Surface Ag granular packs(SAgPs) have been fabricated from dual-phase Ag_(35.5)Zn_(64.5) precursor alloy consisting of both e and c phases by using a facile one-step triangle wave potential cycling in 0.5 mol·L^(...Surface Ag granular packs(SAgPs) have been fabricated from dual-phase Ag_(35.5)Zn_(64.5) precursor alloy consisting of both e and c phases by using a facile one-step triangle wave potential cycling in 0.5 mol·L^(-1) KOH.During the continuous potential cyclic sweeping, the c phases preferentially dissolve during the anodic scan and dominant reduction reactions of Ag cations lead to redeposition and accumulation of Ag atoms together to form SAg Ps during cathodic scan. The e phases stay inactive to form a continuous skeleton in the inner regions. SAg Ps with an average particle size of 94-129 nm can be obtained at scan rates of 25, 50 and 100 mV·s^(-1) for 100 triangle wave potential cycles. SAgPs formed at a scan rate of 50 mV·s^(-1) exhibit superior oxygen reduction reaction performances with the onset potential of 0.93 V, half-wave potential of 0.72 V and an electron transfer number of 4.0.The above-mentioned SAgPs have superior stabilities as ORR catalysts.展开更多
The effects of cycle potential window on electrochemical behaviors,structural characteristics,and surface changes in Li[Ni_(0.133)Li_(0.2)Co_(0.133)Mn_(0.533)]O_(2)(or 0.5 Li_(2)MnO_(3)·0.5 Li(Co_(0.333)Ni_(0.333...The effects of cycle potential window on electrochemical behaviors,structural characteristics,and surface changes in Li[Ni_(0.133)Li_(0.2)Co_(0.133)Mn_(0.533)]O_(2)(or 0.5 Li_(2)MnO_(3)·0.5 Li(Co_(0.333)Ni_(0.333)Mn_(0.333))O2)in lithium-ion battery were investigated.Two flat charge potential plateaus,~3.9 and~4.5 V,are observed in the initial charge curves of the cells.Sharp changes in specific capacity and columbic efficiency are presented at~4.5 V during the first cycle.XRD specific peaks show an obvious shift with the increase in charge cutoff potential.When the charge cutoff potential is above4.4 V,the cycle performance decreases with the increase in charge cutoff potentials.A film with the composition of C and O elements is observed on the cycled composite particle.展开更多
In recent year,desertification has become one of the most important environmental hazards all over the world,especially in developing countries such as Iran.Understanding the factors impacting on desertification and i...In recent year,desertification has become one of the most important environmental hazards all over the world,especially in developing countries such as Iran.Understanding the factors impacting on desertification and identifying the regions with high desertification potential are essential to control this phenomenon(i.e.,desertification).The life cycle assessment(LCA)method is essential in assessing the desertification of ecosystems,especially for susceptible ecosystems with high degradation risks.The aim of the present study was to evaluate the desertification potential of Lorestan Province,Iran,based on the LCA method.We selected aridity,fire and dust as three indicators of desertification and collected data from 2000 to 2015.We divided the study area into 6 types of ecoregions according to the climate types(arid,semi-arid and dry sub-humid)and dominant species(Quercus brantii and Astragalus adscendens),and calculated the characteristic factor(CF)of each indicator(aridity,fire and dust)by combining the indicator layers and ecoregion layer of the study area.In a given ecoregion,the sum of CF values of aridity,dust and fire indicators represents the life cycle inventory(LCI)desertification value(the higher the LCI value,the greater the desertification potential).Then,we obtained the desertification potential map by combining and overlapping the ecoregions and the normalized indicators based on the LCA method.Aridity and fire exhibit significant impacts on desertification in the study area compared with dust.In the study area,semi-arid ecoregion with Quercus brantii as the dominant species is the largest ecoregion,while arid ecoregion with Quercus brantii as the dominant species is the smallest ecoregion.Arid ecoregion with Astragalus adscendens as the dominant species(LCI desertification value of 1.99)and dry sub-humid ecoregion with Quercus brantii as the dominant species(LCI desertification value of 0.79)show the highest and lowest desertification potentials,respectively.Furthermore,arid ecoregion with Quercus brantii as the dominant species also has a higher LCI desertification value(1.89),showing a high desertification potential.These results suggest the necessity of proper management and appropriate utilization in these ecoregions.In general,assessing desertification potential using the LCA method on a local and regional scale can possibly provide a new methodology for identifying and protecting areas with high degradation risks.展开更多
This study addresses the comparative carbon emissions of different transportation modes within a unified evaluation framework,focusing on their carbon footprints from inception to disposal.Specifically,the entire life...This study addresses the comparative carbon emissions of different transportation modes within a unified evaluation framework,focusing on their carbon footprints from inception to disposal.Specifically,the entire life cycle carbon emissions of High-Speed Rail(HSR),battery electric vehicles,conventional internal combustion engine vehicles,battery electric buses,and conventional internal combustion engine buses are analyzed.The life cycle is segmented into vehicle manufacturing,fuel or electricity production,operational,and dismantlingrecycling stages.This analysis is applied to the Beijing-Tianjin intercity transportation system to explore emission reduction strategies.Results indicate that HSR demonstrates significant carbon emission reduction,with an intensity of only 24%-32% compared to private vehicles and 47%-89% compared to buses.Notably,HSR travel for Beijing-Tianjin intercity emits only 24% of private vehicle emissions,demonstrating the emission reduction benefits of transportation structure optimization.Additionally,predictive modeling reveals the potential for carbon emission reduction through energy structure optimization,providing a guideline for the development of effective transportation management systems.展开更多
The study on the changes of stomatal sensitivity in relation to xylem ABA during periodical soil drying and the effect of leaf water status on the stomatal sensitivity has confirmed that xylem ABA concentration is a g...The study on the changes of stomatal sensitivity in relation to xylem ABA during periodical soil drying and the effect of leaf water status on the stomatal sensitivity has confirmed that xylem ABA concentration is a good indicator of soil water status around roots and the relation between xylem ABA concentration and predawn leaf water potential remained constant during the three consecutive soil drying cycles based on the slopes of the fitted lines. The sensitivity of stomata to xylem ABA increased substantially as the soil drying cycles progressed, and the xylem ABA concentration needed to cause a 50% decrease of stomatal conductance was as low as 550 nmol/L in the next two soil drying cycle, as compared with the 750 nmol/L ABA in the first cycle of soil drying. The results using the split_root system showed that leaf water deficit significantly enhanced the stomatal response to xylem ABA and the xylem ABA concentration needed to cause a 50% decrease in stomatal conductance was 2 to 4 times smaller in the whole_root_drying treatment than those in the semi_root_drying treatment. These results suggested that the sensitivity of stomata to xylem ABA concentration is not a fixed characteristic.展开更多
Electrocatalytic reduction of Cr(Ⅵ)to less toxic Cr(Ⅲ)is deemed as a promising technique.Conventional electrocatalytic reduction is always driven by a constant cathodic potential,which exhibits a repelling action to...Electrocatalytic reduction of Cr(Ⅵ)to less toxic Cr(Ⅲ)is deemed as a promising technique.Conventional electrocatalytic reduction is always driven by a constant cathodic potential,which exhibits a repelling action to Cr(Ⅵ)oxyanions in wastewater and consequently suppresses reduction kinetics.In order to remarkably accelerate Cr(Ⅵ)electrocatalytic reduction,we applied a pulsed potential on an Fe^(2+)-NiFe LDH/NF electrode synthesized by in situ growth of Fe^(2+)-doped NiFe LDH nanosheets on Ni foam using a spontaneous redox reaction.Under anodic potential section,HCrO_(4)^(–) anions are adsorbed on the electrode surface and reduced to Cr(Ⅲ)by Fe^(2+).Then,Cr(Ⅲ)ions are desorbed from the electrode surface under coulombic force.The regeneration of Fe^(2+) and direct reduction of Cr(Ⅵ)are achieved under cathodic potential section.The pulsed potential can achieve complete elimination of Cr(Ⅵ)within 60 min at an initial concentration of 10 mg L^(-1),and the removal efficiency shows a 60%increase with respect to that under constant cathodic potential.展开更多
Harboring polyextremotolerant microbial topsoil communities,biological soil crusts(biocrusts)occur across various climatic zones,and have been well studied in the terrestrial drylands.However,little is known about the...Harboring polyextremotolerant microbial topsoil communities,biological soil crusts(biocrusts)occur across various climatic zones,and have been well studied in the terrestrial drylands.However,little is known about the functional metabolic potential of microbial communities involved in the biogeochemical processes during the early succession of biocrusts on the tropical reef islands.We collected 26 biocrusts and bare soil samples from the Xisha Islands and Nansha Islands,and applied a functional gene array(GeoChip 5.0)to reveal nitrogen(N)cycling processes involved in these samples.Both physicochemical measurement and enzyme activity assay were utilized to characterize the soil properties.Results revealed the composition of N-cycling functional genes in biocrusts was distinct from that in bare soil.Additionally,microorganisms in biocrusts showed lower functional potential related to ammonification,denitrification,N assimilation,nitrification,N fixation,and dissimilatory nitrate reduction to ammonium compared to bare soils.Although the abundance of nifH gene was lower in biocrusts,nitrogenase activity was significantly higher compared to that in bare soils.Precipitation,soil physicochemical properties(i.e.,soil available copper,soil ammonia N and pH)and soil biological properties(i.e.,β-glucosidase,fluorescein diacetate hydrolase,alkaline protease,urease,alkaline phosphatase,catalase and chlorophyll a)correlated to the N-cycling functional genes structure.Nitrate N and ammonia N were more abundant in biocrusts than bare soil,while pH value was higher in bare soil.Our results suggested biocrusts play an important role in N-cycling in coral sand soil,and will be helpful in understanding the development and ecological functions of biocrusts on tropical reef islands.展开更多
The significant increase in the demand for biomass waste treatment after garbage classification has led to housefly larvae treatment becoming an attractive treatment option.It can provide a source of protein while tre...The significant increase in the demand for biomass waste treatment after garbage classification has led to housefly larvae treatment becoming an attractive treatment option.It can provide a source of protein while treating biomass waste,which means that nutrients can be returned to the natural food chain.However,the performance of this technology in terms of its environmental impacts is still unclear,particularly with regards to global warming potential(GWP).This study used a life cycle assessment(LCA)approach to assess a housefly larvae treatment plant with a treatment capacity of 50 tons of biomass waste per day.The LCA results showed that the 95% confidence intervals for the GWP in summer and winter were determined to be 24.46-32.81 kg CO_(2) equivalent(CO_(2)-eq)/ton biomass waste and5.37-10.08 kg CO_(2)-eq/ton biomass waste,respectively.The greater GWP value in summer is due to the longer ventilation time and higher ventilation intensity in summer,which consumes more power.The main GWP contributions are from(1)electricity needs(accounting for 78.6% of emissions in summer and 70.2%in winter)and(2)product substitution by mature housefly larvae and compost(both summer and winter accounting for 96.8% of carbon reduction).展开更多
Two estimaton methods are used to calculate the theoretical reservoir potential of China's oceanic thermal energy. One is based on the measured temperature difference between the surface water and the deep water, ...Two estimaton methods are used to calculate the theoretical reservoir potential of China's oceanic thermal energy. One is based on the measured temperature difference between the surface water and the deep water, the other on the net radiation energy income from solar insolation either measured or deduced. The results from these two methods are compared and examined. Then, the maximum amount of the exploitable thermal energy is calculated based on the assumption of a Carnot cycle efficiency. In the process of estimation, such factors as water depth, seasonal water temperature variation and geographic location have been taken into account.The theoretical reservoir capacity and the exploitable quantity of the thermal energy of China's four seas are thus estimated separately.展开更多
电解锰渣是电解金属锰过程产生的固体废弃物,目前主要以堆存方式进行处置,因为其含有重金属、溶解锰和氨氮等有害成分,对土壤、水体和生态环境存在造成严重污染的潜在风险,是当前亟需解决的重要问题;因此,推动电解锰渣的资源化利用,实...电解锰渣是电解金属锰过程产生的固体废弃物,目前主要以堆存方式进行处置,因为其含有重金属、溶解锰和氨氮等有害成分,对土壤、水体和生态环境存在造成严重污染的潜在风险,是当前亟需解决的重要问题;因此,推动电解锰渣的资源化利用,实现其向资源的有效转化,已成为电解锰行业缓解资源环境压力、推动绿色低碳转型的重要方向。采用生命周期评价方法,研究电解锰渣应用于水泥和蒸压砖替代原料的资源和环境综合效益,通过与传统堆存处置、水泥及蒸压砖常规生产工艺的环境影响进行对比,探讨了电解锰渣不同资源化利用路径在节约资源、降低全球变暖潜力、减少环境影响等方面的影响。结果显示,与传统生产工艺相比,每吨电解锰渣的资源化利用可以降低约0.66~1.96 kg Cu当量的矿产资源耗竭影响和43.00~136.77 kg油当量的化石能源耗竭影响;在温室气体减排方面,利用每吨电解锰渣生产32.5强度等级硅酸盐水泥、42.5强度等级硅酸盐水泥以及蒸压砖产品,可分别降低816.75、926.71、300.89 kg CO_(2)当量的全球变暖潜力;在环境影响指标值方面,利用电解锰渣生产42.5强度等级硅酸盐水泥情景下的综合表现优于其他情景,颗粒物生成指标降低1.25 kg细颗粒物(PM 2.5)当量,陆地酸化指标降低4.12 kg SO_(2)当量,陆地生态系统毒性指标降低361.86 kg 1,4-二氯苯当量。展开更多
Microorganisms are major drivers of elemental cycling in the biosphere. Determining the abundance of microbial functional traits involved in the transformation of nutrients, including carbon(C), nitrogen(N), phosphoru...Microorganisms are major drivers of elemental cycling in the biosphere. Determining the abundance of microbial functional traits involved in the transformation of nutrients, including carbon(C), nitrogen(N), phosphorus(P) and sulfur(S), is critical for assessing microbial functionality in elemental cycling. We developed a high-throughput quantitative-PCR-based chip, Quantitative microbial element cycling(QMEC), for assessing and quantifying the genetic potential of microbiota to mineralize soil organic matter and to release C, N, P and S. QMEC contains 72 primer pairs targeting 64 microbial functional genes for C, N, P, S and methane metabolism. These primer pairs were characterized by high coverage(average of 18–20 phyla covered per gene)and sufficient specificity(>70% match rate) with a relatively low detection limit(7–102 copies per run). QMEC was successfully applied to soil and sediment samples, identifying significantly different structures, abundances and diversities of the functional genes(P<0.05). QMEC was also able to determine absolute gene abundance. QMEC enabled the simultaneous qualitative and quantitative determination of 72 genes from 72 samples in one run, which is promising for comprehensively investigating microbially mediated ecological processes and biogeochemical cycles in various environmental contexts including those of the current global change.展开更多
Assessing and accounting for material consumption and environmental impact are necessary to measure environmental externalities of the aluminum industry and to construct an ecological civilization.In this research,lif...Assessing and accounting for material consumption and environmental impact are necessary to measure environmental externalities of the aluminum industry and to construct an ecological civilization.In this research,life cycle assessment(LCA)theory was used to assess the environmental impact of primary aluminum based on the lime soda Bayer process and different power generation modes,and the sources and distributions of the four selected impact categories were analyzed.The results show that,(1)Negative environmental impact of aluminum industry generally occurs from alumina extraction,carbon anode fabrication and electrolysis,particularly electrolysis and alumina extraction.Primary energy demand(PED),water use(WU),global warming potential(GWP)and freshwater eutrophication potential(FEP)are main environmental impact categories.(2)The environmental load with thermal power is higher than that with hydropower,e.g.,for the former,the greenhouse gas emission coefficient of 21800 kg CO2 eq/t(Al)will be generated,while for the latter,4910 kg CO2 eq/t(Al)will be generated.(3)Both power mode methods reflect the energy structure,whereas direct emissions reflect the technical level,indicating the potential for large energy savings and emission reductions,and some policies,related to clean power,energy efficiency and technological progress,should be made for emission reduction.展开更多
Highway frost heave and thawing settlement caused by water migration towards the freezing front and ice lens development is widespread in the alpine meadow area of the southeast QinghaiTibet Plateau(QTP).A laboratory ...Highway frost heave and thawing settlement caused by water migration towards the freezing front and ice lens development is widespread in the alpine meadow area of the southeast QinghaiTibet Plateau(QTP).A laboratory experiment on a highway reconstruction and expansion project in the QTP was carried out in this work to analyze the effects of fine particle content,initial water content,and the number of freeze-thaw cycles(FTCs)on frost depth,temperature gradient(Grad T),total water intake,and water intake flux.Based on the results of the laboratory experiment,a modified model of migration potential related to fine particle content,freeze-thaw history,and freezing time was established.The results show that,with the increase of fine particle content,the frost depth of soil decreases,the curve of total water intake over time is transformed from an Sshape to an arch,and the curve of water intake flux over time is transformed from a peak shape to descending shape.The variation trend of migration potential with freezing time and the freeze-thaw history is the same as that of water intake flux with freezing time and freeze-thaw history.The variation trend of soil intake flux can be used as a reference to determine the variation trend of soil migration potential.This study provides a reference for the design and construction of highway subgrade in the alpine meadow area of the QTP.展开更多
OBJECTIVE:To investigate the effect of Renshenwuweizi decoction(RSWWZ decoction)on the growth of non-small cell lung cancer cells in vitro.METHODS:A549 non-small cell lung cancer cells were divided into two groups:con...OBJECTIVE:To investigate the effect of Renshenwuweizi decoction(RSWWZ decoction)on the growth of non-small cell lung cancer cells in vitro.METHODS:A549 non-small cell lung cancer cells were divided into two groups:control and RSWWZ decoction treatment groups.Cell Counting Kit-8 was used to measure the inhibitory effect of RSWWZ decoction on the growth of A549 cells.4’,6-diamidino-2-phenylindole staining and Annexin V-fluorescein isothiocyanate/propidium iodide double staining were used to investigate apoptosis in A549 cells following RSWWZ decoction treatment,and the mitochondrial membrane potential of treated cells was detected with Rhodamine 123.Cell cycle progression was analyzed by flow cytometry.The m RNA levels of p53,Bax,B-cell lymphoma-2(Bcl-2)and p21 were measured by quantitative real-time reverse transcription polymerase chain reaction.The protein expressions of p53,Bax,Bcl-2,p21,cyclin-dependent kinases 2(CDK2),and cyclin A were detected by Western blot.RESULTS:RSWWZ decoction reduced the viability of A549 cells in a dose-dependent manner by inducing apoptosis and decreased mitochondrial membrane potential.RSWWZ decoction increased p53 and Bax expression and decreased Bcl-2 expression in a dose-dependent manner.RSWWZ decoction also induced an S-phase cell cycle arrest by increasing p21 and decreasing cyclin A and CDK2 expression.CONCLUSION:In vitro experiments revealed that the Renshenwuweizi decoction-induced decrease in A549 cell proliferation was achieved by inducing apoptosis and S-phase cell cycle arrest via the p53 pathway.These findings provide the experimental basis for Renshenwuweizi decoction treatment of lung cancer.展开更多
This study presents the effect of excavator model, loading operation location, shift availability and truck-shovel combination on loading cycle time and productivity of an open-pit mine. The loading cycle time was use...This study presents the effect of excavator model, loading operation location, shift availability and truck-shovel combination on loading cycle time and productivity of an open-pit mine. The loading cycle time was used to assess the material loading system performance which is one of the key components of the total cycle time for material transportation in an open-pit mine. Loading is among the components of cycle time during which material is being handled. The data analyzed?was?collected from a computerized dispatch system at GGM from which 62,000 loading dispatches per month involving several shifts, 14 excavators and 49 trucks were loaded. About 4465 dispatches per excavator and 1276 dispatches per truck were assessed using loading cycle time data for each dispatch for a period of four months (between August and December). Under fixed tonnage loaded and waste type (33 t of non-acid forming waste rock),?it was observed that loading cycle time depends on excavator model, location and truck being loaded. Average cycle times, PDFS?and CDFS of loading cycle time series were used to identify differences in performance under different situations. It was concluded that shift availability for excavators, loading location, excavator model and truck-shovel combinations strongly affect the productivity during loading process in an open-pit mine.展开更多
In this paper, the performance of a waste rock transportation process in an open pit mine was assessed by using cycle time data. A computerized truck-excavator dispatch system was used to record the cycle times. The p...In this paper, the performance of a waste rock transportation process in an open pit mine was assessed by using cycle time data. A computerized truck-excavator dispatch system was used to record the cycle times. The process was broken into seven steps (or components of the total cycle), durations of which were recorded for a period of 1 month, leading to N = 60,690 data points or dispatches. The open pit mine studied consisted of 12 waste types loaded by 14 excavators and hauled by 49 trucks (at a trucks-to-excavator ratio of 3.5:1) in 75 changing locations. The string-type data was coded using integers to allow a FORTRAN code to extract process performance parameters using statistical analysis. The study established a wide range of parameters including: the waste material generation rate (about 1.73 million t/month, 81% comprising waste rock), truck fill factor, f, total cycle time (Tct), production capacity, theoretical cycle time, non-productive cycle time Tnp, and cycle time performance ratio (CTPR), denoted as Tpr. The factors affecting the process performance include: truck model, excavator model, location (haul distance and road conditions) and material type. For a fixed material type and tonnage, the PDFs of the cycle time components were logarithmic in nature, capable of differentiating performance variations under different factors. It was concluded that the performance of the waste material transportation system in this mine was determined to be acceptable due to mean value of Tpr = 2.432 being closer to unity. Reduction measures were suggested to minimize the cycle time for the process bottlenecks determined from Pareto analysis (that is, full haul, empty haul and loading processes).展开更多
To obtain a longer natural period in single degree of freedom(SDF) conservative vibration isolation systems, many scholars have proposed different methods. This paper uncovers a clockwise energy cycle existing in a ma...To obtain a longer natural period in single degree of freedom(SDF) conservative vibration isolation systems, many scholars have proposed different methods. This paper uncovers a clockwise energy cycle existing in a mass-spring system, in which the potential energy and kinetic energy convert with each other, and the natural period is determined by the magnitude of the energy cycle. Compared to water flow inside a pipe, the previous methods can be consolidated into two methods to make the energy cycle narrower;one is to optimize the parameters directly, the other is to indirectly add an anticlockwise energy cycle to the original one. The anticlockwise energy cycle has the characteristic of gravitational potential energy or elastic potential energy that reduces with displacement. The highly abstract method can provide a better optimization tool to design a practice system.展开更多
As natural weather disasters,tropical cyclones(TCs)are destructive in proportion to their peak intensity.This study investigates the association of North Atlantic,western North Pacific,and eastern North Pacific TC pea...As natural weather disasters,tropical cyclones(TCs)are destructive in proportion to their peak intensity.This study investigates the association of North Atlantic,western North Pacific,and eastern North Pacific TC peak intensities with tropospheric air temperature,respectively,by applying NCEP–NCAR and MERRA reanalysis data.Both the correlation between TC peak intensity and air temperature and the difference in air temperature between strong and weak TC peak intensity conditions reveal that significant cooling of the tropopause and uppertropospheric warming are accompanied by strengthening TC peak intensity for North Atlantic TCs,suggesting an important effect of upper-tropospheric static stability on TC peak intensity.However,warming in the lower troposphere is associated with strong TC peak intensity for eastern North Pacific TCs,indicating a major effect of lower-tropospheric static stability on TC peak intensity.The peak intensity of western North Pacific TCs is mainly affected by vertical wind shear,not the atmospheric temperature.展开更多
This study covers the problem that most products become less competitive especially in the decline stages of their life cycle as most companies do not put adequate emphasis on using networked manufacturing systems in ...This study covers the problem that most products become less competitive especially in the decline stages of their life cycle as most companies do not put adequate emphasis on using networked manufacturing systems in the entire life cycle of a single product. The study employed a non-experimental approach to collect data. The research paper relied on secondary data for further analysis. The secondary sources used in this paper have been referenced progressively in the entire paper. The paper found that most companies are often faced with the challenge of coping with quality management in a product life cycle. Also, it found that networked manufacturing systems have provided a new paradigm for real-time monitoring and control at various life stages. The paper is divided as following parts： section 1 is about the background and problem statement. Section 2 comes through literature review including theoretical ＆ empirical review. Section 3 explains the procedures and methods that were used in carrying out the study. It explains how data collection was carried out and how data analysis was performed. Section 4 is about the results the paper found. Section 5 is a discussion of the results presented.展开更多
基金financially supported by the State Key Laboratory of Advanced Metals and Materials (No.2018-ZD04)the State Key Laboratory of Metal Material for Marine Equipment and Application (No. SKLMEA-K201806)+2 种基金the Natural Science Foundation of China (Nos. 51671106 and 51931008)the Natural Science Foundation of Jiangsu Province (Nos. BK20171424and BE2019119)the National Defense Basic Scientific Research Program of China (No. JCKY08414C020)。
文摘Surface Ag granular packs(SAgPs) have been fabricated from dual-phase Ag_(35.5)Zn_(64.5) precursor alloy consisting of both e and c phases by using a facile one-step triangle wave potential cycling in 0.5 mol·L^(-1) KOH.During the continuous potential cyclic sweeping, the c phases preferentially dissolve during the anodic scan and dominant reduction reactions of Ag cations lead to redeposition and accumulation of Ag atoms together to form SAg Ps during cathodic scan. The e phases stay inactive to form a continuous skeleton in the inner regions. SAg Ps with an average particle size of 94-129 nm can be obtained at scan rates of 25, 50 and 100 mV·s^(-1) for 100 triangle wave potential cycles. SAgPs formed at a scan rate of 50 mV·s^(-1) exhibit superior oxygen reduction reaction performances with the onset potential of 0.93 V, half-wave potential of 0.72 V and an electron transfer number of 4.0.The above-mentioned SAgPs have superior stabilities as ORR catalysts.
基金financially supported by the HiTech Research and Development Program of China (No. 2011AA11A254)
文摘The effects of cycle potential window on electrochemical behaviors,structural characteristics,and surface changes in Li[Ni_(0.133)Li_(0.2)Co_(0.133)Mn_(0.533)]O_(2)(or 0.5 Li_(2)MnO_(3)·0.5 Li(Co_(0.333)Ni_(0.333)Mn_(0.333))O2)in lithium-ion battery were investigated.Two flat charge potential plateaus,~3.9 and~4.5 V,are observed in the initial charge curves of the cells.Sharp changes in specific capacity and columbic efficiency are presented at~4.5 V during the first cycle.XRD specific peaks show an obvious shift with the increase in charge cutoff potential.When the charge cutoff potential is above4.4 V,the cycle performance decreases with the increase in charge cutoff potentials.A film with the composition of C and O elements is observed on the cycled composite particle.
文摘In recent year,desertification has become one of the most important environmental hazards all over the world,especially in developing countries such as Iran.Understanding the factors impacting on desertification and identifying the regions with high desertification potential are essential to control this phenomenon(i.e.,desertification).The life cycle assessment(LCA)method is essential in assessing the desertification of ecosystems,especially for susceptible ecosystems with high degradation risks.The aim of the present study was to evaluate the desertification potential of Lorestan Province,Iran,based on the LCA method.We selected aridity,fire and dust as three indicators of desertification and collected data from 2000 to 2015.We divided the study area into 6 types of ecoregions according to the climate types(arid,semi-arid and dry sub-humid)and dominant species(Quercus brantii and Astragalus adscendens),and calculated the characteristic factor(CF)of each indicator(aridity,fire and dust)by combining the indicator layers and ecoregion layer of the study area.In a given ecoregion,the sum of CF values of aridity,dust and fire indicators represents the life cycle inventory(LCI)desertification value(the higher the LCI value,the greater the desertification potential).Then,we obtained the desertification potential map by combining and overlapping the ecoregions and the normalized indicators based on the LCA method.Aridity and fire exhibit significant impacts on desertification in the study area compared with dust.In the study area,semi-arid ecoregion with Quercus brantii as the dominant species is the largest ecoregion,while arid ecoregion with Quercus brantii as the dominant species is the smallest ecoregion.Arid ecoregion with Astragalus adscendens as the dominant species(LCI desertification value of 1.99)and dry sub-humid ecoregion with Quercus brantii as the dominant species(LCI desertification value of 0.79)show the highest and lowest desertification potentials,respectively.Furthermore,arid ecoregion with Quercus brantii as the dominant species also has a higher LCI desertification value(1.89),showing a high desertification potential.These results suggest the necessity of proper management and appropriate utilization in these ecoregions.In general,assessing desertification potential using the LCA method on a local and regional scale can possibly provide a new methodology for identifying and protecting areas with high degradation risks.
基金the financial support of the National Natural Science Foundation of China(U2268208)Science and Technology Program of China National Railway Group Co.,Ltd.(N2022×037).
文摘This study addresses the comparative carbon emissions of different transportation modes within a unified evaluation framework,focusing on their carbon footprints from inception to disposal.Specifically,the entire life cycle carbon emissions of High-Speed Rail(HSR),battery electric vehicles,conventional internal combustion engine vehicles,battery electric buses,and conventional internal combustion engine buses are analyzed.The life cycle is segmented into vehicle manufacturing,fuel or electricity production,operational,and dismantlingrecycling stages.This analysis is applied to the Beijing-Tianjin intercity transportation system to explore emission reduction strategies.Results indicate that HSR demonstrates significant carbon emission reduction,with an intensity of only 24%-32% compared to private vehicles and 47%-89% compared to buses.Notably,HSR travel for Beijing-Tianjin intercity emits only 24% of private vehicle emissions,demonstrating the emission reduction benefits of transportation structure optimization.Additionally,predictive modeling reveals the potential for carbon emission reduction through energy structure optimization,providing a guideline for the development of effective transportation management systems.
文摘The study on the changes of stomatal sensitivity in relation to xylem ABA during periodical soil drying and the effect of leaf water status on the stomatal sensitivity has confirmed that xylem ABA concentration is a good indicator of soil water status around roots and the relation between xylem ABA concentration and predawn leaf water potential remained constant during the three consecutive soil drying cycles based on the slopes of the fitted lines. The sensitivity of stomata to xylem ABA increased substantially as the soil drying cycles progressed, and the xylem ABA concentration needed to cause a 50% decrease of stomatal conductance was as low as 550 nmol/L in the next two soil drying cycle, as compared with the 750 nmol/L ABA in the first cycle of soil drying. The results using the split_root system showed that leaf water deficit significantly enhanced the stomatal response to xylem ABA and the xylem ABA concentration needed to cause a 50% decrease in stomatal conductance was 2 to 4 times smaller in the whole_root_drying treatment than those in the semi_root_drying treatment. These results suggested that the sensitivity of stomata to xylem ABA concentration is not a fixed characteristic.
基金financially supported by the National Natural Science Foundation of China(NSFC)(Nos.62004137,21878257 and 21978196)the Natural Science Foundation(NSF)of Shanxi Province(No.201701D221083)+5 种基金the Key Research and Development Program of Shanxi Province(No.201803D421079)the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(No.2019L0156)the Shanxi Provincial Key Innovative Research Team in Science and Technology(No.201605D131045–10)the Research Project Supported by Shanxi Scholarship Council of China(2020–050)Horizontal Project(203010675-J)Liaoning Baiqianwan Talents Program。
文摘Electrocatalytic reduction of Cr(Ⅵ)to less toxic Cr(Ⅲ)is deemed as a promising technique.Conventional electrocatalytic reduction is always driven by a constant cathodic potential,which exhibits a repelling action to Cr(Ⅵ)oxyanions in wastewater and consequently suppresses reduction kinetics.In order to remarkably accelerate Cr(Ⅵ)electrocatalytic reduction,we applied a pulsed potential on an Fe^(2+)-NiFe LDH/NF electrode synthesized by in situ growth of Fe^(2+)-doped NiFe LDH nanosheets on Ni foam using a spontaneous redox reaction.Under anodic potential section,HCrO_(4)^(–) anions are adsorbed on the electrode surface and reduced to Cr(Ⅲ)by Fe^(2+).Then,Cr(Ⅲ)ions are desorbed from the electrode surface under coulombic force.The regeneration of Fe^(2+) and direct reduction of Cr(Ⅵ)are achieved under cathodic potential section.The pulsed potential can achieve complete elimination of Cr(Ⅵ)within 60 min at an initial concentration of 10 mg L^(-1),and the removal efficiency shows a 60%increase with respect to that under constant cathodic potential.
基金The Strategic Priority Research Program of the Chinese Academy of Sciences under contract Nos XDA13020301 and XDA13010500the Fund of Innovation Academy of South China Sea Ecology and Environmental EngineeringChinese Academy of Sciences under contract No.ISEE2018PY01。
文摘Harboring polyextremotolerant microbial topsoil communities,biological soil crusts(biocrusts)occur across various climatic zones,and have been well studied in the terrestrial drylands.However,little is known about the functional metabolic potential of microbial communities involved in the biogeochemical processes during the early succession of biocrusts on the tropical reef islands.We collected 26 biocrusts and bare soil samples from the Xisha Islands and Nansha Islands,and applied a functional gene array(GeoChip 5.0)to reveal nitrogen(N)cycling processes involved in these samples.Both physicochemical measurement and enzyme activity assay were utilized to characterize the soil properties.Results revealed the composition of N-cycling functional genes in biocrusts was distinct from that in bare soil.Additionally,microorganisms in biocrusts showed lower functional potential related to ammonification,denitrification,N assimilation,nitrification,N fixation,and dissimilatory nitrate reduction to ammonium compared to bare soils.Although the abundance of nifH gene was lower in biocrusts,nitrogenase activity was significantly higher compared to that in bare soils.Precipitation,soil physicochemical properties(i.e.,soil available copper,soil ammonia N and pH)and soil biological properties(i.e.,β-glucosidase,fluorescein diacetate hydrolase,alkaline protease,urease,alkaline phosphatase,catalase and chlorophyll a)correlated to the N-cycling functional genes structure.Nitrate N and ammonia N were more abundant in biocrusts than bare soil,while pH value was higher in bare soil.Our results suggested biocrusts play an important role in N-cycling in coral sand soil,and will be helpful in understanding the development and ecological functions of biocrusts on tropical reef islands.
基金supported by the National Key Research and Development Program of China(No.2018YFD1100600)Shanghai Municipal Government State-Owned Assets Supervision and Administration Commission(No.2022028)。
文摘The significant increase in the demand for biomass waste treatment after garbage classification has led to housefly larvae treatment becoming an attractive treatment option.It can provide a source of protein while treating biomass waste,which means that nutrients can be returned to the natural food chain.However,the performance of this technology in terms of its environmental impacts is still unclear,particularly with regards to global warming potential(GWP).This study used a life cycle assessment(LCA)approach to assess a housefly larvae treatment plant with a treatment capacity of 50 tons of biomass waste per day.The LCA results showed that the 95% confidence intervals for the GWP in summer and winter were determined to be 24.46-32.81 kg CO_(2) equivalent(CO_(2)-eq)/ton biomass waste and5.37-10.08 kg CO_(2)-eq/ton biomass waste,respectively.The greater GWP value in summer is due to the longer ventilation time and higher ventilation intensity in summer,which consumes more power.The main GWP contributions are from(1)electricity needs(accounting for 78.6% of emissions in summer and 70.2%in winter)and(2)product substitution by mature housefly larvae and compost(both summer and winter accounting for 96.8% of carbon reduction).
文摘Two estimaton methods are used to calculate the theoretical reservoir potential of China's oceanic thermal energy. One is based on the measured temperature difference between the surface water and the deep water, the other on the net radiation energy income from solar insolation either measured or deduced. The results from these two methods are compared and examined. Then, the maximum amount of the exploitable thermal energy is calculated based on the assumption of a Carnot cycle efficiency. In the process of estimation, such factors as water depth, seasonal water temperature variation and geographic location have been taken into account.The theoretical reservoir capacity and the exploitable quantity of the thermal energy of China's four seas are thus estimated separately.
文摘电解锰渣是电解金属锰过程产生的固体废弃物,目前主要以堆存方式进行处置,因为其含有重金属、溶解锰和氨氮等有害成分,对土壤、水体和生态环境存在造成严重污染的潜在风险,是当前亟需解决的重要问题;因此,推动电解锰渣的资源化利用,实现其向资源的有效转化,已成为电解锰行业缓解资源环境压力、推动绿色低碳转型的重要方向。采用生命周期评价方法,研究电解锰渣应用于水泥和蒸压砖替代原料的资源和环境综合效益,通过与传统堆存处置、水泥及蒸压砖常规生产工艺的环境影响进行对比,探讨了电解锰渣不同资源化利用路径在节约资源、降低全球变暖潜力、减少环境影响等方面的影响。结果显示,与传统生产工艺相比,每吨电解锰渣的资源化利用可以降低约0.66~1.96 kg Cu当量的矿产资源耗竭影响和43.00~136.77 kg油当量的化石能源耗竭影响;在温室气体减排方面,利用每吨电解锰渣生产32.5强度等级硅酸盐水泥、42.5强度等级硅酸盐水泥以及蒸压砖产品,可分别降低816.75、926.71、300.89 kg CO_(2)当量的全球变暖潜力;在环境影响指标值方面,利用电解锰渣生产42.5强度等级硅酸盐水泥情景下的综合表现优于其他情景,颗粒物生成指标降低1.25 kg细颗粒物(PM 2.5)当量,陆地酸化指标降低4.12 kg SO_(2)当量,陆地生态系统毒性指标降低361.86 kg 1,4-二氯苯当量。
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB15020402, XDB15020302)the Natural Science Foundation of China (41571130063, 41430858)
文摘Microorganisms are major drivers of elemental cycling in the biosphere. Determining the abundance of microbial functional traits involved in the transformation of nutrients, including carbon(C), nitrogen(N), phosphorus(P) and sulfur(S), is critical for assessing microbial functionality in elemental cycling. We developed a high-throughput quantitative-PCR-based chip, Quantitative microbial element cycling(QMEC), for assessing and quantifying the genetic potential of microbiota to mineralize soil organic matter and to release C, N, P and S. QMEC contains 72 primer pairs targeting 64 microbial functional genes for C, N, P, S and methane metabolism. These primer pairs were characterized by high coverage(average of 18–20 phyla covered per gene)and sufficient specificity(>70% match rate) with a relatively low detection limit(7–102 copies per run). QMEC was successfully applied to soil and sediment samples, identifying significantly different structures, abundances and diversities of the functional genes(P<0.05). QMEC was also able to determine absolute gene abundance. QMEC enabled the simultaneous qualitative and quantitative determination of 72 genes from 72 samples in one run, which is promising for comprehensively investigating microbially mediated ecological processes and biogeochemical cycles in various environmental contexts including those of the current global change.
基金Projects(71633006,71403298) supported by the National Natural Science Foundation of ChinaProjects(14YJCZH045,15YJCZH019) supported by the Ministry of Education of Humanities and Social Science,China
文摘Assessing and accounting for material consumption and environmental impact are necessary to measure environmental externalities of the aluminum industry and to construct an ecological civilization.In this research,life cycle assessment(LCA)theory was used to assess the environmental impact of primary aluminum based on the lime soda Bayer process and different power generation modes,and the sources and distributions of the four selected impact categories were analyzed.The results show that,(1)Negative environmental impact of aluminum industry generally occurs from alumina extraction,carbon anode fabrication and electrolysis,particularly electrolysis and alumina extraction.Primary energy demand(PED),water use(WU),global warming potential(GWP)and freshwater eutrophication potential(FEP)are main environmental impact categories.(2)The environmental load with thermal power is higher than that with hydropower,e.g.,for the former,the greenhouse gas emission coefficient of 21800 kg CO2 eq/t(Al)will be generated,while for the latter,4910 kg CO2 eq/t(Al)will be generated.(3)Both power mode methods reflect the energy structure,whereas direct emissions reflect the technical level,indicating the potential for large energy savings and emission reductions,and some policies,related to clean power,energy efficiency and technological progress,should be made for emission reduction.
基金supported by the Fundamental Research Funds for the Central Universities(Grant No.310821173701)Natural Science Basic Research Program of Shaanxi(Grant No.2020JQ-379)。
文摘Highway frost heave and thawing settlement caused by water migration towards the freezing front and ice lens development is widespread in the alpine meadow area of the southeast QinghaiTibet Plateau(QTP).A laboratory experiment on a highway reconstruction and expansion project in the QTP was carried out in this work to analyze the effects of fine particle content,initial water content,and the number of freeze-thaw cycles(FTCs)on frost depth,temperature gradient(Grad T),total water intake,and water intake flux.Based on the results of the laboratory experiment,a modified model of migration potential related to fine particle content,freeze-thaw history,and freezing time was established.The results show that,with the increase of fine particle content,the frost depth of soil decreases,the curve of total water intake over time is transformed from an Sshape to an arch,and the curve of water intake flux over time is transformed from a peak shape to descending shape.The variation trend of migration potential with freezing time and the freeze-thaw history is the same as that of water intake flux with freezing time and freeze-thaw history.The variation trend of soil intake flux can be used as a reference to determine the variation trend of soil migration potential.This study provides a reference for the design and construction of highway subgrade in the alpine meadow area of the QTP.
基金Supported by National Key Research and Development Program of China during the 13th Five-Year Plan Period(No.2017YFC1702100)Major Program of Science and Technology Innovation in Medicine and Health Industry from Changchun City(No.18YJ013)
文摘OBJECTIVE:To investigate the effect of Renshenwuweizi decoction(RSWWZ decoction)on the growth of non-small cell lung cancer cells in vitro.METHODS:A549 non-small cell lung cancer cells were divided into two groups:control and RSWWZ decoction treatment groups.Cell Counting Kit-8 was used to measure the inhibitory effect of RSWWZ decoction on the growth of A549 cells.4’,6-diamidino-2-phenylindole staining and Annexin V-fluorescein isothiocyanate/propidium iodide double staining were used to investigate apoptosis in A549 cells following RSWWZ decoction treatment,and the mitochondrial membrane potential of treated cells was detected with Rhodamine 123.Cell cycle progression was analyzed by flow cytometry.The m RNA levels of p53,Bax,B-cell lymphoma-2(Bcl-2)and p21 were measured by quantitative real-time reverse transcription polymerase chain reaction.The protein expressions of p53,Bax,Bcl-2,p21,cyclin-dependent kinases 2(CDK2),and cyclin A were detected by Western blot.RESULTS:RSWWZ decoction reduced the viability of A549 cells in a dose-dependent manner by inducing apoptosis and decreased mitochondrial membrane potential.RSWWZ decoction increased p53 and Bax expression and decreased Bcl-2 expression in a dose-dependent manner.RSWWZ decoction also induced an S-phase cell cycle arrest by increasing p21 and decreasing cyclin A and CDK2 expression.CONCLUSION:In vitro experiments revealed that the Renshenwuweizi decoction-induced decrease in A549 cell proliferation was achieved by inducing apoptosis and S-phase cell cycle arrest via the p53 pathway.These findings provide the experimental basis for Renshenwuweizi decoction treatment of lung cancer.
文摘This study presents the effect of excavator model, loading operation location, shift availability and truck-shovel combination on loading cycle time and productivity of an open-pit mine. The loading cycle time was used to assess the material loading system performance which is one of the key components of the total cycle time for material transportation in an open-pit mine. Loading is among the components of cycle time during which material is being handled. The data analyzed?was?collected from a computerized dispatch system at GGM from which 62,000 loading dispatches per month involving several shifts, 14 excavators and 49 trucks were loaded. About 4465 dispatches per excavator and 1276 dispatches per truck were assessed using loading cycle time data for each dispatch for a period of four months (between August and December). Under fixed tonnage loaded and waste type (33 t of non-acid forming waste rock),?it was observed that loading cycle time depends on excavator model, location and truck being loaded. Average cycle times, PDFS?and CDFS of loading cycle time series were used to identify differences in performance under different situations. It was concluded that shift availability for excavators, loading location, excavator model and truck-shovel combinations strongly affect the productivity during loading process in an open-pit mine.
文摘In this paper, the performance of a waste rock transportation process in an open pit mine was assessed by using cycle time data. A computerized truck-excavator dispatch system was used to record the cycle times. The process was broken into seven steps (or components of the total cycle), durations of which were recorded for a period of 1 month, leading to N = 60,690 data points or dispatches. The open pit mine studied consisted of 12 waste types loaded by 14 excavators and hauled by 49 trucks (at a trucks-to-excavator ratio of 3.5:1) in 75 changing locations. The string-type data was coded using integers to allow a FORTRAN code to extract process performance parameters using statistical analysis. The study established a wide range of parameters including: the waste material generation rate (about 1.73 million t/month, 81% comprising waste rock), truck fill factor, f, total cycle time (Tct), production capacity, theoretical cycle time, non-productive cycle time Tnp, and cycle time performance ratio (CTPR), denoted as Tpr. The factors affecting the process performance include: truck model, excavator model, location (haul distance and road conditions) and material type. For a fixed material type and tonnage, the PDFs of the cycle time components were logarithmic in nature, capable of differentiating performance variations under different factors. It was concluded that the performance of the waste material transportation system in this mine was determined to be acceptable due to mean value of Tpr = 2.432 being closer to unity. Reduction measures were suggested to minimize the cycle time for the process bottlenecks determined from Pareto analysis (that is, full haul, empty haul and loading processes).
基金Supported by the National Science and Technology Major Project of China(2015ZX02104003)the Natural Science Foundation of Hubei Province of China(2018CFC889)
文摘To obtain a longer natural period in single degree of freedom(SDF) conservative vibration isolation systems, many scholars have proposed different methods. This paper uncovers a clockwise energy cycle existing in a mass-spring system, in which the potential energy and kinetic energy convert with each other, and the natural period is determined by the magnitude of the energy cycle. Compared to water flow inside a pipe, the previous methods can be consolidated into two methods to make the energy cycle narrower;one is to optimize the parameters directly, the other is to indirectly add an anticlockwise energy cycle to the original one. The anticlockwise energy cycle has the characteristic of gravitational potential energy or elastic potential energy that reduces with displacement. The highly abstract method can provide a better optimization tool to design a practice system.
基金supported by the National Natural Science Foundation of China[grant numbers 41675062 and 41375096]the Research Grants Council of the Hong Kong Special Administrative Region,China[project numbers City U 11306417 and 11335316]。
文摘As natural weather disasters,tropical cyclones(TCs)are destructive in proportion to their peak intensity.This study investigates the association of North Atlantic,western North Pacific,and eastern North Pacific TC peak intensities with tropospheric air temperature,respectively,by applying NCEP–NCAR and MERRA reanalysis data.Both the correlation between TC peak intensity and air temperature and the difference in air temperature between strong and weak TC peak intensity conditions reveal that significant cooling of the tropopause and uppertropospheric warming are accompanied by strengthening TC peak intensity for North Atlantic TCs,suggesting an important effect of upper-tropospheric static stability on TC peak intensity.However,warming in the lower troposphere is associated with strong TC peak intensity for eastern North Pacific TCs,indicating a major effect of lower-tropospheric static stability on TC peak intensity.The peak intensity of western North Pacific TCs is mainly affected by vertical wind shear,not the atmospheric temperature.
文摘This study covers the problem that most products become less competitive especially in the decline stages of their life cycle as most companies do not put adequate emphasis on using networked manufacturing systems in the entire life cycle of a single product. The study employed a non-experimental approach to collect data. The research paper relied on secondary data for further analysis. The secondary sources used in this paper have been referenced progressively in the entire paper. The paper found that most companies are often faced with the challenge of coping with quality management in a product life cycle. Also, it found that networked manufacturing systems have provided a new paradigm for real-time monitoring and control at various life stages. The paper is divided as following parts： section 1 is about the background and problem statement. Section 2 comes through literature review including theoretical ＆ empirical review. Section 3 explains the procedures and methods that were used in carrying out the study. It explains how data collection was carried out and how data analysis was performed. Section 4 is about the results the paper found. Section 5 is a discussion of the results presented.
