,and give useful inspiration to explore new catalysts for practical applications.展开更多
It is a key challenge to prepare two-dimensional diamond(2D-diamond).Herein,we develop a method for synthesizing 2D-diamond by depositing monodisperse tantalum(Ta)atoms onto graphene substrates using a hot-filament ch...It is a key challenge to prepare two-dimensional diamond(2D-diamond).Herein,we develop a method for synthesizing 2D-diamond by depositing monodisperse tantalum(Ta)atoms onto graphene substrates using a hot-filament chemical vapor deposition setup,followed by annealing treatment under different temperatures at ambient pressure.The results indicate that when the annealing temperature increases from 700℃ to 1000℃,the size of the 2D-diamond found in the samples gradually increases from close to 20 nm to around 30 nm.Meanwhile,the size and number of amorphous carbon spheres and Ta-containing compounds between the graphene layers gradually increase.As the annealing temperature continues to rise to 1100℃,a significant aggregation of Ta-containing compounds is observed in the samples,with no diamond structure detected.This further confirms that monodisperse Ta atoms play a key role in graphene phase transition into 2D-diamond.This study provides a novel method for the ambient-pressure phase transition of graphene into 2D-diamond.展开更多
基金supported by the NSFC(12474071)Natural Science Foundation of Shandong Province(ZR2024YQ051,ZR2025QB50)+6 种基金Guangdong Basic and Applied Basic Research Foundation(2025A1515011191)the Shanghai Sailing Program(23YF1402200,23YF1402400)funded by Basic Research Program of Jiangsu(BK20240424)Open Research Fund of State Key Laboratory of Crystal Materials(KF2406)Taishan Scholar Foundation of Shandong Province(tsqn202408006,tsqn202507058)Young Talent of Lifting engineering for Science and Technology in Shandong,China(SDAST2024QTB002)the Qilu Young Scholar Program of Shandong University。
文摘As emerging two-dimensional(2D)materials,carbides and nitrides(MXenes)could be solid solutions or organized structures made up of multi-atomic layers.With remarkable and adjustable electrical,optical,mechanical,and electrochemical characteristics,MXenes have shown great potential in brain-inspired neuromorphic computing electronics,including neuromorphic gas sensors,pressure sensors and photodetectors.This paper provides a forward-looking review of the research progress regarding MXenes in the neuromorphic sensing domain and discussed the critical challenges that need to be resolved.Key bottlenecks such as insufficient long-term stability under environmental exposure,high costs,scalability limitations in large-scale production,and mechanical mismatch in wearable integration hinder their practical deployment.Furthermore,unresolved issues like interfacial compatibility in heterostructures and energy inefficiency in neu-romorphic signal conversion demand urgent attention.The review offers insights into future research directions enhance the fundamental understanding of MXene properties and promote further integration into neuromorphic computing applications through the convergence with various emerging technologies.
基金supported by the National Natural Science Foundation of China(Grant Nos.22372142,12304028,12404027)the Foreign Expert Introduction Program(Grant No.G2023003004L)+6 种基金the Central Guiding Local Science and Technology Development Fund Projects(Grant No.236Z7605G)the Natural Science Foundation of Hebei Province(Grant Nos.B2024203051,A2024203023,A2024203002)the Science and Technology Project of Hebei Education Department(Grant No.JZX2023020)the Innovation Capability Improvement Project of Hebei Province(Grant No.22567605H)the Hebei Province Yan Zhao Huang Jin Tai Talent Program(Postdoctoral Platform,Grant No.B2024003003)the financial support from the Spanish Ministry of Science and Innovation(Grant No.PID2022139230NB-I00)the Department of Education,Universities and Research of the Basque Government and the University of the Basque Country(Grant No.IT1707-22)。
文摘Superconductivity in two-dimensional(2D)materials has attracted considerable attention due to their unique physical properties and potential for high-temperature operation.Boron-based 2D compounds are particularly promising,thanks to their structural flexibility and the emergence of strong electron-phonon coupling(EPC)associated with light elements.While most previous studies have focused on stabilizing boron sheets through metal incorporation,we propose an alternative approach based on multicenter bonding enabled by group-IV non-metallic elements(Si,Ge,Sn).The resulting XB_(2)(X=Si,Ge,Sn)monolayers,which adopt a MgB_(2)-like monolayer configuration,are stabilized by a seven-center two-electron(7c-2e)bonding network between the X atoms and the boron honeycomb lattice.This bonding lowers the energy of the B-p_(z)orbitals and enhances lattice stability.The superconducting transition temperature(T_(c))increases significantly with the atomic number of X—from 4.7 K in SiB_(2)to 13.3 K in GeB_(2)and 24.9 K in SnB_(2)—driven by an increased carrier density near the Fermi level(E_(F))and softening of the high-frequency E_(2)phonon mode.Furthermore,we design a SnB_4 monolayer,in which a Sn layer is sandwiched between the two boron layers.This structure enriches in-plane phonon modes and strengthens EPC,yielding a T_(c)of 38 K,close to the McMillan limit.These findings highlight the critical role of multicenter bonding and targeted phonon engineering in enabling high-T_(c)2D boron-based superconductors.
基金supported by the Fundamental Research Funds for the Central Universities(WUT:2024IVA052 and Grant No.104972025KFYjc0089)。
文摘Two-dimensional(2D)multilayer kagome materials hold significant research value for regulating kagome-related physical properties and exploring quantum effects.However,their development is hindered by the scarcity of available material systems,making the identification of novel 2D multilayer kagome candidates particularly important.In this work,three types of 2D materials with trilayer kagome lattices,namely Sc_(6)S_(5)X_(6)(X=Cl,Br,I),are predicted based on first-principles calculations.These 2D materials feature two kagome lattices composed of Sc atoms and one kagome lattice composed of S atoms.Stability analysis indicates that these materials can exist as free-standing 2D materials.Electronic structure calculations reveal that Sc_(6)S_(5)X_(6)are narrow-bandgap semiconductors(0.76–0.95 e V),with their band structures exhibiting flat bands contributed by Sc-based kagome lattices and Dirac band gaps resulting from symmetry breaking.The sulfur-based kagome lattice in the central layer contributes an independent flat band below the Fermi level.Additionally,Sc_(6)S_(5)X_(6)exhibit high carrier mobility,with hole and electron mobilities reaching up to 10^(3)cm^(2)·V^(-1)·s^(-1),indicating potential applications in low-dimensional electronic devices.This work provides an excellent example for the development of novel multilayer 2D kagome materials.
文摘A two-dimensional nonlinear sloshing problem is analyzed by means of the fully nonlinear theory and time domain second order theory of water waves. Liquid sloshing in a rectangular container Subjected to a horizontal excitation is simulated by the finite element method. Comparisons between the two theories are made based on their numerical results. It is found that good agreement is obtained for the case of small amplitude oscillation and obvious differences occur for large amplitude excitation. Even though, the second order solution can still exhibit typical nonlinear features of nonlinear wave and can be used instead of the fully nonlinear theory.
基金National Science Foundation of China under Grant No. 51279133Open Research Fund Program of State Key Laboratory of Hydro-science and Engineering under Grant No. SKLHSE-2011-C-02
文摘Smoothed particle hydrodynamics（SPH） is a mesh-free adaptive Lagrangian particle method with attractive features for dealing with the free surface flow.This paper applies the SPH method to simulate the large-amplitude lateral sloshing both with and without a floating body,and the vertical parametrically-excited sloshing in a two-dimensional tank.The numerical results show that the SPH approach has an obvious advantage over conventional mesh-based methods in handling nonlinear sloshing problems such as violent fluid-solid interaction,and flow separation and wave-breaking on the free fluid surface.The SPH method provides a new alternative and an effective way to solve these special strong nonlinear sloshing problems.
基金Supported by the National Natural Science Foundation of China under Grant No.30770394.
文摘In this research, liquid sloshing behavior in a 2-D rectangular tank was simulated using ANSYS-FLUENT software subject to single or multiple-coupled external excitations （such as sway coupled with roll, and sway and roll coupled with heave）. The volume of fluid （VOF） method was used to track the free surface of sloshing. External excitation was imposed through the motion of the tank by using the dynamic mesh technique. The study shows that if the tank is subjected to multiple coupled excitations and resonant excitation frequencies, liquid sloshing will become violent and sloshing loads, including impact on the top wall, will be intensified.
文摘Numerical simulation of a two-dimensional nonlinear sloshing problem is preceded by the finite element method. Two theories are used. One is fully nonlinear theory; the other is time domain second order theory. A liquid sloshing in a rectangular container subjected to a horizontal excitation is simulated using these two theories. Numerical results are obtained and comparisons are made. It is found that a good agreement is obtained for the case of small amplitude oscillation. For the situation of large amplitude excitation, although the differences between using the two theories are obvious the second order solution can still exhibit typical nonlinear features of nonlinear wave.
基金the support from the National Natural Science Foundation of China(22272004,62272041)the Fundamental Research Funds for the Central Universities(YWF-22-L-1256)+1 种基金the National Key R&D Program of China(2023YFC3402600)the Beijing Institute of Technology Research Fund Program for Young Scholars(No.1870011182126)。
文摘The proliferation of wearable biodevices has boosted the development of soft,innovative,and multifunctional materials for human health monitoring.The integration of wearable sensors with intelligent systems is an overwhelming tendency,providing powerful tools for remote health monitoring and personal health management.Among many candidates,two-dimensional(2D)materials stand out due to several exotic mechanical,electrical,optical,and chemical properties that can be efficiently integrated into atomic-thin films.While previous reviews on 2D materials for biodevices primarily focus on conventional configurations and materials like graphene,the rapid development of new 2D materials with exotic properties has opened up novel applications,particularly in smart interaction and integrated functionalities.This review aims to consolidate recent progress,highlight the unique advantages of 2D materials,and guide future research by discussing existing challenges and opportunities in applying 2D materials for smart wearable biodevices.We begin with an in-depth analysis of the advantages,sensing mechanisms,and potential applications of 2D materials in wearable biodevice fabrication.Following this,we systematically discuss state-of-the-art biodevices based on 2D materials for monitoring various physiological signals within the human body.Special attention is given to showcasing the integration of multi-functionality in 2D smart devices,mainly including self-power supply,integrated diagnosis/treatment,and human–machine interaction.Finally,the review concludes with a concise summary of existing challenges and prospective solutions concerning the utilization of2D materials for advanced biodevices.
文摘A functional interlayer based on two-dimensional(2D)porous modified vermiculite nanosheets(PVS)was obtained by acid-etching vermiculite nanosheets.The as-obtained 2D porous nanosheets exhibited a high specific surface area of 427 m^(2)·g^(-1)and rich surface active sites,which help restrain polysulfides(LiPSs)through good physi-cal and chemical adsorption,while simultaneously accelerating the nucleation and dissolution kinetics of Li_(2)S,effec-tively suppressing the shuttle effect.The assembled lithium-sulfur batteries(LSBs)employing the PVS-based inter-layer delivered a high initial discharge capacity of 1386 mAh·g^(-1)at 0.1C(167.5 mAh·g^(-1)),long-term cycling stabil-ity,and good rate property.
基金supported by the Shihezi University High-Level Talents Research Startup Project(Project No.RCZK202521)the National Natural Science Foundation of China(Grant Nos.12271066,11871121,12171405)+1 种基金the Chongqing Natural Science Foundation Joint Fund for Innovation and Development Project(Project No.CSTB2024NSCQLZX0085)the Chongqing Normal University Foundation(Grant No.23XLB018).
文摘This paper investigates ruin,capital injection,and dividends for a two-dimensional risk model.The model posits that surplus levels of insurance companies are governed by a perturbed composite Poisson risk model.This model introduces a dependence between the two surplus levels,present in both the associated perturbations and the claims resulting from common shocks.Critical levels of capital injection and dividends are established for each of the two risks.The surplus levels are observed discretely at fixed intervals,guiding decisions on capital injection,dividends,and ruin at these junctures.This study employs a two-dimensional Fourier cosine series expansion method to approximate the finite time expected discounted operating cost until ruin.The ensuing approximation error is also quantified.The validity and accuracy of the method are corroborated through numerical examples.Furthermore,the research delves into the optimal capital allocation problem.
基金supported by Beijing Natural Science Foundation(Nos.2232037 and 2242035)the National Natural Science Foundation of China(Nos.22005012,22105012 and 51803183)+1 种基金Chunhui Plan Cooperative Project of Ministry of Education(No.202201298)the China Postdoctoral Science Foundation Funded Project(No.2023M733520).
文摘Lithium-sulfur(Li-S)batteries with high energy density and capacity have garnered significant research attention among various energy storage devices.However,the shuttle effect of polysulfides(LiPSs)remains a major challenge for their practical application.The design of battery separators has become a key aspect in addressing the challenge.MXenes,a promising two-dimensional(2D)material,offer exceptional conductivity,large surface area,high mechanical strength,and active sites for surface reactions.When assembled into layered films,MXenes form highly tunable two-dimensional channels ranging from a few angstroms to over 1 nm.These nanoconfined channels are instrumental in facilitating lithium-ion transport while effectively impeding the shuttle effect of LiPSs,which are essential for improving the specific capacity and cyclic stability of Li-S batteries.Substantial progress has been made in developing MXenes-based separators for Li-S batteries,yet there remains a research gap in summarizing advancements from the perspective of interlayer engineering.This entails maintaining the 2D nanochannels of layered MXenes-based separators while modulating the physicochemical environment within the MXenes interlayers through targeted modifications.This review highlights advancements in in situ modification of MXenes and their integration with 0D,1D,and 2D materials to construct laminated nanocomposite separators for Li-S batteries.The future development directions of MXenes-based materials in Li-S energy storage devices are also outlined,to drive further advancements in MXenes for Li-S battery separators.
基金supported by the National Natural Science Foundation of China(Nos.52271316 and 12302314)the Science and Technology Project in Guangzhou(No.2024A04J9886).
文摘The growing demand for ocean space has generated significant interest in multi-body floating systems,where gap resonance in confined regions plays a critical role in ensuring the safety of offshore operations.This study develops a numerical tank model using the Smoothed Particle Hydrodynamics(SPH)method,implemented through the open-source code DualSPHysics,to investigate hydrodynamic resonance in a twin-floater system and to examine the influence of internal tank sloshing on its hydrodynamic characteristics.The hydrodynamic behavior of the gap flow between a fixed twin-floater system in the numerical tank is validated through systematic comparison with experimental data.Subsequently,the wave-induced motions and forces on a twin-floater system are compared with those on a single floater.Furthermore,the effects of internal tank sloshing on the hydrodynamic response of the twin-floater system are explored.A parametric study is conducted to analyze the influence of incident wave frequency on floater motion and tank sloshing dynamics.The results show that the presence of an internal tank can significantly reduce pitch motion and vertical forces on the floating body,while exerting minimal influence on heave motion and horizontal forces.The findings provide new insights into the hydrodynamic performance of twin-floater systems and their interaction with internal sloshing phenomena.
基金financially supported by the Shandong Provincial Natural Science Foundation(Grant No.ZR2023QE063)。
文摘This paper presents a numerical investigation of nonlinear sloshing in a prismatic tank.A three-dimensional,twophase flow model based on Cartesian grid is developed to simulate the phenomenon.The model solves incompressible Navier-Stokes equations,utilizing the fractional step method for velocity-pressure decoupling.The finite difference method discretizes spatial derivatives,with specific schemes implemented to enhance model robustness.Model validation involves simulating benchmark cases,and comparing wave profiles and pressure results with published experimental data and numerical findings.The model demonstrates robustness and accuracy in simulating violent sloshing.The validated model examines sloshing in a partially filled prismatic tank under combined surge and roll excitations.The study employs eight frequencies encompassing the natural frequencies of tank roll and surge motions.Roll motion excitation is fixed at 2°,while surge motion considers three excitation amplitudes(0.0 m,0.01 m,and 0.02m).Analysis reveals the effects of surge amplitude and excitation frequency on wave patterns,amplitudes,and pressure peaks.Results indicate the presence of multi-component waves,including transverse,diagonal,and longitudinal waves.Furthermore,the findings demonstrate a reduction in the natural frequency for surge motion through pressure peak analysis.
基金supported by the Natural Science Foundation of China with Grant Nos.52371267 and 52171250。
文摘The coupling effect between ship motion and liquid sloshing in a beam sea is investigated,with a focus on the influence of liquid types,namely,water and liquefied natural gas(LNG),on the coupling dynamics.A hybrid numerical model,combining a potential flow model and computational fluid dynamics methods,is employed to simulate these interactions.Numerical validation is performed using experimental data from water sloshing tests.Comparisons between water and LNG reveal that liquid type has minimal effects on the ship’s roll motion response in a beam sea,provided the total liquid masses are the same.Regarding sloshing impact pressure,although differences between LNG and water results are minor,substituting LNG with water in physical experiments is shown to yield reliable results.
基金supported by Science and Technology Planning Project of Sichuan Province with Grant No.2023YFS0429supported by Science and Technology Project of China Road and Bridge Corporation with Grant No.P2220447+1 种基金supported by Foundation of Xinjiang Institute of Engineering 2024(Grant No.2024xgy072605)also supported by Sichuan Natural Science Foundation Project(Grant No.2024NSFSC0162).
文摘In recent years,tuned liquid dampers(TLDs)have emerged as a focal point of research due to their remarkable potential for structural vibration mitigation.Yet,progress in this field remains constrained by an incomplete understanding of the fundamental mechanisms governing sloshing-induced loads in liquid-filled containers.Aqueducts present a distinctive case,as the capacity of their contained water to function effectively as a TLD remains uncertain.To address this gap,the present study investigates the generation mechanisms of sloshing loads under non-resonant cases through a two-dimensional(2D)computational fluid dynamics(CFD)model developed in ANSYS Fluent.The incompressible Reynolds-Averaged Navier–Stokes(RANS)equations are solved,while the Volume of Fluid(VOF)method captures the evolution of the air–water interface.Turbulent flow behavior is modeled using the RNG-approach.The ensuing results reveal the dynamic characteristics of the horizontal force(fℎ)and the fluctuating component of the vertical force(Fof).Fh is predominantly governed by the inertia of the deep-water region and its phase varies coherently with the aqueduct’s acceleration.With increasing excitation amplitude(A)and frequency(f),the contribution of deep-water inertia to𝐹ℎintensifies markedly,accounting for 82.6–92.1%of the total horizontal load at an excitation amplitude of 0.15 m and frequencies of 1.0–1.6 Hz.The extreme values of Fof arise primarily from asymmetric static pressures induced by free-surface fluctuations,which are further amplified when wall gaps appear at large amplitudes(A≥10 cm)and high frequencies(f≥1.4 Hz).Unlike resonant cases dominated by free-surface resonance,non-resonant sloshing loads are principally driven by deep-water inertia and motion-induced surface asymmetry.
基金supported by the National Key Research and Development Project(No.2019YFA0705403)the National Natural Science Foundation of China(No.T2293693,52273311)+2 种基金the Guangdong Basic and Applied Basic Research Foundation(No.2020B0301030002)and the Shenzhen Basic Research Project(Nos.WDZC20200824091903001,JSGG20220831105402004,JCYJ20220818100806014)Shenzhen Major Science and Technology Projects(Nos.KCXFZ20240903094013018,KCXFZ20240903094203005)。
文摘Titanium dioxide(TiO_(2))has been an important protective ingredient in mineral-based sunscreens since the 1990s.However,traditional TiO_(2)nanoparticle formulations have seen little improvement over the past decades and continue to face persistent challenges related to light transmission,biosafety,and visual appearance.Here,we report the discovery of two-dimensional(2D)TiO_(2),characterized by a micro-sized lateral dimension(~1.6μm)and atomic-scale thickness,which fundamentally resolves these long-standing issues.The 2D structure enables exceptional light management,achieving 80%visible light transparency—rendering it nearly invisible on the skin—while maintaining UV-blocking performance comparable to unmodified rutile TiO_(2)nanoparticles.Its larger lateral size results in a two-orders-of-magnitude reduction in skin penetration(0.96 w/w%),significantly enhancing biosafety.Moreover,the unique layered architecture inherently suppresses the generation of reactive oxygen species(ROS)under sunlight exposure,reducing the ROS generation rate by 50-fold compared to traditional TiO_(2)nanoparticles.Through precise metal element modulation,we further developed the first customizable sunscreen material capable of tuning UV protection ranges and automatically matching diverse skin tones.The 2D TiO_(2)offers a potentially transformative approach to modern sunscreen formulation,combining superior UV protection,enhanced safety and a natural appearance.
基金Science and Technology Planning Project of Sichuan Province with Grant No.2023YFS0429supported by Science and Technology Project of China Road and Bridge Corporation with Grant No.P2220447+1 种基金supported by Foundation of Xinjiang Institute of Engineering 2024(Grant No.2024xgy072605)supported by Sichuan Natural Science Foundation Project(Grant No.2024NSFSC0162).The numerical calculations in this study have been done on Hefei advanced computing center.
文摘In recent years,tuned liquid dampers(TLDs)have attracted significant research interest;however,overall progress has been limited due to insufficient understanding of the mechanisms governing sloshing-induced loads.In particular,it remains unclear whether the water in aqueducts—common water-diversion structures in many countries—can serve as an effective TLD.This study investigates the generation mechanisms of sloshing loads during the first-order transverse resonance of water in a U-shaped aqueduct using a two-dimensional(2D)numerical model.The results reveal that,at the equilibrium position,the free surface difference between the left and right walls,the horizontal force on the aqueduct,and the fluctuating component of the vertical force all reach their maxima,with energy predominantly stored as potential energy.At the maximum displacement position,the surface difference and horizontal force drop to zero,while the fluctuating vertical force attains its minimum and energy shifts primarily to kinetic form.At this stage,static pressure is governed solely by the vertical convective acceleration,whereas at equilibrium it is closely linked to both the free surface difference and vertical local acceleration of the water.This dynamic energy exchange generates vertical force oscillations even when the free surface appears nearly symmetric.
基金Supported by National Natural Science Foundation of China(Grant No.52205072).
文摘Owing to their rolling friction,two-dimensional piston pumps are highly suitable as power components for electro-hydrostatic actuators(EHAs).These pumps are particularly advantageous for applications requiring high efficiency and reliability.However,the ambiguity surrounding the output flow characteristics of individual two-dimensional pumps poses a significant challenge in achieving precise closed-loop control of the EHA positions.To address this issue,this study established a comprehensive numerical model that included gap leakage to analyze the impact of leakage on the output flow characteristics of a two-dimensional piston pump.The validity of the numerical analysis was indirectly confirmed through meticulous measurements of the leakage and volumetric efficiency,ensuring robust results.The research findings indicated that,at lower pump speeds,leakage significantly affected the output flow rate,leading to potential inefficiencies in the system.Conversely,at higher rotational speeds,the impact of leakage was less pronounced,implying that the influence of leakage on the pump outlet flow must be carefully considered and managed for EHAs to perform position servo control.Additionally,the research demonstrates that two-dimensional motion does not have a unique or additional effect on pump leakage,thus simplifying the design considerations.Finally,the study concluded that maintaining an oil-filled leakage environment is beneficial because it helps reduce the impact of leakage and enhances the overall volumetric efficiency of the pump system.
基金supported by the National Natural Science Foundation of China(Nos.52272290,21972030,52073119,and 52373210)the Natural Science Foundation of Jilin Province(No.20230101029JC)+1 种基金the Fundamental Research Program of Shanxi Province(No.202303021212159)the Monash University Malaysia–ASEAN grant(No.ASE-000010)。
文摘Environmental catalysis has been considered one of the important research topics.Some technologies(e.g.,photocatalysis and electrocatalysis)have been intensively developed with the advance of synthetic technologies of catalytical materials.In 2019,we discussed the development trend of this field,and wrote a roadmap on this topic in Chinese Chemical Letters(30(2019)2065-2088).Nowadays,we discuss it again from a new viewpoint along this road.In this paper,several subtopics are discussed,e.g.,photocatalysis based on titanium dioxide,violet phosphorus,graphitic carbon and covalent organic frameworks,electrocatalysts based on carbon,metal-and covalent-organic framework.Finally,we hope that this roadmap can enrich the development of two-dimensional materials in environmental catalysis with novel understanding,and give useful inspiration to explore new catalysts for practical applications.
基金supported by the Key Project of the National Natural Science Foundation of China(Grant No.U1809210)the International Science Technology Cooperation Program of China(Grant No.2014DFR51160)+3 种基金the One Belt and One Road International Cooperation Project from the Key Research and Development Program of Zhejiang Province,China(Grant No.2018C04021)the National Natural Science Foundation of China(Grant Nos.50972129,50602039,and 52102052)the Fund from Institute of Wenzhou,Zhejiang University(Grant Nos.XMGL-CX-202305 and XMGLKJZX-202307)the Project from Tanghe Scientific&Technology Company(Grant No.KYY-HX-20230024).
文摘It is a key challenge to prepare two-dimensional diamond(2D-diamond).Herein,we develop a method for synthesizing 2D-diamond by depositing monodisperse tantalum(Ta)atoms onto graphene substrates using a hot-filament chemical vapor deposition setup,followed by annealing treatment under different temperatures at ambient pressure.The results indicate that when the annealing temperature increases from 700℃ to 1000℃,the size of the 2D-diamond found in the samples gradually increases from close to 20 nm to around 30 nm.Meanwhile,the size and number of amorphous carbon spheres and Ta-containing compounds between the graphene layers gradually increase.As the annealing temperature continues to rise to 1100℃,a significant aggregation of Ta-containing compounds is observed in the samples,with no diamond structure detected.This further confirms that monodisperse Ta atoms play a key role in graphene phase transition into 2D-diamond.This study provides a novel method for the ambient-pressure phase transition of graphene into 2D-diamond.
