Although electrostatic bonding between chalcogen(Ch)atoms(O,S,Se,and Te)and nitrogen(N)has emerged as a powerful driving force in the fabrication of supramolecular structures;this noncovalent bond has not yet been use...Although electrostatic bonding between chalcogen(Ch)atoms(O,S,Se,and Te)and nitrogen(N)has emerged as a powerful driving force in the fabrication of supramolecular structures;this noncovalent bond has not yet been used to link polymers to form networks.In this study,we took advantage of additive enthalpy in forming multipoint noncovalent bonds to construct a two-dimensional(2D)network via the hierarchical on-surface synthesis of linear polymer chains,followed by multipoint S···N and S···H bonding.When 4,7-dibromobenzo[c][1,2,5]thiadiazole was used,only short oligomers with embedded bromine atoms and cross-linked byproducts were formed on Ag(111)or Au(111)surfaces after multiple annealing procedures,and no 2D network was observed.By changing the precursor to a similar iodinesubstituted molecule,long linear polymers were generated and assembled with iodine atoms on Au(111)after annealing at 523 K.After annealing at 603 K,iodine atoms were desorbed and polymer chains were assembled via multipoint noncovalent bonding.The 2D network remained intact after annealing at 653 K,demonstrating its high thermostability.The multipoint noncovalent bonds were investigated by the combination of scanning tunneling microscopy,noncontact atomic force microscopy,and density functional theory calculations,which revealed that S···N and S···H bonding were the driving forces to construct thermostable and orderly 2D networks.展开更多
As emerging two-dimensional(2D)materials,carbides and nitrides(MXenes)could be solid solutions or organized structures made up of multi-atomic layers.With remarkable and adjustable electrical,optical,mechanical,and el...As emerging two-dimensional(2D)materials,carbides and nitrides(MXenes)could be solid solutions or organized structures made up of multi-atomic layers.With remarkable and adjustable electrical,optical,mechanical,and electrochemical characteristics,MXenes have shown great potential in brain-inspired neuromorphic computing electronics,including neuromorphic gas sensors,pressure sensors and photodetectors.This paper provides a forward-looking review of the research progress regarding MXenes in the neuromorphic sensing domain and discussed the critical challenges that need to be resolved.Key bottlenecks such as insufficient long-term stability under environmental exposure,high costs,scalability limitations in large-scale production,and mechanical mismatch in wearable integration hinder their practical deployment.Furthermore,unresolved issues like interfacial compatibility in heterostructures and energy inefficiency in neu-romorphic signal conversion demand urgent attention.The review offers insights into future research directions enhance the fundamental understanding of MXene properties and promote further integration into neuromorphic computing applications through the convergence with various emerging technologies.展开更多
The novel complex [K(18-C-6)]_2 [Cd(mnt)_2] [18-C-6 = 18-crown-6, mnt =1,2-dicyanoethene-1,2-dithiolate, C_2S_2-(CN)_2^(2-)] was synthesized and characterized by elementalanalysis, IR spectrum and X-ray diffraction an...The novel complex [K(18-C-6)]_2 [Cd(mnt)_2] [18-C-6 = 18-crown-6, mnt =1,2-dicyanoethene-1,2-dithiolate, C_2S_2-(CN)_2^(2-)] was synthesized and characterized by elementalanalysis, IR spectrum and X-ray diffraction analysis. The complex displays two-dimensional networkstructure of [K(18-C-6)] complex segments and [Cd(mnt)_2] complex segment bridged by S-K-S, S-K-Nand N-K-N interactions between adjacent [K(18-C-6)] and [Cd(mnt)_2] units.展开更多
To avoid the aerodynamic performance loss of airfoil at non-design state which often appears in single point design optimization, and to improve the adaptability to the uncertain factors in actual flight environment, ...To avoid the aerodynamic performance loss of airfoil at non-design state which often appears in single point design optimization, and to improve the adaptability to the uncertain factors in actual flight environment, a two-dimensional stochastic airfoil optimization design method based on neural networks is presented. To provide highly efficient and credible analysis, four BP neural networks are built as surrogate models to predict the airfoil aerodynamic coefficients and geometry parameter. These networks are combined with the probability density function obeying normal distribution and the genetic algorithm, thus forming an optimization design method. Using the method, for GA（W）-2 airfoil, a stochastic optimization is implemented in a two-dimensional flight area about Mach number and angle of attack. Compared with original airfoil and single point optimization design airfoil, results show that the two-dimensional stochastic method can improve the performance in a specific flight area, and increase the airfoil adaptability to the stochastic changes of multiple flight parameters.展开更多
The copper(Ⅱ) complex [Cu_3(nta)_2(azpy)_2(H_2O)_2]·6H_2O (nta =nitrilotriacetate, azpy = 4,4′-azobispyridine) has been synthesized and characterized. The X-rayanalysis reveals that there are two kinds of copp...The copper(Ⅱ) complex [Cu_3(nta)_2(azpy)_2(H_2O)_2]·6H_2O (nta =nitrilotriacetate, azpy = 4,4′-azobispyridine) has been synthesized and characterized. The X-rayanalysis reveals that there are two kinds of copper(Ⅱ) coordination environments. Cu(1) has adistorted square plane symmetry and Cu(2) has a distorted octahedral symmetry. Cu(1) is linked toCu(2) through nta and bound to Cu(1C) by azpy, and Cu(2) is linked to Cu(2A) through azpy, whichextends to two-dimensional network with large rhombus 1.2 nm x 1.7 nm.展开更多
In an attempt to synthesize supra-molecular complex of copper(II) with mixed ligands in a solution reaction of Cu(ClO 4) 2·6H 2O with 4,5-diazafluorene-9-one (dafo) and o-phthalic acid, the bright blue col...In an attempt to synthesize supra-molecular complex of copper(II) with mixed ligands in a solution reaction of Cu(ClO 4) 2·6H 2O with 4,5-diazafluorene-9-one (dafo) and o-phthalic acid, the bright blue column-like crystal [Cu(dafo) 2(H 2O) 2]-(ClO 4) 2 was obtained. Its structure was determined by single-crystal X-ray diffraction study. The crystal belongs to monoclinic system, space group P2(1)/n with cell dimensions: a=0.7947(3) nm, b=1.2021(5) nm, c=1.3190(5) nm, α=90.000(5)°, β=90.000(5)°, γ= 90.000(5)°, V=1.2600(9) nm 3, Z=2, F(000)=670, M r=662.83, D c=1.747 g/cm 3, μ (Mo Kα)=1.154 mm -1, R 1=0.0455, wR 2=0.1041. The analysis of the crystal structure indicates that the complex has a two-dimensional network structure which is formed by hydrogen bonds.展开更多
The proliferation of wearable biodevices has boosted the development of soft,innovative,and multifunctional materials for human health monitoring.The integration of wearable sensors with intelligent systems is an over...The proliferation of wearable biodevices has boosted the development of soft,innovative,and multifunctional materials for human health monitoring.The integration of wearable sensors with intelligent systems is an overwhelming tendency,providing powerful tools for remote health monitoring and personal health management.Among many candidates,two-dimensional(2D)materials stand out due to several exotic mechanical,electrical,optical,and chemical properties that can be efficiently integrated into atomic-thin films.While previous reviews on 2D materials for biodevices primarily focus on conventional configurations and materials like graphene,the rapid development of new 2D materials with exotic properties has opened up novel applications,particularly in smart interaction and integrated functionalities.This review aims to consolidate recent progress,highlight the unique advantages of 2D materials,and guide future research by discussing existing challenges and opportunities in applying 2D materials for smart wearable biodevices.We begin with an in-depth analysis of the advantages,sensing mechanisms,and potential applications of 2D materials in wearable biodevice fabrication.Following this,we systematically discuss state-of-the-art biodevices based on 2D materials for monitoring various physiological signals within the human body.Special attention is given to showcasing the integration of multi-functionality in 2D smart devices,mainly including self-power supply,integrated diagnosis/treatment,and human–machine interaction.Finally,the review concludes with a concise summary of existing challenges and prospective solutions concerning the utilization of2D materials for advanced biodevices.展开更多
A functional interlayer based on two-dimensional(2D)porous modified vermiculite nanosheets(PVS)was obtained by acid-etching vermiculite nanosheets.The as-obtained 2D porous nanosheets exhibited a high specific surface...A functional interlayer based on two-dimensional(2D)porous modified vermiculite nanosheets(PVS)was obtained by acid-etching vermiculite nanosheets.The as-obtained 2D porous nanosheets exhibited a high specific surface area of 427 m^(2)·g^(-1)and rich surface active sites,which help restrain polysulfides(LiPSs)through good physi-cal and chemical adsorption,while simultaneously accelerating the nucleation and dissolution kinetics of Li_(2)S,effec-tively suppressing the shuttle effect.The assembled lithium-sulfur batteries(LSBs)employing the PVS-based inter-layer delivered a high initial discharge capacity of 1386 mAh·g^(-1)at 0.1C(167.5 mAh·g^(-1)),long-term cycling stabil-ity,and good rate property.展开更多
This paper investigates ruin,capital injection,and dividends for a two-dimensional risk model.The model posits that surplus levels of insurance companies are governed by a perturbed composite Poisson risk model.This m...This paper investigates ruin,capital injection,and dividends for a two-dimensional risk model.The model posits that surplus levels of insurance companies are governed by a perturbed composite Poisson risk model.This model introduces a dependence between the two surplus levels,present in both the associated perturbations and the claims resulting from common shocks.Critical levels of capital injection and dividends are established for each of the two risks.The surplus levels are observed discretely at fixed intervals,guiding decisions on capital injection,dividends,and ruin at these junctures.This study employs a two-dimensional Fourier cosine series expansion method to approximate the finite time expected discounted operating cost until ruin.The ensuing approximation error is also quantified.The validity and accuracy of the method are corroborated through numerical examples.Furthermore,the research delves into the optimal capital allocation problem.展开更多
In this study, an orthogonal array experiment is conducted by using a transparent fracture network replica. Image processing and theoretical analysis are performed to investigate the model sealing efficiency(SE), fact...In this study, an orthogonal array experiment is conducted by using a transparent fracture network replica. Image processing and theoretical analysis are performed to investigate the model sealing efficiency(SE), factors influencing SE, and the effect of flowing water on propagation. The results show that grout propagation can be classified into three patterns in the fracture network: sealing off, partial sealing,and major erosion. The factors controlling the SE in a descending order of the amount of influence are the initial water flow speed, fracture aperture, grout take, and gel time. An optimal value for the combination of the gel time and grout take(artificial factors) can result in a good SE. The grouting and seepage pressures are measured, and the results reveal that their variations can indicate the SE to some extent. The SE is good when the seepage pressure at each point increases overall;the frequent fluctuations in the seepage pressure indicate a moderately poor SE, and an overall decline in the seepage pressure indicates a major erosion type. The deflection effect of grouting shows an approximately elliptical propagation with the long axis expanding along the wider fracture opening, demonstrating further application in grouting design.展开更多
Lithium-sulfur(Li-S)batteries with high energy density and capacity have garnered significant research attention among various energy storage devices.However,the shuttle effect of polysulfides(LiPSs)remains a major ch...Lithium-sulfur(Li-S)batteries with high energy density and capacity have garnered significant research attention among various energy storage devices.However,the shuttle effect of polysulfides(LiPSs)remains a major challenge for their practical application.The design of battery separators has become a key aspect in addressing the challenge.MXenes,a promising two-dimensional(2D)material,offer exceptional conductivity,large surface area,high mechanical strength,and active sites for surface reactions.When assembled into layered films,MXenes form highly tunable two-dimensional channels ranging from a few angstroms to over 1 nm.These nanoconfined channels are instrumental in facilitating lithium-ion transport while effectively impeding the shuttle effect of LiPSs,which are essential for improving the specific capacity and cyclic stability of Li-S batteries.Substantial progress has been made in developing MXenes-based separators for Li-S batteries,yet there remains a research gap in summarizing advancements from the perspective of interlayer engineering.This entails maintaining the 2D nanochannels of layered MXenes-based separators while modulating the physicochemical environment within the MXenes interlayers through targeted modifications.This review highlights advancements in in situ modification of MXenes and their integration with 0D,1D,and 2D materials to construct laminated nanocomposite separators for Li-S batteries.The future development directions of MXenes-based materials in Li-S energy storage devices are also outlined,to drive further advancements in MXenes for Li-S battery separators.展开更多
A novel two-dimensional network manganese(Ⅱ) polymer complex [Mn(O2CCH2CI)2-(phen)]n has been synthesized and characterized by elemental analysis and IR spectrum. The crystal structure of title complex has also been ...A novel two-dimensional network manganese(Ⅱ) polymer complex [Mn(O2CCH2CI)2-(phen)]n has been synthesized and characterized by elemental analysis and IR spectrum. The crystal structure of title complex has also been determined, which is in monoclinic of a space group P21/c with the following unit cell parameters at 294K: a=1.9738(4) nm, b =1.1384(2) nm, c =0.74915(14) nm, V =1.6795(5) nm3, Z= 2.展开更多
Dissolved oxygen(DO)content is an important index of river water quality.Water quality sensors have been used in China for urban river water monitoring and DO content prediction.However,water quality sensors are expen...Dissolved oxygen(DO)content is an important index of river water quality.Water quality sensors have been used in China for urban river water monitoring and DO content prediction.However,water quality sensors are expensive and difficult to maintain,and have a short operation period and difficult to maintain.This study developed a scientific and accurate method for prediction of DO content changes using fish school features.The behavioral features of the Carassius auratus fish school were described using two-dimensional fish school images.The degree of DO content decline was graded into five levels,and the corresponding numerical ranges of cluster characteristic parameters were determined by considering the opinions of ichthyologists.Finally,the variation of DO content was predicted using the characteristic parameters of the fish school and the multiple-input single-output Takagi-Sugeno fuzzy neural network.The prediction results were basically consistent with the actual variations of DO content.Therefore,it is feasible to use the behavioral features of the fish school to dynamically predict the level of DO content in water,and this method is especially suitable for prediction of sharp decline of DO content in a relatively short time.展开更多
Mechanically cleaved two-dimensional materials are random in size and thickness.Recognizing atomically thin flakes by human experts is inefficient and unsuitable for scalable production.Deep learning algorithms have b...Mechanically cleaved two-dimensional materials are random in size and thickness.Recognizing atomically thin flakes by human experts is inefficient and unsuitable for scalable production.Deep learning algorithms have been adopted as an alternative,nevertheless a major challenge is a lack of sufficient actual training images.Here we report the generation of synthetic two-dimensional materials images using StyleGAN3 to complement the dataset.DeepLabv3Plus network is trained with the synthetic images which reduces overfitting and improves recognition accuracy to over 90%.A semi-supervisory technique for labeling images is introduced to reduce manual efforts.The sharper edges recognized by this method facilitate material stacking with precise edge alignment,which benefits exploring novel properties of layered-material devices that crucially depend on the interlayer twist-angle.This feasible and efficient method allows for the rapid and high-quality manufacturing of atomically thin materials and devices.展开更多
Titanium dioxide(TiO_(2))has been an important protective ingredient in mineral-based sunscreens since the 1990s.However,traditional TiO_(2)nanoparticle formulations have seen little improvement over the past decades ...Titanium dioxide(TiO_(2))has been an important protective ingredient in mineral-based sunscreens since the 1990s.However,traditional TiO_(2)nanoparticle formulations have seen little improvement over the past decades and continue to face persistent challenges related to light transmission,biosafety,and visual appearance.Here,we report the discovery of two-dimensional(2D)TiO_(2),characterized by a micro-sized lateral dimension(~1.6μm)and atomic-scale thickness,which fundamentally resolves these long-standing issues.The 2D structure enables exceptional light management,achieving 80%visible light transparency—rendering it nearly invisible on the skin—while maintaining UV-blocking performance comparable to unmodified rutile TiO_(2)nanoparticles.Its larger lateral size results in a two-orders-of-magnitude reduction in skin penetration(0.96 w/w%),significantly enhancing biosafety.Moreover,the unique layered architecture inherently suppresses the generation of reactive oxygen species(ROS)under sunlight exposure,reducing the ROS generation rate by 50-fold compared to traditional TiO_(2)nanoparticles.Through precise metal element modulation,we further developed the first customizable sunscreen material capable of tuning UV protection ranges and automatically matching diverse skin tones.The 2D TiO_(2)offers a potentially transformative approach to modern sunscreen formulation,combining superior UV protection,enhanced safety and a natural appearance.展开更多
<div style="text-align:justify;"> Transceiver module and two-dimensional sum difference network are important components of phased array antenna. In this paper, multilayer printed board is used to inte...<div style="text-align:justify;"> Transceiver module and two-dimensional sum difference network are important components of phased array antenna. In this paper, multilayer printed board is used to integrate millimeter wave multi-channel transceiver circuit and sum difference network. The interconnection between them is realized through RF coaxial vertical transition. At the same time, the heat dissipation design and inter channel shielding design of the module are carried out. The RF and low frequency required by the module are completed through the wiring between and within the dielectric plate layers. Finally, 128 arrays are fabricated and verified by multi-channel passive test. The results show that the type transceiver module integrating with two-dimensional sum difference network has good performance, and 128 channels have excellent amplitude and phase characteristics. The integration technology has the characteristics of lightweight, miniaturization, high integration and low manufacturing cost. It can be widely used in miniaturized phased array antennas. </div>展开更多
Owing to their rolling friction,two-dimensional piston pumps are highly suitable as power components for electro-hydrostatic actuators(EHAs).These pumps are particularly advantageous for applications requiring high ef...Owing to their rolling friction,two-dimensional piston pumps are highly suitable as power components for electro-hydrostatic actuators(EHAs).These pumps are particularly advantageous for applications requiring high efficiency and reliability.However,the ambiguity surrounding the output flow characteristics of individual two-dimensional pumps poses a significant challenge in achieving precise closed-loop control of the EHA positions.To address this issue,this study established a comprehensive numerical model that included gap leakage to analyze the impact of leakage on the output flow characteristics of a two-dimensional piston pump.The validity of the numerical analysis was indirectly confirmed through meticulous measurements of the leakage and volumetric efficiency,ensuring robust results.The research findings indicated that,at lower pump speeds,leakage significantly affected the output flow rate,leading to potential inefficiencies in the system.Conversely,at higher rotational speeds,the impact of leakage was less pronounced,implying that the influence of leakage on the pump outlet flow must be carefully considered and managed for EHAs to perform position servo control.Additionally,the research demonstrates that two-dimensional motion does not have a unique or additional effect on pump leakage,thus simplifying the design considerations.Finally,the study concluded that maintaining an oil-filled leakage environment is beneficial because it helps reduce the impact of leakage and enhances the overall volumetric efficiency of the pump system.展开更多
Environmental catalysis has been considered one of the important research topics.Some technologies(e.g.,photocatalysis and electrocatalysis)have been intensively developed with the advance of synthetic technologies of...Environmental catalysis has been considered one of the important research topics.Some technologies(e.g.,photocatalysis and electrocatalysis)have been intensively developed with the advance of synthetic technologies of catalytical materials.In 2019,we discussed the development trend of this field,and wrote a roadmap on this topic in Chinese Chemical Letters(30(2019)2065-2088).Nowadays,we discuss it again from a new viewpoint along this road.In this paper,several subtopics are discussed,e.g.,photocatalysis based on titanium dioxide,violet phosphorus,graphitic carbon and covalent organic frameworks,electrocatalysts based on carbon,metal-and covalent-organic framework.Finally,we hope that this roadmap can enrich the development of two-dimensional materials in environmental catalysis with novel understanding,and give useful inspiration to explore new catalysts for practical applications.展开更多
It is a key challenge to prepare two-dimensional diamond(2D-diamond).Herein,we develop a method for synthesizing 2D-diamond by depositing monodisperse tantalum(Ta)atoms onto graphene substrates using a hot-filament ch...It is a key challenge to prepare two-dimensional diamond(2D-diamond).Herein,we develop a method for synthesizing 2D-diamond by depositing monodisperse tantalum(Ta)atoms onto graphene substrates using a hot-filament chemical vapor deposition setup,followed by annealing treatment under different temperatures at ambient pressure.The results indicate that when the annealing temperature increases from 700℃ to 1000℃,the size of the 2D-diamond found in the samples gradually increases from close to 20 nm to around 30 nm.Meanwhile,the size and number of amorphous carbon spheres and Ta-containing compounds between the graphene layers gradually increase.As the annealing temperature continues to rise to 1100℃,a significant aggregation of Ta-containing compounds is observed in the samples,with no diamond structure detected.This further confirms that monodisperse Ta atoms play a key role in graphene phase transition into 2D-diamond.This study provides a novel method for the ambient-pressure phase transition of graphene into 2D-diamond.展开更多
Electron-hole interactions play a crucial role in determining the optoelectronic properties of materials,and in lowdimensional systems this is especially true due to the decrease of screening.In this review,we focus o...Electron-hole interactions play a crucial role in determining the optoelectronic properties of materials,and in lowdimensional systems this is especially true due to the decrease of screening.In this review,we focus on one unique quantum phase induced by the electron-hole interaction in two-dimensional systems,known as“exciton insulators”(EIs).Although this phase of matter has been studied for more than half a century,suitable platforms for its stable realization remain scarce.We provide an overview of the strategies to realize EIs in accessible materials and structures,along with a discussion on some unique properties of EIs stemming from the band structures of these materials.Additionally,signatures in experiments to distinguish EIs are discussed.展开更多
基金supported by the National Natural Science Foundation of China(grant nos.22002044,21925201,22161160319,22201073,and 21978049)Shanghai Municipal Science and Technology Major Project,China(grant no.2018SHZDZX03)+2 种基金China Postdoctoral Science Foundation(grant nos.2022M711035 and 2021M702188)the Programme of Introducing Talents of Discipline to Universities,China(grant no.B16017)the Fundamental Research Funds for the Central Universities of China.We thank the Research Center of Analysis and Testing of East China University of Science and Technology for help with the characterization of our fabrications.
文摘Although electrostatic bonding between chalcogen(Ch)atoms(O,S,Se,and Te)and nitrogen(N)has emerged as a powerful driving force in the fabrication of supramolecular structures;this noncovalent bond has not yet been used to link polymers to form networks.In this study,we took advantage of additive enthalpy in forming multipoint noncovalent bonds to construct a two-dimensional(2D)network via the hierarchical on-surface synthesis of linear polymer chains,followed by multipoint S···N and S···H bonding.When 4,7-dibromobenzo[c][1,2,5]thiadiazole was used,only short oligomers with embedded bromine atoms and cross-linked byproducts were formed on Ag(111)or Au(111)surfaces after multiple annealing procedures,and no 2D network was observed.By changing the precursor to a similar iodinesubstituted molecule,long linear polymers were generated and assembled with iodine atoms on Au(111)after annealing at 523 K.After annealing at 603 K,iodine atoms were desorbed and polymer chains were assembled via multipoint noncovalent bonding.The 2D network remained intact after annealing at 653 K,demonstrating its high thermostability.The multipoint noncovalent bonds were investigated by the combination of scanning tunneling microscopy,noncontact atomic force microscopy,and density functional theory calculations,which revealed that S···N and S···H bonding were the driving forces to construct thermostable and orderly 2D networks.
基金supported by the NSFC(12474071)Natural Science Foundation of Shandong Province(ZR2024YQ051,ZR2025QB50)+6 种基金Guangdong Basic and Applied Basic Research Foundation(2025A1515011191)the Shanghai Sailing Program(23YF1402200,23YF1402400)funded by Basic Research Program of Jiangsu(BK20240424)Open Research Fund of State Key Laboratory of Crystal Materials(KF2406)Taishan Scholar Foundation of Shandong Province(tsqn202408006,tsqn202507058)Young Talent of Lifting engineering for Science and Technology in Shandong,China(SDAST2024QTB002)the Qilu Young Scholar Program of Shandong University。
文摘As emerging two-dimensional(2D)materials,carbides and nitrides(MXenes)could be solid solutions or organized structures made up of multi-atomic layers.With remarkable and adjustable electrical,optical,mechanical,and electrochemical characteristics,MXenes have shown great potential in brain-inspired neuromorphic computing electronics,including neuromorphic gas sensors,pressure sensors and photodetectors.This paper provides a forward-looking review of the research progress regarding MXenes in the neuromorphic sensing domain and discussed the critical challenges that need to be resolved.Key bottlenecks such as insufficient long-term stability under environmental exposure,high costs,scalability limitations in large-scale production,and mechanical mismatch in wearable integration hinder their practical deployment.Furthermore,unresolved issues like interfacial compatibility in heterostructures and energy inefficiency in neu-romorphic signal conversion demand urgent attention.The review offers insights into future research directions enhance the fundamental understanding of MXene properties and promote further integration into neuromorphic computing applications through the convergence with various emerging technologies.
文摘The novel complex [K(18-C-6)]_2 [Cd(mnt)_2] [18-C-6 = 18-crown-6, mnt =1,2-dicyanoethene-1,2-dithiolate, C_2S_2-(CN)_2^(2-)] was synthesized and characterized by elementalanalysis, IR spectrum and X-ray diffraction analysis. The complex displays two-dimensional networkstructure of [K(18-C-6)] complex segments and [Cd(mnt)_2] complex segment bridged by S-K-S, S-K-Nand N-K-N interactions between adjacent [K(18-C-6)] and [Cd(mnt)_2] units.
文摘To avoid the aerodynamic performance loss of airfoil at non-design state which often appears in single point design optimization, and to improve the adaptability to the uncertain factors in actual flight environment, a two-dimensional stochastic airfoil optimization design method based on neural networks is presented. To provide highly efficient and credible analysis, four BP neural networks are built as surrogate models to predict the airfoil aerodynamic coefficients and geometry parameter. These networks are combined with the probability density function obeying normal distribution and the genetic algorithm, thus forming an optimization design method. Using the method, for GA（W）-2 airfoil, a stochastic optimization is implemented in a two-dimensional flight area about Mach number and angle of attack. Compared with original airfoil and single point optimization design airfoil, results show that the two-dimensional stochastic method can improve the performance in a specific flight area, and increase the airfoil adaptability to the stochastic changes of multiple flight parameters.
文摘The copper(Ⅱ) complex [Cu_3(nta)_2(azpy)_2(H_2O)_2]·6H_2O (nta =nitrilotriacetate, azpy = 4,4′-azobispyridine) has been synthesized and characterized. The X-rayanalysis reveals that there are two kinds of copper(Ⅱ) coordination environments. Cu(1) has adistorted square plane symmetry and Cu(2) has a distorted octahedral symmetry. Cu(1) is linked toCu(2) through nta and bound to Cu(1C) by azpy, and Cu(2) is linked to Cu(2A) through azpy, whichextends to two-dimensional network with large rhombus 1.2 nm x 1.7 nm.
文摘In an attempt to synthesize supra-molecular complex of copper(II) with mixed ligands in a solution reaction of Cu(ClO 4) 2·6H 2O with 4,5-diazafluorene-9-one (dafo) and o-phthalic acid, the bright blue column-like crystal [Cu(dafo) 2(H 2O) 2]-(ClO 4) 2 was obtained. Its structure was determined by single-crystal X-ray diffraction study. The crystal belongs to monoclinic system, space group P2(1)/n with cell dimensions: a=0.7947(3) nm, b=1.2021(5) nm, c=1.3190(5) nm, α=90.000(5)°, β=90.000(5)°, γ= 90.000(5)°, V=1.2600(9) nm 3, Z=2, F(000)=670, M r=662.83, D c=1.747 g/cm 3, μ (Mo Kα)=1.154 mm -1, R 1=0.0455, wR 2=0.1041. The analysis of the crystal structure indicates that the complex has a two-dimensional network structure which is formed by hydrogen bonds.
基金the support from the National Natural Science Foundation of China(22272004,62272041)the Fundamental Research Funds for the Central Universities(YWF-22-L-1256)+1 种基金the National Key R&D Program of China(2023YFC3402600)the Beijing Institute of Technology Research Fund Program for Young Scholars(No.1870011182126)。
文摘The proliferation of wearable biodevices has boosted the development of soft,innovative,and multifunctional materials for human health monitoring.The integration of wearable sensors with intelligent systems is an overwhelming tendency,providing powerful tools for remote health monitoring and personal health management.Among many candidates,two-dimensional(2D)materials stand out due to several exotic mechanical,electrical,optical,and chemical properties that can be efficiently integrated into atomic-thin films.While previous reviews on 2D materials for biodevices primarily focus on conventional configurations and materials like graphene,the rapid development of new 2D materials with exotic properties has opened up novel applications,particularly in smart interaction and integrated functionalities.This review aims to consolidate recent progress,highlight the unique advantages of 2D materials,and guide future research by discussing existing challenges and opportunities in applying 2D materials for smart wearable biodevices.We begin with an in-depth analysis of the advantages,sensing mechanisms,and potential applications of 2D materials in wearable biodevice fabrication.Following this,we systematically discuss state-of-the-art biodevices based on 2D materials for monitoring various physiological signals within the human body.Special attention is given to showcasing the integration of multi-functionality in 2D smart devices,mainly including self-power supply,integrated diagnosis/treatment,and human–machine interaction.Finally,the review concludes with a concise summary of existing challenges and prospective solutions concerning the utilization of2D materials for advanced biodevices.
文摘A functional interlayer based on two-dimensional(2D)porous modified vermiculite nanosheets(PVS)was obtained by acid-etching vermiculite nanosheets.The as-obtained 2D porous nanosheets exhibited a high specific surface area of 427 m^(2)·g^(-1)and rich surface active sites,which help restrain polysulfides(LiPSs)through good physi-cal and chemical adsorption,while simultaneously accelerating the nucleation and dissolution kinetics of Li_(2)S,effec-tively suppressing the shuttle effect.The assembled lithium-sulfur batteries(LSBs)employing the PVS-based inter-layer delivered a high initial discharge capacity of 1386 mAh·g^(-1)at 0.1C(167.5 mAh·g^(-1)),long-term cycling stabil-ity,and good rate property.
基金supported by the Shihezi University High-Level Talents Research Startup Project(Project No.RCZK202521)the National Natural Science Foundation of China(Grant Nos.12271066,11871121,12171405)+1 种基金the Chongqing Natural Science Foundation Joint Fund for Innovation and Development Project(Project No.CSTB2024NSCQLZX0085)the Chongqing Normal University Foundation(Grant No.23XLB018).
文摘This paper investigates ruin,capital injection,and dividends for a two-dimensional risk model.The model posits that surplus levels of insurance companies are governed by a perturbed composite Poisson risk model.This model introduces a dependence between the two surplus levels,present in both the associated perturbations and the claims resulting from common shocks.Critical levels of capital injection and dividends are established for each of the two risks.The surplus levels are observed discretely at fixed intervals,guiding decisions on capital injection,dividends,and ruin at these junctures.This study employs a two-dimensional Fourier cosine series expansion method to approximate the finite time expected discounted operating cost until ruin.The ensuing approximation error is also quantified.The validity and accuracy of the method are corroborated through numerical examples.Furthermore,the research delves into the optimal capital allocation problem.
基金supported by the Natural Science Foundation of China under (Nos. 42172293, 4190020747, and 41472268)。
文摘In this study, an orthogonal array experiment is conducted by using a transparent fracture network replica. Image processing and theoretical analysis are performed to investigate the model sealing efficiency(SE), factors influencing SE, and the effect of flowing water on propagation. The results show that grout propagation can be classified into three patterns in the fracture network: sealing off, partial sealing,and major erosion. The factors controlling the SE in a descending order of the amount of influence are the initial water flow speed, fracture aperture, grout take, and gel time. An optimal value for the combination of the gel time and grout take(artificial factors) can result in a good SE. The grouting and seepage pressures are measured, and the results reveal that their variations can indicate the SE to some extent. The SE is good when the seepage pressure at each point increases overall;the frequent fluctuations in the seepage pressure indicate a moderately poor SE, and an overall decline in the seepage pressure indicates a major erosion type. The deflection effect of grouting shows an approximately elliptical propagation with the long axis expanding along the wider fracture opening, demonstrating further application in grouting design.
基金supported by Beijing Natural Science Foundation(Nos.2232037 and 2242035)the National Natural Science Foundation of China(Nos.22005012,22105012 and 51803183)+1 种基金Chunhui Plan Cooperative Project of Ministry of Education(No.202201298)the China Postdoctoral Science Foundation Funded Project(No.2023M733520).
文摘Lithium-sulfur(Li-S)batteries with high energy density and capacity have garnered significant research attention among various energy storage devices.However,the shuttle effect of polysulfides(LiPSs)remains a major challenge for their practical application.The design of battery separators has become a key aspect in addressing the challenge.MXenes,a promising two-dimensional(2D)material,offer exceptional conductivity,large surface area,high mechanical strength,and active sites for surface reactions.When assembled into layered films,MXenes form highly tunable two-dimensional channels ranging from a few angstroms to over 1 nm.These nanoconfined channels are instrumental in facilitating lithium-ion transport while effectively impeding the shuttle effect of LiPSs,which are essential for improving the specific capacity and cyclic stability of Li-S batteries.Substantial progress has been made in developing MXenes-based separators for Li-S batteries,yet there remains a research gap in summarizing advancements from the perspective of interlayer engineering.This entails maintaining the 2D nanochannels of layered MXenes-based separators while modulating the physicochemical environment within the MXenes interlayers through targeted modifications.This review highlights advancements in in situ modification of MXenes and their integration with 0D,1D,and 2D materials to construct laminated nanocomposite separators for Li-S batteries.The future development directions of MXenes-based materials in Li-S energy storage devices are also outlined,to drive further advancements in MXenes for Li-S battery separators.
基金supported by the National Natural Science Foundation of China(Grant No.20271041)Shaanxi Province Natural Science Foundation(Grant No.2002B04).
文摘A novel two-dimensional network manganese(Ⅱ) polymer complex [Mn(O2CCH2CI)2-(phen)]n has been synthesized and characterized by elemental analysis and IR spectrum. The crystal structure of title complex has also been determined, which is in monoclinic of a space group P21/c with the following unit cell parameters at 294K: a=1.9738(4) nm, b =1.1384(2) nm, c =0.74915(14) nm, V =1.6795(5) nm3, Z= 2.
基金supported by the Natural Science Foundation of Changzhou City,China(Grants No.CE20195026 and CE20205031)the Teaching Steering Committee of Electronics Information Specialty in Colleges and Universities of the Ministry of Education(Grant No.2020-YB-42)the Jiangsu Overseas Visiting Scholar Program for University Prominent Young and Middle Aged Teachers and Presidents.
文摘Dissolved oxygen(DO)content is an important index of river water quality.Water quality sensors have been used in China for urban river water monitoring and DO content prediction.However,water quality sensors are expensive and difficult to maintain,and have a short operation period and difficult to maintain.This study developed a scientific and accurate method for prediction of DO content changes using fish school features.The behavioral features of the Carassius auratus fish school were described using two-dimensional fish school images.The degree of DO content decline was graded into five levels,and the corresponding numerical ranges of cluster characteristic parameters were determined by considering the opinions of ichthyologists.Finally,the variation of DO content was predicted using the characteristic parameters of the fish school and the multiple-input single-output Takagi-Sugeno fuzzy neural network.The prediction results were basically consistent with the actual variations of DO content.Therefore,it is feasible to use the behavioral features of the fish school to dynamically predict the level of DO content in water,and this method is especially suitable for prediction of sharp decline of DO content in a relatively short time.
基金Project supported by the National Key Research and Development Program of China(Grant No.2022YFB2803900)the National Natural Science Foundation of China(Grant Nos.61974075 and 61704121)+2 种基金the Natural Science Foundation of Tianjin Municipality(Grant Nos.22JCZDJC00460 and 19JCQNJC00700)Tianjin Municipal Education Commission(Grant No.2019KJ028)Fundamental Research Funds for the Central Universities(Grant No.22JCZDJC00460).
文摘Mechanically cleaved two-dimensional materials are random in size and thickness.Recognizing atomically thin flakes by human experts is inefficient and unsuitable for scalable production.Deep learning algorithms have been adopted as an alternative,nevertheless a major challenge is a lack of sufficient actual training images.Here we report the generation of synthetic two-dimensional materials images using StyleGAN3 to complement the dataset.DeepLabv3Plus network is trained with the synthetic images which reduces overfitting and improves recognition accuracy to over 90%.A semi-supervisory technique for labeling images is introduced to reduce manual efforts.The sharper edges recognized by this method facilitate material stacking with precise edge alignment,which benefits exploring novel properties of layered-material devices that crucially depend on the interlayer twist-angle.This feasible and efficient method allows for the rapid and high-quality manufacturing of atomically thin materials and devices.
基金supported by the National Key Research and Development Project(No.2019YFA0705403)the National Natural Science Foundation of China(No.T2293693,52273311)+2 种基金the Guangdong Basic and Applied Basic Research Foundation(No.2020B0301030002)and the Shenzhen Basic Research Project(Nos.WDZC20200824091903001,JSGG20220831105402004,JCYJ20220818100806014)Shenzhen Major Science and Technology Projects(Nos.KCXFZ20240903094013018,KCXFZ20240903094203005)。
文摘Titanium dioxide(TiO_(2))has been an important protective ingredient in mineral-based sunscreens since the 1990s.However,traditional TiO_(2)nanoparticle formulations have seen little improvement over the past decades and continue to face persistent challenges related to light transmission,biosafety,and visual appearance.Here,we report the discovery of two-dimensional(2D)TiO_(2),characterized by a micro-sized lateral dimension(~1.6μm)and atomic-scale thickness,which fundamentally resolves these long-standing issues.The 2D structure enables exceptional light management,achieving 80%visible light transparency—rendering it nearly invisible on the skin—while maintaining UV-blocking performance comparable to unmodified rutile TiO_(2)nanoparticles.Its larger lateral size results in a two-orders-of-magnitude reduction in skin penetration(0.96 w/w%),significantly enhancing biosafety.Moreover,the unique layered architecture inherently suppresses the generation of reactive oxygen species(ROS)under sunlight exposure,reducing the ROS generation rate by 50-fold compared to traditional TiO_(2)nanoparticles.Through precise metal element modulation,we further developed the first customizable sunscreen material capable of tuning UV protection ranges and automatically matching diverse skin tones.The 2D TiO_(2)offers a potentially transformative approach to modern sunscreen formulation,combining superior UV protection,enhanced safety and a natural appearance.
文摘<div style="text-align:justify;"> Transceiver module and two-dimensional sum difference network are important components of phased array antenna. In this paper, multilayer printed board is used to integrate millimeter wave multi-channel transceiver circuit and sum difference network. The interconnection between them is realized through RF coaxial vertical transition. At the same time, the heat dissipation design and inter channel shielding design of the module are carried out. The RF and low frequency required by the module are completed through the wiring between and within the dielectric plate layers. Finally, 128 arrays are fabricated and verified by multi-channel passive test. The results show that the type transceiver module integrating with two-dimensional sum difference network has good performance, and 128 channels have excellent amplitude and phase characteristics. The integration technology has the characteristics of lightweight, miniaturization, high integration and low manufacturing cost. It can be widely used in miniaturized phased array antennas. </div>
基金Supported by National Natural Science Foundation of China(Grant No.52205072).
文摘Owing to their rolling friction,two-dimensional piston pumps are highly suitable as power components for electro-hydrostatic actuators(EHAs).These pumps are particularly advantageous for applications requiring high efficiency and reliability.However,the ambiguity surrounding the output flow characteristics of individual two-dimensional pumps poses a significant challenge in achieving precise closed-loop control of the EHA positions.To address this issue,this study established a comprehensive numerical model that included gap leakage to analyze the impact of leakage on the output flow characteristics of a two-dimensional piston pump.The validity of the numerical analysis was indirectly confirmed through meticulous measurements of the leakage and volumetric efficiency,ensuring robust results.The research findings indicated that,at lower pump speeds,leakage significantly affected the output flow rate,leading to potential inefficiencies in the system.Conversely,at higher rotational speeds,the impact of leakage was less pronounced,implying that the influence of leakage on the pump outlet flow must be carefully considered and managed for EHAs to perform position servo control.Additionally,the research demonstrates that two-dimensional motion does not have a unique or additional effect on pump leakage,thus simplifying the design considerations.Finally,the study concluded that maintaining an oil-filled leakage environment is beneficial because it helps reduce the impact of leakage and enhances the overall volumetric efficiency of the pump system.
基金supported by the National Natural Science Foundation of China(Nos.52272290,21972030,52073119,and 52373210)the Natural Science Foundation of Jilin Province(No.20230101029JC)+1 种基金the Fundamental Research Program of Shanxi Province(No.202303021212159)the Monash University Malaysia–ASEAN grant(No.ASE-000010)。
文摘Environmental catalysis has been considered one of the important research topics.Some technologies(e.g.,photocatalysis and electrocatalysis)have been intensively developed with the advance of synthetic technologies of catalytical materials.In 2019,we discussed the development trend of this field,and wrote a roadmap on this topic in Chinese Chemical Letters(30(2019)2065-2088).Nowadays,we discuss it again from a new viewpoint along this road.In this paper,several subtopics are discussed,e.g.,photocatalysis based on titanium dioxide,violet phosphorus,graphitic carbon and covalent organic frameworks,electrocatalysts based on carbon,metal-and covalent-organic framework.Finally,we hope that this roadmap can enrich the development of two-dimensional materials in environmental catalysis with novel understanding,and give useful inspiration to explore new catalysts for practical applications.
基金supported by the Key Project of the National Natural Science Foundation of China(Grant No.U1809210)the International Science Technology Cooperation Program of China(Grant No.2014DFR51160)+3 种基金the One Belt and One Road International Cooperation Project from the Key Research and Development Program of Zhejiang Province,China(Grant No.2018C04021)the National Natural Science Foundation of China(Grant Nos.50972129,50602039,and 52102052)the Fund from Institute of Wenzhou,Zhejiang University(Grant Nos.XMGL-CX-202305 and XMGLKJZX-202307)the Project from Tanghe Scientific&Technology Company(Grant No.KYY-HX-20230024).
文摘It is a key challenge to prepare two-dimensional diamond(2D-diamond).Herein,we develop a method for synthesizing 2D-diamond by depositing monodisperse tantalum(Ta)atoms onto graphene substrates using a hot-filament chemical vapor deposition setup,followed by annealing treatment under different temperatures at ambient pressure.The results indicate that when the annealing temperature increases from 700℃ to 1000℃,the size of the 2D-diamond found in the samples gradually increases from close to 20 nm to around 30 nm.Meanwhile,the size and number of amorphous carbon spheres and Ta-containing compounds between the graphene layers gradually increase.As the annealing temperature continues to rise to 1100℃,a significant aggregation of Ta-containing compounds is observed in the samples,with no diamond structure detected.This further confirms that monodisperse Ta atoms play a key role in graphene phase transition into 2D-diamond.This study provides a novel method for the ambient-pressure phase transition of graphene into 2D-diamond.
基金supported by the National Key Research&Development Program of China(Grant Nos.2022YFA1403500 and 2021YFA1400500)the National Science Foundation of China(Grant Nos.62321004,12234001,and 12474215)+1 种基金supported by New Cornerstone Science Foundationa fellowship and a CRF award from the Research Grants Council of the Hong Kong Special Administrative Region,China(Grant Nos.HKUST SRFS2324-6S01 and C7037-22GF)。
文摘Electron-hole interactions play a crucial role in determining the optoelectronic properties of materials,and in lowdimensional systems this is especially true due to the decrease of screening.In this review,we focus on one unique quantum phase induced by the electron-hole interaction in two-dimensional systems,known as“exciton insulators”(EIs).Although this phase of matter has been studied for more than half a century,suitable platforms for its stable realization remain scarce.We provide an overview of the strategies to realize EIs in accessible materials and structures,along with a discussion on some unique properties of EIs stemming from the band structures of these materials.Additionally,signatures in experiments to distinguish EIs are discussed.
