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Postoperative effective lens position and refraction changes with three different types of intraocular lens
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作者 Xi-Xia Ding Lin-Feng Xiang +5 位作者 Wen-Tao Tong Dan-Dan Wang Hong-FangZhang Ping-Jun Chang Fu-Man Yang Yun-E Zhao 《International Journal of Ophthalmology(English edition)》 2026年第2期260-265,共6页
AIM:To evaluate and compare alterations in the effective lens position(ELP)and refractive outcomes among three distinct intraocular lens(IOL)types.METHODS:Patients with cataracts were enrolled and allocated to 3 group... AIM:To evaluate and compare alterations in the effective lens position(ELP)and refractive outcomes among three distinct intraocular lens(IOL)types.METHODS:Patients with cataracts were enrolled and allocated to 3 groups:Group A(implanted with the SN6CWS),Group B(implanted with the MI60),and Group C(implanted with the Aspira-aA).ELP measurements were obtained with swept-source optical coherence tomography(SS-OCT)at 1d,1wk,1mo,and 3mo postoperatively.Subjective refraction assessments were conducted at 1wk,1mo,and 3mo following surgery.RESULTS:The study included 189 eyes of 150 cataract patients(66 males).There were 77 eyes in Group A,55 eyes in Group B,and 57 eyes in Group C.The root mean square of the ELP(ELPRMS)within the initial 3mo was significantly lower for Group A than for Groups B and C.Refractive changes within Group A were not significant across the time points of 1wk,1mo,and 3mo.Conversely,both Group B and Group C demonstrated statistically significant shifts toward hyperopia from 1wk to 3mo postsurgery.CONCLUSION:Among the three IOLs examined,the SN6CWS IOL showes the greatest stability during the first 3mo postoperatively.Between 1wk and 3mo after surgery,notable hyperopic shifts are evident in eyes implanted with the MI60 and Aspira-aA IOLs,whereas refractive outcomes remain relatively constant in eyes implanted with SN6CWS IOLs. 展开更多
关键词 effective lens position REFRACTION intraocular lens swept-source optical coherence tomography
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Application of BDRM Theory in the Two-AXIS Underwater Channel 被引量:1
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作者 张林 笪良龙 卢晓亭 《Marine Science Bulletin》 CAS 2007年第2期12-17,共6页
Two-axis underwater channel often exists in deep ocean. Because of the coupling between surface channel and SOFAR channel, sound propagation in the two-axis underwater channel is complex and so its calculations of aco... Two-axis underwater channel often exists in deep ocean. Because of the coupling between surface channel and SOFAR channel, sound propagation in the two-axis underwater channel is complex and so its calculations of acoustic fields are difficult. The beam-displacement ray-mode (BDRM) theory is a normal mode method for propagation modeling in the common horizontally stratified shallow water. We improve the theory, proposing a new method for computing the upper boundary reflection coefficient, and apply it to calculate the acoustic fields of two-axis underwater channel. Transmission losses in the two-axis underwater channel are calculated by the BDRM theory. The results are in good agreement with the KRAKEN code and the computational speed excels those of the other methods. 展开更多
关键词 two-axis underwater channel BDRM theory reflection coefficient phase-shift correction
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Two-mode intelligent coordinating control of position for the welding positioner 被引量:2
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作者 樊丁 周万坤 谭伟明 《China Welding》 EI CAS 1998年第1期50-55,共6页
A new intelligent control method for welding positioner is proposed. Applying an improved fuzzy controller and a variable PID controller, a two-mode intelligent coordinating controller ( TMICC ) is designed on basis o... A new intelligent control method for welding positioner is proposed. Applying an improved fuzzy controller and a variable PID controller, a two-mode intelligent coordinating controller ( TMICC ) is designed on basis of fuzzy logic and rules. The simulation and experimental results show that this control system can obtain better dynamic and static characteristics. 展开更多
关键词 AC servo position control two-mode coordinating controller fuzzy control welding positioner
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Study on general inverse kinematics of rotating/tilting positioner for robotic arc welding off-line programming 被引量:3
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作者 田劲松 吴林 戴明 《China Welding》 EI CAS 2001年第1期27-33,共7页
Off line programming provides an essential link between CAD and CAM, whose development will result in greater use of robotic arc welding. An arc welding system with a robot and a rotating/tilting positioner is one of... Off line programming provides an essential link between CAD and CAM, whose development will result in greater use of robotic arc welding. An arc welding system with a robot and a rotating/tilting positioner is one of the most typical workcells. The inverse kinematics of robot and positioner is the foundation of the off line programming system. The previous researchers only focused on a special solution of the positioner inverse kinematics, which is the solution at down hand welding position. In this paper, we introduce a method for representing welding position. Then a general algorithm of rotating/tilting positioner inverse kinematics is presented, and an approach to find the unique solution of the inverse kinematics is discussed. The simulation experiment results show that the general algorithm can improve the ability of robotic arc welding off line programming system to program all types of welding positions. 展开更多
关键词 robotic arc welding off line programming rotating/tilting positioner inverse kinematics
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A Novel Roll Compensation Method for Two-Axis Transportable Satellite Antennas 被引量:3
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作者 Laiding Zhao Jidong Xie +1 位作者 Xiaodong Bai Zhicheng Qu 《China Communications》 SCIE CSCD 2018年第3期137-148,共12页
Two-axis transportable satellite antennas(TATSAs) have been widely adopted owing to its simple structure and low cost. However, by searching in a wide range, it will take a very long searching time. Under extreme cond... Two-axis transportable satellite antennas(TATSAs) have been widely adopted owing to its simple structure and low cost. However, by searching in a wide range, it will take a very long searching time. Under extreme conditions, it will even fail to work. In this paper, we propose a novel roll compensation(RC) method for the low-cost TATSAs to achieve faster tracking even if when the antenna has no azimuth sensor. By analyzing the influence of roll axis on the system performance, details of the compensation method are derived. Simulation and measurement results indicate that the proposed RC method can effectively reduce the initial searching time for satellite communication. In addition, tracking along with the ellipse path with the RC method provides the highest tracking efficiency. 展开更多
关键词 two-axis transportable satelliteantenna (TATSA) satellite tracking roll com-pensation (RC) searching time.
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A high-precision control system for robotic welding positioner 被引量:1
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作者 石玗 樊丁 陈剑虹 《China Welding》 EI CAS 2005年第1期53-57,共5页
Aiming at the robotic welding positioner with characteristic of parameter change, load change, nonlinearity, and an intelligent control system was researched and developed. This control system used a two-mode controll... Aiming at the robotic welding positioner with characteristic of parameter change, load change, nonlinearity, and an intelligent control system was researched and developed. This control system used a two-mode controller that based on Fuzzy and PID control method. The results of simulation show that the dynamic and steady performances of the intelligent controller are better than that of single PID or Fuzzy controller. This paper has made a detail theoretical analysis of the constitution design and real-time controlled software and brought up the design and fulfillment method of multi-task real-time control software of high precisely and numerically controlled welding positioner, which has a good result in practice. 展开更多
关键词 numerically controlled welding positioner intelligent tow-mode controller multi-task real-time control system arc welding robot
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LOADS INFLUENCE ANALYSIS ON NOVEL HIGH PRECISION FLEXURE PARALLEL POSITIONER 被引量:1
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作者 SUN Lining DONG Wei DU Zhijiang 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2006年第1期37-40,共4页
A large workspace flexure parallel positioner system is developed, which can attain sub-micron scale accuracy over cubic centimeter motion range for utilizing novel wide-range flexure hinges instead of the conventiona... A large workspace flexure parallel positioner system is developed, which can attain sub-micron scale accuracy over cubic centimeter motion range for utilizing novel wide-range flexure hinges instead of the conventional mechanism joints. Flexure hinges eliminate backlash and friction, but on the other hand their deformation caused by initial loads influences the positioning accuracy greatly, so discussions about loads' influence analysis on this flexure parallel positioner is very necessary. The stiffness model of the whole mechanism is presented via stiffness assembly method based on the stiffness model of individual flexure hinge, And the analysis results are validated by the finite element analysis (FEA) simulation and experiment tests, which provide essential data to the practical application of this positioner system. 展开更多
关键词 Flexure hinge Parallel positioner Stiffness analysis Finite element analysis (FEA)
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Design strategy of intelligent CAD for welding positioner scheme design
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作者 林三宝 杨春利 +1 位作者 吴林 黎明 《China Welding》 EI CAS 2002年第1期29-33,共5页
Traditional CAD technique does not support the design processes such as function definition, conceptual design and preliminary design, which are most creative and play significant roles on the design quality. Because ... Traditional CAD technique does not support the design processes such as function definition, conceptual design and preliminary design, which are most creative and play significant roles on the design quality. Because scheme design has close relationship with product structure, performance and technology cost, it is important for applying the intelligent CAD of scheme design to improve the quality and competitive level of the product. The definition and function of welding positioner are discussed in this paper. The new definition of welding positioner extends the research scope of welding positioner to welding fixture and welding positioning motion mechanism. The design process of welding fixture and positioning motion system is described, and the cased based and knowledge based design strategy of welding positioner scheme design intelligent CAD is then put forward, which lays foundation for developing proto type system of welding positioner scheme design. 展开更多
关键词 scheme design intelligent CAD welding positioner design strategy
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Sound propagation in two-axis underwater channel based on beam-displacement ray-mode theory
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作者 张林 笪良龙 卢晓亭 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2007年第3期300-303,共4页
Sound propagation in a deep ocean two-axis underwater channel is often complex and difficult to simulate between surface channel and sound fixing and ranging (SOFAR) channel. The beam-displacement ray-mode (BDRM) theo... Sound propagation in a deep ocean two-axis underwater channel is often complex and difficult to simulate between surface channel and sound fixing and ranging (SOFAR) channel. The beam-displacement ray-mode (BDRM) theory is a normal mode method for propagation modeling in horizontally stratified shallow water. An improved method for computing the upper boundary reflection coefficient in the BDRM is proposed and applied to calculate the acoustic fields of a two-axis underwater channel. Transmission losses in the two-axis underwater channel are calculated in the new BDRM. The corresponding results are in good agreement with those from the Kraken code, and furthermore the computed speed of the new BDRM excels the other methods. 展开更多
关键词 two-axis underwater channel BDRM theory reflection coefficient phase-shift correction
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Tunable two-axis spin model and spin squeezing in two cavities
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作者 俞立先 李彩凤 +3 位作者 樊景涛 陈刚 张天才 贾锁堂 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第5期31-37,共7页
Multi-mode cavities have now attracted much attention both experimentally and theoretically. In this paper, inspired by recent experiments of cavity-assisted Raman transitions, we realize a two-axis spin Hamiltonian H... Multi-mode cavities have now attracted much attention both experimentally and theoretically. In this paper, inspired by recent experiments of cavity-assisted Raman transitions, we realize a two-axis spin Hamiltonian H = q(J_x^2+ χJ_y^2) + ω_0J_z in two cavities. This realized Hamiltonian has a distinct property that all parameters can be tuned independently. For proper parameters, the well-studied one- and two-axis twisting Hamiltonians are recovered, and the scaling of N^(-1) of the maximal squeezing factor can occur naturally. On the other hand, in the two-axis twisting Hamiltonian, spin squeezing is usually reduced when increasing the atomic resonant frequency ω_0. Surprisingly, we find that by combining with the dimensionless parameter χ(-1), this atomic resonant frequency ω_0 can enhance spin squeezing greatly. These results are beneficial for achieving the required spin squeezing in experiments. 展开更多
关键词 two-axis spin model spin squeezing two cavities
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Research of the Data Processing Method in Two-Axis Servo Drift Testing
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作者 郭素云 田自耘 +1 位作者 李东林 张宏伟 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 1996年第1期34-37,共4页
The theory and algorithm of Singular Value Decomposition(SVD) is introduced.The advantage of Singular Value Decomposition used in system identification is studied,compared and illustrated through analyzing the data of... The theory and algorithm of Singular Value Decomposition(SVD) is introduced.The advantage of Singular Value Decomposition used in system identification is studied,compared and illustrated through analyzing the data of navigational gyroscopes drift in two-axis servo testing. 展开更多
关键词 ss:Gyroscope DRIFT SINGULAR Value DECOMposition two-axis SERVO
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Endoscopic Optical Doppler Tomography Based on Two-Axis Scanning MEMS Mirror
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作者 王东琳 郝蕴琦 +4 位作者 翟凤潇 杨坤 刘洪琼 陈巧 谢会开 《Chinese Physics Letters》 SCIE CAS CSCD 2018年第12期5-9,共5页
We study the feasibility of endoscopic optical Doppler tomography with a micro-electro-mechanical system(MEMS) mirror based probe. The additional phase shifts introduced by the probe are tracked and formulated.The sup... We study the feasibility of endoscopic optical Doppler tomography with a micro-electro-mechanical system(MEMS) mirror based probe. The additional phase shifts introduced by the probe are tracked and formulated.The suppression method of the probe phase shifts is proposed and validated by fluid flow detection experiments.In vivo blood flow detection is also implemented on a hairless mouse. The velocities of the blood flow in two directions are obtained to be-8.1 mm/s and 6.6 mm/s, respectively. 展开更多
关键词 Endoscopic Optical Doppler Tomography Based on two-axis Scanning MEMS Mirror
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Tracheal intubation in the lateral position in emergency medicine:a narrative review and clinical protocol 被引量:2
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作者 Ping Cui Tingting Wen +4 位作者 Bingduo Wang Shuijing Wu Shiyu Chen Xiangming Fang TILP consortium 《World Journal of Emergency Medicine》 2025年第2期103-112,共10页
BACKGROUND:Tracheal intubation(TI)is a fundamental procedure for securing the airway or assisting ventilation in emergency medicine.Tracheal intubation in the lateral position(TILP)has been utilized in clinical practi... BACKGROUND:Tracheal intubation(TI)is a fundamental procedure for securing the airway or assisting ventilation in emergency medicine.Tracheal intubation in the lateral position(TILP)has been utilized in clinical practice,demonstrating potential advantages in specific scenarios,including emergency settings.However,there is a lack of comprehensive reviews and practical protocols on TILP application.To address this gap,we performed a narrative review,and provided evidence-based recommendations to formulate a practice protocol,to assist clinicians to effectively apply TILP.METHODS:We conducted a narrative review of TILP applications and developed recommendations based on clinical research evidence and clinical experience.Delphi method was used among the TILP consortium to grade the strength of the recommendations and to help reach consensus.The practice protocols were formulated as warranted by advancements in medical knowledge,technology,and practice.RESULTS:This narrative review summarized the current evidence on TILP application,highlighting its safety,efficacy,challenges,and potential complications.In total,24 recommendations and a clinical protocol for TILP application in emergency patients were established.CONCLUSION:TILP is a valuable technique in emergency medicine.We reviewed its application in emergency settings and formulated recommendations along with a clinical practice protocol.Future studies are needed to evaluate the safety and efficacy of TILP,broaden its scope of application,and explore effective training protocols. 展开更多
关键词 Tracheal intubation Lateral position Emergency medicine Critical care
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High Precision Sensorless Control of Rotor Mechanical Position based on Cross Correction of Dual Air Gap Information
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作者 Yukun Lin Ronggang Ni +1 位作者 Shengming Yang Qingwen Deng 《CES Transactions on Electrical Machines and Systems》 2025年第4期445-453,共9页
Position sensors are indispensable in robotic joint servo systems for acquiring mechanical positions, yet their installation inevitably occupies an axial space and increases system complexity, limiting their applicabi... Position sensors are indispensable in robotic joint servo systems for acquiring mechanical positions, yet their installation inevitably occupies an axial space and increases system complexity, limiting their applicability in compact robot design where spatial constraints and integration efficiency are critical. Sensorless control reduces mechanical and circuit complexity through hardware simplification, but inherently estimates only the electrical instead of mechanical rotor position information, thus remaining constrained in robot joint control applications. Based on the previously proposed dual-gap dualpole composite machine(DDCM), this paper systematically analyzes the causes of mechanical position estimation errors and proposes a correction method that utilizes a correction coefficient to reduce these errors and enhance estimation accuracy. Furthermore, this paper derives the applicability constraints of the proposed scheme, demonstrating that its requirements for electrical angle position errors are not stringent, thus enabling wide applicability in conventional sensorless control scenarios. The effectiveness of the proposed method is verified by conducting experiments on a 0.75 kW prototype. 展开更多
关键词 Dual-gap dual-pole composite machine(DDCM) Electrical angle position errors Mechanical position estimation errors Sensorless control
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The influence of position errors on stray light in compensation interferometry
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作者 Yutong Sun Qiang Cheng +3 位作者 Longxiang Li Xin Zhang Donglin Xue Xuejun Zhang 《Astronomical Techniques and Instruments》 2025年第2期111-118,共8页
Null compensation interferometry is the primary testing method for the manufacture of ultra-high-precision aspheric mirrors.The crosstalk fringes generated by stray light in interferometry can affect accuracy and pote... Null compensation interferometry is the primary testing method for the manufacture of ultra-high-precision aspheric mirrors.The crosstalk fringes generated by stray light in interferometry can affect accuracy and potentially prevent the testing from proceeding normally.Position errors include the decenter error,tilt error,and distance error.During the testing process,position errors will impact the testing accuracy and the crosstalk fringes generated by stray light.To determine the specific impact of position errors,we use the concept of Hindle shell testing of a convex aspheric mirror,and propose the simulation method of crosstalk fringes in null compensation interferometry.We also propose evaluation indices of crosstalk fringes in interferometry and simulate the influence of position errors on the crosstalk fringes.This work aims to help improve the design of compensation interferometry schemes,enhance the feasibility of the design,reduce engineering risks,and improve efficiency. 展开更多
关键词 Compensation interferometry Stray light Multi-beam interference position error
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Leaf Position on the Sunflower Stem Determines Physiological Condition during Flowering
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作者 Antonela Markulj Kulundzic Daniela Horvat +7 位作者 Marija Kovacevic Babic Anto Mijic Aleksandra Sudaric Maja Matosa Kocar Tomislav Duvnjak Ivica Liovic Ivana Varga Marija Viljevac Vuletic 《Phyton-International Journal of Experimental Botany》 2025年第7期2075-2095,共21页
Sunflower leaf photosynthesis strongly depends on the leaf position in the plant stem conditioning,which directly affects other physiological processes.Therefore,a study of the leaf’s physiological status regarding t... Sunflower leaf photosynthesis strongly depends on the leaf position in the plant stem conditioning,which directly affects other physiological processes.Therefore,a study of the leaf’s physiological status regarding the leaf position in the stem was performed on sunflowers in the flowering stage.Eight differently positioned leaves were investigated,starting with the youngest leaf on the top of the stem to the leaves of the stem bottom,assigned as the oldest senescent leaves.According to chlorophyll fluorescence(ChlF)parameters connected to photosystem II(PSII)processes,significant changes in PSII functioning occurred only in the senescent leaves,while photosystem I(PSI)describing parameters showed a linear decrease with leaf age,i.e.,position on the stem.The antioxidative status of the leaves was dynamic,as stress indicators(lipid peroxidation and hydrogen peroxide content)fluctuated regarding leaf position on the stem,but no link was found between the activities of antioxidative enzymes and oxidative stress indicators.Linear decrease trend of secondary metabolites(mainly phenolic compounds)correlated with antioxidant activity,except for some phenolic acids(caffeic and ferulic acid),which increased in senescent leaves.The most changes in the physiological status of the leaves were confirmed in senescent leaves,which stand out the importance of younger leaves in maintaining the plant’s vitality after flowering,which is the most important for sunflower yield. 展开更多
关键词 Helianthus annuus antioxidative enzymes chlorophyll fluorescence leaf position oxidative stress PHOTOSYNTHESIS POLYPHENOLS
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Research on Forward Position Solutions of Triangular Platform Stewart-Type Parallel Robot
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作者 LI Sa YOU Jingjing +2 位作者 WEN Wanghu HUANG Ningning LI Chenggang 《Transactions of Nanjing University of Aeronautics and Astronautics》 2025年第S1期131-140,共10页
This study presents a novel analytical algorithm for solving the forward position problem of a triangular platform Stewart-type parallel robot(STPR).By introducing a virtual chain and leveraging tetrahedral geometric ... This study presents a novel analytical algorithm for solving the forward position problem of a triangular platform Stewart-type parallel robot(STPR).By introducing a virtual chain and leveraging tetrahedral geometric principles,the proposed method derives analytical solutions for the position and orientation of the moving platform.The algorithm systematically addresses the nonlinearity inherent in the kinematic equations of parallel mechanisms,providing explicit expressions for the coordinates of key moving attachment points.Furthermore,the methodology is extended to general triangular platform STPRs with non-coplanar fixed attachments.Numerical validation through virtual experiments confirms the accuracy of the solutions,demonstrating that the mechanism admits eight distinct configurations for a given set of limb lengths.The results align with established kinematic principles and offer a computationally efficient alternative to iterative analytical approaches,contributing to the advancement of precision control in parallel robotic systems. 展开更多
关键词 parallel robot forward position solution TETRAHEDRON analytical solution
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Effectiveness of nulliparous women’s different childbirth positions during the second stage of labor:A systematic review and network meta-analysis
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作者 Hongyan Liu Lingling Li +5 位作者 Xiaojiao Wang Xinli Zhu Liping Sun Chunxiang Zhu Hui Min Chunyi Gu 《International Journal of Nursing Sciences》 2025年第3期268-275,共8页
Objectives A systematic review and network meta-analysis was conducted to evaluate the effectiveness of different childbirth positions in reducing the duration of the second stage of labor,providing evidence-based ins... Objectives A systematic review and network meta-analysis was conducted to evaluate the effectiveness of different childbirth positions in reducing the duration of the second stage of labor,providing evidence-based insights for obstetric institutions to guide interventions related to childbirth positions.Methods A comprehensive literature search was conducted in databases,including PubMed,Web of Science,the Cochrane Library,Embase,Wanfang Databases,China National Knowledge Infrastructure Databases(CNKI),China Science and Technology Journal Database(CSTJ),and China Biology Medicine disc(CBMdisc)to identify studies on the effectiveness of different childbirth positions in reducing the duration of the second stage of labor.The search included randomized controlled trials published from database inception to September 30,2024.The Cochrane risk-of-bias tool was used to assess the quality of the studies.Two independent reviewers screened the literature,extracted data,and evaluated study quality.Subsequently,a network meta-analysis was performed using STATA software.The study protocol has been registered in PROSPERO(CRD42023428217).Results This study analyzed data from 25 randomized controlled trials involving 9,844 women.The findings indicated that in comparison to lithotomy position,free position(MD=20.53,95%CI[11.38,29.68])and upright position(MD=−24.13,95%CI[−42.94,-5.32])were found to be superior in reducing the duration of the second stage of labor.Free position outperformed kneeling position(MD=21.48,95%CI[4.67,38.28])and squatting position(MD=23.43,95%CI[1.88,44.97]);upright position was superior to kneeling position(MD=−25.08,95%CI[−46.93,−3.22]);semirecumbent position surpassed squatting position(MD=19.71,95%CI[2.05,37.38]);and upright position was also superior to squatting position(MD=−27.03,95%CI[−51.48,−2.57]).According to the surface under the cumulative ranking curve(SUCRA),the upright position emerged as the most effective for reducing the duration of the second stage of labor(87.4%),followed by free position(81.1%),semirecumbent position(70.0%),and lateral position(62.3%).Conclusion These findings offer valuable insights for midwifery practice and help inform future research directions.Considering the limitations of this review,more larger-scale,multicenter randomized controlled trials are warranted to further evaluate the relative effectiveness of different childbirth positions in reducing the duration of the second stage of labor. 展开更多
关键词 CHILDBIRTH position Nulliparous women Network meta-analysis Second stage of labor
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Effects of Benzene-fused Position on Photophysical Properties of Benzocoumarin-based Two-Photon Fluorescent Probes for HClO Detection
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作者 Minghui Geng Xuexue Ma +2 位作者 Xiayu Cheng Tongshu Zhang Ke Zhao 《Chinese Journal of Chemical Physics》 2025年第2期212-221,I0040,共11页
Four benzocoumarin-based two-photon fluorescent probes(BH1-BH4)are proposed for ra-tiometric detection of hypochlorous acid(HClO)and their two-photon sensing perfor-mance are evaluated by means of time-dependent densi... Four benzocoumarin-based two-photon fluorescent probes(BH1-BH4)are proposed for ra-tiometric detection of hypochlorous acid(HClO)and their two-photon sensing perfor-mance are evaluated by means of time-dependent density func-tional theory and quadratic re-sponse theory.The effects of benzene-fused position on Stokes shift,fluorescence quantum yield and two-photon absorption are discussed comprehensively.The results show that fusing a benzene ring in coumarin can enhance Stokes shift efficiently.The benzene-fused position has important effects on these photophysical properties.The benzo[g]coumarins(BH1)and benzo[f]coumarins(BH2)derivatives have larger Stokes shifts in comparison with benzo[h]coumarins(BH3)and dihydrophenazine(BH4)derivatives.The two-photon absorp-tion of benzo[f]coumarins(BH2)derivative is much smaller than those of other benzo-coumarins derivatives.The large Stokes shift and increased two-photon action cross section can be achieved simultaneously in the dihydrophenazine(BH4)derivative.Therefore,the de-signed BH4 is expected to have superior performance for the ratiometric detection of HClO.To explore the reasons behind these effects,the intramolecular charge transfer degrees are il-lustrated quantitatively by plotting the hole-electron isosurface map,and the relation be-tween charge transfer and Stokes shift is revealed.A two-state model analysis is employed to understand two-photon absorption ability.Moreover,the fluorescence near-quenching mecha-nism of the product molecules B1 and B3 is explained by analyzing reorganization energy and Huang-Rhys factor,as well as related normal mode.Our research could contribute to the effi-cient design of ratiometric two-photon fluorescent probes with large Stokes shift and signifi-cant two-photon action cross section. 展开更多
关键词 Stokes shift Fluorescence quantum yield Two-photon absorption Benzene-fused position Benzocoumarin
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Landscape Position and Shape as Drivers of Soil Properties and Quality Variation along Hillslope Sequences in a Semiarid Oak Forest
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作者 Javad Cheraghi Mehdi Heydari +3 位作者 Mahmood Rostaminia Reza Omidipour Yahya Kooch Daniel C.Dey 《Journal of Earth Science》 2025年第5期2279-2295,共17页
Forest ecosystems can be characterized by a set of catenas arranged along the slope in mountainous areas as these affect microhabitat features,which in turn influence soil properties.Heretofore,few studies have examin... Forest ecosystems can be characterized by a set of catenas arranged along the slope in mountainous areas as these affect microhabitat features,which in turn influence soil properties.Heretofore,few studies have examined how topographic variables affect soil properties and quality in semiarid regions.This study aimed to provide important insights into how catena position and shape influence soil properties,soil quality,and their interrelationships in a semiarid protected oak forest in western Iran.Basic soil properties were measured in the laboratory.In addition,the soil quality index(SQI)was calculated at different topographic positions along both convex(Λ-shaped)and concave(V-shaped)catenas at two soil depths(0-15 and 15-30 cm).The findings indicated that soil organic carbon and total nitrogen declined in the lower depth in both V-andΛ-shaped catenas and at all catena positions.The lowest porosity was observed in the lower depth at toeslope positions(TS)of both catenas.Substrate-induced respiration(SIR),microbial biomass carbon(MBC),and basal respiration(BR)were higher in the upper depths at TS positions on V-shaped catenas than onΛ-shaped catenas.These biological indices were consistently higher in the upper depths than in the lower depths across all positions of both catenas.SQI had the highest values at TS positions on both catenas and in the upper depths across all positions.Pearson correlations between soil properties indicated that SQI was most strongly and positively correlated with biological properties in both catenas.The nutrient levels,microbial activity,and soil porosity in both catena shapes and at both soil depths displayed a relatively downward trend with increasing elevation from toeslope to summit positions.The results showed that catena topographic sequence shape and position affected most of the soil properties,providing evidence of the important role of topography in creating pedodiversity in oak forest ecosystems. 展开更多
关键词 LANDFORM catena position soil depth organic carbon microbial activities environment geology
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